FEB 2? L v..,.. · 2016. 6. 14. · FEB 2? SUPERFUND DIVISION L v..,.. MW #1217431.010305 Ms. Diana...

OU&2L,

MONTGOMERY WATSON

February 23. 1999

RECEIVED

FEB 2?SUPERFUND DIVISION

L v..,..

MW #1217431.010305

Ms. Diana EngemanEPA Project CoordinatorSuperfund Branch, Waste Management DivisionU.S. Environmental Protection Agency. Region VII726 Minnesota AvenueKansas City, KS 66101

RE:: Former Manufactured Gas Plant SiteClinton, IowaDocket No. VII-97-F-0020

Dear Diana:

Enclosed for your use and files are copies of the qua l i ty control data from the U n i v e r s i t y ofIowa Hygienic Laboratory for the soil and groundwater split samples collected at theClinton manufactured gas plant site. Montgomery Watson reviewed the data and updatedthe project database by assigning "I" flags to samples potential ly effected by q u a l i t y controldata outside the prescribed l imi ts . For your convenience, an electronic copy of the updateddatabase files w i l l be sent via e-mail.

If you have any questions, please feel free to contact Bruce Greer at (608) 252-3948 or me.

Sincerely,

Randy J. Kroneman. P.G.Project Manager

/rjk:vasEnclosurescc: Bruce Greer, Alliant/Interstate Power Company

Johanshir Golchin. Iowa Department of Natural Resources (2 copies)Laura Clemenson. Sverdrup Environmental

SOQ085842SUPERFUND RECORDS

1 1 1 0 / A.j'iyj[)(;:, Moi'if-'j lW3?? 7938

Tel SIS 253 0830Fax 515253959?

, ?o?i Response Factor Report 7201

Method : J:\7201\METHODS\SOIL8260.M (RTE Integrator)Title : GC/MS TCL 8260 volatiles for low level soilsLast Update : Mon Dec 15 08:50:31 1997Response via : Continuing Calibration

Calibration Files

1)2)3)4)5)6)7)8)9)

10)11)12)13)14)15)

16)17)18)19)20)21)22)23)24)25)26)27)

9 Q \£. O /

29)30)31)32)33)34)35)36)37)38)39)

10100

ITTCTCTMTCTTTGTTCTCSTCT

T

TCTCMTCMTCTTCTCTCTCTCTC

ISTMTCTCTMTCT f~*

GTCTCS"-./-,

=5349103. D 20=5349105. D 200

Compound

Bromochlorome thaneChl or ome thaneVinyl ChlorideBromome thaneChloroethane1 , 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2 -Dichloroethene (t1 , 1 -Dichlo roe thaneChloroform1 , 2 - Dichlo roe thane-d41 , 2 -Dichlo roe thane2 -Butanone

1 , 4 -Dif luorobenzene1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodlchlorome thaneCis- 1 , 3 -DichloropropeTrans - 1 , 3 -Dichloropro1,1,2 -TrichloroethaneDibromochlorome thaneBromof orm

("*}") 1 (~>T~O ^ n 7 pn £» - (\ 5^ _ 1 1 A. \J 1_ \-J *^ ~ » 1 £* C 1 1C V_4 -J

Toluene-d84 -Methyl -2 -PentanoneTolueneTetrachloroethene2 -HexanoneChlorobenzeneEthyl benzeneXylene (total)StyreneBromof luorobenzene1,1,2,2 -Tetrachloroet

11101311133231

00100000000

101001001VJ

0

= 534!= 534!

10

.707

.405

.230

.891

.400

.807

.055

. 872

.795

.357

. 942

. 846

.558

.874

.642

.564

. 131

.416

.453

.833

. 727

. 707

.405

. 599

.654

.286

. 976

.581

. 555

.747

. 103

. 528

.641

. 173

. 855

. 858

3131

11101311133231

00_^

00rs•-J

00000

10]_0rf\^

•i

^~

04 .D06 .D

20

.502

.142

.088

.808

.276

.463

.OG6

.684

.647

.084

.640

.455

.237

.561

.581

.506

.023

.371

.413

.765

.664

.651

.370

.551

.591

.113

.851

.435

.498

.605

. 993

.475

.578

.054

.713

. 767

11101301i.1.33231

00000000000

10100000100

50

50

.554

. 189

. 105

.830

.283

.323

. 928

.617

.618

.007

.539

.623

. 112

.508

- - T c

. 576

. 507

. 993

. 366

.401

.745

.648

.641

.360

. 541

.604

. 199

.805

.394

.492

.559

. 968

.465

.574

.048

.774

.755

1

-t rpT-vD ID

1 .0 .1 .0 .1 .3 .0 .1 .1 .3 .3 .2 .3 .1 .

-t >"pr-iD I D

0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0.

"* TTDID

1 .0 .1 .0 .0 .0 .0 .0 .1 .0 .0 .

= 53

00

401 1933 0033 1804 0257 1293 3723 0615 1603 1012 3524 3430 2043 2293 1

585 0514 0988 0355 0403 0757 0652 0640 0352 0538 0570 0

134 1781 0377 1477 0557 0955 0462 0573 0048 1726 0713 C

49S01

200

.518

. 887

.090

.841

.301

.387

.669

.641

.628

. 063

.553

.409

.999

.240

.598

. 524

. 998

.357

.412

.768

. 667

. 658

.355

. 539

. 584

. 175

.763

.400

.478

. 544

. 968

.472

.583

.070

.733

. 702

I .

11101301133231

00100000000

101c000c10'•J

D

A.vg

. 536

. Ill

. 109

. 835

. 304

.455

. 888

.686

. 658

. 104

. 640

. 552

. 190

.495

. 596

.523

. 026

.373

.417

. 774

.672

.660

. 368

.553

.601

. 182

. 835

.437

. 500

. 602

. 997

.430

. 591

.078

.761

. 759

%

71864A*i

620644477

16

44565.144545

51C56

1365i-i4™3

RSD

.22

. 35

. 56

.21

. 32

. Cl

. 31

.40

. 71

.67

. 30

.23

. 04

.86

. 51

. 59

. 34

. 63

. 04

.42

. 77

.21

. 82

. 66

.38

. 71

. 19

. 73

.45

. 95

. 07

. 71

. 37

. 95

. 4 9

. * t

= Out of RangeSOIL8260.M Mon Dec 15 11:21:03 1997 ?aae 1

Quantitation Report (Not Reviewed)

Data File : J:\7201\DATA\5349S02.D Position: 1Acq On : 15 Dec 1997 8:21 am Operator: JNSample : VSTD050 , INIT.CAL. , 8260-Heated Purge Inst : 7201Misc : 5ul V-1147A+5ul V-1147B+5ml ofw Multiplr: 1.00MS Integration Params: rteint.pQuant Time: Dec 15 8:49 1997 Quant Results File: SOIL8260.R1

Quant MethodTitleLast UpdateResponse viaDataAcq Meth

M (RTE Integrator)for low level soils,

J: \7201\METHODS\SOIL8260GC/MS TCL 8260 volatilesMon Dec 15 13:34:11 1997Continuing Cal File: J:\7201\DATA\5314S02SOIL8260

,D

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) Bromochloromethane16) 1 , 4 -Dif luorobenzene28) Chlorobenzene-d5

System Monitoring Compounds13) 1, 2-Dichloroethane-d4Spiked Amount 50.00029) Toluene-d8Spiked Amount 50.000

38) Bromof luorobenzeneSpiked Amount 50.000

Target Compounds2) Chloromethane3) Vinyl Chloride4) Bromomethane5) Chloroethane6) 1 , 1 -Dichloroethene7) Carbon Disulfide8) Acetone9) Methylene Chloride

101119

11Range

15Range

23Range

.31

.82

.56

.1976.2088.7286

128114117

65- 114

98- 110

95- 115

108579543768465874

284756Recovery

558694Recovery

360595Recovery

505050

72

50

62

.00

.00

.00

.76=. 12=.37=

ug/Kgug/Kgug/Kg

ug/Kg145.52ug/Kg100 .24ug/Kg124 .74

0.010.000.00

0.00%#

0.00%

0 .00%#

Qvalue45557777

10) 1, 2 -Dichloroethene (total) 911) 1 , 1 -Dichloroethane12) Chloroform14) 1, 2 -Dichloroethane15) 2-Butanone17) 1, 1, 1-Trichloroethane18) Carbon Tetrachloride19) Benzene20) Trichloroethene21) 1 , 2 -Dichloropropane22) Bromodichloromethane23) Cis-1, 3-Dichloropropene

810119

10111112121314

24) Trans- 1 , 3 -Dichloropropene 1525) 1 , 1 , 2-Trichloroethane26) Dibromochloromethane27) Bromof orm30) 4-Methyl-2-Pentanone31) Toluene32) Tetrachloroethene33) 2-Hexanone

16172314151716

.81

.03

.79

. 91

.20

. 99

.01

.86

.78

.86

.01

.35

.46

.68

.16

.43

.55

.88

.38

.55

.76

.22

.77

.03

.03

.40

. 19

.20

5062946496764384966383624397

1177813063837575971291734391

16443

168707 121129132 14311998490164

1393083608461C0810175584351254m 1326477384240337896163744312953275748539757199217213216405269352300343700195491294125323403375202649606229097260464

8279643537540553566542565443465666576451534854464046

.25

.68

.71

.68

. 54

.70

.45

. 11

.24

. 12

.09

.03

. 63

. 11

.01

. 52

.26

.21

. 08

.21

.00

.63

.03

. 13

.69

. 58

.64

.57

ug/Kgug/Kgug/Kgug/Kgug/Kg#ug/Kgug/Kgug/Kgug/Kg#ug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kg

10099979880999591

99999910099

10088949999999899100100979910093

(#) = qualifier out of range (m) = manual integration5349S02.D SOIL8260.M Mon Dec 15 08:49:58 1997 Page 1


Data File : J:\7201\DATA\5349S02.D Position: 1Acq On : 15 Dec 1997 8:21 am Operator: JNSample : VSTD050 , INIT.CAL. , 8260-Heated Purge Inst : 7201Misc : 5ul V-1147A+5ul V-1147B+5ml ofw Multiplr: 1.00MS Integration Params: rteint.pQuant Time: Dec 15 8:49 1997 Quant Results File: SOIL8260.RE


M (RTE Integrator)for low level soils

J:\7201\METHODS\SOIL8260GC/MS TCL 8260 volatilesMon Dec 15 13:34:11 1997Continuing Cal File: J:\7201\DATA\5314S02SOIL8260

.D

Compound R.T. Qlon Response Cone Unit Qvalue

34)35)36)37)39)

ChlorobenzeneEthylbenzeneXylene (total)Styrene1,1,2,2 -Tetrachloroethane

1919212123

.69

.83

.68

.81

.47

11210610610483

450832216489267209488108351533

4950505354

.68

.42

.93

.69

.24

ug/Kgug/Kg#ug/Kgug/Kgug/Kg

10089889099

(#) = qualifier out of range (m) = manual integration5349S02.D SOIL8260.M Mon Dec 15 08:49:58 1997 Page 2

Quantitation Report

Data File : J:\7201\DATA\5349S02.DAcq On : 15 Dec 1997 8:21 amSample : VSTD050 , INIT.CAL. , 8260-Heated PurgeMisc : 5ul V-1147A+5ul V-1147B+5ml ofwMS Integration Params: rteint.pQuant Time: Dec 15 8:49 1997

Position:Operator:Inst :

1JN7201

Multiplr: 1.00

Quant Results File: SOIL8260.RES

MethodTitleLast UpdateResponse via

Abundance

650000 •I

i

600000 !J

550000J

500000

450000 i

400000

350000

300000 •

250000

200000

150000

100000 '•

50000•\

J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soils.Mon Dec 15 13:34:11 1997Continuing Cal File: J:\7201\DATA\5314S02.D

TIC: 5349S02.D

1 .

;,uu.iw.Tlme-> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00

5349S02.D SOIL8260.M Mon Dec 15 08:50:02 1997

2000 2loO 22oO 2.OO 24.00 25.0026.00

Page 3


Continuing Calibration Report 7201

J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samplesThu Dec 18 11:40:00 1997Continuing Calibration

Continuing Calibration File: 5352S07.D

Min. RRF :Max. RRF Dev :

Compound

0.000 Min. Rel. Area : 50%25% Max. Rel. Area : 150%

AvgRF CCRF

(tt) = Out of Range5352S07.D CS8260.M Thu Dec 18 11:40:16 1997

%Dev Area%

123456789

1011121314151617

181920212223242526272829303132

333435363738394041

I

TTCTCTTTCMTTTGTTCTCSTCT

ITCTCTCMTCMTTCI

TCTCTCTTCTC

ISTTCMT*^i L.L

TCM

TC

Bromochlorome thaneDichlorodif luorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luorome thane1, 1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2-Dichloroethene (total)1 , 1 -DichloroethaneChloroform1 , 2 -Dichloroethane-d41 , 2 -Dichloroethane2 -Butanone

1 , 4 -Dif luorobenzene1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodichloromethaneDibromome thane2 -ChloroethylvinyletherCis-1 , 3-DichloropropeneTrans -1,3 -Dichloropropene1,1,2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof orm

Chlorobenzene-dSToluene-d84 -Methyl -2 -PentanoneTolueneTetrachloroethene2 -HexanoneChlorobenzene1,1,1, 2 -TetrachloroethaneEthylbenzene

13111031401134230

100100000000000

110100100

.000

.324

.528

.405

.269

.897

.061

.479

.665

.480

.882

.874

.545

.048

.529

.199

.749

.000

.617

.543

.053

.378

.411

.752

.352

.062

.631

.570

.297

. 533

.481

.431

.000

.216

. 117

.489

.534

.293

.016

.484

.484

12111021401133220

100000000000000

110100000

.000

.118

.260

.284

.149

.853

.781

.401

.172

.407

.695

.766

.318

.746

.383

.747

.601

.000

.580

.517

.976

.350

.376

.686

.322

.056

.574

.505

.262

.472

.435

.371

.000

.251

.097

.427

.517

.130

.960

.458

.466

0.36.17.8.9.4 .9.5.10.15.10.5.6.7.5.14.19.

0 .6.4 .7.7.8.8.8 .10.9.

11.11 .11 .9.

13 .

0 .-2 .16.4 .3 .

55.5.5.3 .

03#565913610745817

007365838048558

095116$657

1195680849799971009792

1011021031021149895

121102104101102103103104101101101102102104100

11811992

10210345**

1C11C2102

Page 1


Method : J:\7201\METHODS\CS8260.M (RTE Integrator)Title : GC/MS TCL + CS 8260 for 5ml water samples.Last Update : Thu Dec 18 11:40:00 1997Response via : Continuing Calibration


Min. RRF : 0.000 Min. Rel. Area : 50%Max. RRF Dev : 25% Max. Rel. Area : 150%

Compound AvgRF CCRF %Dev Area%

4243444546474849

GTCTCSTCTTTT

Xylene (total)StyreneBromofluorobenzene1,1,2, 2 -Tetrachloroethane1,2,3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene

01000000

.599

.072

.767

.473

.385

.953

.982

.866

01000000

.563

.018

.764

.440

.333

.926

.948

.836

6507

13233

.0

.0

.4

.1

.5

.8

.5

.5

10010011610299102102101

(#) = Out of Range SPCC's out = 0 CCC's out = 05352S07.D CS8260.M Thu Dec 18 11:40:17 1997 Page 2


J:\7201\DATA\5352S07.D18 Dec 1997 11:02 amVSTD050 , CONT.CAL. , 82605ul V-1147A+5ul V-1144E+5ml ofw

MS Integration Params: rteint.pQuant Time: Dec 18 11:35 1997

Data FileAcq OnSampleMisc

Position:Operator:Inst :Multiplr:

1JN72011.00

Quant Results File: CS8260.RES


J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Mon Dec 08 10:36:44 1997Continuing Cal File: J:\7201\DATA\5342S02.DCS8260


1)18)33)

Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5

10.11.19.

308157

128114117

113733629589506148

505050

.00

.00

.00

ug/1ug/1ug/1

000

.00

.00

.00

System Monitoring Compounds15) 1,2-Dichloroethane-d4 11.18 65Spiked Amount 50.000 Range 76 - 11434) Toluene-d8 15.20 98Spiked Amount 50.000 Range 88 - 110

44) Bromofluorobenzene 23.72 95Spiked Amount 50.000 Range 86 - 115

271030Recovery

633141Recovery

386616Recovery

47

50

49

.64

.55

.39

ug/195.

ug/1101.ug/198 .

28%

10%

78%

0

0

0

.00

.00

.00

Target Compounds2)3)4)5)6)7)8)9)

10)11)12)13)14)16)17)19)20)21)22)23)24)25)26)27)28)29)30)31)

Dichlorodi f luoromethaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luoromethane1 , 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1, 2 -Dichloroethene (total)1 , 1 -DichloroethaneChloroform1 , 2 -Dichloroethane2 -Butanone1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodichlorome thaneDibromome thane2 -ChloroethylvinyletherCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1, 2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thane

445556777798

10119

10111112121313161415161617

.32

.80

.01

.78

. 89

.29

. 19

.99

.22

.85

.77

.87

.01

.35

.63

.68

. 15

.44

.55

.89

.39

.55

. 91

.54

.76

.22

.91

.77

85506294641019676438496638362439711778

1306383

1746375759776129

24087714331614604513063997064316266159286474483463181927882040623773784260783124716836036507532556461444022018223649143199820296635034361599317840164700297032273632

23333540414041403842434342413942424142424243414141424242

.45

.38

.23

.48

.63

.78

.78

.59

.72

.33

.31

.33

.84

. 12

.93

. 19

.85

.88

.30

.49

.49

.02

.71

.97

.77

.03

.34

.83

Qvalueug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1

100999999999997

100769593100100999799

10010099

10010094991001001009699

(#) = qualifier out of5352S07.D CS8260.M

range (m) = manualThu Dec 18 11:35

integration34 1997 Page 1

Quantitation Report




(Not Reviewed)

Position: 1Operator: JNInst : 7201Multiplr: 1.00



J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Mon Dec 08 10:36:44 1997Continuing Cal File: J:\7201\DATA\5342S02.DCS8260


32)35)36)37)38)39)40)41)42)43)45)46)47)48)49)

Bromoform4 -Methyl - 2 - PentanoneTolueneTetrachloroethene2-HexanoneChlorobenzene1,1,1,2 -TetrachloroethaneEthylbenzeneXylene (total)Styrene1,1,2,2 -Tetrachloroethane1,2,3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene

231415171619191921212323262627

.04

.11

.40

.19

.25

.69

.80

.84

.69

.81

.49

.90

.21

.40

.05

1735891164431121311061061048375146146146

2337434923572228426172765961

485653231642235915285100515374222464168517468741479736423099

413943431842434342424342434342

.21

.18

.26

.56

.93

.95

.42

.41

.45

.33

.45

.03

.10

.45

.89

ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1

99969999961009910099981001009910099

(#) = qualifier out of5352S07.D CS8260.M



Quantisation Report

Data File : J:\7201\DATA\5352S07.DAcq On : 18 Dec 1997 11:02 amSample : VSTD050 , CONT.CAL. , 8260Misc : 5ul V-1147A+5ul V-1144E+5ml ofwMS Integration Params: rteint.pQuant Time: Dec 18 11:35 1997



MethodTitleLast Update

: J:\7201\METHODS\CS8260.M (RTE Integrator): GC/MS TCL + CS 8260 for 5ml water samples.: Mon Dec 08 10:36:44 1997

Response via : Continuing Cal File: J:\7201\DATA\5342S02.DAbundanceI 8500001

800000;

750000ij

700000J

650000

600000

550000

500000

450000

400000

350000

300000

250000

200000

150000

100000

50000

0

TIC: 5352S07.D

ll

\ I 11 ,U 1,1————WV,V^

Tlme-> 5.00 6.00 7.00 8.00 9.00 1000 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27.00 28.00 29.00

5352S07.D CS8260.M Thu Dec 18 11:35:39 1997

3o!oo siloo

Page 3



J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soilsFri Dec 19 09:24:41 1997Continuing Calibration


Min. RRF : 0.000 Min. Rel.Max. RRF Dev : 25% Max. Rel.

123456789

101112131415

161718192021222324252627

282930313233343536373839

ITTCTCTMTCTTT1

GTTCTCSTCT

ITCTCMTCMTCTTCTCTCTCTCTC

ISTMTCTCiMTCTCGTCTCS

(#) = Out5353SC2 .D

Compound

Bromochlorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethane1 , 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2 -Dichloroethene (total)1, 1 -DichloroethaneChloroform1 , 2 -Dichloroe thane -d41 , 2 -Dichloroethane2 -Butanone

1 , 4 -Dif luorobenzene1,1, 1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneB r orr.od i c h 1 o r orr.e t ha neCis- 1 , 3 -DichlorcpropeneTrans -1,3 -Dichloropropene1,1,2 -TrichloroethaneDibromochlorome thaneBromof orm

Chlcrobenzene-d5Toluene-d84 -Methyl -2 - PentanoneTolueneTetrachloroethene2 -HexancneChlorobenzeneEthylbenzeneXyler.e i total)StyreneBrorrof luorcbenzene1,1,2,2 -Tet rachlcroethane

of Range SPCC'SOIL8260.M Fri Dec 19 09

Area :Area :

50%150%

AvgRF

1.1 .1 .1 .0 .1.3 .0 .1.J_ .

3 .3 .2 .3 .1.

1 .0 .0 .1 .0.0 .0 .c .0 .0 .0 .0 .

1 .1 .0.1 .0 .0 .0 .0 .0 .1 .0 .0 .

s out =:26 : 35

000536111109835304455888686658104640552190495

000596523026373417774672660368553601

000182835437500602997480591078761759

01997

CCRF

110101301123221

100u00G00000

1101c000n1

o0

ccc

. 000

. 168

. 956

.044

.772

.268

.436

.885

. 598

.626

.983

.482

. 513

. 971

.326

.000

.578

.510

. 984

.359

. 391

.742

. 625

. 609

.345

.535

. 584

. 000

.201

.733

. 376

.492

.484

. 953

.452

.560

. 043

.781

. 72C

' s cut = 0

%Dev

0231457200513-1

16

11

032436467632

0-11241

194553

-25

.0

. 9

. 0

.9

. 6

. 7

. 5

.4

.2

. 9

. 9

.3

.6

. 8

. 3

. 0

. 1

. 5

. 1

.6

.2

. 1

. 9

. 7

.2

.4

. 7

. 0

.6

.2

. 3

.6

. 7

.4

. 8

. 1

. 3

. 6

. 1

Area%

1068085

10099

10511010110510710510510210294

106107107105104103106102101102105103

10510596

10410591

1041021C3105106100

Paae !



J:\7201\DATA\5353S02.D Position: 119 Dec 1997 8:51 am Operator: JNVSTD050 , CONT.CAL. , 8260-Heated Purge Inst : 72015ul V-1147A+5U1 V-1144E+5ml ofw Multiplr: 1.00

MS Integration Params,: rteint.pQuant Time: Dec 19 9:23 1997 Quant Results File: SOIL8260.RE


M (RTE Integrator)for low level soils.

J: \7201\METHODS\SOIL8260GC/MS TCL 8260 volatilesThu Dec 18 08:17:58 1997Continuing Cal File: J:\7201\DATA\5352S02SOIL8260


1) Bromochloromethane16) 1 , 4 -Dif luorobenzene28) Chlorobenzene-d5

System Monitoring Compounds13) 1, 2-Dichloroethane-d4Spiked Amount 50.000

29) Toluene-d8Spiked Amount 50.000

38) Bromof luorobenzeneSpiked Amount 50.000

Target Compounds2) Chloromethane3) Vinyl Chloride4) Bromomethane5) Chloroethane6) 1 , 1 -Dichloroethene7) Carbon Disulfide8) Acetone9) Methylene Chloride

101119

11Range

15Range

23Range

.30

.82

.56

. 1976. 1988.7186

128114117

65- 114

98- 110

95- 115

115450577324490234

290080Recovery

588618Recovery

382976Recovery

505050

48

49

49

.00

.00

.00

.93=.89=. 77=

ug/Kgug/Kgug/Kg

ug/Kg97.86%

ug/Kg99.78%

ug/Kg99.54%

0.000.000.00

0.00

0.00

0 . 00

Qvalue45557777

10) 1 , 2 -Dichloroethene (total) 911) 1 , 1 -Dichloroethane12) Chloroform14) 1 , 2 -Dichloroethane15) 2-Butanone17) 1 , 1 , 1-Trichloroethane18) Carbon Tetrachloride19) Benzene20) Trichloroethene21) 1 , 2 -Dichloropropane22) Bromodichloromethane23) Cis- 1 , 3 -Dichloropropene

810119

10111112121314

24) Trans- 1 , 3 -Dichloropropene 1525) 1, 1, 2-Trichloroethane26) Dibromcchloromethane27) Bromoform30) 4-Methyl-2-Pentanone31) Toluene32) Tetrachloroethene33) 2-Hexanone

16172314151716

.79

.00

.77

.88

.19

.97

.01

.85

. 77

.85

.00

.34

.47

.68

. 15

.43

.55

.88

.38

.54

.76

.21

.76

.02

. 03

.39

. 19

.21

5062946496764384966383624397

117781306383757597

1291734391

16443

13490011040012047489089146429396742102127184531

4949515151505850

375533m 103344407401951343055153141333475294429568262207526225639428374360939351342199442308668337394359500674405241260237167

50515154515150515151515152515354515253

.32

.27

.15

.20

.48

.94

. 98

.41

.06

.45

.12

. 13

.18

.88

. 97

.94

.27

.39

.83

. 00

.30

.02

.89

.26

.63

.61

.36

.06

ug/Kgug/Kgug/Kgug/Kgug/Kg#ug/Kgug/Kgug/Kgug/Kgtfug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kg

100999798831009693

999999

10099

1009094

10098999999

10010097

1009994

(#) = qualifier out of range (m) = manual integration5353S02.D SOIL8260.M Fri Dec 19 09:24:09 1997 Page



J:\7201\DATA\5353S02.D Position: 119 Dec 1997 8:51 am Operator: JNVSTD050 , CONT.CAL. , 8260-Heated Purge Inst : 72015ul V-1147A+5ul V-1144E+5ml ofw Multiplr: 1.00

MS Integration Params: rteint.pQuant Time: Dec 19 9:23 1997 Quant Results File: SOIL8260.RE


J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soilsThu Dec 18 08:17:58 1997Continuing Cal File: J:\7201\DATA\5352S02.DSOIL8260


34)35)36)37)39)

ChlorobenzeneEthylbenzeneXylene (total)Styrene1,1,2,2 -Tetrachloroethane

1919212123

.69

.83

.67

.80

.46

11210610610483

467380221812274712511127353113

5152515254

.84

.60

.96

.38

.65

ug/Kgug/Kg#ug/Kg#ug/Kgug/Kg

10087879299

(#) = qualifier out of range (m) = manual integration5353S02.D SOIL8260.M Fri Dec 19 09:24:10 1997 Page 2

Quantitation Report

Data File : J : \7201\DATA\5353S02.D Position: 1Acq On : 19 Dec 1997 8:51 am Operator: JNSample : VSTD050 , CONT.CAL. , 8260-Heated Purge Inst : 7201Misc : 5ul V-1147A+5ul V-1144E+5ml ofw Multiplr: 1.00MS Integration Params: r teint .pQuant Time: Dec 19 9 :23 1997 Quant Results File: SOIL8260.RES

Method : J : \7201 \METHODS\SOIL8260 .M (RTE Integrator)Title : GC/MS TCL 8260 volatiles for low level soils.Last Update : Thu Dec 18 08:17:58 1997Response via : Continuing Cal File: J : \7201\DATA\5352S02.D

Abundance

800000

; 750000

700000

650000

600000

550000

500000

450000

400000

350000

300000

250000

200000

150000

100000

50000

TIC: 5353S02.D

Jiu'i ii

I-',0-

I

Time-> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27.00 28.00 29.00 30.00 31.00

5353S02.D SOIL8260.M Fri Dec 19 09:24:13 1997 Page

f, '



J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samplesMon Dec 22 08:34:24 1997Continuing Calibration



Compound AvgRF

123456789

1011121314151617

181920212223242526272829303132

333435363738394041

I


ITCTCTCMTCMTTCI

TCTCTCTTCTC

ISTTCMTCTTCM

TC

Bromochlorome thaneDichlorodif luorome thaneChlorome thaneVinyl ChlorideBromomethaneChloroethaneTrichlorof luorome thane1, 1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2-Dichloroethene (total)1, 1 -DichloroethaneChloroform1 , 2 -Dichloroethane-d41 , 2 -Dichloroethane2-Butanone

1 , 4 -Dif luorobenzene1,1, 1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodichlorome thaneDibromome thane2 -Chloroethyl vinyl etherCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1, 2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof orm

Chlorobenzene-d5Toluene-da4 -Methyl -2 -PentanoneTolueneTetrachloroethene2 -HexanoneChlorobenzene1,1,1, 2 -TetrachloroethaneEthylbenzene

13111031401i

34230

100100000000000

1101001cc

.000

.324

. 528

.405

.269

.897

.061

.479

.665

.480

. 882

. 874

.545

. 048

.529

.199

.749

. 000

.617

.543

. 053

.378

.411

.752

.352

. 062

.631

.570

.297

. 533

.481

.431

. 000

.216

. 117

.489

. 534

.293

. 016

.484

.484

CCRF

I2I11031401134230

100100000000000

110100100

.000

.163

.361

.365

.248

.916

.012

.540

.631

.574

. 934

. 974

. 704

.257

.486

.285

.812

.000

.660

.583

.127

.408

.439

.810

.387

.069

.682

.618

.321

. 580

.530

.482

.000

.229

.127

. 616

.587

.203

. 104

.533

. 529

%Dev Area%

0341021

-21

-40

-19-2-5-4-51

-2-8

0-7-7-7-7-7-7

-10-11-8-8-8-8

-10-11

0-1-8-8

-1030-8

-10-9

.0

. 9#

.9

.8

.6

. 1

.6

.2

. 7

.6

. 7

.3

. 5

.2

. 7

. 7

.4

.0

.0

. 5

. 0

. 7

.0

.6

. 1

.2

. 1

.5

.2

. 8

.3

. 9

.0

. 1

.8

. 5

. 0

. 9#

.6

. 0

.3

10450#75789193929594

11310099100101103102112

104100100100102103104107108103106107108108111

10410310610210361

103105102

(#) = Out of Range5356S02.D CS8260.M Mon Dec 22 08:36:51 1997 Page 1


Method : J:\7201\METHODS\CS8260.M (RTE Integrator)Title : GC/MS TCL + CS 8260 for 5ml water samplesLast Update : Mon Dec 22 08:34:24 1997Response via : Continuing Calibration


Min. RRF : 0.000 Min. Rel . Area :Max. RRF Dev : 25% Max. Rel. Area :

4243444546474849

GTCTCSTCTTTT

Compound

Xylene (total)StyreneBromof luorobenzene1,1,2,2 -Tetrachloroethane1,2, 3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene

50%150%

AvgRF

01000000

.599

.072

.767

.473

.385

.953

.982

.866

CCRF

01000110

.655

.187

.768

.529

.419

.062

.096

.956

%Dev Area%

-9-10-0

-11-8

-11-11-10

.3

.7

.2

.9

. 9

.4

.5

.4

103103103109110103105102

(#) = Out of Range SPCC's out = 0 CCC's out = 05356S02.D CS8260.M Mon Dec 22 08:36:52 1997 Page 2






1JN72011 .00



J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Fri Dec 19 16:43:40 1997Continuing Cal File: J:\7201\DATA\5352S07.DCS8260


1)18)33)


111

0.1.9.

308156

128114117

99006539587447141

505050

.00

.00

. 00

ug/1ug/1ug/1

0.0.

-0.

000002

System Monitoring Compounds15) l,2-Dichloroethane-d4 11.18 65Spiked Amount 50.000 Range 76 - 11434) Toluene-d8 15.19 98Spiked Amount 50.000 Range 88 - 110


246161 52.17 ug/1 0.00Recovery = 104.34%

549512 49.12 ug/1 -0.02Recovery = 98.24%

343625 50.30 ug/1 0.00Recovery = 100.60%


10)11)12)13)14)16)17)19)20)21)22)23)24)25)26)27)28)29)30)31)

Dichlorodifluorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorofluorome thane1, 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2 -Dichloroethene (total)1, 1-DichloroethaneChloroform1 , 2 -Dichloroethane2 -Butanone1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodichlorome thaneDibromome thane2 -ChloroethylvinyletherCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1, 2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thane

445556777798

10119

10111112121313161415161617

.30

.79

.00

.76

.88

.29

. 18

. 97

. 17

. 84

.76

.85

.00

.34

.57

.67

. 15

.42

. 54

. 87

.38

.54

. 90

. 53

.76

.21

. 91

.76

8550629464

101967643849663836243971177813063831746375759776

129

21411713478613518212357190644

298199152468458514284131914762001573667134215133251948037935618631476860808321990023700743682920886337418

367938333699173179313212286011

51545354535454553557575556596756565758585860625961616160

.06

.02

. 17

.33

.64

. 16

.98

.50

.23

. 05

.24

.81

.82

.78

.54

.92

.41

.74

.27

.47

. 99

.03

.31

.36

.25

.34

. 52

. 98


100999999999997

1006098959910010097

100100100991001009599

1001001009899

(#) = qualifier out of range (m) = manual integration5356S02.D CS8260.M Mon Dec 22 08:33:37 1997 Page 1

Quantitation Report

Data File : J:\7201\DATA\5356S02.DAcq On : 22 Dec 1997 8:00 amSample : VSTD050 , CONT.CAL. , 8260Misc : 5ul V-1147A-t-5ul V-1144E+5ml ofwMS Integration Params: rteint.pQuant Time: Dec 22 8:33 1997

(Not Reviewed)




J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Fri Dec 19 16:43:40 1997Continuing Cal File: J:\7201\DATA\5352S07.DCS8260


32)35)36)37)38)39)40)41)42)43)45)46)47)48)49)

Bromoform4 -Methyl -2 -PentanoneTolueneTetrachloroethene2-HexanoneChlorobenzene1,1,1, 2 -TetrachloroethaneEthylbenzeneXylene (total)Styrene1,1,2,2 -Tetrachloroethane1,2,3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene

231415171619191921212323262627

.03

.06

.39

.18

.23

.69

.79

.82

.67

.80

.47

.88

.21

.40

.06

1735891164431121311061061048375146146146

2600775667572235726254290660

493499238128236503292809530681236728187483474780489869427318

646556567757585658586062575757

. 91

. 15

.60

.77

.79

.51

. 18

.74

. 13

.28

.23

.97

.33

.79

. 16


10097100100971009998

10098

1009999

10099

(#) = qualifier out of range (m) = manual integration5356S02.D CS8260.M Mon Dec 22 08:33:38 1997 Page 2

Quantitation Report

Data File : J:\7201\DATA\5356S02.DAcq On : 22 Dec 1997 8:00 amSample : VSTD050 , CONT.CAL. , 8260Misc : 5ul V-1147A+5ul V-1144E+5ml ofwMS Integration Params: rteint.pQuant Time: Dec 22 8:33 1997




: J:\7201\METHODS\CS8260.M (RTE Integrator): GC/MS TCL + CS 8260 for 5ml water samples.: Fri Dec 19 16:43:40 1997

Response via : Continuing Cal File: J:\7201\DATA\5352S07.D

I I

Abundance TIC: 5356S02.D850000

800000

i 750000II

700000I

650000

; 600000I

550000

500000

450000

400000ij 350000

300000

250000

200000

150000

100000

50000

0Tlme-> 500 6.00 700 8.00 9.00 10.0011.0012.0013.0014.0015.0016.0017:0018.0019.0020.0021.0022.0023.0024.0025.0026.0027.0028.0029.0030.00

5356S02.D CS8260.M Mon Dec 22 08:33:42 1997

*o ,

II!I

Ii

li

i

Page 3

fMof-Vi'MethodTitleLast UpdateResponse via


J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples,Fri Feb 27 13:55:43 1998Continuing Calibration


Min. RRF : 0.000 Min. Rel . Area :Max. RRF Dev : 25% Max. Rel. Area :

Compound

1234S67891011121314. 51617

18.9:o212223242526272829)03132

3354

2556)7•89:0

;i-.2':3

:4

:5

-.6i7

I


ITCTCTCMTCMTTCI

TCTCTCTTCTC

ISTTCMTCTTCM

TCGTCTCSTCTT

Bromochlorome thaneDichlorodif luorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luorome thane1, 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2 -Dichloroethene (total)1 , 1 -DichloroethaneChloroform1 , 2 -Dichloroethane-d41 , 2 -Dichloroethane2 -Butanone

1 , 4 -Dif luorobenzene1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBr omod ichl or ome thaneDibromome thane2 -ChloroethylvinyletherCis- 1 , 3 -DichloropropeneTrans -1,3 -Dichloropropene1,1,2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBrorr.of orm

Chlorobenzene-d5Toluene-d84 -Methyl -2 -PentanoneTolueneTetrachloroethene2 -HexanoneChlorobenzene1,1,1,2 -TetrachloroethaneEthylbenzeneXylene (total)StyreneBromof luorobenzene1,1,2,2 -Tetrachloroethane1,2,3 -Trichloropropane1 , 3 -Di chlorobenzene

10101011401T

33120

100100000000000

10010000c00000c

50%150%

AvgRF

.000

.849

.283

. 967

. 344

.819

.774

.436

.953

.292

.696

.788

.281

.671

.351

.423

.553

.000

. 558

.499

. 058

. 385

. 393

.635

. 337

.000

. 584

.498

.291

.472

.438

.412

. 000

. 716

. 105

.409

. 523

.209

. 971

.427

.464

. 561

. 992

.592

.445

. 321

. 906

10111011501133120

100100000000000

T

0010c1

0.">••J

0^

co

Q

c

CCRF

.000

. 787

.240

. 069

.211

. 792

.763

.487

. 023

.353

. 704

. 839

.256

.643

.284

.334

.570

. 000

.547

.488

.053

.387

.379

.610

.334

.000

.573

.486

.285

.454

.427

.395

. 000

.740

. 105

.475

. 557

.203

. 015

.442

.437

. 581

. 040

.618

.453

. 310

. 930

%Dev

073

-10930

-3-1

-20-0-20043

-3

0220

-03300121324

0-30

-4-62-4-3-5-3-4-4-13

-2

.0

.3

.4

. 5

. 9

.3

.6

.5

.4

.9

.5

. 9

. 7

.8

. 9

. 7

. 0

.0

. 1

.2

.5

. 7

.4

. 9

. 7

.0

. 9

. 5

. 9

.6

. 5

. 1

. 0

.4

. 0

. 7

.6

.8

.6

. 5

. 0

.6

. 8

.4

.8

. 3

. 7

Area%

85768187778283878610488878686868796

8686868789878794Otf

889093919193

858783899088898339888889999283

1,4-Dichlorobenzene 0.936 0.950 -1.4 881,2-Dichlorobenzene 0.818 0.835 -2.1 90

(#) = Out of Range SPCC's out = 0 CCC's out = 0

5058S07.D CS8260.M Fri Feb 27 13:58:43 1998

Quantitation Report (QT Reviewed)

J:\7201\DATA\5058S07.D27 Feb 1998 1:22 pmVSTD050 CONT CAL5UL V1161E, V1161A + 5ML OFW

MS Integration Params: rteint.pQuant Time: Feb 27 13:58 1998



1LL72011.00

Quant Results File: CS8260.R2S


J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Thu Feb 26 08:53:10 1998Continuing Cal File: J:\7201\DATA\5057S02.DCS8260


1)18)33)


101119

.29

.81

.56

128114117

118710670107551551

50.50.50.

000000

ug/1ug/1ug/1

000

.00

.00

.00

System Monitoring Compounds15) 1,2-Dichloroethane-d4 11.18Spiked Amount 50.000 Range 7634) Toluene-dS 15.19Spiked Amount 50.000 Range 88

44) Bromofluorobenzene 23.72Spiked Amount 50.000 Range 86

65 152427 54.69 ug/1 0.00114 Recovery = 109.38%98 408161 54.99 ug/1 0.00110 Recovery = 109.98%95 340766 54.18 ug/1 0.01115 Recovery = 108.36%


10)11)12)13)14)16)17)19)20)21)22)23)24)25)27)28)29)30)31)32)

Dichlorodifluorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luorome thane1 , 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2 -Dichloroethene (total)1, 1 -DichloroethaneChloroform1 , 2 -Dichloroethane2 -Butanone1,1,1 -Tri chloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2-DichloropropaneB romodichl or ome thaneDibromome thaneCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1,2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof orm

444556776788

10119

10111112121313141516161723

.29

.78

.97

.75

.86

.26

.17

.97

.97

.83

.25

.85

.00

.34

.41

.68

. 14

.43

.54

.87

.39

.53

.54

.76

.21

. 91

.76

.03

8550629464

10196764384966383624397

11778130638317475759776129173

9344914724812691914378194014

209334176507596294419122C2293436676m38655943249027710267627

3662523272927054202594382542864CS5732240863840643254591 9 1 j 6 9304522286304264605

48495449485151514952

1035151504751505150505049504949494946

.68

.05

. 94

.53

.71

.23

.51

.37

.35

.24

. 95

.82

.83

.79

. 37

. 17

.40

.26

.31

.95

.55

.39

. 38

.53

. " 3

. 30

. 1 5

. 10


100100999310099971009393

10010010093

10010010099

10010093

10010C10:99100100

(#) = qualifier out of range5058S07.D CS8260.M Fri

(m) = manualFeb 27 13:58


Quantitation Report

J:\7201\DATA\5058S07.D27 Feb 1998 1:22 pmVSTD050 CONT CAL5UL V1161E, V1161A + 5ML OFW



(QT Reviewed)

Position: 1Operator: LLInst : 7201Multiplr: 1.00



J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Thu Feb 26 08:53:10 1998Continuing Cal File: J:\7201\DATA\5057S02.DCS8260


35) 4-Methyl-2-Pentanone 13.99 58 57779 48.59 ug/1 9936) Toluene 15.40 91 813654 52.05 ug/1 10037) Tetrachloroethene 17.19 164 307255 51.62 ug/1 10038) 2-Hexanone 16.16 43 111824 48.14 ug/1 10039) Chlorobenzene 19.69 112 559980 51.90 ug/1 10040) 1,1,1,2-Tetrachloroethane 19.80 131 243754 51.20 ug/1 9941) Ethylbenzene 19.82 106 268781 51.71 ug/1 9942) Xylene (total) 21.68 106 320410 51.13 ug/1 9943) Styrene 21.81 104 573396 50.86 ug/1 9945) 1,1,2,2-Tetrachloroethane 23.48 83 249732 49.81 ug/1 9946) 1,2,3-Trichloropropane 23.89 75 171212 47.41 ug/1 9947) 1,3-Dichlorobenzene 26.21 146 513032 51.45 ug/1 10048) 1,4-Dichlorobenzene 26.40 146 523919 51.05 ug/1 9949) 1,2-Dichlorobenzene 27.05 146 460568 50.63 ug/1 99

(tf) = qualifier out of range (m) = manual integration5058S07.D CS8260.M Fri Feb 27 13:58:58 1998 Page 2

Quantitation Report

Data File : J:\7201\DATA\5058S07.DAcq On : 27 Feb 1998 1:22 pmSample : VSTD050 CONT CALMisc : 5UL V1161E, V1161A + 5ML OFWMS Integration Params: rteint.pQuant Time: Feb 27 13:58 1998




Abundance800000

J : \7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Fri Feb 27 13:55:43 1998Continuing Cal File: J:\7201\DATA\5057S02.D

TIC: 5058S07.D

750000;ii

700000j

650000

600000

550000

500000

450000

400000

350000

300000

250000

200000

150000

100000

50000I '

*, j

ii

0 '

5058S07.D CS8260.M

.uv. . . . . . .5.00 6.00 7.00 8.00 9.00 10.00 11.00 12!00 13.00 14.00 15.00 16.00 17.00 1800 19.00 2000 2liOO 22.00 23XX) 24.00 25.00 2600 27lOO 28.00 29!00 30.00 3liOO

Fri Feb 27 13:59:01 1998 Page 3

/. 4-



J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 5ml volatiles for water samplesMon Jun 08 08:33:42 1998Continuing Calibration


Min. RRF : 0.000 Min. Rel.Max. RRF Dev : 25% Max. Rel.

123456789

1011121314151617

181920212223242526272829303132

333435363738394041

(#)115

I


ITCTCTCMTCMTTCI

TCTCTCTTCTC

ISTTCMTCTTCMTC

= Out9S02 .D

Compound

Bromochlorome thaneDichlorodif luorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luorome thane1, 1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2-Dichloroethene (total)1, 1-DichloroethaneChloroform1 , 2-Dichloroethane-d41 , 2 -Dichloroethane2 -Butanone

1 , 4 -Dif luorobenzene1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroether.e1 , 2 -DichloropropaneBromodichlororr.e thaneDibromome thane2 -Chloroethyl vinyl etherCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1, 2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof orm

Chlorobenzene-d5Toluene-d84 -Methyl -2 -PentanoneTolueneTetrachloroethene2 -HexanoneChlorobenzeneEtihyl benzene1,1,1,2 -Tetrachloroethane

of RangeCS8260LO.M Mon Jun 08 0£

Area :Area :

50%150%

AvgRF

112111321012366120

100100000000000

110200T_

00

! : 33 : 50

.000

.484

. 923

.342

. 939

. 905

.322

.810

. 909

. 107

.837

.223

.008

. 152

.896

.630

.344

.000

.682

. 577

. 112

.403

.284

.383

.139

.000

.352

.242

. 122

.220

. 190

. 101

.000

.354

.033

. 062

. 599

. 062

. 099

.654

.382

1998

CCRF

1.0.2 .1 .1 .1 .2 .2 .8 .0.1.2 .5.5.1.2 .0.

1 .0 .0 .0 .0 .0 .0 .0 .

-0 .0.0 .0 .0 .0 .0 .

1 .1 .0 .1 .0 .0 .0 .0 .0 .

70

000982400024642596444334481358894633071082802120366

000564466985350246320109OOOtf307219105190167083

000303033714477073948575325

01

%Dev Area%

0331723151626172267331815175

19-6

0171911131316210

129

14131218

03

-01620

-16131214

.0

.8#

.9

. 7

.3

.2

. 4#

.0

.3

. 7#

.2#

. 1

.6

.4

.0

.4

.2

.0

.2

.2

.4

.2

.4

.4

.4

.0

. 7

.3

.4

. 5

.2

. 1

. 0

.8

.2

. 9

.4

.2

. 7

. 1

. 9

Pa

14597

118115123118105120119103123117123121139120136

1461151161291301261191130

124120119122123107

143135122120113133123124120

iqe


Method : J:\7001\METHODS\CS8260LO.M (RTE Integrator)Title : GC/MS TCL 8260 5ml volatiles for water samples.Last Update : Mon Jun 08 08:33:42 1998Response via : Continuing Calibration



Compound AvgRF CCRF %Dev Area%

4243444546474849

GTCTCSTCTTTT

Xylene (total)StyreneBromof luorobenzene1,1,2, 2 -Tetrachloroethane1,2, 3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene

00000000

.683

.953

.551

. 168

. 123

.783

.765

.596

00000000

.580

.874

.498

. 142

.094

.650

.614

.471

15.8.9.

15.23 .17.19.21.

13636060

125127125117106111108105

(#) = Out of Range SPCC's out = 0 CCC's out = 01159S02.D CS8260LO.M Mon Jun 08 08:33:51 1998 7001 Page 2


Data File : J:\7001\DATA\1159S02.DAcq On : 8 Jun 1998 8:06 amSample : VSTD010, Cont.Cal. , 8260-25mlMisc : 5ul V-1185B+5ul V-1185A+35ul MeOHMS Integration Params: rteint.pQuant Time: Jun 8 8:31 1998


9JN70011.00

Quant Results File: CS8260LO.RH


J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 5ml volatiles for water samplesMon Jun 08 07:16:32 1998Continuing Cal File: J:\7001\DATA\1156I12.DCS8260LO


1)18)33)


79

13

.78

.14

.94

128114117

46161415962282799

101010

.00

.00

.00

ug/1ug/1ug/1

0-00

.00

.01

.00

System Monitoring Compounds15) l,2-Dichloroethane-d4 8.43 65Spiked Amount 10.000 Range 76 - 11434) Toluene-da 11.42 98Spiked Amount 10.000 Range 88 - 11044) Bromofluorobenzene 16.53 95Spiked Amount 10.000 Range 86 - 115

83171 9.55 ug/1 0.00Recovery = 95.50%

368399 9.12 ug/1 -0.01Recovery = 91.20%

140972 8.46 ug/1 0.00Recovery = 84.60%#


10)11)12)13)14)16)17)19)20)21)22)23)24)25)27)28)29)30)31)32)

Dichlorodif luorome thaneChloromethaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luorome thane1, 1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2-Dichloroethene (total)1, 1-DichloroethaneChloroform1 , 2 -Dichloroethane2 -Butanone1,1, 1-Tri chloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodi chloromethaneDibromome thaneCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1, 2 -Tri chloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof orm

44444556567678788899

109

101111121215

.00

.21

.37

.76

.89

.33

.84

.32

.40

. 11

.50

.94

.83

.52

. 17

. 38

. 82

.79

.68

.76

. 02

.86

.68

.36

.73

.00

.61

.57

8550629464

1019676438496638362439711778

130638317475759776129173

453391108044724975797736521128351077213915111650687415

243581m2341022346089788016875

234774193980409840145494102212133214453011276149125343481792406949934510

6878878878

1688897788887888887

.69

.12

. 90

.47

. 15

.27

.25

.23

. 07

.45

. 15

.45

.31

.27

.37

.89

. 97

.81

.93

.60

. 15

. 74

. 51

.23

. 15

.38

. 39

.33

Qvalueug/1ug/1ug/1ug/1ug/1ug/1ug/1 #ug/1ug/1ug/1ug/1 #ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1 nug/1ug/1ug/1ug/1ug/1ug/1

97979899999778979699

979998889897829197936699

100100949697

(#) = qualifier out of range (m) = manual integration1159S02.D CS8260LO.M Mon Jun 08 08:31:11 1998 7001 Page 1

Quantitation Report


(Not Reviewed)


9JN70011 .00

Quant Results File: CS8260LO.RE<


J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 5ml volatiles for water samplesMon Jun 08 07:16:32 1998Continuing Cal File: J:\7001\DATA\1156I12.DCS8260LO


35) 4-Methyl-2-Pentanone 10.60 58 386 0.34 ug/1 9836) Toluene 11.54 91 484825 8.08 ug/1 8337) Tetrachloroethene 12.73 164 134892 7.67 ug/1 9238) 2-Hexanone 11.84 43 20511 9.35 ug/1 # 9939) Chlorobenzene 14.02 112 268198 8.28 ug/1 10040) Ethylbenzene 14.64 106 172848 8.94 ug/1 9441) 1,1,1,2-Tetrachloroethane 14.11 131 91919 8.11 ug/1 9942) Xylene (total) 15.38 106 163971 8.45 ug/1 # 4443) Styrene 15.32 104 247065 8.56 ug/1 # 6145) 1,1,2,2-Tetrachloroethane 16.07 83 40144 7.89 ug/1 9646) 1,2,3-Trichloropropane 16.51 75 62105 16.87 ug/1 # 3447) 1,3-Dichlorobenzene 19.34 146 183815 7.51 ug/1 9348) 1,4-Dichlorobenzene 19.60 146 173768 7.29 ug/1 9349) 1,2-Dichlorobenzene 20.23 146 133195 7.12 ug/1 91

(#) = qualifier out of range (m) = manual integration1159S02.D CS8260LO.M Mon Jun 08 08:31:12 1998 7001 Page 2

Quantitation Report



Quant Results File: CS8260LO.RES


Abundance600000

550000

! 500000

450000

400000

350000

300000

250000

200000

150000

100000

50000

, Yo -•Tlme-> 4.00

J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 5ml volatiles for water samples.Mon Jun 08 07:16:32 1998Continuing Cal File: J:\7001\DATA\1156I12.D

TIC:1159S02.D

<n«

• ;:> ''UUUiiUJ>.y^-- ^.y>--» , VW-^v

!o

Mi , : ,l.liy.WJiJ ill5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 J8.00 19.00 20.00 21.00 22.00

1159S02.D CS8260LO.M Mon Jun 08 08:31:16 1998 7001 Page 3


J:\7201\DATA\5353V06.D Position: 119 Dec 1997 11:30 am Operator: JN9709455MS, SB36-SL-16-205MS, M.Watson Inst : 72015g + 5ml ofw-t-Sul SSIS V-1147A+5ul MS V-114 Multiplr: 1.00



Quant Results File: SOIL8260.RE;


J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soilsFri Dec 19 09:24 :41 1997Continuing Cal File: J:\7201\DATA\5353S02.DSOIL8260


1)16)28)


101119

.32

.83

.57

128114117

126352

592791559765

505050

. 00

. 00

. 00

ug/Kgug/Kgug/Kg

000

.02

.00

.00

System Monitoring Compounds13) 1,2-Dichloroethane-d4 11.21 65Spiked Amount 50.000 Range 76 - 114

29') Toluene-d8 15.21 98Spiked Amount 50.000 Range 88 - 110


Target Compounds6) 1,1-Dichloroethene 7.21 967) Carbon Disulfide 8.00 768) Acetone 7.27 439) Methylene Chloride 7.87 84

14) 1,2-Dichloroethane 11.43 6215) 2-Butanone 9.63 4319) Benzene 11.44 7820) Trichloroethene 12.56 13024) Trans-1,3-Dichloropropene 15.41 7531) Toluene " 15.41 9134) Chlorobenzene 19.70 112

329496 52Recovery

648563 50Recovery

402971 48Recovery

.07=

. 98=

. 68=

ug/Kg104 . 14%ug/Kg101 . 96%ug/Kg97.36%

0 .02

0 . 02

0 .02

Qvalue171300 53

8081 088742 395455 18043 1

22236 6709940 56241840 526440 0

795256 54539772 53

.63

. 93

.83

. 36

. 07

. 66

.42

.63

. 83

.56

.44

ug/Kg# '<•'ug/Kg#ug/Kgug/Kg#ug/Kgug/Kgug/Kg • ' }ug/Kg 10 *ug/Kg#ug/Kg ic.^ug/Kg .c-)

'"7 °o817599848093

> 96r 94

1100100

{#) = qualifier out of5353V36.D SCIL8260.M

range (rrO = manual integrationFri Dec 19 12 : C2 : 55 1997 Page 1

Quant itation Report

Data File : J:\7201\DATA\5353V06.D Position: 1Acq On : 19 Dec 1997 11:30 am Operator: JNSample : 9709455MS, SB36-SL-16-205MS, M.Watson Inst : 7201Misc : 5g+5ml ofw+5ul SSIS V-1147A+5ul MS V-114 Multiplr: 1.00MS Integration Params: rteint.pQuant Time: Dec 19 12:02 1997 Quant Results File: SOIL8260.RES


Abundance600000

550000

500000

450000

400000

350000

300000

250000

J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soils,Fri Dec 19 09:24:41 1997Continuing Cal File: J:\7201\DATA\5353S02.D

TIC: 5353V06.D

200000o~.

150000

100000

50000I

Time~> 500 6.00 7.00 800 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27.00 28.00 29.00 30.00 31.00 i

5353V06.D SOIL8260.M Fri Dec 19 12:03:01 1997 Page 2


J:\7201\DATA\5353V07.D Position:•19 Dec 1997 12:11 pm Operator:9709455MSD, SB36-SL-16-205MSD, M.Watson Inst :5g+5ml ofw+5ul SSIS V-1147A-t-5ul MS V-114 Multiplr:


XData FileAcq OnSampleMisc

JN72011 . 00

Quant Results File: SOIL8260.RE£



J:\7201\METHODS\SOIL8260GC/MS TCL 8260 volatilesFri Dec 19 09:24:41 1997Continuing Cal File: J:\7201\DATA\5353S02SOIL8260


1)16)28)


10 .11 .19.

328356

128114117

119477591312496975

505050

.00

.00

.00

ug/Kgug/Kgug/Kg

000

.02

.01

. 00

System Monitoring Compounds13) 1,2-Dichloroethane-d4 11.21 65Spiked Amount 50.000 Range 75 - 114

29) Toluene-d8 15.21 98Spiked Amount 50.000 Range 63 - 110


Target Compounds6) 1,1-Dichloroethene7) Carbon Disulfide8) Acetone9) Methylene Chloride

14) 1,2-Dichloroethane15) 2-Butanone19) Benzene20) Trichloroethene21) 1,2-Dichloropropane24) Trans-1,3-Dichloropropene31) Toluene34) Chlorobenzene

309850 51.61 ug/Kg 0.02Recovery = 103.22%

600847 50.35 ug/Kg 0.02Recovery = 100.70%

384953 49.58 ug/Kg 0.01Recovery = 99.16%

Qvalue7877

119

111212151519

.22

.00

.07

.37

.45

.56

.45

. 57

. 56

.40

.41

.69

96764384624378

130637591

112

1607896943

393853859761413961

666191225900

9245698

749865510238

530

18114

575300

5453

. 05

.85

.63

.01

.07

.40

.23

. 14

.20

.79

. 84

. 84

ug/Kgtt '--ug/Kgtfug/Kgug/Kg#ug/Kgug/Kgug/Kg 'Hug/Kg <-X;ug/Kgttug/Kgtfug/Kg -.0ug/Kgicb

'"< 817582808178969411

100100

(#) = qualifier out of5353V07.D SOIL8260.M

range (m) = manualFri Dec 13 12:

jration1997 Page

Quantitation Report

Data File : J:\7201\DATA\5353V07.D Position: 1Acq On -.19 Dec 1997 12:11 pm Operator: JNSample : 9709455MSD, SB36-SL-16-205MSD, M.Watson Inst : 7201Misc : 5g+5ml ofw+5ul SSIS V-1147A+5ul MS V-114 Multiplr: 1.00MS Integration Params: rteint.pQuant Time: Dec 19 12:43 1997 Quant Results File: SOIL8260.RES


Abundance550000

500000

450000

400000

350000

300000

250000

200000

150000

100000

50000


J:\7201\METHODS\SOIL8260GC/MS TCL 8260 volatilesFri Dec 19 09:24:41 1997Continuing Cal File: J:\7201\DATA\5353S02 ,D

TIC: 5353V07.D

II

Time»> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27.00 28.00 29.00 30.00 31.00__ j

S353V07.D SOU,8260.M Fri Dec 19 12:43:59 1997 Page 2

J 7YJ-Data FileAcq OnSampleMisc


J:\7001\DATA\1160V16.D Position: 129 Jun 1998 4:10 pm Operator: JN

9803564MS, SO-MS, M.Watson , 8260-25ml Inst : 70015ul V-1185B+5ul MS V-1184B+35ul MeOH Multiplr: 1.00

MS Integration Params : rteint.pQuant Time: Jun 9 16:34 1998 Quant Results File: 25M8260.RES


J:\7001\METHODS\25M8260.M (RTE Integrator)GC/MS TCL method 8260 25ml volatiles.Tue Jun 09 14:29:37 1998Continuing Cal File: J:\7001\DATA\1160S11.D25M8260


1)16)28)


79

13

.80

.17

.98

128114117

33310318147224484

101010

.00

.00

.00

ug/1ug/1ug/1

000

.00

.00

.00

System Monitoring Compounds13) 1,2-Dichloroethane-d4Spiked Amount 10.00029) Toluene-d8Spiked Amount 10.000

38) BromofluorobenzeneSpiked Amount 10.000

Target Compounds5) Chloroethane6) 1,1-Dichloroethene7) Carbon Disulfide8) Acetone9) Methylene Chloride

14) 1,2-Dichloroethane15) 2-Butanone19) Benzene20) Trichloroethene22) Bromodichloromethane24) Trans-1,3-Dichloropropene25) 1,1,2-Trichloroethane31) Toluene33) 2-Hexanone34) Chlorobenzene

8.45 65

11.45 98

16.57 95

76709 11.97 ug/1 0.00Recovery = 119.70%

284604 9.65 ug/1 0.00Recovery = 96.50%

123827 10.30 ug/1 0.00Recovery = 103.00%

5565687899

1111111114

.87

.87

.34

.45

. 13

.82

.23

.82

.71

.71

.58

.48

.58

.92

.06

6496764384624378

1308375979143112

1116738945628181

18423852183

339828101445

1261256637207

368311186

203831

0.219.820.200. 160 .270 .480 . 14

10.858 .980. 120.37

11 .059.360.129.49


Qvalue# 45#<%0/0 85# 76# 58# 65# 62# .., 59' ' 100;?<-°'o 94# 61# 1# . 14C-'w 99tt 35• S'% 99

(#) = qualifier out of1160V16.D 25M8260.M

range (m) = manual integrationTue Jun 09 16:34:30 1998 7001 Page 1

Quantitation Report

Data File : J:\7001\DATA\1160V16.DAcq On : 9 Jun 1998 4:10 pmSample : 9803564MS, SO-MS, M.Watson , 8260-25mlMisc : 5ul V-1185B+5ul MS V-1184B+35ul MeOHMS Integration Params: rteint.pQuant Time: Jun 9 16:34 1998


Quant Results File: 25M8260.RES


Abundance

700000

650000

600000

550000

500000

450000

400000

350000

300000 !

250000 '

200000

150000

100000

50000

J:\7001\METHODS\25M8260.M (RTE Integrator)GC/MS TCL method 8260 25ml volatiles.Tue Jun 09 14:29:37 1998Continuing Cal File: J:\7001\DATA\1160S11.D

TIC: 1160V16.D

Time-> 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00

1160V16.D 25M8260.M Tue Jun 09 16:34:32 1998 7001 Page 2

/*J A .Quantisation Report (Not Reviewed)

Data File : J:\7001\DATA\1160V17.D Position:Acq On : 9 Jun 1998 4:42 pm Operator:Sample : 9803564MSD, SO-MSD, M.Watson , 8260-25ml Inst :Misc : 5ul V-1185B+5ul MS V-1184B+35ul MeOH Multiplr:MS Integration Params: rteint.pQuant Time: Jun 9 17:06 1998 Quant Results File:


J:\7001\METHODS\25M8260.M (RTE Integrator)GC/MS TCL method 8260 25ml volatiles.Tue Jun 09 14:29:37 1998Continuing Cal File: J:\7001\DATA\1160S11.D25M8260

13JN70011 .00

25M8260.RES


1)16)28)


79

13

.80

. 17

.98

128114117

34314215

375810170

101010

. 00

.00

.00

ug/1ug/1ug/1

000

.00

. 00

.00

System Monitoring Compounds13) 1,2-Dichloroethane-d4Spiked Amount 10.000



Target Compounds6) 1,1-Dichloroethene7) Carbon Disulfide8) Acetone9) Methylene Chloride

14) 1,2-Dichloroethane19) Benzene20) Trichloroethene22) Bromodichloromethane24) Trans-1,3-Dichloropropene25) 1,1,2-Trichloroethane31) Toluene33) 2-Hexanone34) Chlorobenzene

8.46 65

11.45 98

16.57 95

2

1

73339Recovery87391Recovery

18193Recovery

11

10

10

.09

. 17

.26

ug/110ug/101ug/102

1

1

1

90%

70%

60%

0

0

0

.00

.00

.00

56568899

1111111114

.87

.34

.52

. 13

.81

.82

.71

.71

. 57

.47

.57

.82

.06

9676438462781308375979143112

816595409281

21954155

345876108086

15373426

36158388462

185211649

Qvalue100000

11900

10100

10

.52

. 19

.24

.31

. 50

.16

.67

. 15

.49

.86

.30

. 13

.28

ug/1 >o£**°ug/1ug/1 #ug/1 #ug/1 #ug/1 >"-*<•ug/1 <T~'c/<-ug/1 #ug/1 #ug/1 #ug/1 !£**£ug/1 tfug/1 -o^c/

9185587852

> 99> 98361

13» 9735

o 99

(#) = qualifier out of range (m) = manual integration1160V17.D 25M8260.M Tue Jun 09 17:06:48 1998 7001 Page 1

Quantitation Report

J:\7001\DATA\1160V17.D9 Jun 1998 4:42 pm9803564MSD, SO-MSD, M.Watson

Position: 13Operator: JN

8260-25ml Inst : 7001

Data FileAcq OnSampleMisc : 5ul V-1185B+5ul MS V-1184B+35ul MeOHMS Integration Params: rteint.pQuant Time: Jun 9 17:06 1998 Quant Results File

Multiplr: 1.00

: 25M8260.RES


Abundance900000

850000

800000

j 750000

i 700000

650000

600000

550000

500000

450000

400000

350000

300000

250000

200000

150000

100000

50000

Tlm«-> 4.00 5.00 6.00 7.00

1160V17.D 25M8260.M

J:\7001\METHODS\25M8260.M (RTE Integrator)GC/MS TCL method 8260 25ml volatiles.Tue Jun 09 14:29:37 1998Continuing Cal File: J:\7001\DATA\1160S11.D

TIC: 1160V17.D

8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00

Tue Jun 09 17:06:50 1998 7001

IB!OO ig!oo 2oloo 21^00 ^22.00 23.00

Page 2

9 7 0 9 2 7 7 2 7* Quantitation Report (Not Reviewed)


J:\7201\DATA\5349B07.D Position: 215 Dec 1997 11:23 am Operator: JNVBLK15 , METHOD BLANK , Heated Purge Inst : 72015ml ofw+5ul SSIS V-1147A Multiplr: 1.00

MS Integration Params: rteint.pQuant Time: Dec 15 11:52 1997 Quant Results File: SOIL8260.RES


J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soilsMon Dec 15 08:50:31 1997Continuing Cal File: J:\7201\DATA\5349S02.DSOIL8260


1) Bromochloromethane16) 1,4-Difluorobenzene28) Chlorobenzene-d5




Target Compounds4) Bromomethane7) Carbon Disulfide8) Acetone9) Methylene Chloride

10) 1,2-Dichloroethene (total)12) Chloroform14) 1,2-Dichloroethane15) 2-Butanone17) 1,1,1-Trichloroethane18) Carbon Tetrachloride19) Benzene20) Trichloroethene22) Bromodichloromethane23) Cis-1,3-Dichloropropene24) Trans-1,3-Dichloropropene27) Bromoform30) 4-Methyl-2-Pentanone31) Toluene32) Tetrachloroethene33) 2-Hexanone34) Chlorobenzene35) Ethylbenzene36) Xylene (total)37) Styrene39) 1,1,2,2-Tetrachloroethane

10.31 12811.82 11419.58 117

11.19 65Range 76 - 114

15.20 98Range 88 - 110

23.72 95Range 86 - 115

57778

10119

1011111213141523141517161919212123

.78

.98

.08

.84

.28

.03

.35

.47

.71

. 18

.44

.55

.39

.56

.78

.03

. 11

.41

.20

.24

.71

.83

.69

.81

.48

94764384968362439711778

13083757517343911644311210610610483

141124 50.00 ug/Kg 0.00706483 50.00 ug/Kg 0.00587020 50.00 ug/Kg 0.02

334843 45.24 ug/Kg 0.00Recovery = 90.48%

649851 46.16 ug/Kg 0.00Recovery = 92.32%

419166 46.13 ug/Kg 0.00Recovery = 92.26%

Qvalue125 0.04 ug/Kg# 2

13172 1.40 ug/Kg 864525 1.73 ug/Kg 623104 0.68 ug/Kg# 82515m 0.11 ug/Kg#906 0.09 ug/Kg# 37975 0.11 ug/Kg# 42761 0.18 ug/Kg# 62631 0.08 ug/Kg# 18640 0.09 ug/Kg# 462479 0.18 ug/Kg# 551709 0.33 ug/Kg# 84519 0.05 ug/Kgtf 18913 0.10 ug/Kgtf 43930 0.10 ug/Kgtf 43

1338 0.16 ug/Kg# 2812939 1.37 ug/Kg 864449 0.27 ug/Kg 932695 0.47 ug/Kg 98

15122 2.30 ug/Kg 883419 0.30 ug/Kg# 561666 0.31 ug/Kg# 281277 0.19 ug/Kg# 16940 0.56 ug/Kg 1002017 0.23 ug/Kgtf 79

(#) = qualifier out of range (m) = manual integration5349B07.D SOIL8260.M Mon Dec 15 11:52:13 1997 Page 1

Quantitation Report

Data File : J:\7201\DATA\5349B07.DAcq On : 15 Dec 1997 11:23 amSample : VBLK15 , METHOD BLANK , Heated PurgeMisc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 15 11:52 1997 Quant Results File: SOIL8260.RES



J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soils,Mon Dec 15 08:50:31 1997Continuing Cal File: J:\7201\DATA\5349S02.D

TIC: 5340B07.D

550000

500000

450000

400000

350000

300000

250000

200000

150000

100000

50000

Tim«-> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27.00

5349B07.D SOIL8260.M Mon Dec 15 11:52:17 1997 Page 2

Quantisation Report

Data File : J:\7201\DATA\5352B08.DAcq On : 18 Dec 1997 11:44 amSample : VBLK18 , METHOD BLANK , 8260Misc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 18 12:17 1997

(Not Reviewed)




J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Thu Dec 18 11:40:00 1997Continuing Cal File: J:\7201\DATA\5352S07.DCS8260


1)18)33)

Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene -d5

101119

.31

.83

.57

128114117

110480597940503455

505050

.00

.00

.00

ug/1ug/1ug/1

0.000.020.00

System Monitoring Compounds15) 1 , 2 -Dichloroethane-d4Spiked Amount 50.00034) Toluene-dSSpiked Amount 50.00044) Bromof luorobenzeneSpiked Amount 50.000

11Range

15Range

23Range

.2076.2188.7286

65- 114

98- 110

95- 115

265584Recovery

604741Recovery

384297Recovery

50

48

49

.44=.01=.97=

Target Compounds2)3)5)9)

10)11)12)13)14)16)17)19)20)21)22)23)24)25)27)28)29)30)31)32)36)37)38)39)

Dichlorodifluorome thaneChlorome thaneBromome thaneCarbon DisulfideAcetoneMethylene Chloride

445777

1, 2-Dichloroethene (total) 91 , 1-Dichloroe thaneChloroform1 , 2 -Dichloroethane2 -Butanone1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodichlorome thaneDibromome thaneCis- 1 , 3 -Dichloropropene

810119

1011111212131314

Trans- 1 , 3 -Dichloropropene 151,1, 2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof ormTolueneTetrachloroethene2 -HexanoneChlorobenzene

1616172315171619

.29

.81

.77

.98

.16

.86

.78

.87

.02

.35

.59

.69

. 15

.43

.56

.89

.39

.55

.57

.79

.23

. 93

. 77

.04

.40

. 19

. 19

.70

855094764384966383624397

11778

13063831747575977612917391

16443112

656535

1002488323384883948

222727252959436

2095946

4530829

17273309257330673003133231772292253176172422379453851

00002100000000000000000000

280

.14

.19

.39

.53

.60

.30

.24

.30

.33

.49

.33

.30

. 15

.39

.20

.38

.40

.67

.45

.50

.43

.56

.44

.57

. 53

.47

. 92

.40

ug/1100 .ug/196.

ug/199.

ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1

88%

02%

94%

0.02

0.00

0.00

Qvalue#####

##

####

##

####

#

#

42423

76569863439758624564787544958359585689997965879263

(#) = qualifier out of5352B08.D CS8260.M




Quantitation Report

J:\7201\DATA\5352B08.D18 Dec 1997 11:44 amVBLK18 /METHOD BLANK , 82605ml ofw+5ul SSIS V-1147A


(Not Reviewed)




J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Thu Dec 18 11:40:00 1997Continuing Cal File: J:\7201\DATA\5352S07.DCS8260


40)41)42)43)45)46)47)48)49)

1,1,1,2 -TetrachloroethaneEthylbenzeneXylene (total)Styrene1,1,2,2 -Tetrachloroethane1,2,3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene

191921212323262627

.81

.83

.67

.81

.49

.72

.21

.40

. 05

1311061061048375146146146

13971174148238542905

230350 T-5475 *57515599

00000

**,££•000

.30

.25

.26

.38

.66

.59

.60

.67

ug/1ug/1ug/1ug/1ug/1"ug/1ug/1ug/1ug/1

tf##

##

64412778743949695

(#) = qualifier out of5352B08.D CS8260.M



Quantitation Report

Data File : J:\7201\DATA\5352B08.DAcq On : 18 Dec 1997 11:44 amSample : VBLK18 , METHOD BLANK , 8260Misc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 18 12:17 1997




Abundance' 550000 ,

J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Thu Dec 18 11:40:00 1997Continuing Cal File: J:\7201\DATA\5352S07.D

TIC: 5352BOB.D

500000

450000

400000

350000

300000

250000

200000

150000

100000

50000

/-A -A_. -'.

Tlm«-> 5.00 6.00 7.00 B.OO 9.00 10 00 11.00 12.00 13 00 14.00 15.00 16 00 17.00 18.00 19.00 20.00 21 00 22.00 23.00 24!6o 2s!oO 2s!oO 2/lod 2s!oO 29!oO 31X00 3l!6o "''

5352B08.D CS8260.M Thu Dec 18 12:17:30 1997 Page 3

Quantitation Report

Data File : J:\7201\DATA\5353B03.DAcq On : 19 Dec 1997 9:30 amSample : VBLK19 , METHOD BLANK , Heated PurgeMisc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 19 10:02 1997

(Not Reviewed)


Quant Results File: SOIL8260.RE5



J:\7201\METHODS\SOILS260GC/MS TCL 8260 volatilesFri Dec 19 09:24:41 1997Continuing Cal File: J:\7201\DATA\5353S02.DSOIL8260


1)16)28)


101119

.31

.82

.57

128114117

112558464

972116912

505050

.00

.00

.00

ug/Kgug/Kgug/Kg

000

.01

.00

.01



Target Compounds7) Carbon Disulfide8) Acetone9) Methylene Chloride

14) 1,2-Dichloroethane33) 2-Hexanone

11.19 65Range 75 - 114

"l5.2: 98Range 83 - 110

"23.72 95Rancre 85 - 115

7.99 767.13 437.85 84

11.81 6216.23 43

294256 51Recovery

551457 50Recovery

358911 49Recoverv

115739351051

166147252

29

. 15,97.294761

ug/Kg103 .66%ug/Kg100 . 58%ug/Kg 098 .82%

0.00

0 . 01

01

Qvalueug/Kgtfug/Kg#ug/Kg#ug/Kgtfug/Kg#

7551334756

(#) = qualifier out of5353B03.D SOIL3260.M

range (m; =Fri Eer

manual integration19 10:02:41 1997 Page 1

Quantitation Report

Data File : J:\7201\DATA\5353B03.DAcq On : 19 Dec 1997 9:30 amSample : VBLK19 , METHOD BLANK , Heated PurgeMisc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 19 10:02 1997


Quant Results File: SOIL8260.RES


Abundance500000

450000

400000 •

350000

300000

250000

200000

150000

100000

50000

J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soilsFri Dec 19 09:24:41 1997Continuing Cal File: J:\7201\DATA\5353S02.D

TIC: 5353B03.D

ia9

Time--> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 2200 23.00 24.00 25.00 26.00 27.00 28.00 29.00 3000 31.00 j

5 3 5 3 B 0 3 . D SOIL8260.M Fri Dec 19 1 0 : 0 2 : 4 4 1997 Page 2

Quantitation Report

Data File : J:\7201\DATA\5356B03.DAcq On : 22 Dec 1997 8:41 amSample : VBLK22 , Method BlankMisc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 22 9:14 1997

(Not Reviewed)




J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL -i- CS 8260 for 5ml water samples.Mon Dec 22 08:34:24 1997Continuing Cal File: J:\7201\DATA\5356S02.DCS8260


1)18)33)


10.11.19.

328257

128114117

113471608321512993

505050

.00

. 00

.00

ug/1ug/1ug/1

000

.02

.02

. 00

System Monitoring Compounds15) l,2-Dichloroethane-d4Spiked Amount 50.00034) Toluene-d8Spiked Amount 50.00044) Bromof luorobenzeneSpiked Amount 50.000

Target Compounds2) Dichlorodif luoromethane9) Carbon Disulfide10) Acetone11) Methylene Chloride19) 1, 1, 1-Trichloroethane21) Benzene25) Dibromomethane36) Toluene37) Tetrachloroethene38) 2-Hexanone39) Chlorobenzene41) Ethylbenzene46) 1, 2, 3-Trichloropropane47) 1, 3-Dichlorobenzene48) 1 , 4 -Dichlorobenzene49) 1 . 2 -Dichlorobenzene

11.19Range 76

15.20Range 88

23.71Range 86

65 288923114 Recovery98 617644 48110 Recovery95 395455 50115 Recovery

51.20 ug/1

4777

101113151716192023262627

.32

.99

. 15

.84

.67

.45

.56

.42

.19

.23

.67

.09

.71

.21

.40

.05

85764384977817491

1644311210675146146146

75393262472127761057184271825971276

2885211681962

241467331234214185

£'

0 .02

99

16

102 .40%ug/197.98%

ug/1 0100 .32%

0 . 02

00

Qvalue001200000

1300&000

.15

.89

.90

.91

. 13

. 13

.15

. 16

.21

.87

. 10

.36

.30

.30

.43

ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1

#

#

#####

###

42805699325017607994426743959291

(#) = qualifier out of range (m) = manual integration5356B03.D CS8260.M Mon Dec 22 09:14:40 1997 Page 1

Quantisation Report

Data File : J:\7201\DATA\5356B03.DAcq On : 22 Dec 1997 8:41 amSample : VBLK22 , Method BlankMisc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 22 9:14 1997




Abundance

550000

500000

450000

400000

350000

300000

250000

200000

150000

100000

50000

J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Mon Dec 22 08:34:24 1997Continuing Cal File: J:\7201\DATA\5356S02.D

TIC: 5356B03.D

o£

O

Io

Time-> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 2300 24.00 25.00 26.00 27.00 28.00 29.00 30.00 31.00___{

5356B03.D CS8260.M Mon Dec 22 09:14:45 1997 Page 2

Quantitation Report


J:\7201\DATA\5058B08.D27 Feb 1998 2:04 pmVBLK27 METHOD BLANK5UL V1161E + 5ML OFW


(Not Reviewed)




J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Fri Feb 27 13 :55:43 1998Continuing Cal File: J:\7201\DATA\5058S07.DCS8260


1)18)33)


111

019

.29

.81

.57

128114117

128135709132595366

505050

.00

.00

.00

ug/1ug/1ug/1

0.0.0.

,00.00.00



Target Compounds9) Carbon Disulfide

11) Methylene Chloride38) 2-Hexanone46) 1,2,3-Trichloropropane47) 1,3-Dichlorobenzene48) 1,4-Dichlorobenzene49) 1,2-Dichlorobenzene

11. 18Range 76

15.20Range 88

23 .73Range 86

65- 114

98- 110

95- 115

167891 51.02 ug/1 0.00Recovery = 102.04%

436926 49.58 ug/1 0.00Recovery = 99.16%

372930 50.69 ug/1 0.00Recovery = 101.38%

771623262627

.96

.83

. 18

.73

.22

.41

. 06

76844375146146146

353747641088

188537158617071100

010

000

270945

141511

ug/1ug/1ug/1ug/i-ug/1ug/1ug/1

Qvalue# 76

95# 30

43678158

(#) = qualifier out of range (m) = manual integration5058B08.D CS8260.M Fri Feb 27 14:36:44 1998 Page 1

Quantitation Report

Data File : J:\7201\DATA\5058B08.DAcq On : 27 Feb 1998 2:04 pmSample : VBLK27 METHOD BLANKMisc : 5UL V1161E -t- 5ML OFWMS Integration Params: rteint.pQuant Time: Feb 27 14:36 1998




Abundance

J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Fri Feb 27 13:55:43 1998Continuing Cal File: J:\7201\DATA\5058S07.D

TIC: 5058B08.D

450000.

400000]

350000

300000

250000

200000

150000

100000.

50000

;!o

Tlme-> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19100 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27XX) 2s!do 29.00 30.00 3l!oO

5058B08.D CS8260.M Fri Feb 27 14:36:45 1998 Page 2

Quantitation Report

Data File : J:\7001\DATA\1159B03.DAcq On : 8 Jun 1998 8:42 amSample : VBLK08 , Instrument BlankMisc : 5ul V-1185B+40ul MeOHMS Integration Params: rteint.pQuant Time: Jun 8 9:06 1998

8260-25ml

(Not Reviewed)




J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 25ml volatiles for water samplesMon Jun 08 08:31:20 1998Continuing Cal File: J:\7001\DATA\1159S02.DCS8260LO


1)18)33)


7 .9.

13.

771494

128114117

39358368693264997

101010

.00

.00

.00

ug/1ug/1ug/1

000

.00

.00

.00




Target Compounds10) Acetone11) Methylene Chloride29) 1,1,2-Trichloroethane35) 4-Methyl-2-Pentanone46) 1,2,3-Trichloropropane

8Range

11Range

16Range

427642885386

5.406. 11

11.4310 .7316 .53

651149811095115

4384975875

76329 10Recovery

342940 9Recovery

138493 10Recovery

8792148

42238193

61298

00

76

93

48

6229

0.22

ug/1107.60%ug/199.30%

ug/1 0104.80%

0 .00

0 .00

00

ug/1ug/1ug/1ug/1ug/1

Qvalue# 56tf#n#

64133535

(#) = qualifier out of range (m) = manual integration1159B03.D CS8260LO.M Mon Jun 08 09:07:01 1998 7001 Page 1

Quantitation Report

Data File : J:\7001\DATA\1159B03.DAcq On : 8 Jun 1998 8:42 amSample : VBLK08 , Instrument BlankMisc : 5ul V-1185B+40ul MeOHMS Integration Params: rteint.pQuant Time: Jun 8 9:06 1998

8260-25ml




J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 25ml volatiles for water samplesMon Jun 08 08:31:20 1998Continuing Cal File: J:\7001\DATA\1159S02.D

TIC: 1159B03.D

450000

400000

350000

300000

250000

200000 ,

150000 •

100000 .

50000

0T!me-> 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00

1159B03.D CS8260LO.M Mon Jun 08 09:07:02 1998 7001 Page 2

c <j • A.-^y-.-'-v «.-970">Z77 Response Factor Report 7002

Method : J:\7002\METHODS\8270.M (RTE Integrator)Title : GC/MS method 8270 TCL extractables.Last Update : Tue Dec 16 10:12:52 1997Response via : Continuing Calibration

Calibration Files

1)2)3)4)5)6)7)8)9)

10)11)12)13)14)15)16)

17)18)19)20)21)22)23)24)25)26)27)28)29)30)

31)32)33)34)35)36)37)38)39)40)41)

50120

ISSSSMTCTCMTCTCMTCTCTCTTCMTCTC

ISTCTCCTCTCTCTCTMCTTTCTMCT

ITCTCTSCTTT1

CTCTi.

=2350502.0 20=2350505.0 160

Compound

1 , 4 -Dichlorobenzene-d2 - FluorophenolPhenol -d52 -Chlorophenol-d41 , 2 -Dichlorobenzene-dPhenolbis (2-Chloroethyl) eth2 -Chlorophenol1 , 3 -Dichlorcbenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chlorop4 -Methylphenoln-Nitroso-di-n-propylHexachloroe thane

Naphthalene-d8Nitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2 -Chloroethoxy) me2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzenNaphthalene4-ChloroanilineHexachlorobutadiene4 -Chloro- 3 -methylphen2 -Methylnaphthalene

Acenaphthene-dlOHexachlorocycl open tad2,4,6 -Trichlorophenol2,4,5 -Trichlorophenol2 - Fluorobiphenyl2 -Chloronaphthalene2 -NitroanilineDimethylphthaiateAcenaphthylene2 , 6 -Dir.it re toluene3 -Nitroanil ine

=2350503 .D=2350507. D

50 20

11101II11113I00

.332

.581

.249

.765

.947

.524

.463

.542

.547

.316

. 166

.255

.395

.976

.609

1110111111]_3100

.314

.622

.281

.840

.819

.554

.380

.673

.640

.513

.163

.325

.270

. 992

.573

111011111103110

80

80

_ _ _ T C

.415

.660

.274

.690

.620

.611

.203

.315

.294

.053

.866

.593

.215

.146

.621

=2350504 .D

120 160 Avg

•> rr TaTD- - - -1.2571.3851.0460.5411.6131.5001.1861 .2851.2820.9460.7843 .4871.2481.0910.551

111011111003110

.320

.393

.019

.471

.463

.422

.059

.197

. 153

.798

.639

.247

.183

.016

.541

111011111103110

.328

.528

.174

.661

.692

.522

.258

.402

.383

.125

.924

.381

.262

. 044

.579

%RSD

48

112311412141425254666

.28

.52

.05

. 17

.26

.58

.85

. 12

.65

. 58#-40#.51.42. 90.03

___ __ _ _ _ _ T QTD- - - - - - - - ___

0000000000000

0001101100

.397

.437

.859

.266

.365

.433

.344

.358

. 967

.436

.222

.357

.617

.413

.462

.502

. 152

. 030

.523

.248

.778

. 353

.306

0000000000000

00

11110

.385

.408

.809

.226

.322

.448

.282

.361

.992

.299

.217

.282

.601

.355

.401

.226

.069

.295

.798

.296

0000000000000

000110110c

.426

.448

.889

.217

. 308

.454

.291

.350

.942

.459

.218

.311

.598

_ _ T C-L k.

.447

. 390

.419

. 115

. 065

. 532

.287

.740

. 349

.371

0.3670.3800 .7950.2160 .2970 . 3990 .2880 .2890.7950.4030 . 1820.3040.497

-i rr>T~\3 I U- - - -

0 .3890 .3730.3800 . 8710 . 9000.4751. 1051 .4490 . 3070 . 343

0000000000000

0000000100

.356

.357

.783

. 195

.257

.374

.248

.260

.685

.376

. 162

.264

.435

.366

.324

.322

.757

. 789

.438

.965

.247

.288

.337

0000000000000

0001001100

.386

.406

.827

.224

.310

.422

.291

.324

. 876

.395

.200

.304

.550

.394

.390

.406

.024

. 970

.492

. 180

.603

. 318

. 339

795

11128

11141415131114

9121819128

121597

.05

.38

.46

.65

.67

.12

.81

.31

.98

.75

.38

.54

.52

.38

.79

.56

. 52

.62

. 99

.06

.23

.60

. 91

= Out of Range8270.M Tue Dec 16 14:10:18 1997 Page 1


Response Factor Report 7002

J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 10:12:52 1997Continuing Calibration

42)43)44)45)46)47)48)49)50)

51)52)53)54)55)56)57)58)59)60)61)62)

63)64)65)66)67)68)69)70)

71)72)73)74)75)76)77)78)

50120

CMTTMTCTCMTTCTCTT

ITTSCTCTCMTCTTCTTCT

ICMTSTCTTCTT

ITCTCTCTCTCTCT

=2350302. D 20=2350305.0 160

Compound

Acenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl-phenyl4 -Nitroaniline

Phenanthrene-dlO4, 6-Dinitro-2 -methylpn-Nitrosodiphenylamin2,4, 6-Tribromophenol4 -Bromophenyl -phenyleHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi-n-butylphthalateFluoranthene

Chrysene-dl2PyreneTerphenyl-dl4ButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidinChrysenebis (2-Ethylhexyl) phth

Perylene-dl2Di -n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2,3 -cd] pyrenDibenz [a , h] anthraceneBenzo [g, h, i] perylene

=2350303 .D=2350307.0

50 20

1.0950.2080.1211.5770.4471.3311.2400.6450.239

0. 1780.4450.1980.2590.3620.2330.9900.6020.9711.1791. 146

1.0560.7380.4650.9790.1770.9670.616

1.0641.0621.0380.9480.9760.7540.833

1.163

1.6090.4061.2941.2550.669

0 .4900.1830.2570.368

1.0340.8940.9771.1981. 147

1.0350.7570 .4390 . 9800.2200.9700.610

1.0040. 9971.0950.8910.8840.6510.737

80

80

1 .0460.2080.1261 .4320.4391.2511.1760.6460.286

. _ _ _ _ !0. 1480.4430.2140.2540.3430.1980.9330.7340.9281 . 1391.075

- - - - - I0.9850.7020 .4660. 9470.2170.8990.557

- - - - - I1.0391.0940. 9010.9420.9690.7590.858

=2350304 .D

120 160 Avg

0 .0 .0.1 .0.1.0.0 .0.

STD0.0.0.0.0.0.0.0.0 .0 .0 .

STD0.0 .0 .0.0.0 .0 .

STD0 .0 .0 .0.0 .0 .0 .

849240148158382056982548285

140359179224293203785620787988919

834569407806203770438

893878738827841639765

0.7190.2270.1431.0080 .3620.9200.8220.4650.294

0.1040 .2890.1570.1810.2470.1740.6650.5910.6650 .8370 .801

0.6910.4860.3550.7130. 1810.6660.339

0 .7600.7950.7950 .7340 .5950 .4470.561

000101100

00000000011

0000000

0000000

. 974

.220

.135

.357

.407

. 170

.095

.595

.276

.143

.405

.186

.235

.322

.202

.881

.688

.866

. 068

.018

. 920

.650

.426

.885

.200

.855

.512

.952

.965

.913

.868

.853

.650

.751

%RSD

18 . 937.059.60

19.478.96

15.0017. 1014 .489.09

21 . 1119.7711 .4814 . 1315. 9612 .0217.3818.6215.6814 . 3715.02

16 .8018 .0710.8613.559.97

15.5623 .48

13 .2113 .0816.7510.2818 . 1819.4615. 58

Out of Range8270 .M Tue Dec 16 14:10:24 1997 Page 2



J:\7002\DATA\2350S02.D16 Dec 1997 9:02 amSSTD0502ul of S-1020B

MS Integration Params: LSCINT.PQuant Time: Dec 16 10:11 1997

Position: 1Operator: ESInst : 7002Multiplr: 1.00

Quant Results File: 8270.RES


J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 09:40:03 1997Continuing Cal File: J:\7002\DATA\2350S02.D8270


1) 1 , 4 -Dichlorobenzene-d417) Naphthalene-dS31) Acenaphthene-dlO51) Phenanthrene-dlO63) Chrysene-dl271) Perylene-dl2

System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2-Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000

35) 2-FluorobiphenylSpiked Amount 100.000

54) 2 , 4 , 6-TribromophenolSpiked Amount 150.00065) Terphenyl-dl4Spiked Amount 100.000

Target Compounds6) Phenol7) bis (2-Chloroethyl) ether8) 2-Chlorophenol9) 1 , 3-Dichlorobenzene10) 1 , 4 -Dichlorobenzene11) 1 , 2 -Dichlorobenzene12) 2-Methylphenol

81013162326

7Range

8Range

8Range

8Range

9Range

12Range

15Range

20Range

.68

.46

.68

.95

.37

.75

.2321. 1810.4433.9316.4235.2643.4010.7133

152136164188240264

112- 11099

- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

69576244938138865252027279863266428

115849Recovery

137496Recovery


121651Recovery


258234Recovery

404040404040

50

50

50

50

50

50

50

50

.00

.00

.00

.00

.00

.00

.00=.00=.00=.00=.00=.00=.00=

. 00=

ngngngngngng

ng33

ng33

ng33

ng50

ng50

ng50

ng33

ng50

000000

0.33%

0.33%

0.33%

0.00%

0.00%

0. 00%

0.33%

0.00%

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

Qvalue

13) 2 , 2 ' -oxybis ( 1 -Chloropropan14) 4 -Methylphenol15) n-Nitroso-di -n-propylamine16) Kexachloroethane19) Nitrobenzene20) Isophorone21) 2-Nitrophenol22) 2 , 4 -Dimethylphenol

888888889999999

. 19

.32

.46

.64

.70

.95

.92

. 98

.09

. 17

.36

.44

.75

.89

.83

9493

12814614614610845108701177782

139107

169359132548127251134150134530114449101425283051121296849085294813371826305081478111742

505050505050505050505050505050

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

. 00

ngngngngngngngngngngngngngngng

#

#

9979999810098894199948697989797

(#) = qualifier out of range (m) = manual integration2350S02.D 8270.M Tue Dec 16 10:11:55 1997 Page 1


Data File : J:\7002\DATA\2350S02.DAcq On : 16 Dec 1997 9:02 amSample : SSTD050Misc : 2ul Of S-1020BMS Integration Params: LSCINT.PQuant Time: Dec 16 10:11 1997






23)24)25)26)27)28)29)30)32)33)34)36)37)38)39)40)41)42)43)44)45)46)47)48)49)50)52)53)55)56)57)58)59)60)61)62)64)66)67)68)69)

bis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDime thylpht ha lateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -DinitrotolueneDie thylpht ha lateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4 , 6-Dinitro-2-methylphenoln-Nitrosodiphenylamine4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthenePyreneButylbenzylphthalateBenzo [a] anthracene3,3' -Dichlorober.zidineChrysene

810101010101111121212121213131313131313141414141414141515161617171718192021232323

.32

.22

.36

.48

.55

.71

.25

.62

.00

.14

.22

.53

.76

.06

.38

.26

.58

.75

.79

.84

.07

.09

.52

.82

.74

.93

.98

.00

.83

.24

.62

.01

.46

. 11

.24

.86

.43

.88

. 32

.23

.44

9316218012812722510714223719619616265163152165138153184109168165149166204138198169248284266178167178149202202149228252228

1325481053101095182962041335756802410917018898571610801358709917871390842

2166253086796127753118190036360942106627379777675

2310542151831119724144155989

140339814761139457346131188518961930597037137536112536947716261534246162084

338307

505050505050505050505050505050505050505050505050505050505050505050505C50505C505050

.00

.00

. 00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

. 00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

. 00

. 00

. 00

.00

.00

.00

.00

. 00

ngngngngngngngngngngngngngngngngngngng #ng #ngngngngngng #ngngngngngngngngngngngngngngng

9996971001009998999998989797999889969533849786989896649796979910099949999939292999899

(#) = qualifier out of range (m) = manual integration2350S02.D 8270.M Tue Dec 16 10:12:00 1997 Page 2

Quantisation Report




(Not Reviewed)






70)72)73)74)75)76)77)78)

bis (2-Ethylhexyl)phthalate 23Di -n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2, 3-cd] pyreneDibenz [a, h] anthraceneBenzo [g, h, i] perylene

24252526292930

.25

.65

.84

.89

.61

.60

.58

.44

149149252252252276278276

215561354340353564345698315677324997250958277325

50.50.50.50.50.50.50.50.

0000000000000000

ngngngngngngngng

9796979998869593

(ft) = qualifier out of range (m) = manual integration2350S02.D 8270.M Tue Dec 16 10:12:01 1997 Page 3

Quantitation Report

Data File : J:\7002\DATA\2350S02.DAcq On : 16 Dec 1997 9:02 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Dec 16 10:11 1997


1ES70021.00



Abundance

J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 09:40:03 1997Continuing Cal File: J:\7002\DATA\2350S02.D

TIC: 2350S02.D

650000

600000

550000

500000

450000

400000

350000

300000

250000

200000

150000

100000

50000

0

W

1

M

?"•*?«£~9 5

"p°z5s"**.

V)

1

u.

itii

,

- - • ., ..

1Cr

<0

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— -9 °^ ij ~ *s '15

i3

!

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11

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Time-> 6.00 8.00

2350S02.D 8270.M

10.00 12.00 14.00 16.00 18.00 2000

Tue Dec 16 10:12:11 1997

22.00 24.00 26.00 28.00 30.00 32.00 34.00

Page 4

Evaluate Continuing Calibration Report

•JrData File : J:\7002\DATA\2351S02.D Position: 1Py^Acq On : 17 Dec 1997 9:31 am Operator: ES/ Sample : SSTD050 Inst : 7002

Misc : 2ul of S-1020B Multiplr: 1.00MS Integration Params : LSCINT.P

Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Tue Dec 16 14:37:18 1997Response via Single Level Calibration

Min. RRF 0.000 Min. Rel . Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%

123456789

10111213141516

1718192021222324252627282930

313233343536373839



IT1-i.

CTCTSCTr»~.

TCT

Compound

1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol -d52 -Chlorophenol -d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis (1-Chloropropane4 -Methylphenoln-Nitroso-di-n-propylamineHexachloroe thane

Naphthalene-daNitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2, 4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methyl phenol2 -Methylnaphthalene

Acenaphthene-dlOHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 - Fluorobiphenyl2 -Chloronaphthalene2 -Nit roanil ineDime thylpht ha lateAcenaphthylene

AvgRF

1111011111103110

10000000000000

100010011

.000

.328

.528

.174

.661

.692

.522

.258

.402

.383

.125

.924

.381

.262

.044

.579

.000

.386

.406

.827

.224

.310

.422

.291

.324

.876

.395

.200

.304

.550

.000

.394

.390

.406

.024

. 970

.492

. 180

.603

CCRF

1111011111112100

10000000000000

10001]_011

.000

.253

.441

.232

.718

.719

.320

.419

.502

.502

.282

.010

.313

.318

.829

.546

.000

.348

.371

.749

.270

.361

.396

.370

.382

. 965

.465

.236

.342

.626

. 000

.429

.497

. 516

. 179

. 055

.410

.224

.761

%Dev Area%

055

-4-8-113

-12-7-8

-14-931-4205

0989

-20-166

-27-17-10-17-18-12-13

0-8

-27-27-15-816-3-9

.0

.6

.7

. 9

.6

.6

.3

.8

. 1

.6

.0

.3

.6#

.4

.6

. 7

.0

.8

.6

.4

.5

.5

.2

.!#

.9

.2

. 7

.0

. 5

.8

. 0

. 9

.4#

.!#

. 1

.8

. 7

. 7

. 9

170tf160#155#168#160#151#148165#166tf166#166#148121161#145153#

162#142137141164#160tf148174#172tf161#172#172*1155#164#

166#172#178#170#170#170#130162tf164tt

Dev (min)

0000000000000000

00000000000000

000000000

.00

.00

.00

.00

. 00

.00

. 00

.00

. 00

. 00

. 00

.00

. 00

.00

.00

.00

.00

.00

. 00

. 00

. 00

.00

. 00

. 00

.00

. 00

.00

.00

. 00

. 00

. 00

. 00

. 00

. 00

.00

. 00

. 00

. 00

. 00

(#) = Out of Range2351S02.D 8270.M Wed Dec 17 13:39:40 1997 Page 1


^ Data File : J:\7002\DATA\2351S02.D Position: 1WT Acq On : 17 Dec 1997 9:31 am Operator: ES/ Sample : SSTD050 Inst : 7002


Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Tue Dec 16 14:37:18 1997Response via Single Level Calibration

Min. RRF 0.000 Min. Rel. Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%

4041424344454647484950

515253545556575859606162

6364656667686970

71727374757677

CTTCMTTMTCTCMTTCTCTT

ITTSCTCTCMTCTTCTTCT

ICMTSTCTTCTT

ITCTCTCTCTCT

Compound

2 , 6 -Dinitro toluene3-NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzofuran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline

Phenanthrene-dlO4 , 6-Dinitro-2-methylphenoln-Nitrosodiphenylamine2,4, 6 -Tribromophenol4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi-n- butyl phthalateFluoranthene

Chrysene-dl2PyreneTerphenyl-dl4Butyl benzyl phthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysenebis (2 -Ethylhexyl ) phthalate

Perylene-dl2Di-n-octyl phthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2,3 -cd] pyreneDibenz [a, h] anthracene

AvgRF

00000101100

10000000001110000000

1000000

.318

.339

. 974

.220

.135

.357

.407

.170

.095

.595

.276

. 000

.143

.405

.186

.235

.322

.202

. 881

.688

.866

.068

.018

.000

.920

.650

.426

.885

.200

.855

.512

.000

.952

. 965

. 913

.868

.853

.650

CCRF

00100101100

10000000001111000000

1000000

.355

.382

.074

.213

.119

.561

.447

.253

.223

.659

.315

.000

.173

.454

.181

.252

.349

.243

.968

.826

. 971

.081

. 108

.000

.055

.745

.435

. 983

.274

. 959

.535

. 000

.812

.865

.823

. 967

. 923

.724

%Dev

-11-12-10

311-15-9-7

-11-10-14

0-21-122-7-8

-20-9

-20-12-1-8

0-14-14-2

-11-37-12-4

014109

-11-8

-11

.6

.7

.3

.2

. 9

.0

.8

. 1

. 7

.8

. 1

.0

.0

. 1

. 7

.2

.4

.3

.9

. 1

. 1

.2

.8

.0

.7

.6

.1

. 1

. on

.2

. 5

. 0

. 7

.4

. 9

. 4

.2

.4

Area%

166**207**162**170**162**164**166**156**163**169**218**

167**163**170**153**163**161**174**163**229**167**153**1621*

168**168**170**157**169**259**167**146

193**147157**153**197**183**186**

Dev (min;

00000000000

000000000000

00000000

0000000

. 00

.00

.00

. 00

. 00

.00

. 00

. 00

.00

.00

.00

. 00

. 00

.00

.00

.00

.00

.00

. 00

. 00

. 00

. 00

.00

.00

.00

.00

.00

.00

.00

. 00

.00

.00

.00

. 00

.00

.00

. 00

.00

(#) = Out of Range2351S02.D 8270.M Wed Dec 17 13:39:46 1997 Page 2

Evaluate Continuing Calibration ReportrData File : J:\7002\DATA\2351S02.DAcq On : 17 Dec 1997 9:31 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.P



Min. RRFMax. RRF Dev

J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 14:37:18 1997Single Level Calibration

1ES70021. 00


Max. R.T. Dev O.SOmin

Compound

Benzo[g,h,i]perylene

AvgRF

0.751

CCRF

0.780

%Dev Area% Dev(min)

-3.9 181# 0.0078 CT

(#) = Out of Range2351S02.D 8270.M

SPCC's out = 0 CCCWed Dec 17 13:39:47 1997

s out = 3Page 3





Position:Operator:Inst ;Multiplr:

1ES70021.00





1) 1 , 4 -Dichlorobenzene-d417) Naphthalene-d831) Acenaphthene-dlO51) Phenanthrene-dlO63) Chrysene-dl271) Perylene-dl2

System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2 -Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000


54) 2 , 4 , 6-TribromophenolSpiked Amount 150.000

65) Terphenyl-dl4Spiked Amount 100.000

Target Compounds6) Phenol7) bis (2-Chloroethyl) ether8) 2-Chlorophenol9) 1 , 3 -Dichlorobenzene

10) 1 , 4 -Dichlorobenzene11) 1 , 2 -Dichlorobenzene12) 2-Methylphenol

81013162326

7Range

8Range

8Range

8Range

9Range

12Range

15Range

20Range

.67

.45

.66

.93

.36

.74

.2321.1710.4433.9116.4135.2543.3810.7033

152136164188240264

112- 110

99- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

118615395982230024421255470272514557

185714

404040404040

47

.00

.00

.00

.00

.00

.00

.02Recovery =

213623Recovery

182723Recovery

106492Recovery

172294Recovery


438095Recovery

45

49

46

43

51

45

50

.57=.35=.95=.80=.16=.70=.48=

ngngngngngng

ng31

ng30

ng32

ng46

ng43

ng51

ng30

ng50

-0-0-0-0-0-0

0.35%

0.38%

0.90%#

-0.95%

0.80%

-0. 16%

-0.47%

-0.48%

.01

.01

.02

.01

.01

.01

. 00

.00

.00

.01

.00

.01

.02

.01

Qvalue

13) 2 , 2 ' -oxyb is (1 -Chloropropan14) 4 -Methylphenol15) n-Nitroso-di -n-propylamine16) Hexachloroethane19) Nitrobenzene20) Isophorone21) 2 -Nitrophenol22) 2 , 4 -Dimethylphenol

888888889999999

. 19

.32

.46

.63

.69

. 93

.91

. 97

.09

. 17

.34

.44

.74

.88

.83

9493

12814614614610845108701177782

139107

25492719577821040422274922265819007914979334298619539012287580894183666370528133866178598

444348484848433547424442435049

. 15

.32

.49

. 70

. 54

. 71

.31

. 54

.24

.44

.81

.48

. 56

. 81

.43


#

#

889088999998979599838787957695

(#) = qualifier out of range (m) = manual integration2351S02.D 8270.M Wed Dec 17 10:08:43 1997 Page 1



Position;Operator;Inst :Multiplr:

1ES70021.00





23)24)25)26)27)28)29)30)32)33)34)36)37)38)39)40)41)42)43)44)45)46)47)48)49)50)52)53)55)56)57)58)59)60)61)62)64)66)67)68)69)

bis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDimethylphthalateAcenaphthylene2 , 6 -Dinitro toluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4 , 6-Dinitro-2-methylphenolr.-Nitrosodiphenylamine4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluor ant henePyreneButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysene

810101010101111111212121213131313131313141414141414141415161616171718192021232323

.32

.20

.35

.48

.54

.69

.24

.61

.98

. 13

.21

.51

.74

.05

.37

.25

.57

.73

.78

.82

. 05

.08

.50

.80

.72

.91

. 97

.99

.82

.22

.61

.99

.45

. 10

.22

.84

.41

.87

.31

.22

.42

9316218012812722510714223719619616265163152165138153184109168165149166204138198169248284266178167178149202202149228252228

1957781833171888634776572299511168661690363100841232891430111483213034591179023518305064071019511099123087836124234223

4489231285833604003515501896049051291279

239127132694183581128036509673434831511407568962583669620130255989578039161004563749

45535349535347505153515139494950624951494949474951654850484852486850454849465C7749

.68

.84

.33

.87

.24

. 13

.89

.75

.97

.87

.40

.25

.18

.02

.52

.22

.46

.05

.22

.04

.49

.97

.08

.31

. 11

.93

.77

.97

.72

.20

. 14

.88

.60

.00

.83

. 35

. 94

.84

.22

. 17

.58

ngngngngngngngngngngngngng #ngngngng tfngng #ng #ngngngngngng #ngngngngngngngngngngngngngngng

1009698981009892100999996967610010088789742889382989992698598949999

10096999994958910098100

(#) = qualifier out of2351S02.D 8270.M

range (m) = manual integrationWed Dec 17 10:08:46 1997 Page 2

Quantitation Report


MS Integration Params : LSCINT.PQuant Time: Dec 17 10:08 1997


(Not Reviewed)






70)72)73)74)75)76)77)78)

bis (2-Ethylhexyl)phthalate 23Di-n-octylphthalateBenzo [b]Benzo [k]Benzo [a]Indeno [1Dibenz [aBenzo [g,

f luoranthenef luoranthenepyrene,2,3 -cd] pyrene,hj anthraceneh, i] perylene

24252526292930

.24

.64

.83

.88

.60

.58

.56

.42

149149252252252276278276

314379522354556669529456621750593943465639501740

43.38.40.39.50.47.48.46.

4016766599310484

ngngngngngng fngng

999999100100

t 10010099

(#) = qualifier out of range (m) = manual integration2351S02.D 8270.M Wed Dec 17 10:08:46 1997 Page 3

Quantitation Report



1ES70021.00




Abijndaace

900000

850000

800000

750000

700000

650000

600000

550000

500000

450000

400000

350000

300000

250000

200000

150000

100000

50000

0trim*->

TIC:2351S02.D

n

|

ww—

M

?£

|~

'

fji i 'tf

i _ L. __ r,,_

« «! - i

i2V a

2

1z

1

';

t * *** ^-J -

« S1 1

. j' ': ' • : .| i !

, .1 '.i

I

j

ji , _ ; : . :; •., i

1<Jar ^

•

i

I

i

i.VM*

[i

1

* I n 1 - !i iV-^vVS

i

l|

1

! fiT

i

4

|.

I

I l i ' ' . 1 i * V , ' \ _ 1 \1 11 II i "• _v_—— —— ' — ---- ----- ———— —— - ——————————

8.00 1(XOO 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 2800 30.00 32.00 34.00

2351S02.D 8270.M Wed Dec 17 10:08:54 1997 Page 4

Evaluate Continuing Calibration Report <p 70 j X/2.' % 7o9v c3' -

J Data File : J:\7002\DATA\2354S02.D Position: 'l^T Acq On : 20 Dec 1997 8:09 am Operator: ESF Sample : SSTD050 Inst : 7002


Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Fri Dec 19 10:25:03 1997Response via Single Level Calibration


123456789

10111213141516

1713192021222324252627282930

313233343535373339



ITCTCTSCTTTCT

Compound

1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol -d52 -Chlorophenol-d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chloropropane4 -Methylphenoln-Nitroso-di-n-propylamineKexachloroe thane

Naphthalene-d8Nitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3-methylphenol2 -Methylnaphthalene

Acenaphthene-dlOHexachlorocyclopentadiene2,4,6 -Tri chlorophenol2,4,5 -Tri chlorophenol2 -Fluorobiphenyl2 -Chloronaphthalene2 -NitroanilineDime thylphthal ateAcenaphthylene

AvgRF

11I1011111103110

10000000000000

100010011

.000

.328

.528

. 174

.661

.692

. 522

.258

.402

.383

. 125

. 924

.381

.262

.044

.579

.000

.386

.406

.827

.224

.310

.422

.291

.324

.876

.395

.200

.304

.550

. 000

. 394

.390

.406

.024

. 970

.492

. 180

.603

CCRF

11110111111I2100

10000000000000

100011011

.000

.362

.574

.272

.734

. 903

.428

.465

.568

. 547

.329

.069

.740

.437

. 947

. 571

.000

.381

.403

. 802

.258

.371

.413

.350

.350

. 970

.469

.210

.357

.623

.000

.281

.467

.484

. 155

. 050

.468

.244

.800

%Dev

0-2-3-8

-11-126

-16-11-11-18-1519

-1391

0103

-15-192

-20-8

-10-18-5

-17-13

028-19-19-12-84

-5-12

.0

.6

.0

.3

.0

.5

.2

.5

.8

. 9

. 1

. 7

.0

. 9

.3

.4

. 0

.3

. 7

. 0

.2

. 7

. 1

.3

. 0

.7

.7

.0

.4

.3

.0

. 7#

.7

.2

.8

.2

. 9

.4

.3

Area%

152tf155#151#154#145148142152#154#152 it153#139128156#147142

149143137139145151#142152#1461491608141149150#

144'98

146139144147129144146

Dev (min)

0000000000000000

00000000000000

000000000

.00

.00

.00

.00

.00

.00

.00

. 00

. 00

. 00

. 00

.00

.00

.00

.00

.00

.00

. 00

.00

.00

.00

.00

.00

.00

.00

.00

.00

. 00

.00

. 00

. 00

.00

.00

. 00

.00

. 00

. 00

.00

.00

(#) = Out of Range2354S02.D 8270.M Sat Dec 20 08:55:37 1997 Page 1


^Data File : J:\7002\DATA\2354S02.D Position: 1Acq On : 20 Dec 1997 8:09 am Operator: ESSample : SSTD050 Inst : 7002Misc : 2ul of S-1020B Multiplr: 1.00MS Integration Params : LSCINT.P



' CTTCMTTMTCTCMTTCTCTT

ITTSCTCTCMTCTTCTTCT

ICMTSTCTTCTT

ITCTCTCTCTCT

Compound

2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 ,4-Dinitro tolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline

Phenanthrene-dlO4 , 6-Dinitro-2-methylphenoln-Nitrosodiphenylamine2,4,6 -Tribromophenol4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthene

Chrysene-dl2PyreneTerphenyl-dl4ButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysenebis (2 -Ethylhexyl) phthalate

Perylene-dl2Di-n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2,3 -cd] pyreneDibenz [a, h] anthracene

AvgRF

00000101100

10000000001110000000

1000000

.318

.339

. 974

.220

.135

.357

.407

. 170

. 095

.595

.276

.000

.143

.405

. 186

.235

.322

.202

.881

.688

.866

.068

. 018

.000

.920

.650

.426

.885

.200

.855

. 512

. 000

.952

. 965

. 913

.868

.853

.650

CCRF

00100101100

100000000011110c1000

111_

1000

.345

.400

. 105

. 108

. 125

.575

.453

.288

.217

.637

.354

.000

. 106

.474

. 190

.254

.355

.224

.993

. 872

. 996

. 164

. 133

.000

. 070

.755

.453

.006

.279

. 976

.583

. 000

.232

. 120

. 114

. 963

. 983

.785

%Dev Area%

-8-18-13507

-16-11-10-11-7

-28

025-17-2-8

-10-10-12-26-15-9

-11

0-16-16-6

-13-39-14-13

0-29-16-22-10-15-20

.5

.0

.4

.9#

.4

. 1

.3

. 1

. 1

. 1

.3#

. 0• 9#. 0.2. 1.2. 9. 7• 7#.0.0. 3

.0

.3

.2

.3

.7

.5#

.2

. 9

. 0

.4#

. 1

. 0

. 9

.2

.8

141188#14575148144146139141142214tf

13883147133135135132138200#142136136

136133139132140214#137129

112129113120113112116

Dev (min)

00000000000

000000000000

00000000

0000000

.00

.00

. 00

.00

. 00

.00

.00

. 00

.00

.00

.00

.00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

.00

. 00

. 00

.00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

.00

. oc

. 00

.00

.00

. 00

•) = Out of Range54S02.D 8270.M Sat Dec 20 08:55:43 1997 Paae 2

Evaluate Continuing Calibration ReportrData File : J:\7002\DATA\2354S02.DAcq On : 20 Dec 1997 8:09 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.P




J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Single Level Calibration

0.000 Min. Rel. Area25% Max. Rel. Area

50% Max. R.T. Dev150%

0.50min

Compound


AvgRF

0.751

CCRF

0.756

%Dev Area% Dev(min)

-0 .7 101 0.0078 CT

(#) = Out of Range SPCC's out = 0 CCC's out = 02354S02.D 8270.M Sat Dec 20 08:55:43 1997 Paqe 3



Position:Operator;Inst :Multiplr:

1ES70021.00



J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2353S02.D8270


1) 1, 4-Dichlorobenzene-d4 8.6517) Naphthalene-dS 10.4231) Acenaphthene-dlO 13.6451) Phenanthrene-dlO 16.9163) Chrysene-dl2 23.3371) Perylene-dl2 26.71

System Monitoring Compounds2) 2-Fluorophenol 7.21Spiked Amount 150.000 Range 213) Phenol -d5 8.15Spiked Amount 150.000 Range 104) 2-Chlorophenol-d4 8.41Spiked Amount 150.000 Range 335) 1, 2-Dichlorobenzene-d4 8.90Spiked Amount 100.000 Range 1618) Nitrobenzene-d5 9.39Spiked Amount 100.000 Range 35

35) 2-Fluorobiphenyl 12.22Spiked Amount 100.000 Range 43

54) 2 , 4, 6-Tribromophenol 15.36Spiked Amount 150.000 Range 1065) Terphenyl-dl4 20.67Spiked Amount 100.000 Range 33

Target Compounds6) Phenol 8.177) bis (2-Chloroethyl) ether 8.298) 2-Chlorophenol 8.439) 1, 3-Dichlorobenzene 8.61

10) 1 , 4 -Dichlorobenzene 8.6711) 1, 2 -Dichlorobenzene 8.9212) 2-Methylphenol 8.8913) 2 , 2 ' -oxybis (1 -Chloropropan 8.9514) 4-Methylphenol 9.0715) r.-Nitroso-di-n-propylamine 9.1516) Hexachloroethane 9.3219) Nitrobenzene 9.4220) Isophorone 9.7221) 2-Nitrophenol 9.8622) 2, 4-Dimethylphenol 9.80

152136164188240264

112- 11099

- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

94931281461461461084510870

1177782139107

105463 40.00 ng364772 40.00 ng199973 40.00 ng347860 40.00 ng380266 40.00 ng297255 40.00 ng

179589 52.81 ngRecovery = 35

207531 52.47 ngRecovery = 34

167720 50.93 ngRecovery = 3396709 49.33 ngRecovery = 49

173636 52.91 ngRecovery = 52

288619 50.31 ngRecovery = 5082804 52.03 ngRecovery = 34

359011 52.03 ngRecovery = 52

250842 52.73 ng188285 53.09 ng193194 50.23 ng206712 49.83 ng203917 49.97 ng175196 49.21 ng140909 49.58 ng361210 53.45 ng189445 52.02 ng124797 54.58 ng75326 50.95 ng183842 52.69 ng365745 52.91 ng117744 50.41 ng169264 50.17 ng

-0.02-0.02-0.02-0.02-0.02-0.02

-0.02.21%

-0.02.98%

-0.02.95%

-0.02.33%

-0 .02.91%

-0 .02.31%

-0 .02.69%

-0 .02.03%

Qvalue909391999898

100959887999497

# 7895

(#) = qualifier out of range (m) = manual integration2354S02.D 8270.M Sat Dec 20 08:46:25 1997 Page 1



Position: 1Operator: ESInst 7002Multiplr: 1.00





23)24)25)26)27)28)29)30)32)33)34)36)37)38)39)40)41)42)43)44)45)46)47)48)49)50)52)53)55)56)57)58)59)60)61)62)64)66)67)68)69)

bis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDimethylphthalateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4,6-Dinitro-2 -methylphenoln-Nitrosodiphenylamine4 - Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi-n-butylphthalateFluoranthenePyreneButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysene

810101010101111111212121213131313131313141414141414141415161616171718192021232323

.29

. 19

.33

.46

.52

.67

.22

.58

. 95

. 11

.19

.49

.71

.03

.34

.22

.55

.71

.76

. 80

.03

. 06

.48

.78

.70

.88

. 94

.96

.80

.20

. 59

.97

.43

.07

.20

.83

.38

.85

.29

.20

.39

9316218012812722510714223719619616265163152165138153184109168165149166204138198169248284266178167178149202202149228252228

1882851597091596764423332139289569016295428413670281116791121050262571116916310913450024861801000542761902709931205393667113153321867304293159239885964625120615311032715438897198

431850379208433103506223492747508422215254478170132749463990

5247484949475048524850495550504953505354505051494958545051505049515051495150505150

.99

. 90

.36

.95

.96

.71

.73

.71

. 16

.93

. 10

.84

.00

.67

.66

.73

.86

. 13

. 84

.08

.21

.45

.05

.83

.23

.28

.02

.31

.08

. 93

. 58

. 53

. 84

. 58

. 62

. 82

. 93

. 68

.44

.79

. 98

ngngngngngngngngngngngngngngngngng ftngng tfngngngngngngng #ngngngngngngngngngngngngngngng

9998100981009795

10099999798851009994859942929690

10010095743999969999

10099

10099989790

1DO9999

(#) = qualifier out of range (m) = manual integration2354S02.D 8270.M Sat Dec 20 08:46:27 1997 Page 2

Quantisation Report




(Not Reviewed)






70)72)73)74)75)76)77)78)

bis (2-Ethylhexyl)phthalate 23.Di-n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2, 3-cd] pyreneDibenz [a, h] anthraceneBenzo [g, h, i] perylene

24.25.25.26.29.29.30 .

2162818658555339

149149252252252276278276

277186457769416004413876357820365260291564280746

5152494949585958

.77

.38

.08

.57

.76

.98

. 50

.74

ngngngngngng #ngng

9899989998

1009998

(#) = qualifier out of2354S02.D 8270.M

range (m) = manual integrationSat Dec 20 08:46:28 1997 Page 3

Quantitation Report





[Abundance

J : \7002 \METHODS\8270 .M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J : \7002\DATA\2353S02.D

TIC: 2354S02.D950000

900000

850000

800000

750000

700000

650000

600000

550000 *

500000 \{

450000 ;j

400000

350000

300000

250000

200000

150000

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2354S02.D 8270.M

12.00 14.00 16.00 18.00 20.00

Sat Dec 20 0 8 : 4 6 : 3 4 1997

22100 24.00 26.00 2soO 30.00 32.00 34.00

Page 4

Evaluate Continuing Calibration Report c A9709V?/,

^ Kta File : J:\7002\DATA\2363S03.D Position: 1•HVcq On : 29 Dec 1997 10:40 am Operator: ES^T Sample : SSTD050 Inst : 7002r Misc : 2ul of S-1020B Multiplr: 1.00

MS Integration Params : LSCINT.P



123456789

10111213141516

1718192021222324252627282930

313233343536373839



ITCTCTSCTTTCT

Compound

1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol -d52 -Chlorophenol -d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2'- oxybi s ( 1 - Chloropropane4 -Methylphenoln-Nitroso-di -n-propylamineHexachloroe thane

Naphthalene-dSNitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4 -Chloro-3 -methyl phenol2 -Methylnaphthalene

Acenaphthene-dlOHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5 -Tri Chlorophenol2 - Fluorobiphenyl2 -Chloronaphthalene2 -NitroanilineDime thylphthal ateAcenaphthylene

AvgRF

111101111I103110

10000000000000

100010011

.000

.328

.528

.174

.661

.692

.522

.258

.402

.383

.125

. 924

.381

.262

. 044

.579

.000

.386

.406

.827

.224

.310

.422

.291

.324

.876

.395

.200

.304

.550

.000

.394

.390

.406

.024

.970

.492

. 180

.603

CCRF

1111011111112100

10000000000000

100011011

.000

.334

.612

.277

.753

.931

.453

.482

.571

. 546

.331

. 128

.813

.395

.969

.579

.000

.388

.414

.806

.251

.366

.416

.348

.340

.976

.483

.201

.353

.621

.000

.263

.459

.454

.163

. 068

.492

.228

.806

%Dev Area%

0-0-5-8

-13-144

-17-12-11-18-2216

-1070

0-0-22

-12-181

-19-4

-11-22-0

-16-12

033-17-11-13-100

-4-12

.0

.5

.5

.8

. 9

. 1

. 5

.8

. 1

.8

.3

. 1

.8

.5

.2

. 0

. 0

. 5

.0

. 5

. 1

. 1

.4

.6

.9

.4

.3

.5

. 1

.9

. 0

.2#

. 7

. 8

.6

. 1

. 0

. 1

. 7

135135138138133134129137137135136130117135134128

134131127126126134129135127135148121132135

12579124113126130117123127

Dev (min)

0000000000000000

00000000000000

000000000

.00

.00

.00

.00

.00

. 00

.00

.00

.00

.00

.00

.00

.00

. 00

.00

. 00

.00

.00

.00

.00

. 00

.00

.00

.00

.00

.00

.00

.00

.00

. 00

.00

.00

.00

.00

.00

.00

.00

.00

. 00

(#) = Out of Range2363S03.D 8270.M Mon Dec 29 11:23:30 1997 Page 1


l W&ta File : J:\7002\DATA\2363S03.D Position: 1jj PAcq On : 29 Dec 1997 10:40 am Operator: ESf Sample : SSTD050 Inst .- 7002' Misc : 2ul of S-1020B Multiplr: 1.00




4041424344454647484950

515253545556575359€05132

S3343556'~158>9'0

'12'34

' 56'7


ITTSCTCTCMTCTTCTTCT

ICMTSTCTTCTT

ITCTCTCTCTCT

Compound

2, 6 -Dinitro toluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2, 4 -Dinitro tolueneDiet hylphthal ateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline

Phenanthrene-dlO4, 6 -Dinitro -2 -methylphenoln-Nitrosodiphenylamine2,4, 6-Tribromophenol4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthene

Chrysene-dl2PyreneTerphenyl -d!4Butylbenzylph thai ateBenzo [a] anthracene3,3' -DichlorobenzidineChrysenebis (2-Ethylhexyl) phthalate

Perylene-dl2Di -n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneInder.o [ 1 , 2 , 3 -cd] pyreneDibenz [a, h] anthracene

AvgRF

00000101100

10000000001110000000

1000000

.318

.339

. 974

.220

.135

.357

.407

. 170

. 095

.595

.276

.000

. 143

.405

. 186

.235

.322

.202

.881

.688

. 866

.068

.018

.000

. 920

.650

.426

.885

.200

.855

.512

.000

. 952

.965

. 913

.868

. 853

.650

CCRF

0.0.1 .0 .0.1.0.1.1 .0.0.

1.0.0 .0.0.0 .0.1 .0.1 .1 .1.1.1.0.0.0.0.0.0.

1.1 .1 .1 .0 .0 .0.

354401144094107573449279219617325

000104488175251345170010880008197142

000119762501981227944622

000496174202971622511

%Dev Area%

-11-18-175720-15-10-9

-11-3

-17

027-205

-6-715-14-27-16-12-12

0-21-17-17-10-13-10-21

0-57-21-31-112721

.3

.3

.5

.3#

.7

.9

.3

.3

.3

. 7

.8

.0

.3#

.5

. 9

.8

. 1

.8

.6

.9#

.4

. 1

.2

.0

. 6

.2

.6

.8

. 5

.4

. 5

.0

. 1#

. 7• 7#. 9.!#.4

125163tf13056

110124125120123119170#

1186912910411411386121173#123120118

113120117122114145111115

791128892815154

Dev (min)

00000000000

000000000000

00000000

0000000

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

.00

. 00

.00

.00

.00

. 00

. 00

. 00

.00

. 00

. 00

.00

.00

.00

. 00

. 00

. 00

.00

(#) = Out of Range2363S03.D 8270.M Mon Dec 29 11:23:36 1997 Page 2


File : J:\7002\DATA\2363S03.Dicq On : 29 Dec 1997 10:40 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.P




J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Single Level Calibration

1ES70021 .00



Compound


AvgRF

0.751

CCRF

0.486

%Dev Area% Dev(min)

35.3tf 461* 0.00CT

(#) = Out2363S03.D

of Range8270. M Mon

SPCC's out = 0 CCC 'Dec 29 11:23:36 1997

s out = 3?aae 3






1ES70021 .00










10) 1 , 4 -Dichlorobenzene11) 1 , 2 -Dichlorobenzene12) 2-Methylphenol

81013162326

7Range

8Range

8Range

8Range

9Range

12Range

1 5Range

20Range

.69

.47

.69

.96

.39

.78

.2621.2010.4633.9416.4335.2743.4110.7333

152136164188240264

112- 11099

- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

93837327872173340297710317544211728

156439Recovery

189134Recovery


159163Recovery


302483Recovery

404040404040

52

51

51

48

50

49

54

48

.00

.00

.00

.00

.00

.00

. 90=.93=.73=.29=.72=.46=.96=. 90=

ngngngngngng

ng35

ng34

ng34

ng48

ng50

ng49

ng36

ng48

.27%

.62%

.49%

.29%

.72%

.46%

.64%

. 90%

000000

0

0

0

0

0

0

0

0

Qvala888888

13) 2 , 2 ' -oxybis ( 1 -Chloropropan 914) 4 -Methylphenol 915) n-Nitroso-di -n-propylamine 916) Hexachloroethane19) Nitrobenzene20) Isophorone21) 2-Nitrophenol22) 2 , 4-Dimethylphenol

99999

.22

.34

.48

.66

.71

.96

.94

.00

. 11

. 19

.37

.46

. 77

.91

.85

9493

12814614614610845108701177782139107

22653117048617387218432018130615611413230533000316367611369667907169864330489102947149906

515051515049505053545050505151

. 90

.71

.04

.54

.32

.00

.21

. 99

. 76

. 70

.27

. 70

.78

. 90

.34


#

.01

.00

.00

. 00

.00

.01

.02

.01

.01

.01

.00

.00

.00

.00

ue909391999999989499909898977998

(#) = qualifier out2363S03.D 8270.M

of range (m) = manual integrationMon Dec 29 11:17:33 1997 Page 1








23)24)25)26)27)28)29)30)32)33)34)36)37)38)39)40)41)42)43)44)45)46)47)48)49)50)52)53)55)56)57)58)59)60)61)62)64)66)67)68)69)

bis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2-NitroanilineDime thy IphthalateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2,4-DinitrotolueneDie thy IphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4,6-Dinitro-2 -methylphenoln-Nitrosodiphenylamine4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthenePyreneButylbenzy IphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysene

810101010101111121212121213131313131313141414141414151515161617171718192021232323

.34

.24

.38

.50

.57

.72

.27

.63

.01

. 16

.24

. 54

.77

.08

.39

.28

.60

.76

.81

.86

.08

. 11

.53

.83

.75

.93

.00

.02

.85

.26

.65

.02

.48

. 12

.25

.88

.44

. 90

. 34

.25

.45

9316218012812722510714223719619616265

163152165138153184109168165149166204138198169248284266178167178149202202149228252228

17048614245113929639980419797282263144516254690569129935598327

2314591065512660373912227663186839247844203192316034083797364

2771172642081337927037838672181560932731282456319937586732747737498644538442509044413819888338957189925374563

4952494855495349605251505149495355497560495048495063605051515549485047494948485348

.53

.66

.93

.90

.03

.65

.22

.50

.32

.25

. 14

.43

.47

.32

.32

.70

.30

.40

.75

.43

.06

.05

.04

.42

.06

.39

.41

.24

.60

.34

.47

.36

.68

. 19

.79

. 15

. 19

.73

.50

.48

.59

ngngngngngngngngngngngngngngngngng #ngngngngngngngngng #ngngngngngngngngngngngngngngng

109

109999999998

1099899999999799999

109

109999999

(#) = qualifier out of range (m) = manual integration2363S03.D 8270.M Mon Dec 29 11:17:36 1997 Page 2

Quantitation Report




(Not Reviewed)






70)72)73)74)75)76)77)78)

bis (2-Ethylhexyl)phthalateDi-n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2, 3-cd] pyreneDibenz [a, h] anthraceneBenzo [g, h, i] perylene

2324252526292930

.26

.66

.86

.91

.64

.65

.62

.49

149149252252252276278276

247083395969310579318100256874164638135272128652

4648495150434744

.40

.08

.23

.17

.02

.51

.27

.27

ngngngngngng ftngng

96989899981009798

(ft) = qualifier out of range (m) = manual integration2363S03.D 8270.M Mon Dec 29 11:17:36 1997 Page 3

Quantitation Report

Data File : J : \ 7002 \DATA\2363S03 .DAcq OnSampleMisc

: 29 Dec 1997 10:40 am: SSTD050: 2ul of S-1020B


MS Integration Params : LSCINT.PQuant Time: Dec 29 11:17 1997

MethodTitleLast

: J : \7002 \METHODS\8270 .M

Quant Results File: 8270. RES

(RTE Integrator): GC/MS method 8270 TCL extractables.

Update : Fri Dec 19 10:25:03 1997Response via : Continuing Cal File: J:

Abundance850000

800000

750000

700000

650000

600000

550000

500000

450000

400000

350000

300000

250000

200000

150000

100000

50000

0Tlme->

\7002\DATA\2363S02.DTIC:

*

*> —.i£^

« «».} '

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ii

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2363S03.D

£ 10! =10

12;

i ]

1 i i

2 V --•v t 2t ]

I S]C

? 'I;!i

5.V

:l !•! t| t

''

: : • . ; { • j' 1 ' ' .' : . ; : ''.

8.00 10.00 12.00 14.00 16.00

i

i

^

i

*

18.00 20.00

I

jfvf

;1 .; i» ii

: I'. >.\. H22.00 2440 2600 28.00 3000 "12.00 34.00

Mon Dec 29 11:17:42 1997 Page 4

Evaluate Continuing Calibration Report /' «•/> f. -

H^BData File : J:\7002\DATA\2058S02.D Position: 2^TAcq On : 27 Feb 1998 8:58 am Operator: ESr Sample : SSTD050 Inst : 7002


Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Fri Feb 20 14:27:15 1998Response via Single Level Calibration


123456789

10111213141516

1718192021222324252627282930

313233343536373839

(**20



ITCTCTSCTTTCT

) =

Compound

1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol -d52 -Chlorophenol -d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1-Chloropropane4 -Methylphenoln-Nitroso-di -n-propylamineHexachlo roe thane

Naphthalene -d8Nitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -Methylnaphthalene

Acenaphthene-dlOHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2 -Fluorobiphenyl2 -Chloronaphthalene2 -NitroanilineDimethylphthalateAcenaphthylene

Out of Range58S02.D 8270. M Fri Feb 27 09

AvgRF

1 .1.I .1 .0.1 .1 .1 .1.1 .I .0.1.0.0.0.

1.0.0.0.0.0.0 .0 .0 .0.0 .0 .0 .0.

1 .0.0 .0.1 .1 .0 .1 .1 .

:56

000123169092709302054163380403182819186907620521

000361366611211295376299379936310272258567

000271441464305127342255698

:56

CCRF

1 .1.1.1.0 .1 .1.1 .1.1 .1.1.1.1.0.0 .

1 .0.0 .0.0.0.0.0.0 .0.0 .0 .0.0.

1 .0.0.0.1 .1 .0 .1 .1 .

1998

000381381216773652150415561526318002248059573504

000355373646238338424334393969394251293579

000183468489302105351190745

%Dev Area%

0-23-18-11-9

-26-9

-21-13-8

-11-22-5

-1673

01

-1-5

-12-14-12-11-3-3

-277

-13-2

032-6-502

-25

-2

.0

.0

. 1

.4

.0

.9**

. 1

. 7

.1

.8

.5

.3

.2

.8

.6

.3

. 0

. 7

.9

. 7

.8

.6

.8

.7

.7

.5

.1**

. 7

.6

. 1

.0

.5**

. 1

.4

.2

. 0

.6

.2

.8

214**249**236**222**212**236**233**218**217**206**207**214**232**210**199**196**

205**196**198**202**193**187**233**195**197**199**197**181**195**188**

199**151**185**187**191**193**201**185**196**

De

0000000000000000

00000000000000

000000000

v (min)

.00

.00

.00

.00

.00

.00

.00

. 00

.00

.00

.00

.00

.00

.00

.00

.00

.00

. DO

.00

.00

. 00

.00

.00

.00

.00

. DO

.00

. 30

.DO

. DO

.DO

. DO

. 30

. 30

. 30

. 30

. 30

. 30

. 30

Page 1


•Data File : J:\7002\DATA\2058S02.D Position: 2^Acq On : 27 Feb 1998 8:58 am Operator: ESr Sample : SSTD050 Inst : 7002

Wise : 2ul of S-1020B Multiplr: 1.00MS Integration Params : LSCINT.P

Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Fri Feb 20 14:27:15 1998Response via Single Level Calibration


4041424344454647484950

515253545556"7£359606162

636465666768€970

71727374757677


ITTSCTCTCMTCTTCTTCT

ICMTSTCTTCTT

ITCTCTCTCTCT

Compound

2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -Dinitro tolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline

Phenanthrene-dlO4, 6 -Dinitro -2 -methyl phenoln-Nitrosodiphenylamine2,4, 6-Tribromophenol4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthene

Chrysene-dl2PyreneTerphenyl-dl4ButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysenebis (2-Ethylhexyl) phthalate

Perylene-dl2Di -n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1 , 2 , 3 -cd] pyreneDibenz [a, h] anthracene

AvgRF

0010C101100

10000000001110000000

1011000

.297

.301

.069

.065

.103

.466

.360

. 180

.116

.660

.212

.000

. 081

.458

. 173

.287

. 367

. 123

.956

. 729

. 932

.075

.082

. 000

. 934

. 707

.376

.911

.226

. 914

.476

.000

.908

. CIS

. 117

.925

. 907

.729

CCRF

00100101100

10000000001111000000

1011000

.303

.305

.083

.023

. 082

.587

.373

. 122

.168

.633

.234

.000

. 066

.458

. 167

.278

. 384

. 098

. 993

.860

. 976

.004

. 187

.000

. 121

.821

.372

.960

.235

. 964

.437

. 000

.898

. 059

.307

.971

.904

.696

%Dev Area%

-2-1-16420-8-34

-44

-10

018033

-420-3

-18-46

-9

0-20-161

-5-4-58

01

-4-17-504

.0

.3

.3

.6#

.4

.3

.6

. 9

.7

.1

.4

.0

.5

. 0

.5

. 1

.6

.3

.9

.0

.7

.6

. 7

.0

.0

. 1

. 1

.4

.0

. 5

.2

. 0

. 1

. 0

. 0

. 0

.3

.5

186#193#194#144211#200#188#176#201#188#257#

207#205#199#188#190#200#230#202tf220#211#188#217#

195#217#213#191#191#189#202#170#

156#148153#174#149144138

Dev (min)

00000000000

000000000000

00000000

0000000

.00

.00

.00

.00

.00

.00

. 00

. 00

.00

.00

.00

. 00

. 00

.00

.00

. 00

. 00

.00

.00

. 00

. 00

. 00

.00

. 00

. 00

. 00

.00

. 00

.00

.00

. 00

. 00

. 00

. CO

. CO

. CO

. CO

.00

(#) = Out of Range2058S02.D 8270.M Fri Feb 27 09:57:03 1998 Page 2


ata FileAcq OnSampleMisc

J:\7002\DATA\2058S02.D27 Feb 1998 8:58 amSSTD0502ul of S-1020B

PositionOperatorInst

2ES7002

Multiplr: 1.00MS Integration Params: LSCINT.P



J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 20 14:27:15 1998Single Level Calibration

0.000 Min. Rel. Area25% Max. Rel. Area

50% Max. R.T. Dev O.SOmin150%

Compound

78 CT Benzo [g,h,i]perylene

AvgRF CCRF

0.756 0.784

%Dev Area% Dev(min)

-3.7 146 0.00

(#) = Out of Range2058S02.D 8270.M

SPCC's out = 0 CCC's out = 1Fri Feb 27 09:57:03 1998 Page 3


Data File : J:\7002\DATA\2058S02.DAcq On : 27 Feb 1998 8:58 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Feb 27 9:54 1998


2ES70021 .00



J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 20 14:27:15 1998Continuing Cal File: J:\7002\DATA\2051S02.D8270


1) 1, 4-Dichlorobenzene-d417) Naphthalene-dS31) Acenaphthene-dlO51) Phenanthrene-dlO63) Chrysene-dl271) Perylene-dl2





Target Compounds6) Phenol7) bis (2-Chloroethyl) ether8) 2-Chlorophenol9) 1, 3 -Dichlorobenzene

10) 1 , 4 -Dichlorobenzene11) 1, 2 -Dichlorobenzene12) 2-Methylphenol

81013162326

7Range

8Range

8Range

8Range

9Range

12Range

15Range

20Range

.69

.46

.69

.95

.37

.77

.2521.1910.4533.9416.4335.2743.4110.7233

152136164188240264

112- 110

99- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

260063705267341150559584616910403634

448870Recovery

448879Recovery

395195Recovery

251138Recovery

312782Recovery

555316Recovery

116886Recovery

633055Recovery

404040404040

57

53

52

50

49

48

44

53

.00

.00

.00

.00

.00

.00

.48=.54=.27=. 14=.47=.22=.04=.98=

ngngngngngng

ng38

ng35

ng34

ng50

ng49

ng48ng29

ng53

000000

0.32%

0.69%

0.85%

0.14%

0.47%

0.22%

0.36%

0. 98%

.03

.03

.04

.03

.03

.04

.02

.02

.02

.03

.03

.03

.03

.04

Qvalue

13) 2 , 2 ' -oxybis (1 -Chloropropan14) 4 -Methylphenol15) n-Nitroso-di -n-propylamine16) Hexachloroethane19) Nitrobenzene20) Isophorone21) 2-Nitrophenol22) 2 , 4-Dimethylphenol

888888889999999

.21

.33

.47

.65

.71

.96

. 93

.99

. 11

. 18

.36

.46

.76

.91

.85

9493

12814614614610845108701177782

139107

536934373709460018507438496094428354325777405576344297186318163684329050569851209632297672

535251504948505148474650505148

. 77

.45

. 18

. 98

. 00

. 93

. 89

.80

. 92

.63

.94

.27

.46

.08

.31


#

#

9285849910098977099798385926794

(#) = qualifier out of range (m) = manual integration2058S02.D 8270.M Fri Feb 27 09:55:16 1998 Page 1




Position:Operator;Inst ;

2ES7002

MS Integration Params: LSCINT.PQuant Time: Feb 27 9:54 1998

Multiplr: 1.00





23)24)25)26)27)28)29)30)32)33)34)36)37)38)39)40)41)42)43)44)45)46)47)48)49)50)52)53)55)56)57)58)59)60)61)62)64)66)67)68)69)

bis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDime thylphthal ateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzofuran2,4-DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4 , 6-Dinitro-2 -methylphenoln-Nitrosodiphenylamine4 -Bromophenyl -phenyletherKexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthenePyreneB'_;tylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysene

810101010101111121212121213131313131313141414141414151515161617171718192021232323

.33

.24

.38

.50

.58

.71

.27

. 63

.00

.16

.24

.54

.77

.07

.39

.27

.59

.76

.84

.87

.08

. 10

.52

.82

.74

.94

. 01

.01

.84

.25

.65

.01

.48

. 12

.24

.87

.43

.89

.32

.25

.44

9316218012812722510714223719619616265

163152165138153184109168165149166204138198169248284266178167178149202202149228252228

37370929485234666285416434726522149925864451072377868199593208642471166149737507637743989128998129944461745

971034805m67666815916447847949795727014099723m46502m32036919439926846868590694686601715682611702186830053864144286971740023181311743065

5447484947455148354851485348505253493350505450514862474644444648564948535655505851

.59

.61

.91

.03

.81

.05

.38

.01

.80

.54

.01

.78

.62

.83

.75

.57

.09

.06

.43

. 15

. 97

.36

.00

.89

.69

.72

.71

.79

.08

.03

.77

.28

.30

.95

.77

.70

.38

.44

. 15

. 16

. 18

ngngngngngngngngngngngngng tfngngngng #ngng #ngngngngngngngngngngngngngngngngngngngngngng

9994999897999210099989796769910096829942

9490989992

97929998999898100848387989598


of range (m) = manual integrationFri Feb 27 09:55:18 1998 Page 2

Quantitation Report


MS Integration Params: LSCINT.PQuant Time: Feb 27 9:54 1998


(QT Reviewed)






70)72)73)74)75)76)77)78)

bis (2-Ethylhexyl) phthalate 23Di-n-octylphthalateBenzo [b]Benzo [k]Benzo [a]Indeno [1Dibenz [aBenzo [g,

f luoranthenef luoranthenepyrene, 2, 3 -cd] pyrene, h] anthraceneh, i] perylene

24252526292930

.24

.65

.85

.90

.64

.66

.64

.48

149149252252252276278276

337163453169534102659538489717456119m351033m395456m

5053485450464646

.04

.82

.55

.37

.47

. 14

.97

.64

ngngngngngngngng

9798929493

(#) = qualifier out of range (m) = manual integration2058S02.D 8270.M Fri Feb 27 09:55:18 1998 Page 3

Quantitation Report

Data File : J:\7002\DATA\2058S02.DAcq On : 27 Feb 1998 8:58 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Feb 27 9:54 1998


2ES7002

Multiplr: 1.00



Abundance

J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 20 14:27:15 1998Continuing Cal File: J:\7002\DATA\2051S02.D

^TICfZ058S02.D

2200000

2000000

1800000

1600000

1400000

1200000

1000000

M

S

?|

*!*•<* '

1>vf*

800000 I

600000

400000

200000

tlm«->

i|lr

]

8.00

jj:

!i

V)«rt

a

ii

~.Y9J

i<3

j:l: i'-. -."i'1

10.00

M

|

f

9 o"* VM • —f i

s12.(

9 f

I Io, a

»-V

,! i :

• i ^ i' ; I ' ':J\ ' ; " I ' \' • ' r i " J \ ; ' i •/. '.l. K^J," l^^^V ~)0 14.00 16.0018.00

jgui20.00 2200 2440 26o 28oo 3ooo 32.00 34.00

2058S02.D 8270.M Fri Feb 27 0 9 : 5 5 : 2 6 1998 Page 4

Evaluate Continuing Calibration Report 0r

^^^Ka File : J:\7002\DATA\2155S02.D Position: 2Hfcq On : 4 Jun 1998 10:13 am Operator: ES^^Sample : SSTD050 Inst : 7002Y Misc : 2ul of S-1029C Multiplr: 1.00


Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Thu Jun 04 10:48:37 1998Response via Single Level Calibration


123456789

1011121314151617

181920212223242526272829303132

33343536373839

ISCscSCscMTCTCMTCTCMTCTTCTCTTCMTCTC

ISCTCTCCTCTTCTCTCTMCTTTCTMCT

ITCTCTSCTT

Compound

1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol -d52 - Chlorophenol -d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -DichlorobenzeneBenzyl Alcohol1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chloropropane4 -Methylphenoln-Nitroso-di-n-propylamineHexachloroe thane

Naphthalene-d8Nitrobenzene-d5NitrobenzeneIsophorone2-Nitrophenol2 , 4 -DimethylphenolBenzoic Acidbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -Methylnaphthalene

Acenaphthene - dl 0Hexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2 - Fluorobiphenyl2 -Chloronaphthalene2 -Nitroaniline

AvgRF

11110131111112110

100000000000000

1000110

.000

.273

.667

.263

.754

.764

.420

.341

.450

.461

.048

.247

.063

.367

.229

.060

.565

. 000

.332

.350

.747

.221

.323

. 197

. 918

.299

.328

. 949

.444

. 179

.306

.640

.000

.122

.378

.394

. 137

.082

.332

CCRF

1111013I111112110

100000000000000

1000110

.000

.376

.790

.337

.808

.713

.580

.281

.511

.530

.079

.359

. 137

.418

.266

.075

.596

.000

.340

.363

.781

. 199

.293

. 136

.945

.265

.320

. 969

.460

.172

.288

.663

.000

.069

.346

.377

.167

. 128

.342

%Dev Area%

0-8-7-5-72

-44

-4-4-3-9-7-2-3-1-5

0-2-3-4109

31-2112

-2-335

-3

04384-2-4-3

.0

.1

.4

.9

.2

.9

.7

.5

.2

.7

.0

.0

.0

.2

.0

.4

.5

. 0

.4

. 7

.6

.0

.3

. 0#

.9

.4

.4

. 1

.6

.9

.9

.6

.0

. 4#

.5

.3

.6

.3

.0

8891898889909089888885909091898888

848586848283639079828482828181

73507375777773

Dev (min)

00000000000000000

000000000000000

0000000

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

. 00

.00

. 00

.00

.00

.00

.00

.00

.00

. 00

. 00

.00

(#) = Out of Range2155S02.D 8270.M Thu Jun 04 11:24:54 1998 Page 1


^ Kita File : J:\7002\DATA\2155S02.D Position: 2^ Acq On : 4 Jun 1998 10:13 am Operator: ESW Sample : SSTD050 Inst : 7002^ Misc : 2ul of S-1029C Multiplr: 1.00


Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Thu Jun 04 10:48:37 1998Response via Single Level Calibration

40414243444546474849505152

535455565758596061626364

6566676869707172

7374757677

Min.Max.

TCTCTTCMTTMTCTCMTTCTCTT

ITTSCTCTCMTCTTCTTCT

ICMTSTCTTCTT

ITCTCTCT

RRF 0.000 Min. Rel .RRF Dev 25% Max. Rel.

Compound

DimethylphthalateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline

Phenanthrene-dlO4,6-Dinitro-2 -methyl phenoln-Nitrosodiphenylamine2,4, 6 -Tribromophenol4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthene

Chrysene-dl2PyreneTerphenyl -d!4ButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysenebis (2-Ethylhexyl) phthalate

Perylene-dl2Di-n-octyl phthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyrene

Area :Area :

AvgRF

1100100I01100

100000000011

11100000

11111

.247

.650

.318

.359

.030

. 157

.072

.503

.425

.201

. 172

.670

.358

.000

.136

.484

. 177

.260

.343

.134

.934

. 901

.963

. 136

.016

.000

.139

.000

.466

.921

.338

.861

.586

.000

.418

.318

.272

.100

50% Max.R.T. Dev 0 .SOmin150%

CCRF

1100100101100

100000000010

11100000

11111

.218

.734

.322

.347

.053

.083

.048

.524

.409

.112

.165

.625

.294

.000

. 109

.486

.185

.252

.347

.093

.954

.881

. 985

.028

. 952

.000

.199

.049

.437

.935

.324

.879

. 544

.000

.290

.276

.317

. 108

%Dev

2-5-13

-24733-1370617

019-0-43

-130-22

-296

0-5-46

-14

-27

093

-3-0

.3

. I

.3

.3

.2-1#.3#.4.8.4.6.7.9

.0

.9

.4

.5

. 1

.2

.6#

.1

.2

.3

.5

.3

.0

.3

. 9

.2

.5

. 1

. 1

.2

. 0

.0

.2

.5

. 7

Area%

747671667443#54726569717056

665469676967536761676262

6161625960546162

6262596764

Dev (min)

0000000000000

000000000000

00000000

00000

.00

.00

.00

. 00

.00

.00

. 00

. 00

.00

. 00

. 00

.00

.00

. 00

. 00

. 00

. 00

. 00

.00

.00

.00

. 00

.00

.00

. 00

. 00

. 00

. 00

.00

.00

. 00

. 00

. 00

. 00

. 00

.00

. 00

.00

(#) = Out of Range2155S02.D 8270.M Thu Jun 04 11:25:00 1998 Page 2


a File'Acq OnSampleMisc

J:\7002\DATA\2155S02.D4 Jun 1998 10:13 amSSTD0502ul of S-1029C

Position;Operator;Inst :

MS Integration Params: LSCINT.P



Compound

J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Thu Jun 04 10:48:37 1998Single Level Calibration

2ES7002

Multiplr: 1.00


AvgRF CCRF


%Dev Area% Dev(min)

78 CT Indeno[1,2,3-cd]pyrene79 CT Dibenz[a,h]anthracene80 CT Benzo[g,h,i]perylene

0.844 0.921 -9.1 68 0.000.632 0.702 -11.1 70 0.000.720 0.671 6.8 62 0.00

(#) = Out of Range2155S02.D 8270.M

SPCC's out = 0 CCC's out = 1Thu Jun 04 11:25:00 1998 Page 3



MS Integration Params: LSCINT.PQuant Time: Jun 4 10:47 1998


Position:Operator;Inst :Multiplr:

2ES70021.00



J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 03 13:57:53 1998Continuing Cal File: J:\7002\DATA\2154S04.D8270


1) 1 , 4-Dichlorobenzene-d418) Naphthalene-d833) Acenaphthene-dlO53) Phenanthrene-dlO65) Chrysene-dl273) Perylene-dl2

System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2-Dichlorobenzene-d4Spiked Amount 100.00019) Nitrobenzene-d5Spiked Amount 100.00037) 2-FluorobiphenylSpiked Amount 100.00056) 2 , 4 , 6-TribromophenolSpiked Amount 150.00067) Terphenyl-dl4Spiked Amount 100.000


10) 1 , 4 -Dichlorobenzene11) Benzyl Alcohol12) 1, 2 -Dichlorobenzene13) 2-Methylphenol

81013162326

7Range

7Range

8Range

8Range

9Range

11Range

15Range

20Range

.45

.19

.36

.60

.00

.34

.0221.9710.2233.6916. 1735.9643. 0610.3533

152136164188240264

112- 11099

- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

187018 40708757 40401186 40673428 40528111 40311922 40

321570 49Recovery

418420 48Recovery

312517 49Recovery

188871 51Recovery

301620 48Recovery

585342 49Recovery

155624 48Recovery

692533 50Recovery

.00

.00

.00

.00

.00

.00

.32=.44=.05=.17=.77=.03=.56=.93=

ngngngngngng

ng32

ng32

ng32

ng51

ng48

ng49

ng32

ng50

.88%

.29%

.70%tf

.17%

.77%

.03%

.37%

.93%

000000

0

0

0

0

0

0

0

0

.00

.00

.00

.00

.00

.01

.00

.00

.00

.00

.00

.00

.00

.00

Qvalue

14) 2 , 2 ' -oxybis ( 1 -Chloropropan15) 4-Methylphenol16) n-Nitroso-di -n-propylamine17) Hexachloroethane20) Nitrobenzene21) Isophorone22) 2-Nitrophenol

788888888889999

. 98

. 10

.24

.41

.47

.59

.71

.70

.75

.87

.94

. 11

.20

.49

.64

9493

128146146791461084510870

1177782

139

400497 49836867 49299456 49353145 50357626 50252295 47317627 51265804 51565169 49296028 50251320 50139307 50321899 49692210 49176449 48

.98

.50

.66

.20

.57

.98

.54

.06

.40

.95

.20

. 19

.43

.74

.86


#

#

#

tf

774685999986989488947192899568

(#) = qualifier out of range (m) = manual integration2155S02.D 8270.M Thu Jun 04 10:47:59 1998 Page 1










23)24)25)26)27)28)29)30)31)32)34)35)36)38)39)40)41)42)43)44)45)46)47)48)49)50)51)52)54)55)57)58)59)60)61)62)63)64)66)68)69)

2 , 4 -DimethylphenolBenzoic Acidbis (2-Chloroethoxy) methane2 , 4 -Dichlorophenol1,2, 4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDimethylphthalateAcenaphthylene2 , 6 -Dinitrotoluene3-NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzofuran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4,6-Dinitro-2 -methylphenoln-Nitrosodiphenylamine4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi-n-butylphthalateFluoranthenePyreneButylbenzylphthalateBenzo [a] anthracene

9989

10101010101111111112121213121313131313131414141414141515161617161719202122

.59

.71

. 10

.97

.10

.21

.29

.43

.93

.33

.70

.85

.93

.22

.45

.75

.06

.95

.27

.43

.49

. 53

.74

.77

.20

.48

.41

.59

.66

.68

.50

.90

.30

.66

. 12

.77

. 90

.50

.06

. 54

.95

1071059316218012812722510714223719619616265163152165138153184109168165149166204138198169248284266178167178149202202149228

25976612084383686723439328361985878040772115270325472458782034743173387189167565649171658610557869557161536173939528072416402400376446620519055786458399831356814745191482

40899521227029246778298802666741686829479865221801390791647288726616904

4945494848494948525234484849515151495050414650505050494946494949465050504848524949

.01

.18

. 17

.17

.77

.31

.37

.53

.71

.57

.60

.51

.54

.79

.80

.50

.45

.20

.31

.18

.33

.08

.85

.25

.98

.70

.82

.66

.98

.93

.38

. 58

.29

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.32

.73

.39

.85

.75

.80

. 99

ngng #ngngngngngngngngngngngngng #ngngngng #ngngng #ngngngngngng #ngngngngngngngngngngngngng

8686679898961001009498959999967199100907797907792839898906679969399969998989999999099


of range (m) = manual integrationThu Jun 04 10:48:01 1998 Page 2

Quantitation Report



(Not Reviewed)

Position: 2Operator: ESInst 7002


Multiplr: 1.00





70) 3,3'-Dichlorobenzidine 22.87 252 213855 49.05 ng71) Chrysene 23.06 228 580377 49.13 ng72) bis(2-Ethylhexyl)phthalate 22.91 149 359353 48.34 ng74) Di-n-octylphthalate 24.31 149 502924 48.96 ng75) Benzo[b]fluoranthene 25.47 252 497457 48.95 ng76) Benzo[k]fluoranthene 25.52 252 513410 51.71 ng77) Benzo[a]pyrene 26.21 252 432089 52.34 ng78) Indeno[l,2,3-cd]pyrene 29.05 276 358942 47.91 ng79) Dibenz[a,h]anthracene 29.03 278 273668 50.30 ng80) Benzo[g,h,i]perylene 29.85 276 261695 41.42 ng

99100999999991001009899

(#) = qualifier out of range (m) = manual integration2155S02.D 8270.M Thu Jun 04 10:48:02 1998 Page 3

Quantitation Report

Data File : J:\7002\DATA\2155S02.DAcq On : 4 Jun 1998 10:13 amSample : SSTD050Misc : 2ul of S-1029CMS Integration Params: LSCINT.PQuant Time: Jun 4 10:47 1998




J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 03 13:57:53 1998Continuing Cal File: J:\7002\DATA\2154S04.D

Abundance

1900000

1800000

1700000

1600000

1500000

1400000

1300000

1200000

1100000

1000000

H

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8?

1*

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900000 i

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700000 £

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500000

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2155S02.D 8270.M Thu Jun 04 10:48:06 1998 Page 4


J^Data File : J:\7002\DATA\2159S03.D Position: 1 '* Acq On : 8 Jun 1998 10:18 am Operator: ES

Sample : SSTD050 Inst : 7002Misc : 2ul of S-1029C Multiplr: 1.00MS Integration Params : LSCINT.P

Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Mon Jun 08 09:55:55 1998Response via Single Level Calibration


123456789

1011121314151617

181920212223242526272829303132

33343536373839

ISCSCSCSCMTCTCMTCTCMTCTTCTCTTCMTCTC

ISCTCTCCTCTTCTCTCTMCTTTCTMCT

ITCTCTSCTT

Compound

1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol-d52 -Chlorophenol -d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -DichlorobenzeneBenzyl Alcohol1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis (1 -Chloropropane4 -Methylphenoln-Nitroso-di-n-propylamineHexachloroe thane

Naphthalene-d8Nitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -DimethylphenolBenzoic Acidbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -Methylnaphthalene

Acenaphthene-dlOHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5 -Trichlorophenol2 -Fluorobiphenyl2 -Chloronaphthalene2 -Nitroanil ine

AvgRF

111i

013i~1X

112110

^Cc00c00vj

0ccQCC

1o^"•

_»Q

.000

.273

.667

.263

.754

.764

.420

.341

.450

.461

.048

.247

.063

.367

.229

.060

.565

.000

.332

.350

.747

.221

.323

.197

.918

.299

.328

. 949

.444

. 179

.306

.640

. 000

.122

.378

. 394

. 137

.082

.332

CCRF

11110131111112100

100000010000000

1000110

.000

.371

.816

.353

.791

.707

.524

.270

.510

.524

.042

.347

.112

.203

.203

. 974

.556

.000

.346

.363

.752

.207

.295

.122

.002

.270

.331

.979

.444

.172

.270

.631

.000

.066

.339

.367

. 195

. 127

.316

%Dev Area%

0-7-8-7-43

-35

-4-40

-8-46281

0-4-3-068

38-99

-0-303

111

045106

-5-44

.0

.7

.9

.1

.9

.2

.0

.3

. 1

.3

.6

.0

.6

.9

.1

.1

.6

.0

.2

.7

.7

.3

.7

.!#

.2

.7

.9

.2

.0

.9

.8

.4

.0

. 9#

.3

. 9

. 1

.2

.8

8890908986898887888781898882847982

778079757877528874787873757071

634 1#6263686658

Dev (min)

00000000000000000

000000000000000

0000000

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

. 00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

(tt) = Out of Range2159S03.D 8270.M Mon Jun 08 11:03:16 1998 Page 1


PF Data File : J:\7002\DATA\2159S03.DAcq On : 8 Jun 1998 10:18 amSample : SSTD050Misc : 2ul of S-1029CMS Integration Params : LSCINT.P

Method J:\7002\METHODS\8270.M (RTETitle GC/MS method 8270Last Update Mon Jun 08 09:55:

Position: 1Operator: ESInstMultipl

: 7002r: 1.00

Integrator)TCL extractables .55 1998

Response via Single Level Calibration

Min. RRF 0.000 Min. RelMax. RRF Dev 25% Max. Rel

Compound

40 T Dimethylphthalate41 CT Acenaphthylene42 CT 2, 6-Dinitrotoluene43 T 3 -Nitroaniline44 CMT Acenaphthene45 T 2,4-Dinitrophenol46 MT 4-Nitrophenol47 CT Dibenzofuran48 CMT 2 , 4-Dinitrotoluene49 T Diethylphthalate50 CT Fluorene51 CT 4 -Chlorophenyl -phenylether52 T 4-Nitroaniline

53 I Phenanthrene-dlO54 T 4 , 6-Dinitro-2-methylphenol55 T n-Nitrosodiphenylamine56 S 2 , 4 , 6-Tribromophenol57 CT 4 -Bromophenyl -phenylether58 CT Hexachlorobenzene59 CMT Pentachlorophenol60 CT Phenanthrene61 T Carbazole62 CT Anthracene63 T Di-n-butylphthalate64 CT Fluoranthene

65 I Chrysene-dl266 CMT Pyrene67 S Terphenyl-dl468 T Butylbenzylphthalate69 CT Benzo [a] anthracene70 T 3, 3 ' -Dichlorobenzidine71 CT Chrysene72 T bis (2-Ethylhexyl)phthalate

73 I Perylene-dl274 T Di-n-octylphthalate75 CT Benzo [b] f luoranthene76 CT Benzo [k] f luoranthene77 CT Benzo [a] pyrene

. Area : 50% Max.R.T. Dev 0.SOmin

. Area : 150%

AvgRF

1.2471.6500.3180.3591.0300. 1570.0721 . 5030.4251 .2011.1720 .6700.358

1.0000.1360 .4840. 1770.26C0 .3430. 1340. 9340 . 9010. 9631 . 1361 . 016

1.0001 . 1391 .0000.4660. 9210. 3380.8610 . 586

1 .0001 .4181 .3181 .2721 . 100

CCRF

1.1361.6700.3000.3201.0370.0770.0401 .5110.3731 . 0041. 1270.6020.269

1.0000.0930.4850. 1770 .2500.3530 .0750 . 9500.3540 . 9690 . 9470. 954

1.0001. 1501 .0000 .3370 . 9310 .3050 .8900.433

i . oc:1 . IZ61.2351 .3251 . 121

%Dev Area%

8. 9-1.25.710. 9-0.751. on44 4 H" ~ • ~ TT

-0.512.216.43 .810. 124 . 9

0.027. 9#-0.20.03 .8

-2 . 944 .0#-1.75.2

-0.616.66.1

0.0-1.00.017.0-1. 19.8

-3.418. 1

0 . 022 . 02.3

-4.2-1.9

606357536334#39#625154595844#

5440#5652555534#5448#5447#50

53505145#5244#5347#

5346#515755

Dev (min)

0.000.000.000.000.000.000.000.000.000.000.000.000.00

0.000.000.000.000. 000. 000. 000.000.000.000.000.00

0.000.000.000.000.000. 000.000 . 00

0 .000 . 000.000.000.00

(#) = Out of Range2159S03.D 8270.M Mon Jun 08 11:03:21 1998 Page 2





MS Integration Params: LSCINT.P



Compound

J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Mon Jun 08 09:55:55 1998Single Level Calibration

1ES7002

Multiplr: 1.00

0.00025%

Min. Rel. Area : 50%Max. Rel. Area : 150%


AvgRF CCRF %Dev Area% Dev(min)

78 CT Indeno[1,2,3-cd]pyrene79 CT Dibenz [a,h]anthracene80 CT Benzo[g,h,i]perylene

0.8440.6320.720

0.9150.6720.676

-8.4 58 0.00-6.3 57 0.006.1 53 0.00

(tf) = Out of Range2159S03.D 8270.M

SPCC's out = 0 CCC1Mon Jun 08 11:03:22 1998

s out = 1Page 3


J: \7002\DATA\2159S03 .D8 Jun 1998 10:18 amSSTD0502ul of S-1029C




1ES70021.00



J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Mon Jun 08 09:55:55 1998Continuing Cal File: J:\7002\DATA\2159S03.D8270



System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2 -Dichlorobenzene-d4Spiked Amount 100.00019) Nitrobenzene-d5Spiked Amount 100.00037) 2-FluorobiphenylSpiked Amount 100.000



10) 1 , 4 -Dichlorobenzene11) Benzyl Alcohol12) 1 , 2 -Dichlorobenzene13) 2-Methylphenol

81013162226

7Range

7Range

8Range

8Range

9Range

11Range

15Range

20Range

.43

.17

.35

.59

.99

.33

.0221.9610.2133.6816.1735.9643

. 0510.3533

152136164188240264

112- 110

99- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

185624652748345766548613456240266677

318196Recovery

421448Recovery

313880Recovery

183616Recovery

282521Recovery

516322Recovery

121501Recovery

570205Recovery

404040404040

50

50

50

50

50

50

50

50

.00

.00

.00

.00

.00

.00

.00=.00=.00=.00=.00=.00=.00=.00=

ngngngngngng

ng33

ng33

ng33

ng50

ng50

ng50

ng33

ng50

.33%

.33%

.33%

.00%

.00%

.00%

.33%

.00%

000000

0

0

0

0

0

0

0

0

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

Qvalue

14) 2 , 2 ' -oxybis (1-Chloropropan15) 4 -Methylphenol16) n-Nitroso-di -n-propylamine17) Hexachloroethane20) Nitrobenzene21) Isophorone22) 2-Nitrophenol

788888888889999

. 98

.09

.23

.40

.46

.58

.70

.69

.74

.86

. 93

.10

.19

.49

.64

9493

1281461467914610845108701177782

139

396068817720294593350379353544241860312535258092511138279045225917128927296450613750168897

505050505050505050505050505050

.00

.00

.00

.00

. 00

. 00

.00

. 00

.00

. 00

. 00

.00

. 00

.00

.00


#

#

#

#

784685979988999688967096849665

(#) = qualifier out of range (m) = manual integration2159S03.D 8270.M Mon Jun 08 13:13:18 1998 Page 1








23)24)25)26)27)28)29)30)31)32)34)35)36)38)39)40)41)42)43)44)45)46)47)48)49)50)51)52)54)55)57)58)59)60)61)62)63)64)66)68)69)

2 , 4 -DimethylphenolBenzoic Acidbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2-NitroanilineDime thylphthal ateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2,4-DinitrotolueneDie thylphthal ateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4 , 6-Dinitro-2-methylphenoln-Nitrosodiphenylamine4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi-n-butylphthalateFluoranthenePyreneButyl benzyl pht ha lateBenzo [a] anthracene

9989

10101010101111111112121213121313131313131414141414141515161617161719202122

.58

.70

.09

.96

.09

.21

.28

.42

. 97

.32

.69

.84

.93

.21

.44

.75

.05

. 94

.25

.41

.49

.52

.74

.76

.19

.47

.39

.58

.66

.66

.48

.89

.29

.64

. 11

.75

.89

.49

.05

.52

.94

10710593

16218012812722510714223719619616265163152165138153184109168165149166204138198169248284266178167178149202202149228

24053499773817720219923270041798703362237140399220149514745284541466791586024870661364424911937218891294711381474481223310517293

65285716112843385448712026020211644066957

33261317135124223851129651407585623664763649098654026655888220950531032

5050505050505050505050505050505050505050505050505050505050505050505050505050505050

.00

.00

.00

.00

.00

.00

.00

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.00

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.00

ngng #ngngngngngngngngngngngngng #ngngngng #ngngng ftngngngngngng #ngngngngngngngngngngngngng

8685679799961009992989997979569999988779989889284981008964819493999898989898999990

100


Quantisation Report (Not Reviewed)




1ES70021.00

MS Integration Params: LSCINT.PQuant Time: Jun 8 13:13 1998 Quant Results File: 8270.RES




70) 3,3'-Dichlorobenzidine 22.87 252 173946 50.00 ng71) Chrysene 23.05 228 507613 50.00 ng72) bis(2-Ethylhexyl)phthalate 22.89 149 274012 50.00 ng74) Di-n-octylphthalate 24.30 149 368763 50.00 ng75) Benzo[b]fluoranthene 25.45 252 429371 50.00 ng76) Benzotk]fluoranthene 25.51 252 441602 50.00 ng77) Benzo[a]pyrene . 26.20 252 373829 50.00 ng78) Indeno[l,2,3-cd]pyrene 29.03 276 305087 50.00 ng79) Dibenz[a,hjanthracene 29.02 278 223935 50.00 ng80) Benzo[g,h,ijperylene 29.83 276 225447 50.00 ng

989998989998991009798


Quantitation Report





J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Mon Jun 08 09:55:55 1998Continuing Cal File: J:\7002\DATA\2159S03.D

TlCf2159S03.DAbundance1900000

1800000

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1600000

1500000

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2159S03.D 8270.M Mon Jun 08 13:13:25 1998

2 2 ( O 23.00 \ 2soO 26'do \27.00 28.00 29!do 3o!oO 3l!do 32.00 33.00

Page 4

9709277, Quantitation Report (Not Reviewed)

Data File : J:\7002\DATA\2350E09.DAcq On : 16 Dec 1997 3:12 pmSample : GSS3816Misc : 2ul of 500ul-t-5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 16 15:49 1997


2ES70021 .00




Internal Standards R.T. Qlon Response Cone Units Dev(Min]

1)17)31)51)63)71)

1 , 4 -Dichlorobenzene-d4Naphthalene-dSAcenaphthene-dlOPhenanthrene-dlOChrysene-dl2Perylene-dl2

81013162326

.69

.45

.67

.94

.36

.74

152136164188240264

94556369847205383376578327502296943

404040404040

.00

.00

.00

.00

.00

.00

ngngngngngng

0000.00

.01

.00

. 00

.00

.00

. 00

System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1,2-Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000

35) 2-FluorobiphenylSpiked Amount 100.00054) 2,4,6-TribromophenolSpiked Amount 150.00065) Terphenyl-dl4Spiked Amount 100.000

7Range

8Range

8Range

8Range

9Range

12Range

15Range

20Range

.2721.2010.4633.9416.4335.2543.3910.7133

112- 11099

- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

315696 100.26 ng 0.04Recovery = 66.84%

392054 104.91 ng 0.02Recovery = 69.94%

279547 94.71 ng 0.02Recovery = 63.14%

152002 84.07 ng 0.01Recovery = 84.07%

289450 78.79 ng C.01Recovery = 78.79%

418759 70.80ng 0.30Recovery = 70.80%

180578 96.69 ng 0.00Recovery = 64.46%

540480 89.43 ng O.CORecovery = 89.43%

Target Compounds6)8)9)

10)12)13)15)19)24)25)29)42)44)46)47)

Phenol2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chloropropann-Nitroso-di -n-propylamineNitrobenzene2 , 4 -Dichlorophenol1,2,4 -Trichlorobenzene4 -Chloro- 3 -methylphenolAcenaphthene4 -Nitrophenol2,4-DinitrotolueneDiethylphthalate

8888889910101113131414

.22

.48

.71

.71

.94

.98

. 18

.42

.24

.37

.25

.74

.83

.08

.52

94128146146108457077162180107153109165149

378340263931224341224341

7131677

222644411729

20728929343537338990350183736

1028

8276Si61009600

628966144790

.19

.31_S4..35.26.22.47.10.23.68.00.42.99.97. 15

Qyalueng i >' Ti-ng i~' cngng t (t'cng #ng #ng si/'ong #ng #ng c-i -'~ng ^ i ong L 'Ong -,T 'bng f>Wng #

9998

130984

3393372413013097953258

(#) = qualifier2350E09.D 8270

out of range (m) = manual integrationM Tue Dec 16 16:06:23 1997 Page 1

Quantitation Report

J:\7002\DATA\2350E09.D16 Dec 1997 3:12 pmGSS38162ul of 500ul+5ul IS,V=1000



(Not Reviewed)






57)61)64)70)72)

PentachlorophenolDi-n-butylphthalatePyrenebis (2-Ethylhexyl) phthalateDi-n-octylphthalate

1618202324

.62

.23

.42

.24

.65

266149202149149

2069743018

78744244852745

940

9100

.28

.27

.06

.89

.35

ngngngngng

C--

#O^o##

9978997375

(#) = qualifier2350E09.D 8270

out of range (m) = manual integrationM Tue Dec 16 16:06:25 1997 Page 2

Quantitation Report

Data File : J:\7002\DATA\2350E09.DAcq On : 16 Dec 1997 3:12 pmSample : GSS3816Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 16 15:49 1997

Position:Operator:Inst :Multiplr;

2ES70021.00



Abundance


TIC: 2350E09.D ~2000000

1900000

1800000

1700000

1600000

1500000

1400000

1300000

1200000

1100000

1000000

900000

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2350E09.D 8270.M Tue Dec 16 16:06:31 1997 Page 3

5/> ; A < Quantitation Report

Data File : J:\7002\DATA\2354E04.DAcq On : 20 Dec 1997 9:46 amSample : GWS3828Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params : LSCINT.PQuant Time: Dec 20 10:23 1997

(Not Reviewed)




J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2354S028270


1)17)31)51)63)71)

1 , 4 -Dichlorobenzene-d4Naphthalene-dSAcenaphthenePhenanthreneChrysene-dl2Perylene-dl2

-dlO-dlO

81013162326

.66

.42

.63

. 90

.33

. 71

152136164188240264

121629446431255233472603440499319289

404040404040

.00

.00

.00

. 00

.00

.00

ngngngngngng

00.0,0 .0 ,0 ,

.CO

. CO

. CO

. CO

. CO

.CD

System Monitorir.g Compounds2) 2-FluorophenolSpiked Amount 150.0003') Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1,2-Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000

35) 2-FluorobiphenylSpiked Amount 100.00054) 2,4,6-TribromophenolSpiked Amount 150.000


7Range

8Range

8Range

8Range

9Range

12Range

15Range

20Range

.2521. 1710.4333.9016.3935.2243.3510.6733

112- 11:

99- 11C132

- 11C152

- 11:82

- 110172

- 115330

- 123244

- 144

378564 91 .39 ng 0 . Z=>Recovery = 60.93%

437192 91.33 ng O.C2Recovery = 60.89%

339217 87.69 ng 0.02Recovery = 58.46%

190048 85.20 ng O.CORecovery = 85.20%

306274 72.06 r.g 0.33Recovery = 72.06%

525357 71.51 ng 0 . : :Recovery = 71.51%

213022 96 . 90 ng 0.:0Recovery = 64.60%

745795 89. 67 ng 0.TORecovery = 89-67%


10)12)13)15)19)25)26)29)42)44)46)47)

Phenol2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chloropropann-Nitroso-di -n-propylamineNitrobenzene1,2,4 -TrichlorobenzeneNaphthalene4 -Chloro- 3 -T.e thy 1 phenolAcenaphthene4 -Nitropher.ol2,4-DinitrctolueneD i e t hy 1 pht ha 1 a t e

88888899

10101113131414

.19

.45

.68

.68

. 90

.84

. 15

. 39

. 33

.45

.21

. 71

.79

. 05

.48

94128146146108457077

180128107153109165149

4322

2

2

34

2

i238

2

5

353C

0723193119391939102238527705325

591911203937?733597970701641

7072

.99

.245-9TTT5900

790

650

8563107710

. 94

. 31

.46

. 10

. 18

.73

. 10

.23

. 93

. 94

. 69

.20


Qvalue•i -/ "'c 96^- ' e 91

99dC^'a 9 3

# 4# 1

-j '/o £5#~ 37

L C " '® 59# "1

•i 1 uc 954M'"'c 93

#-i'-J? 35tf 1 -''c ~ Jif ^3

(#) = qualifier out of range (m) = manual integration2354E04.D 8270.M Sat Dec 20 12:41:44 1997 Page 1

Quantitation Report


J:\7002\DATA\2354E04.D20 Dec 1997 9:46 amGWS38282ul of 500ul+5ul IS,V=1000


(Not Reviewed)






57)61)64)70)72)

PentachlorophenolDi -n-butylphthalatePyrenebis (2-Ethylhexyl) phthalateDi -n-octylphthalate

1618202324

.58

. 19

.38

.20

.62

266149202149149

2343443290

89337530742350

880

7500

.73

.24

.84

.48

.24

ng sv°bng |ng i'c 'ong #ng #

9978947475

(#) = qualifier out2354E04.D 8270.M

of range (m) = manual integrationSat Dec 20 12:41:46 1997 Page 2

Quantitation Report

Data File : J:\7002\DATA\2354E04.DAcq On : 20 Dec 1997 9:46 amSample : GWS3828Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 20 10:23 1997




J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2354S02.D

Abundance

1700000

1600000

1500000

1400000

1300000

1200000

1100000

1000000

900000

800000

700000

600000

500000

400000

300000

200000

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22.00 2400 30^00 32oO 3400

Page 3

Sf<Quantitation Report

Data File : J:\7002\DATA\2363E05.DAcq On : 29 Dec 1997 12:24 pmSample : GSS3840Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params : LSCINT.PQuant Time: Dec 29 13:01 1997

(Not Reviewed)






1)17)31)51)63)71)

1 , 4 -Dichlorobenzene-d4Naphthalene-dSAcenaphthene-dlOPhenanthrene-dlOChrysene-dl2Perylene-dl2

81013162326

.70

.46

.69

. 96

. 38

. 77

152136164188240264

108094407621222524371015303834195673

40.40.40.40.40.40.

000000000000

ngngngngngng

000000

.00

. 00

.00

.00

.00

. 00


35) 2-FluorobiphenylSpiked Amount 100.00054) 2,4,6-TribromophenolSpiked Amount 150.00065) Terphenyl-dl4Spiked Amount 100.000

7Range

8Range

8Range

8Range

9Range

12Range

15Range

20Range

.2821.2110.4733. 9416.4335.2643.4110

. 7233

112- 110

99- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

304650 84.53 ng 0.03Recovery = 56.35%

376571 86.42 ng. 0.02Recovery = 57.61%

289618 83.94 ng 0.00Recovery = 55.96%

153662 75.48 ng 0.00Recovery = 75.48%

251937 63.66 ng 0.00Recovery = 63.66%

433709 67.03 ng -0.01Recovery = 67.03%

136573 84.05 ng 0.00Recovery = 56.03%

490950 84.82 ng 0.00Recovery = 84.82%


10)12)15)24)25)29)42)44)46)47)57)61)

Phenol2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene2 -Methylphenoln-Nitroso-di -n-propylamine2 , 4 -Dichlorophenol1,2,4 -Trichlorobenzene4 -Chloro-3 -methyl phenolAcenaphthene4 -N'itrophenol2 , 4 -DinitrotolueneDiet hylpht ha latePentachlorophenolDi -n-butylphthalate

888889

101011131314141618

.23

.49

.72

. 72

. 94

. 19

.26

. 37

. 26

.75

.85

. 1C

. 53

.64

.23

9412814614610870162180107153109165149266149

356591274490226670226670

689182008

38120349627438836769654838

1531561300

1389353249

68685-3-540

690

58765792610

880

.33

. 52

.27

.23

.48

. 11

.75

.36

.78

.22

.27

. 18

.20

.29

Qvalueng J/C"Qng -.(**' a•ngng s HC/Cng #ng u-^vong *ng ^^'ong s • ~ng v-'-bng •,,"'j_ng -#»(*ng «ng -, -.-'-ng #

949299

1004

8624100959791

,"c 73539878

(#) = qualifier out of range (m) = manual integration2363E05.D 8270.M Mon Dec 29 13:01:17 1997 Page 1

Quantisation Report


(Not Reviewed)






64) Pyrene 20.43 202 592022 69.66 ng ?i/'° 9770) bis(2-Ethylhexyl)phthalate 23.25 149 1220 0.26 ng # 45

(#) = qualifier out of range (m) = manual integration2363E05.D 8270.M Mon Dec 29 13:01:18 1997 Paae 2

Quantisation Report


PositionOperatorInstMultiplr

2ES70021.00

Quant Results File: 8270. RES


Abundance


TIC: 2363E05.D

1400000

1300000

1200000

1100000

1000000

900000

800000

700000

600000

500000

400000I

300000 |\

200000

100000 j1w

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JI1,"

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2 3 6 3 E 0 5 . D 8 2 7 0 . M

12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00

Mon Dec 29 13 :01 :24 1997

3400Page 3

Quantitation Report

J:\7002\DATA\2058E10.D27 Feb 1998 4:57 pmGSS48432ul of 500ul+5ul IS,V=1000

MS Integration Params : LSCINT.PQuant Time: Feb 27 17:33 1998


(Not Reviewed)






1)17)31)51)63)71)


-dlO-dlO

81013162326

.69

.46

.68

.95

.39

.79

152136164188240264

317579943139447297707201590223404602

404040404040

.00

.00

.00

.00

.00

.00

ngngngngngng

00

-0000

.00

.00

.01

.00

.01

.01

System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0002} Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1,2-Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000

35) 2-FluorobiphenylSpiked Amount 100.00054) 2,4,6-TribromophenolSpiked Amount 150.000


7Range

8Range

8Range

8Range

9Range

12Range

15Range

20Range

.2821.2010.4633.9316.4335.2743.4010.7033

112- 11099

- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

862926 78.71 ng 0.03Recovery = 52.47%

925181 84.39 ng 0.00Recovery = 56.26%

785526 81.39 ng 0.00Recovery = 54.26%

370099 60.34 ng 0.00Recovery = 60.34%

512865 61.31 ng 0.00Recovery = 61.31%

913903 62.76 ng 0.00Recovery = 62.76%

351005 118.81 ng -0.01Recovery = 79.21%

1764247 145.64 ng -0.01Recovery = 145.64%#


10)12)13)15)19)25)26)29)42)44)46)47)

Phenol2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chloropropann-Nitroso-di -n-propylamineNitrobenzene1,2,4 -TrichlorobenzeneNaphthalene4 -Chloro- 3 -methyl phenolAcenaphthene4 -Nitrophenol2, 4 -Dinitro tolueneDiethylphthalate

88.21.48

•8-rTl88999

10101113131414

.71

.93

.01

. 18

.43

. 37

.49

.26

.74

.86

.10

.52

94128146146108457077180128107153109165149

921226766014^fi77 f) p56770223942295

3421541474

4906429847

57903374806270706

2662471406

70684S-4600

750

520

836177630

.25

. 18^r&f

.85

.30

.23

.19

. 17

. 92

.43

.70

.78

.47

.79

. 11

Qvalueng -J •> *»ng rivo'ngng tj-r^cng #ng #ng.',-<3#ng #ng * v'ong tfng * u, 'ong -!.-'Gng i'V 'o#ngo^b#ng #

958799

1004

38783899779497657158


of range (m) = manual integrationFri Feb 27 17:33:47 1998 Page 1


Data File : J:\7002\DATA\2058E10.DAcq On : 27 Feb 1998 4:57 pmSample : GSS4843Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Feb 27 17:33 1998


3ES70021 .00





57) Pentachlorophenol61) Di-n-butylphthalate64) Pyrene

161820

632342

266149202

70) bis(2-Ethylhexyl)phthalate 23.25 149

2553554616

1496948907

1470.

90

292653

ngngng

0.14 ng

96788445

(tf) = qualifier out of range (m) = manual integration2058E10.D 8270.M Fri Feb 27 17:33:48 1993 Paae 2

Quantitation Report

Data File : J:\7002\DATA\2058E10.DAcq On : 27 Feb 1998 4:57 pmSample : GSS4843Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Feb 27 17:33 1998




fTlme->


TIC: 2058E10.DAbundance6000000

5500000

5000000

4500000

4000000

3500000

3000000

2500000

2000000

1500000 |

1000000 ;I

500000

n

v) 5 aQ P

I 1li » "

«• - ! ;- I: l i f f ! I s

!l * I -: 12 « N ]

I; Iu

8.00 10.00

2058E10.D 8270.M

16.00 18.00 20.0012.00 14.00

Fri Feb 27 17:33:50 1998

2200 24.00 26.00 28.00 30.00 32.00

Page 3



J:\7002\DATA\2155E06.D4 Jun 1998 4:21 pm

GWS45132ul of 250ul+250ul+5ul IS,V=1000


PositionOperatorInstMultiplr:

2ES70021.00



J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Thu Jun 04 10:48:37 1998Continuing Cal File: J:\7002\DATA\2155S02.D8270


1)18)33)53)65)73)


-dlO-dlO

81013162326

.45

.20

.37

.61

.01

.35

152136164188240264

171311775871484288861267729455443471

404040404040

.00

.00

.00

.00

.00

.00

ngngngngngng

000000

.00

.00

.00

.00

.00

.00




Target Compounds6) Phenol8) 2-Chlorophenol

10) 1 , 4 -Dichlorobenzene11) Benzyl Alcohol

7Range

7Range

8Range

8Range

9Range

11Range

15Range

20Range

7888

16) r.-Nitroso-di-n-propylamine 827) 1 , 2 , 4 -Trichlorobenzene31) 4 -Chloro-3-methylphenol44) Acenaphthene46) 4 -Xitrophenol48) 2 , 4 -Dinitrotoluene49) Dierhylphthalate59) Per.rachlorophenol63) Di-n-butylphthalate66) Pyrene

(#) = qualifier out of range

101013131314161720

(m) =2155E06.D 8270. M Fri Jun 05 1

.0321.9810.2333.7116.2035.9743.0710.3633

. 99

.24

.48

.70

.96

.12

.99

.43

.54

.78

.21

.30

.91

.07

112- 11099

- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

941281467970180107153109165149266149202

159958Recovery

179864Recovery

261672Recovery

112190Recovery

201613Recovery

548672Recovery

229155Recovery

1060645Recovery

1972842678101739892386

21151118158335943951033816812m

2256642494

1462843940

979193

27

23

45

32

30

38

57

55

2648260

4529644029450

730

44

.15=.46=.70=.42=.53=.83=. 57=.44=

.89

. 82

. 56

. 52

. 94

.24

.45

.03

.01

.55

.19

. 04

. 18

. 77

ng18

ng15

ng30

ng32

ng30

ng38

ng38

ng55

ng \ng -3ng :ngng '-\ng ng c.ng <-ng \ng Mngng <-ngng n

0.00.10%#

0.00.64%

0.00. 47%#

0 .02.42%

0 .02. 53%#

0.00.83%#

0.00.38%

0.00.44%

Qvalue3 78>3 85-j 98# 15

fc # 71<» 99A 94ic 98c\c # 67# 58

1-'t 98# 78

,4 100

manual integration1 :32:51 1998 Page 1

Quantisation Report

Data File : J:\7002\DATA\2155E06.DAcq On : 4 Jun 1998 4:21 proSample : GWS4513Misc : 2ul of 250ul -t 250ul + 5ul IS,V=1000MS Integration Params: LSCINT.P


Quant Time: Jun 5 11:32 1998 Quant Results File: 8270.RES


Abundance1300000

1200000

1100000

1000000

900000

800000

700000

600000

500000

400000

300000

200000

100000

0nma->

i'4

ir

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H

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* I** 5

9.0(

J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Thu Jun 04 10:48:37 1998Continuing Cal File: J:\7002\DATA\2155S02.D

TIC: 2155E06.D

2VOO 22 26!o(i 27!()0 3o!oO 3lT6o 32!(>0 33

2155E06.D 8 2 7 0 . M Fri Jun 05 11:32:54 1998 Page 2


Quantitation Report

J:\7002\DATA\2161E06.D10 Jun 1998 12:57 pmGWS4 5 15, Montgomery Watson2ul of 250ul+250ul+5ul IS,V=1000


(Not Reviewed)






1)18)33)53)65)73)

1 , 4 -Dichlorobenzene-d4Naphthalene -d8Acenaphthene-dlOPhenanthrene-dlOChrysene-dl2Perylene-dl2

81013162326

.44

.19

.36

.60

.00

.34

152136164188240264

3589741255058582247980942581963373389

404040404040

.00

.00

.00

.00

.00

.00

ngngngngngng

000000

.00

.00

.01

.00

.01

.02


37) 2-FluorobiphenylSpiked Amount 100.00056) 2,4,6-TribromophenolSpiked Amount 150.00067) Terphenyl-dl4Spiked Amount 100.000.

7Range

7Range

8Range

8Range

9Range

11Range

15Range

20Range

.0321.9710.2233.6916. 1835.9643.0610.3633

112- 11099

- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

455722 34.62 ng 0.00Recovery = 23.08%

456409 27.30 ng 0.00Recovery = 18.20%

634274 53.25 ng 0.00Recovery = 35.50%

285948 42.15 ng 0.00Recovery = 42.15%

462976 40.94 ng 0.00Recovery = 40.94%

842734 46.32 ng 0.00Recovery = 46.32%

318592 62.00 ng 0.00Recovery = 41.33%

1275263 91.50 ng 0.00Recovery = 91.50%


10)11)13)16)27)31)44)46)48)49)59)63)

Phenol2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -DichlorobenzeneBenzyl Alcohol2 -Methylphenoln-Nitroso-di-n-propylamine1,2,4 -Trichlorobenzene4 -Chloro-3 -methyl phenolAcenaphthene4 -Nitrophenol2 , 4 -DinitrotolueneDiethylphthalatePentachlorophenolDi -n-butylphthalate

111111

78888880033341617

. 99

.24

.47

.47

.69

.69

. 94

. 11

. 98

.43

. 54

.73

.22

.29

. 91

941281461467910870180107153109165149266149

509683636119448698448698

67501325

444790382483579679731859257833292282824

2269887101

3156

.93

.60ngng

Qvaluelf'/~*)%'/•

-3-3-T64 ng3300

4735644831540

800

.33

.67

.15

.24

. 91

.30

. 17

. 15

.26

. 18

.74

.29

ngngngngngngngngngngngng

}}y-ftft/?/£#}C/oI?'/*w %21 '/-fV/uft

ftr /*-ft

79889998264719893989070589978

(ft) = qualifier out of range (m) = manual integration2161E06.D 8270.M Wed Jun 10 13:33:10 1998 Page 1

Quantitat ion Report

Data File : J:\7002\DATA\2161E06.DAcq On : 10 Jun 1998 12:57 pmSample : GWS4515,Montgomery WatsonMisc : 2ul of 250ul+250ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Jun 10 13:31 1998

(Not Reviewed)






66) Pyrene 20.06 202 1265001 78.96 ng7 9i 9772) bis(2-Ethylhexyl)phthalate 22.91 149 1121 0.14 ng # 4574) Di-n-octylphthalate 24.32 149 1436 0.14 ng # 75

(#) = qualifier out of range (m) = manual integration2161E06.D 8270.M Wed Jun 10 13:33:11 1998 Page 2

Quantitation Report

Data File : J:\7002\DATA\2161E06.DAcq On : 10 Jun 1998 12:57 pmSample : GWS4515,Montgomery WatsonMisc : 2ul of 250ul+250ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Jun 10 13:31 1998


1ES70021.00



Abundance

J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 10 11:09:16 1998Continuing Cal File: J:\7002\DATA\2161S03.D

TTCT7161E06.D —& 1 WWW

2000000

1900000

1800000

1700000

1600000

1500000

1400000

1300000

1200000

1100000

1000000

900000

800000

700000

600000

500000

400000

300000

200000

100000

0

b1

1J"if*

-,'

.

1

.

a?i1f

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l2

-.''-.

-

£§I

|

:-^I1*r

I

1I

J „

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!ii2

I

i

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•

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i«1

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7.00 8.00 9.00 10.00 1l!oO 12!oO 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 2l!oO 2 !oV^23!doT4Tdo 25!ooT6!oO 27!(X) 28!oO 29.'oo 3o!oO 31.'do

Wed Jun 10 13:33:14 1998

• ' I ' '•'•T'-r'-rT32.00 33.00

2161E06.D 8270.M Page 3

9 7092.7? Quantitation Report

Data File : J:\7002\DATA\2350E08.DAcq On : 16 Dec 1997 2:26 pmSample : GSB3816AMisc : 2ul Of 500ul+5ul IS,V=1000MS Integration Params : LSCINT.PQuant Time: Dec 16 15:03 1997

(QT Reviewed)





Internal Standards R.T. Qlon Response Cone Units Dev(Min]


System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2 -Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.00035) 2 -FluorobiphenylSpiked Amount 100.000


Target Compounds6) Phenol12) 2-Methylphenol

81013162326

7Range

8Range

8Range

8Range

9Range

12Range

15Range

20Range

.69

.47

.69

. 96

. 37

.75

.2721.2010.4633. 9416.4335.2743.4110.7133

152136164188240264

112- 11099

- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

85541304128158179337538349591313667

261062

404040404040

91

.00

.00

.00

.00

.00

.00

.64Recovery

365167 108 .01Recovery =

252455 94 .55Recovery

118418 72 .40Recovery =

232831 77 .07Recovery

309429 67 .93Recovery =

163509 97 .68Recovery =

527463 81 .76Recovery =

ngngngngngng

ng61

ng72

ng63

ng72

ng77

ng67

ng65

ng81

.09%

.01%

.03%

.40%

. 07%

.93%

.12%

.76%

000000

0

0

0

0

0

0

0

0

.01

.01

.01

.01

.00

.00

.04

.02

. 02

.01

. 02

. 01

.01

.00

Qvalue88

13) 2 , 2 ' -oxybis ( 1-Chloropropan 815) n-Nitroso-di -n-propylamine 947) Diethylphthalate61) Di-n-butylphthalate

1418

70) bis (2-Ethylhexyl)phthalate 23

.22

. 94

. 97

. 21

.53

.24

.25

941084570149149149

914588

1190928643

16262354

0000000

.22

.24

.17

.44

.12

. 16

.44

ngngngngngngng

tt»#tt««»

3543810587865


of range (m) = manual integrationTue Dec 16 15:23:06 1997 Page 1

Quantitation Report

Data File : J:\7002\DATA\2350E08.DAcq On : 16 Dec 1997 2:26 pmSample : GSB3816AMisc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 16 15:03 1997

Position;Operator:Inst :Multiplr:

1ES70021.00




TIC: 2350E08.DAbundance1900000

1800000

1700000

1600000

1500000

1400000

1300000

1200000

1100000

1000000

900000 ;800000

700000

600000 •

500000

400000

300000

200000l

100000 liII«w'l

«1 <"? m

i oj • .. "1'

\f c j 1 * J 5 t I* 1 i t ' i5 « i |

i, !l 'Tlme-> 8.00 1000 12.00 14.00 16.00 18.00 20.00 22.00 24.00

I

f

26.00 28.00

2 3 5 0 E 0 8 . D 8 2 7 0 . M Tue Dec 16 15 :23 :14 1997

30!00 32.00 34.00 j

Page 2


Data File • J:\7002\DATA\2354E03.DAcq On : 20 Dec 1997 9:01 amSample : GWB3828AMisc : 2ul Of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 20 12:57 1997




J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2354S028270

D







Target Compounds6) Phenol12) 2-Methylphenol19) Nitrobenzene61) Di-n-butylphthalate64) Pyrene

81013162326

7Range

8Range

8Range

8Range

9Range

12Range

15Range

20Range

.66

.43

.65

.92

.33

.71

.2521.1710.4333.9116.4035.2443.3710.6833

152136164188240264

112- 11099

- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

128075417290220373401555435986321442

420014

404040404040

96

.00

.00

.00

.00

.00

.00

.29Recovery

527661 104 .68Recovery =

411877 101 .11Recovery

195160 83 .09Recovery

309756 77 .97Recovery

502125 78 .94Recovery

201513 105 .41Recovery

775888 94 .25Recovery

ngngngngngng

ng64

ng-69

ng67

ng83

ng77

ng78

ng70

ng94

.19%

.79%

.41%

.09%

.97%

. 94%

.27%

.25%

000000

0

0

0

0

0

0

0

0

.01

.00

.01

.00

.00

.00

.05

.02

.02

.01

.01

.01

.00

.00

Qvalue

70) bis (2-Ethylhexyl) phthalate72) Di-n-octylphthalate

889

18202324

.19

.91

.40

.20

.67

.21

.62

9410877149202149149

67510114633453137274964414

0000010

. 11

.30

. 11

.30

. 12

.18

.45

ngngngngngngng

#$tttttt##

35437781

8875

(#) = qualifier out2354EO3.D 8270. M

range (m) = manual integrationSat Dec 20 12 -.58 :01 1997 Page 1

Quantltation Report

Data File : J:\7002\DATA\2354E03.DAcq On : 20 Dec 1997 9:01 amSample : GWB3828AMisc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 20 12:57 1997


1ES70021.00



Abundance


TIC: 2354E03.D2100000

2000000

1900000

1800000

1700000

1600000

1500000

1400000

1300000

1200000

1100000

1000000

900000

800000

700000

600000

500000

400000

300000

200000

100000T

0

">1 aT)1 ? ".§ •"'! i£ |S £ </i

|V-| ]

jis i§n - ^.0™ c - uO*- • A

* S Si I 1•» I -*" a

5

i '' I I I ' |

11 •' -. ..'. • .-!..,--.-,'. _. _-

,

oV«e

c«

<

, — _-.

a.

iTime-> 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00

2354E03.D 8270.M Sat Dec 20 12:58:06 1997 Page 2

Quantitation Report

J:\7002\DATA\2363E04.D29 Dec 1997 11:39 amGSB3840A2ul of 500ul+5ul IS,V=1000



(Not Reviewed)







System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2 -Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000

35) 2 -FluorobiphenylSpiked Amount 100.000



Target Compounds6) Phenol12) 2-Methylphenol26) Naphthalene47) Diethylphthalate61) Di-n-butylphthalate

81013162326

7Range

8Range

8Range

8Range

9Range

12Range

15Range

20Range

.70

.47

.71

.98

.39

.77

.2921.2210.4833.9516.4435.2843.4310.7333

152136164188240264

112- 110

99- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

122140406920218167383823332733216344

375163

404040404040

92

.00

.00

.00

.00

.00

.00

. 12Recovery =

502798 102 . 12Recovery

377079 96 .72Recovery

180713 78 .56Recovery =

300476 76 .06Recovery =

497096 78 .36Recovery =

154410 91 .85Recovery

361117 56 .97Recovery =

ngngngngngng

ng61

ng68

ng64

ng78

ng76

ng78

ng61

ng56

.41%

.08%

.48%

. 56%

. 06%

. 36%

.23%

.97%

000000

0

0

0

0

0

0

0

0

.00

.00

.01

.01

. 00

.00

. 03

. 02

. 02

.00

.CO

. 00

.01

. 00

Qvalue88

101418

70) bis (2 -Ethylhexyl) phthalate 2372) Di-n-octylphthalate 24

.24

.95

.51

.54

.25

.26

.68

94108128149149149149

1559951

17122364652429481118

0000000

.26

.28

. 17

.34

.57

.57

. 14

ngngngngngngng

#######

354

7153786375

(#) = qualifier out of range (m) = manual integration2363E04.D 8270.M Mon Dec 29 12:16:01 1997 Page 1

Quantitation Report

Data File : J:\7002\DATA\2363E04.DAcq On : 29 Dec 1997 11:39 amSample : GSB3840AMisc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 29 12:15 1997




J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997

Response via : Continuing Cal File: J:\7002\DATA\2363S03.DAbundance TIC: 2363E04.D

1700000 :

1600000

1500000

1400000 '

1300000

1200000

1100000

1000000

900000

800000

700000

600000

500000

400000 •: ,

300000(

200000I

100000 | I

n

|

|oiT

VI

J urf> C ^*

.1 £ "

* & * — "fll I?l 1•5 w s£9 £ 2 «5" ' *r ~ - —• • • • " M ° | oS S ? ' 1 T w

!!i I i i ?3 i I ||| | ?? ? 2 ? I *

5 5 -. I £ •

* ' ! *: ia!i

LI ' !

.*'.e • .. . '.. ... . - .'Time-> 8.00 10.00

2 J 6 3 E U 4 .1) H 2 V O .M

12.00 14.00 16.00 18.00 20.00

Mon Dec 29 12 :16 : 07 1997

22.00 24.00 26.00 28.00 30.00 32.00 34.00

Page 2

Quantitation Report

Data File : J:\7002\DATA\2058E09.DAcq On : 27 Feb 1998 4:09 pmSample : GSB4843AMisc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Feb 27 16:45 1998

(Not Reviewed)







System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.000-5) 1, 2-Dichlorobenzene-d4Spiked Amount 100.000

18) Nitrobenzene-d5Spiked Amount 100.000

35) 2-FluorobiphenylSpiked Amount 100.00054) 2 , 4 , 6-TribromophenolSpiked Amount 150.00065) Terphenyl-dl4Spiked Amount 100.000

Target Compounds6) Phenol12) 2-Methylphenol

81013162326

7Range

8Range

8Range

8Range

9Range

12Range

15Range

20Range

.69

.47

.69

. 97

.38

.78

.2821.2010.4733.9416.4435.2843.4110.7133

152136164188240264

112- 110

99- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

341148994226459413758482668568436669

978173

404040404040

83

.00

.00

.00

.00

.00

.00

.06Recovery

1118190 94 .95Recovery

926726 89 .38Recovery

410255 62 .27Recovery

579261 65 .69Recovery

994433 66 .49Recovery

325938 102 .86Recovery

1814251 132 .22Recovery

ngngngngngng

ng55

ng63

ng59

ng62

ng65

ng66

ng68

ng132

.37%

.30%

.59%

.27%

.69%

.49%

.57%

.22%

000000

0

0

0

0

0

0

0

0

.00

.00

.00

.02

.01

.01

.03

.00

.01

.00

.01

. 00

.00

.00

Qvalue

15) n-Nitroso-di-n-propylamine19) Nitrobenzene26) Naphthalene27) 4-Chloroaniline30) 2-Methylnaphthalene58) Phenanthrene60) Anthracene61) Di-n-butylphthalate

8899

101011171718

.22

.94

.30

.44

. 50

. 50

.65

.01

.01

.25

941087077128127142178178149

5462330015921107

3439649656269188718873987

0000100000

.39

.39

.33

. 12

.43

.51

.44

. 10

. 10

.21

ngngngngngngngngngng

#tt##

#####

3541

37964290606078

(#) = qualifier out of range (m) = manual integration2058E09.D 8270.M Fri Feb 27 16:45:57 1998 Page 1

Data File : J:\7002\DATA\2058E09.DAcq On : 27 Feb 1998 4:09 pmSample : GSB4843AMisc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Feb 27 16:45 1998




Abundance


TIC: 205BE09.D

6000000

5500000

5000000

4500000

4000000

3500000

3000000

2500000

2000000

1500000

1000000

500000

M—• *>

I j"

I $?v-l£™c? o M

§£ a«

: i 1 1 jo 2 " " o1 ' J

3

^

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2058E09.D 8270.M

12.00 14.00 16.00 18.00 20.00

Fri Feb 27 16:46:00 1998

22.00 24.00 26.00 28.00 30.00 32.00 34.00

Page 2

{-. Quantitation Report (Not Reviewed)

Data File : J:\7002\DATA\2155E08.DAcq On : 4 Jun 1998 5:49 pmSample : GWB4513AMisc : 2ul of 250ul+250ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Jun 4 18:24 1998

Position: 1OperatorInstMultiplr

ES70021 .00



J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Thu Jun 04 10:48:37 1998Continuing Cal File: J:\7002\DATA\2155S02.D8270


1) 1 , 4-Dichlorobenzene-d418) Naphthalene-d833) Acenaphthene-dlO53) Phenanthrene-dIO65) Chrysene-dl273) Perylene-dl2

81013162326

.46

.21

.37

.62

.01

.35

152136164188240264

223473825349446338771354539720341367

404040404040

.00

.00

.00

. 00

.00

.00

ngngngngngng

000000

.00

.02

.02

.02

.00

. 00

System Monitoring Compounds2) 2-FluorophenolSpiked Amount 1503) Phenol -d5Spiked Amount 1504) 2-Chlorophenol-d4Spiked Amount 150

.000

.000

.0005) 1, 2-Dichlorobenzene-d4Spiked Amount 10019) Nitrobenzene-d5Spiked Amount 10037) 2-FluorobiphenylSpiked Amount 100

.000

.000

.00056) 2 , 4 , 6 -TribromophenolSpiked Amount 15067) Terphenyl-dl4Spiked Amount 100

Target Compounds6) Phenol11) Benzyl Alcohol13) 2-Methylphenol

.000

.000

63) Di -n-butylphthalate

7Range

7Range

8Range

8Range

9Range

11Range

15Range

20Range

78817

.0321.9910.2333.71IS.2135

.9 =43. 0310.3533

.93

.71

. 71

.92

112- 11099

- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

9479108149

256759Recovery

254482Recovery

402220Recovery

174819Recovery

270482Recovery

595009Recovery

189622Recovery

1035974Recovery

35973293656

3216

33

25

53

38

38

45

53

73

0000

.41=.45=.85=.73=.50=.68=.19=.19=

.38

.55

. 10

. 16

ng22

ng16

ng35

ng38

ng38

ng45

ng35

ng73

ngngngng

.27%

.97%

. 90%

.73%

.50%

.68%

.46%

. 19%

Qvatf###

0

0

0

0

0

0

0

0

1±.

.00

.02

.00

.02

.04

.02

.02

.00

ue1

15478

(#) = qualifier out of2155EC3.D 8270.M

range (m) = manual integrationThu Jun 04 18:24:19 1998 Page I

Data File : J:\7002\DATA\2155E08.DAcq On : 4 Jun 1998 5:49 pmSample : GWB4513AMisc : 2ul of 250ul+250ul+5ul IS,V=1000MS Integration Params: LSCINT.P




J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Thu Jun 04 10:48:37 1998Continuing Cal File: J:\7002\DATA\2155S02.D

)undance

1200000

1100000

1000000

900000

800000

o700000 ,-

600000 1H-

500000

400000

300000

200000

100000

: io -

i•

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2155E08.D 8270.M Thu Jun 04 18:24:22 1998 Page 2

Quantitation Report

J:\7002\DATA\2161E07.D10 Jun 1998 1:43 pmGWB4515B,Montgomery Watson2ul of 250ul+250ul+5ul IS,V=1000



(Not Reviewed)






1) 1 , 4 -Dichlorobenzene-d418) Naphthalene-da33) Acenaphthene-dlO53) Phenanthrene-dlO65) Chrysene-dl273) Perylene-dl2


37) 2 -F luorobiphenylSpiked Amount 100.000

56} 2 , 4 , 6-TribromophenolSpiked Amount 150.00067) Terphenyl-dl4Spiked Amount 100.000

Target: Compounds6) Phenol11) Benzyl Alcohol13) 2 -Methylphenol

81013162326

7Range

7Range

8Range

8Range

9Range

11Range

15Range

20Range

.45

.20

. 37

.61

. 00

. 34

.0221. 9810.2233.7016

. 1935

. 9743. 0710

. 3533

152136164188240264

112- 110

99- 110132

- 110152

- 11082

- 110172

- 115330

- 123244

- 144

3093941268441664920949340478082339818

397824

404040404040

35

.00

.00

.00

.00

.00

.00

.07Recovery =

453756 31 .49Recovery =

678707 66 .12Recovery

285331 48 .80Recovery =

492754 43 .12Recovery

1053941 50 .73Recovery =

353167 71 .02Recovery =

1394586 121 .80Recovery

ngngngngngng

ng23

ng20

ng44

ng48

ng43

ng50

ng47

ng121

.38%

.99%

.08%

.80%

. 12%

.73%

.35%

.80%

000000

0

0

0

0

0

0

0

0

.00

.01

.01

.01

.00

.01

.00

.00

.00

.00

.01

.00

.00

.00

Qvalue788

16) n-Nitroso-di -n-propylamine 846) 4 -Nitrophenol49) Diethylphthalate63) Di-n-butylphthalate

131417

. 99

. 69

.69

.99

. 37

. 21

. 91

947910870

109149149

1463662831274175020727605622

1000000

.06

.73

.17

.22

.22

. 15

.24

ngngngngngngng

####tt##

29234171

6978

(#) = qualifier out of2161E^7.2 8270.M

range (m) = manual integrationWed Jun 10 14:19:20 1993 Page 1

uuancitation Keport

Data File : J:\7002\DATA\2161E07.DAcq On : 10 Jun 1998 1:43 pmSample : GWB4515B,Montgomery WatsonMisc : 2ul of 250ul+250ul+5ul IS,V-1000MS Integration Params: LSCINT.P




J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 10 11:09:16 1998

Response via : Continuing Cal File: J:\7002\DATA\2161S03.DAbundance

1600000 '

1500000 '

1400000

1300000

1200000 :

1100000uin

1000000 §£Q.

900000 i

t^t

800000

700000

600000

500000 :

400000 :

300000

200000

100000

o - -v.Tlme-> 7.00

u40^—f

il2S& Cfi*j**

u*/>w»"^c*a

IIo

Z, oO«*."

i

TIC:2161E07.D ~

o'

1in J">. j* inc a.i s -a • Yi ^ *•

» i' Cc c•Saz

O

?t, t

J10p

z ,

it ;i

. , '. <• ^

i

1

t

o

1 £2 |O *

9 4

£*7

VM

i

; i

.

1

rJ

I

1 ;u "Ii *

, .1I1 !

!' !'

8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 2s!oO 26^00 2?loO 28^00 29lOO 30.00 31.00 32iOO 33.00 ^

2161E07.D 8270.M Wed Jun 10 14:19:23 1998 Page

Montgomery Watson

1 'A 2i.O 7/.50 1 0 Chiomiurn

ICV ICH (JCV' (%Rec) (mg.'L) (%Rec )

1 <J ( .2//(0&3) 103 <00? 1039/0.12/8 996

9/04412 10.' < 0 0 2 99 8' ) .)4.>3 (08. 3) 998!

9/0<J4'>4 999/0[)4')5 992

1 J<)4'?1 (08, :i) 104 <00? 1049/0')4<)3 104

104'103;102

1 CTO')7(D8,£>) 104 <C02 104100

986:994992 !

9303615 103 <:00? 105ii; irnple 106

VV. .M -t spik€-d 110

i,r a - .icated 109i; oic.cstion) 108

930:i6/5 994 <00? 9949f. ,;> '-',5 (OS,:i) 100

101996101

Montgomery Watson

. ;

EF'A 200//o010 Copper

CX:B 1 Duplit^tti Spike(mg/L) (RPO) (%Rec ) (".

<002 91 99 1 9709277(08,5)<002 : 9/0')2/8

<002 9709412<002, 1 tt 101 9709453 (D&S)<002, 9709454<0 02 9700455

<002 1/1 85 9709491 (D4L.)<0()2J 97004 W<0 02<0 02<002

<002<002<0()2<0 02<002

<0 02<002<0 02<0 02<0 02

i •

37 102! 9801097(045).

9803615(T his samplewas not spikedor duplicatedin diciestior.)

i i

<OO2<0 02<0 02<002<>.) 02

'•• 9JJ036/59' 99 9803/45(D4S)

•

ICV ICB CCV«Re<:) (mg/L) i%Rec)

101 :!005 101956

100 x005 984 '964

9795

101 ^006 102100101

: 99'974

102 C005 102942!

'] 926!93!

934

98 4 <0 05 99996'101

982992

989 0)05 994965968

92 !

94

CCB 0.(mg/L) ,

<005<005

<OC6<005<OC6<OC6

<OC6<OC6<005<OC6<OC-5

<0.05:

<OC-5<OC6<QC<5<OC6

<0 05<005<OC6<OC6<OC6

<OC6<005<OC6<OCo<0 C6

iplicatr- SpikeR.^)) .%Rec)

1 4 95

NA 995

23? 84

I

31 94

1l> 100

Paq«; 1

Monlgnmery Watson

El 'A nO 7A>CUi I eacl

ICV ICh CCV OCB(%«ec | (mg.'L) (%Rec ) (mg/L)

97092>'7 (D&.S) 109 «.'0 ) 100 'Q 19/092/8 104 '01

9/09412 10b <0 1 102 ,019/094';3 '.04 P>) 104 cO 1

9/09454 103 ;0 19/09455 103 ^01

97094"! ;0&S) 107 oJ 1 10?' ,'.019/09433 105 -'01

107 :01107 -'.01105 c.O 1

107 <01103 ^.Q]104 v01104 -0 1

*

Montgomery Watson

EPA200 //6010

Duplicate Spike ICV ICB(HPD) (%Hec) a (%Rec) (mg/L)

29 98 9709277 (D&S) 101 i.0 059709278

9709412 995 =:0 05NA 1C6 9709453 (D&S)

97094549709455

29? 96 9709491 (D&S) 102 '00597094 ;.)3

NA 113j 9801097(DAS| 101 '• <.0 05I ' , '

i ;

9803615 100 <005(Tins samplewas not spikedor duplicatedin digestion)

9803675 981 -0059803745 (DAS)

1

Nickel

cx:vl%Hec)

104998

974988986982

103103104102103

102 i992,976;101!99

104:

105109109108

978996101101103

C:CB Duplicate Spine(mg/L) (RPD) :%Rec),

<005 58 94:

<005

<OC6<005 NA 104<OC6<OC6

<005 89 90<OC6<OC6<OG5<OC6 :

<OC6; 52 102

<005<0 05<OC6

<OG5 !<OC6<OC6<OC6<005

<OC6 :<OC6 9 t 95<OC6<OC6<() C6

MWAfSONXLS

iri

Montgomeiy Watson

\ ?i X) 7/6C 1 0

I bf K:V ICB

" (%Hec | (mg/L)

92?7(D&3) 101 <X'0?97092/8

9709412 101 «:CO?94!>3(D&:">)

97094549709455

9491 (D&5) 10;j - - C O ?9709493

!0<J7[DKiJi) 101 <CO?

9303615 101 - .CO?is samplei not spikedImplicated!()(: M ()ll)

93036/6 9» I -X 0?3/.1')(H«i >)

Zinc

C.CV(%Rec ) (

104101

102102102101

105104;

1041041021

104-101 j

996101100'

106'107110109109

10010?10?101103

:X;BTKI/L)

<0 02<0 02

<0 02<0 02<002<0 02

OJ 02<0 02<0 02<0 02<0 02

<002<0 02<0 02<0 02<0 02

<0 02<0 02<0 02<0 02v.i 02

<0 02<< J 020.) 02<0 02< )02

Montgomery Watson

EF:>A2()0 7/6U10

Duplicate Spike ICV ICB(RPD) (%Rec ) Lab * (%Rec .) (mg/L)

21 97 9709277 (D&S) 996 <0 19/09278

9709412 104 <0 1101 1CO! 9709453(08,5)

9/094549/09455

13 h 104 9709491 (DAS) 105 <0 19/09493

i

,

25 103 98010<)7(DA?,) 106 <0 1I .

iI • :

9803615 101 <01; (This sample

was not spiked; or duplicated

in ditjebtior )

9U036/5 106 <011 H. 99! <M)03/45(DM.)

i

Iron

CCV CCQ O'jphcati?%Rec) (mg/L) (RfD)

106 <0 1 1 ?106 <0 1

108 <0 1112 <0 1 32IDS' <oi104 <0 1

114 <0 1 09106 <0 1

99 8| <01109* <0 1108 : <01

109 <01 4109' <01

96 8' <01117' <01

<0 1

104 -:oi108 <01105 <0 1106 <0 1109 <0 1

88 <0192 4 <0 1 7896 4 <0 195 6 <0 191 2 -:0 1

Spike•%Rec )

92

120

6fl

100

100

Sheet!

Montgomery Wat

EPA 7060Lab*

97092779709278

9709412970945397094549709455

97094919709493

9801097

SM3113B

9803615

98036759803745

ICV(%Rec.)

105

105

105

105

100

105

son

ArICB

(mg/l)

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

senicCCV

(%Rec.)

111111

10899

105108

99102

CCB(mg/l)

<0.01

<0.01

<0.01

<0.01

"105| <0.01102

9290

<0.01

DUPLICATE(RPD)

5.4

0

NA

SPIKE(%Rec.)

115

90

NASamples were not spikedor duplicated

0

NA

during dige

85

NA

stion

samples were not spikedor duplicated dunng digestion

NA NA I -samples were not spiked

Montgorr

SM3113BLab*

980361598036759803745

'

'

........

-

iery We

ICV(%Rec.)

104

»tson

LeadICB

(mg/l)

<0.005

- - - - -

or duplicated during digestion I

ccv(%Rec.....

108116

- - —

-

- -

-- -

—

CCB {DUPLICATEjmg/l)

IjcO.OOS

" " -

(RPD)

NA

—— - — -

SPIKE(%Rec.)

97Samples were not spikedor duplicated during digestion.

.... . l _ __ .. _.J -^

r

, - . - ; - - -

_.•

This is a postdigestion spike

.. - .. —

-- —

Page 1

Sheetl

Montgomery Watson

ERA 330.Lab#

97092779709278970941297094539709454970945597094919709493

9801097

98036159803675

9803745

SulfateICV

(%Rec.)

90

103

98

101

ICBmg/l

0.07

0

0

0

CCV(%Rec.)

94

102

98

96

CCBmg/l

0

0.07

0

0

-

Spike(%Rec.)

Spikes anc

|

- -

I duplicates wererun on other samples in the run" /:: """same as a

94

Spike andrun on oth<

bove

duplicatesif samples

werein the run

Page 1

Sheetl

Montgomery Watson

EPA9010ALab*

9709278

970945397094549709455

97094919709493

901097

ERA 335.2

980361598036759803745

CyanideICV

(%Rec.)

98

Spike(%Rec.)

99A calibration blank was includedwith each run

97

89A calibration blank was includedwith each run

101 116

A calibration blank was includedwith each run

107 91A calibration blank was includedwith each run

ICV

100

CCV

102

Spike

107A calibration blank was includedwith each run |

Page 1

'•' ,-

o Pane no,,

LiHL

OOOO1

DES MOINES

B:71231BR1

TRAACS 3 O- C i

\12-31-97 10:57 BARB ROSE NH3-S

HK.-1 ANALYSIS REPORT FORM

^ DESCRIPTIONPeakl^Peak 3

RUN INFORMAL I UN SAMPLE ID

PeakQPeak?Peak:Peak:,PeakPeak]Peakl<Peak 11PeakK

#19

,.•.PâlX^r ..,:•' l.V.Fv-iÂ

-- .-• i

-ur-' : 1 -g:Zup: j^^*-«t- • .up: J

k"2:^ V

_up:(. -"••p:7 -Jup:l -ûpj-. -e: : -uD:2 -:up::.' -

Cup: )'!Cuo:2Lur; : ..•.:<_.- ? • 'Luc' ::•

Cup

L. L.' T'

'_!! 2':.- *-' Ch'-'..

NUL'..rJi-. •,.NULL^LK, -

'- • - ' < ' ' -C '

LUWLOW

NULLNULLNUL._.

! -4 : 1' L

i - i :r

'j. OO5.00BLANKBLANKBLANK

. . -

.00

. ! ' _ >

VV=3.50BLANK^HLANt'<L AMI

?/

9^09455

!;!••!•'

TEST #15. I'")5.160.08V.oyo.u

%:$t1 . O'J

!bio^3.450.050.061.011 . '.'•:.o.'..- •

1:!:10*2/70

o.o,:8.5.:-

NH3-S.XLS

Calculation of concentration as Mg/Kg (uG/g) from rag/1 for soil/sludge

Sample ID's

MeasuredCone.(mo/1)

Weightsampleused

% TotalResidue as%

Volumesample (I)

Test - NH3-S

9709453

9709454

9709455

9709455 DUP

9709455 SPK

SPK ADDED

9709491

9709493

0.86

0.14

1.27

1.58

2.29

0.99

0.06

8.53

5.36

5.292

5.513

5.507

5.513

5.513

5.185

5.351

87.4437

79.2157

83.015

83.015

83.015

83.015

94.2193

75.1207

0.10

0.10

0.10

0.10

0.10

0.10

0.10

0.10

Cone, bydry wt

18.35

3.34

27.75

34.56

50.04

21.63

1.23

212.20

Cone, as %by dry wt.

0.00

0.00

0.00

0.00

0.01

0.00

0.00

0.02

Page 1

I2-21-97

Paqe? no. OO001 B:71222BR2 12-22-97 12:03 BARB ROSE NH3-512/22/97

UHL DES MOINES TRAACS 9'JO SYSTEM ANALYSIS REPORT k 0PM

DESCRIPTIONPeaklPeak 2Peak 3Peak 4Peak: 5Feak6Peak 7Peak. 8Peak 9Peak 10Peakl1Peak 12Peak 13Peak 14Peak 15

Peak 16Peak 17Peak 18Peak 19

Peak20T'e.at 21r --..-1 ' '_•

RUN CNFORMATIQNCup I -..CJPCupCupCupCupCUDC u pCUDCUPC L. pCUDL U pCUDLupCUPC u pCueL . i ' :•

L .: "•

P

r . .-C:

L'..ID:''' " r-,

•- '-

1 - -:•

Z i- !'2 — '••'"". — ':•

4 -;:s — '•-o ~ .:7 - '•;•\ —1. —3 — '•.-

— '':

B ->2 — ••9 ->1 '"••^"•i . -i "" _

1 i1 l-

^J — ,

"

PRIMNULLNULLNULLCALBCALBCALBCALBCALBCALBCALBHIGHLOWLOWISMPNULLNULLNULL

NULL-NULLMUL. L.r",f"v«Hf-S'AMPT.'-I P

'-. -~-r-ir-''"-;. .-v.>1P

i '-" r u~-'^ IL'L LNULLf i ! i i 1r : ; j ." ~r- , i

riuL^.' • \ " '" i

SAMPLE ID TE5 . OO5 . 00BLANKBLANKBLANKO 1 0(") 5'"'i OO cje><"*"* -2 00 ooe» f3 oo oivn^-5 005 00("> i Oo 1 6REF *Y?*76r«c-TV=3.50BLANK.BLANK If.SPIKE (61 'Yc.oexL-BLANKSPIKE rr>tZ 'j&rQr.BLANK ' °BLANKBL ANt:970927797O927B97O9278 *?.,Pt97O9278 lOS%»f«c-SPK97O9412REF /CsC btec-TV = 3 . b'.iBLANKBLANKCf , pj n J (.

"'".'1O'^-' ^°3'. oo^ . '"* ':.'

sr <n4.91'b . • ) "-'O . O<v0 . Oy•j . OtJ<j . 0/3i j r_ji 1 ol1 ^ A

-.'.94

5 '. 0 4'.> . 0 'o . o 73. 48

0 . O*-~i") I'lQi . 6 11 . '. b

v > _ i : :' ' .' • ., Lj-~6 . 3 10. 341 . 351,8-?L ,

1 ' ' I'-T

1 • ""

"•-

'- ' i'.

NH3-S.XLS

Calculation of concentration as Mg/Kg (uG/g) from mg/1 for soil/sludge

Sample ID'S

MeasuredCone,(mg/l)

Weightsampleused

% TotalResidue as%

Volumesample (I)

Test = NH3-S

9709277

9709278

9709278

9709278

SPK ADDED

9709412

0.28

0.31

0.34

1.35

0.99

1.89

5.133

5.141

5.143

5.141

5.141

5.935

86.4523

78.6111

78.6111

78.6111

78.6111

85.9469

0.10

0.10

0.10

0.10

0.10

0.10

Cone, bydry wt

6.31

7.67

8.41

33.40

24.50

37.05

Cone, as %by dry wt.

0.00

0.00

0.00

0.00

0.00

0.00

Page 1

F'aae no. OOO01•03 / 16/93

UHL DES noiMEs

B:30316BR2 03-16-98 11:59 BARB ROSE NH3-C

TRAACS 800 SYSTEM ANALVSIS REPORT FORM

DESCRIPTIONPeaklPeak 3Peak 4PeakSPeak 6Peaky-Peak 8PeakPeakPeakPeakPeak 13Peak 14Peak 15

:9101 112

Peak 16Peakl?Peat.: 18Peak 19

Peal 20Peal 21Peal 22

Peat. 27Peak23Peal 2^

RUN INFORMATION SAMPLE ID TESTCUDCUDCUDCUDCUDCUDCUDCUDCUDC U DCUDCUDCUDCUDCUDCUDCUDCUDCUDC U DCUDCUD

C ._• oLLIDCUDCUDCUDC u oC U D

C -i cC ..I DL-UD

'•-. ' • C1

C ;. • ~C '.I.E.'

1 - >1 ->2 — ;2 — '•2 — "3 — '':•4 -:::5 ->6 ->"7 — 'i ->1 -:;"" — ''..T _ "•.,

8 ->2 — *'"* — ;9 - >10 -2 — •-—T i -\ *-\ _

i _• ~

14 -1 C"

__> ~~ .

16 -17 -

13 -1 '-• -20 -o — ''

—2 1 —2 22 ~- ~24 -2 5 —

PRIMNULLNULLNULLCALBCALBCALBCALBCALBCALBCALBHIGHLOWLOWISMPNULLNULLNULLNULL

NULLNULL

••• SAMP•• SAMPSAMPSAMPSAMPSAMPSAMP

••• SAMPSAMPSAMP

I SM ~'

iMLJLLSAMPSAMPSAMP

SAMPSAMP

5. GO5 . 00BLANKBLANK:BLANKO 1 (")0 501 002 007; oo5 GO5 000 1 00 1 0REFT V = -~^BLANKBLANKSP I KEBLANKSPIKEBLANKBLANKBLANK9852198521985211 : 2^8521985221:4985.22lt4""

98522DUP9 o 5 "*"'SPK*""REFT" V — ~*-BLANKS* J^i S ''""•9852::9 3 ' '1 : 2935229S5221 : 2

<

00

1 ~181 9

"'''iTi114163 IZ

"'i"1

3Z

i ) * i

*54!~ "' \~'if- T

C" C.'

75

i. 18;. 13

:: . 14O.981 .882.885. 1 15. 120. 150. 152.880. O60. O70. 981

X.«/o«Pt>

oe

4. 5

6 . -

1 5

a.I

e. • \cs.3-

c. •}-C..5

Paae no. OOOO03/16/98

B:80316BR2 03-16-98 11:59 BARB ROSE NH3-L

LJHL DES MOINES TRAACS 800 SYSTEM ANALYSIS REPORT FORM

DESCRIPTION. _-k:39Peak:4OPeak: 41Peak: 4 2Peak. 43Peak:44Peak45Peak46Peak47Peak48Peak49Peak50PeakS1Peak:52Peak53Peak54F'eak:55Peak56Peak57Peak58Peat 59Peak:60F'eat 6 1Peat 62F1 e a t.. 6 3Peak.64F'eat 65

PeakGOPeal 07'-'ear 6y

Peat. 71

RUN INFORMATIONCUD 26 -CUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDLUDCUDCUDCUDCUDC LI D

C LI D

C'JOC U D

C .I D

C .IDC J.G

("_ ,_(£,

C L.I D

~2~ —

23 -29 -7O —3"-;2 — :31 -32 —~T ~T _

34 -•-•wJ —

36 -37 -38 -39 -40 -3 - •:

~ -41 -41 -47 -44 -

45 -

4o -47 -

4 £: —

4 -5 —

S ' " —:~

_<=? •cr ^ _

;5 ~

cr i __

3 *~> ~

:• SAMP: SAMP> SAMP:; SAMP; SAMPI SMPNULL

:; SAMP> SAMP> SAMP> SAMP.; SAMP> SAMP:; SAMP':•• SAMP.. SAMP. SAMPI SMPNULL

. SAMPSAMPSAMP

. SAMPSAMPSAMP

:- SAMPSAMP

SAMP

' SAMPI SMP

NULL.SAMPSAMPSAMP

SAMP

SAMP

SAMPLE ID985227698523371:49852337DUP9852337SPK9852373REF *]TV=3.00BLANK:9852374985237598523789852379985238098523819852382985238398523849852443REF QTV=3.OO 'BLANC98524509852451985245298524531:109852453 o.DUP9852453 <#•SPK98524541 : 1 00852455

1 : 1 OO98524561 : 1009852457REF <KTV =3. 00BLANI .9352453935241493O1O971:498O1O97DUP98O1097 <SPK

7! 847.54 7.5

0.13 o.l2.82("). ("i i("'. 78 o.*f-0.11 e> -12.913.67 _S-^i A^l'!57 ?.6«0.14 o • (2.5.1 a. s2! 34 C>'

I ! 2'~: 1-3-1.33 I-*

1 i.i .43 I Cs10. 44

110.34i -.:. -' 68. 551.2"

4.715. 108. 06

/oc

B:80316BR2 03-16-98 11:59 BARB ROSE IMH3-D

UHL DES MOINES TRAACS SO'.".' SYSTEM ANALYSIS REPORT FORh

P a a e no. 0 0 O 0 3O3/16/98

DESCRIPTION RUN INFORMATION SAMPLE IDPeak 75Peak 76Peak 77Peak 78Peak 79Peak SOPeak 81Peak82Peak83Peak 84

ULID :CUD :CUD:CUD:CUD:CUD :CUD:CUD :CUD :CUD :

s -~->j-jL.

~T _~~. —

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NH3-S.XLS


Sample ID's

MeasuredCone.(mo/1)

Weightsampleused

% TotalResidue as%

Volumesample (I)

Test = NH3-S

9852414

9801097

9801097 DUP

9801097 SPK

SPK ADDED

3.1

4.71

5.1

8.08

4

5.0754

5.2236

5.2236

5.2236

5.2236

14.1683

73.9229

73.9229

73.9229

73.9229

0.25

0.25

0.25

0.25

0.25

Cone, bydry wt

1077.74

304.94

330.19

523.12

258.97

Cone, as% by dry

wt.

0.11

0.03

0.03

0.05

0.03

Page 1

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Sample ID's

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Volumesample (1)

Test = NH3-S

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9856339

5.5

0.57

4.4903

7.0678

20.5566

24.597

0.25

0.25

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Cone, as% by dry

wt.

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81.97

0.15

0.01

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Sample ID'S

MeasuredCone.(mg/1)

Weightsampleused

% TotalResidue as%

Volumesample (I)

Test = NH3-S

9856672

9856672 DUP

9856672 SPK

SPK ADDED

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24.22

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10

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29653.71

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12243.48

2.97

2.97

4.10

1.22

Page 1

FEB 2? L v..,.. · 2016. 6. 14. · FEB 2? SUPERFUND DIVISION L v..,.. MW #1217431.010305 Ms. Diana...

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Transcript of FEB 2? L v..,.. · 2016. 6. 14. · FEB 2? SUPERFUND DIVISION L v..,.. MW #1217431.010305 Ms. Diana...