FACULTY OF ENGINEERING1 Contact address in Japan (Miyazaki) : University of Miyazaki Address : 1-1,...

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1 Contact address in Japan (Miyazaki) : University of Miyazaki Address : 1-1, Gakuen – Kibanadai – Nishi Miyazaki 889-2192 Web site : http://www.miyazaki-u.ac.jp/english/ Email: kokusai@cc.miyazaki-u.ac.jp “Material Science” Research Unit---Characterization--- FACULTY OF ENGINEERING Characterization of Semiconductor Materials and Devices Material /device Photothermal spectra Photoluminescence Photo reflectance Raman Scattering High-Resolution X-Ray Diffraction Scanning Electron Microscopy Transmission Electron Microscopy technics 0.9 1.0 1.1 1.2 1.3 1.4 10nm 7nm 5nm 3nm PPT Signal Intensity (arb. unit) Photon Energy (eV) e1-hh1 e1-hh1 e1-lh1 e3-hh3 e2-hh2 e2-hh2 e1-lh1 As-grown sample Room Temperature e1-hh1 e1-hh1 Photothermal spectra of GaInNAs SQW (Single quantum well) 3 nm -- 10 nm MQW solar cell Nano-Disk solar cell CIGS solar cell ZnO QW LED and Laser Nano-Wire LED Si Clathrate The photo-reflectance (PR) technique to determine the band-gap energy of semiconductor. PR detects the modulated reflectance from the semiconductor surface induced by the laser irradiation. Quantum Efficiency (QE) measurement system. QE is the ratio of the number of carriers collected by the solar cell to the number of irradiated photons. 500 nm 100 periods MQW with Graded Buffer layers 10 nm GaAsP InGaAs 10 nm InGaAs GaAsP SEM image of the 100 periods quantum wells (QWs) for the ultra-high efficient multiple-junction solar cells Photoluminescence spectra of P-doped ZnO nanowires . Fabrication of nanowires Challenge to p-type doping Fabrication and characterization of new functional semiconductor materials High-resolution transmission electron microscope (HR-TEM) image of Al- doped ZnO nanowires. Raman Spectroscopy of Wurtzite and Zinc- blende GaAs Nanowaires 240 260 280 300 Normalized Raman Intensity (a. u.) Raman Shift [cm -1 ] 5 μm GaAs-NWs A B C A B B B B A A The transversal optical (TO) and longitudinal optical (LO) mode are related to the both Zinc-blende and Wurtzite structures. E 2 H is the transvesal optical mode related to the Wurtzite structure. Surface optical(SO) mode is attri- -buted to the crystalline surface. Multi-Wavelength Integrated Light Source for Optical Sensing Application: (1) Multi-gas sensor array using multi- wavelength resonant cavity gas cell device (2) Optical coherence tomography using wide wavelength range infrared laser array

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Contact address in Japan (Miyazaki) : University of Miyazaki

Address : 1-1, Gakuen – Kibanadai – Nishi Miyazaki 889-2192

Web site : http://www.miyazaki-u.ac.jp/english/ Email: [email protected]

“Material Science” Research Unit---Characterization---

FACULTY OF ENGINEERING

Characterization of Semiconductor Materials and Devices

Material /device

Photothermal spectra

Photoluminescence

Photo reflectance

Raman Scattering

High-Resolution X-Ray Diffraction

Scanning Electron Microscopy

Transmission Electron Microscopy

technics

0.9 1.0 1.1 1.2 1.3 1.4

10nm

7nm

5nm

3nm

PP

T S

igna

l In

tensity (

arb

. u

nit)

Photon Energy (eV)

e1-hh1

e1-hh1

e1-lh1e3-hh3

e2-hh2

e2-hh2e1-lh1

As-grown sampleRoom Temperature

e1-hh1

e1-hh1

Photothermal spectra of GaInNAs SQW (Single quantum

well) 3 nm -- 10 nm

MQW solar cell

Nano-Disk solar cell

CIGS solar cell

ZnO

QW LED and Laser

Nano-Wire LED

Si Clathrate

The photo-reflectance (PR) technique to

determine the band-gap energy of

semiconductor. PR detects the modulated

reflectance from the semiconductor surface

induced by the laser irradiation.

Quantum Efficiency (QE) measurement

system. QE is the ratio of the number of

carriers collected by the solar cell to the

number of irradiated photons. 500 nm

100 p

eri

od

s M

QW

with G

raded B

uffe

r la

yers

10 nm

GaAsP

InGaAs

10 nm

InGaAs

GaAsP

SEM image of the 100 periods quantum wells (QWs) for the

ultra-high efficient multiple-junction solar cells

Photoluminescence spectra

of P-doped ZnO nanowires .

• Fabrication of nanowires

• Challenge to p-type doping

Fabrication and characterization of

new functional semiconductor materials

High-resolution transmission electron

microscope (HR-TEM) image of Al-

doped ZnO nanowires.

Raman Spectroscopy of Wurtzite and Zinc-

blende GaAs Nanowaires

240 260 280 300

Nor

mal

ized

Ram

an Int

ensi

ty (a.

u.)

Raman Shift [cm-1]

5 μm

GaAs-NWs

A B C A B

B

B

B A

A

・The transversal optical (TO) and

longitudinal optical (LO) mode

are related to the both Zinc-blende

and Wurtzite structures.

・E2H is the transvesal optical mode

related to the Wurtzite structure.

・Surface optical(SO) mode is attri-

-buted to the crystalline surface.

Multi-Wavelength Integrated Light Source for

Optical Sensing

Application:

(1) Multi-gas sensor array using multi-

wavelength resonant cavity gas cell device

(2) Optical coherence tomography using

wide wavelength range infrared laser array