Fabrication of antireflective SiC surface using plasma etching with self-assembled nanopattern

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Fabrication of antireflective SiC surface using plasma etching with self-assembled nanopattern Y. Ou 1,2 , A. Argyraki 1 , and H. Ou 1 1. DTU Fotonik, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark 2. Light Extraction ApS, Diplomvej 373, DK-2800 Kgs. Lyngby, Denmark [email protected] Introduction Characterization and results Summary Pseudo-periodic ARS have been fabricated on SiC substrate by using self-assembled nanopattern Density and average size of ARS can be controlled by tuning the deposited Au film thickness and thermal processing conditions Suppressed surface reflectance and enhanced light transmittance can be obtained by fabricating ARS with various size This method is time-efficient, low cost, and scalable Reference Y. Ou, et al., Opt. Lett. 37, 3816, 2012. Y. Ou, et al., Opt. Mater. Express 3, 86, 2013. Nano-islands size distribution Au thickness (nm) Particle density (/μm 2 ) Mean effective diameter (nm) Structure height (nm) 3 1910 15.5 83-245 5 200 42.2 133-262 7 88.9 63 156-315 9 19 125 162-531 11 4.32 231 214-782 13 1.73 319 494-1040 Fabrication process (a) Thin metal film deposition; (b) Rapid thermal processing; (c) Reactive- ion etching SEM: Au nano-islands (made from different Au film thickness) SEM: SiC ARS (made from different Au film thickness) 200nm 3 nm 5 nm 200nm 7 nm 200nm 9 nm 1µm 11 nm 1µm 13 nm 1µm 200nm 3 nm 200nm 5 nm 200nm 7 nm 200nm 9 nm 200nm 11 nm 200nm 13 nm 3 nm 5 nm 7 nm 9 nm 11 nm 13 nm Surface reflectance and transmittance were measured in a spectral range from 350-785nm by using an integrating sphere Lower reflectance and higher transmittance are observed after introducing SiC ARS Merits of SiC as substrate in LEDs : •Small lattice mismatch with GaN (3.5%) •Can be conductive which allows for a fabrication of vertical device structure •Excellent thermal conductivity, preferred in high power LEDs Challenge: •Low light extraction efficiency and large internal reflection loss due to high refractive index value of 6H-SiC (n=2.68) Method to enhance the light extraction: •Fabrication of antireflective structures (ARS) on SiC substrate

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Fabrication of antireflective SiC surface using plasma etching with self-assembled nanopattern. Y. Ou 1,2 , A. Argyraki 1 , and H. Ou 1 1. DTU Fotonik, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark 2. Light Extraction ApS, Diplomvej 373, DK-2800 Kgs. Lyngby, Denmark - PowerPoint PPT Presentation

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Fabrication of antireflective SiC surface using plasma etching with self-assembled nanopattern

Fabrication of antireflective SiC surface using plasma etching with self-assembled nanopattern

Y. Ou1,2, A. Argyraki1, and H. Ou1

1. DTU Fotonik, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark 2. Light Extraction ApS, Diplomvej 373, DK-2800 Kgs. Lyngby, Denmark

[email protected]

Introduction Characterization and results

Summary

• Pseudo-periodic ARS have been fabricated on SiC substrate by using self-assembled nanopattern

• Density and average size of ARS can be controlled by tuning the deposited Au film thickness and thermal processing conditions

• Suppressed surface reflectance and enhanced light transmittance can be obtained by fabricating ARS with various size

• This method is time-efficient, low cost, and scalable

Reference

Y. Ou, et al., Opt. Lett. 37, 3816, 2012.Y. Ou, et al., Opt. Mater. Express 3, 86, 2013.

Nano-islands size distribution

Au thickness (nm)

Particle density (/μm2)

Mean effective diameter (nm)

Structure height (nm)

3 1910 15.5 83-2455 200 42.2 133-2627 88.9 63 156-3159 19 125 162-531

11 4.32 231 214-78213 1.73 319 494-1040Fabrication process

(a) Thin metal film deposition; (b) Rapid thermal processing; (c) Reactive-ion etching

SEM: Au nano-islands(made from different Au film thickness)

SEM: SiC ARS (made from different Au film thickness)

200nm3 nm 5 nm 200nm 7 nm 200nm

9 nm 1µm 11 nm 1µm 13 nm 1µm

200nm3 nm 200nm5 nm 200nm7 nm

200nm9 nm 200nm11 nm 200nm13 nm

3 nm 5 nm 7 nm

9 nm 11 nm 13 nm

• Surface reflectance and transmittance were measured in a spectral range from 350-785nm by using an integrating sphere

• Lower reflectance and higher transmittance are observed after introducing SiC ARS

Merits of SiC as substrate in LEDs :

•Small lattice mismatch with GaN (3.5%)

•Can be conductive which allows for a fabrication of vertical device structure

•Excellent thermal conductivity, preferred in high power LEDs

Challenge:

•Low light extraction efficiency and large internal reflection loss due to high refractive index value of 6H-SiC (n=2.68)

Method to enhance the light extraction:

•Fabrication of antireflective structures (ARS) on SiC substrate