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www.novatio.com11. 2 2
EXTRA INFO
Materiaal AbbreviationSelf-extinguishing
Flameappearance
Combustionappearance Odour General
Acrylionitril-butadien-styrene ABS no orange-yellow flame very sooty hyacinth with rubber hard, flexible
Acrylate (moulded) MMMA no yellow-blue flame crackles sweetish hard, flexible, smooth surface.
Acrylate (extruded) PMMA no yellow-blue flame crackles sweetish hard, shiny, extrusion strips
Polyacetate POM no blue-transparent flame difficult to observe formalin hard, brittle, shiny
Polyamide PA no blue flame, yellow top no smoke burnt horn quite hard, flexible
Polycarbonate PC yes yellow flame soot with bubble formation phenol hard. flexible, unbreakable
Polyethylene (hard) hPE no blue flame, yellow top white smoke stearin hard, flexible, slightly greasy
Polyethylene (high molecular) HmPE no blue flame, yellow top white smoke stearin hard, slightly greasy
Polyethylene (soft) zPE no blue flame, yellow top white smoke stearin flexible, slightly greasy
Polyethlene terephthalate PETP no orange-yellow flame light grey smoke sweetish very hard, chalky surface
Polyphenylene oxide PPO yes light-yellow flame slightly sooty sweetish chlorine very hard
Noryl PPO yes yellowish flame very sooty sweetish chlorine hard
Polypropylene PP no blue flame, yellow top light grey smoke stearin with incense hard, flexible, slightly greasy
Polystyrene PS no orange-yellow flame very sooty (flakes) strong hyacinth hard, brittle metallic sound
Polytetrafluorethylene PTFE yes does not burn - - flexible, quite greasy
Polyurethane PUR yes light orange flame light grey smoke disinfectant air rubbery, high tear strength
Polyvinylchloride (hard) PVC yes yellow-green flame grey smoke hydrochloric acid hard
Polyvinylchloride (high-temp) PVC-C yes yellow-green flame grey smoke hydrochloric acid very hard, usually matt surface
Polyvinylchloride (soft) zPVC yes yellow-green flame grey smoke hydrochloric acid rubbery
Pofyvinylchloride (high impact resistant) HsvPVC yes yellow-green flame grey smoke weak hydrochloric acid hard, flexible, impact-resistant
Polyvinylidene fluoride PVDF yes blue-yellow flame light grey smoke, carbonises fluorine water gas hard, shiny
Synthetic resin bonded paper HaPa yes yellow flame carbonises ammonia very hard, laminate visible
Synthetic resin bonded fabric HaWe yes yellow flame carbonises ammonia very hard, fabric visible
RECOGNITION OF PLASTICS
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EXTRA INFO
CLARIFICATION OF TECHNICAL TERMS
Tear strength — N/mm2 This is the maximum force required to tear the material. The tear strength is expressed in N/mm2.
E-modulus (elasticity modulus) —N/tm’ The elasticity modulus, indicated by E, is a material’s characteristic which is a measure forr a material’s stiffness or rigidity, and which partially determines the material’s elasticity under a (pulling) load. The elasticity modulus unit is expressed in N/m2. Most materials have a quite high modulus, which is why N/mm2 is often used.
Compression strength N/mm2 The compression strength is the resistance to pressure, the ability to withstand pressure.
Electrical resistance - Ohm The electrical resistance is the electrical characteristic of materials to ‘impede’ the flow of electrical current: if an electrical current flows through a material, this does not happen without impedance and energy is required; the current encounters “resistance”.
Shear strength — N/mm2 A material’s shear strength is the internal resistance which a material needs against plastic deformation due to sliding.
Insulation resistance - Ohm The insulation resistance is the resistance between the conductor and the earth in electrical installations or electrical appliances. The greater the insulation resistance, the smaller the current leakage.
Compactness or density — g/cm3 In physics and chemistry the density or specific mass of a material indicates how much mass of this material is present in a specific volume. Density is expressed in S.I. in kg/m3, but the older unit g/cm3 is used more. The conversion is: 1000kg/m3= 1 g/cm3.
Electrical voltage - V The electrical voltage is the potential difference between two points in space. The electri-cal voltage is usually determined between two points of an electrical connection, such as a wire.
Melting point - °C The melting point is the temperature whereby a solid is in equilibrium with the liquid form of this substance. It is usually assumed here that the pressure is 1 atmosphere.
Flammability The flammability is the extent to which a very local and limited source of heat can ignite a material.
Hardness The hardness of a material is the resistance that the material offers against permanent mechanical deformation.
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EXTRA INFO
CLARIFICATION OF TECHNICAL TERMS
Volatile organic substances - % Volatile organic substances (VOS) are a colection of carbon compounds which, as the name suggests, evaporate easily. Among other items, think of fuel and solvent compo-nents. These substances are related to a number of different environmental problems in-cluding (summer) smog and acidification. Some of these substances can have a harmful effect on human health.
Flash point - °C The flash point of a chemical substance is the lowest temperature at which the substance still releases sufficient vapour to be able to ignite when it comes into contact with a source of ignition.The flash point cannot be confused with the self-ignition temperature. The latter is the temperature at which a vapour/air mixture ignites spontaneously.
Tensile strength — N/mm2 The tensile strength is the maximum mechanical tension which a material reaches when it is plastically deformed.
Tractive force — N/mm2 Tractive force is force that is directed in such a way that the material to which the tractive force is applied wants to tear away.
Viscosity - mPa.s or millipoiseuille Viscosity is the ‘syrupy-ness’ of a liquid or gas. Thus water is an example of a liquid with a low viscosity, while honey is an example of a liquid with a high viscosity.
Evaporation Evaporation is the phase transition from a liquid to a gas in physics. Evaporation can oc-cur when the liquid boils. Evaporation also occurs when a liquid is exposed to drier air.
Specific resistance — Ohm/mm Specific resistance (p) or impedance is an electronic component’s capacity to resist an electrical current. A component’s resistance value is expressed in ohm/mm.
Solidification In physics solidification is the phase transition where a liquid transforms into a solid. Heat is released during this transition. To solidify a substance artificially, cooling is required so that the substance can get rid of its heat.
Thermal conductivity or heat conductivity coefficient I9W/mk
Thermal conductivity or the heat conductivity coefficient (k symbol) is a material constant which indicates how well the material conducts heat. It is also used in Fourier’s law (heat transfer through conduction).
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EXTRA INFO
Length 1 inch = 2.54 cm 1 millimetre = 0.03937 in
1 foot = 0.3048 m 1 centimetre = 0.3937 in
1 yard = 0.9144 m 1 decimetre = 0.3281 ft
1 rod = 5.0292 m 1 metre = 3.281 ft
1 chain = 20.117 m 1 metre = 1.094 yd
1 furlong = 201.17 m 1 decametre = 10.94 yds
1 mile = 1.6093 km 1 kilometre = 0.6214 mi
1 nautical mile = 1.8532 km 1 kilometre = 0.539 naut. mi
Weight 1 ounce = 28.35 gr 1 gram = 0.035 oz
1 pound = 453.59 gr 1 hectogram = 3.527 ozs
1 hundredweight = 45.36 kg 1 kilogram = 2.205 lbs
1 ton = 907.18 kg 1 ton = 1.102 sh. tn
Temperature Fahrenheit = F Celsius = C Celsius° = 5/9 (F°-32°) Fahrenheit° = 9/5 (C°+32°)
Pressure measurements 1 kg/cm2 = 14.223 lb/in2 1kg/m2 = 0.205 lb/ft2 1 kg/cm3 = 36.127 lb/in3
Surface 1 square inch = 6.4516 cm2 1 sq. centimetre = 0.1550 in2
1 square foot = 929.03 cm2 1 sq. metre = 1.550 ins2
1 square yard = 0.8361 m2 1 are = 119.60 yds2
1 acre = 4,046.9 m2 1 hectare = 2.4711 a
1 square mile = 259.0 ha 1 sq. kilometre = 0.3861 mi2
Solid content (Imperial) Liquid content (USA)
Content 1 pint = 0.5506 l 1 pint = 0.473 l
1 quart = 1.136 l 1 quart = 0.9463 l
1 gallon = 4.546 l 1 gallon = 3,785 l
1 peck = 9.092 l 1 peck = 8.809 l
1 bushel = 36.369 l 1 bushel = 35.24 l
Volume 1 cubic inch = 16.387 cm3 1 cubic centimetre = 0.061 in3
1 cubic foot = 0.0283 m3 1 cubic decimetre = 0.035 ft3
1 cubic yard = 0.7646 m3 1 cubic metre = 1.308 yd3
Speed mph 20 30 40 50 60 70 80 90 100km/h 32 48 64 80 96 112 128 144 160
Energy values 1 kilocalorie (kcal) = 3.963 British thermal units (Btu)1 joule (j) = 0.239 cal1000 joule = 0.948 Btu
Standard wire measurements mm 1.59 1.98 2.38 3.18 3.97 4.76 6.35 12.70
inch 1/16 5/64 3/32 1/8 5/32 3/16 1/4 1/2
swg 17 14 12 10 8 6 4 6/0
CONVERSION TABLES
Other 1 min = 60 s 1 dm3 = 1 l (liter)
1 hour = 3600 s 1 cm3 = 1 ml
1 day = 8.640.104 s 1 rad = 57.30°
1 year = 3.156.107 s 1 kWh = 3.6.106 J
1 km/h = 0.2778 m/s ? (°C) + 273 = T(K)
1 m/s = 3.6 km/h
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EXTRA INFO
Quantity Symbol Unit Symbol Derived units
Length l metre m
Position s Metre m
Wavelength metre m
Time t second s
Mass m kilogram kg
Surface S, A m2
Volume V m3
Speed v m/s
Acceleration a m/s2
Force F newton N kg.m/s2
Weight G newton N
Energy E joule J N.m = kg.m2/s2
Entropy S joule J
Enthalpy H joule J
Internal energy U joule J
Capacity P watt W J/s = kg.m2/s2
Density kg/m3
Pressure p pascal Pa N.m2 = kg/m.s2
Temperature T Kelvin K
Temperature* T gr. Celcius °C
Current I Ampère A
Voltage U volt V W/A
Resistance R ohm ? V/A
Charge Q coulomb C A.s
Magnetic induction B tesla T Wb/m2 = V.s/m2
Quantity of substance n mol mol
Light strength I candela cd
Frequency f hertz Hz 1/s
Elastic constant k N/m
According to the:
S.I. UNIT SYSTEM
The basic quantities are printed in bold.
* not an SI unit
QUANTITIES, SYMBOLS AND UNITS
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EXTRA INFO
SAFETY SYMBOLS
Respiratory protection obliged
Head protection obliged
General command Protective clothing obliged
Ear protection obliged Safety footwear obliged
Face protection obliged
Eye protection obliged
Crossing obliged
Apron obliged
Safety belt obliged
Hand proteciton obliged
Light respiratory proteciton
Heavy respiratory protection obliged
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EXTRA INFO
DANGER SYMBOLS
EExplosive
OOxidant
FFlammable
F+Highly flammable
TToxic
T+Highly toxic
CCorrosive
XnHarmful
NDangerous forthe environmenty
XiIrritating
The labels of many substances must contain the stipulated symbols and R and S phrases.The division depends on the substance’s characteristics.A safety label of this type means that the user can see how the product may be dangerous at a glance.
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EXTRA INFO
SECURITY PHRASES
snumBer codenr text(01/02) (01/02) (Keeplockedupandoutofreachofchildren)(02) (02) (Keepoutofreachofchildren)(27) (27) (Takeoffimmediatelyallcontaminatedclothing)(29) (29) (Donotemptyintodrains)(46) (46) (Ifswallowed,seekmedicaladviceimmediatelyandshowthiscontainerorlabel)(62) (62) (Ifswallowed,donotinducevomiting:seekmedicaladviceimmediatelyandshowthiscontainer
orlabel)(63) (63) (Incaseofaccidentbyinhalation:removecasualtytofreshairandkeepatrest)(64) (64) (Ifswallowed,rinsemouthwithwater(onlyifthepersonisconscious)01 01 Keeplockedup01/02 01/02 Keeplockedupandoutofreachofchildren02 02 Keepoutofreachofchildren03 03 Keepinacoolplace03/07 03/07 Keepcontainertightlyclosedinacoolplace03/07/09 03/07/09 Keepcontainertightlyclosedinacool,well-ventilatedplace03/09 03/09 Keepinacool,well-ventilatedplace03/09/14 03/09/14(101) Keepinacool,well-ventilatedplaceawayfromallsubstances03/09/14 03/09/14(102) Keepinacool,well-ventilatedplaceawayfromoxidizingagents03/09/14 03/09/14(103) Keepinacool,well-ventilatedplaceawayfromreducingagents03/09/14 03/09/14(104) Keepinacool,well-ventilatedplaceawayfrom(strong)acids03/09/14 03/09/14(105) Keepinacool,well-ventilatedplaceawayfrom(strong)bases03/09/14 03/09/14(106) Keepinacool,well-ventilatedplaceawayfromalcohols03/09/14 03/09/14(107) Keepinacool,well-ventilatedplaceawayfromcombustiblematerials03/09/14 03/09/14(108) Keepinacool,well-ventilatedplaceawayfromiron03/09/14 03/09/14(109) Keepinacool,well-ventilatedplaceawayfromreducingagents/
(strong)acids/(strong)bases03/09/14 03/09/14(110) Keepinacool,well-ventilatedplaceawayfrommoisture03/09/49 03/09/49 Keeponlyintheoriginalcontainerinacoolwell-ventilatedplace03/09/14/49 001(101) Keeponlyintheoriginalcontainerinacool,
well-ventilatedplaceawayfromallsubstances03/09/14/49 001(102) Keeponlyintheoriginalcontainerinacool,
well-ventilatedplaceawayfromoxidizingagents03/09/14/49 001(103) Keeponlyintheoriginalcontainerinacool,
well-ventilatedplaceawayfromreducingagents03/09/14/49 001(104) Keeponlyintheoriginalcontainerinacool,
well-ventilatedplaceawayfrom(strong)acids03/09/14/49 001(105) Keeponlyintheoriginalcontainerinacool,
well-ventilatedplaceawayfrom(strong)bases03/09/14/49 001(106) Keeponlyintheoriginalcontainerinacool,
well-ventilatedplaceawayfromalcohols03/09/14/49 001(107) Keeponlyintheoriginalcontainerinacool,
well-ventilatedplaceawayfromcombustiblematerials03/09/14/49 001(108) Keeponlyintheoriginalcontainerinacool,
well-ventilatedplaceawayfromiron03/09/14/49 001(109) Keeponlyintheoriginalcontainerinacool,
well-ventilatedplaceawayfromreducingagents/(strong)acids/(strong)bases03/09/14/49 001(110) Keeponlyintheoriginalcontainerinacool,
well-ventilatedplaceawayfrommoisture03/14 03/14(101) Keepinacoolplaceawayfromallsubstances03/14 03/14(102) Keepinacoolplaceawayfromoxidizingagents03/14 03/14(103) Keepinacoolplaceawayfromreducingagents03/14 03/14(104) Keepinacoolplaceawayfrom(strong)acids03/14 03/14(105) Keepinacoolplaceawayfrom(strong)bases03/14 03/14(106) Keepinacoolplaceawayfromalcohols03/14 03/14(107) Keepinacoolplaceawayfromcombustiblematerials03/14 03/14(108) Keepinacoolplaceawayfromiron03/14 03/14(109) Keepinacoolplaceawayfromreducingagents/(strong)acids/(strong)bases04 04 Keepawayfromlivingquarters05 05(101) Keepcontentsunderwater05 05(102) Keepcontentsunderparaffinoil05 05(103) Keepcontentsunderpetroleum/kerosene05 05(104) Keepcontentsunderalcohol05 05(105) Keepcontentsunderparaffinoil/petroleum/kerosene06 06(101) Keepcontentsundernitrogen06 06(102) Keepcontentsunderinertgas07 07 Keepcontainertightlyclosed07/08 07/08 Keepcontainertightlyclosedanddry07/09 07/09 Keepcontainertightlyclosedinawell-ventilatedplace
snumBer codenr text07/47 07/47(101) Keepcontainertightlyclosedandatatemperaturenotexceedingtheflashpoint07/47 07/47(102) Keepcontainertightlyclosedandatatemperaturenotexceeding21°C07/47 07/47(103) Keepcontainertightlyclosedandatatemperaturenotexceeding15°C07/47 07/47(104) Keepcontainertightlyclosedandatatemperaturenotexceeding10°C07/47 07/47(105) Keepcontainertightlyclosedandatatemperaturenotexceeding5°C07/47 07/47(106) Keepcontainertightlyclosedandatatemperaturenotexceeding0°C07/47 07/47(107) Keepcontainertightlyclosedandatatemperaturenotexceeding-15°C07/47 07/47(108) Keepcontainertightlyclosedandatatemperaturenotexceeding45°C07/47 07/47(109) Keepcontainertightlyclosedandatatemperaturenotexceeding-20°C08 08 Keepcontainerdry09 09 Keepcontainerinawell-ventilatedplace.12 12 Donotkeepthecontainersealed13 13 Keepawayfromfood,drinkandanimalfeedingstuffs14 14(101) Keepawayfromallsubstances14 14(102) Keepawayfromoxidizingagents14 14(103) Keepawayfromreducingagents14 14(104) Keepawayfrom(strong)acids14 14(105) Keepawayfrom(strong)bases14 14(106) Keepawayfromalcohols14 14(107) Keepawayfromcombustiblematerials14 14(108) Keepawayfromiron14 14(109) Keepawayfromreducingagents/(strong)acids/(strong)bases14 14(110) Keepawayfromreducingagents/(strong)acids/(strong)basesandmetals15 15 Keepawayfromheat16 16 Keepawayfromsourcesofignition-Nosmoking17 17 Keepawayfromcombustiblematerials18 18 Handleandopencontainerwithcare20 20 Whenusingdonoteatordrink20/21 20/21 Whenusingdonoteat,drinkorsmoke21 21 Whenusingdonotsmoke22 22 Donotbreathedust23 23(101) Donotbreathegas23 23(102) Donotbreathefumes23 23(103) Donotbreathevapour23 23(104) Donotbreathespray23 23(105) Donotbreathedust23 23(106) Donotbreathe24 24 Avoidcontactwithskin24/25 24/25 Avoidcontactwithskinandeyes25 25 Avoidcontactwitheyes26 26 Incaseofcontactwitheyes,rinseimmediatelywithplentyofwater
andseekmedicaladvice26/28 26/28 Incaseofcontactwithskinoreyes,rinseimmediatelywithplentyofwater
andseekmedicaladvice27 27 Takeoffimmediatelyallcontaminatedclothing27/28 27/28(101) Aftercontactwithskin,takeoffimmediatelyallcontaminatedclothing,
andwashimmediatelywithplentyof1%sodiumbicarbonatesolution27/28 27/28(102) Aftercontactwithskin,takeoffimmediatelyallcontaminatedclothing,
andwashimmediatelywithplentyofwaterandsoap27/28 27/28(103) Aftercontactwithskin,takeoffimmediatelyallcontaminatedclothing,
andwashimmediatelywithplentyofacidsolution(1mlHCl/100mlwater),thenwaterandsoap27/28 27/28(104) Aftercontactwithskin,takeoffimmediatelyallcontaminatedclothing,
andwashimmediatelywithplentyof1%hyposulphitesolution27/28 27/28(105) Aftercontactwithskin,takeoffimmediatelyallcontaminatedclothing,
andwashimmediatelywithplentyofwater27/28 27/28(106) Aftercontactwithskin,takeoffimmediatelyallcontaminatedclothing,
andwashimmediatelywithplentyofwaterlesshandcleaner27/28 27/28(107) Aftercontactwithskin,takeoffimmediatelyallcontaminatedclothing,
andwashimmediatelywithplentyofpolyethyleneglycol/ethanol(1/1solution)28 28(101) Aftercontactwithskin,washimmediately
withplentyof1%sodiumbicarbonatesolution28 28(102) Aftercontactwithskin,washimmediatelywithplentyofwaterandsoap28 28(103) Aftercontactwithskin,washimmediatelywithplentyofacidsolution
(1mlHCl/100mlwater,thenwithwaterandsoap28 28(104) Aftercontactwithskin,washimmediatelywithplentyof1%hyposulphitesolution28 28(105) Aftercontactwithskin,washimmediatelywithplentyofwater28 28(106) Aftercontactwithskin,usewaterlesshandcleaner28 28(107) Aftercontactwithskin,washimmediatelywithpolyethyleneglycol/ethanol(1/1solution)
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EXTRA INFO
SECURITY PHRASES
snumBer codenr text29 29 Donotemptyintodrains29/35 29/35 Donotemptyintodrains,disposeofthismaterialanditscontainerinasafeway29/56 29/56 Donotemptyintodrains,
disposeofthismaterialanditscontainertohazardousorspecialwastecollectionpoint30 30 Neveraddwatertothisproduct33 33 Takeprecautionarymeasuresagainststaticdischarges34 34 Avoidshockandfriction35 35 Thismaterialanditscontainermustbedisposedofinasafeway36 36 Wearsuitableprotectiveclothing36/37 36/37 Wearsuitableprotectiveclothingandgloves36/37/39 36/37/39 Wearsuitableprotectiveclothinggloves,
andeye/faceprotection36/39 36/39 Wearsuitableprotectiveclothingandeye/faceprotection37 37 Wearsuitablegloves37/39 37/39 Wearsuitableglovesandeye/faceprotection38 38 Incaseofinsufficientventilation,wearrespiratoryequipment39 39 Weareye/faceprotection40 40 Tocleanthefloorandallobjectscontaminatedbythismaterial,use....
(tobeindicatedbythemanufacturer)40 40(101) Tocleanthefloorandallobjectscontaminatedbythismaterial,usewhitespirit41 41 Incaseoffireand/orexplosiondonotbreathefumes42 42(101) Duringfumigationwearsuitablerespiratoryequipment42 42(102) Duringsprayingwearsuitablerespiratoryequipment43 43(101) Incaseoffire,usesand43 43(102) Incaseoffire,usepowderextinguisher43 43(103) Incaseoffire,usepowderextinguisher,“neverusewater”43 43(104) Incaseoffire,usesand,“neverusewater”43 43(105) Incaseoffire,usewater43 43(106) Incaseoffire,usewater43 43(107) Incaseoffire,usefoam,drypowderorsand43 43(108) Incaseoffire,allextinguishingmediaallowed44 44 Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible)45 45 Incaseofaccidentorifyoufeelunwell,seekmedicaladviceimmediately
(showthelabelwherepossible)46 46 Ifswallowed,seekmedicaladviceimmediatelyandshowthiscontainerorlabel47 47(101) Keepattemperaturenotexceedingtheflashpoint47 47(102) Keepattemperaturenotexceeding21°C47 47(103) Keepattemperaturenotexceeding15°C47 47(104) Keepattemperaturenotexceeding10°C47 47(105) Keepattemperaturenotexceeding5°C47 47(106) Keepattemperaturenotexceeding0°C47 47(107) Keepattemperaturenotexceeding-15°C47 47(108) Keepattemperaturenotexceeding45°C47 47(109) Keepattemperaturenotexceeding-20°C47/49 47/49(101) Keeponlyintheoriginalcontainerattemperaturenotexceedingtheflashpoint47/49 47/49(102) Keeponlyintheoriginalcontainerattemperaturenotexceeding21°C47/49 47/49(103) Keeponlyintheoriginalcontainerattemperaturenotexceeding15°C47/49 47/49(104) Keeponlyintheoriginalcontainerattemperaturenotexceeding10°C47/49 47/49(105) Keeponlyintheoriginalcontainerattemperaturenotexceeding5°C47/49 47/49(106) Keeponlyintheoriginalcontainerattemperaturenotexceeding0°C47/49 47/49(107) Keeponlyintheoriginalcontainerattemperaturenotexceeding-15°C47/49 47/49(108) Keeponlyintheoriginalcontainerattemperaturenotexceeding45°C47/49 47/49(109) Keeponlyintheoriginalcontainerattemperaturenotexceeding-20°C48 48(101) Keepwettedwithwater48 48(102) Keepwettedwithalcohol48 48(103) Keepwettedwithorganicsolvent48 48(104) Keepwettedwithmineraloil49 49 Keeponlyintheoriginalcontainer50 50(101) Donotmixwithotherproducts50 50(102) Donotmixwithacids50 50(103) Donotmixwithbases50 50(104) Donotmixwithoxidizingagents50 50(105) Donotmixwithreducingagents50 50(106) Donotmixwithorganicmaterials50 50(107) Donotmixwithperoxidationaccelerator50 50(108) Donotmixwithorganicperoxides51 51 Useonlyinwellventilatedarea52 52 Notrecommendedforinterioruseonlargesurfacearea
snumBer codenr text53 53 Avoidexposure-obtainspecialinstructionsbeforeuse54 54 Obtaintheconsentofpollutioncontrolauthoritiesbeforedischarging
towastewatertreatmentplants55 55 Treatusingthebestavailabletechniquesbeforedischargeintodrainsortheaquaticenvironment56 56 Disposeofthismaterialanditscontainertohazardousorspecialwastecollectionpoint57 57 Useappropriatecontainmenttoavoidenvironmentalcontamination58 58 Tobedisposedofashazardouswaste59 59 Refertomanufacturer/supplierforinformationonrecovery/recycling60 60 Thismaterialand/oritscontainermustbedisposedofashazardouswaste61 61 Avoidreleasetotheenvironment.Refertospecialinstructions/safetydatasheets.62 62 Ifswallowed,donotinducevomiting:seekmedicaladviceimmediately
andshowthiscontainerorlabel.63 63 Incaseofaccidentbyinhalation:removecasualtytofreshairandkeepatrest64 64 Ifswallowed,rinsemouthwithwater(onlyifthepersonisconscious)079 079 Keeplampsfilledwiththisliquidoutofthe reachofchildren080 080 Userestrictedtoindustrialinstallations 081 081 Keepawayfromsourcesofignition-No smoking082 082 Keepoutofthereachofchildren.083 083 Warning!Containslead. 084 084 Warning!Containscadmium.Dangerousfumesareformedduringuse.
Seeinformationsuppliedbythemanufacturer085 085 Complywiththesafetyintructions086 086 Containsepoxyconstituents.Seeinformation 087 087 Warning!Donotusetogetherwithother products.
Mayreleasedangerousgases(chlorine).088 088 Restrictedtoprofessionalusers.
Warning!Avoidexposure-obtainspecialinstructionsbeforeuse.089 089 Containsisocyanates.Seeinformationsuppliedbythemanufacturer 090 090 Followthesafetyrules.091 091 Containslead.Shouldnotbeusedonsurfaces liabletobechewedorsuckedbychildren092 092 Cyanoacrylate.Danger.Bondsskinandeyesinseconds.
Keepoutofthereachofchildren.093 093 Reservedforindustrialandprofessionaluse094 094 Pressurizedcontainer.
Protectfromsunlightanddonotexposetotemperaturesexceeding50°C.095 095 Donotpierceorburn,evenafteruse.096 096 Donotsprayonanakedflameoranyincandescentmaterial 097 097 Insuffientdataavailable 098 098099 099 Noavailabledata 100 100 Dependingontheconcentration 101 101 Seeseparatesubstances 102 102 Ecotoxicologicaldatainsufficient 103 103 Noecotoxicologicaldataavailable 104 104 Insufficientdataonchronictoxicity 111 111 DependingontheselectedRphrases 112 112 Ifcompositionisknown,applythepreparations’directive 113 113 CompletewithS-phrases(02),23,24,(62)ifR45expires114 114 CompletewithS-phrases(02),09,16ifR45expires115 115 Dependentonthecomposition 200 200 Warning-substancenotyettestedcompletely 201 201 Warning-thispreparationcontainsasubstancenotyettestedcompletely 301 301 Toavoidriskstomanandtheenvironment,complywiththeinstructionsforuse310 310 Mayproduceanallergicreaction 311 311 Canbecome(highly)flammableinuse 313 313 Safetydatasheetavailableforprofessionaluseronrequest 314 314 Containshexavalentchromium 315 315 Mayproduceanallergicreaction 316 316 ##%bymassofthecontentsareflammable 400 400 Substancenotyettestedcompletelybecauseoflimitedproduction
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EXTRA INFO
DANGER PHRASES
rnumBer codenr text01 01 Explosivewhendry02 02 Riskofexplosionbyshock,friction,fireorothersourcesofignition03 03 Extremeriskofexplosionbyshock,friction,fireorothersourcesofignition04 04 Formsverysensitiveexplosivemetalliccompounds05 05 Heatingmaycauseanexplosion06 06 Explosivewithorwithoutcontactwithair07 07 Maycausefire07 07(O) Maycausefire08 08 Contactwithcombustiblematerialmaycausefire09 09 Explosivewhenmixedwithcombustiblematerial10 10 Flammable10 10(20) Flammable11 11 Highlyflammable12 12 Extremelyflammable12 12(20) Extremelyflammable13 13 Extremelyflammableliquefiedgas14 14 Reactsviolentlywithwater14/15 14/15 Reactsviolentlywithwater,liberatingextremelyflammablegases15 15 Contactwithwaterliberatesextremelyflammablegases15/29 15/29 Contactwithwaterliberatestoxic,extremelyflammablegas16 16 Explosivewhenmixedwithoxidizingsubstances17 17 Spontaneouslyflammableinair18 18 Inuse,mayformflammable/explosivevapour-airmixture19 19 Mayformexplosiveperoxides20 20 Harmfulbyinhalation20 20(2) Alsoharmfulbyinhalation20/21 20/21 Harmfulbyinhalationandincontactwithskin20/21 20/21(2) Alsoharmfulbyinhalationandincontactwithskin20/21/22 20/21/22 Harmfulbyinhalation,incontactwithskinandifswallowed20/21/22 20/21/22(2) Alsoharmfulbyinhalation,incontactwithskinandifswallowed20/22 20/22 Harmfulbyinhalationandifswallowed20/22 20/22(2) Alsoharmfulbyinhalationandifswallowed21 21 Harmfulincontactwithskin21 21(2) Alsoharmfulincontactwithskin21/22 21/22 Harmfulincontactwithskinandifswallowed21/22 21/22(2) Alsoharmfulincontactwithskinandifswallowed22 22 Harmfulifswallowed22 22(2) Alsoharmfulifswallowed23 23 Toxicbyinhalation23 23(2) Alsotoxicbyinhalation23/24 23/24 Toxicbyinhalationandincontactwithskin23/24 23/24(2) Alsotoxicbyinhalationandincontactwithskin23/24/25 23/24/25 Toxicbyinhalation,incontactwithskinandifswallowed23/24/25 23/24/25(2) Alsotoxicbyinhalation,incontactwithskinandifswallowed23/25 23/25 Toxicbyinhalationandifswallowed23/25 23/25(2) Alsotoxicbyinhalationandifswallowed24 24 Toxicincontactwithskin24 24(2) Alsotoxicincontactwithskin24/25 24/25 Toxicincontactwithskinandifswallowed24/25 24/25(2) Alsotoxicincontactwithskinandifswallowed25 25 Toxicifswallowed25 25(2) Alsotoxicifswallowed26 26 Verytoxicbyinhalation26 26(2) Alsoverytoxicbyinhalation26/27 26/27 Verytoxicbyinhalationandincontactwithskin26/27 26/27(2) Alsoverytoxicbyinhalationandincontactwithskin26/27/28 26/27/28 Verytoxicbyinhalation,incontactwithskinandifswallowed26/27/28 26/27/28(2) Alsoverytoxicbyinhalation,incontactwithskinandifswallowed26/28 26/28 Verytoxicbyinhalationandifswallowed26/28 26/28(2) Alsoverytoxicbyinhalationandifswallowed27 27 Verytoxicincontactwithskin27 27(2) Alsoverytoxicincontactwithskin27/28 27/28 Verytoxicincontactwithskinandifswallowed27/28 27/28(2) Alsoverytoxicincontactwithskinandifswallowed28 28 Verytoxicifswallowed28 28(2) Alsoverytoxicifswallowed29 29 Contactwithwaterliberatestoxicgas30 30 Canbecomehighlyflammableinuse
rnumBer codenr text31 31 Contactwithacidsliberatestoxicgases32 32 Contactwithacidsliberatesverytoxicgases33 33 Dangerofcumulativeeffects34 34 Causesburns35 35 Causessevereburns36 36 Irritatingtoeyes36/37 36/37 Irritatingtoeyesandrespiratorysystem36/37/38 36/37/38 Irritatingtoeyes,respiratorysystemandskin36/38 36/38 Irritatingtoeyesandskin37 37 Irritatingtorespiratorysystem37/38 37/38 Irritatingtorespiratorysystemandskin38 38 Irritatingtoskin38 38(30) Irritatingtoskin39 39 Dangerofveryseriousirreversibleeffects39/23 39/23 Toxic:dangerofveryseriousirreversibleeffectsthroughinhalation39/23 39/23(2) Alsotoxic:dangerofveryseriousirreversibleeffectsthroughinhalation39/23/24 39/23/24 Toxic:dangerofveryseriousirreversibleeffectsthroughinhalationandincontactwithskin39/23/24 39/23/24(2) Ookgiftig:gevaarvoorernstigeonherstelbareeffectenbijinademingenaanrakingmetdehuid39/23/24/25 39/23/24/25 Alsotoxic:dangerofveryseriousirreversibleseffectsthroughinhalation, incontactwithskinandifswallowed39/23/24/25 39/23/24/25(2) Alsotoxic:dangerofveryseriousirreversibleeffectsthroughinhalation andincontactwithskin39/23/25 39/23/25 Toxic:dangerofveryseriousirreversibleeffectsthroughinhalation,incontactwithskinandifswallowed39/23/25 39/23/25(2) Alsotoxic:dangerofveryseriousirreversibleeffectsthroughinhalationandifswallowed39/24 39/24 Toxic:dangerofveryseriousirreversibleeffectsincontactwithskin39/24 39/24(2) OAlsotoxic:dangerofveryseriousirreversibleeffectsincontactwithskin39/24/25 39/24/25 Toxic:dangerofveryseriousirreversibleeffectsincontactwithskinandifswallowed39/24/25 39/24/25(2) Alsotoxic:dangerofveryseriousirreversibleeffectsincontactwithskinandifswallowed39/25 39/25 Toxic:dangerofveryseriousirreversibleeffectsifswallowed39/25 39/25(2) Alsotoxic:dangerofveryseriousirreversibleeffectsifswallowed39/26 39/26 Verytoxic:dangerofveryseriousirreversibleeffectsthroughinhalation39/26 39/26(2) Alsoverytoxic:dangerofveryseriousirreversibleeffectsthroughinhalation39/26/27 39/26/27 Verytoxic:dangerofveryseriousirreversibleeffectsthroughinhalationandincontactwithskin39/26/27 39/26/27(2) Alsoverytoxic:dangerofveryseriousirreversibleeffectsthroughinhalationandincontactwithskin39/26/27/28 39/26/27/28 Verytoxic:dangerofveryseriousirreversibleeffectsthroughinhalation, incontactwithskinandifswallowed39/26/27/28 39/26/27/28(2) Alsoverytoxic:dangerofveryseriousirreversibleeffectsthroughinhalation, incontactwithskinandifswallowed39/26/28 39/26/28 Verytoxic:dangerofveryseriousirreversibleeffectsthroughinhalationandandifswallowed39/26/28 39/26/28(2) Alsoverytoxic:dangerofveryseriousirreversibleeffectsthroughinhalationandandifswallowed39/27 39/27 Verytoxic:dangerofveryseriousirreversibleeffectsincontactwithskin39/27 39/27(2) Alsoverytoxic:dangerofveryseriousirreversibleeffectsincontactwithskin39/27/28 39/27/28 Verytoxic:dangerofveryseriousirreversibleeffectsincontactwithskinandifswallowed39/27/28 39/27/28(2) Alsoverytoxic:dangerofveryseriousirreversibleeffectsincontactwithskinandifswallowed39/28 39/28 Verytoxic:dangerofveryseriousirreversibleeffectsifswallowed39/28 39/28(2) Alsoverytoxic:dangerofveryseriousirreversibleeffectsifswallowed40(old) 40 Possiblerisksofirreversibleeffects40/20 40/20 Harmful:possibleriskofirreversibleeffectsthroughinhalation40/20 40/20(2) Alsoharmful:possibleriskofirreversibleeffectsthroughinhalation40/20/21 40/20/21 Harmful:possibleriskofirreversibleeffectsthroughinhalationandincontactwithskin40/20/21 40/20/21(2) Alsoharmful:possibleriskofirreversibleeffectsthroughinhalationandincontactwithskin40/20/21/22 40/20/21/22 Harmful:possibleriskofirreversibleeffectsthroughinhalation,incontactwithskinandifswallowed40/20/21/22 40/20/21/22(2) Alsoharmful:possibleriskofirreversibleseffectsthroughinhalation, incontactwithskinandifswallowed40/20/22 40/20/22 Harmful:possibleriskofirreversibleeffectsthroughinhalationandifswallowed40/20/22 40/20/22(2) Alsoharmful:possibleriskofirreversibleeffectsthroughinhalationandifswallowed40/21 40/21 Harmful:possibleriskofirreversibleeffectsincontactwithskin40/21 40/21(2) Alsoharmful:possibleriskofirreversibleeffectsincontactwithskin40/21/22 40/21/22 Harmful:possibleriskofirreversibleeffectsincontactwithskinandifswallowed40/21/22 40/21/22(2) Alsoharmful:possibleriskofirreversibleeffectsincontactwithskinandifswallowed40/22 40/22 Harmful:possibleriskofirreversibleeffectsifswallowed40/22 40/22(2) Alsoharmful:possibleriskofirreversibleeffectsifswallowed40 40A Limitedevidenceofacarcinogeniceffect41 41 Riskofseriousdamagetoeyes42 42 Maycausesensitisationbyinhalation42/43 42/43 Maycausesensitisationbyinhalationandskincontact43 43 Maycausesensitisationbyskincontact44 44 Riskofexplosionifheatedunderconfinement
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EXTRA INFO
DANGER PHRASES
rnumBer codenr text45 45 Maycausecancer45 45(10) Maycausecancer45 45(10)(11)(17) Maycausecancer45 45(10)(12) Maycausecancer45 45(10)(13) Maycausecancer45 45(11)(15) Maycausecancer45 45(13)(15) Maycausecancer45 45(14)(15) Maycausecancer45 45(16) Maycausecancer46 46 Maycauseheritablegeneticdamage46 46(80) Maycauseheritablegeneticdamage46 46(81) Maycauseheritablegeneticdamage47 47 Maycausebirthdefects48 48 Dangerofseriousdamagetohealthbyprolongedexposure48/20 48/20 Harmful:dangerofseriousdamagetohealthbyprolongedexposurethroughinhalation48/20 48/20(2) Alsoharmful:dangerofseriousdamagetohealthbyprolongedexposurethroughinhalation48/20/21 48/20/21 Harmful:dangerofseriousdamagetohealth byprolongedexposurethroughinhalationandincontactwithskin48/20/21 48/20/21(2) Alsoharmful:dangerofseriousdamagetohealth byprolongedexposurethroughinhalationandincontactwithskin48/20/21/22 48/20/21/22 Harmful:dangerofseriousdamagetohealth byprolongedexposurethroughinhalation,contactwithskinandifswallowed48/20/21/22 48/20/21/22(2) Alsoharmful:dangerofseriousdamagetohealth byprolongedexposurethroughinhalation,contactwithskinandifswallowed48/20/22 48/20/22 Harmful:dangerofseriousdamagetohealth byprolongedexposurethroughinhalationandifswallowed48/20/22 48/20/22(2) Alsoharmful:dangerofseriousdamagetohealth byprolongedexposurethroughinhalationandifswallowed48/21 48/21 Harmful:dangerofseriousdamagetohealthbyprolongedexposureincontactwithskin48/21 48/21(2) Alsoharmful:dangerofseriousdamagetohealthbyprolongedexposureincontactwithskin48/21/22 48/21/22 Harmful:dangerofseriousdamagetohealth byprolongedexposureincontactwithskinandifswallowed48/21/22 48/21/22(2) Alsoharmful:dangerofseriousdamagetohealth byprolongedexposureincontactwithskinandifswallowed48/22 48/22 Harmful:dangerofseriousdamagetohealth byprolongedexposureifswallowed48/22 48/22(2) Alsoharmful:dangerofseriousdamagetohealth byprolongedexposureifswallowed48/23 48/23 Toxic:dangerofseriousdamagetohealthbyprolongedexposurethroughinhalation48/23 48/23(2) Alsotoxic:dangerofseriousdamagetohealthbyprolongedexposurethroughinhalation48/23/24 48/23/24 Toxic:dangerofseriousdamagetohealth byprolongedexposurethroughinhalationandincontactwithskin48/23/24 48/23/24(2) Alsotoxic:dangerofseriousdamagetohealth byprolongedexposurethroughinhalationandincontactwithskin48/23/24/25 48/23/24/25 Toxic:dangerofseriousdamagetohealth byprolongedexposurethroughinhalation,incontactwithskinandifswallowed48/23/24/25 48/23/24/25(2) Alsotoxic:dangerofseriousdamagetohealth byprolongedexposurethroughinhalation,incontactwithskinandifswallowed48/23/25 48/23/25 Toxic:dangerofseriousdamagetohealth byprolongedexposurethroughinhalationandifswallowed48/23/25 48/23/25(2) Alsotoxic:dangerofseriousdamagetohealth byprolongedexposurethroughinhalationandifswallowed48/24 48/24 Toxic:dangerofseriousdamagetohealthbyprolongedexposureincontactwithskin48/24 48/24(2) Alsotoxic:dangerofseriousdamagetohealth byprolongedexposureincontactwithskin48/24/25 48/24/25 Toxic:dangerofseriousdamagetohealth byprolongedexposureincontactwithskinandifswallowed48/24/25 48/24/25(2) Alsotoxic:dangerofseriousdamagetohealth byprolongedexposureincontactwithskinandifswallowed48/25 48/25 Toxic:dangerofseriousdamagetohealthbyprolongedexposureifswallowed48/25 48/25(2) Alsotoxic:dangerofseriousdamagetohealthbyprolongedexposureifswallowed49 49 Maycausecancerbyinhalation50 50 Verytoxictoaquaticorganisms50/53 50/53 Verytoxictoaquaticorganisms, maycauselong-termadverseeffectsintheaquaticenvironment50/53 50/53(2) Verytoxictoaquaticorganisms.Containssubstanceswhicharedangerousfortheaquaticenvironment51 51 Toxictoaquaticorganisms51/53 51/53 Toxictoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironment
rnumBer codenr text51/53 51/53(2) Toxictoaquaticorganisms.Containssubstanceswhicharedangerousfortheaquaticenvironment51/53 51/53(40) Toxictoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironment52 52 Harmfultoaquaticorganisms52/53 52/53 Harmfultoaquaticorganisms, maycauselong-termadverseeffectsintheaquaticenvironment52/53 52/53(2) Harmfultoaquaticorganisms.Containssubstanceswhicharedangerousfortheaquaticenvironment53 53 Maycauselong-termadverseeffectsintheaquaticenvironment53 53(2) Containssubstanceswhichmaybedangerousaquaticenvironment53 53(41) Maycauselong-termadverseeffectsintheaquaticenvironment54 54 Toxictoflora55 55 Toxictofauna56 56 Toxictosoilorganisms57 57 Toxictobees58 58 Maycauselong-termadverseeffectsintheenvironment59 59 Dangerousfortheozonelayer59 59(2) Containssubstanceswhichdepletetheozonelayer60 60 Mayimpairfertility61 61 Maycauseharmtotheunbornchild62 62 Possibleriskofimpairedfertility63 63 Possibleriskofharmtotheunbornchild63 63(90) Possibleriskofharmtotheunbornchild64 64 Maycauseharmtobreastfedbabies65 65 Harmful:maycauselungdamageifswallowed65 65(2) Alsoharmful:maycauselungdamageifswallowed65 65(2)(50) Harmful:maycauselungdamageifswallowed65 65(50) Harmful:maycauselungdamageifswallowed65 65(50)(51) Harmful:maycauselungdamageifswallowed65 65(51) Harmful:maycauselungdamageifswallowed66 66 Repeatedexposuremaycauseskindrynessorcracking66 66(60) Repeatedexposuremaycauseskindrynessorcracking66 66(61) Repeatedexposuremaycauseskindrynessorcracking67 67 Vapoursmaycausedrowsinessanddizziness67 67(70) Vapoursmaycausedrowsinessanddizziness68 68 Possibleriskofirreversibleeffects68/20 68/20 Harmful:possibleriskofirreversibleeffectthroughinhalation68/20 68/20(2) Alsoharmful:possibleriskofirreversibleeffectsthroughinhalation68/20/21 68/20/21 Harmful:possibleriskofirreversibleeffectsthroughinhalationandincontactwithskin68/20/21 68/20/21(2) Alsoharmful:possibleriskofirreversibleeffectsthroughinhalationandincontactwithskin68/20/21/22 68/20/21/22 Harmful:possibleriskofirreversibleeffectsthroughinhalation,incontactwithskinandifswallowed68/20/21/22 68/20/21/22(2) Alsoharmful:possibleriskofirreversibleeffectsthroughinhalation,incontactwithskinandifswallowed68/20/22 68/20/22 Harmful:possibleriskofirreversibleeffectsthroughinhalationandifswallowed68/20/22 68/20/22(2) Alsoharmful:possibleriskofirreversibleeffectsthroughinhalationandifswallowed68/21 68/21 Harmful:possibleriskofirreversibleeffectsincontactwithskin68/21 68/21(2) Alsoharmful:possibleriskofirreversibleeffectsincontactwithskin68/21/22 68/21/22 Harmful:possibleriskofirreversibleeffectsincontactwithskinandifswallowed68/21/22 68/21/22(2) Alsoharmful:possibleriskofirreversibleeffectsincontactwithskinandifswallowed68/22 68/22 Harmful:possibleriskofirreversibleeffectifswallowed68/22 68/22(2) Alsoharmful:possibleriskofirreversibleeffectsifswallowed090 090 Inhalationofasbestosdustisharmfultohealth097 097 Insuffientdataavailable 098 098099 099 Noavailabledata 100 100 Dependingontheconcentration 101 101 Seeseparatesubstances 102 102 Ecotoxicologicaldatainsufficient 112 112 Assignmentonacase-by-casebasis 115 115 Dependentonthecomposition 198 198 Notclassifiedasdangerousaccordingtothecriteriaofdirective(s)67/548/EECand/or1999/45/EC 298 298 ClassifieddangerousinaccordancewithDirectives67/548/EECand1999/45/EC299 299 Innormalconditionsofuse,thecomponentscannotbereleasedbecauseof theforminwhichthearticleorpreparationisplacedonthemarket 398 398 ClassifieddangerousinaccordancewithDirective67/548/EEC399 399 Innormalconditionsofuse,thesubstancecannotbereleasedbecauseof theforminwhichtheproductisplacedonthemarket498 498 TheclassificationincategoriesofdangerincompliancewithDirective67/548/EECand1999/45/EC doesnotapplytopharmaceuticals 598 598 TheclassificationincategoriesofdangerincompliancewithDirective67/548/EECand1999/45/EC doesnotapplytocosmeticproducts
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EXTRA INFO
GHS
Serious damage to health
Corrosive Oxidant
Explosive Toxic
Flammable Gas under pressure
Dangerous for the environment
Less serious damage to health
Globally Harmonised Systemof classification and labelling
of chemicals
GHS or Globally Harmonised System of Classification and Labelling of Chemicals is the new way of classifying, characterising and labelling chemical substances and preparations.
Depending on the associated dangers, a substance or mixture of substances is divided into one or more categories of dangers. There are three different categories of dangers:
• Physical dangers (e.g. explosive, flammable, oxidant)• Health dangers (e.g. toxic, carcinogenic)• Dangers to the environment (e.g. toxic for water organisms)
The motivation for reaching an internationally clear system is logical. After all, the differences per country in the designations and information relating to dangerous substances were quite big occasionally. The same substance could be labelled as ‘toxic’ in one country, but not be viewed as a dangerous substance in a different country. This also led to absences of clarity in safety information sheets and companies had to produce different safety information sheets for different parts of the world.
The introduction of a globally harmonised system (GHS) should eliminate these obstacles to world trade.
The draft regulation proposes the phased introduction of GHS:
• the current system will be retained for substances until 1 December 2010; for mixtures
and preparations it will be kept until 1 June 2015. The GHS label can be used sooner on a voluntary basis.
• substances will be classified according to both systems between 1 December 2010 and 1 June 2015 but the GHS label is obligatory.
• the current classification and labelling system expires from 1 June 2015 and only the GHS system will be valid.
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EXTRA INFO
H2001 Unstableexplosives.H201 Explosive;massexplosionhazard.H202 Explosive,severeprojectionhazard.H203 Explosive;fire,blastorprojectionhazard.H204 Fireorprojectionhazard.H205 Maymassexplodeinfire.H220 Extremelyflammablegas.H221 Flammablegas.H222 Extremelyflammableaerosol.H223 Flammableaerosol.H224 Extremelyflammableliquidandvapour.H225 Highlyflammableliquidandvapour.H226 Flammableliquidandvapour.H228 Flammablesolid.H240 Heatingmaycauseanexplosion.H241 Heatingmaycauseafireorexplosion.H242 Heatingmaycauseafire.H250 Catchesfirespontaneouslyifexposedtoair.H251 Self-heating:maycatchfire.H252 Self-heatinginlargequantities;maycatchfire.H260 Incontactwithwaterreleasesflammablegaseswhichmayignitespontaneously.H261 Incontactwithwaterreleasesflammablegases.H270 Maycauseorintensifyfire;oxidiser.H271 Maycausefireorexplosion;strongoxidiser.H272 Mayintensifyfire;oxidiser.H280 Containsgasunderpressure;mayexplodeifheated.H281 Containsrefrigeratedgas;maycausecryogenicburnsorinjury.H290 Maybecorrosivetometals.H300 Fatalifswallowed.H301 Toxicifswallowed.H302 Harmfulifswallowed.H304 Maybefatalifswallowedandentersairways.H310 Fatalincontactwithskin.H311 Toxicincontactwithskin.H312 Harmfulincontactwithskin.H314 Causessevereskinburnsandeyedamage.H315 Causesskinirritation.H317 Maycauseanallergicskinreaction.H318 Causesseriouseyedamage.H319 Causesseriouseyeirritation.H330 Fatalifinhaled.H331 Toxicifinhaled.H332 Harmfulifinhaled.H334 Maycauseallergyorasthmasymptomsorbreathingdifficultiesifinhaled.H335 Maycauserespiratoryirritation.H336 Maycausedrowsinessordizziness.H340 Maycausegeneticdefects(staterouteofexposureifitisconclusivelyproventhatnootherroutes ofexposurecausethehazard).H341 Suspectedofcausinggeneticdefects(staterouteofexposureifitisconclusivelyproven thatnootherroutesofexposurecausethehazard).H350 Maycausecancer(staterouteofexposureifitisconclusivelyproventhatnootherroutes ofexposurecausethehazard).H351 Suspectedofcausingcancer(staterouteofexposureifitisconclusivelyproventhatnootherrouts ofexposurecausethehazard).H360 Maydamagefertilityortheunbornchild (statespecificeffectifknown) (staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard).H361 Suspectedofdamagingfertilityortheunbornchild(statespecificeffectifknown)(staterouteofexposure ifitisconclusivelyproventhatnootherroutesofexposurecausethehazard).H362 Maycauseharmtobreast-fedchildren.H370 Causesdamagetoorgans(orstateallorgansaffected,ifknown)(staterouteofexposure ifitisconclusivelyproventhatnootherroutesofexposurecausethehazard).H371 Maycausedamagetoorgans(orstateallorgansaffected,ifknown)(staterouteofexposure ifitisconclusivelyproventhatnootherroutesofexposurecausethehazard).H372 Causesdamagetoorgans(orstateallorgansaffected,ifknown) throughprolongedorrepeatedexposure (staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard).H373 Maycausedamagetoorgans(orstateallorgansaffected,ifknown) throughprolongedorrepeatedexposure (staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard).H400 Verytoxictoaquaticlife.H410 Verytoxictoaquaticlifewithlonglastingeffects.H411 Toxictoaquaticlifewithlonglastingeffects.H412 Harmfultoaquaticlifewithlonglastingeffects.H413 Maycauselonglastingharmfuleffectstoaquaticlife.
EUH001 Explosivewhendry.EUH006 Explosivewithorwithoutcontactwithair.EUH014 Reactsviolentlywithwater.EUH018 Inusemayformflammable/explosivevapour-airmixture.EUH019 Mayformexplosiveperoxides.EUH044 Riskofexplosionifheatedunderconfinement.
EUH029 Contactwithwaterliberatestoxicgas.EUH031 Contactwithacidsliberatestoxicgas.EUH032 Contactwithacidsliberatesverytoxicgas.EUH066 Repeatedexposuremaycauseskindrynessorcracking.EUH070 Toxicbyeyecontact.EUH071 Corrosivetotherespiratorytract.
EUH059 Hazardoustotheozonelayer.
EUH201/201A Containslead.Shouldnotbeusedonsurfacesliabletobechewedorsuckedbychildren. Warning!Containslead.EUH202 Cyanoacrylate.Danger.Bondsskinandeyesinseconds. Keepoutofthereachofchildren.EUH203 Containschromium(VI).Mayproduceanallergicreaction.EUH204 Containsisocyanates.Mayproduceanallergicreaction.EUH205 Containsepoxyconstituents.Mayproduceanallergicreaction.EUH206 Warning!Donotusetogetherwithotherproducts.Mayreleasedangerousgases(chlorine).EUH207 Warning!Containscadmium.Dangerousfumesareformedduringuse. Seeinformationsuppliedbythemanufacturer.Complywiththesafetyinstructions.EUH208 Contains(nameofsensitisingsubstance).Mayproduceanallergicreaction.EUH209/209A Canbecomehighlyflammableinuse.Canbecomeflammableinuse.EUH210 Safetydatasheetavailableonrequest.
EUH401 Toavoidriskstohumanhealthandtheenvironment,complywiththeinstructionsforuse.
GHS
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EXTRA INFO
P101 Ifmedicaladviceisneeded,haveproductcontainerorlabelathand.P102 Keepoutofreachofchildren.P103 Readlabelbeforeuse.
P201 Obtainspecialinstructionsbeforeuse.P202 Donothandleuntilallsafetyprecautionshavebeenreadandunderstood.P210 Keepawayfromheat/sparks/openflames/hotsurfaces.–Nosmoking.P211 Donotsprayonanopenflameorotherignitionsource.P220 Keep/Storeawayfromclothing/…/combustiblematerials.P221 Takeanyprecautiontoavoidmixingwithcombustibles…P222 Donotallowcontactwithair.P223 Keepawayfromanypossiblecontactwithwater,becauseofviolentreactionandpossibleflashfire.P230 Keepwettedwith…P231 Handleunderinertgas.P231+P232 Handleunderinertgas.Protectfrommoisture.P232 Protectfrommoisture.P233 Keepcontainertightlyclosed.P234 Keeponlyinoriginalcontainer.P235 Keepcool.P235+P410 Keepcool.Protectfromsunlight.P240 Ground/bondcontainerandreceivingequipment.P241 Useexplosion-proofelectrical/ventilating/lighting/…/equipment.P242 Useonlynon-sparkingtools.P243 Takeprecautionarymeasuresagainststaticdischarge.P244 Keepreductionvalvesfreefromgreaseandoil.P250 Donotsubjecttogrinding/shock/…/friction.P251 Pressurizedcontainer:Donotpierceorburn,evenafteruse.P260 Donotbreathedust/fume/gas/mist/vapours/spray.P261 Avoidbreathingdust/fume/gas/mist/vapours/spray.P262 Donotgetineyes,onskin,oronclothing.P263 Avoidcontactduringpregnancy/whilenursing.P264 Wash…thoroughlyafterhandling.P270 Donoeat,drinkorsmokewhenusingthisproduct.P271 Useonlyoutdoorsorinawell-ventilatedarea.P272 Contaminatedworkclothingshouldnotbeallowedoutoftheworkplace.P273 Avoidreleasetotheenvironment.P280 Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.P280 Usepersonalprotectiveequipmentasrequired.P282 Wearcoldinsulatinggloves/faceshield/eyeprotection.P283 Wearfire/flameresistant/retardantclothing.P284 Wearrespiratoryprotection.P285 Incaseofinadequateventilationwearrespiratoryprotection.
P301 IFswallowed:P301+P310 IFSWALLOWED:ImmediatelycallaPOISONCENTERordoctor/physician.P301+P312 IFSWALLOWED:CallaPOISONCENTERordoctor/physicianifyoufeelunwell.P301+P330+P331 IFSWALLOWED:rinsemouth.DoNOTinducevomiting.P302 IFonskin:P302+P334 IFONSKIN:Immerseincoolwater/wrapinwetbandages.P302+P350 IFONSKIN:Gentlywashwithplentyofsoapandwater.P302+P352 IFONSKIN:Washwithplentyofsoapandwater.P303 IFonskin(orhair):P303+P361+P353 IFONSKIN(orhair):Remove/Takeoffimmediatelyallcontaminatedclothing. Rinseskinwithwater/shower.P304 IFinhaled:P304+P340 IFINHALED:Removevictimtofreshair andkeepatrestinapositioncomfortableforbreathing.P304+P341 IFINHALED:Ifbreathingisdifficult,removevictimtofreshairandkeepatrest inapositioncomfortableforbreathing.P305 Ifineyes:P305+P351+P338 IFINEYES:Rinsecautiouslywithwaterforseveralminutes. Removecontactlenses,ifpresentandeasytodo.Continuerinsing.P306 IFonclothing:P306+P360 IFONCLOTHING:rinseimmediatelycontaminatedclothingandskin withplentyofwaterbeforeremovingclothes.P307 IFexposed:P307+P311 IFexposed:CallaPOISONCENTERordoctor/physician.P308 IFexposedorconcerned:P308+P313 IFexposedorconcerned:Getmedicaladvice/attention.P309 IFexposedorifyoufeelunwell:P309+P311 IFexposedorifyoufeelunwell:CallaPOISONCENTERordoctor/physician.P310 ImmediatelycallaPOISONCENTERordoctor/physician.P311 CallaPOISONCENTERordoctor/physician.P312 CallaPOISONCENTERordoctor/physicianifyoufeelunwell.P313 Getmedicaladvice/attention.
P314 Getmedicaladvice/attentionifyoufeelunwell.P315 Getimmediatemedicaladvice/attention.
P320 Specifictreatmentisurgent(see…onthislabel).P321 Specifictreatment(see…onthislabel).P322 Specificmeasures(see…onthislabel).P330 Rinsemouth.P331 DoNOTinducevomiting.P332 Ifskinirritationoccurs:P332+P313 Ifskinirritationoccurs:Getmedicaladvice/attention.P333 Ifskinirritationorrashoccurs:P333+P313 Ifskinirritationorrashoccurs:Getmedicaladvice/attention.P334 Immerseincoolwater/wrapinwetbandages.P335 Brushofflooseparticlesfromskin.P335+P334 Brushofflooseparticlesfromskin.Immerseincoolwater/wrapinwetbandages.P336 Thawfrostedpartswithlukewarmwater.Donorubaffectedarea.P337 Ifeyeirritationpersists:P337+P313 Ifeyeirritationpersists:Getmedicaladvice/attention.P338 Removecontactlenses,ifpresentandeasytodo.Continuerinsing.P340 Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.P341 Ifbreathingisdifficult,removevictimtofreshair andkeepatrestinapositioncomfortableforbreathing.P342 Ifexperiencingrespiratorysymptoms:P342+P311 Ifexperiencingrespiratorysymptoms:CallaPOISONCENTERordoctor/physician.P350 Gentlywashwithplentyofsoapandwater.P351 Rinsecautiouslywithwaterforseveralminutes.P352 Washwithplentyofsoapandwater.P353 Rinseskinwithwater/shower.P360 Rinseimmediatelycontaminatedclothingandskinwithplentyofwaterbeforeremovingclothes.P361 Remove/Takeoffimmediatelyallcontaminatedclothing.P362 Takeoffcontaminatedclothingandwashbeforereuse.P363 Washcontaminatedclothingbeforereuse.P370 Incaseoffire:P370+P376 Incaseoffire:Stopleakifsafetodoso.P370+P378 Incaseoffire:Use…forextinction.P370+P380 Incaseoffire:Evacuatearea.P370+P380+P375 Incaseoffire:Evacuatearea.Fightfireremotelyduetotheriskofexplosion.P371 Incaseofmajorfireandlargequantities:P371+P380+P375 Incaseofmajorfireandlargequantities:Evacuatearea. Fightfireremotelyduetotheriskofexplosion.P372 Explosionriskincaseoffire.P373 DONOTfightfirewhenfirereachesexplosives.P374 Fightfirewithnormalprecautionsfromareasonabledistance.P375 Fightfireremotelyduetotheriskofexplosion.P376 Stopleakifsafetodoso.P377 Leakinggasfire:Donotextinguish,unlessleakcanbestoppedsafely.P378 Use…forextinction.P380 Evacuatearea.P381 Eliminateallignitionsourcesifsafetodoso.P390 Absorbspillagetopreventmaterialdamage.P391 Collectspillage.
P401 Store…P402 Storeinadryplace.P402+P404 Storeinadryplace.Storeinaclosedcontainer.P403 Storeinawell-ventilatedplace.P403+P233 Storeinawell-ventilatedplace.Keepcontainertightlyclosed.P403+P235 Storeinawell-ventilatedplace.Keepcool.P404 Storeinaclosedcontainer.P405 Storelockedup.P406 Storeincorrosiveresistant/…containerwitharesistantinnerliner.P407 Maintainairgapbetweenstacks/pallets.P410 Protectfromsunlight.P410+P403 Protectfromsunlight.Storeinawell-ventilatedplace.P410+P412 Protectfromsunlight.Donoexposetotemperaturesexceeding50°C/122°F.P411 Storeattemperaturesnotexceeding…°C/…°F.P411+P235 Storeattemperaturesnotexceeding…°C/…°F.Keepcool.P412 Donotexposetotemperaturesexceeding50°C/122°F.P413 Storebulkmassesgreaterthan…kg/…lbsattemperaturesnotexceeding…°C/…°F.P420 Storeawayfromothermaterials.P422 Storecontentsunder…
P501 Disposeofcontents/containerto…
GHS
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EXTRA INFO
MISCELLANEOUS
Surface calculation Name Figuur Formula for circumference Formula for surface area
Triangle O = sum of the sidess = b . h 2
Trapezoid O = sum of the sidess = (B + b) . h 2
Parallellogram O = 2 . (b + s) s = b . h
Rhombus O = 4 . zs = D . d 2
Rectangle O = 2 . (l + b) s = l . b
Square O = 4 . z s = z2
Circle O = 2 . π . r s = π . r2
The 3 rule We frequently compare two quantities with each other. When one quantity gets bigger, the other also increases.When one quanttity gets smaller, the other quantity also decreases.Example:A box of nails contains 75 nails and costs € 10. How much do 90 nails cost?Such questions can be solved by using the 3 rule.75 nails ====> € 101 nail ====> € 10 : 7590 nails ====> € 10 : 75 x 90 = 12Answer: you pay € 12 for 12 nails.
Consumption for spraying a joint Width of the joint or diameter of spraying nozzle (mm) x depth of the joint (mm) = ml joint cement/running metre
ml content of cartridge
Consumption of epoxy mortar CALCULATION PRINCIPLEAlways calculate the volume in dm3 and multiply by 2 (the specific gravity or density of epoxy mortar is always 2kg/dm3)
e.g.: Fill a groove that is 3 m long, 8 mm deep and 12 cm wide with epoxy mortarStep 1:Convert eveything into dm 3 metres = 30 decimetres 8 millimetres = 0.08 decimetre 12 centimetres = 1.2 decimetreStep 2:calculate the volume: 30 dm x 0.08 dm x 1.2 dm = 2.88 dm3
Step 3:convert this into the quantity of product: 2.88 dm3 x 2 kg/dm3 = 5.76 kg
RULE OF THUMBConsumption per m2 per mm of thickness = 2 kg/m2/mm
This is done according to the calculation:100 dm2 (=1m2) x 0.01 dm (=1mm) x 2 kg/dm3 (density) = 2 kg/mm
e.g.: treating a 10 m2 surface area with 6 mm epoxy mortar entails consumption of:6mm x 2 kg/m2 = 12 kg/m2
12 kg/m2 x 10 m2 = 120 kg
It is therefore simple to multiply the number of mm by 2 to find out the consumption per m2.
r
z
b
dz
D
s
b
h
h
b
b
B
h
l
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EXTRA INFO
Calculation of content Name Figure Formula for circumference
Bar
The surface area of the floor of this bar is 2 cm x 1 cm =2 cm2
The height is 3 cm
The content of this bar is:2 cm x 1 cm x 3 cm = 6 cm3
Cube
The surface area of the floor of this cube is 3 cm x 3 cm = 9 cm2
The height is also 3 cm
The content of this cube is:3 cm x 3 cm x 3 cm = 27 cm3
Cylinder
The surface of the floor of this cylinder isradius x radius x pi =1.5cm x 1.5 cm x pi = 7.07 cm2
The height of this cylinder is 4 cm
The content of this cylinder is:1.5 cm x 1.5 cm x pi x 4 cm = 28.27 cm3
Pyramid
The content of a pyramid and cone is:The surface of the floor multiplied by the height:3 Abbreviated: B x H : 3 or B x H 3
The surface of the rectangular floor is: 4cm x 3 cm = 12 cm2
The height of the pyramid is 6 cm
The content of this pyramid is:4 cm x 3 cm x 6 cm : 3 = 24 cm3
Cone
The surface area of the circle is:radius x radius x pi = 2cm x 2 cm x pi = 12,57 cm2
The height of the cone is 3 cm
The content of the cone is:2 cm x 2 cm x pi x 3 cm : 3 = 12,57 cm3
Prism
You also calculate the content of a prism by:base multiplied by height.With this prism it is best to take the triangular front as the base (floor) because it has the shape of the flat surfaces that you can cut away.
The surface of the base is:4 cm x 3 cm : 2 = 6 cm2
The height of the figure is 2 cm.
The content of this prism is:4 cm x 3 cm : 2 x 2 cm = 12 cm3
MISCELLANEOUS
In general, the content of a figure is:The surface area of the floor multiplied by the height. This is also written as B&H. Where B is the surface of the base area and H is the height of the figure. The base is the floor of a figure.
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EXTRA INFO
Density kg/dm3, kg/m2, kg/l
Boiling point °C
Viscosity mPa’s Bsmokefield 20°C.
Specific gravit g/mm3, kg/dm3, g/cm3
Flash point °C
Temperature resistance °C
Thermal stability °C
Dielectric strength KV/mm
Specific resistance Ohm/mm
Compactness [density] g/m3, g/cm3
Tensile strength N/cm2, N/mm2
Shear strength N/mm2, N/cm2
pH value pH
Hardening time minute
Apparent compactness of g/l
Heat conductivity capacity W/mk (thermal conductivity)
Fire resistance classification B1, B2, B3
Noise dampening db
Peel force N/cm
E-modulus N/mm2
Non-volatile matter %
Pressure resistance N/mm2
Flexible tensile strength N/mm2
Electrical resistance Ohm, Ohm/cm
Hardening through hours
Test method TFM 9 N/mm2 (see DOT)
Tensile force (FTM 1) N/mm2 (see DOT) ,kg/cm2 (see HCS)
Peel force (FTM 1) N/mm2 (see DOT)
Shear strength kg/mm2, kg/cm2
Shear strength minutes/seconds
Initial reaction time minutes
Loss of tension V
Connection resistance Ohm
Insulation resistance Ohm
Disruptive discharge voltage V
Melting point °C
Self ignition °C
Drying time minutes
Evaporation time seconds
Dripping point °C
relative humidity RV
Dynamic tear-off force g/cm
Solidification point °C
Impact strength KJ/m2
Open working time minutes at °C
Hand-tight hours at °C
Shore hardness A, D
Water absorption %
Potlife minutes
Tear strength N/mm2
Notched bar test cm/kg/cm2
Ignition temperature °C
Salt haze test hours (ASTM B117 at Metalsol)
Lubricating capacity kg (Falex Step test at MC5)
Mass volume g/ml
Active components % (see BIL)
Steam reduction %
Elasticity at breakage (after...days at...?C) %
Elasticity %
VOS content %
Freezing point °C
Elastic strength %
Four Ball Test (IP-239) N/cm2
4 Ball EP-Test (ASTMD 25%) kgf
4 Ball Wear-Test (ASTMD 2266) WIM
Rolling Bali Tack Test method GB7125-84
Term Unit used Term Unit used
TERMS AND ABBREVIATIONS USED IN THIS CATALOGUE