Evaluation of Wintertime CO and NOx Emissions Inventories ...
Transcript of Evaluation of Wintertime CO and NOx Emissions Inventories ...
EvaluationofWintertimeCOandNOxEmissionsInventoriesfromtheTreasureValleyPM2.5
PrecursorStudyH.W.Wallace,M.H.Erickson,J.Vaughan,J.K.McCoskey,B.K.Lamb,B.T.Jobson
NW‐AIRQUESTAnnualMeetingApril1,2010
TreasureValleyPM2.5PrecursorStudy Goal:Tocharacterizeatmospheric
PM2.5,precursorgases,andtherelevantmeteorologyduringtypicalwintertimeconditions.
TwomonthstudyinBoise,ID. Dec.2008‐Jan.2009
Success! >90%Datacompletenessforall
buttwoinstruments. Sampledasignificantwintertime
stagnationevent.
SiteOverview
MACLLocation
ThesiteisborderedonthesouthbyI‐84.DowntownBoiseisapproximately7milestotheeastandSt.Luke’sMeridianMedicalCenterislocatedimmediatelywestofthesite.
Aerosol
ParticleSizeDistributionnanoSMPS(3‐60nm)(Assembledinhouse
withTSIcomponents)longSMPS(40‐700nm)(Assembledin
housewithTSIcomponents)APS(0.6‐20um)(TSI)
BulkSolubleCompositionParticle‐Into‐LiquidSampler–PILS
(Brechtel)Inorganics(SO4,NO3,Cl,NH4,Na,Mg,...)
byIonChromatography(Metrohm‐Peak)WatersolubleorganiccarbonbyTOC
analysis(Sievers/GEAnalytical)
CloudCondensationNuclei(DMT)AerosolSpatialVariabilityandOptical
Depth(LeosphereAerosolLidar)
Meteorology
P,T,RH,Windspeed&direction,Precip(VaisalaWXT)
BoundaryLayerHeight(LeosphereAerosolLidar)
TraceGases
Ozone(Dasibi)CarbonMonoxide(Aerolaser)NOx/NOy(AirQualityDesign)SO2(Teledyne)TimeResolvedVOCs(PTR‐MS,Ionicon)SpeciatedVOCs(notdeployedinBoise)
VarianGC‐MSCustom2‐channelVOCpreconcentrator
MACLInstrumentation
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WindRosePlot:
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10Wind Speed 2 min average, (m/s)
WXT 2 Minute Average
WindSpeedLogHistogram:
BoiseWinds
DiurnalAverageProfileofPBLHeightandAerosolOpticalDepth,Dec‐Jan
NormalizedresidencetimeforTreasureValleyairmasses10meterheight 50meterheight
GraphicscourtesyofIliasKavourasofTheDesertResearchInstituteandIdahoDepartmentofEnvironmentalQuality.
UsehighresolutionCOandNOxobservationstoevaluateemissions
•Parishetal.(2006)comparedmeasuredratiosofCOtoNOxtoemissionsinventories.
•MeasuredCOtoNOxratiosaremuchlowerthanemissionsinventories.
•WhatisthesituationinBoise?
TimeseriesofCOandNOxduringJanuary2009
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Ben
zene
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uene
, C2-
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zene
s, (
nmol
/mol
)
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x, (nmol/m
ol)
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ol/m
ol)
Diel CO Diel NOx Diel Benzene Diel Toluene
DiurnalconcentrationsofautomobileexhausttracersandNOx
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CO, (nmol/mol) NOx, (nmol/mol)
•COandNOxlevelsdisplayedlittlewinddirectiondependence.•CO/NOxratioswerealsonotdependentonwinddirection
ObservedCOvs.NOxratiofortheentiremonitoringperiod(90sdata)
ObservedCOvs.NOxratioduringmorningrushhour(5:00amto9:00am)
DielvariationofΔCO/ΔNOxfromDec2,2008toJan31,2009
EmissionsgeneratedforAIRPACT‐3
•76%COemissionsmobile•57%NOxemissionsmobile
MeasurementandAIRPACT‐3resultsforJanuary2009
AIRPACT‐3TotalEmissions
AIRPACT‐3MobileEmissions
Measuredmixingratios
AIRPACT‐3mixingratios
HistogramofAIRPACT‐3andmeasuredCOmixingratios
HistogramofAIRPACT‐3andmeasuredNOxmixingratios
Source ΔCO/ΔNOxMeasurement (mol/mol)
Entirecampaignhighres. 4.6Rushhourhighres. 4.0Rushhourmedian 3.6
Entirecampaign1hravg. 4.6IDEQ1hr 3.3Model
Mixingratioresults 13.8Mobileemissions 18.9TotalEmissions 14.4
EmissionsRatioSummary:
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2.0
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1.0
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Ben
zene
, (nm
ol/m
ol)
12001000800600400200CO, (nmol/mol)
SLOPE=0.0013 ± 0.00005
R2=.88
Morning Rush Hour Benzene vs. CO
BENZENE vs. CO fit_BENZENE vs. CO
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4
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uene
, (nm
ol/m
ol)
12001000800600400200 CO, (nmol/mol)
Rush Hour Toluene vs CO fit Rush Hour Toluene vs CO
Morning Rush Hour Toluene vs. CO
SLOPE=0.003 ± 0.0005
R2=.88
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zene
, (nm
ol/m
ol)
20015010050 NOx, (nmol/mol)
Morning Rush Hour Benzene vs. NOx
Benzene vs. NOx fit_Benzene vs. NOx
SLOPE=0.0054 ± 0.0005
R2=.77
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ol/m
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Rush Hour Toluene vs NOx fit Rush Hour Toluene vs NOx
Morning Rush Hour Toluene vs. Nox
SLOPE =0.010 ±.001
R2=. 73
VOCRatiosformorningrushhour
Conclusions:•ModelCO/NOxratiosare3to4timeshigherthanobserved
•HistogramssuggestthattheemissionsinventorycapturesNOxemissionsbetterthanCOemissions.
•HowwillthischangewithanewEIand/orwiththenewMOtorVehicleEmissionsSimulator2010(MOVES2010)?
•Howdomodelratioscomparetoobservationsforotherspecies(VOC/NOx)?
Acknowledgements:WewouldliketothankIDEQforsupport,NSFforfundingtheMobileAtmosphericChemistryLabandNW‐AIRQUESTforsupportoftheAIRPACTforecastsystem.
Instrumentation:
NOx:•AirQualityDesign,Inc.twochannel,highsensitivity,chemiluminescentNOdetector.•Molybdenumoxidecatalyticconverteronchannel1(NOy).•SolidstatephotolyticNO2converteronchannel2(NOx).•Calibrationinzeroairwith5.03ppmv±1.0%EPANOstandardfromScottMarrin,Inc.•90secondaverage
CO:•AeroLaserAL5002FastCOMonitor.•Spancalibrationwith0.250%±2%NISTtraceable.•90secondaverage