and assisting in the diagnosis of problems affecting converter efficiency.Information obtained from the multi-point recorder is used to adjust manualcontrol valves and setpoints of automatic control systems. Reliable andaccurate operation of this recorder is important to the operation of the plantwith low emission levelsand assisting in the diagnosis of problems affecting converter efficiency.Information obtained from the multi-point recorder is used to adjust manualcontrol valves and setpoints of automatic control systems. Reliable andaccurate operation of this recorder is important to the operation of the plantwith low emission levelsand assisting in the diagnosis of problems affecting converter efficiency.Information obtained from the multi-point recorder is used to adjust manualcontrol valves and setpoints of automatic control systems. Reliable andaccurate operation of this recorder is important to the operation of the plantwith low emission levelsA more advanced treatise of activation energies and collision and transition-statetheories isBENSONS, . W., The Foundations of Chemical Kinetics. New York: McGraw-J. I. STEINFELDJ., S . FRANCISCO, W. L. HASE, Chemical Kinetics ana' Dynam-2. The books listed above also give the rate laws and activation energies for a numberof reactions; in addition, as mentioned earlier in this chapter, an extensive listingof rate laws and activation energies can be found in NBS circulars:NATIONAL BUREAU OF STANDARDS, Tables of Chemical Kinetics: HomogeneousReactions. Circular 510, Sept. 28, 1951; Supplement 1, Nov. 14, 1956;Supplement 2, Aug. 5, 1960; Supplement 3, Sept. 15, 1961. Washington,D.C.: U.S. Government Printing Office.3. Also consult the cumnt chemistry literature for the appropriate algebraic form ofthe rate law for a given reaction. For example, check the Journal of PhysicalChemistry in addition to the journals listed two reactions:C2H5Br + OH- --+ C2HSOH + Br- (2)Use SPAIT' (see Appendix J) or some other software package to answer the following:(a) What is the ratio of the rates of reaction at 25"C? lWC? 50O0C?(b) Which reactior, scheme would you choose ta make ethanol? (Hint: ConsultChemical Marketing Reporter or www.chemweek.com for chemical prices).[Professor R. Baldwin, Colorado School of Mines]bad the Interactive Computer Module from the CD-ROM. Run the mcduleand then imrd your performance number for the module which indicates your masteringof tlhe material. Your professor has the key to && your performance nurnber.ICM Kinetics Challenge performance #P3-2SB Sgt. Amkrcromby - It is believed, although never proven, that Bonnie murdemi herfirst husband, kfty, by poisoning the tepid brandy they drank together on their firstanniversxy. Lefty was unware she had coated her glass with an antidcte before shefilled both glasses with the poison brandy. Bonnie manied her second husband, Clyde,and some years later when she had tired of him, she called him one day to tell him ofher new pmmotion at work and to suggest that they celebrate with a glass of brandythat evening. She had the fatal end in mind for Clyde However, Clyde suggested thatinstead of brandy, they celebrate with ice coldThis dielectric is typically more resistant to oxidation than other coatings. Setup a stoichiometric table for this reaction and plot the concentration of eachspecies as a function of conversion. The entering pressure is 1 Pa and the temperatureis constant at 700C. The feed is equimolar in NH3 and SiH,.P3-24, It is proposed to produce ethanol by one of two reactions:C2H5Br + OH- --+ C2HSOH + Br- (2)Use SPAIT' (see Appendix J) or some other software package to answer the following:(a) What is the ratio of the rates of reaction at 25"C? lWC? 50O0C?(b) Which reactior, scheme would you choose ta make ethanol? (Hint: ConsultChemical Marketing Reporter or www.chemweek.com for chemical prices).[Professor R. Baldwin, Colorado School of Mines]bad the Interactive Computer Module from the CD-ROM. Run the mcduleand then imrd your performance number for the module which indicates your masteringof tlhe material. Your professor has the key to && your performance nurnber.ICM Kinetics Challenge performance #P3-2SB Sgt. Amkrcromby - It is believed, although never proven, that Bonnie murdemi herfirst husband, kfty, by poisoning the tepid brandy cited in this chapter. Activation energy is usually discussed in terms of either collisiontheory or transition-state theory. A concise and readable account of thesetwo theories can be found inLAIDLERK, . J. Chemical Kinetics. New York Harper & Row, 1987, Chap. 3.An expanded but still elementary presentation can be found inGARDINER, W. C., Rates and Mechanism of Chemical Reactions. New York:MOORE,J . W., and R. G. FEARSOKNin, etics and Mechanism, 3rd ed. New YorkA more advanced treatise of activation energies and collision and transition-statetheories isBENSONS, . W., The Foundations of Chemical Kinetics. New York: McGraw-J. I. STEINFELDJ., S . FRANCISCO, W. L. HASE, Chemical Kinetics ana' Dynam-2. The books listed above also give the rate laws and activation energies for a numberof reactions; in addition, as mentioned earlier in this chapter, an extensive listingof rate laws and activation energies can be found in NBS circulars:NATIONAL BUREAU OF STANDARDS, Tables of Chemical Kinetics: HomogeneousReactions. Circular 510, Sept. 28, 1951; Supplement 1, Nov. 14, 1956;Supplement 2, Aug. 5, 1960; Supplement 3, Sept. 15, 1961. Washington,D.C.: U.S. Government Printing Office.3. Also consult the cumnt chemistry literature for the appropriate algebraic form ofthe rate law for a given reaction. For example, check the Journal of PhysicalChemistry in addition to the journals listeds as p1anned forfuture operation.1. The p1ant must be operated at or above its design production rateoThe acid concentration must be at or above the design concentration.During the performance tests as required by the N8P8, the su1furicacid p1ant must be operated under these conditions:iments