Electrochemical behavior and electrochemical determination of ...
Electrochemical sensor 01 mm 717 iit b 2016
-
Upload
yetoo-muzzamil -
Category
Engineering
-
view
48 -
download
1
Transcript of Electrochemical sensor 01 mm 717 iit b 2016
![Page 1: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/1.jpg)
Carbon-Metal composite as Electrocatalyst in electrochemical
sensors
• MUZZAMIL AHMAD EATOO• Roll No: 163110059• IIT Bombay• MEMS • MM 717• Autumn 2016
![Page 2: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/2.jpg)
contents
• Sensor and electrochemical sensor• Classification • Carbon- metal nanocomposite• Why nanoparticles• Problem with nanoparticles• Properties of support (graphene)• Preparation of graphene• Preparation of nanocomposite• conclusion
![Page 3: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/3.jpg)
INTRODUCTION:
Sensor:
A small device used for direct measurement of a physical quantity
of an analyte in a sample.
- Response is continuous and reversible
Electrochemical Sensor:
- Produces an electrical signal that is related to the concentration
of an analyte.
![Page 4: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/4.jpg)
![Page 5: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/5.jpg)
Screen printed electrochemical sensor
The basic components of an electrochemical sensor are a working (or sensing) electrode, a counter electrode and usually a reference electrode as well.
![Page 6: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/6.jpg)
Glucose monitoring in body by screen printed electrochemical sensor
![Page 7: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/7.jpg)
There are three main types of electrochemical sensors:
01) potentiometric:
Measure the potential at working electrode when zero or negligible current flow between
them.
02) Amperometric :
They measure the change in current produced, as a result of chemical reaction between
electroactive materials, when a constant potential is applied between the electrodes.
03) Conductometric:
They measure change in conductivity of analyte solution between the electrodes.
![Page 8: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/8.jpg)
Carbon-Metal Nanocomposite
It consists of:Metal (nanoparticles)Carbon as Support (usually graphene, CNT,…)
![Page 9: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/9.jpg)
Why Nanoparticles
The unique chemical and physical properties of nanoparticles make them extremely
suitable for designing new and improved sensing devices, especially electrochemical
sensors and biosensors
Many kinds of nanoparticles, such as metal, oxide and semiconductor nanoparticles
have been used for constructing electrochemical sensors and biosensors.
Very high Specific surface area.
![Page 10: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/10.jpg)
The Functions of nanoparticles:
Immobilization of biomolecules
Catalysis of electro-chemical reactions
Enhancement of electron transfer
![Page 11: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/11.jpg)
Problem of Nanoparticles
Agglomeration:
![Page 12: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/12.jpg)
Carbon
![Page 13: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/13.jpg)
Properties which make graphene useful in sensor:
Large surface to volume ratio High electron mobility Good chemical stability Unique optical properties, excellent electrical
conductivity Exceptional thermal conductivity (5000W/m/K) Extremely light weight Very low resistivity
![Page 14: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/14.jpg)
Preparation:
Graphene: Liquid exfoliation of graphite Chemical Vapour Deposition Hummers Method These methods generally involve the oxidation of graphite to graphite oxide, the subsequent exfoliation to graphene oxide (GO) and the final reduction to reduced graphene oxide(rGO).
![Page 15: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/15.jpg)
Preparation of Graphene
![Page 16: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/16.jpg)
Preparation of nanocomposite
![Page 17: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/17.jpg)
Conclusion
• Metal-Carbon Nanocomposites are made, not only to avoid agglomeration of nanoparticles but results in extraordinary sensing properties.
![Page 18: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/18.jpg)
References:
1).For screen printed sensor; Sensors 2014, 14, 10432-10453; doi:10.3390/s140610432
2).Nanoscale, 2014, 6, 11303
3).Nelson R. Stradiotto*, Hideko Yamanaka and Maria Valnice B. Zanoni Instituto de Química, Universidade Estadual Paulista, CP 355, 14801-970 Araraquara - SP, Brazil
4). S. Sansuk, E. Bitziou, M. B. Joseph, J. A. Covington, M. G. Boutelle, P. R. Unwin and J. V. Macpherson, Anal. Chem., 2013, 85, 163–169.
5).Trogadas, P., Fuller, T.F., Strasser, P., Carbon as Catalyst and Support for Electrochemical Energy Conversion, Carbon (2014)
![Page 19: Electrochemical sensor 01 mm 717 iit b 2016](https://reader036.fdocuments.net/reader036/viewer/2022062503/58d122591a28ab2a738b5bcb/html5/thumbnails/19.jpg)