Detection of externally mixed metal nanoparticles with ...
Transcript of Detection of externally mixed metal nanoparticles with ...
![Page 1: Detection of externally mixed metal nanoparticles with ...](https://reader033.fdocuments.net/reader033/viewer/2022042311/625bca7e0bc3072d226a4eda/html5/thumbnails/1.jpg)
Detection of externally mixed metal nanoparticles
with Laser Vaporisation Aerosol MS
PT Nilsson, AC Eriksson, L Ludvigsson, ME Messing, K Deppert, E. Fortner, TB Onasch, JH Pagels.
Ergonomics and Aerosol Technology, Lund University
Solid State Physics, Lund University
Aerodyne Research, Boston, USA
![Page 2: Detection of externally mixed metal nanoparticles with ...](https://reader033.fdocuments.net/reader033/viewer/2022042311/625bca7e0bc3072d226a4eda/html5/thumbnails/2.jpg)
Motivation
• The aim is to illustrate possibilities and challenges with the LV-
AMS technique within nanotechnology, especially synthesis of
nanoparticles via the aerosol route:
– Synthesis of Engineered Metal NPs
» Detection of refractory metal cores
» Quantification of organic impurities/surface coatings
• Use silver particles with controlled properties combined with DOS
coating to investigate quantification issues in the LV-AMS (SP-
AMS).
![Page 3: Detection of externally mixed metal nanoparticles with ...](https://reader033.fdocuments.net/reader033/viewer/2022042311/625bca7e0bc3072d226a4eda/html5/thumbnails/3.jpg)
Experimental Set-up
![Page 4: Detection of externally mixed metal nanoparticles with ...](https://reader033.fdocuments.net/reader033/viewer/2022042311/625bca7e0bc3072d226a4eda/html5/thumbnails/4.jpg)
Detection of Engineered Metal
Nanoparticles
Au
Ag
PT Nilsson et al. Accepted for publication in
Nanoresearch 2015
![Page 5: Detection of externally mixed metal nanoparticles with ...](https://reader033.fdocuments.net/reader033/viewer/2022042311/625bca7e0bc3072d226a4eda/html5/thumbnails/5.jpg)
![Page 6: Detection of externally mixed metal nanoparticles with ...](https://reader033.fdocuments.net/reader033/viewer/2022042311/625bca7e0bc3072d226a4eda/html5/thumbnails/6.jpg)
Selective Emissions of Metal NPs
Opened up the
spark discharge
generator
PT Nilsson et al. J. Nanopart. Res. 2013, 15:2052
Nano-objects emitted during maintenance of common particle generators: direct chemical
characterization with aerosol mass spectrometry and implications for risk assessments
![Page 7: Detection of externally mixed metal nanoparticles with ...](https://reader033.fdocuments.net/reader033/viewer/2022042311/625bca7e0bc3072d226a4eda/html5/thumbnails/7.jpg)
Impurities depend on synthesis method
Figure 5. a) Unit mass resolution spectrum of impurities on 100 nm Au aggregated particles
generated with the HTF. b) Unit mass resolution spectrum of impurities for 100 nm Au aggregated
particles generated with the SDGP. Nilsson et al. 2015, Nanoresearch
![Page 8: Detection of externally mixed metal nanoparticles with ...](https://reader033.fdocuments.net/reader033/viewer/2022042311/625bca7e0bc3072d226a4eda/html5/thumbnails/8.jpg)
AMS Quantification - Collection Efficiency
𝐶𝐸 = 𝐸𝐿 ∗ 𝐸𝐵 ∗ 𝐸𝑆
o EL: The fraction penetrating lens+inlet
o ES: The fraction hitting the vaporizer (W and/or L).
o EB: The fraction of material that hits the vaporiser (W and or L) that
becomes vaporized
o Bounce off W vaporizer
o Incomplete vaporisation due to insufficient absorption at 1064 nm
o The instrument was calibrated with monodisperse (300 nm) NH4NO3
(tungsten vaporiser) and Regal Black (laser vaporiser)
![Page 9: Detection of externally mixed metal nanoparticles with ...](https://reader033.fdocuments.net/reader033/viewer/2022042311/625bca7e0bc3072d226a4eda/html5/thumbnails/9.jpg)
Relationship between dva and dme upon DOS
coating of Ag NPs with different morphologies
Sintered
Semi-sintered
Aggregates
All 5 fg Ag cores
𝜌 𝑒𝑓𝑓(𝐼𝐼𝐼 = 𝜌0
𝑑𝑣𝑎
𝑑𝑚
![Page 10: Detection of externally mixed metal nanoparticles with ...](https://reader033.fdocuments.net/reader033/viewer/2022042311/625bca7e0bc3072d226a4eda/html5/thumbnails/10.jpg)
Instrument Sensitivity to Ag NPs
6
5
4
3
2
1
0
miE
(norm
aliz
ed to b
are
)
543210
RAg (mDOS/mAg)
1.0
0.8
0.6
0.4
0.2
0.0
BW
P C
ente
r/Edge
mIE_norm Center_edge
BW
P tra
nsm
issio
n a
t cente
r
Ion
s p
er
pg (
no
rm . t
o b
are
)
![Page 11: Detection of externally mixed metal nanoparticles with ...](https://reader033.fdocuments.net/reader033/viewer/2022042311/625bca7e0bc3072d226a4eda/html5/thumbnails/11.jpg)
Conclusions
• LV-AMS is a promising tool for highly time- and size resolved
analysis of metal ENP agglomerates and their organic surface
coatings and impurities
• Sensitivity to silver well correlated with BWP measurements
• In addition to chemical information, also particle physical
properties can be extracted (when combined with mobility
based techniques)