Day 1 Session III - 03 James Walters.ahri AREP

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    Overview of AHRI Research on Low-

    GWP RefrigerantsJames Walters

    Vice President, International AffairsAir-Conditioning, Heating, and Refrigeration Institute

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    New Reality

    CFCs HCFCs HFCs ??

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    Things to think about

    Maintaining refrigerant choice

    Evaluating refrigerant characteristics forinformed choices

    Making transition predictable, smooth,and informed

    Educating policy makers and trainingtechnicians

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    Choosing a Refrigerant

    Refrigerants have unique operating characteristics – Choicenot based on one factor, but an analysis of factors: – Safe – Energy efficient – Widely available – Economical – GWP

    Operating factors can be different: – Pressures – Incompatible lubricants – Incompatible metals and alloys – Flammability levels

    Needs will be different for each application

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    AHRI Research on Low-GWPRefrigerants

    Recently completed projects:• Review of Regulations and Standards for the Use of Refrigerants with

    GWP Values Less than 20 in HVAC&R Applications• Defining the Configurations of Residential Air-Conditioning and Heat

    Pump Systems Using Hydrocarbons, Ammonia, Carbon Dioxide, andHFO-1234yf as Refrigerants and Meeting Previously Defined SafetyRequirements

    • Material Compatibility & Lubricants Research for Low GWPRefrigerants – Phase I: Thermal and Chemical Stability of Low GWPRefrigerants with Lubricants

    • Risk Assessment of Residential Heat Pump Systems Using 2LFlammable Refrigerants

    Ongoing projects:• Material Compatibility & Lubricants Research for Low GWP Refrigerants• Risk Assessment of Refrigeration Systems Using A2L Flammable

    Refrigerants (contractor selection in progress.)Ongoing program: Low-GWP AREP

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    Low-GWP AREP IntroductionCooperative research program to identify suitablealternatives to high GWP refrigerantsResearch strongly desired by OEMs – assess research needs – accelerate industry’s response to environmental

    challenges – avoid duplicative workThe program is NOT to prioritize refrigerants,rather test and present results in a consistentmannerThe program started in March 2011All final reports will be available to the public in3rd quarter of 2013

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    Low-GWP AREP Introduction

    Solicited the industry for a list of low-GWPrefrigerant candidatesSolicited OEMs for test plans – Testing companies propose test plans according to

    their individual interest

    – Testing companies directly report test results toAHRI Low-GWP AREP Technical Committee

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    AcknowledgmentsU.S. Testing Entities:

    International Testing Entities

    Refrigerant Suppliers

    – Carrier Corporation – Climate Master – Emerson Climate Technologies – Follett Corporation – Goodman Manufacturing

    – Hussmann (share results) – Johnson Controls, Inc. – Lennox Industries Inc. – Manitowoc Ice, Inc. – McQuay International

    – Oak Ridge National Laboratory – Tecumseh Company Co. – Thermo King / Ingersoll Rand – Trane/ Ingersoll Rand – University of Maryland

    – ARMINES-MINES ParisTech – Daikin Industries Ltd

    – Embraco Brazil – Embraco Slovakia Sro

    – GD Midea Air-conditioning Equipment Co.,Ltd – Shanghai Hitachi Electrical Appliances CO.,LTD

    – Arkema, Inc. – Daikin Industries Ltd

    – E.I.du Pont de Nemours&Co – Honeywell International, Inc

    – Mexichem Fluor, Inc – National Refrigerants, Inc

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    Identified Alternative RefrigerantCandidates

    Baseline Refrigerant Composition (Mass%) Classification GWP 100

    R-134a

    AC5X R-32/R-134a/R-1234ze(E) (7/40/53) A1* 622ARM-41a R-32/R-134a/R-1234yf (6/63/31) A1* 943

    D-4Y R-134a/R-1234yf (40/60) A1* 574N13a R-134a/R-1234yf/R-1234ze(E) (42/18/40) A1* 604

    N13b R-134a/R-1234ze(E) (42/58) A1* 604XP-10 R-134a/R-1234yf (44/56) A1* 631AC5 R-32/R-152a/R-1234ze(E) (12/5/83) A2L* 92

    ARM-42a R-134a/R-152a/R-1234yf (7/11/82) A2L* 117R1234yf R1234yf 100 A2L 4

    R1234ze R1234ze 100 A2L 6R600a R600a 100 A3

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    Identified Alternative RefrigerantCandidates

    Baseline Refrigerant Composition (Mass%) Classification GWP 100

    R404A

    ARM-32a R-32/R-125/R-134a/R-1234yf (25/30/25/20) A1* 1577

    DR-33 R-32/R-125/R-134a/R-1234yf (24/25/26/25) A1* 1410

    N40a R-32/R-125/R-134a/R-1234yf/R-1234ze(E) (25/25/21/9/20) A1* 1346

    N40b R-32/R-125/R-134a/R-1234yf (25/25/20/30) A1* 1331

    R744 R-744 100 A1 1ARM-30a R-32/R-1234yf (29/71) A2L* 199ARM-31a R-32/R-134a/R-1234yf (28/21/51) A2L* 491

    D2Y65 R-32/R-1234yf (35/65) A2L* 239DR-7 R-32/R-1234yf (36/64) A2L* 246L40 R-32/R-152a/R-1234yf/R-1234ze(E) (40/10/20/30) A2L* 285R-32 R-32 100 A2L 675

    R-32/R-134a R-32/R-134a (50/50) A2L* 1053R290 R-290 100 A3

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    Identified Alternative RefrigerantCandidates

    Baseline Refrigerant Composition (Mass%) Classification GWP 100

    R410A

    R-744 R-744 100 A1 1

    ARM-70a R-32/R-134a/R-1234yf (50/10/40) A2L* 482

    D2Y60 R-32/R-1234yf (40/60) A2L* 272

    DR-5 R-32/R-1234yf (72.5/27.5) A2L* 490

    HPR1D R-32/R-744/R-1234ze(E) (60/6/34) A2L* 407

    L41a R-32/R-1234yf/R-1234ze(E) (73/15/12) A2L* 494

    L41b R-32/R-1234ze(E) (73/27) A2L* 494

    R32 R32 100 A2L 675

    R32/R134a R-32/R-134a (95/5) A2L* 713

    R32/R152a R-32/R-152a (95/5) A2L* 647*estimated safety group rating, a safety group has not yet been assigned by ASHRAE in accordance withrequirements of ASHRAE Standard 34‐2010.

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    Identified Alternative RefrigerantCandidates

    Baseline Refrigerant Composition (Mass%) Classification GWP 100

    R22

    ARM-32a R-32/R-125/R-134a/R-1234yf (25/30/25/20) A1* 1577LTR4X R-32/R-125/R-134a/R-1234ze(E) (28/25/16/31) A1* 1295

    N20R-32/R-125/R-134a/R-1234yf/R-

    1234ze(E)(12.5/12.5/31.5

    /13.5/30) A1* 975D52Y R-32/R-125/R-1234yf (15/25/60) A2L* 979L20 R-32/R-152a/R-1234ze(E) (45/20/35) A2L* 331

    LTR6A R-32/R-744/R-1234ze(E) (30/7/63) A2L* 206R290 R290 100 A3

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    Low-GWP Alternative RefrigerantCandidates

    0

    200

    400

    600

    800

    10001200

    1400

    1600

    1800

    G W P 1

    0 0 V a

    l u e

    Alternative Refrigerant Candidates

    A1

    A2L

    A3

    B2L

    R-134a

    (GWP=1430)replacements

    R-404A

    (GWP=3900)replacements

    R-410A

    (GWP=2100)replacements

    R-22

    (GWP=1810)replacements

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    Overview of TestingSixteen (16) U.S. companies/organizations and

    five (5) international companies/organizationsare conducting testsSix (6) refrigerant producers supplied thirty-eight (38) refrigerant candidatesTests cover the following applications – Air-conditioners and heat pumps (air-source,

    water-source, VRF, unitary, mini-split) – Chillers (screw, centrifugal) – Heat pump water heater

    – Refrigeration (commercial refrigerator, icemachine) – Transport refrigeration – Bus air-conditioning

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    Tests being Conducted

    Compressor calorimeter testSystem drop-in test – only minor modifications are allowedSystem “soft -optimization” test – systems are modified for the alternative

    refrigerants using standard productionline components

    Test Types Number of candidates beingtested

    Number of products beingtested

    Compressor Calorimeter 28 35

    Drop-in 27 30

    Soft-optimization 18 19

    Note: Number of candidates and product types in the table are based on approved test plans submitted bytesting entities. Actual numbers may vary due to testing entities’ schedule changes.

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    Test Results-Residential Heat Pump

    [Data sources:AHRI Low-GWP AREPReports 003, 004, and

    005, 2012]

    R-32, 3.5-tonDrop-in, Acondition

    R-32, 3.5-tonDrop-in, Bcondition

    R-32, 3-ton Soft-optimized, A

    condition

    R-32, 3-ton Soft-optimized, B

    condition

    5-ton, R-32/R-152a (95/5),Drop-in, ACondition5-ton, R-32/R-

    152a (95/5),Drop-in, BCondition

    -8%

    -6%

    -4%

    -2%

    0%

    2%

    4%

    6%

    8%

    0% 2% 4% 6% 8% 10%

    C O P R e l a t i v e t o

    R - 4 1 0 A

    Capacity Relative to R-410A

    Residential Heat Pump-Cooling Mode

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    Test Results-Residential Heat Pump

    R-32, 3.5-tonDrop-in, H1condition

    R-32, 3.5-tonDrop-in, H3condition

    R-32, 3-ton Soft-optimized, H1

    condition

    R-32, 3-ton Soft-optimized, H3

    condition

    5-ton, R-32/R-152a (95/5),Drop-in, H1Condition

    5-ton, R-32/R-152a (95/5),Drop-in, H3Condition

    0%

    1%

    2%

    3%

    4%

    5%

    6%

    7%

    8%

    9%

    10%

    -2% 0% 2% 4% 6% 8% 10%

    C O P R e l a t i v e t o R - 4

    1 0 A

    Capacity Relative to R-410A

    Residential Heat Pump-Heating Mode

    [Data sources:AHRI Low-GWP AREPReports 003, 004, and

    005, 2012]

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    Test Results-Residential Heat Pump

    19

    R-32, 3.5-tonDrop-in

    R-32, 3-ton Soft-optimized

    5-ton, R-32/R-152a (95/5),

    Drop-in

    0%

    1%

    2%

    3%

    4%

    5%

    6%

    7%

    8%

    9%

    10%

    -2% 0% 2% 4% 6%

    H S P F R e l a t i v e t o R - 4

    1 0 A

    SEER Relative to R-410A

    Residential Heat Pump-Seasonal Performance

    [Data sources:AHRI Low-GWP AREPReports 003, 004, and

    005, 2012]

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    Test Results-Chiller

    20

    [Data source: AHRI Low-GWP AREP Report 007, 2012]

    -30%

    -25%

    -20%

    -15%

    -10%-5%

    0%

    5%

    10%

    15%

    20%

    ARM-42a N-13a N-13b R-1234ze(E) XP-10

    R e l a t i v e P e r f o r m a c e t o R - 1 3 4 a

    230-ton Water-cooled Screw Chiller (R-134a)

    CapacityCOP

    T_chilled water, outlet=44 °FT_cooling water, inlet=85 °Fmfr_chilled water=550 gpmmfr_cooling water=700 gpm

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    Test Results-Chiller

    21

    [Data source: AHRI Low-GWP AREP Report 001, 2012]

    -30%

    -25%

    -20%

    -15%

    -10%-5%

    0%

    5%

    10%

    15%

    20%

    ARM-32aARM-70a DR-5 HPR1D L-41a L-41b R-32

    R e l a t i v e P e r f o r m a c e t o R - 4

    1 0 A

    5-ton Air-cooled Chiller (R-410A)Capacity

    EER

    T_ambient=95 °FT_water, outlet=45 °Fmfr_water=14 gpm

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    Test Results-Chiller

    [Data source: AHRI Low-GWP AREP Report 006, 2012]

    -25.0%

    -20.0%

    -15.0%

    -10.0%

    -5.0%

    0.0%

    5.0%

    10.0%

    15.0%

    ARM-32a DR-7 L-20 LTR4X LTR6A D52Y

    R e l a t i v e P e r f o r m a c e t o R - 2

    2

    5-ton Air-cooled Chiller (R-22)

    Capacity EER T_ambient=95 °FT_water, outlet=45 °Fmfr_water=14 gpm

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    AHRI Low-GWP AREP – Next StepsConference on January 16, 2014 in New

    York City• Testing results will be presented• Conference open to the public

    Second round of testing to start in Fall2013

    • Testing at high ambient conditions• Additional refrigerants

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    SummaryThe program is an ongoing industry effort to identify low-GWPrefrigerants

    Thirty-eight low-GWP candidates are being evaluated by twenty-oneentities domestically and internationally

    The program is to evaluate the refrigerant candidates, and presenttheir performance in a consistent manner

    The program is not to prioritize alternative refrigerants

    Twenty-two test reports have been made available to the public, andall the results will be released to the public at the completion of theprogram

    Reports can be downloaded from AHRI’s website http://www.ahrinet.org/ahri+low_gwp+alternative+refrigerants+evaluation+program.aspx

    http://www.ahrinet.org/ahri+low_gwp+alternative+refrigerants+evaluation+program.aspxhttp://www.ahrinet.org/ahri+low_gwp+alternative+refrigerants+evaluation+program.aspxhttp://www.ahrinet.org/ahri+low_gwp+alternative+refrigerants+evaluation+program.aspxhttp://www.ahrinet.org/ahri+low_gwp+alternative+refrigerants+evaluation+program.aspxhttp://www.ahrinet.org/ahri+low_gwp+alternative+refrigerants+evaluation+program.aspxhttp://www.ahrinet.org/ahri+low_gwp+alternative+refrigerants+evaluation+program.aspxhttp://www.ahrinet.org/ahri+low_gwp+alternative+refrigerants+evaluation+program.aspx

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    Thank you for your attention!