Crystal Dishwasher Powder SDS - May 2016 - Crystal Dishwas… · Crystal Dishwasher Powder Mountain...

SafetyDataSheet

CrystalDishwasherPowderMountainCleaningProducts

IssueDate:May2016Validto:May2021

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SECTION1:IDENTIFICATIONOFPRODUCTANDCOMPANY

TradeName: CrystalDishwasherPowderSynonyms: NA

ChemicalFormula: NACASNumber: NAProductUses: Machinedishwashing.Hasbuiltinrinseaid.

Supplier/Manufacturer: MountainCleaningProducts

Address: 7/7/SnowSt,SouthLismore,NSW2480Telephone: 0266228733

Fax: 0266228744Email: [email protected]

Website: www.mountaincleaning.com.auEmergencyTelephone: 131126(PoisonsInformationCentre)

SECTION2:HAZARD(S)IDENTIFICATION

GHSClassification: Skincorrosion(Category1B)Singletargetorgantoxicity(Category3)

LABELLINGELEMENTS:

SignalWord: DangerPictogram(s):

CorrosiveHealthhazards

HazardStatements(s): H314Causessevereskinburnsandeyedamage.H335Maycauserespiratoryirritation.

PrecautionaryStatement(s):

PreventionP260Donotbreathedusts.P264Washhandsthoroughlyafterhandling.P271Useonlyinawellventilatedarea.P273Avoidreleasetotheenvironment(ifnotintendeduse).P280Wearprotectivegloves.

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ResponseP301+P330+P331IFSWALLOWED:Rinsemouth.DoNOTinducevomiting.P303+P361+P353IFONSKIN(orhair):Immediatelytakeoffallcontaminatedclothing.Rinseskinwithwater/shower.P363Washcontaminatedclothingbeforereuse.P304+P340IFINHALED:Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.P305+P351+P338IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing.P310ImmediatelycallaPOISONCENTRE(131126)ordoctor.P321Specifictreatment,seeFirstAidMeasuresonthisSafetyDataSheet.

Storage: P403+P233Storeinawell-ventilatedplace.Keepcontainertightlyclosed.P405Storelockedup.

Disposal: P501Disposeofcontents/containertoanapprovedwastedisposalplant.

SECTION3:COMPOSITIONANDINFORMATIONONINGREDIENTSIngredients CASNo.s Percentage(w/w) ClassificationSodiummetasilicatepentahydrate

10213-79-3 20-40% H314+H335

Sodiumcarbonate 497-19-8 20-40% H319Sodiumpercarbonate 16630-89-4 <10% H272+H302+H318Otheringredientsdeterminedtobenonhazardousorbelowconcentrationcutoffs

<30%

SECTION4:FIRSTAIDMEASURES

FirstAidFacilities: Normalwashroomfacilities.EyeContact: Immediatelyirrigatewithcopiousquantitiesofwaterforat

least30minutes.Eyelidstobeheldopen.Avoidrinsewater

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enteringuncontaminatedeye.Seekmedicaladvice(e.g.ophthalmologist)ifthereareongoingsymptoms.

SkinContact: Removecontaminatedclothing.Washaffectedskinwithplentyofwater.Seekmedicaladviceifirritation,burningorrednessdevelops.

Inhalation: Removevictimtofreshairawayfromexposure-avoidbecomingacasualty.Removecontaminatedclothingandloosenremainingclothing.Allowpatienttoassumemostcomfortableposition,keepwarmandatrest.Ifbreathinglabouredandpatientcyanotic(blue),ensureairwaysareclearandhavequalifiedpersongiveoxygenthroughafacemask.Seekmedicalattention.

Ingestion: DoNOTinducevomiting.DoNOTattempttogiveanythingbymouthtoanunconsciousperson.Ifconscious,rinsemouththoroughlywithwaterandgivewatertodrink.Ifvomitingoccurs,givefurtherwatertoachieveeffectivedilution.Seekmedicaladvice.

AdvicetoDoctor: Nospecificantidote.Treatsymptomaticallyforchemicalburns.Alltreatmentsshouldbebasedonobservedsignsandsymptomsofdistressofthepatient.PoisonsInformationCentreineachAustralianStatecapitalcityorinChristchurch,NewZealandcanprovideadditionalassistanceforscheduledpoisons.

ScheduledPoisons: PoisonsInformationCentreineachAustralianStatecapitalcitycanprovideadditionalassistanceforscheduledpoisons.PhoneAustralia131126.

SECTION5:FIREFIGHTINGMEASURESFireandExplosionHazard: Non-combustible.However,ifinvolvedinafire,willemittoxic

fumes.ExtinguishingMedia: Usefinewaterspray,normalfoamordryagentextinguisher

(carbondioxideordrychemicalpowder).FireFighting: Keepcontainersexposedtoextremeheatcoolwithwater

spray.Firefighterstowearself-containedbreathingapparatusifriskofexposuretoproductsofcombustionordecomposition.Evacuatearea-moveupwindoffire.

FlashPoint: None.

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HazchemCode: 2X.SECTION6:ACCIDENTALRELEASEMEASURES

MinorSpills: Collectspills,avoidinggenerationofdust.Rinseareawithwater.

MajorSpills: Forexampletransportaccidentorbulkspill.Clearareaofunprotectedpersonnel.Workupwindorincreaseventilation.Preventspillagefromenteringdrainsorwatercourses.Wearappropriateprotectiveequipment(seesection8)topreventskinandeyecontamination.Spiltmaterialshouldbeshovelledupandandplacedintosuitablecontainers,appropriatelylabeled,fordisposalbyanapprovedagentaccordingtolocalconditions.Spillageareamayremainslippery.Flushspillareawithexcesswater.Considerneutralisationwithacidifrequired.Ifcontaminationofsewersorwaterwayshasoccurredadvisethelocalemergencyservices.Intheeventofalargespillagenotifythelocalenvironmentprotectionauthorityoremergencyservices.

PPE: PersonalprotectiveequipmentadviceiscontainedinSection8ofthisdocument.

SECTION7:HANDLINGANDSTORAGE

Handling: Avoidskinandeyecontact.Donoteat,drinkorsmokewhenhandlingproduct.Keepoutofreachofchildren.Alwayswashhandswithwaterafterhandling.

Storage: Storeinacool,dry,placewithgoodventilation.Avoidstoringinaluminiumandlightalloycontainers.Storeawayfromincompatiblematerials(seeSection10).Keepcontainersclosedatalltimeswhennotinuse.Checkregularlyforleaksordamage.

SECTION8:EXPOSURECONTROLSANDPERSONALPROTECTION

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OCCUPATIONALEXPOSURELIMITS:Noneestablishedforthisproduct.Howevertheexposurestandardfordust,nototherwisespecifiedis10mg/m3(inspirabledust)and3mg/m3(respirabledust).Ingredient TWA STEL DNEL

PersonalProtection: Rubberglovesundernormalconditionsofuse.Chemicalgogglesorsafetyglasses,gloves,longsleevedcoverallsandsafetyfootwearwherecontaminationislikely.

EngineeringControls: Ensureventilationisadequate.Avoidgeneratingdust.Ensureairflowisdirectedawayfromoperators.

EyeandFaceProtection: Chemicalgogglesorsafetyglassestohandleinquantity.HandandSkinProtection: WearimperviousPVCorrubberglovestodispense.

Whenusinglargequantitiesorwhereheavycontaminationislikely,wearcoverallsandfootwearthatprovidesprotectionagainstacids/alkalis.

InhalationProtection: Notnormallyrequiredundernormaluseconditions.Whereadustinhalationriskexistswearafilter/apparatusthatmeetsAS/NZS1715andAS/NZS1716.Foremergencies,includinginstanceswhereexposurelevelsarenotknown,usefull-facepositivepressureair-suppliedrespirator.

SECTION9:PHYSICALANDCHEMICALPROPERTIES

Appearance: Whitecrystallinepowder

Odour: Faint VapourPressure: NotavailableOdourThreshold: Notavailable RelativeVapour

Density:Notavailable

pH: 12.0-13.0at1%solution

RelativeDensity(Water=1):

Notavailable

MeltingPoint: Notavailable WaterSolubility: Miscibleinallportions

BoilingPoint: Notavailable PartitionCoefficientn-Octanol/Water

Notavailable

FlashPoint: Notavailable Auto-ignition Notavailable

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TemperatureEvaporationRate: Notavailable Decomposition

TemperatureNotavailable

Flammability: Notflammable Viscosity NotavailableUpper/LowerFlammability:

Notavailable

SECTION10:STABILITYANDREACTIVITY

Reactivity: Reactsviolentlywithacidsyieldingheatandpressurethatcanburstaclosedcontainer.Reactsslowlywithair,absorbingcarbondioxide,whichmaycauseinsolublesaltstoforminsolutionsoftheproduct.

ChemicalStability: Stableundernormalconditionsofstorageandhandling.Contaminationofproductandexposuretoheatandlightwillacceleratedecomposition.

PossibilityofHazardousReactions:

Noneknown.

ConditionstoAvoid: Avoidcontactwithincompatiblematerialsandstorageinmetalcontainers.

IncompatibleMaterials: Acids,amines,ammoniumsalts,aziridine,methanolandphenylacetonitrile.Reactswithmetalsaltsandreducingagents.

SECTION11:TOXICOLOGICALINFORMATION

Inhaled: Corrosive.Breathingindustsmayresultinsorethroat,cough,shortnessofbreathandirritationintherespiratorytract.Inhalationofgranuleswillresultinrespiratoryirritationandpossiblyharmfulcorrosiveeffectsincludingpulmonaryoedema,lesionsofthenasalseptum,pneumonitisandemphysema.

SkinContact: Corrosivetoskin.Maycauseskinburns.EyeContact: Corrosivetoeyes.Contactcancausecornealburnswith

possibleriskofseriousdamagetoeyes.Ingestion: Corrosive.Swallowingcanresultinnausea,vomiting,diarrhoea,

abdominalpain,convulsions,chemicalburns,lostconsciousnessandpossibledeath.Ingestionofdryorliquidformulationscontaining10%orhigherconcentrationofthe

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productcanresultinserioushealthproblems.AcuteToxicity: NoLD50dataavailableforthisproduct.

Foractiveconstituent,sodiumcarbonate(at100%):OralLD50(rat)-4090mg/kg Foractiveconstituent,sodiummetasilicatepentahydrate(at100%):OralLD50(rat)-847mg/kg Foractiveconstituent,sodiumpercarbonate(at88%):OralLD50(rat)-1034mg/kg

Chronic: Noinformationavailable.SECTION12:ECOLOGICALINFORMATION

Ecotoxicity: Acuteaquatictoxicity(Category3).Chronicaquatictoxicity(Category3).Harmfultoaquaticlifewithlonglastingeffects.Nodataavailableforthisproduct.Foractiveconstituent,sodiumcarbonate(at100%):LC50(Pimephalespromelas(fatheadminnow))–400mg/litre.Foractiveconstituent,sodiummetasilicatepentahydrate(at100%):LC50(Gambusiaaffnis)–2320mg/litre-96h.Foractiveconstituent,sodiumtripolyphosphate(at>94%):EC50(bacteria)>1000mg/litre–48h. Foractiveconstituent,sodiumpercarbonate(at88%):LC50(Pimephalespromelas(fatheadminnow))–70.7mg/litre-96h.Forminorconstituent,alkoxylatedalcohol(at>60%):LC50(fish)–0.65-1.05mg/litre–96h.Longtermeffect:Nodataavailable.Avoidcontaminatingwaterways.Acuteandchronictoxicityduetoalkoxylatedalcohol,whichisaminorconstituentoftheproduct,pluspHriseeffect.

PersistenceandDegradability:

Individualcomponentsstatedtobebiodegradable.

Bioaccumulative Bioaccumulationisnotexpected.

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Potential:MobilityinSoil: Notknown.

OtherAdverseAffects: Noneknown.SECTION13:DISPOSALCONSIDERATIONS

DisposalMethods: RefertoWasteManagementAuthority.Disposeofmaterialthroughalicensedwastecontractor.Decontaminationanddestructionofcontainersshouldbeconsidered.

SECTION14:TRANSPORTINFORMATIONADGCodeClassification: DangerousGoods.

UNNo.: 1759ProperShippingName: CORROSIVESOLIDS,N.O.S.TransportHazardClass: 8–Corrosive

PackingGroup: IIIHazchemCode: 2X

EnvironmentalHazardsforTransport:

Aquatoxicity.

SECTION15:REGULATORYINFORMATIONSUSMP(PoisonSchedule): S6PoisonSECTION16:OTHERINFORMATION

Abbreviations: ADG–AustralianCodefortheTransportofDangerousGoodsbyRoadandRail.CASNo.-ChemicalAbstractServiceNumberusedtouniquelyidentifychemicalcompounds.

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GHS-GloballyHarmonisedSystem.IARC-InternationalAgencyforResearchonCancer.LD50-LethalDose,50%/medianLethalDose.Mg/m3-Milligramspercubicmetre.PPM–Partspermillion.STEL–ShortTermExposureLimit.STOT-RE–SpecificTargetOrganToxicity(repeatedexposure).STOT–SE-SpecificTargetOrganToxicity(singleexposure).SUSMP–StandardfortheUniformSchedulingofMedicinesandPoisons.TWA/OEL–TimeWeightedAverageorOccupationalExposurelimit.

RevisionHistory: Rev1.0InitialSDSforGHScompliance.PreparedBy: MountainCleaningProductsRegulatoryService.

ENDOFSDS

Crystal Dishwasher Powder SDS - May 2016 - Crystal Dishwas… · Crystal Dishwasher Powder Mountain...

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