COPPER ANTIMONY SULFIDE THIN FILMS BY SPRAY PYROLYSIS FOR PHOTOVOLTAIC...
Transcript of COPPER ANTIMONY SULFIDE THIN FILMS BY SPRAY PYROLYSIS FOR PHOTOVOLTAIC...
UNIVERSIDAD AUTONOMA DE NUEVO LEON
FACULTAD DE INGENIERIA MECANICA Y ELECTRICA
TESIS
COPPER ANTIMONY SULFIDE THIN FILMS BY SPRAY PYROLYSIS
FOR PHOTOVOLTAIC APPLICATIONS
POR
JOSE AGUSTIN AQUINO RAMOS
EN OPCION AL GRADO DE
MAESTRIA EN CIENCIAS DE LA INGENIERIA MECANICA CON ESPECIALIDAD EN
MATERIALES
MAYO, 2017
UNIVERSIDAD AUTONOMA DE NUEVO LEON
FACULTAD DE INGENIERIA MECANICA Y ELECTRICA
SUBDIRECCION DE ESTUDIOS DE POSGRADO
TESIS
COPPER ANTIMONY SULFIDE THIN FILMS BY SPRAY PYROLYSIS
FOR PHOTOVOLTAIC APPLICATIONS
POR
JOSE AGUSTIN AQUINO RAMOS
EN OPCION AL GRADO DE
MAESTRIA EN CIENCIAS DE LA INGENIERIA MECANICA CON ESPECIALIDAD EN
MATERIALES
SAN NICOLAS DE LOS GARZA, NUEVO LEON, MEXICO, MAYO, 2017
San Nicolás de los Garza, Nuevo León, a mayo de 2017
Dedicatory
To my mother Dr. Patricia Danahe Ramos Lopez for her constant support and
example at all times, she demads herself every day to give her best. To be a
excellent doctor, a responsible teacher, and a great mom. Who is the person I
most want, and for her I am,thank you cute mommy.
iii
Acknowledgments
For this research work, although it takes my name for defense, it is also part of all
the people and institutions that trusted and supported me during this stage.
Dr. Bindu Krishnan: For the opportunity of working in this research project, her
support with the reagents and the laboratory equipment for the experimen-
tation. For her time and knowledge brought to be a researcher.
Dr. David Avellaneda Avellaneda: For his advice, his thesis review, his support
and his time granted for the characterization with the XPS.
Dr. Shadai Lugo Loredo: For her advice, and her review for the thesis.
Dr. Sadasivan Shaji: For characterized by AFM the thin films and the observa-
tions during the master.
UANL: To my alma mater, for being a source of knowledge and culture, allowing
me to develop my skills and give me a professional training to meet the
challenges of our society.
CONACYT: To the National Science and Technology Council for the scholarship
granted during the master’s degree.
CIIDIT: For being my great working place during this research. To all the staff, for
gave me an excellent attention during my stay.
iv
FIME-CIDET: For the access to the laboratories and the equipment for the char-
acterization of the thin films.
IER-UNAM: For characterized by GIXRD the thin films.
FCQ-Postgraduate: For the access to the Stylus Profiles for my characterization
of thin films.
MSc. Pedro Martın Varguez: For his teaches of chemistry topics, and for show-
ing me LaTeX as a more complicated way of writing a thesis.
MSc. Daniel Acuna Leal: For his observations of the physics topics, and more
important for being a permanent member of the coffee club.
Contents
Dedicatory iii
Acknowledgments iii
Abstract viii
1 Thin Film Solar Cells 1
1.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.1.1 Semiconducting Thin Films . . . . . . . . . . . . . . . . . . 2
1.1.2 Solar cell equation . . . . . . . . . . . . . . . . . . . . . . . 4
1.1.3 Inorganic thin films . . . . . . . . . . . . . . . . . . . . . . . 6
1.1.4 New materials for Thin Film Photovoltaic . . . . . . . . . . . 9
1.2 CuSbS2 Thin Films . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
1.2.1 Hypothesis . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
1.2.2 General objective . . . . . . . . . . . . . . . . . . . . . . . . 12
1.2.3 Specific objective . . . . . . . . . . . . . . . . . . . . . . . . 12
2 CuSbS2: a novel photovoltaic material 13
2.1 Structure and properties . . . . . . . . . . . . . . . . . . . . . . . . 13
2.2 Synthesis methods . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
2.2.1 Chemical bath deposition (CBD) . . . . . . . . . . . . . . . 17
vi
2.2.2 Thermal Vacuum Evaporation(TVE) . . . . . . . . . . . . . 18
2.2.3 Chemical bath deposition & thermal evaporation . . . . . . 19
2.2.4 Electrodeposition . . . . . . . . . . . . . . . . . . . . . . . . 20
2.2.5 Spin coating . . . . . . . . . . . . . . . . . . . . . . . . . . 21
2.2.6 Spray pyrolysis thin films (SPTF) . . . . . . . . . . . . . . . 22
3 Experimentation 28
3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
3.2 Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
3.2.1 Reactants . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
3.2.2 Spray Pyrolysis equipment . . . . . . . . . . . . . . . . . . 31
3.2.3 Substrate cleaning . . . . . . . . . . . . . . . . . . . . . . . 32
3.3 Synthesis of Copper sulfide . . . . . . . . . . . . . . . . . . . . . . 33
3.4 Synthesis of antimony sulfide . . . . . . . . . . . . . . . . . . . . . 35
3.5 Synthesis of CuSbS2 with (CH3CO2)3Sb as Sb precursor . . . . . 37
3.6 Synthesis of CuSbS2 using SbCl3 as Sb precursor . . . . . . . . . 38
4 Characterization of CuSbS2 thin films 41
4.1 Introduction: Choosing the samples . . . . . . . . . . . . . . . . . 41
4.2 Stylus Profiler . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
4.3 X-Ray Diffraction (XRD) . . . . . . . . . . . . . . . . . . . . . . . . 43
4.4 Raman spectroscopy . . . . . . . . . . . . . . . . . . . . . . . . . . 51
4.5 X-Ray Photoelectron spectroscopy (XPS) . . . . . . . . . . . . . . 52
4.6 Atomic Force Microscopy (AFM) . . . . . . . . . . . . . . . . . . . 58
4.7 UV-visible Spectroscopy (UV-Vis) . . . . . . . . . . . . . . . . . . . 60
4.8 Photoresponse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 66
4.9 Hall Effect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68
5 Conclusions 71
5.1 Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71
5.2 Future work . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
6 Publication 74
Bibliography 75
List of Figures 84
List of Tables 88
Abstract
The present project is on the synthesis of absorber material which belongs to I-
V-VI group viz Copper Antimony Sulfide thin films by spray pyrolysis technique.
CuSbS2 has an ideal optical band gap of Eg=1.55 eV [1] that is suitable for photo-
voltaic applications. The spray pyrolysis technique is a chemical deposition that it
does not need vacuum and also the process is carried at low temperatures near
500 C. We obtained good quality thin films of thickness under 1µm using this low
cost technique.
In chapter one, Thin Film Solar Cells, it is mentioned how the first photovoltaic
cell was born, and the theory of the Photovoltaic effect. It was shown the func-
tionally of a typical pn junction solar cell, the PV structures and the configurations
used in the photovoltaic industry.
In chapter two, CuSbS2: a novel photovoltaic material, a summary on differ-
ent types of deposition techniques for thin films is presented. Further, a detailed
description on the spray pyrolysis method along with a complete theoretical views
on the mechanism of the film growth process.
Chapter three, Experimentation, begins with the problem approach, the justi-
fication of the present study, the objectives, and the proposed hypothesis. The
chapter continues with the approach of experiments through a diagram of the pro-
totype spray pyrolysis set up and the parameters that were considered for the
synthesis process. Further, description of the characterization technique used for
ix
the present work are given. In chapter four, Characterization of CuSbS2 thin films,
detailed analysis of the results is presented.
In chapter five, Conclusions and recommendations, the important findings of
the present research project are highlighted and also, further scope of the project.
1Thin Film Solar Cells
”There’s plenty of room at the bottom.”
by Richard Phillips Feynman.
1.1 Introduction
The key factors to slow down the development of the photovoltaic industry in its
early days were the costs of production, the availability of raw materials, the
toxicity of the materials during manufacture [2] and the competition against oil
industry. At that point, a new technology based on the silicon wafer has had an
important role in this technology for the development. Considering the thickness
necessary for the fabrication of a monocrystal solar cell between 250 µm to
300 µm implied a high cost of production [3]. In this way, the raw materials and
the Czochralski process reflect in a 50% of the total module cost [4]. So it has
had an interest to reduce the thickness of the material without decreasing the
efficiency, with this Thin Film technology, the reduction of the material cost and
thus production of a solar cell would be profitable [5].
There are a few specific definitions for thin films. Some of them refer to the
thickness and others to how the layers are formed. Focusing on the layer growth
view, formation of thin film depending on condensation or nucleation or ionic reac-
tion of species (atoms/moleculas/ions) on the surface substrate (metal, polymer
1
or glass) as homogeneous solid material that can be single crystalline, polycrys-
talline, or amorphous structure [3,6,7].
In addition to the cost benefit, there are other reasons for interests in thin films.
Some of them are the following: facility to use any substrate shapes for growth
thin film, monolithic integration between others thin films, facility of large areas
for growth thin film, the availability of numerous deposition techniques, different
configurations of the junctions for the cells, complementary films for a range of
bandgaps, deposition parameters control to improve the film properties and the
reagent reduction in the synthesis, short payback to the costumer, synthesis at
low temperature, and ability of forming of transparent modules for buildings and
homes [3,5].
Thus thin films have a special attention in the photovoltaic research and deve-
lopment. Also, the proper use of the resources are indeed for viable manufacture
with a low impact in the environment [2].
1.1.1 Semiconducting Thin Films
The compound semiconductors are the compounds between different groups of
elements, to form new thin film materials in configurations as binary, ternary and
quaternary having a specifics lattice constants, bandgap values, and index refrac-
tion for specific applications.
The group elements define the properties of the solid materials and the kind of
crystal structure [5].
The semiconductor at absolute zero kelvin acts as an insulator and has high
energy gap (Eg) between the valence band and the conduction band.
The valence band is a lower energy band that is occupied by valence elec-
trons and the conduction band is an upper energy band where the conduction of
electrons generate the current. The semiconductor conductivity is between the
metal conductivity and insulator conductivity, which is conditioned by Eg. Exam-
ple, some semiconductor with an extremely small Eg could be the InAs, with a
2
Eg = 0.36eV , compared of the Eg = 2.42eV of CdS [5,8,9].
The electrical conductivity (σ) is the inverse of the resistivity (ρ) of a material. From
the Ohm’s law, (σ) is equal of current density (J) divided by electric field strength
(E ) as is showed in Eq. (1.1).
σ =JE
(1.1)
With current density equals as J = N V qe and the electric field equals as
E =V me
τqe.
Then, the conductivity in a semiconductor is given by the Eq. (1.2).
σ =N qe
2τ
me(1.2)
Where: τ is the relaxation time, N is the number of electrons, V is the drift
velocity, qe is the charge of electron, and me is the mass of electron.
Other factors which impact the semiconductor properties are the intrinsic de-
fects that contribute to conduction. The intrinsic defects belong to the crystal struc-
ture, that is why they are known as stoichiometric defects. The vacancy defect is
called Schottky defect and the interstitial defect is Frenkel defect. The Schottky
defects are cation and anion vacancies in a lattice with an overall neutral charge
in the solid. The Frenkel defects are atoms or ions shifting at sublattice between
unoccupied site in the crystal [10].
Apart from the intrinsics defects, most of the semiconductors used in the tech-
nology applications are fabricated with extrinsic defects. The extrinsic defects are
the impurity aggregated in the crystals causing vacancies or excess of electrons.
Thus both extrinsic and intrinsic defects can contribute n-type and p-type conduc-
tivity.
The n-type semiconductor present surplus of free electrons and the p-type
present electron vacancies known as holes. In band theory, a hole represents an
electron vacant state in a band and is dynamically considered as an electron of
positive charge sited with a wave vector [8].
3
By bringing together a p-type and a n-type semiconductor, a junction is formed,
this may be homojunction or heterojunction, which has the function of separating
the charge carriers generated by the electromagnetic radiation (illumination) [5].
As seen in Fig. (1.1), a junction is formed between the same material as the p-
type and the n-type semiconductor, it is said to be homojunction and thus has the
same optical characteristics in the two semiconductors. This type of junction is
manufactured using silicon (Si) as a material in the form of wafers, and is widely
used in electronics and optoelectronics industry. When a union between different
materials of p-type and n-type semiconductivity, it is said to be a heterojunction as
shown in Fig. (1.1b). In the photovoltaic thin film technology, this configuration is
used mostly, such as CdTe and CIGS based solar cells.
n-typep-type
n-typep-type
a) b)
Figure 1.1: a) Homojunction has the same material in p-type and n-type. b) Hete-
rojunction has different material between p-type and n-type.
Thin film solar cells basically are p-n heterojunction diodes, which can ge-
nerate electric energy by photovoltaic effect when they are exposed to sunlight
[5, 11, 12]. In this way, the energy generated in solar cell is due to photovoltaic
effect, and it can explained using solar cell equation.
1.1.2 Solar cell equation
We already said the tremendous development in photovoltaic cells since Shockley
et al. contributed. The first Eq. (1.3) represents a diode behavior.
ID = I0
[exp
(V + IRs
nVT
)− 1
](1.3)
And it is called Shockley diode equation, where:
I: is the current
4
Ipv : is the current generated by incidence of light.
I0: is the reverse saturation current.
Ns: is the number of cells connected in series.
VD is the voltage.
n: is the diode ideal factor.
VT : is the thermal voltage.
The thermal voltage is represented with Eq. (1.4) [5].
VT =kBT
q(1.4)
Where,
q: is the electron charge (1.602 166 46× 10−19 C).
kB: is the Boltzman constant (1.380 650 3× 10−23 J/K).
T : is the temperature (K).
Starting from the Shockley diode equation there are three general approaches
to represent a solar cell, these are the single diode model, the double diode, and
the triple diode model [13, 14]. The single diode model is illustrated in the circuit
diagram Eq. (1.2). It shows the current source parallel to the diode and it takes
into account the shunt resistance (Rp) and series resistance (Rs).
IL Rp
Rs
+
-
Figure 1.2: Circuit diagram of single diode model for solar cell
The mathematical interpretation is represented in Eq. (1.5),
I = Ipv − I0
[exp
(V + IRs
nVT
)− 1
]−(V + IRs
Rp
)(1.5)
5
Where Rs are the series resistances and Rp are the parallel resistances. Already
in the field when a solar panel is working there are low efficiencies due the recom-
bination loss in the depletion region that were not taken into consideration in the
single diode model. For the double diode model these losses are considered. It
shows the circuit diagram, where we can already see a second diode in parallel of
the current source and the other diode in Fig. (1.3). The mathematic interpreta-
IL Rp
Rs
+
-
Figure 1.3: Circuit diagram of double diode model of solar cell
tion shows in Eq. (1.6), where it aggregates a second diode for the recombination
loss in the depletion region. For the calculation used the Levenberg-Marquardt
algorithm for solving curve fitting to obtain the I-V curves [15].
I = Ipv − I01
[exp
(V + IRs
n1VT1
)− 1
]− I02
[exp
(V + IRs
n2VT2
)− 1
]−(V + IRs
Rp
)(1.6)
1.1.3 Inorganic thin films
The suitable properties of absorber thin films for photovoltaic application are:
1. The direct of bandgap of 1 eV to 1.5 eV.
2. The optic absorption coefficient is around of 1× 104 cm−1 to 1× 106 cm−1.
3. The conductivity of the material is 0.03Ω−1 cm−1 [16].
4. Low ratio or recombination velocity of charge carriers generated.
5. High diffusion length of charge carriers.
6
6. Materials abundance for large scale.
7. Non toxic and reproducibles fabrication.
So far, the main approaches thin film photovoltaics have been dominated by
a−Si : H, CdTe, CIS & CIGS based Solar Cells [17].
Amorphous silicon (a−Si : H) Photovoltaic Semiconductor
Being a highly investigated the technology of silicon thin films have gained the
most attention by the photovoltaic industry. The a−Si : H thin films are a kind of
silicon technology with amorphous structure. Currently, the efficiency of a−Si : H
thin films are 13.6% in a triple junction by substrate configuration [18].
The material has two drawbacks, when exposed to sunlight undergoes a
degradation effect of the material known as effect Staebler-Wronski and
conversion efficiency is about half the efficiency of solar cells with silicon
wafer [19]. A typical configurations of a−Si : H thin films are show in Fig. (1.4).
i-layer
p-layer
Textured tin oxide
Silicon dioxide
Glass
n-layer
Aluminium back contact
Figure 1.4: Schematic of solar cell based on a-Si:H [20].
7
CdTe Photovoltaics
Cadmium telluride thin films are used as an absorber material due to their ideal
energy gap of 1.45 eV with direct absorption coefficient [21]. The efficiency of
CdTe thin films have achieved 22.1% by First Solar [22].
CdTe absorber layer
CdS buffer layer
Tin oxide
Glass
Back contact
Figure 1.5: Schematic of CdTe solar cell based on [20].
The techniques usually used for the deposition of CdTe are closed space sub-
limation, physical deposit by evaporation, electro-deposition, chemical spray and
electroplating. [3,4].
Some drawbacks of such solar cells are the lack of research and development
on CdTe thin films. One of the factor is the toxicity of cadmium in the environment
during the life cycle of the thin films. Another issue is the degradation of the ohmic
or the resistive contact [3,4].
CIS & CIGS Photovoltaics
Copper indium sulfide or selenide (CIS) and copper indium gallium sulfide or se-
lenide (CIGS) are materials containing elements of IB, IIIA and VIA groups of the
periodic table, which possess high optical absorption coefficients. The best effi-
ciency of CIGS thin film cell laboratory scale was 22.3 % by the company Solar
Frontier [23]. The biggest problem of this technology is the scarcity of indium.
CuInS2 has a band gap of 1.53 eV of which is suitable as an absorber material.
The research on thin films CIS and CIGS, lead to obtain a suitable bandgap to
8
CIGS absorber layer
CdS buffer layer
ZnO : Al
Contact
Glass
Molybdemun back contact
Contact Contact Contact Contact
Figure 1.6: Schematic of CIGS solar cell based on [20].
achieve high efficiencies, the technology contains of alloying or In1−xGax. These
cations to be present in the lattice prevent easy mobility of copper ions (Cu+) so
that the thin film is stable [16], and hence the device performance.
The elements involved at the fabrication of CIS and CIGS thin films increase
the complexity of the processes, limiting the reproducibility, so it is important to
have control of the stoichiometry during the deposition. The high price of In and
Ga makes this technology costlier [3,4].
1.1.4 New materials for Thin Film Photovoltaic
Perovskite
The Perovskite thin films have direct energy gap of 1.55 eV, and achieved 22.1 %
efficiency in 2015 by KRICT/UNIST [24].
Much of the research on a global level in this new material called perovskites,
in honor of Gustav Rose in 1839, are already of great interest in applications of
optoelectronics because of its low cost of using organic compounds unlike those
used in inorganic cells and because the manufacturing process. Perovskite has
a crystal structure as calcium titanate with a general formula ABX3, wich forms
octahedral geometry (Oh and octahedral cube). It has twelve coordinated cations
9
Thin Film Perovskite
TiO2
HTM
Glass
Back contact
TCO
Figure 1.7: Schematic of Perovskite solar cell based on [25].
(A, B) and six anions (X) [26,27], where A is the organic cation which are CH3NH +3
or NH2CH3NH +2 , and the other cation is the divalent metal Pb2+ or Sn2+, and the
anion is a monovalent halide which can be the (I– ,Br– , Cl– ) [28].
For applications in solar cells it is used as absorber material between an elec-
tron carrier film and a holes carrier film, where at only nanometers thickness of
deposition is sufficient [27].
CZTS
An absorber material known by its acronym (CZTS) is the quaternary semiconduc-
tor Cu2ZnSnS4, which has low toxicity, its raw materials are abundant. Recently, it
has been reported the CZTS with an efficiency of 12.6% in laboratory cells using
hydrazine based pure solution by spin coating [29].
Currently for this absorber material, there are many synthesis testings using
diverse deposition techniques to develop a inexpensive production process. For
example, the spray pyrolysis and sputtering [30]. This material is obtained by
replacing in the ternary CIS, to indium (In) by 0.5 zinc(Zn) and 0.5 of tin(Sn) [30].
It has a direct band gap of 1.5 eV, with an absorption coefficient at visible
region near 104 cm−1 and shows a kesterite crystal structure [30]. As illustrated in
Fig. (1.8), the usual configuration is a glass substrate, coated molybdenum (Mo),
10
Back contact : Mo
Absorber (p-type) : CZTS
Buffer(n-type) : CdS/ZnS
Window (n-type) : Al:ZnO
Soda Lime Glass Substrate
Grid Al/Ni
Figure 1.8: Schematic of solar cell based on CZTS [30].
absorber p-type material with CZTS, the material n-type CdS or ZnS, the window
layer of zinc oxide doped with aluminum, and a contact of aluminum or nickel.
1.2 CuSbS2 Thin Films
The cost of the production, the abundance of raw materials, and the high
efficiency absorber properties lead the CuSbS2 thin film to be innovate in this
area. CuSbS2 thin film has been reported in literature with a suitable bandgap
around of Eg=1.52 eV [16, 31, 32] and it presents p-type conductivity of
2× 10−4 Ω−1 cm−1 [16].
Chalcostibite (CuSbS2) is a compound semiconductor belongs to I-V-VI group
and exhibits an orthorhombic crystal structure with a space group Pnma (No. 62)
[16, 33, 34]. It can be observed a lead gray or gray iron color with metallic gloss
[35] with lattice parameters a=6.018 A, b=3.7958 A, and c=14.495 A [16, 33, 34].
The chemical composition (w/w %), corresponding atomic masses to obtaine the
CuSbS2 phase, are copper (25.48%), antimony (48.815%) and sulfur (25.71%)
[16].
Cu, Sb and S are low toxic materials and abundant in the earth’s crust [36]
compared with the scarcity of In, Ga, and Te [37]. Among various techniques to
11
prepare thin films, spray pyrolysis has the features and the proven technologies in
industries such as oil, automotive, and coatings parts.
1.2.1 Hypothesis
CuSbS2 thin films of suitable PV properties can be synthesized by spray pyrolysis
by varying the molar ratio of Cu, Sb and S in the precursor solution at varying
substrate temperature.
1.2.2 General objective
To synthesize thin films of CuSbS2 using the precursors of copper (Cu), antimony
(Sb) and sulfur (S) in aqueous, aqueous-alcoholic or alcoholic solution by spray
pyrolysis.
1.2.3 Specific objective
Specific objectives for this project were achieved as follows:
1. To refine spray pyrolysis set up.
2. To find a suitable molarity S/(Cu + Sb) ratio in the precursor solution.
3. To obtain the optimum parameters of substrate temperature required for a
homogeneous thin film of CuSbS2.
4. To characterize the composition, morphology, crystalline structure, elemen-
tal compositions, and electrical/optical properties of the CuSbS2 thin films.
12
2CuSbS2: a novel photovoltaic material
2.1 Structure and properties
The CuSbS2 phase has its mineral name as chalcostibite, is one of the three
phases, in the ternary system of copper antimony sulfide ternary known as
Cu3SbS4 (Famatinite), Cu3SbS3 (Skinnerite / Wittichenite) and Cu12Sb14S13
(Tetrahedrite) [38] and it is a compound semiconductor of I-V-VI groups
according to the periodic table.
It can be observed in lead gray or gray iron color with metallic gloss in its
appearance [35]. The mass density was reported as 4.95 g cm−1 and the decay
from ternary to binary is due to the low boiling point of sulfur at 444.6 C.
In the present study, the precursors used for the synthesis (CuCl2, SbCl3,
NH2CSNH2) obey these conditions, in same way the solvents (H2O, CH3CH2OH)
and the air as transport carrier of the precursor solution.
There have been reported depositions of CuSbS2 thin films by thermal evap-
oration, chemical bath, electrodeposition, and spin coating [39]. In addition, of
to obtain the CuSbS2 phase, it must be possible to have a scalable process for
mass production. The spray pyrolysis technique has the features of scalability
production as of thin films.
13
Crystal structure
It has a crystal structure of orthorhombic form as shown in Fig. (2.1) where its
lattice parameters are a=6.018 A, b=3.7958 A, and c=14.495 A; with traces of
chlorine (Cl) and iron (Fe) from the Pnma space group and crystal system class
number 62 corresponding to a bipyramidal as it has been reported in JCPDS
44-1417 and literature [16,33,34].
Its unit cell contains a total of sixteen atoms with four copper (Cu), four anti-
mony (Sb) and eight sulfur (S) atoms. The layered structure can have some ad-
vantages such as the structural stability, better charge transport properties and the
ability to form the interface structures comparing with other structural forms [40].
Figure 2.1: Orthorhombic structure of CuSbS2 phase that shows a normal view of
the unit cell [41].”Reprinted from [Mukesh Kumar and Clas Persson. CuSbS2 and
CuBiS2 as potential absorber materials for thin-film solar cells. Journal of Renew-
able and Sustainable Energy, 5(3), 2013.] with the permission of AIP Publishing.”
There were many studies reported of CuSbS2 synthesize and its crystal struc-
ture. Since 2001, Rodriguez et al. reported that CuSbS2 phase was synthesized
in a range of 350 C- 400 C and they proved that chalcostibite phase was formed
with X-ray diffraction and evaluated 20 nm cristallite size by Scherrer Eq. (4.1) [16].
Starting from 2008, Rabhi et al. deposited by thermal evaporation and annealed at
14
different temperatures. The samples below 200 C, had amorphous phase while
for the annealed samples exceeding 200 C, they formed CuSbS2 polycrystalline
structures. Rodriguez et al. used the Scherrer Eq. (4.1) to determine crystallite
size. From samples annealed at 200 C, they reported 60 nm of diameter using
the (200) plane and they observed that increasing the substrate temperature will
decreased the bandgap [42,43].
Electrical properties
The CuSbS2 thin films exhibited p-type conductivity of 2× 10−4 Ω−1 cm−1 by
chemical bath deposition in thin films [16].
In theory simulation, phase stability and defects structure using first principles,
it is found that CuSbS2 phase possesses a p-type conductivity due to the shallow
defect of copper vacancy (Vcu) with lowest formation energy in all electrochemical
potential conditions [39].
Rodriguez et al. reported a resistivity of 35 Ω cm (dark) and under light a very
low resistivity. In the test of hot probe obtained a 0.03Ω−1 cm−1 and an p-type
material [16].
Rabhi et al. presented resistivity of below 200 C annealed samples values of
3.10−2 to 9.10−2 Ω cm and for samples annealed at 200 C, they reported values
of 2Ω cm and the hot probe determined the p-type conductivity of their thin films
[42,44].
Optical properties
The CuSbS2 thin film has been reported possess a bandgap of Eg=1.52 eV, suit-
able for pv applications [16,31,32]
The optical absorption spectrum and the optical band gap of this material were
calculated theoretically by Lipping Yu et al., their calculation showed an enhance-
ment in absorption strength through the s-like valance band to p-like conduction
band since Sb is in oxidation state of 3+ (s2 p0 configuration) in this compound,
15
the absorption values were even higher than that of CuInSe2 [45] as shown in Fig.
(2.2). This is due to the sharp conduction band minimum (CBM) in contrary to the
flat band nature of CuInSe2. According to the calculations based on GW approx-
imations for the electrons self energy, the absorption coefficient rises more that
105 cm−1 above its band gap energy of 1.5 eV, which is the ideal band gap for the
best photovoltaic conversion efficiency. Experimentally direct allowed transition
across a band gap of 1.5 eV.
Figure 2.2: Calculated optical absorption spectra for Cu−V5+−VI compounds (blue) and
Cu−V3+−VI compounds (red) [45].”Reprinted from [Liping Yu, Robert S. Kokenyesi, Douglas a.
Keszler, and Alex Zunger. Inverse design of high absorption thin-film photovoltaic materials. Ad-
vanced Energy Materials, 3:43–48, 2013.] with the permission of John Wiley and Sons.”
The CuSbS2 semiconductor has a wide direct bandgap between 1.38 eV to
1.5 eV [16,39]. The optical absorption coefficient over 104cm−1 [39] is suitable for
terrestrial solar cell. In the transmission of CuSbS2 with a 900 nm of wavelength
results with 50% of transmission, then the absorption coefficient (α) is obtained
with Eq. (2.1), where d is the thickness, R is the reflectance, and T% is the trans-
mittance data [46].
α =1d
ln(
(1− R)2
T
)(2.1)
Now, the bandgap can be calculated, through (hv ) vs (αhv )n plot, extrapolating the
linear region to τ [45]. (α hv)n relation shows in Eq. (2.2), where h is the Planck’s
16
constant, A is a constant, v is frequency of the photon and n has a different
values 2, 1/2, 3/2. For this case, n = 2 value due to direct bandgap reported for
CuSbS2 [47].
(αhv )n = A(hv − Eg) (2.2)
2.2 Synthesis methods
There are different deposition techniques for thin films, we can classify into phys-
ical and chemical deposits. Different types of physical depositions as Laser ab-
lation, Sputtering, Molecular beam epitaxy (MBE), and Physical vapor deposition
(PVD) have been reported in the literature for thin films [48].
For the chemical deposition of thin films is divided into two types, gas phase re-
action and solution phase reaction [48,49]. Gas phase methods include chemical
vapor deposition (CVD), and atomic layer epitaxy. For solution phase reaction
include Spray Pyrolysis, Sol-Gel, centrifugal thin film, immersion thin film, and
chemical bath deposition (CBD) [50].
CuSbS2 thin films have been obtained by chemical bath deposition [16, 50], ther-
mal vacuum evaporation [43,51], electrodeposition [52–55], spin coating [39], hy-
drid of CBD & TVE [31, 46, 47], and spray pyrolysis [56–61], which will be briefly
explained below.
2.2.1 Chemical bath deposition (CBD)
Chemical bath deposition is commonly used for thin films deposition due its
simplicity, low cost, scalability and viability as its advantages compared to other
techniques. There are basic chemical reagents used for the synthesis of CuSbS2
thin films. They are antimony trichloride (SbCl3), acetone ((CH3)2CO), sodium
thiosulphate (Na2S2O3), copper (II) chloride (CuCl2) dimethylthiourea
(CH3NHCSNHCH3) and water (H2O) [16,50].
17
There are two ways of chemical procesees to form CuSbS2. One way, the
deposition of Sb2S3 thin film and then the deposition on this one, the CuS
followed by heating [16] as shown in Table 2.1.
Table 2.1: Two baths [16]
Step Description
1 1st bath preparation stirred continuously at 10 C for 4 h: 5 mL of acetone + 1.3 g of
SbCl3 + 50 mL of 1M Na2S2O3 at 10 C + 145 mL of cold deionized water
2 50 mL of 1M Na2S2O3 at 10 C poured over of solution and stirred continuously.
3 145 mL of cold deionized water poured over the solution.
4 Glass substrates were placed vertically in the beaker bath and CBD was prepared at
10 C for 4 h
5 Coated substrates were changed to a fresh bath by the same time. After, substrates
were removed from the bath and rinsed with distilled water. Then, they were dried.
6 The 2nd bath, 5 mL of 0.5 M CuCl2 · 5 H2O mixed with 9 mL of 1 M Na2S2O3 solution.
7 10 mL of 0.5 M dimethylthiourea were pour over and mixed to the solution.
8 79 mL distilled water was poured over the beaker.
9 Glass substrates were placed vertically in the beaker bath and CBD was prepared at
70 C by 2 h.
10 Substrates were removed from the bath and rinsed with distilled water.Then they
were dried.
Second method is the formation of the CuSbS2 thin films from single bath con-
taining (Cu), (Sb) and (S) sources [50].S.C.Ezugwu et al. prepared CuSb2S2 from
chemical bath containing antimony trichloride (SbCl3), acetone, sodium thiosul-
phate (Na2S2O3), and copper (II) chloride (CuCl2) as precursors for synthesis of
CuSbS2 thin films [50]. They synthesized as shown in Table (2.2).
2.2.2 Thermal Vacuum Evaporation(TVE)
Rabhi et al. prepared CuSbS2 thin films on glass substrates by vacuum evapora-
tion of CuSbS2 powder, using heated molybdenum boats [42, 43]. The pressure
18
Table 2.2: One baths [50]
Step Description
1 In 5 mL of acetone was added 1.3 g of SbCl3
2 25 mL of 1M Na2S2O3 poured over of solution.
3 5 mL of 0.1M CuCl2 poured over the solution.
4 15 mL of H2O poured over the solution.
5 Glass substrates immersed on the baker at 25 C with four dip times(1 h, 1.5 h, 3 h,
and 3.5 h).
6 Substrates were removed from the bath and rinsed with distilled water.Then they
were dried
was at 10−5 Torr, in vacuum atmosphere for 2 h in a range of temperature of 130 C
to 200 C.
Fadhli et al. deposited CuSbS2 thin films by TVE at 100 C onto glass substrates
by 1 h. Then, they annealed at 250 C for 60 min and 120 min the thin films [51].
2.2.3 Chemical bath deposition & thermal evaporation
C.Garza et al. formed in three processes the CuSbS2 thin films, first a formation
of Sb2S3 thin films by chemical bath deposition as described below. First
process, on glass substrates by chemical bath deposition were made Sb2S3 thin
films. To prepare the bath mixture the reactants: 1) 650 mg of SbCl3 dissolved in
2.5 ml of acetone. 2) Added 25 ml of 1 M Na2S2O3 pre-cooled. 3) Added 72.5 ml
of deionized (pre-cooled) water. 4) Stirred well. 5) In a Petri dish placed in
horizontal position the glass substrates (75 mm x 25 mm x 1 mm), then slowly
pour the solution into the petri with a t = 3h of deposition. Then in a vacuum of
10−5Torr on a molybdenum boat a copper wire (99.99%) was evaporated on the
glass/Sb2S3. With a in situ quartz crystal thickness monitor fixed as 20, 30, 40,
and 50 nm. and third annealed the substrates to form the CuSbS2 thin films [31].
Finally, Sb2S3 / Cu thin films were heated at 300 and 380 C in vacuum of
19
10−3Torr for 1 to 2 h [31].
R.E. Ornelas-Acosta et al. prepared Sb2S3 by chemical bath deposition like
C.Garza et al. C.Garza et al. only added a second pathway, where the
glass/Sb2S3/Cu thin films were annealed at 350 C, 375 C, 400 C in low vacuum
(10−3 Torr) for 1 h in a vacuum furnace [46,47].
2.2.4 Electrodeposition
D. Colombara et al. deposited CuSbS2 using precursor films of a molar ratio (1:1)
of Cu:Sb by electrodeposition from aqueous solutions onto Mo coated glass
substrates. In two configurations viz stacked and co-electroplated. In
co-electroplated technique, they chose the thickness of 2 µm, and the
temperature between 200 C and 500 C, for 5 to 960 min, and the heating rate
between 5 and 600 C min−1. In a graphite box with elemental sulfur atmosphere
the metal precursor films converted to the corresponding sulfides [52].
Ikeda et al. fabricated metallic stacks of Cu on Mo/glass substrate by
electrodeposition won an aqueous solution containing 15 mmol dm−3 CuSO4 and
15 mmol dm−3 citric acid at -0.4 V. After Cu-film deposited, an Sb film was
deposited on the Cu/Mo/glass to an aqueous solution containing 15 mmol dm−3
K2(Sb2(C4H2O6)2) and 50 mmol dm−3 tartaric acid at -0.3 V. With a fixed
temperature at 24 C by immersing the electrolyte solutions in a thermostatted
water bath. The amount of deposited metal was estimated by the electric charge.
In this study, metallic stacks with Cu/Sb atomic composition ratios. Thus obtained
metallic stacks were sulfurized to form CuSbS2 films using a three-step
temperature profile. First, the precursor film was heated to 510 C in Ar, and then
heating at this temperature was continued for 60 min. In the second step, the film
treated at 510 C was cooled to 450 C in Ar; sulfurization of the film was
performed by introduction of hydrogen sulfide (H2S, 5% in Ar) at this temperature
for 30 min. Finally, the film was allowed to cool down to ambient temperature in
Ar.
20
The XRD showed that the films were due rich in CuS, and CuSbS2 phase. The
formation temperature of CuSbS2 was at 300 C and the excess sulfur increase
the formation of Sb2S3 [52].
Ikeda et al. did a water bath at 24±1 C where they immersed an electrolyte cell
of aqueous solution containing 15 mmol dm−3 of CuSO4 as a precursor of Cu and
15 mmol dm−3 with citric acid (C6H8O7) with a cell configuration of a three
electrode cell where Mo/glass substrate like a working electrode, Pt wire as a
counter electrode and an Ag/AgCl as a reference electrode. After the Cu thin film
formation covering the Mo/glass substrate, the electrolyte solution changed for
an aqueous solution containing 15 mmol dm−3 of K2(Sb2(C4H2O6)2) and
50 mmol dm−3 of tartaric acid(C4H6O6) maintaining the 24±1 C of the water
bath. Finally a sulfurization with hydrogen sulfide in Ar atmosphere with a three
step temperature profile(510-450- 25 C) for 30 min [53].
Septina et al. reported that in water bath at 25 C, they immersed an electrolyte
cell of aqueous solution containing same parameters as Ikeda et al. [53], with pH
adjusted to 1.3 by the addition of H2SO4, maintaining the 25 C of the water bath.
Finally a sulfurization with hydrogen sulfide in Ar atmosphere with a three step
temperature profile (510-450-25 C) for 30 min [54].
Rastogi et al. mixed 1 mol of choline chloride (C5H12ONCl) and 2 mol of urea
((NH2)2CO) at 80 C under stirring. After, they obtained the Cu2+ from anhydrous
salts CuCl2 (99%) and the Sb3+ ions were derived from SbCl3 (99% ), with molar
concentrations of Cu to Sb of 1:1; 1:1.4; and 1:0.71stoichiometric ratios. The
sulfur ions were sourced by dissolving 10 mM sodium thiosulfate, Na2S2O3 (99%)
to the clear ChCl–urea solution containing CuCl2 and SbCl3 [55].
2.2.5 Spin coating
Yang et al. reported deposition by spin coating of 2 mL of hydrazine solution. They
containing0.226 g of Cu and a 0.175 g of S. They stirred the solution for few days.
21
In parallel process, 2 mL of hydrazine were dissolved 0.484 g of Sb and a 0.445 g
of S. It stirred for few days too. The two solutions were mixed with a Cu/Sb molar
ratio of 0.9:1 and stirred t≥ 2 h before deposition. On FTO substrates, the film was
deposited by spin coating at 500 rpm for 10 s, and 2100 rpm for 45 s. Dried on a
preheated blade at 100 C for 10 min and then annealed at 250 C by 3 min. Did
by 4 times the spin coating deposition and the soft bake, then a final annealing at
350 C for 10 min [39].
2.2.6 Spray pyrolysis thin films (SPTF)
The spray pyrolysis is a chemical deposition technique that was developed to
deposit sulfides and selenides thin films.
In 1966, R.R. Chamberlin y J.S. Skarman published a deposition technique
thin films sulfides and selenides, that was presented as the spray of solution on
heated substrates, with the condition that the precurs elements were contained
solely in the precursor solution to be sprayed [62].
Given the interest in the deposition of metals and oxides, J.C. Viguie and J.
Spitz explained a chemical vapor deposition at temperature range <500 C and a
pressure of 100 kPa. It was described that the chemical reaction shall could be
at low temperatures without vacuum. They classified four stages of the deposition
mechanism at various substrate temperatures as shown in Fig. (2.3) [63].
A-Process: The drops are spread over the surface of substrate where the sol-
vent is evaporated and the dried precipitate precursors decomposition takes
place.
B-Process: The solvent is evaporated before falling the drops on the substrate
surface, leaving a precipitate which decomposes on the substrate.
C-Process: The solvent evaporates from the drops nearby the substrate surface.
The precipitated solids melt and sublime, and the vapor diffuses on the subs-
trate by heterogeneous reaction.
22
D-Process: At high temperatures, the drops precipitate and sublime. A chemical
reaction of precursors effect in vapor phase near the substrate surface.
A B C D
Figure 2.3: Deposition process with increasing substrate temperature. (A) The
solvent is evaporated and the decomposition of dried precipitate precursors takes
place. (B) The drops spread over substrate and the solvent is evaporated before
the falling drops on the substrate surface, leaving a precipitate which decomposes
on the substrate. C: The solvent evaporate at the drop nearby on the substrate
surface. The precipitated solids melt and sublime, the vapor diffuse in the subs-
trate in a heterogeneous reaction. D: At high temperatures, the drops precipitate
and sublimate. A chemical reaction of precursors effect in vapor phase near the
substrate surface [63].
Spray pyrolysis is used due this does not require vacuum, cost efficient, coat-
ings complex geometry, high quality layers, uniformity of film, and scalability.
By spray pyrolysis technique, it can be synthesize dense and porous deposits
films, with controlled thicknesses. It is also one of the preferred techniques for
making powders and ceramic coatings [64].
23
The basic parts that constitute the spray pyrolysis equipment are the
precursor solution container, the substrate heater, the spray nozzle, and the
temperature controller. The spray pyrolysis technique was first used in 1966 by
Chamberlin and Skarman to deposit CdS films for photovoltaic applications. The
feasibility and scalability of this technique due to its reproducibility in the process
and easiness for depositing noble metals, metal oxides, spinel oxides,
chalcogenides and superconductor compounds, place it as a preferred technique
over many other [65].
Theoretical aspect
The process of depositing thin films by spray pyrolysis includes many physical
and chemical phenomena, and to date only been reported approaches for film
formation. The entire process generally is divided into three stages, starting with
the preparation of the solution, atomization of the solution, transportation of the
atomized solution, to the hot substrate, decomposition of precursors and
nucleation of the film on the substrates.
In the preparation of the precursor solution, care should be taken to choose
precursors from the source elements to form the thin film, and a suitable solvent
to dissolve the precursor solutes.
The parameters affect the growth, the morphology, and the properties of the thin
films are atomization, aerosol transport, decomposition, substrate surface
temperature, precursor solution and substrate-nozzle distance.
1. Atomization: The atomization of the precursor solution is a very important in
making the type of spray that was used partly because depending on the
application the ideal atomizer is adjusted. There are several types of atomizers,
such as the air blast, ultrasonic, and electrostatic. In a study electrostatic
atomizers stability have the load drops isolated with Rayleigth study, depending
on the parameters of dew, there are different types of behavior of the solution
was atomized. Currently, there are different atomizers where it can obtain a
24
various types of droplets and distributions. As examples there are the cone-jet,
multi-jet, plane-jet, and dona-jet [48].
2. Aerosol transport: During aerosol transport process, the droplets travel from
nozzle to substrate surface. Where they travel as liquid phase or they could
change to a gas phase by the heat radiation near the substrate surface. There
are forces those affect the trajectory and the evaporation of the droplets, these
forces are the gravitational, electric, thermophoretic and Stokes [48].
3. Decomposition: The precursor droplets carry out a chemical reaction almost
since it is close to the substrate surface, during spreads and after that. Viguie
and Spitz observed this process with detail, and they proposed four process
those can be occur [48,63] as showing in the Fig. (2.3).
4. Substrate surface temperature: The temperature in surface substrate
defines the morphology, the structure, and the properties of the thin films formed.
In morphology, it was reported that the films had changed from dense to highly
porous surface [48]. Also, for the films structure, it was observed that certain
preferential plane orientation appeared in a direct relation with the film thickness.
The optical and electrical properties are effected by the homogeneity of the film,
that it influenced by temperature [48]. Due it takes part in the solvent evaporation
process, it affects the droplets those impacted onto substrate surface, and it
changes the precuror solution in the chemical reaction or the precursor
decomposition, so it is an important parameter in the spray pyrolysis [48].
5. Precursor solution: It is the mixture of the solutes (salts), the solvent and in
some cases additives, where it can varying the molar ratio of them for pursuit
specifics properties and structures due they affect the chemical and physical
properties of the precursor solution [48].
6. Substrate-Nozzle distance: The nozzle distance is defined by the
manufacturers. The manufacturers design and test nozzles with a specif distance
range functional to work. The substrate-nozzle distance, it is known as
spray distance. It is search the theoretical coverage on the substrate
surface, and this depends of the spray distance, the spray angle, the
25
viscosity of precursor solution, nozzle capacity and spraying pressure
(Http://www.spray.com/cat76/automatic-m/offline/download.pdf, 16) [66].
State of art
S. Manolache et al. prepared CuSbS2 thin films by spray pyrolysis on two types of
substrates: First on TCO substrates, and second on TCO/dense TiO2/nanoporous
TiO2 substrates. They used copper(II) chloride dehydrate(CuCl2 · 2 H2O), anti-
mony(III) acetate ((CH3COO)3Sb, thiourea (H2NCSNH2) as precursors of CuSbS2
thin films, in aqueous solution with small amounts of HCl. The temperature was
optimized at 240 C with a carrier gas Argon (Ar), 1.2 bars of pressure, and at
27 cm of distance between fixed nozzle and heater [56–58].
I. Popovici et al. reported the formation of CuSbS2 thin films with different molar
ratios as showed in Table (2.3), on a FTO conductive glass substrates heated
by sprayed with an aqueous solution of copper (II)-chloride dehydrate (Schar-
lau, CuCl2 · 2 H2O, min 99 % ), antimony (III) acetate (Alfa Aesar, (CH3COO)3Sb,
99.99%), thiourea (H2NCSNH299 % and the same S. Manolache et al., they added
few drops of HCl. The innovation in this synthesis, was that they added 100 ppm
sodium maleate-methyl metacrylate (Hydrophilic polymer, HFL) and in other sam-
ple, added 100 ppm sodium maleate-vinyl acetate (hydrophobic polymer, HFB).
At temperature of 240 C, carrier gas (air) with pressure of 1.5 bar and distance of
between nozzle and substrates of 25 cm, and pause of 60 seconds between two
sprayed sequences [59]. They observed that increasing antimony in the precursor
solution affect the grain size and the band gap increase.
Thiruvenkadam et al. prepared the precursor solution at 0.01 M of CuCl2, 0.003
M (to 0.03 M in steps of 0.006 M) of Sb(CH3CO2)3, 0.006 M of SC(NH2)2, and
small amount of acetic acid in a aqueous solution. In the sprayed rate was at
5 mL min−1 onto a glass substrate at 240 C to 320 C with increase of 20 C [60,
61].
26
Sample Cu : Sb : S Sample Cu : Sb : S
# (molar ratio) # (molar ratio)
A 1:1.48:13 E 1:4.4:13
B 1:1.97:13 F 1:1.84:13
C 1:2.48:13 G 1:1.84:13
D 1:3.47:13 H 1:1.84:13
Table 2.3: Precursor solution composition [59].
27
3Experimentation
3.1 Introduction
In the literature there are only a few articles for copper antimony sulfide synthesis
by spray pyrolysis; From the reports of Manolache et al., they used argon as
carrier gas [56–58], in that way, we preferred air due to its lower cost than argon.
Other issue, as Manolache et al. and Popovici et al. reported the use of HCl
for their synthesis to increase the solubility of the precursors [56–59].
Thiruvenkadam et al. used acetic acid for the precursor solubility [60,61].
Based on the reports, we designed the experimental conditions of CuS as A
product, Sb2S3 as B product, CuSbS2 as C and D product formulation. The A
product or CuS, to achieve the experience in the synthesis and deposition of
binary thin films by spray pyrolysis technique. The B product or antimony sulfide
thin films, it started to recycle the precursors from bath depositions, where the
Sb2S3 nanoparticles were obtained by laser ablation from tablets of chemical
bath wastes. The C and D products were the main synthesis of this research, the
difference between them was that in the C-product, antimony(III) acetate was
used as precursor for antimony and in D-product was used SbCl3 as antimony
precursor. The copper and sulfur precursors were the same for both products. In
Fig. (3.1) shows a flow chart of the experimentation design to synthesize CuS,
Sb2S3, and CuSbS2 thin films.
28
Experimentation
• Varying molar ratio
• Preparing precursor solution
• Checking solubility and time stability
• Spraying solution on heated glass sub-
strates
CuSO4 · 2 H2O + NH2CSH2N 250 C−−−−−−−−−−→H2O/CH3CH2OH
A−product (3.1)
Sb2S3 + NH2CSH2N 250 C−−−−−−−−−−→H2O/CH3CH2OH
B−product (3.2)
CuCl2 + (CH3COO)3Sb + NH2CSH2N 250 C−−−−−−−−−−−−−→H2O/CH3CH2OH/HCl
C−product (3.3)
CuCl2 + SbCl3 + NH2CSH2N 250 C−−−−−−−→CH3CH2OH
D−product (3.4)
Observating film and obtaining the properties
Annealing films, characteri-
zating, and reporting data
• CuS
• Sb2S3
• CuSbS2
Figure 3.1: Experimental chart
29
3.2 Materials
3.2.1 Reactants
The aim was to prepare a low-cost synthesis for CuSbS2 thin films, thus, low
temperatures and inexpensive materials were preferred. The ethanol was chosen
as solvent due to its high volatility.
The SbCl3 was used as precursor of antimony based on a report of 2001 for
Sb2S3 thin films by chemical bath deposition [16]. The used of CuSO4 ·5 H2O
was reported for coppper sulfide hollow spheres by hydrothermal conditions [67].
For the CuSbS2 thin films synthesis by spray pyrolysis it was reported the use of
(CH3COO)3Sb as a precursor for antimony too, but by adding HCl to increase its
water solubility [56–58]. The CuCl2 was used as a precursor of copper for
CuSbS2 thin films by chemical bath deposition as reported by Ezugwu et al. [68],
although it could also be CuCl2 ·2 H2O as a precursor as reported by Manolache
et al. [56–58].
Even when Na2S2O3 has been employed in chemical bath deposition of
CuSbS2 [16], the H2NCSNH2 was preferred as precursor for the sulfur, because
the decomposed species are volatile [56–58]. These materials are shown in
Table (3.1).
The synthesis of copper sulfide precursor solution was made with
CuSO4 ·5 H2O, NH2CSH2N, and deionized water. For the synthesis of antimony
sulfide, the precursor solution was made with Sb2S3 nanoparticles, NH2CSH2N,
and deionized water.
Synthesis CuSbS2 was done with two different precursor solutions. The first
precursor solution set was prepared by dissolution of CuCl2, (CH3COO)3Sb, and
NH2CSH2N in deionized water, CH3CH2OH, HCl, and HNO3. The second
precursor solution set was prepared with CuCl2, SbCl3, NH2CSH2N, deionized
water and CH3CH2OH.
30
Table 3.1: Materials for experiments.
Formula Assay Name Brand
SbCl3 ≥ 99% Antimony(III) chloride Sigma-Aldrich
CuCl2 99% Copper(II) chloride, anhydrous Acros Organics
NH2CSH2N 99% Thiourea Fermont
(CH3COO)3Sb 99.99% Antimony (III) acetate Aldrich
CuSO4 ·5 H2O ≥98% Copper(II) sulfate pentahydrate Meyer
HCl 34 - 36% Hydrochloric acid Fermont
CH3CH2OH 99.7% Ethanol Fermont
H2O - Deionized water -
3.2.2 Spray Pyrolysis equipment
The spray pyrolysis equipment consisted of the following parts as shows in the
Fig. (3.2).
• Laboratory extractor hood
• Pneumatic valve
• Air nozzle # 1
• Pneumatic push-in fittings
• Rigid hose
• Flexible hose
• Separation funnel valve
• Step motor
• Micro limit switch roller lever arm
• Heater
Spray pyrolysis procedure
We set two distances, between nozzle and heater at 25 cm and distance between
micro limit switches for linear movement of the nozzle at 32 cm.
1. Set at 25 cm distance between nozzle and heater.
2. Set at 32 cm distance between micro limit switches.
3. Placed the cleaned substrates on the heater plate’s surface.
4. Set the heater at 250 C.
5. Pour the precursor solution in the 500 mL separatory funnel.
31
1 2
3
4
Figure 3.2: 1) General view of the spray pyrolysis equipment. 2) Zoom of the
prototype of the spray pyrolysis. 3) The movement parts of the spray. 4) The
stainless steel air nozzle.
6. To set the air pressure at 30 psi.
3.2.3 Substrate cleaning
Glass substrates (Corning R©, 25 mm x 75 mm x 1mm) were used for the deposit.
The substrates were contaminated with dusties/fuzzies and oil. It was reported in
literature that cleaning process of substrate affect the reproducibility of the films
[69]. The glass substrates were immersed in deionized water with liquid neutral
detergent (Jalmek R©). Then we carved with a flannel to remove completely the oil
or dusty. After the substrates were rinsed of first with deionized water and then
with isopropyl alcohol. Finally, we dried them in hot air.
32
3.3 Synthesis of Copper sulfide
Stock solution of CuSO4 ·5 H2O at (1 M) concentration in 100 mL of Deionized wa-
ter (DI water) was prepared. The molar mass of CuSO4 ·5 H2O is 249.68 g mol−1
as solute. Where 1 M = 1 mol L−1 and 100 mL = 0.1 L. The CuSO4 ·5 H2O mass
needed was calculated multiplying volume × Molar Concentration × Molar Mass.
(0.1L)(1mol L−1)(249.68g mol−1) = 24.97g
Then, 24.97 g of CuSO4 ·5 H2O were dissolved in 100 mL of DI water. For
NH2CSH2N with P.M. = 76.12 g mol−1, it was prepared stock solution of Thiourea
at 0.1 M in 100 mL, calculating the mass needed with Eq. (3.5).
(0.1L)(1mol L−1)(76.12g mol−1) = 0.7612g (3.5)
CuSO4 ·2 H2O + NH2CSH2N 250 C−−−−−−−−−→H2O/CH3CH2OH
A−product (3.6)
The experiment steps showed below as the Fig. (3.1),the synthesis were
prepared corresponding to the Table (3.2) in 250 mL beaker.
1. First, CuSO4 ·5 H2O(0.01 M) was dissolved in solvent (water/ethanol) ac-
cording Table (3.2).
2. Then, H2NCSNH2 was added and stirred in the solution at 7500 rpm during
40 min and only in 11 sample was 5 mL Ethylene glycol to improve solubility.
3. Finally, the preheated glass substrates were sprayed with the solution at
conditions indicated in Table (3.2).
Observations
The precursor solution was only for five samples can to perform with all the solu-
tion, the others samples presented precipitation in the precursor solution during
the deposition.
33
Table 3.2: Experimental data of copper sulfide synthesis.
Sample CuSO4 · 5 H2O NH2CSH2N DI water Temperature Time Pressure
(0.01 M) mL (0.1 M) mL mL C min psi
1 1 20 89 300 - 360 11 30
2 1 10 89 200 11 30
3 1 10 89 200 - 250 7 50
4 1 10 89 250 - 230 9 50
5 1 10 89 250 4 50
6 2 20 178 250 5 40
7 1.1 11 99 150 8 30
8 1.1 11 97.9 200 33 30
9 2.2 22 195.8 235 - 250 43 30
10 1 10 89 200 - 235 9 30
11* 2 20 173 200 - 250 30 30
12 2 20 178 200 - 250 30 30
13 1 10 79 250 15 40
14 2 20 79 250 8 40
15 1 10 79 200 8 40
CuSO45H
2O (1M)
Thiourea (0.1M)
b)
a) c)
d)
e)
f)
Figure 3.3: a)Stock solutions of a)CuSO4 ·5 H2O at (1 M) concentration in 100 mL of DI
water. b) Thiourea at 0.1 M in 100 mL. c) samples were prepared with — ration molar.
d) samples were synthesized with — ratio molar. e) samples were prepared with – ratio
molar. f) samples were prepared with — ratio molar.
34
3.4 Synthesis of antimony sulfide
Sb2S3 + NH2CSH2N 250 C−−−−−−−−−→H2O/CH3CH2OH
B−product (3.7)
The experiment steps as Fig. (3.1) were realized with the data of the Table
(3.3).
Sb2S
3 (Nanoparticles) Thiourea (0.1M)
b)a) c)
d)
Figure 3.4: Stock solutions of a)Sb2S3 nanoparticles from laser ablation in 100 mL of DI
water. b) Thiourea at 0.1 M in 100 mL.
1. Sb2S3(ac) nanoparticles were poured in a 250 mL beaker with ethanol.
2. Then, H2NCSNH2(ac) was aggregated in the solution.
3. After, deionized water was poured and stirred at 7500 rpm during 5 min.
4. Finally, Precursor solution was sprayed at conditions according Table (3.3)
onto the heated substrates.
Observations
It was observed the films grew during the spray pyrolysis, but after the precursor
solution was done, the substrate temperature was increased very fast even
though the heater was turned off to cool the samples, the films were evaporated.
35
Table 3.3: Experimental data of antimony sulfide synthesis.
Sample Sb2S3
mL
NH2CSH2N (0.1 M)
mL
DI-water/Ethanol
mL
Temp.C
Time
min
Pressure
psi
6 10 10 30 / 50 250 12 30
7 20 20 30 / 30 250 14 30
8 30 14.5 25.5 / 30 250 16 30
9 50 14.5 25.5 / 50 270 6 30
36
3.5 Synthesis of CuSbS2 with (CH3CO2)3Sb as Sb
precursor
CuCl2 + (CH3COO)3Sb + NH2CSH2N 250 C−−−−−−−−−−−−→H2O/CH3CH2OH/HCl
C−product (3.8)
The experiment steps as Fig. (3.1) were realized with the data of the Table (3.4)
and they are presented below.
1. In a 250 mL beaker with deionized water and ethanol according Table (3.4)
for each sample, (CH3COO)3Sb(aq) was poured.
2. Second, CuCl2(aq) was added to the solution.
3. Third, H2NCSNH2(aq) was poured in the beaker.
4. Then,HCl was dissolved in the solution.
5. After, the solution was stirred at 7500 rpm during 20 min.
6. Finally, On the preheated substrates were sprayed the precursor solution at
conditions indicated in table 3.4.
Table 3.4: Experimental data of copper antimony sulfide synthesis with
(CH3COO)3Sb.
Sample DI water Ethanol (CH3CO2)3Sb CuCl2 NH2CSH2N HCl Temperature Time
# (0.01 M) (0.01 M) (0.1 M)
mL mL mL mL mL mL C min
10 30 40 10 10 10 5 250-320 19
11 25 40 10 10 10 5 300-345 22
12 0 45 20 20 10 10 250-320 9
13 20 25 30 30 10 5 300-345 9
Observations
The films were formed on the substrates, but those experiments were not appro-
priate for the equipment, because the HCl corrodes the stainless steel nozzle.
And the acid was necessary for solubility of the (CH3COO)3Sb.
37
3.6 Synthesis of CuSbS2 using SbCl3 as Sb precur-
sor
CuCl2 + SbCl3 + NH2CSH2N 250 C−−−−−−→CH3CH2OH
D−product (3.9)
We obtained the CuSbS2 thin films using precursor solutions were prepared with
SbCl3, CuCl2 and H2NCSNH2 at different molar ratios. The experiment steps, as
seen in Fig. (3.1), were realized with the conditions of Table (3.5).
1. In a 100 mL beaker, SbCl3 was dissolved and stirred in ethanol (CH3CH2OH)
at 4500 rpm during 5 min.2. CuCl2 was stirred with ethanol at 4500 rpm during 5 min in a 100 mL beaker,3. As same, H2NCSNH2 was dissolved in ethanol and stirred at 4500 rpm dur-
ing 5 min in a 100 mL beaker.4. The three solutions were mixed in a 500 mL Erlenmeyer flask and then
ethanol was added until 500 mL.5. The solution was stirred at 1000 rpm at 60 C for 5 min to dissolved it.6. The heated substrates were sprayed with the solution at conditions indicated
in Table (3.5).
Thiourea
a)
SbCl3
CuCl2
Ethanol
Spraying
Mixing
b)
d)
c)
Figure 3.5: a)Reactants. b)Precursor solutions. c) Precipitated and solubility
solutions. d) Sprayed solution.
38
Table 3.5: Experiments using CuCl2,SbCl3, and H2NCSNH2
Sample Molar ratio CuCl2 SbCl3 H2NCSNH2 Pressure Temperature Volume Time
# Cu : Sb : S (mol-L−1) (mol-L−1) (mol-L−1) (psi) (C) (L) (min)
14 1 : 0.96 : 05.53 0.0109 0.0104 0.0.0601 30 398 0.105 8
15 1 : 0.98 : 05.47 0.0110 0.0107 0.0.0602 30 426 0.105 31
16 1 : 0.85 : 05.01 0.0110 0.0094 0.0.0551 30 398 0.115 42
17 1 : 0.81 : 13.02 0.0104 0.0084 0.0.1359 30 382 0.250 25
18 1 : 1.02 : 05.67 0.0157 0.0160 0.0.0889 30 382 0.150 17
19 1 : 0.44 : 15.00 0.0221 0.0097 0.0.3307 30 382 0.250 61
20 1 : 0.82 : 13.20 0.0104 0.0085 0.0.1370 30 310 0.250 32
21 1 : 0.74 : 12.10 0.0114 0.0084 0.0.1382 30 310 0.250 32
22 1 : 0.84 : 12.98 0.0106 0.0089 0.0.1377 30 310 0.500 45
23 1 : 0.88 : 12.96 0.0106 0.0093 0.0.1378 30 310 0.500 46
24 1 : 0.71 : 14.30 0.0142 0.0100 0.0.2032 30 310 0.500 45
25 1 : 0.84 : 13.45 0.0107 0.0090 0.0.1440 30 310 0.250 22
26 1 : 0.97 : 12.92 0.0114 0.0109 0.0.1466 30 315 0.250 30
27 1 : 0.79 : 11.67 0.0119 0.0093 0.0.1390 30 448 0.250 30
28 1 : 0.65 : 17.31 0.0110 0.0071 0.0.1905 30 310 0.300 17
29 1 : 1.08 : 13.47 0.0100 0.0108 0.0.1348 30 310 0.250 22
30 1 : 3.86 : 47.50 0.0035 0.0136 0.0.1674 30 310 0.750 90
31 1 : 0.82 : 12.37 0.0111 0.0090 0.0.1370 30 226 0.500 22
32 1 : 0.81 : 11.64 0.0117 0.0094 0.0.1364 30 226 0.500 40
33 1 : 0.66 : 12.34 0.0124 0.0081 0.0.1527 30 226 0.250 20
34 1 : 0.46 : 08.35 0.0163 0.0074 0.0.1360 30 226 0.250 20
35 1 : 0.54 : 10.07 0.0143 0.0077 0.0.1443 30 226 0.500 40
36 1 : 0.81 : 13.02 0.0104 0.0084 0.0.1359 30 282 0.250 25
Determination of the values of the parameters for the CuSbS2
synthesis
The values of the parameters were determined from the state of the art and the
datasheet of the equipment. For this synthesis, we took account the following
parameters:
Molar ratio: Popovici et al. reported a molar ratio of 1:1.48:13 with HCl for the
solubility of the precursor solution and 1:1.84:13 with polymer additives as
sustite of the acid [59]. Manolache et al. reported a molar ratio starting from
39
1:2.57:5.71 aggregating HCl to increase the solubility of the Antimony (III)
Acetate [58]. These two reports are for spray pyrolysis deposition. We did
not use HCl for this synthesis of CuSbS2, but we had precipitation with the
antimony acetate, so we changed for Antimony (III) chloride, and after the
mixed of the precursors, we stirred and warmed at 70 C for 30 min. Due to
the sulfur loss during the pyrolytic process, the sulfur was determined as in
the molar ratio of Popovici et al. [59]. Also we increased above 13, but the
precursor solution was precipitated due to thiourea saturation.
Pressure: This parameter is constant at 30 psi due the atomization works
efficiently according to the manufacturer’s datasheet of the nozzle
(http://www.spray.com/cat76/automatic/). The pressure can be determined
with accuracy due of the graduated pneumatic valve and by the constant
airflow of the laboratory. It affects the surface temperature of the substrate
and the aerosol transport.
Temperature: Manolache et al. reported the synthesis of thin films of CuSbS2 by
spray pyrolysis. They obtained CuSbS2 films at 240 C with 21 psi, and they
observed with X-Ray Diffraction that the crystal structure corresponds to the
CuSbS2 according PDF# 44-1417 [58]. Also, Thiruvenkadam et al. reported
synthesis of CuSbS2 at 300 C with 1.40 eV. This temperature was referring
to the heater temperature, we started in the range of 240 C to 300 C as
reported in literature [58,61].
Volume: This value was assigned since we had only one separating funnel of
0.500 L and other of 0.250 L for the containment of the precursor solution.
Deposition time: This value depends of the precursor solution volume. For
0.500 L results around 40 to 46 min and For 0.250 L results around 20 to 25
min.
40
4Characterization of CuSbS2 thin films
4.1 Introduction: Choosing the samples
We selected the D-17, D-22 and D-23 samples to analyze their structure, mor-
phology, electrical, and optical properties. The conditions for the synthesis of the
selected samples are given in Table (4.1). Visually, they present the dark gray
color described by Rodrıguez-Lazcano et al. [16] and it is visually appreciated,
uniform films without porosity.
Table 4.1: Experimental conditions of D-17, D-22 and D-23 samples using
CuCl2,SbCl3, and H2NCSNH2
Sample Molar ratio CuCl2 SbCl3 H2NCSNH2 Pressure Temperature Volume Time
# Cu : Sb : S (mol-L−1) (mol-L−1) (mol-L−1) (psi) (C) (L) (min)
17 1 : 0.81 : 13.02 0.0104 0.0084 0.0.1359 30 382 0.250 25
22 1 : 0.84 : 12.98 0.0106 0.0089 0.0.1377 30 310 0.500 45
23 1 : 0.88 : 12.96 0.0106 0.0093 0.0.1378 30 310 0.500 46
4.2 Stylus Profiler
The thin films thickness of D-17, D-22 and D-23 samples were measured using
Alpha-Step D-100 Stylus Profiler. It is a equipment to record the surface profile
41
characteristics, specially in thin films, from the step height can be determined the
thickness, where by applying a constant force in a stylus profiler, which goes up
and down, amplified the signal according to the surface, at the same time, sensed
by a sensor amplified and then send the data to a computer to read [1,70].
It is an economic-rapid characterization technique that also has the advan-
tages of no need of sample preparation and measurement through layers of dif-
ferent compositions [70].
The average thickness of the samples D-17, D-22 and D-23 were showed in
Table (4.2) according to the data sheet of the equipment, the software of 2D
stress analysis uses the polynomial curve fit models to calculate the heights and
then it do average thickness.
In the stylus profiler for thin films, we make a scratch on the film and remove it
then the profiler measured the step between the glass substrate and the film.
Table 4.2: Average thickness for samples D-17, D-22, and D-23.
Sample Molar ratio Volume (L) Thickness (nm)
D-17 1.23 : 1 : 16.09 0.250 348
D-22 1.18 : 1 : 15.39 0.500 609
D-23 1.14 : 1 : 14.77 0.500 283
The D-22 and D-23 samples were prepared at similar spray rate, but they
presented a 326 nm of difference in thickness between them. In spray pyrolysis
deposition are several factors those affected apart from spray rate, such as subs-
trate temperature, solution concentration and droplet radius [62, 63, 71]. These
samples were formed at the same substrate temperature and similar conditions of
molar ratio, at hence the change in thickness suggested by the droplet radius.
42
4.3 X-Ray Diffraction (XRD)
X-Ray Diffraction is used to identify the crystalline structure. We tracked the phase
composition of the major, minor and traces compounds starting of the intensity
peaks. The grain size (Gsize) was obtained by the Scherrer equation.
Gsize =Kλ
βcosθ; (4.1)
Where K is a shape factor near of unity value, λ is the X-ray wavelength, β is
the FWHM, and θ is the Bragg angle. It can be identified the preferred orientation
planes.
Since thin film thickness was below 1 µm, the characterization was made by
Grazing Incidence X-Ray Diffraction (GIXRD) to avoid the noise of the glass subs-
trate. GIXRD consists of X-Ray Incidence angle (φ) that fixes below 1, and the
angle (2θ) between incident beam and diffracted beam was varied. The equipment
for the characterization was made by a Rigaku Ultima IV diffractometer employing
Cu Kα1 radiation (λ = 1.540 59 A).
Each sample was tested with three different grazing incidence angles (φ), 0.1,
0.3 and 0.5 between scan range (2θ) of 10 to 70.
D-17 thin film
The D-17 GIXRD pattern is shown in Fig. (4.1) and the planes relation in Table
(4.3). The molar ratio was made with 1.23Cu : 1Sb : 16.09S. The spray pyrolysis
parameters were 382 C of substrate temperature, 0.250 L of precursor solution
volume, 25 min spraying time at 30 psi of pressure.
From Fig. (4.1), at φ=0.1, we observed two peaks, one peak at 2θ=27.96
identifying as (422)/(222) plane corresponding to Cu2S phase according PDF#
42-1393 and other peak at 2θ=28.72 identifying as (410) plane corresponding to
43
10 20 30 40 50 60 70
(820
)
(630
)*
(-211
) / (1
11) *
(120
)**
(610) / (134)*
(111)
(510
)/(04
2) *
(-422)/(222)*
(911
)
(410)
(400
)
(221) / (610)(2
10)
(301
)
(412
)(4
02)
(212)/(430)
(521
)(002
)
(321
)
(501
)(320
)
(220
)
(200
)
C
ount
s (a
.u)
2 ( )
Figure 4.1: GIXRD Pattern of D-17 sample with Molar Ratio Cu : Sb : S → 1.23 :
1 : 16.09 on thin film/glass substrate at φ( (0.1, 0.3 and 0.5) shows the formation of
orthorhombic crystal of CuSbS2 phase according PDF# 44-1417. The parameter depo-
sitions were 382 C of temperature, 0.250 L of precursor solution volume, 25 min process
time at 30 psi of pressure.
44
CuSbS2 phase according to PDF# 44-1417. With these data, we can not tracked
phase composition yet.
At φ=0.3, we identified the majority of the characteristic peaks of CuSbS2
phase according to PDF# 44-1417. There are thirteen peaks corresponding to
(200), (400), (410), (301), (220), (501), (321), (002), (521), (212)/(430), (402)
and (412) planes according to the CuSbS2 phase. Peaks of Cu2S phase was
also presented corresponding to (211)/(111), (510)/(042), (610)/(134), and (630)
planes according to the PDF# 83-1462.
At φ=0.5, there were thirteen peaks plus five more than φ=0.3, corresponding
of characteristics peaks of CuSbS2 phase that are reported in table 4.3 and listed
below (200), (210), (400), (111), (410), (301), (220), (320), (501), (221), (610),
(321), (002), (521), (430), (402), (412), and (911) corresponding of the CuSbS2
phase in accordance of PDF# 44-1417 (orthorhombic phase).
The form shows a preferred orientation of planes (111) and (410), since the
most intensity peaks were 28.45 and 28.73 corresponding to these planes.
The Cu2S phase was also present marked by (211)/(111), (422), (222), (042)
and (510) planes (PDF# 83-1462).
(120) plane observed at 17.53 that it can be corresponding for Sb2S3 phase
according PDF# 42-1393.
45
Table 4.3: Planes and phase according of 2 θ of D-17 thin film showed at φ=0.5.
Planes 2 θ Phase Planes 2 θ Phase Planes 2 θ Phase
(200) 12.20 CuSbS2 (301) 29.90 CuSbS2 (321) 42.61 CuSbS2
(211) 13.87 Cu2S (220) 32.17 CuSbS2 (630) 45.93 Cu2S
(111) 13.87 Cu2S (042) 33.58 Cu2S (002) 47.86 CuSbS2
(120) 17.52 Sb2S3 (510) 33.58 Cu2S (521) 49.78 CuSbS2
(210) 19.14 CuSbS2 (320) 35.09 CuSbS2 (212) 52.03 CuSbS2
(400) 24.35 CuSbS2 (501) 39.05 CuSbS2 (430) 52.03 CuSbS2
(422) 27.96 Cu2S (221) 40.16 CuSbS2 (402) 54.51 CuSbS2
(222) 27.96 Cu2S (610) 40.16 CuSbS2 (412) 56.79 CuSbS2
(111) 28.44 CuSbS2 (610) 40.29 Cu2S (820) 59.47 CuSbS2
(410) 28.72 CuSbS2 (134) 40.29 Cu2S (911) 64.67 CuSbS2
46
It was calculated crystallite size around 20.11 nm using Eq. (4.1), at φ = 0.5
in peaks 28.44 and 28.72.
D-22 Thin Film
The GIXRD pattern D-22 thin film showed in Fig. (4.2) and Table (4.4)
summarized the planes and angles. The molar ratio was made with
1.18Cu : 1Sb : 15.39S. The spray pyrolysis parameters were 310 C of
temperature, 0.500 L of precursor solution volume during 45 min by 30 psi of
pressure.
10 20 30 40 50 60 70
(212)/(430)(5
21)
2 ( )
(610) / (134)*(6
30)*
(-422)/(222)*
(120
) **
(400
)(-211
) / (1
11) *
(210
)
Cou
nts
(a.u
)
(820
)
(412
)(4
02)(002
)
(321
)(501
)
(320
)
(220
)(3
01)
(410
)
(200
)
(111)(510)/(042) *
(221) / (610)
Figure 4.2: GIXRD of D-22 sample with Molar Ration Cu : Sb : S → 1.18 : 1 :
15.39, at three φ(0.1,0.3, and 0.5) shows the formation of orthorhombic CuSbS2
phase.
47
At φ=0.1 few peaks presented in the pattern were CuSbS2 major phase. At
φ=0.3, chalcostibite phase pattern was presented by most characteristic peaks
of and two peaks for Cu2S phase. At φ=0.5 diffractogram, it was identified the
characteristic peaks corresponding of the CuSbS2 phase in accordance of PDF#
44-1417 and they are shown in table 4.4.
The crystallite size was calculated of 24.41 nm using Eq. (4.1), in peaks 28.44
and 28.72.
Table 4.4: Planes and 2 θ corresponding to sample D-22.
Planes 2 θ Phase Planes 2 θ Phase Planes 2 θ Phase
(200) 12.20 CuSbS2 (301) 29.90 CuSbS2 (321) 42.61 CuSbS2
(211) 13.87 Cu2S (220) 32.17 CuSbS2 (630) 45.93 Cu2S
(111) 13.87 Cu2S (042) 33.58 Cu2S (002) 47.86 CuSbS2
(120) 17.52 Sb2S3 (510) 33.58 Cu2S (521) 49.78 CuSbS2
(210) 19.14 CuSbS2 (320) 35.09 CuSbS2 (212) 52.03 CuSbS2
(400) 24.35 CuSbS2 (501) 39.05 CuSbS2 (430) 52.03 CuSbS2
(422) 27.96 Cu2S (221) 40.16 CuSbS2 (402) 54.51 CuSbS2
(222) 27.96 Cu2S (610) 40.16 CuSbS2 (412) 56.79 CuSbS2
(111) 28.44 CuSbS2 (610) 40.29 Cu2S (820) 59.47 CuSbS2
(410) 28.72 CuSbS2 (134) 40.29 Cu2S
48
D-23 Thin Film
In the Fig. (4.3), it shows the GIXRD pattern of D-23 thin film which with molar
ratio of 1.14Cu : 1Sb : 14.79S at 310 C, of 0.500 L of precursor solution sprayed
during 46 min by 30 psi.
In grazing incidence angle of 0.5, we observed characteristics planes (200),
(400), (111), (410), (301), (220), (320), (501), (221)/(610), (321), (002), (521),
(212)/(430), (402), (412), and (820) as showed in Table (4.5) corresponding to
the CuSbS2 phase.
Others planes were presented by (211)/(111),(422)/(222), (510)/(042),
(610)/(134), and (630) corresponding to the Cu2S phase (PDF# 83-1462). In this
sample, no peak was observed corresponding to Sb2S3 phase.
The D-23 sample showed preferred orientation in (111) and (410) planes cor-
responding to CuSbS2 phase, and one intensity peak in (422)/(222) corresponding
to Cu2S phase.
The calculated crystallite size was 25.59 nm at φ = 0.5 in peaks 28.44 and
28.72, it was measured using Eq. (4.1).
Table 4.5: Planes and 2 θ corresponding to sample D-23.
Planes 2 θ Phase Planes 2 θ Phase Planes 2 θ Phase
(200) 12.20 CuSbS2 (220) 32.17 CuSbS2 (321) 42.61 CuSbS2
(211) 13.87 Cu2S (042) 33.58 Cu2S (630) 45.93 Cu2S
(111) 13.87 Cu2S (510) 33.58 Cu2S (002) 47.86 CuSbS2
(400) 24.35 CuSbS2 (320) 35.09 CuSbS2 (521) 49.78 CuSbS2
(422) 27.96 Cu2S (501) 39.05 CuSbS2 (212) 52.03 CuSbS2
(222) 27.96 Cu2S (221) 40.16 CuSbS2 (430) 52.03 CuSbS2
(111) 28.44 CuSbS2 (610) 40.16 CuSbS2 (402) 54.51 CuSbS2
(410) 28.72 CuSbS2 (610) 40.29 Cu2S (412) 56.79 CuSbS2
(301) 29.90 CuSbS2 (134) 40.29 Cu2S (820) 59.47 CuSbS2
49
10 20 30 40 50 60 70
(400
) (212)/(430)
(521
)
(630
)*
(-422)/(222)*
(-211
) / (1
11) *
(820
)(4
12)
(402
)
(002
)
(321
)
(501
)
(320
)(220
)
(301)(410)
Cou
nts
(a.u
.)
2 ( )
(200
)
(610) / (134)*
(510)/(042) * (610) / (221)
(111)
Figure 4.3: GIXRD of sample D-23 with Molar Ration Cu : Sb : S → 1.14 : 1 :
14.77, with φ =0.1,0.3, and 0.5 as grazing incidence angle shows the formattion
of orthorhombic crystal of CuSbS2 phase.
50
4.4 Raman spectroscopy
It is the inelastic scattering of photons, better known as Raman scattering, where
the irradiated molecules or crystals, scatter a specific vibrational spectrum being
the fingerprint of the material, and it is used for structural characterization [70].
Raman spectra to the D-17, D-22 and D-23 thin films at room temperature
were measured using Thermo Scientific DXR Raman Microscopy at excitation
wavelength of 532 nm to identify present phases in the film as shown in Fig. (4.4).
100 200 300 400 500 6000
252 cm-1
332 cm-1
D-17
D-23
Cou
nts
(a.u
)
Raman shift (cm)-1
D-22
316 cm-1
Figure 4.4: Raman spectroscopy
The peaks at 332 cm−1 and 252 cm−1in the spectra were identified in the all
the samples matched with CuSbS2 phase, according to the Raman spectrum for
un-oriented CuSbS2 at same excitation wavelength that was published in RRUFF
Project database (http://rruff.info/).
From Fig. (4.4), only for D-17 sample, the nearly phase pure film prepared with
S\Cu precursor ratio 13.1, even the predicted low intense peak at 316 cm−1 was
observed.
51
4.5 X-Ray Photoelectron spectroscopy (XPS)
Compositional analysis of thin films was done using X-ray photo-electron spectra
recorded after etching by 3 keV Ar+ ions for 60 s.
XPS is used the photoelectric effect as a fundamental, where the binding energy
(EB) of core-level electron is a result of X-ray photon energy (hν) minus the kinetic
energies of the ejected photoelectrons (EK ) of the sample and the work function
(Φ) of the electron spectrometer as see in Eq. (4.2) [72].
EB = hν − EK − Φ (4.2)
From Fig. (4.5) the spectras show the presence of copper at 932 eV and
952 eV in all the samples. The binding energies for antimony are identified at 529
±1 eV and 938 ±1 eV in all the samples too. For the sulfur, they are identified at
161.64 ±0.15 eV and 162.80 ±0.15 eV.
The spectra of Fig. (4.5-b,4.5-c,4.5-d) showed other peaks and the
corresponding elements are noted in Fig. (4.5-a), according National Institute of
Standards and Technology (NIST) database (https://srdata.nist.gov/).
The Cl is present due of the use of synthesis for SbCl3 and CuCl2 as precursors.
The Si, and Al are presented in the spectra because the silica (SiO2) and the
alumina (Al2O3) in the glass substrates defined by EN-572-1 where
it gives the general chemical property of the soda lime silicate glass
(http://www.glassforeurope.com/images/cont/167 32370 file.pdf), respectively.
The other elements could be as contamination during the synthesis or from the
precursors.
52
b
c
d
Bindingenergy(eV)
Element–SpectralLine
33 Sb 4d
51 - 53 Fe 3p
74 - 76 Al 2p 3/2
99 - 100 Si 2p
122 - 123 Cu 3s
162 S 2p
180 S 2p 3/2
190 Cl 2p
225 - 226 S 2s
496 - 497 Sn 3d
529 - 530 Sb 3d 5/2
538 - 539 Sb 3d 3/2
549 - 550 Cu LMM
569 Cu LMM
649 Mn 2p 1/2
713 - 721 Fe 2p 1/2
767 - 768 Sb 3p 3/2
932 Cu 2p 3/2
952 Cu 2p 1/2
a
Figure 4.5: In Figure shows of: a) Binding energy and element-spectral line cor-
responding to D-17, D-22, D-23 sample. b) The D-17 survey on XPS. c) The D-22
survey on XPS. d) The D-23 survey on XPS.
53
In Fig. (4.6-a,4.7-a & 4.8-a) show C1s high resolution spectrum, the
adventitious carbon contamination, it presents typically C−C, C−O−C and
O−C−−O components. As charge correction reference is used the C−C
component. The carbon contamination was removed by etching with 3 keV Ar+
ions for 60 s.
The copper, antimony and sulfur peaks were deconvoluted through Shirley type
background calculation and Gaussian-Lorentzian sum function were used for
peak fitting.
For Copper core level spectrum in Fig. (4.6-b) for D-17 showed at 932.44 eV
b
c d
a
Figure 4.6: In D-17 sample obtained the high resolution spectra of: a) C1s without
etched time. b) Cu2p after etching time of 60 s. c) Sb3d after etching time of 60 s.
d) S2p after etching time of 60 s.
54
and 952.22 eV binding energies corresponding to Cu2p3/2 and Cu2p1/2,
respectively, only change ± 0.20 in the other samples D-22 and D-23 as showed
in Fig. (4.7-b) and in Fig. (4.8-b). The spin-orbit coupling components of Cu2p
peak are theCu2p3/2 and Cu2p1/2 doublet present 19.8 eV distance between
them. They were had an area ratio of 1 : 0.50, in the D-17 the FWHM fitted at
1.39 eV for Cu2p3/2 and 1.93 eV for Cu2p1/2. In D-22 the FWHM fitted at 1.32 eV
for Cu2p3/2 and 1.88 eV for Cu2p1/2. In D-23 the FWHM fitted at 1.39 eV for
Cu2p3/2 and 1.93 eV for Cu2p1/2.
In Fig. (4.6-c,4.7-c,and 4.8-c), the Sb3d shows the antimony core level spectra,
which were de-convoluted into two, a doublet of Sb3d5/2 and Sb3d3/2. For D-17
sample showed in Fig. (4.6-c). There are identified four doublets with high
intense peaks at (530.38 eV - 539.72 eV), (529.51 eV - 538.91 eV), (528.90 eV -
538.27 eV), and (528.08 eV - 537.65 eV) with a separation of 9.34 eV, 9.40 eV,
9.37 eV, and 9.57 eV respectively corresponding to Sb3+ states, as expected for
CuSbS2. The two weak peaks at 531.08 eV and 532.08 eV were assigned to O1s
peak.
For D-22 sample analysis is shown in Fig. (4.7-c). There were three dou-
blets identified with high intense peaks at (529.17 eV - 538.50 eV), (530.61 eV -
539.90 eV), and (528.18 eV - 537.68 eV) with a separation of 9.33 eV, 9.29 eV,
and 9.50 eV, respectively corresponding to Sb3+ states, as expected for CuSbS2.
For D-23 sample showed in Fig. (4.8-c). Three doublets with high intense peaks
at (528.94 eV - 538.25 eV), (530.49 eV - 539.66 eV), and (528.16 eV - 537.45 eV)
with a separation of 9.31 eV, 9.17 eV, and 9.29 eV were spotted out, respectively
corresponding to Sb3+ states, as expected for CuSbS2. The weak peak at nearly
531 eV corresponds to O1s peak.
For sulfur core level spectrum shows doublet with a separation of 1.2 eV, the
reported B.E. values for S2− in CuSbS2 as see in Fig. (4.6-d) at 161.64 eV and
162.80 eV binding energies corresponding to S2p3/2 and S2p1/2, respectively. In
Fig. 4.7-d for D-17 showed at 161.58 eV and 162.77 eV and in Fig. 4.8-d for D-
55
17 showed at 161.40 eV and 162.56 eV, so the change between the samples are
only change ± 0.30 at S2p3/2 and ± 0.25 at S2p1/2, these values at maximum and
minimum in the samples D-17, D-22 and D-23. In Cu-Sb-S system, there can be
other phases such as Cu3SbS3 and Cu3SbS4. However, combining our results of
the B.E. values of Cu2p, Sb3p and S2p core levels and of the phases detected in
our XRD results, we assigned the values for the formation of CuSbS2.
a b
c d
Figure 4.7: In D-22 sample obtained the high resolution spectra of: a) C1s without
etched time. b) Cu2p after etching time of 60 s. c) Sb3d after etching time of 60 s.
d) S2p after etching time of 60 s.
56
b
c d
a
Figure 4.8: In D-23 sample obtained the high resolution spectra of: a) C1s without
etched time. b) Cu2p after etching time of 60 s. c) Sb3d after etching time of 60 s.
d) S2p after etching time of 60 s.
57
4.6 Atomic Force Microscopy (AFM)
This technique measures the surface morphology by scanning over sample
surface with a sharp probe, acquiring the height data of the surface [73]. The
advantages of AFM are the amplification of the axes in three dimension, no
treatment needed for samples, measurement in ambient atmosphere and works
for conductive or insulating samples [73].
All the samples were measured in semi-contact mode in Solver Pro, NT-MDT
atomic force microscope. Morphological features of the nearly pure phase
CuSbS2 thin film is illustrated by 1.5 µm x 1.5 µm atomic force micrographs for the
three samples (D-17,D-22 & D-23).
The direct morphology image displayed in Fig. (4.9-a) shows spherical and
compact grains in a range of 20 nm to 100 nm diameter. In Fig. (4.9-b), the
sample presents different grain heights in the z axis but the most of them below
150 nm.
200 nm
0 50 100 150 200 250 nm
a) b)
Figure 4.9: (a)AFM of CuSbS2(D-17) with 1.5 micrometers. (b) AFM of CuSbS2(D-
17) in 3D of 1.5 micrometers.
The micrograph of D-22 sample have a very compact morphology with bigger
grains than D-17 sample as can be seen in Fig. (4.10-a). Unlike D-17 sample,
the 3D data of D-22 sample shows the majority of grains above 150 nm and grain
diameters of 100 nm to 200 nm approximately.
58
200 nm
0 20 40 60 80 100 120 140 160 nm
a) b)
Figure 4.10: (a)AFM of CuSbS2(D-22) with 1.5 micrometers. (b) AFM of
CuSbS2(D-22) in 3D of 1.5 micrometers.
200 nm
0 50 100 150 200 250 300 nm
a) b)
Figure 4.11: (a)AFM of CuSbS2(D-23) with 1.5 micrometers. (b) AFM of
CuSbS2(D-23) in 3D of 1.5 micrometers.
The morphology of D-23 sample presents compact spherical grains with diam-
eters between 100 nm to 200 nm as can be seen in Fig. (4.11-a). The z-axis of
3D of Fig. (4.11-b) gives heights from 40 nm to 180 nm. It can be concluded, that
the surfaces of the thin films are not uniform and in consequence, their thickness
are not uniform.
59
4.7 UV-visible Spectroscopy (UV-Vis)
The optical transmittance spectra and the optical reflectance spectra of the thin
films were measured using an UV-Vis-NIR spectrometer of the trademark Stellar-
net Inc. of the Model DXR-UVN-512.
knowing the thickness, the absorption coefficient at each wavelength was cal-
culated. The optical band gap value of the thin film was determined using the
relation Eq. (2.2).
In D-17, the transmittance and reflectance spectras recorded in the wavelength
range of 300 nm to 1100 nm, they are shown Fig. (4.12). In transmittance we
observed that at 300 nm started with 10 % and it increased until 50 % at 1100 nm.
For Reflectance, it started at 5 % for 300 nm and it started gradually increased
until 850 nm at 33 %, where the slope of the curve changed drastically.
The Fig. (4.12-c) illustrate in (a), the plot of α vs. wavelength, and in (b),
the plot of (αhν)2 vs. hν (Tauc plot) for the nearly phase pure sample giving
good linear fit for n = 2. This implies that the fundamental optical absorption in
the CuSbS2 thin films is dominated by direct allowed transition. From the curve,
the value of band gap was estimated 1.59 eV by extrapolating the linear region
of the respective plot to α = 0, as shown in the figure. This value agrees with
reported value of 1.5 eV on optical properties of CuSbS2, both theoretical [41,45]
and experimental values [39,43,46].
60
1,0 1,1 1,2 1,3 1,4 1,5 1,6 1,7 1,8 1,9 2,0
0
1x109
0,5 1,0 1,5 2,0 2,5 3,0 3,5 4,010
100
1000
10000
100000
300 400 500 600 700 800 900 1000 11000
10
20
30
40
50
Eg=1.54 eV
(c)
hv (eV)
(cm
-1)
hv (eV)
(b)
(a)
(hv
)2 (cm
-1 e
V)2
Perc
ent (
%)
(nm)
T R
Figure 4.12: a) Transmittance and Reflectance spectrums measured. b) Absorp-
tion coefficient spectrum calculated. c) Bandgap for D-17 thin film in UV-Visible.
61
In the D-22 optical spectrum measurements were realized using the
absorbance spectrum recorded for the same wavelength range, as shown Fig.
(4.13), we did the measurement of the transmittance and the reflectance for the
D-22 thin film. In transmittance we observed that in the range of 300 nm to
600 nm, the value was near of 0 % and it started to increase after 600 nm until
15 % at 1100 nm. Reflectance showed same behavior, it started at less than 5 %
for 300 nm and it started gradually increased until a maximum of 11 % at
1100 nm.
1,0 1,1 1,2 1,3 1,4 1,5 1,6 1,7 1,8 1,9 2,0
0,0
4,0x1010
300 400 500 600 700 800 900 1000 1100-2
0
2
4
6
8
10
12
14
0,5 1,0 1,5 2,0 2,5 3,0 3,5 4,0
150000
Eg=1.54 eV
hv (eV)
Perc
ent (
%)
(nm)
T R
(c)(b)
(a)
(cm
-1)
(hv
)2 (cm
-1 e
V)2
hv (eV)
Figure 4.13: a) Transmittance and Reflectance spectrums measured. b) Absorp-
tion coefficient spectrum calculated. c) Bandgap for D-22 thin film in UV-Visible.
The Fig. (4.13-c) illustrate in (a), the plot of α vs. wavelength, and in (b),
the plot of (αhν)2 vs. hν (Tauc plot) for the nearly phase pure sample giving
62
good linear fit for n = 2. This implies that the fundamental optical absorption in
the CuSbS2 thin films is dominated by direct allowed transition. From the curve,
the value of band gap was estimated 1.54 eV by extrapolating the linear region
of the respective plot to α = 0, as shown in the figure. This value agrees with
reported value of 1.5 eV on optical properties of CuSbS2, both theoretical [41,45]
and experimental values [39,43,46].
63
In the D-23 optical spectrum measurements were realized using the
absorbance spectrum recorded for the wavelength range of 300 nm to 1100 nm,
as shown Fig. (4.14), we did the measurement of the transmittance and the
reflectance for the D-23 thin film. In transmittance we observed that in the range
of 300 nm to 700 nm, the value was increased between the range of 9 % to 15 %,
then the slope changed and it started to increase more so between the range of
700 nm to 1100 nm the transmittance started at 15 % and end in 30 %. For
Reflectance, it showed inverse behavior, it started with a bigger slope from 3 % to
15 % and then decreased the slope at 800 nm to 1100 nm near of 15 % of
reflectance.
1,0 1,1 1,2 1,3 1,4 1,5 1,6 1,7 1,8 1,9 2,0
0,0
1,7x1010
0,5 1,0 1,5 2,0 2,5 3,0 3,5 4,0
30000
40000
50000
60000
700008000090000
100000
300 400 500 600 700 800 900 1000 11000
10
20
30
40
50
Eg=1.37 eV
(c)(
hv)2 (c
m-1
eV)2
hv (nm)
(cm
-1)
hv (nm)
(b)
(a)
Perc
ent (
%)
(nm)
R T
Figure 4.14: a) Transmittance and Reflectance spectrums measured. b) Absorp-
tion coefficient spectrum calculated. c) Bandgap for D-23 thin film in UV-Visible.
64
The Fig. (4.14-c) illustrate in (a), the plot of α vs. wavelength, and in (b),
the plot of (αhν)2 vs. hν (Tauc plot) for the nearly phase pure sample giving
good linear fit for n = 2. This implies that the fundamental optical absorption in
the CuSbS2 thin films is dominated by direct allowed transition. From the curve,
the value of band gap was estimated 1.39 eV by extrapolating the linear region
of the respective plot to α = 0, as shown in the figure. This value agrees with
reported value of 1.5 eV on optical properties of CuSbS2, both theoretical [41,45]
and experimental values [39,43,46].
65
4.8 Photoresponse
The photoresponse characterization is important to visualize if the material was
response time and sensitivity of photoresponse materials [74]. The response time
is the time required to increase For the Direct Current (dc) conductivity measure-
ments the contacts used were two planar electrodes of 3 mm in length and 3 mm
in separation using conductive silver paint, (SPI Supplies).
0 10 20 30 40 50 60
1,210
1,212
1,215Light OnLight Off Light Off
I ()
Time (s)
Figure 4.15: D-17 sample on Photoresponse curve
The Fig. (4.15,4.16,4.17) show the photoresponse of D-17, D-22 and D-23 thin
films at room temperature by applying a dc bias of 5 V.
First, current was measured in darkness for 20 s, then under illuminated for
20 s, and finally in darkness for another 20 s. The three samples showed photore-
sponse.
66
0 10 20 30 40 50 60
4,200x10-1
4,220x10-1
4,240x10-1
Light Off Light OffLight On
I ()
Time (s)
Figure 4.16: D-22 sample on Photoresponse curve
0 10 20 30 40 50 60
3,420x10-1
3,430x10-1
3,440x10-1 Light Off Light On Light Off
I ()
Time (s)
Figure 4.17: D-23 sample on Photoresponse curve
67
4.9 Hall Effect
The electrical properties of the thin films were measured using the Hall effect.
The Hall effect is physical phenomenon occurred in metals and semiconductors
when an electric current (Jx) was flowing in x direction across a rectangular bar
and it applies an perpendicular magnetic field (Bz) in z direction. It exists a
deflection of the charge carriers due to the Lorentz force. The deflected charge
carriers accumulate on both of the y directions of the bar, generating a
transverse electric field (Ey) that cancels the Lorentz force and exerts a voltage
in the same direction. This voltage is called the Hall voltage and the electric field
is named the Hall electric field [8,75,76].
The growth of D-17, D-22 and D-23 thin films are nonuniform as noted by
AFM, we used the Van Der Pauw technique. It is convenient for these irregular
morphology. In the samples are square and we painted four contacts (1,2,3,4)
in the corners. We applied an electric current in contacts 3 to 4 and everted a
magnetic field at perpendicular way. The Hall voltage was measured in contacts
1 to 2, these are perpendicular to the electric current and the magnetic field [77].
In the Van der Pauw technique can be estimated the Hall coefficient(RH) with Eq.
(4.3), where d is the film thickness, B is the magnetic field, and I34 is the electric
current flowing from contact 3 to contact 4.
RH =[V12(B)− V12(0)]d
I34B=
[V12(B)− V12(−B)]d2I34B
(4.3)
To calculate the carrier concentration (n) is used Eq.(4.4), where e is the charge
of the electron.
n =1
RHe(4.4)
Yang et al. reported a conductivity of 20.83 (Ωcm)−1, a hole mobility of 49 (cm2
Vs )
and a carrier concentration of 2.66× 1018 (cm−3). They commented that their high
hole mobility is due hole concentration [39].
Garza et al. reported for CuSbS2 films with p-type conductivity. Their measure-
ments showed a conductivity of 60 (Ωcm)−1, a mobility of 0.01 ( cm2
Vs ) and a carrier
68
concentration of 3.9× 1018 (cm−3) in 30 nm of thickness. In thin film of 40 nm
reported a conductivity of 9 (Ωcm)−1, a mobility of 0.001 ( cm2
Vs ) and a carrier con-
centration of 6.1× 1019 (cm−3). And 50 nm thin film, they reported a conductivity
of 0.5 (Ωcm)−1, a mobility of 0.1 (cm2
Vs ) and a carrier concentration of 1.4× 1020
(cm−3) [31].
The CuSbS2 thin films were measured using an Ecopia HMS-3000 Hall
measurement system at room temperature applying a fixed magnetic field of 0.55
T on samples with four corners painted with silver as showed in Fig. (4.18). Were
calculated the carrier concentration (cm−3), mobility (cm2/V s) and conductivity
(Ω−1 cm−1).
Figure 4.18: a) Sample of 1 cm x 1 cm. b) Sample adapter of Ecopia SPCB.
c) Dispositive where board is inserted. d) Then it is connected to the hall effect
system. e) Hall effect measurement system. f) The HMS-300 software.
Table (4.6) shows the results of D-17, D-22 and D-23 samples. All of which
do have positive Hall coefficients, proving that they are p-type films. Only the D-
22 sample shows a higher value than reported by Garza et al., the others show
similar results [31]. The conductivity is less than the reported by Yang et al..
69
Table 4.6: Carrier concentration, mobility, conductivity and Hall Coefficient are
shown of the CuSbS2 thin films at 10 (µA). The Hall Coefficients are positive in all
the samples corresponding to a p-type conduction.
Sample Carrier-concentration Mobility Conductivity Hall Coefficient
(cm−3) ( cm2
Vs ) ((Ωcm)−1) (cm3/C)
D-17 1.446× 1021 3.324× 10−2 7.739 4.318× 10−3
D-22 1.793× 1018 2.630 0.755 3.482
D-23 6.389× 1020 1.362× 10−2 1.394 9.770× 103
70
5Conclusions
5.1 Conclusions
Material
The CuSbS2 thin films were prepared on glass substrates at 300 C to 382 C by
spray pyrolysis using the precursor solutions containing SbCl3, CuCl2, CS(NH2)2.
• The samples formed from precursor solutions Cu:Sb:S molar ratio:
[1.23:1:9.16] [1.18:1:15.39] and [1.14:14.77:1] were analyzed.
Characterizations
These results show that thin films CuSbS2 different optoelectronic properties can
be obtained using the spray pyrolysis technique by varying the precursor compo-
sitions [78].
• The thickness was measured with a Stylus Profiler. The D-17 sample was
prepared with 0.250 L of precursor solution and it was measured 348 nm.
The D-22 sample was prepared with twice of the volume of D-17 sample, and
proportional it was measured 609 nm. Not so the D-23 sample, which has
a volume of 0.500 L and the thickness resulted in 283 nm, perhaps because
the surface temperature of the substrate can not be accurately controlled,
could have affected the growth of the film.
71
• The XRD showed chalcostibite crystal structure CuSbS2 and Cu2S as minor
phase.
• Raman spectral analysis confirmed the compound CuSbS2 phase.
• The XPS indicated the presence of copper, antimony and sulfur.
• The atomic force micrographs of the three samples (D-17/D-22/D.23)
showed a spherical and compact grains. There were grains in the range of
20 nm to 100 nm in D-17 sample. Bigger grains around 200 nm in D-22
sample. For the D-23 sample, its grains were in the range of 100 nm to
200 nm in size. The AFM showed that the morphologies of the samples
were composed of compact grains.
• In the UV-Vis characterization, the D-17 thin film showed an Eg = 1.54 eV.
The bandgap for the D-22 was 1.54 eV and for the D-23 was 1.37 eV. These
values are agree in according of the reported literature [39,43,46].
• The Photoresponse showed that all the thin films were photoconductive.
• Hall effect measurements showed the p-type conductivity for these sam-
ples with good carrier concentration. The D-17 presented a 7.739 (Ωcm)−1
conductivity. The D-22 presented a 0.755 (Ωcm)−1 conductivity. The D-23
presented a 1.394 (Ωcm)−1 conductivity.
Spray Pyrolysis
The spray pyrolysis machine was tested with a wide values for the suitable pa-
rameters for solution precursor deposition to obtain uniform thin films of CuSbS2
at substrate temperature of 310 C to 382 C .
• The pressure for the air supply to the transportation system of the precursor
solution to the substrate atomizer was set at 30 Psi, as best nucleation on
the substrate surface for forming thin film was shown. At higher pressure, the
72
solution was spread out leaving the substrate film formation. A lower pres-
sure, the solution accumulated on the film and not let be the right pyrolysis
process for the homogeneous formation on the substrate.
5.2 Future work
• Standardize the deposition of the CuSbS2 thin films by to replace full cone
to flat even nozzles, to replace the separating funnel by a suitable container
and to fit a ceramic container for the glass substrates.
• To realize thin film solar cell of CuSbS2 by spray pyrolysis deposition.
73
6Publication
Jose Agustin Ramos Aquino, Dorian Leonardo Rodriguez Vela, Sadasivan Shaji,
David Avellaneda Avellaneda, and Bindu Krishnan. Spray pyrolysed thin films
of copper antimony sulfide as photovoltaic absorber. Physica Status Solidi (C),
13(1):24–29, 2016.
74
Bibliography
[1] Jose Agustin Ramos Aquino, Dorian Leonardo Rodriguez Vela, Sadasivan
Shaji, David Avellaneda Avellaneda, and Bindu Krishnan. Spray pyrolysed
thin films of copper antimony sulfide as photovoltaic absorber. Physica Status
Solidi (C), 13(1):24–29, 2016.
[2] Vasilis Fthenakis. Sustainability of photovoltaics: The case for thin-film solar
cells. Renewable and Sustainable Energy Reviews, 13(9):2746–2750, 2009.
[3] K L Chopra, P D Paulson, and V Dutta. Thin-film solar cells: an overview.
Progress in Photovoltaics: Research and Applications, 12(23):69–92, 2004.
[4] Martin A. Green. Thin-film solar cells: review of materials, technologies and
commercial status. J Mater Sci: Mater Electron, 18:15–19, 2007.
[5] Chetan Singh Solanki. Solar photovoltaics. Fundamentals, technologies and
applications. PHI Learning private limited, second edition, 2013.
[6] A Goswami. Thin Film Fundamentals. New Age International Pub, 1996.
[7] P. Arunkumar, Sushil Kumar Kuanr, and K. Suresh Babu. Thin Film Structures
in Energy Applications. chapter Thin Film:. Springer International Publishing.
[8] M.A. Omar. Elementary Solid State Physics: Principles and Applications.
Addison-Wesley Publishing Company, 1993.
75
[9] Siegfried Eigler and Andreas Hirsch. Chemistry with graphene and graphene
oxide - Challenges for synthetic chemists. Angewandte Chemie - Interna-
tional Edition, 53(30):7720–7738, 2014.
[10] L E Smart and E A Moore. Solid State Chemistry: An Introduction, Third
Edition. E-Books von NetLibrary. Taylor & Francis, 2005.
[11] Antonio Luque and Steven Hegedus, editors. Handbook of Photovoltaic Sci-
ence and Engineering. John Wiley & Sons, 2011.
[12] Tom Markvart and Luis Castaner, editors. Practical Handbook of Photo-
voltaics: Fundamentals and Applications. Elsevier Ltd, 2003.
[13] Kashif Ishaque, Zainal Salam, and Hamed Taheri. Simple, fast and accurate
two-diode model for photovoltaic modules. Solar Energy Materials and Solar
Cells, 95(2):586–594, 2011.
[14] Jieming Ma, Ka Lok Man, T. O. Ting, Nan Zhang, Sheng-Uei Guan, Prudence
W. H. Wong, Jieming Ma, Ka Lok Man, T. O. Ting, Nan Zhang, Sheng-Uei
Guan, and Prudence W. H. Wong. Approximate Single-Diode Photovoltaic
Model for Efficient I-V Characteristics Estimation. The Scientific World Jour-
nal, 2013:1–7, 2013.
[15] J.a. Gow and C.D. Manning. Development of a photovoltaic array model
for use in power-electronics simulation studies. IEE Proceedings - Electric
Power Applications, 146(2):193–200, 1999.
[16] Y. Rodrıguez-Lazcano, M.T.S. Nair, and P.K. Nair. CuSbS2 thin film formed
through annealing chemically deposited Sb2S3-CuS thin films. Journal of
Physics D: Applied Physics, 34(1):12–17, 2001.
[17] Lawrence L. Kazmerski. Solar photovoltaics R&D at the tipping point: A
2005 technology overview. Journal of Electron Spectroscopy and Related
Phenomena, 150(2-3):105–135, 2006.
76
[18] Hitoshi Sai, Takuya Matsui, Takashi Koida, Koji Matsubara, Michio Kondo,
Shuichiro Sugiyama, Yoshiaki Takeuchi, and Isao Yoshida. Triple-junction
thin-film silicon solar cell fabricated on periodically textured substrate with a
stabilized efficiency of 13.6%. Applied Physics Letters, 106:213902, 2015.
[19] D. L. Staebler and C. R. Wronski. Reversible conductivity changes in
discharge-produced amorphous Si. Applied Physics Letters, 31(4):292–294,
1977.
[20] R. W. Miles. Photovoltaic solar cells: Choice of materials and production
methods. Vacuum, 80(10):1090–1097, 2006.
[21] L. El Chaar, L. A. Lamont, and N. El Zein. Review of photovoltaic technolo-
gies. Renewable and Sustainable Energy Reviews, 15(5):2165–2175, 2011.
[22] First Solar Press Release. First solar achieves yet another cell conversion
efficiency world record, 24 February 2016.
[23] Solar Frontier Press Release. Solar Frontier Achieves World Record Thin-
Film Solar Cell Efficiency: 22.3%, 8 December 2015. 2015.
[24] NREL. Solar cell efficiency chart, mar 2016.
[25] Wan-Jian Wanjian Yin, Ji-Hui Jihui Yang, Joongoo Kang, Yanfa Yan, and Su-
Huai Wei. Halide Perovskite Materials for Solar Cells: A Theoretical Review.
J. Mater. Chem. A, 3(17):Advance, 2015.
[26] Henry J Snaith. Perovskites : The Emergence of a New Era for Low - Cost ,
High Efficiency Solar Cells. Journal of Physical Chemistry Letters, 4:3623–
3630, 2013.
[27] Tze-bin Song, Qi Chen, Huan-Ping Zhou, Chengyang Jiang, Hsin-Hua Wang,
Yang Yang, Yongsheng Liu, Jingbi You, and Yang Yang. Perovskite solar cells:
film formation and properties. J. Mater. Chem. A, 3:9032–9050, 2015.
77
[28] Zhaoning Song, Suneth C. Watthage, Adam B. Phillips, and Michael J.
Heben. Pathways toward high-performance perovskite solar cells: review
of recent advances in organo-metal halide perovskites for photovoltaic appli-
cations. Journal of Photonics for Energy, 6(2):022001, 2016.
[29] Wei Wang, Mark T. Winkler, Oki Gunawan, Tayfun Gokmen, Teodor K.
Todorov, Yu Zhu, and David B. Mitzi. Device characteristics of CZTSSe thin-
film solar cells with 12.6% efficiency. Advanced Energy Materials, 4(7):1–5,
2014.
[30] M P Suryawanshi, G L Agawane, S M Bhosale, S W Shin, P S Patil, J H Kim,
and a V Moholkar. CZTS based thin film solar cells: a status review. Materials
Technology: Advanced Performance Materials, 28(1):98–109, 2013.
[31] C. Garza, S. Shaji, A. Arato, E. Perez Tijerina, G. Alan Castillo, T. K. Das Roy,
and B. Krishnan. P-Type CuSbS2 thin films by thermal diffusion of copper into
Sb2S3. Solar Energy Materials and Solar Cells, 95(8):2001–2005, 2011.
[32] D. Colombara, L. M. Peter, K. D. Rogers, J. D. Painter, and S. Roncallo.
Formation of CuSbS2 and CuSbSe2 thin films via chalcogenisation of Sb-Cu
metal precursors. Thin Solid Films, 519(21):7438–7443, 2011.
[33] A Wachtel and A Noreika. Growth and Characterization of CuSbS2 Crystals.
Journal of Electronic Materials, 9(2):281–297, 1980.
[34] Vijay Kumar Gudelli, V. Kanchana, G. Vaitheeswaran, a. Svane, and N. E.
Christensen. Thermoelectric properties of chalcopyrite type CuGaTe2 and
chalcostibite CuSbS2. Journal of Applied Physics, 114:0–8, 2013.
[35] J W Anthony. Handbook of Mineralogy: Halides, Hydroxides, Oxides. Hand-
book of Mineralogy. Mineral Data Publishing, 1997.
[36] Jesse T R Dufton, Aron Walsh, Pooja M Panchmatia, Laurence M Peter,
Diego Colombara, and M Saiful Islam. Structural and electronic properties of
78
CuSbS2 and CuBiS2: Potential absorber materials for thin-film solar. Phys.
Chem. Chem. Phys., 14:7229–7233, 2012.
[37] Satoshi Suehiro, Keisuke Horita, Masayoshi Yuasa, Tooru Tanaka, Katsuhiko
Fujita, Yoichi Ishiwata, Kengo Shimanoe, and Tetsuya Kida. Synthesis of
Copper-Antimony-Sulfide Nanocrystals for Solution-Processed Solar Cells.
Inorganic chemistry, pages 2–7, 2015.
[38] C. Tablero. Electronic property analysis of O-doped Cu3SbS3. Solar Energy
Materials and Solar Cells, 104:180–184, 2012.
[39] Bo Yang, Liang Wang, Jun Han, Ying Zhou, Huaibing Song, Shiyou Chen,
Jie Zhong, Lu Lv, Dongmei Niu, and Jiang Tang. CuSbS2 as a promising
earth-abundant photovoltaic absorber material: A combined theoretical and
experimental study. Chemistry of Materials, 26:3135–3143, 2014.
[40] B. Krishnan, S. Shaji, and R. Ernesto Ornelas. Progress in development of
copper antimony sulfide thin films as an alternative material for solar energy
harvesting. Journal of Materials Science: Materials in Electronics, 26:4770–
4781, 2015.
[41] Mukesh Kumar and Clas Persson. CuSbS2 and CuBiS2 as potential ab-
sorber materials for thin-film solar cells. Journal of Renewable and Sustain-
able Energy, 5(3), 2013.
[42] a. Rabhi, M. Kanzari, and B. Rezig. Growth and vacuum post-annealing
effect on the properties of the new absorber CuSbS2 thin films. Materials
Letters, 62(20):3576–3578, 2008.
[43] a. Rabhi, M. Kanzari, and B. Rezig. Optical and structural properties of
CuSbS2 thin films grown by thermal evaporation method. Thin Solid Films,
517(7):2477–2480, 2009.
[44] a Rabhi and M Kanzari. Effect of air annealing on CuSbS2 thin film grown by
vacuum thermal evaporation. Chalcogenide Letters, 8(4):255–262, 2011.
79
[45] Liping Yu, Robert S. Kokenyesi, Douglas a. Keszler, and Alex Zunger. Inverse
design of high absorption thin-film photovoltaic materials. Advanced Energy
Materials, 3:43–48, 2013.
[46] R. E. Ornelas-Acosta, D. Avellaneda, S. Shaji, G. a. Castillo, T. K. Das Roy,
and B. Krishnan. CuSbS2 thin films by heating Sb2S3/Cu layers for PV appli-
cations. Journal of Materials Science: Materials in Electronics, 25(10):4356–
4362, 2014.
[47] R.E. Ornelas-Acosta, S. Shaji, D. Avellaneda, G.a. Castillo, T.K. Das Roy,
and B. Krishnan. Thin films of copper antimony sulfide: A photovoltaic ab-
sorber material. Materials Research Bulletin, 61:215–225, 2014.
[48] Dainius Perednis. Thin Film Deposition by Spray Pyrolysis and the Applica-
tion in Solid Oxide Fuel Cells. PhD thesis, Swiss Federal Institure of Tech-
nology Zurich, 2003.
[49] A. Rabhi and M. Kanzari. Structural, optical, and electrical properties of
CuSbS2 these amorphous films: effect of the thickness variation. Chalco-
genide Letters, 8(6):383–390, 2011.
[50] S C Ezugwu, F I Ezema, and P U Asogwa. Synthesis and characterization of
ternary CuSbS2 thin films: effect of deposition time. Chalcogenide Letters,
7(5):341–348, 2010.
[51] Y. Fadhli, a. Rabhi, and M. Kanzari. Effect of annealing time and substrates
nature on the physical properties of CuSbS2 thin films. Journal of Materials
Science: Materials in Electronics, 25(11):4767–4773, 2014.
[52] Diego Colombara, Laurence M. Peter, Keith D. Rogers, and Kyle Hutchings.
Thermochemical and kinetic aspects of the sulfurization of Cu-Sb and Cu-Bi
thin films. Journal of Solid State Chemistry, 186:36–46, 2012.
[53] Shigeru Ikeda, Yuta Iga, Wilman Septina, Takashi Harada, and Michio Mat-
sumura. CuSbS2 -based thin film solar cells prepared from electrodeposited
80
metallic stacks composed of Cu and Sb layers. Conference Record of the
IEEE Photovoltaic Specialists Conference, pages 2598–2601, 2013.
[54] Wilman Septina, Shigeru Ikeda, Yuta Iga, Takashi Harada, and Michio Mat-
sumura. Thin film solar cell based on CuSbS2 absorber fabricated from an
electrochemically deposited metal stack, 2013.
[55] a. C. Rastogi and N. R. Janardhana. Properties of CuSbS2 thin films elec-
trodeposited from ionic liquids as p-type absorber for photovoltaic solar cells.
Thin Solid Films, 565:285–292, 2014.
[56] Simona Manolache, Anca Duta, Luminita Isac, Marian Nanu, Albert
Goossens, and Joop Schoonman. The influence of the precursor concen-
tration on CuSbS2 thin films deposited from aqueous solutions. Thin Solid
Films, 515(15 SPEC. ISS.):5957–5960, 2007.
[57] S. a. Manolache, L. Andronic, a. Duta, and a. Enesca. The influence of the
deposition condition on crystal growth and on the band gap of CuSbS2 thin
film absorber used for Solid State Solar Cells (SSSC). Journal of Optoelec-
tronics and Advanced Materials, 9(5):1269–1272, 2007.
[58] S a Manolache and A Duta. The influence of the spray deposition pa-
rameters in the photovoltaic response of the three-dimensional (M) solar
cell: TCO/dense TiO2/CuSbS2/graphite. Journal of Optoelectronics and Ad-
vanced Materials, 9(10):3219–3222, 2007.
[59] Ionut Popovici and Anca Duta. Tailoring the Composition and Properties
of Sprayed CuSbS2 Thin Films by Using Polymeric Additives. International
Journal of Photoenergy, 2012:1–6, 2012.
[60] S. Thiruvenkadam and A. Leo Rajesh. Effect of Temperature on Structural
and Optical Properties of Spray Pyrolysed CuSbS2 Thin Films for Photo-
voltaic Applications. International Journal of Scientific & Technology Re-
search, 5(1):248–251, 2014.
81
[61] S Thiruvenkadam and a Leo Rajesh. Effect Of Antimony Concentration On
The Properties Of Spray Pyrolysed CuSbS2 Thin Film Absorbing Layer For
Photovoltaic Application. International Journal of Scientific & Technology Re-
search, 3(2):38–41, 2014.
[62] R. R. Chamberlin and J. S. Skarman. Chemical Spray Deposition Process
for Inorganic Films. Journal of the Electrochemical Society, 113(1):86–89,
1966.
[63] J C Vigui and J Spitz. Chemical Vapor Deposition at Low Temperatures. J.
Electrochem. Soc.: Solid-State Science and Technology, 122(4):585–588,
1975.
[64] Dainius Perednis and Ludwig J Gauckler. Thin Film Deposition Using Spray
Pyrolysis. Journal of Electroceramics, 14:103–111, 2005.
[65] Pramod S Patil. Versatility of chemical spray pyrolysis technique. Materials
Chemistry and Physics, 59:185–198, 1999.
[66] http://www.spray.com/cat76/automatic-m/offline/download.pdf.
[67] Xiangying Chen, Zhenghua Wang, Xiong Wang, Rui Zhang, Xinyuan Liu,
Wanjuan Lin, and Yitai Qian. Synthesis of novel copper sulfide hollow
spheres generated from copper (II)-thiourea complex. Journal of Crystal
Growth, 263(1-4):570–574, 2004.
[68] Chalcogenide Letters, S C Ezugwu, F I Ezema, and P U Asogwa. Synthesis
and characterization of ternary CuSbS2 thin films: effect of deposition time.
Chalcogenide Letters, 7(5):341–348, 2010.
[69] Kirtiman Deo Malviya, Hen Dotan, Ki Ro Yoon, Il-Doo Kima, and Avner
Rothschild. Rigorous substrate cleaning process for reproducible thin
film hematite (α-Fe2O3) photoanodes. Journal of Materials Research,
31(October):1–23, 2015.
82
[70] C R Brundle, C A Evans, and S Wilson. Encyclopedia of Materials Char-
acterization: Surfaces, Interfaces, Thin Films. Characterization Series.
Butterworth-Heinemann, 1992.
[71] J B Mooney and S B Radding. Spray Pyrolysis Processing. Annual Review
of Materials Science, 12(1):81–101, 1982.
[72] D R Vij. Handbook of Applied Solid State Spectroscopy. Springer US, 2007.
[73] P Eaton and P West. Atomic Force Microscopy. OUP Oxford, 2010.
[74] N V Joshi. Photoconductivity: Art: Science & Technology. Optical Science
and Engineering. Taylor & Francis, 1990.
[75] C Kittel. Introduction to Solid State Physics. Wiley, 2004.
[76] B G Yacobi. Semiconductor Materials: An Introduction to Basic Principles.
Microdevices. Springer US, 2006.
[77] P YU and M Cardona. Fundamentals of Semiconductors: Physics and Ma-
terials Properties. Graduate Texts in Physics. Springer Berlin Heidelberg,
2010.
[78] Armin G. Aberle. Thin-film solar cells. Thin Solid Films, 517(17):4706–4710,
2009.
83
List of Figures
1.1 a) Homojunction has the same material in p-type and n-type. b)
Heterojunction has different material between p-type and n-type. . 4
1.2 Circuit diagram of single diode model for solar cell . . . . . . . . . 5
1.3 Circuit diagram of double diode model of solar cell . . . . . . . . . 6
1.4 Schematic of solar cell based on a-Si:H [20]. . . . . . . . . . . . . 7
1.5 Schematic of CdTe solar cell based on [20]. . . . . . . . . . . . . . 8
1.6 Schematic of CIGS solar cell based on [20]. . . . . . . . . . . . . . 9
1.7 Schematic of Perovskite solar cell based on [25]. . . . . . . . . . . 10
1.8 Schematic of solar cell based on CZTS [30]. . . . . . . . . . . . . . 11
2.1 Orthorhombic structure of CuSbS2 phase that shows a normal view
of the unit cell [41].”Reprinted from [Mukesh Kumar and Clas Pers-
son. CuSbS2 and CuBiS2 as potential absorber materials for thin-
film solar cells. Journal of Renewable and Sustainable Energy, 5(3),
2013.] with the permission of AIP Publishing.” . . . . . . . . . . . . 14
2.2 Calculated optical absorption spectra for Cu−V5+−VI compounds (blue) and
Cu−V3+−VI compounds (red) [45].”Reprinted from [Liping Yu, Robert S.
Kokenyesi, Douglas a. Keszler, and Alex Zunger. Inverse design of high
absorption thin-film photovoltaic materials. Advanced Energy Materials,
3:43–48, 2013.] with the permission of John Wiley and Sons.” . . . . . . . . . 16
84
2.3 Deposition process with increasing substrate temperature. (A) The
solvent is evaporated and the decomposition of dried precipitate
precursors takes place. (B) The drops spread over substrate and
the solvent is evaporated before the falling drops on the substrate
surface, leaving a precipitate which decomposes on the substrate.
C: The solvent evaporate at the drop nearby on the substrate sur-
face. The precipitated solids melt and sublime, the vapor diffuse
in the substrate in a heterogeneous reaction. D: At high tempera-
tures, the drops precipitate and sublimate. A chemical reaction of
precursors effect in vapor phase near the substrate surface [63]. . 23
3.1 Experimental chart . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
3.2 1) General view of the spray pyrolysis equipment. 2) Zoom of the
prototype of the spray pyrolysis. 3) The movement parts of the
spray. 4) The stainless steel air nozzle. . . . . . . . . . . . . . . . . 32
3.3 a)Stock solutions of a)CuSO4 ·5 H2O at (1 M) concentration in 100 mL of
DI water. b) Thiourea at 0.1 M in 100 mL. c) samples were prepared
with — ration molar. d) samples were synthesized with — ratio molar. e)
samples were prepared with – ratio molar. f) samples were prepared with
— ratio molar. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
3.4 Stock solutions of a)Sb2S3 nanoparticles from laser ablation in 100 mL of
DI water. b) Thiourea at 0.1 M in 100 mL. . . . . . . . . . . . . . . . . 35
3.5 a)Reactants. b)Precursor solutions. c) Precipitated and solubility
solutions. d) Sprayed solution. . . . . . . . . . . . . . . . . . . . . 38
4.1 GIXRD Pattern of D-17 sample with Molar Ratio Cu : Sb : S → 1.23 :
1 : 16.09 on thin film/glass substrate at φ( (0.1, 0.3 and 0.5) shows
the formation of orthorhombic crystal of CuSbS2 phase according PDF#
44-1417. The parameter depositions were 382 C of temperature, 0.250 L
of precursor solution volume, 25 min process time at 30 psi of pressure. . 44
85
4.2 GIXRD of D-22 sample with Molar Ration Cu : Sb : S → 1.18 :
1 : 15.39, at three φ(0.1,0.3, and 0.5) shows the formation of
orthorhombic CuSbS2 phase. . . . . . . . . . . . . . . . . . . . . . 47
4.3 GIXRD of sample D-23 with Molar Ration Cu : Sb : S → 1.14 : 1 :
14.77, with φ =0.1,0.3, and 0.5 as grazing incidence angle shows
the formattion of orthorhombic crystal of CuSbS2 phase. . . . . . . 50
4.4 Raman spectroscopy . . . . . . . . . . . . . . . . . . . . . . . . . . 51
4.5 In Figure shows of: a) Binding energy and element-spectral line
corresponding to D-17, D-22, D-23 sample. b) The D-17 survey on
XPS. c) The D-22 survey on XPS. d) The D-23 survey on XPS. . . 53
4.6 In D-17 sample obtained the high resolution spectra of: a) C1s with-
out etched time. b) Cu2p after etching time of 60 s. c) Sb3d after
etching time of 60 s. d) S2p after etching time of 60 s. . . . . . . . 54
4.7 In D-22 sample obtained the high resolution spectra of: a) C1s with-
out etched time. b) Cu2p after etching time of 60 s. c) Sb3d after
etching time of 60 s. d) S2p after etching time of 60 s. . . . . . . . 56
4.8 In D-23 sample obtained the high resolution spectra of: a) C1s with-
out etched time. b) Cu2p after etching time of 60 s. c) Sb3d after
etching time of 60 s. d) S2p after etching time of 60 s. . . . . . . . 57
4.9 (a)AFM of CuSbS2(D-17) with 1.5 micrometers. (b) AFM of
CuSbS2(D-17) in 3D of 1.5 micrometers. . . . . . . . . . . . . . . . 58
4.10 (a)AFM of CuSbS2(D-22) with 1.5 micrometers. (b) AFM of
CuSbS2(D-22) in 3D of 1.5 micrometers. . . . . . . . . . . . . . . . 59
4.11 (a)AFM of CuSbS2(D-23) with 1.5 micrometers. (b) AFM of
CuSbS2(D-23) in 3D of 1.5 micrometers. . . . . . . . . . . . . . . . 59
4.12 a) Transmittance and Reflectance spectrums measured. b) Absorp-
tion coefficient spectrum calculated. c) Bandgap for D-17 thin film
in UV-Visible. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
86
4.13 a) Transmittance and Reflectance spectrums measured. b) Absorp-
tion coefficient spectrum calculated. c) Bandgap for D-22 thin film
in UV-Visible. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62
4.14 a) Transmittance and Reflectance spectrums measured. b) Absorp-
tion coefficient spectrum calculated. c) Bandgap for D-23 thin film
in UV-Visible. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
4.15 D-17 sample on Photoresponse curve . . . . . . . . . . . . . . . . 66
4.16 D-22 sample on Photoresponse curve . . . . . . . . . . . . . . . . 67
4.17 D-23 sample on Photoresponse curve . . . . . . . . . . . . . . . . 67
4.18 a) Sample of 1 cm x 1 cm. b) Sample adapter of Ecopia SPCB.
c) Dispositive where board is inserted. d) Then it is connected to
the hall effect system. e) Hall effect measurement system. f) The
HMS-300 software. . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
87
List of Tables
2.1 Two baths [16] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
2.2 One baths [50] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
2.3 Precursor solution composition [59]. . . . . . . . . . . . . . . . . . 27
3.1 Materials for experiments. . . . . . . . . . . . . . . . . . . . . . . . 31
3.2 Experimental data of copper sulfide synthesis. . . . . . . . . . . . 34
3.3 Experimental data of antimony sulfide synthesis. . . . . . . . . . . 36
3.4 Experimental data of copper antimony sulfide synthesis with
(CH3COO)3Sb. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
3.5 Experiments using CuCl2,SbCl3, and H2NCSNH2 . . . . . . . . . . 39
4.1 Experimental conditions of D-17, D-22 and D-23 samples using
CuCl2,SbCl3, and H2NCSNH2 . . . . . . . . . . . . . . . . . . . . . 41
4.2 Average thickness for samples D-17, D-22, and D-23. . . . . . . . 42
4.3 Planes and phase according of 2 θ of D-17 thin film showed at φ=0.5. 46
4.4 Planes and 2 θ corresponding to sample D-22. . . . . . . . . . . . 48
4.5 Planes and 2 θ corresponding to sample D-23. . . . . . . . . . . . 49
4.6 Carrier concentration, mobility, conductivity and Hall Coefficient are
shown of the CuSbS2 thin films at 10 (µA). The Hall Coefficients
are positive in all the samples corresponding to a p-type conduction. 70
88