Conforms to HazCom 2012/United States SAFETY … · Fiber Glass Insulation Versatile Blanket,...

Fiber Glass Insulation

Versatile Blanket, TexTuf Fiberglass Blanket, Regular G-Glass.

Solid.

GHS product identifier

Other means of identification

Product type

Emergency telephone number (with hours of operation)

Section 1. Identification:

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Supplier's details :

Identified uses


SAFETY DATA SHEETConforms to HazCom 2012/United States

QuietFlex Manufacturing Company L.P.4518 Brittmoore Rd.Houston, Texas 77041 Tel : (713) 849-2163 Toll Free : 1-877-694-3669 Fax : (713) 849-0753Web site: http://www.quietflex.com

CANUTEC: +1-613-996-6666 or *666 (cellular)CHEMTREC, U.S.: 1-800-424-9300 International: +1-703-527-388724/7

Fiberglass blanket applications for the automotive, natural gas, and construction industries. Thermal Insulation uses.

Product code : Not available.

Product code : Not available.

Section 2. Hazards identification

SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2ASPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3

Classification of the substance or mixture

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Signal word : Warning

Hazard statements : H319 - Causes serious eye irritation.H315 - Causes skin irritation.H335 - May cause respiratory irritation.

Hazard pictograms :

Precautionary statements

Prevention : P280 - Wear protective gloves. Wear eye or face protection.P271 - Use only outdoors or in a well-ventilated area.P261 - Avoid breathing dust.P264 - Wash hands thoroughly after handling.

GHS label elements

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

1/10Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com


Section 2. Hazards identificationResponse : P304 + P340 + P312 - IF INHALED: Remove person to fresh air and keep comfortable

for breathing. Call a POISON CENTER or physician if you feel unwell.P302 + P352 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse.P332 + P313 - If skin irritation occurs: Get medical attention.P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing.P337 + P313 - If eye irritation persists: Get medical attention.

Storage : P405 - Store locked up.

Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.

: None known.Hazards not otherwise classified (HNOC)

Section 3. Composition/information on ingredients

Glass, oxide, chemicals 65997-17-3 80 - 95Phenol, polymer with formaldehyde, reaction products with hexamethylenetetramine (Cured) 68585-23-9 5 - 20

Ingredient name CAS number %

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Other means of identification

: Versatile Blanket, TexTuf Fiberglass Blanket, Regular G-Glass.

Substance/mixture

CAS number/other identifiers

:

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

“Phenolic Novalac Resin / Hexamine” is thermoset into our insulation during our glass manufacturing process.

Rinse out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. This material is not meant to be ingested. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Do not rub or scratch eyes. Dust particles may cause the eye to be scratched.

Wash gently with soap and cool or room temperature water to remove dust and fibers.Get medical attention if symptoms occur.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Drink water to clear throat, and blow nose to remove dust. A saline spray in the nose may help clear any fibers. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

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Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Potential acute health effects



Section 4. First aid measures

Protection of first-aiders : No special protection is required.

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments : No specific treatment.

Inhalation : Dusts and fibers form of this product may cause temporary mechanical irritation to the nose, throat and respiratory track.

Ingestion of this product is unlikely; however, ingestion may cause gastrointestinal irritation.

:Ingestion

Skin contact : Dusts and fibers form of this product may cause temporary mechanical irritation and redness to the skin.

Dusts and fibers form of this product may cause temporary mechanical irritation to the eyes.

:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughing

No known significant effects or critical hazards.

Adverse symptoms may include the following:irritationredness

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Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Fire fighters should avoid inhaling any combustion products.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:Carbon dioxideCarbon monoxideAmmoniaWater

No specific fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use dry chemical, CO2, water spray (fog) or foam.

Extinguishing media

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None known.

Suitable extinguishing media

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Unsuitable extinguishing media

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Special protective actions for fire-fighters

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Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

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: Put on appropriate personal protective equipment.

Pick up large pieces and dispose as listed in Section 13 of this SDS.

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Pick up large pieces. Vacuum dusts and loose fibers. If sweeping is necessary, use dust suppressant such as water. Do not dry sweep dust. Never use compressed air for clean-up. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

:Spill

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep in original packaging until ready for use.

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Protective measures Put on appropriate personal protective equipment (see Section 8).:

Precautions for safe handling

: Storage should be in accordance with packaging directions, if any. Material should be stored in a dry place and kept in its original packaging until use.

Storage

Glass, oxide, chemicals NIOSH REL (United States, 10/2016). TWA: 3 f/cc 10 hours. Form: Fibers of spec length TWA: 3 f/cc 10 hours. Form: Fibers of specific length TWA: 5 mg/m³ 10 hours. Form: TotalACGIH TLV (United States, 3/2017). TWA: 5 mg/m³ 8 hours. Form: Inhalable fraction TWA: 1 f/cc 8 hours. Form: Respirable fibers: length greater than 5 uM;aspect ratio equal to or greater than 3:1 as determined by the membrane filter method at 400-450X magnification (4-mm objective) phase contrast illumination.

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Environmental exposure controls

: Pick up solid pieces and dispose of as listed in Section 13.

Appropriate engineering controls

: Good general ventilation should be sufficient to control worker exposure to airborne dust.

Control parameters

Occupational exposure limits

The Occupational Safety and Health Administration (OSHA) have not adopted specific exposure standards for fiber glass. Fiber glass is treated as a nuisance dust and is regulated by OSHA as a particulate not otherwise regulated (total dust) shown in CFR 1910.1000 Table Z-3.

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Section 8. Exposure controls/personal protection

Hand protection

A NIOSH approved N-95 series disposable respirator should be used if ventilation is unavailable, or is inadequate for keeping dust and fiber levels below applicable exposure limits referenced in Section 8 of this SDS.

Cotton or leather gloves should be worn to protect against mechanical abrasion.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.In dusty environments chemical goggles should be worn to protect against mechanical abrasion.

Eye/face protection

Respiratory protection :

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Body protection Wear a cap, a loose-fitting long sleeved shirt and long pants to protect skin from mechanical irritation. Exposed skin areas should be washed with soap and water after handling or working with fiberglass.

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Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Other skin protection : Clothing should be washed separately from other cloths, and the washer should be rinsed thoroughly (run empty for a wash cycle). This will help reduce the chances of fiber glass being transferred to other clothing.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Solid. [Fibrous glass blanket.]

Not available.

Not applicable.

Not applicable.

Not applicable.

Slight

Organic (resin).Odor

pH

Yellow to brown.Color

Evaporation rate Not applicable.

Auto-ignition temperature

Flash point

Not available.

Not applicable.

Not available.

Not applicable.

Viscosity Not applicable.

Not available.Odor threshold

Partition coefficient: n-octanol/water

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Appearance

Boiling point : Not applicable.

Flammability (solid, gas) : Non-flammable.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

Volatility Not available.:

VOC (w/w) : 0 % (w/w)



Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid None.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable under normal conditions.Chemical stability

None.

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Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Acute toxicity

Carcinogenicity

Irritation/Corrosion

Sensitization

Information on the likely routes of exposure

Inhalation : Dusts and fibers form of this product may cause temporary mechanical irritation to the nose, throat and respiratory track.

Skin contact : Dusts and fibers form of this product may cause temporary mechanical irritation and redness to the skin.

Dusts and fibers form of this product may cause temporary mechanical irritation to the eyes.

:Eye contact

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Name Category

Aspiration hazard

Route of exposure

Target organs

Information on toxicological effects

: Dermal contact. Eye contact. Inhalation. Ingestion.

Potential acute health effects

There is no data available.

Dust from this product is a mechanical irritant; which means that it may cause irritation or scratchiness of the throat and/or itching and redness of the eyes and skin.


Classification

Product/ingredient name

Glass, oxide, chemicals - 3 - A4 - -

ACGIH EPA NIOSHNTPIARCOSHA

Fiber Glass Insulation Category 3 Not applicable. Respiratory tract irritation





Section 11. Toxicological informationIngestion of this product is unlikely; however, ingestion may cause gastrointestinal irritation.

:Ingestion

No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughing

No known significant effects or critical hazards.

Adverse symptoms may include the following:irritationredness

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Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Acute toxicity estimates

Potential immediate effects

: No known significant effects or critical hazards.

Short term exposure

Potential delayed effects : No known significant effects or critical hazards.

Potential immediate effects

: No known significant effects or critical hazards.

Long term exposure

Potential delayed effects : No known significant effects or critical hazards.


Section 12. Ecological information

Bioaccumulative potential

Toxicity

Persistence and degradability

Mobility in soil






Section 12. Ecological information

Other adverse effects : No known significant effects or critical hazards.

Soil/water partition coefficient (KOC)

: There is no data available.

Section 13. Disposal considerationsThis product is not expected to be a hazardous waste when it is disposed of according to the U.S. Environmental Protection Agency (EPA). Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

:Disposal methods

Section 14. Transport information

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Not regulated.

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Not regulated. Not regulated.

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DOT IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

No. No. No.

AERG : Not applicable.

Special precautions for user

Transport in bulk according to Annex II of MARPOL and the IBC Code

These products are not classified as dangerous goods according to international transport regulations.

: Not available.

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Section 15. Regulatory informationU.S. Federal regulations :

: Listed

: Not listed

: Not listed

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): All components are listed or exempted.

Clean Water Act (CWA) 311: Formaldehyde

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)

Clean Air Act Section 602 Class I Substances

Clean Air Act Section 602 Class II Substances



Section 15. Regulatory information

The following components are listed: Glass, oxide, chemicalsMassachusetts :

SARA 313

: Not listed

: Not listed

New York : None of the components are listed.

New Jersey : None of the components are listed.

Pennsylvania : None of the components are listed.

State regulations

SARA 302/304

SARA 304 RQ : Not applicable.

Composition/information on ingredients

Name % EHS (lbs) (lbs)(gallons) (gallons)

SARA 302 TPQ SARA 304 RQ

SARA 311/312

Classification : Immediate (acute) health hazard

Name % Fire hazard

Sudden release of pressure

Reactive Immediate (acute)health hazard

Delayed (chronic)health hazard

Composition/information on ingredients

Formaldehyde 0 - 0.001 Yes. 500 - 100 -

Glass, oxide, chemicals 80 - 95 No. No. No. No. Yes.

DEA List I Chemicals (Precursor Chemicals)

DEA List I Chemicals (Precursor Chemicals)

No products were found.

California Prop. 65

WARNING: This product can expose you to Formaldehyde, which is known to the State of California to cause cancer.For more information go to www.P65Warnings.ca.gov.

Formaldehyde Yes. -

Ingredient name No significant risk level

Maximum acceptable dosage level

Section 16. Other informationHistory

Prepared by :

Date of issue mm/dd/yyyy

Date of previous issue

Version :

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2

01/30/2018

05/15/2015

KMK Regulatory Services Inc.



Section 16. Other informationKey to abbreviations : ATE = Acute Toxicity Estimate

BCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations

Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.


Conforms to HazCom 2012/United States SAFETY … · Fiber Glass Insulation Versatile Blanket,...

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