CO2 Capture System with Chilled Ammonia: Pilot to Demonstration to Commercial Scale
Transcript of CO2 Capture System with Chilled Ammonia: Pilot to Demonstration to Commercial Scale
Robert Hilton June 5, 2012
RECS 2012
CO2 Capture System With Chilled Ammonia: Pilot to
Demonstration to Commercial
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Equipment & services for power generation Alstom Thermal Power
Equipment & services for rail transport Alstom Transport
Three main activities in 4 sectors*
Equipment & services for power transmission Alstom Grid Alstom Renewable Power
* Organisation as of 4 July 2011 Alstom – CO2 Capture Systems - P 2
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Some key numbers
Transport 5.6 €bn
Thermal Power 9.7 €bn
Grid 3.6 €bn
Renewable Power 2 €bn
17%
10%
27%
46%
92,500 employees in 100 countries
Total sales 2010/11: €20.9 billion
Alstom – CO2 Capture Systems - P 3
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Alstom – CO2 Capture Systems - P 4
Agenda
Introduction to CO2 emissions
CO2 Capture within Alstom
Conclusion
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
CO2 Réductio
n
CO2 emissions Scénarios
Global CO2 emissions due to fossil (all sectors, coal, gas, oil) GtCO2
* Source: WEO/IEA 2011
Présentation CSC - IEEE-PES- 12 avril 2012 - P 5
Outstanding effort needed to reach 450 ppm objective +2°C The door is closing !
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
1990 2009 2035
Global Fossil related CO2 emissions
21 GtCO2
29 GtCO2
43 GtCO2
36 % 41 % 46 %
Other sectors
Power Generation
Evolution of global CO2 emissions
Alstom – CO2 Capture Systems - P 6
* Source: IEA 2011 - Current Policies Scenario
2035: Power Generation remains the main contributor of CO2 emissions
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Developing countries represent 100% of incremental CO2 emissions
Power sector – Annual CO2 emissions
12
20 GtCO2
Oil Gas
Coal
India
China
Europe
RoW
NAM
2009 2035
20
15
10
5
0
By fuel By region
12
20
2009 2035
20
15
10
5
0
Evolution of Power CO2 emissions
Alstom – CO2 Capture Systems - P 7
* Source: IEA 2011 - Current Policies Scenario
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
CCS is essential for Power generation
Power generation CO2 Emissions
12 CCS pilots 5 large-scale
demo in development
CCS on gas and coal power generation is essential to massively reduce CO2 emissions from fossil plants complementary to REN &
NUC technologies
Source : Alstom analysis from IEA WEO 2011
0
5
10
15
20
25
Gt/y
1990 2035 Current Policies
path +6°C
2035 New Policies path +3,5°C
2035 450 ppm
Needed path +2°C
Includes CCS 75 GWe
Includes CCS 540 GWe
Alstom – CO2 Capture Systems - P 8
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Clean coal and gas solutions
CCS also apply to the installed base
Source: Vattenfall
Pre-combustion (New only)
Power Plant with CO2 capture
Post-combustion Oxy-combustion (New + retrofit) (New + retrofit)
Alstom – CO2 Capture Systems - P 9
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Alstom – CO2 Capture Systems - P 10
Agenda
Introduction to CO2 emissions
CO2 Capture within Alstom
Conclusion
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Technologies developed by Alstom
CO2 capture technologies pursued by Alstom
Post-combustion Oxy-combustion (New + retrofit) (New + retrofit)
• Advanced Amines
• Chilled Ammonia
• Oxy combustion with Air Separation Unit
• Chemical Looping Combustion (2nd generation)
Alstom – CO2 Capture Systems - P 11
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
CO2 capture and storage Projects and partnerships
tCO2 captured
Alstom – CO2 Capture Systems - P 12
Oxy-combustio
n
Schwarze Pumpe (Germany)–Lignite 70’000 t/y
Tests complete Operating
Lacq (France) – Gas 60’000 t/y
30 MWth
30 MWth
Alstom Windsor (US) – Coals Eq +/-30’000 t/y 15 MWth UK oxy CCS demo (UK)- Coal –
Application NER300 2’000’000 t/y 426 MWe
Chemical Looping (Germany)-Coal 2’000 t/y eq. 1 MWth Chemical Looping(USA) - Coal 6’000 t/y eq. 3 MWth 2nd Gen
Daqing (China)– Lignite Feasibility study signed >1’000’000 t/y 350 MWe
Mountainer (US)–Coal–Chilled Ammonia 100’000 t/y
Pilot West Virginia (US) – coal Joint development programme – Adv. Amines
Post-combustio
n Mongstad (Norway) – Gas – Chilled Ammonia 80’000 t/y
Pleasant Prairie (US) – coal Chilled Ammonia 15’000 t/y
Karlshamm (Sweden) – Fuel/Gas Chilled Ammonia 15’000 t/y
Le Havre (France)–Coal– Adv. Amines
1’800 t/y
8’000 t/y
Belchatow (Poland) – Lignite Adv. amines - FEED complete – Application NER 300 >1’800’000 t/y
58 MWth
40 MWth
5 MWth
5 MWth
2 MWth
5 MWth
260 MWe
Getica-Turceni (Romania) – Lignite Chilled Ammonia-feasibility study– Application NER 300 >1’500’000 t/y 250 MWe
Dongying (China) – Coal - MoU signed >1’000’000 t/y 350 MWe
Under construction
Alstom labs Växjö (Sweden) – multi-purp. 400 t/y eq. 0.25 MWth
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Principle • Ammonium carbonate solution reacts with
CO2 of cooled flue gas to form ammonium bicarbonate
• Raising the temperature reverses this reaction, pressurized CO2 is released, the solution is recycled
Chilled Ammonia Process Technology Overview
Advantages
• High CO2 purity • Tolerant to oxygen and flue gas
impurities • Stable reagent, no degradation nor
emission of trace contaminants • Low-cost, globally available reagent
A promising new technology Alstom – CO2 Capture Systems - P 13
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Chilled Ammonia Process Overview
Cooling & Cleaning CO2 Absorption CO2 Regeneration
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Roadmap to scale-up promising Chilled Ammonia!
Test Rigs Validation Pilots
Commercial Industrial Pilots
Large-scale demonstration
Alstom Vaxjö Sweden 0.25 MWth
We Energies Pleasant Prairie USA - 5 MWth, Coal EoN Karlshamn
Sweden - 5 MWth, Oil
AEP Mountaineer USA - 58 MWth, Coal
TCM Mongstad Norway - 40 MWth, Gas
Getica Turceni Feasability Romania - >250 Mwe net, Lignite
2015 2006 2008 2009
Tests successful
Tests completed Targeted In operation In construction
Chilled Ammonia Process Update on Alstom roadmap
Datang - Dongying (Post AAP or CAP) China - 350 MWe eq. , coal - MOU
Alstom – CO2 Capture Systems - P 15
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Chilled Ammonia Process Field Pilot – Pleasant Prairie
Pleasant Prairie - Field Pilot – USA WI
We Energies • Operational June 2008 – Oct 2009 • 7700+ hours of operation on flue gas from PRB Coal through completion of program in Oct 2009 • Proof of Concept technology validation:
− 90% CO2 capture efficiency − NH3 slip from DCC2 (~5 ppm) − 99+% CO2 purity; >10 ppm NH3;
>2,000 ppm H2O − Functional unit operations − Confirmation of process design tools − Confirmation of equipment design
methods CO2 Field Pilot at Pleasant
Prairie Alstom – CO2 Capture Systems - P 16
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Chilled Ammonia Process Field Pilot - Karlshamn
Karlshamn - Field Pilot - Sweden - E.ON
• Designed to capture over 1,600 kg CO2/hr (~15,000 tonnes/yr at full capacity)
• Operational Apr 2009 • Test phase completed in 2010 • Flue gases from sulfur fuel oil and
from gas combustion tested
• Located less than 60 miles (90 km) from Alstom’s Global Technology Center in Vaxjo
• Proof of Concept technology validation: - 90% CO2 capture efficiency - NH3 slip from DCC2 (~5 ppm) - 99+% CO2 purity; <10 ppm NH3 - Functional unit operations - HP Stripper operation affirmed
CAP Field Pilot
Karlshamn Power Plant (Sweden)
Alstom – CO2 Capture Systems - P 17
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Mountaineer - Validation coal pilot - USA WV- AEP
• Designed to capture & store 100,000 tCO2/year
• Commenced engineering and permitting Oct07
• First CO2 captured in Sept 09,
• Captured CO2 sequestered into through two wells on the plant property, first injection started 1st of October 2009
• Alstom responsible for CAP island (others by AEP)
• Test completed:
− Approx 52000 tons of CO2 captured
− Approx 37000 tons of CO2 stored
− CO2 product quality : 99.94%
− Capture rate: 90% validated
− Low ammonia emissions observed
Chilled Ammonia Process Validation Pilot - AEP Mountaineer
Alstom’s Chilled Ammonia Process at AEP’s PP Tests completed - Technology validated – Ready for scale-up
Alstom – CO2 Capture Systems - P 18
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Chilled Ammonia Process Validation Pilot – Mongstad Norway
• European CO2 Technology Centre
Mongstad (TCM)
• Flue gases from natural gas CHP plant and
a catalytic cracker (refinery)
• Designed to capture 80 000 tons CO2/year
• Cold commissioning initiated on some
systems that are mechanically complete
• Plant commissioning 1st quarter 2012
CCS technology validation on gas Alstom – CO2 Capture Systems - P 19
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Chilled Ammonia Process Demonstration project at Turceni
Romanian CCS Demonstration Project
• Integrated CCS demo: 1.5 Mtpa CO2 – Capture: 85% minimum capture – Transport: onshore pipeline – Storage: deep saline aquifers (>800m) within
a radius of 50 km • Developers-Operators:
– Capture: Turceni Energy Complex – Transport: Transgaz – Storage: Romgaz
• Technical Consortium: – Project Management and Technical &
Financial Consultant: ISPE (Institute for Studies and Power Engineering)
– Capture Plant: Alstom – Storage: GeoEcoMar, Schlumberger
• Alstom feasibility study completed • Candidate for NER 300 funding
Turceni Power Plant 4x330 MW
Alstom – CO2 Capture Systems - P 20
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
What we have achieved
Pilot operation confirm CO2 capture works and performances will improve
We Energies Pleasant Prairie USA - Coal - Chilled Ammonia
Vattenfall Schwarze Pumpe Germany - Lignite & Bit. Coal - Oxy
Dow Chemical Co. Charleston USA - Coal - Advanced Amines
CO2 capture rate
CO2 purity
Reached
>99.7%
>99.9%
>99.5% 90%
90%
90%
Parasitic load [%] on net efficiency
Pilot phase Demo phase Commercial phase
Thermodynamic theoretical limit: assuming ideal separation and compression processes*
Realistic limit
*Theoretical limit assumes ideal separation and compression processes (110bar): isentropic, no losses
AEP Mountaineer USA - Coal - Chilled Ammonia
>99% 90%
15
20
25
10
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Tests complete
Vattenfall Schwarze-
Pumpe Germany- 30 MWth Oxy -
Lignite
Dow Chemical Co. US -2 MWth
Adv. Amines - coal
Datang- China Oxy 350 MWe lignite,
Post 350 MWe eq. coal Alstom BSF
Windsor US - 15 MWth Oxy - coals
Getica - CET Turceni Roumania – >250MWe
Chilled ammonia - Lignite
PGE Belchatow Poland – 260 MWe
Adv. Amines - Lignite
DOE/Alstom Windsor
US – 3 MWth Chemical looping
- coal
2nd Gen
NER300
NER300
Selected for receiving EEPR funding
NER300: Applied for EU ETS New Entrant Reserve funding
EoN Karlshamn Sweden - 5 MWth
Chilled Ammonia–Fuel oil
WE – Energie US - 5 MWth
Chilled Ammonia, Coal
AEP Mountaineer US - 58 MWth
Chilled Ammonia, coal
Total Lacq France - 30 MWth
Oxy - Gas
Operating
Alstom Labs Växjö Sweden – 0.25 MWth
Post C. – multi purpose
Large-scale projects-under development
White Rose CCS Project UK - 426 MWe
Oxy – coal
NER300
Under construction
TCM Mongstad Norway - 40 MWth
Chilled Ammonia - Gas
EDF – Le Havre France – 5 MWth
Adv. Amines - Coal
Alstom activity on demonstration 1st and 2nd Generation CCS
RFCS EU -Darmstadt Germany –1 MWth Chemical looping -
coal
2 Gen
Alstom – CO2 Capture Systems - P 22
Reaching demonstration
Support is essential
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Potential Large Scale CCS Projects Opportunity in China
Datang Daqing 350 MWe Project • Full size Oxy-combustion CO2 capture (~1MtCO2/yr) • Cogeneration of Heat and Power based on Super Critical boiler using lignite • Location: Daqing, Heilongjiang province • EOR and CO2 storage: adjacent to PetroChina’s Daqing oil field for EOR,
near to Songliao basin for geological sequestration
Datang Dongying 350 MWe Project • Partial flue gas stream slip to Post-combustion CO2 capture (~1MtCO2/yr) • Ultra Super Critical boiler using bituminous or sub-bituminous coal • Location: Dongying, Shangdong province • EOR: very near to Sinopec’s Shengli oil field for EOR
MOU Datang-Alstom signed in Sept 2011 to develop projects Alstom – CO2 Capture Systems - P 23
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
CCS roadmap: time-to market
First CCS commercial plants before 2020 Market and technology development require large-scale demos
now ! Alstom – CO2 Capture Systems - P 24
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
6 58 6
0
5 0
1 0 0
1 5 0
2 0 0
2 5 0
3 0 0
H a rd C o a lw ith C C S
2 0 1 5
G a s C Cw ith C C S
2 0 1 5
N u c le a r H y d ro G e o -th e rm a l
W in dO n s h o re
W in dO ffs h o re
S o la rT h e rm a l
S o la r P V0
5 0
1 0 0
1 5 0
2 0 0
2 5 0
3 0 0
€ / MWh CoE Low Carbon technologies over 2011-2016 period (New PP)
Reference case
Under realistic assumptions and with a conservative variation range, CCS is already competitive on coal and gas from 2015
CCS competitiveness against other low carbon alternatives in Europe in 2015
Source : Alstom analysis 2011. CCS Post amine 2015 costs, including on shore T&S and CO2 price (Flue Gas Recirculation case for CCS Gas CC) - Cost for firming intermittent Power Generation not accounted
EUR
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Alstom – CO2 Capture Systems - P 26
Agenda
Introduction to CO2 emissions
CO2 Capture within Alstom
Conclusion
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Conclusion
Alstom: a key partner in CCS!
• Fossil Plants will still remain for several decades
• Reducing CO2 emissions from these plants is an absolute need to limit global warming to 2 °C (the current path leads to 6°C !)
• CCS is the only alternative to do it. It is competitive and affordable on both gas and coal
• Alstom is currently developing CO2 capture technologies and is on the good path to commercialise the technology by 2016-17
Alstom – CO2 Capture Systems - P 27
• Large scale demonstrators must happen now to validate the technology on time
• Policy instruments are needed to support demonstration and early commercial phases (ex: FITs...)
• Retrofitable CCS technologies and CCS-Ready are also a must to reach CO2 target
www.alstom.com
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Advanced Amine Process Technology Overview
Advantages
• Proven in natural gas & syngas purification
• CO2 capture from flue gas is a new application
• More efficient capture of CO2 and less solvent degradation than MEA
• Higher tolerance against oxygen & trace contaminants
Source: Alstom
Principle
• An amine based solvent reacts with the CO2 in the flue gas
• Raising the temperature reverses this reaction, the CO2 is released and the solvent recycled
Joint Development A strong team to develop a new application
Alstom – CO2 Capture Systems - P 29
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Pilot Commercial Industrial / Validation Large-scale demonstration
University of Texas USA
2007 2009 2011
Advanced Amine Process Update on Alstom roadmap
Dow Chemical Co. USA - 2MWth, Coal
EdF Le Havre France - 5 MWth, Coal
PGE Belchatow Poland - 260 MWe net, Lignite
Tests completed Targeted In operation In construction
2014-2015
Moving forward to scale-up the technology Alstom – CO2 Capture Systems - P 30
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
J.J. Pickle Energy Research Center
Advanced Amine Process Pilot - University of Texas
University of Texas Test Program
• Designed to capture over 5 tonnes CO2/day – Gas flow 500 SCFM – Synthetic Flue Gas
Project Schedule
• Phase I Testing Completed Dec 2007 – Initial Solvent Validation
• Phase II Testing Completed Nov. 3, 2008 – Packing Studies
• Phase III Testing Completed Nov. 17, 2008 – Process Simulator Validation
Alstom – CO2 Capture Systems - P 31
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Charleston - field pilot - USA WV - Dow
• Designed to capture 1,800 t CO2/year
• Installation on commercially operating coal-fired boiler
• Project schedule
- Commissioning in August 09
- Testing started in September 09
- Conversion to advanced configuration in early 2010 to test proprietary process flow scheme jointly developed by Dow and Alstom
Advanced Amine Field Pilot Charleston, West Virginia
Advanced Amine Process Field Pilot - Charleston
Alstom – CO2 Capture Systems - P 32
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Advanced Amine Process Field Pilot - Le Havre
C2A2 - field pilot - Le Havre - France
• Designed to capture 25 t CO2/ day, 90% CO2 capture
• Advanced flow scheme & operation validation
• Flue gas: slipstream from 600 MWe coal plant (EdF host facility)
• French funding by ADEME • Project schedule
- Overall 2010-2013 program - Test from Q3 12 to Q2 13 (1
year) Alstom – CO2 Capture Systems - P 33
EdF Le Havre coal power plant (field pilot represented in
orange)
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Advanced Amine Process Large scale demonstration - Belchatow
Belchatow - Large scale - Poland - PGE
• MOU Alstom - PGE Elektrownia Belchatow
• Large-scale CCS demonstration facility 260 MWe net
• Host facility 850 MW lignite unit (built by Alstom)
• 1.8 Mt CO2 to be captured and stored per year
• Selected for EERP funding, preselected for NER300
• Project schedule: – Engineering for permitting completed – 2012: Finalizing Contract – Target for operation 2015
Belchatow Power Plant Reaching large scale demonstration phase
Alstom – CO2 Capture Systems - P 34
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Oxy-Combustion Process Technology Overview
A sound technological option !
Advantages • Reliability • Adaptable to all boiler types and fuels • Rapid scale-up to 1,000 Mwe range • Retrofit in Oxy can be addressed • Higher efficiency with supercritical/
ultra-supercritical cycles
Principle • Fuel is burned in a mixture of oxygen and re-circulated flue-gas. Due to the absence
of Nitrogen, the resulting flue gas is enriched in CO2 • After water condensing and further purification, CO2 is compressed and send to
storage
Alstom – CO2 Capture Systems - P 35
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Moving forward to scale-up the technology
Oxy-Combustion Process Update on Alstom roadmap
Alstom – CO2 Capture Systems - P 36
Coming
Commercial
2017/18
White Rose 426 MWe g - Selby (UK)
90’s R&D and Lab
scale Large –scale
demonstration
In operation
Alstom BSF USA - 15 MWth,
Vattenfall Schwarze Pumpe Germany - 30 MWth,
Total Lacq France - 30 MWth,
GPU mobile pilot
Pilots
2008 2012
Daqing 350 MWe g Datang (China)
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
(source: Vattenfall) Schwarze Pumpe Pilot
Oxy-Combustion Process Vattenfall Schwarze Pumpe – 30 MWth pilot
Experience makes success possible
Boiler
FGC CO2 Compression
Air Separation Unit
CO2 Purification
Control Room
FGD
ESP
Boiler
FGC CO2 Compression
Air Separation Unit
CO2 Purification
Control Room
FGD
ESP
Objective • Demonstration of the technology path
at pilot scale
Alstom-Scope • Oxy-boiler, ESP and other
components • Technology Partnership with
Vattenfall
Status of Operation • Start of operation: Sept 2008 • Test with Alstom Burners completed
Alstom – CO2 Capture Systems - P 37
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Main features • Retrofit to oxy-combustion of a 30 MWth
existing boiler (natural gas) • Located in SW of France • Oxy-combustion process started Jul 09 • End test expected end 2012 (18 mths
extension of the original programme) • Approx 120,000 t CO2 to be stored in a
depleted gas field • ALSTOM scope : Boiler retrofit 30 MWt retrofitted Boiler – Lacq,
France
(source: Total)
First fully integrated CCS with pipeline transportation & storage
Oxy-Combustion Process TOTAL Lacq - 30 MWth Pilot
Alstom – CO2 Capture Systems - P 38
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Main features • Located at the Alstom Power Plant
Laboratory (PPL) in Windsor, CT, USA • 15 MWth oxy-fuel boiler simulation facility
(BSF), multi-burner arrangement (tangential firing system)
• 15 MWth oxy-fuel industrial scale single burner test facility (ISBF)
• Bituminous coals and lignites • Modification of the existing BSF and ISBF
test facilities with support from the US Department of Energy (DOE)
• Started testing in Sept. 09 • Oxygen supply via tanks • Wet and dry flue gas recycle options
Boiler Simulation Facility (BSF)
Oxy-Combustion Process Alstom Windsor – 15 MW Pilot
Alstom – CO2 Capture Systems - P 39
© ALSTOM 2012. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Oxy-Combustion Process The White Rose CCS project in the UK
Largest Oxyfuel CCS Demo
• A new modern ultra-supercritical 426MWe Gross Oxy-fuel Power Plant
• Clean power generation with the entire flue gas treated to capture 2 Million t/y CO2
• Biomass co-firing leading to zero (or negative!) CO2 emissions
• Associated with National Grid’s (NG) regional CO2 transport & offshore storage network
• Project development activities on-going
• NER funding application under EC evaluation.
• UK Demo funding application planned Alstom – CO2 Capture Systems - P 40
Location: Drax Power Station, North Yorkshire, UK
ALSTOM DRAX
Project Promoters
NATIONAL GRID
Oxy-fuel Power Plant CO2
Transportation & Storage
BOC-Linde