Clean Harbors Profile No. CH425704B - DTSC · 2010. 4. 23. · Boeing Company The - SSFL 5800...

Clean Harbors Profile No. CH425704B

WASTE MATERIAL PROFILE SHEET

Report Printed On : Tuesday, March 23, 2010 /WINWEB/Profile\Waste Profile.rdl Page 1 of 3

Canoga Park

A. GENERAL INFORMATIONGENERATOR EPA ID #/REGISTRATION # CAD093365435GENERATOR CODE (Assigned by Clean Harbors)

5800 Woolsey Canyon Road

GENERATOR NAME:

CITY STATE/PROVINCE

Boeing Company The - SSFL

ZIP/POSTAL CODE 91304

PHONE: (818) 466-8779

CABO1226ADDRESS

ZIP/POSTAL CODECUSTOMER CODE (Assigned by Clean Harbors)ADDRESS

CUSTOMER NAME:CITY STATE/PROVINCECanoga Park CA 91304

Boeing Company The - SSFL5800 Woolsey Canyon Road

BO1226

B. WASTE DESCRIPTIONWASTE DESCRIPTION: CTL-5 Fuel Loop Road Base, Aera 1

PROCESS GENERATING WASTE (Please provide detailed description of process generating waste):

Demolition

C. PHYSICAL PROPERTIES (at 25C or 77F)

PHYSICAL STATESOLID WITHOUT FREE LIQUIDPOWDERMONOLITHIC SOLIDLIQUID WITH NO SOLIDSLIQUID/SOLID MIXTURE

% FREE LIQUID% SETTLED SOLID% TOTAL SUSPENDED SOLID

SLUDGE

GAS/AEROSOL

% BY VOLUME (Approx.)

NUMBER OF PHASES/LAYERS

TOP

MIDDLE

BOTTOM

321 0.00

0.00

0.00

ODOR

NONE

MILD

STRONG

Describe:

BOILING POINT ºF (ºC)

<= 95 (<=35)

95 - 100 (35-38)

101 - 129 (38-54)

>= 130 (>54)

COLOR

Brown

VISCOSITY (If liquid present)1 - 100 (e.g. Water)

101 - 500 (e.g. Motor Oil)

501 - 10,000 (e.g. Molasses)

> 10,000

TOTAL ORGANIC CARBON

<= 1%

1-9%

>= 10%

< 140 (<60)

140-200 (60-93)

> 200 (>93)

MELTING POINT ºF (ºC)

FLASH POINT ºF (ºC)

< 73 (<23)

73 - 100 (23-38)

101 -140 (38-60)

141 -200 (60-93)

> 200 (>93)

SPECIFIC GRAVITY

< 0.8 (e.g. Gasoline)

0.8-1.0 (e.g. Ethanol)

1.0 (e.g. Water)

> 1.2 (e.g. Methylene Chloride)

1.0-1.2 (e.g. Antifreeze)

pH

2.1 - 6.9

<= 2

7 (Neutral)

7.1 - 12.4

>= 12.5

BTU/LB (MJ/kg)

< 2,000 (<4.6)

2,000-5,000 (4.6-11.6)

5,000-10,000 (11.6-23.2)

> 10,000 (>23.2)

Actual:

ASH

< 0.1

0.1 - 1.0

1.1 - 5.0

5.1 - 20.0

> 20

Unknown

DOES THIS WASTE CONTAIN ANY HEAVY GAUGE METAL DEBRIS OR OTHER LARGE OBJECTS (EX., METAL PLATE OR PIPING >1/4” THICK OR >12” LONG, METAL REINFORCED HOSE >12” LONG, METAL WIRE >12” LONG, METAL VALVES, PIPE FITTINGS, CONCRETE REINFORCING BAR OR PIECES OF CONCRETE >3”)?

YES NO

If yes, describe, including dimensions:

D. COMPOSITION (List the complete composition of the waste, include any inert components and/or debris. Ranges for individual components are acceptable. If a trade name is used, please supply an MSDS. Please do not use abbreviations.)

FUEL HYDROCARBONS C10-C24 0.0000000 -- 86.0000000 PPM

FUEL HYDROCARBONS C25-C40 7.0000000 -- 540.0000000 PPM

CRUSHED MISCELLANEOUS BASE 99.0000000 -- 100.0000000 %

CHEMICAL MIN -- MAX UOM

DOES THIS WASTE CONTAIN ANY METALS IN POWDERED OR OTHER FINELY DIVIDED FORM? YES NO

DOES THIS WASTE CONTAIN OR HAS IT CONTACTED ANY OF THE FOLLOWING; ANIMAL WASTES, HUMAN BLOOD, BLOOD PRODUCTS, BODY FLUIDS, MICROBIOLOGICAL WASTE, PATHOLOGICAL WASTE, HUMAN OR ANIMAL DERIVED SERUMS OR PROTEINS OR ANY OTHER POTENTIALLY INFECTIOUS MATERIAL?

YES NO

I acknowledge that this waste material is neither infectious nor does it contain any organism known to be a threat to human health. This certification is based on my knowledge of the material. Select the answer below that applies:

The waste was never exposed to potentially infectious material. YES NO

Chemical disinfection or some other form of sterilization has been applied to the waste. YES NO

I ACKNOWLEDGE THAT THIS PROFILE MEETS THE CLEAN HARBORS BATTERY PACKAGING REQUIREMENTS. YES NO

I ACKNOWLEDGE THAT MY FRIABLE ASBESTOS WASTE IS DOUBLE BAGGED AND WETTED. YES NO

SPECIFY THE SOURCE CODE ASSOCIATED WITH THE WASTE. SPECIFY THE FORM CODE ASSOCIATED WITH THE WASTE.G44 W301



If based on knowledge, please describe the rationale applied to identify and characterize the waste material (ex., include reference to Material Safety Data Sheets, process considerations, operating procedures).

TestingKnowledgeAre these values based on testing or knowledge?

E. CONSTITUENTS

CYANIDE AMENABLE

AMMONIA

SODIUM

SULFIDE REACTIVE

CYANIDE TOTAL

CYANIDE REACTIVE

POTASSIUM

CHLORINE

BROMINE

OTHER CONSTITUENTS MAX UOM NOT APPLICABLE

SULFUR

IODINE

FLUORINE

D035 METHYL ETHYL KETONE 200.0

D029 1,1-DICHLOROETHYLENE 0.7

D039 TETRACHLOROETHYLENE 0.7

D043 VINYL CHLORIDE 0.2

D040 TRICHLOROETHYLENE 0.5

D028 1,2-DICHLOROETHANE 0.5

D018 BENZENE 0.5

VOLATILE COMPOUNDS

D019 CARBON TETRACHLORIDE 0.5

D022 CHLOROFORM 6.0

D021 CHLOROBENZENE 100.0

D036 NITROBENZENE 2.0

D034 HEXACHLOROETHANE 3.0

D033 HEXACHLOROBUTADIENE 0.5

D037 PENTACHLOROPHENOL 100.0

D042 2,4,6-TRICHLOROPHENOL 2.0

D041 2,4,5-TRICHLOROPHENOL 400.0

D038 PYRIDINE 5.0

D032 HEXACHLOROBENZENE 0.13

D024 m-CRESOL 200.0

D023 o-CRESOL 200.0

SEMI-VOLATILE COMPOUNDS

D025 p-CRESOL 200.0

D030 2,4-DINITROTOLUENE 0.13

D027 1,4-DICHLOROBENZENE 7.5

D026 CRESOL (TOTAL) 200.0

D017 2,4,5-TP (SILVEX) 1.0

D016 2,4-D 10.0

D031 HEPTACHLOR (AND ITS EPOXIDE) 0.008

D020 CHLORDANE 0.03

D015 TOXAPHENE 0.5

D012 ENDRIN 0.02

PESTICIDES AND HERBICIDES

D014 METHOXYCHLOR 10.0

D013 LINDANE 0.4

HOCs

NONE

< 1000 PPM

>= 1000 PPM

PCBs

NONE

< 50 PPM

>=50 PPM

IF PCBS ARE PRESENT, IS THE WASTE REGULATED BY TSCA 40 CFR 761?

YES NO

Please indicate which constituents below apply. Concentrations must be entered when applicable to assist in accurate review and expedited approval of your waste profile. Please note that the total regulated metals and other constituents sections require answers.

ADDITIONAL HAZARDSDOES THIS WASTE HAVE ANY UNDISCLOSED HAZARDS OR PRIOR INCIDENTS ASSOCIATED WITH IT, WHICH COULD AFFECT THE WAY IT SHOULD BE HANDLED?

YES NO (If yes, explain)

DEA REGULATED SUBSTANCE EXPLOSIVE FUMING

NONE OF THE ABOVEPOLYMERIZABLE RADIOACTIVE REACTIVE MATERIAL

D009 MERCURY 0.2

D008 LEAD 5.0

D011 SILVER 5.0

D010 SELENIUM 1.0

D007 CHROMIUM 5.0

D004 ARSENIC 5.0

RCRA REGULATED METALS REGULATORYLEVEL (mg/l)

TCLPmg/l

TOTAL UOM NOT APPLICABLE

D006 CADMIUM 1.0

D005 BARIUM 100.0

CHOOSE ALL THAT APPLY

OSHA REGULATED CARCINOGENS



NONE, NON HAZARDOUS, NON D.O.T. REGULATED, N/A, SOIL

G. DOT/TDG INFORMATION

DOT/TDG PROPER SHIPPING NAME:

YES NO IF THIS IS A US EPA HAZARDOUS WASTE, DOES THIS WASTE STREAM CONTAIN BENZENE?

YES NO DO ANY CANADIAN PROVINCIAL WASTE CODES APPLY?

YES NO IS THE GENERATOR OF THE WASTE CLASSIFIED AS CONDITIONALLY EXEMPT SMALL QUANTITY GENERATOR (CESQG)?

YES NO IS THIS WASTE STREAM SUBJECT TO THE INORGANIC METAL BEARING WASTE PROHIBITION FOUND AT 40 CFR 268.3(C)?

Pharmaceuticals production (subpart GGG)Hazardous Organic NESHAP (HON) rule (subpart G)

YES NO IS THE WASTE SUBJECT TO ONE OF THE FOLLOWING NESHAP RULES?

YES NO IS THIS MATERIAL GOING TO BE MANAGED AS A RCRA EXEMPT COMMERCIAL PRODUCT, WHICH IS FUEL (40 CFR 261.2 (C)(2)(II))?

Texas Waste Code

YES NO DO ANY STATE WASTE CODES APPLY?

YES NO USEPA HAZARDOUS WASTE?

NO IS THIS WASTE PROHIBITED FROM LAND DISPOSAL WITHOUT FURTHER TREATMENT PER 40 CFR PART 268?

LDR CATEGORY:VARIANCE INFO:

YES NO IS THIS A UNIVERSAL WASTE?

YES NO DOES TREATMENT OF THIS WASTE GENERATE A F006 OR F019 SLUDGE?

YES NO

YES NO DOES THE WASTE CONTAIN GREATER THAN 20% OF ORGANIC CONSTITUENTS WITH A VAPOR PRESSURE >= .3KPA (.044 PSIA)?

YES NO DOES THIS WASTE CONTAIN AN ORGANIC CONSTITUENT WHICH IN ITS PURE FORM HAS A VAPOR PRESSURE > 77 KPA (11.2 PSIA)?

NO IS THIS CERCLA REGULATED (SUPERFUND ) WASTE ?YES

YES

DOES THIS WASTE CONTAIN VOC'S IN CONCENTRATIONS >=500 PPM?

Not subject to LDR

Megagram/year (1 Mg = 2,200 lbs)

Describe the knowledge :

Knowledge TestingThe basis for this determination is: Knowledge of the Waste Or Test Data

What is the TAB quantity for your facility?

YES NO Is the generating source of this waste stream a facility with Total Annual Benzene (TAB) >10 Mg/year?

YES NO Does the waste stream come from a facility with one of the SIC codes listed under benzene NESHAP or is this waste regulated under the benzene NESHAP rules because the original source of the waste is from a chemical manufacturing, coke by-product recovery, or petroleum refinery process?

F. REGULATORY STATUS

H. TRANSPORTATION REQUIREMENTS

CONTAINER TYPE:STORAGE CAPACITY:

CONTAINERS/SHIPMENT

CONTAINERIZED

0-0

DRUMOTHER:TOTE TANK

PALLETCUBIC YARD BOX

DRUM SIZE:

BULK LIQUID

GALLONS/SHIPMENT: GAL.0 Min -0 Max

ESTIMATED SHIPMENT FREQUENCY OTHERYEARLYQUARTERLYMONTHLYWEEKLYONE TIME

TONS/YARDS/SHIPMENT:

SHIPMENT UOM: TON YARD

BULK SOLID

140.00 Min - 800.00 Max

I. SPECIAL REQUEST

COMMENTS OR REQUESTS:

GENERATOR'S CERTIFICATIONI hereby certify that all information submitted in this and attached documents is correct to the best of my knowledge. I also certify that any samplessubmitted are representative of the actual waste. If Clean Harbors discovers a discrepancy during the approval process, Generator grantsClean Harbors the authority to amend the profile, as Clean Harbors deems necessary, to reflect the discrepancy.

AUTHORIZED SIGNATURE NAME (PRINT) TITLE

3/12/2010

DATE

This waste profile has been submitted using Clean Harbors’ electronic signature system.

[email protected]

Santa Susana Field Laboratory The Boeing Company

CTL-V_Lower_Loop_Waste_Certification_Rev_1.doc November 18, 2009 Page 1 of 3

CTL-V Lower Loop, Area I. Waste Certification.

This data package provides the field survey results of the material comprising the CTL-V Lower Loop prior to demolition. This survey complies with Boeing procedure RS-000121. The surveys of excavated road bed material and gravel were performed at the same locations where chemical characterization has been performed. Instrument measurements were made for beta/gamma total surface contamination (Ludlum 3 plus Ludlum 44-9 GM probe) and gamma exposure rate (Bicron microrem meter). Wipes were taken for removable alpha/beta contamination and counted in a low-background Tennelec laboratory alpha/beta counter or by a Ludlum 2224 counter with a Ludlum 43-89 probe. Instrument minimum detectable activity (MDA) for total beta/gamma contamination measurements are < 5,000 dpm/100 cm2 (44-9 probe). Removable contamination MDAs are ~11 dpm/100 cm2 alpha and ~21 dpm/100 cm2 beta. Removable contamination MDAs for the Ludlum 2224 counter plus Ludlum 43-89 probe are 61 dpm/100 cm2 alpha and 508 dpm/100 cm2 beta. The Bicron MDA is ~4 μR/hr. Survey results are provided in Appendix 1. Conclusions Results of the field measurements of the material were all indistinguishable from background. The dose from the resulting solid debris is therefore zero mrem per year. If it is conservatively assumed that the debris is contaminated at the MDA levels, then the effective dose would be less than 1 mrem per year2,3. The waste generated following demolition at this location is certified to be “radiologically” acceptable for off-site disposal and/or recycling. There are no radiological controls or restrictions imposed on future disposition or use of this debris. This waste meets the requirements of disposal facility permits4,5 and complies with the California Health & Safety Code6.

1 Boeing, “Methods and Procedures for Radiological Monitoring.” RS-00012, Revision B, August 6, 2006. 2 ANSI N13.12-1999. “Surface and Volume Radioactivity Standards for Clearance.” American National Standards Institute/Health Physics Society. 1999. The most limiting beta/gamma screening value is 6,000 dpm/100 cm2 corresponding to a dose of 1 mrem per year. 3 NUREG-1640, “Radiological Assessments for Clearance of Materials from Nuclear Facilities.” Nuclear Regulatory Commission. June 2003. The most restrictive beta/gamma dose conversion from Table 2.1 is 0.16 μrem/y per dpm/100 cm2. This corresponds to 0.8 mrem/y per 5,000 dpm/100 cm2. http://www.nrc.gov/reading-rm/doc-collections/nuregs/staff/sr1640/ 4 This waste is exempt from regulation and licensing or is expressly authorized for disposal under the Radiation Control Law (Division 104, Part 9, Chapter 8 of the California Health & Safety Code). 5 This waste is not prohibited from disposal by any government agency with jurisdictional authority over this waste.



The Governor’s Executive Order D-62-02 (September 2002) prohibits the “disposal of decommissioned materials to Class 3 landfills or unclassified management units.” The subject debris is not decommissioned material, and has not originated from a radiological facility. The surveys in this certification have therefore been conducted as a best management practice that also comply with the requirements of D-62-02. Verification surveys and/or approval by the California Department of Public Health (CDPH) Radiologic Health Branch (RHB) are not required for the off-site disposal of decommissioned material or of the subject material7.

Phil Rutherford Manager, Health, Safety & Radiation Services

6 Division 104, Part 9, Chapter 5, Article 1, Section 114715, “No person shall bury, throw away, or in any manner dispose of radioactive wastes within the state except in a manner and at locations as will result in no significant radioactive contamination of the environment.” For the purposes of this requirement, “significant” is defined in Section 114710 as amounts of radioactive materials that are likely to expose persons to ionizing radiation greater than the guide levels published by the Federal Radiation Council (FRC). The FRC no longer exists, but the applicable guide level last published by the FRC was 500 mrem per year to a member of the public. Because the regulatory dose limit to members of the public has since been lowered to 100 mrem per year, CDPH/RHB conservatively utilizes the lower dose for purposes of defining “significant” radioactive contamination in this Article of the California Health and Safety Code. http://www.leginfo.ca.gov/cgi-bin/displaycode?section=hsc&group=114001-115000&file=114705-114780 7 The California Department of Public Health (CDPH) Radiologic Health Branch (RHB) has stated in a November 9, 2007 email to Phil Rutherford (Boeing) … “The Governor's Executive Order D-62-02, does not specifically require the Department of Health Services (now the Department of Public Health) to perform verification sampling of decommissioned material or to provide approval for disposal of specific decommissioned material shipped offsite (e.g., to Class I or II landfills). The California DPH has not imposed a requirement that Boeing or the Department of Energy (DOE) seek DPH verification sampling or approval of all decommissioned material destined for Class I or II landfills in compliance with the Governor's Executive Order.”



Appendix 1

Field Survey Results

FACILITY: SSFL, Area I, POD 7LOCATION: CTL5 Lower Loop

SAMPLE DATE DATE PURPOSE: Release Survey UNITS dpm/100 cm2 α dpm/100 cm2 β β cpm γ (μrem/hr)

NUMBER SAMPLED ANALYZED DESCRIPTION LIMIT 1000 dpm 1000 dpm < MDA N/A

1-11 11/18/2009 11/18/2009 Road Bed and Gravel (see attached resuts) < 1000 < 1000 -- --

N/A 11/18/2009 N/A Road Bed and Gravel (see attached map) -- -- 50-110 5-10

COMMENTS: MDA = minimum detectable activity INSTRUMENT Ludlum 32 Bicron3

1Ludlum 2224 (MDA = 61 dpm/100 cm2 α and 508 dpm/100 cm2 β) IDENTIFICATION EX054113 EX041001 2Ludlum 3 with 44-9 GM probe (MDA < 100 cpm over lowest background) CALIBRATION DUE 8/26/2010 8/26/2010 2Bicron micro rem meter (MDA = 4 μrem/hr) BACKGROUND 0.6 cpm 323 cpm 40-150 cpm 4-12 μrem/hr

EFFICIENCY 15.4% 19.1% 10.00% N/ASAMPLED BY: R. Ford DATE:

COUNT TIME 1 min. 1 min. Scan ScanREVIEWED BY: Phil Rutherford DATE:

Page 1 of 5FORM 732-A REV 10-2005

11/18/2009

RADIATION SURVEY REPORT

Ludlum 2224 & 43-891

ZO257835

8/26/2010

11/18/2009

Sample Location CTL5LWR_RB_S03

Page 3 of 5

Sample Location CTL5LWR_RB_S05 Location S06 in background

Page 4 of 5

Date Smear # α β α β α β α Eff β Eff α dpm α MDA β dpm β mda11/18/2009 1 1 308 0.6 322.6 0.4 -14.6 0.154 0.191 3 61 0 50811/18/2009 2 1 354 0.6 322.6 0.4 31.4 0.154 0.191 3 61 165 50811/18/2009 3 0 332 0.6 322.6 -0.6 9.4 0.154 0.191 0 61 49 50811/18/2009 4 1 337 0.6 322.6 0.4 14.4 0.154 0.191 3 61 75 50811/18/2009 5 1 327 0.6 322.6 0.4 4.4 0.154 0.191 3 61 23 50811/18/2009 6 0 305 0.6 322.6 -0.6 -17.6 0.154 0.191 0 61 0 50811/18/2009 7 3 306 0.6 322.6 2.4 -16.6 0.154 0.191 16 61 0 50811/18/2009 8 0 314 0.6 322.6 -0.6 -8.6 0.154 0.191 0 61 0 50811/18/2009 9 1 310 0.6 322.6 0.4 -12.6 0.154 0.191 3 61 0 50811/18/2009 10 0 311 0.6 322.6 -0.6 -11.6 0.154 0.191 0 61 0 50811/18/2009 11 0 325 0.6 322.6 -0.6 2.4 0.154 0.191 0 61 13 508

Page 5 of 5

Calculated ResultsGross cpm Bkg cpm (Daily) Net cpm Efficiency

Clean Harbors Profile No. CH425704B - DTSC · 2010. 4. 23. · Boeing Company The - SSFL 5800...

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