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    CHPE 5612: Chemical

    Process SafetyChapter 10

    by

    Dr. Omar Houache

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    Hazards are everywhere

    Unfortunately, a hazard is not always identified until anaccident occurs. It is essential to identify the hazards and

    reduce the risk well in advance of an accident.

    For each process in a chemical plant the following questions

    must be asked:

    1. What are the hazards? (Hazard Identification)

    2. What can go wrong and how?

    3. What are the chances?

    4. What are the consequences?

    Risk Assessment

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    Definitions

    HAZARD: A hazard introduces the potential for anunsafe condition, possibly leading to an accident.

    RISKis the probability or likelihood of a Hazard

    resulting in an ACCIDENT

    INCIDENTis an undesired circumstance that produces

    the potential for an ACCIDENT

    ACCIDENTis an undesired circumstance that results in

    ill health, damage to the environment, or damage to

    property

    HAZARD INCIDENT ACCIDENT

    (includes near misses)

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    Definitions

    Risk assessment is sometimes called hazard analysis. Hazard identification and risk assessment are sometimes

    combined into a general category called hazard evaluation.

    A risk assessment procedure that determines probabilities is

    frequently called probabilistic risk assessment (PRA),whereas a procedure that determines probability and

    consequences is called quantitative risk analysis (QRA).

    Figure 10-1 illustrates the normal procedure for using

    hazards identification and risk assessment.

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    HAZID Approach

    What can go wrong?

    What incidents or scenarios could

    arise as a result of things going

    wrong?

    What could cause or could

    contribute to these incidents?

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    HAZID Approach

    The HAZID approach can be used

    in the first stages of the life cycle

    phase of a project

    Prior to design phase, little

    information will be available andthe HAZID approach will need to

    be undertaken on flow diagrams

    Assumptionswill need to be

    transparentand documented

    Concept

    Design

    Commission

    Production

    Decommission

    Disposal

    Construction

    Life Cycle Phases of a Project

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    Conducting the HAZID Consider the Past, Present and Future

    Existing

    conditions

    Future

    conditions

    Historical

    conditions

    What has gone wrong in the past?

    What could go wrong currently?

    What could go wrong due to change?

    Root CauseHistorical RecordsProcess ExperienceNear Misses

    Identified

    HazardsHAZID WorkshopHAZOP StudyScenario DefinitionsChecklists

    Change ManagementWhat-If JudgementPrediction

    unforeseeable

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    Conducting the HAZID

    It is tempting to disregard Non-Credible Scenarios BUT

    Non-credible scenarios have happened to others

    Worst cases are important to emergency planning

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    Issues for consideration

    Equipment can be off-line

    Safety devices can be disabled or fail to operate

    Several tasks may be concurrent

    Procedures are not always followed People are not always available

    How we act is not always how we plan to act

    Things can take twice as long as planned

    Abnormal conditions can cross section limits

    Power failure

    Conducting the HAZID

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    Conducting the HAZIDHAZID Process

    Existing studies

    Define boundary System description

    Divide system into sections

    Systematically record all hazards

    Independent check

    Revisit after risk assessmentHazard Register

    Selected methods

    asset or equipment failure

    external events

    process operational deviations

    hazards associated with all materials

    human activities which could contribute to incidents

    interactions with other sections of the facility

    Analyse each section

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    Recording Detail The level of detail is important for:

    - Clarity

    - Transparency and

    - Traceability

    A system (hazard register) is required for keeping track of the process

    for each analysed section of the facility

    The items to be recorded are:

    - Study team

    - System being evaluated- Identified hazard scenario

    - Consequences of the hazard being realised

    - Controls in place to prevent hazard being realised and their

    adequacy

    - Opportunity for additional controls

    Conducting the HAZID

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    HAZID Techniques - Overview

    Checklists - questions to assist in hazard identification

    Brainstorming - whatever anyone can think of

    What If Analysis - possible outcomes of change

    HAZOP (Hazard and operability study )- identifiesprocess plant type incidents

    FMEA/FMECA (Failure modes and effects analysis/

    Failure modes and effects criticality analysis )-

    equipment failure causes

    Task Analysismaintenance activities, procedures

    Fault Tree Analysis - combinations of failures

    Increasing

    eff

    ortrequired

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    Checklists

    Simple set of prompts or checklist questions to assist inhazard identification

    Can be used in combination with any other techniques, such

    as What If

    Can be developed progressively to capture corporatelearning of organisation

    Particularly useful in early analysis of change within

    projects

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    Initiating Events General Causes Initiating Causes

    Overfills And

    Spills

    Improper Operation Operating Error

    Inadequate / Incorrect Procedure

    Failure To Follow Procedure

    Outside Operating Envelope

    Inadequate Training

    Vessel/Tanker

    Shell Failure

    Corrosion Wet H2S Cracking

    General Process

    Cooling Water

    Steam / CondensateService Water

    Mechanical Impact Missiles

    Crane

    Vehicles

    Checklists

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    Advantages Highly valuable as a cross check review tool following application of other

    techniques

    Useful as a shop floor tool to review continued compliance with SMS

    Disadvantages

    Tends to stifle creative thinking

    Used alone introduces the potential of limiting study to already known

    hazards - no new hazard types are identified

    Checklists on their own will rarely be able to satisfy regulatory requirements

    Checklists

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    Brainstorm

    Team based exercise Based on the principle that several experts with different

    backgrounds can interact and identify more problems

    when working together

    Can be applied with many other techniques to vary thebalance between free flowing thought and structure

    Can be effective at identifying obscure hazards which

    other techniques may miss

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    Advantages Useful starting point for many HAZID techniques to focus a groups

    ideas, especially at the projects concept phase

    Facilitates active participation and input

    Allows employees experience to surface readily

    Enables thinking outside the square

    Very useful at early stages of a project or study

    Disadvantages

    Less rigorous and systematic than other techniques High risk of missing hazards unless combined with other tools

    Caution required to avoid overlooking the detail

    Relies on experience and competency of facilitator

    Brainstorm

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    What If

    What if analysis is an early method of identifying hazards Brainstorming approach that uses broad, loosely structured

    questioning to postulate potential upsets that may result in

    an incident or system performance problems

    It can be used for almost every type of analysis situation,especially those dominated by relatively simple failure

    scenarios

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    Normally the study leader will develop a list of questions to consider at thestudy session

    This list needs to be developed before the study session

    Further questions may be considered during the session

    Checklists may be used to minimise the likelihood of omitting some areas

    What If

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    Example of a What If report for a single assessed item

    What If

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    Advantages Useful for hazard identification early in the process, such as when only PFDs

    are available

    What If studies may also be more beneficial than HAZOPs where the project

    being examined is not a typical steady state process, though HAZOP

    methodologies do exist for batch and sequence processes

    Disadvantages

    Inability to identify pre-release conditions

    Apparent lack of rigour

    Checklists are used extensively which can provide tunnel vision, thereby

    running the risk of overlooking possible initiating events

    What If

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    HAZOP

    A HAZOP study is a widely used method for theidentification of hazards

    A HAZOP is a rigorous and highly structured hazard

    identification tool

    It is normally applied when PFDs and P&IDs are available The plant/process under investigation is split into study

    nodes and lines and equipment are reviewed on a node by

    node basis

    Guideword and deviation lists are applied to processparameters to develop possible deviations from the design

    intent

    HAZOP results in a very systematic assessment of hazards

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    Example of a HAZOP report for a single assessed item

    HAZOP

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    Advantages Will identify hazards, and events leading to an accident, release or

    other undesired event

    Systematic and rigorous process

    The systematic approach goes some way to ensuring all hazards are

    considered

    Disadvantages

    HAZOPs are most effective when conducted using P&IDs, though they

    can be done with PFDs Requires significant resource commitment

    HAZOPs are time consuming

    The HAZOP process is quite monotonous and maintaining participant

    interest can be a challenge

    HAZOP

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    FMEA/FMECA

    Objective is to systematically address all possible failuremodes and the associated effects on a technical system

    The underlying equipment and components of the system

    are analysed in order to eliminate, mitigate or reduce the

    failure or the failure effect Best suited for mechanical and electrical hardware systems

    evaluations

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    Example of an FMEA/FMCEA report for a single assessed item

    PotentialFailureMode

    PotentialEffects ofFailure

    PotentialCausesofFailure

    Comments Recommendations

    Openindicatorswitch failed

    Wrongindication ofvalve back tocontrol systemcausingpossibleincorrectcontrolleraction to betaken

    Wear andtear

    Commissioningand testproceduresmust ensurethat all diverterequipmentindicators arecorrectly wiredto the divertercontrol system

    The integrity of theposition indicators forthe Diverter systemequipment is critical tothe logic of the controlsystem.

    It is recommended thatthe position indicatorsare discretely functiontested prior to

    commencement of eachprogram

    FMEA/FMECA

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    Advantages Generally applied to solve a specific problem or set of problems

    FMEA/FMECA was primarily considered to be a tool or process toassist in designing a technical system to a higher level of reliability

    Designed correction or mitigation techniques can be implemented so

    that failure possibilities can be eliminated or minimized

    Disadvantages

    It is very time consuming and needs specialist skills from differentbackgrounds to obtain maximum effect

    Very hard to assess operational risks within an FMEA/FMECA (likethey can be within a HAZOP or What if study)

    FMEA/FMECA

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    Task Analysis

    Technique which analyses human interactions with thetasks they perform, the tools they use and the plant, process

    or work environment

    Approach breaks down a task into individual steps and

    analyses each step for the presence of potential hazards Used widely to manage known injury related tasks in

    workplace

    Excellent tool for hazard identification related to human

    tasks

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    Disadvantages

    Does not address plant process deviations which are not

    related to human interaction

    Caution

    Relies on multi-disciplined input with specific input of

    person who normally carries out the task

    Often assumed to be the only tool of hazard identification orrisk assessment, as it is used generally at the shop floor

    Task Analysis

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    Fault Tree Analysis

    Graphical technique approach Provides a systematic description of the combinations of

    possible occurrences in a system which can result in an

    identified undesirable outcome (top event)

    This method combines hardware failures and humanfailures

    Uses logic gates to define modes of interaction (ANDs/

    ORs)

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    AND OR

    PSV does not

    relieve

    Process

    pressurerises

    Control fails

    high

    PSV too

    small

    Set point too

    high

    PSV stuck

    closed

    Fouling inletor outlet

    Pressure rises

    Process

    vessel overpressured

    AND

    Fault Tree Analysis

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    Advantages Quantitative - defines probabilities to each event which can be used to

    calculate the probability of the top event

    Easy to read and understand hazard profile

    Easily expanded to bow tie diagram by addition of event tree

    Disadvantages

    Need to have identified the top event first

    More difficult than other techniques to document

    Fault trees can become rather complex Time consuming approach

    Quantitative data needed to perform properly

    Fault Tree Analysis

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    Safety considerations of the facility layout will include the

    provision of:

    Separation between flammable hydrocarbons and ignition

    sources.

    Separation between hydrocarbon handling areas and

    emergency services, main safety equipment,accommodation, temporary safe refuge areas, means of

    evacuation and escape, muster points and control centers.

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    HAZOPHazard and Operability Study

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    HAZOPis a formal and systematic procedure forevaluating a process

    - It is time consuming and expensive

    HAZOP is basically for safety

    - Hazards are the main concern

    - Operability problems degrade plant performance

    (product quality, production rate, profit), so they are

    considered as well

    Considerable engineering insightis required - engineers

    working independently could (would) develop different

    results

    HAZOP - Hazard and operability

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    HAZOP keeps all team members

    focused on the same topic andenables them to work as a team

    1 + 1 + 1 = 5

    NODE: Concentrate on one location in the process

    PARAMETER: Consider each process variable individually(F, T, L, P, composition, operator action, corrosion, etc.)

    GUIDE WORD: Pose a series of standard questions about deviations from

    normal conditions. We assume that we know a safe normal operation.

    HAZOP - Hazard and operability

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    NODE: Pipe after pump and splitter

    PARAMETER*: Flow rate

    GUIDE WORD: Less (less than normal value)

    DEVIATION: less flow than normal

    CAUSE: of deviation, can be more than one

    CONSEQUENCE: of the deviation/cause

    ACTION: initial idea for correction/

    prevention/mitigation

    All group

    members focus

    on the sameissue

    simultaneously

    * For an expanded list of parameters and associated guide words, see Wells (1996)

    HAZOP - Hazard and operability

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    Guide Word Explanation

    NO or NOT or NONE Negation of the design intent

    MORE

    LESS

    Quantitative increase

    Quantitative decrease

    AS WELL AS

    PART OF

    Qualitative increase e.g.,

    extra activity occursQualitative decrease

    REVERSE Opposite of the intention

    OTHER THAN Substitution

    SOONER/LATER THAN Activity occurring a time other than

    intended

    TYPICAL GUIDEWORDS USED FOR PROCESSES

    Selected Parameters with Applicable Guide Words (See Wells, 1996, p. 95-6)

    Flow (no, more, less, reverse)

    Temperature (higher, lower)

    Pressure (higher, lower)

    Level (none, higher, lower)

    Composition (none, more, less, as well as, other than)

    Action (sooner, later, insufficient, longer, shorter)

    HAZOP - Hazard and operability

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    fuel

    air

    feed

    product

    When do we use

    a fired heater in

    a process plant?

    Fired heaters are used in process plants and have manypotential hazards. Lets perform a HAZOP study!

    HAZOP - Hazard and operability

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    Class Example: Fired Heater1. Discuss the first entry in the HAZOP form

    2. Select another guide word for the parameter

    3. Select a different parameter for the same node

    4. Select a different node/parameter/guide word

    fuel

    air

    feed

    product

    HAZOP - Hazard and operability

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    HAZOP FORM

    Unit: Fired Heater

    Node: Feed pipe Parameter: Flow(after feed valve, before split)

    Location (line or vessel) Process variables

    or procedure (start up)

    Guide Word Deviation Cause Consequence Action

    Select from

    official list ofwords to ensure

    systematicconsideration ofpossibilities

    applying guide

    word to thisparameter

    process

    engineering

    process

    engineering

    preliminary result

    which should bereconsidered when

    time is available

    no no feed flow 1. feed pump stops damage to pipes inradiant section,

    possible pipefailure

    1. automaticstartup of backup

    pump on low feedpressure

    fuel

    air

    feed

    product

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    2. feed valve

    closed 2. fail open valve

    3. feed flow meter

    indicates false high

    flow (controllercloses valve)

    3. redundant flow

    meters

    4. pipe blockage 4. a) test flow

    before startup

    4. b) place filter in

    pipe

    5. Catastrophicfailure of pipe

    5.a) damage topipes in radiant

    section

    b) pollution and

    hazard for oil

    release to plant

    environment

    Install remotelyactivated block

    valves at feed

    tanks to allow

    operators to stop

    flow

    For 1-5, SIS to

    stop fuel flow on

    low feed flow,

    using separate feed

    flow sensor

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    HAZOP - PROCESS APPLICATIONS

    Thorough review at or near the completion of a new process design

    - Equipment and operating details known

    - Can uncover major process changes

    Review of existing processes (periodic update)

    - Safe operation for years does not indicate that no Hazards exist

    Review of changes to an existing process that had been HAZOPed -

    Important part of Change Management- No consistency on what type of changes require formal HAZOP

    HAZOP - Hazard and operability

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    MANAGING THE HAZOP PROCESS The HAZOP group should contain people with different

    skills and knowledge

    - operations, design, equipment, maintenance, quality

    control, ..- do not forget operators!!!

    The team should understand the plant well

    Documents should be prepared and distributed before the

    meeting

    The HAZOP leader should be expert in the HAZOP process

    Results must be recorded and retained

    HAZOP - Hazard and operability

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    Risk management

    Risk managementis the identification, assessment, and

    prioritization of risksfollowed by coordinated and

    economical application of resources to minimize, monitor,

    and controlthe probabilityand/or impactof unfortunate

    events.

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    Risk

    A Riskis the amount of harm that can be expected to occur

    during a given time period due to specific harm event (e.g.,

    an accident).

    Risk is a product of the likelihood of a hazard occurring and

    the consequences that would follow:

    RISK = HAZARD X CONSEQUENCE

    In practice, the amount of risk is usually categorized into a

    small number of levels because neither the probability nor

    harm severity can typically be estimated with accuracy and

    precision.

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    Risk Matrix

    A Risk Matrixis a matrix that is used during Risk

    Assessmentto define the various levels of risk as the

    productof the harm probability categories and harm

    severity categories.

    This is a simple mechanism to increase visibility of risks and

    assist management decision making.

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    Risk Matrix

    Although many standard risk matrices exist in different

    contexts individual projects and organizations may need to

    create their own or tailor an existing risk matrix.

    E.g., the harm severity can be categorized as:

    Catastrophic- Multiple Deaths Critical- One Death or Multiple Severe Injuries

    Marginal- One Severe Injury or Multiple Minor Injuries

    Negligible - One Minor Injury

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    The resulting Risk Matrix could be :

    Negligible Marginal Critical Catastrophic

    Certain High High Extreme Extreme

    Likely Moderate High High Extreme

    Possible Low Moderate High Extreme

    Unlikely Low Low Moderate Extreme

    Rare Low Low Moderate High

    Risk Matrix

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    The resulting Risk Matrix could be :

    Negligible Marginal Critical Catastrophic

    Certain Stubbing Toe

    LikelyMinor Car

    Accident

    PossibleMajor Car

    Accident

    Unlikely Aircraft Crash

    Rare Major Tsunami

    Risk Matrix