Chemistry for Changing Times 12 th Edition Hill and Kolb Chapter 10 Polymers: Giants among Molecules...

Chemistry for Changing Times12th Edition

Hill and Kolb

Chapter 10Polymers: Giants among Molecules

John SingerJackson Community College, Jackson, MI

© 2010 Pearson Prentice Hall, Inc.


10/2

Polymerization

Polymers are composed of macromolecules. Many of them have formula weights in the thousands.

The word polymer comes from the Greek. Poly means many. Mer comes from meros meaning parts.

Polymers consist of many smaller molecules called monomers that are connected to form the larger macromolecule.


10/3

Natural Polymers

Many natural substances exist as polymers including:

• Starch• Cotton (cellulose)• Wood (cellulose)• Proteins


10/4

Celluloid

Celluloid is one of the earliest synthetic substances that is a polymer. It is produced when natural cellulose is treated with nitric acid. Cellulose nitrate was used for billiard balls, men’s fashion collars, and movie film.

The first truly synthetic polymers were phenol-formaldehyde resins.


10/5

Polyethylene

Perhaps the most common synthetic polymer is the plastic, polyethylene.


10/6

Polyethylene


10/7

Polyethylene

High density polyethylene (HDPE) exists as mostly linear molecules that pack closely together. It is used for milk jugs, bottle caps, toys, etc.

Low density polyethylene (LDPE) is a more highly branched form of polyethylene. It is used to make plastic bags, plastic films, electric wire insulation, etc.


10/8

Polyethylene

These two bottles, both made of polyethylene, were heated in the same oven for the same length of time. Which is made of HDPE and which is made of LDPE?


10/9

Thermoplastic and Thermosetting Polymers

Thermoplastic polymers will soften upon heating. Polyethylene is one such polymer.

Thermosetting polymers were heated to harden when they were formed. They will not soften upon heating, but will discolor and decompose.


10/10

Addition Polymers

Addition polymerization occurs when monomers add to one another in such a way that the resulting molecule contains all atoms that are present in the monomers. Addition polymers are all derivates of polyethylene.


10/11

Addition Polymers

Polystyrene


10/12

Addition Polymers

Vinyl Polymers


10/13

Addition Polymers

Polytetrafluoroethylene (PTFE)


10/14

Addition Polymers


10/15

Molding Plastics

Plastic materials can be made to flow under heat and pressure.

Compression molding: Heat and pressure are applied directly to the polymer powder in the mold cavity.

Injection molding: The plastic is melted and forced by a plunger into cold molds to set.


10/16

Molding Plastics

Extrusion molding: Process during which a molten polymer is extruded through a die in continuous form to be cut into lengths or coiled.

Blow-molding: Process during which a “bubble” of molten polymer is blown up like a balloon inside a hollow mold. This is how bottles are formed.


10/17

Rubber and Other ElastomersElastomers are polymers that will elongate when subjected to a tensile force. They will return to the original shape when the force is removed.

Rubber is an elastomer. Natural rubber is composed of isoprene units. Isoprene is polymerized into polyisoprene (rubber).


10/18

Rubber and Other Elastomers

Natural rubber is soft and tacky when hot. Reacting it with sulfur cross-links the polyisoprene and makes the rubber harder. This process is known as vulcanization and was discovered by Charles Goodyear.


10/19

Synthetic Rubber

Synthetic rubber is similar to polyisoprene. One example is polybutadiene.


10/20

Synthetic Rubber

Neoprene is very similar to polybutadiene, but contains chlorine in the place of the methyl group. It is more resistant to solvents like oil and gasoline.


10/21

Synthetic RubberAnother synthetic rubber is styrene-butadiene rubber (SBR). SBR is a copolymer of styrene (25%) and butadiene (75%). It is tougher and more resistant to oxidation than natural rubber, but its mechanical properties are less satisfactory.


10/22

Polymers in Paints

Elastomers are often used as binders in paints. Paints made with elastomeric binders are more resistant to cracking. Latex paints are such a product. These paints use water as a solvent and are more “environmentally friendly” than oil-based paints.


10/23

Condensation Polymers

In condensation polymerization, small molecules such as water, alcohols, ammonia, or HCl are released as by-products.


10/24


Nylon is a polyamide. Most nylon is manufactured as fibers.


10/25

Condensation PolymersPolyesters are condensation polymers made from molecules containing alcohol and carboxylic acid functional groups. The linkage is an ester.


10/26


Phenol-formaldehyde resin was the first synthetic polymer. It was known as Bakelite in honor of its discoverer, Leo Baekeland. Leo Baekeland received a patent in 1909 for this polymer.


10/27


Polycarbonates are tough, clear polymers used in protective helmets, safety glasses, and dental crowns. Lexan is one such polycarbonate.


10/28


Polyurethanes are similar to nylon. They may be elastomers or tough and rigid, depending on the monomers used. Polyurethanes are used in foam rubber, skate wheels, and tough furniture finishes.


10/29


Epoxy resins are often sold as two-part liquids. They make durable, clear coatings and are an excellent adhesive. They are very strong when cross-linked.


10/30

Composite Materials

Composite materials are composed of high-strength fibers (i.e., fiberglass, graphite, or ceramic fibers) held in a polymeric matrix. Examples of composite materials include: boat hulls, tennis rackets, automobile panels, fishing rods, etc.


10/31

Silicones

Silicones are polymers that contain silicon rather than carbon. An example is polysiloxane.

Silicone polymers take many forms depending on their structure and degree of cross-linking. They can be in the form of liquid oils, gels, synthetic rubber elastomers, etc.


10/32

Properties of Polymers

Polymers have very high molecular weights. Since the strength of intermolecular forces increases with molecular weight, polymeric materials exhibit very strong intermolecular forces. For these reasons, polymeric materials exist as strong fibers and polymers form viscous solutions.


10/33

Properties of PolymersThe molecules of crystalline polymers line up in neat rows forming fibers of great strength. Crystalline polymers tend to be very rigid.Amorphous polymers, on the other hand, have molecules that are randomly tangled. Amorphous polymers tend to be soft and rubbery.


10/34


The glass transition temperature (Tg) is the temperature above which the polymer is tough and rubbery, and below which it is like glass―hard, brittle, and stiff.


10/35


Some synthetic polymers can be converted to fibers. Many can exhibit properties that are superior to natural fibers. The majority of fibers and fabrics used in the United States are synthetic.


10/36

Disposal of Plastics

Most plastics do not decompose readily in the natural environment.

Unwanted plastic waste can be dealt with by disposal in landfills, incineration, biodegradation, and recycling.


10/37


Landfills

Plastics make up 11% by mass of solid waste and 20% by volume. More than half of all solid waste ends up in landfills. Landfill space is becoming increasingly difficult to obtain.


10/38


Incineration

Many plastic materials have significant fuel value and incineration of solid waste, along with using the heat energy to generate electricity, is attractive. However, the combustion of plastics and rubbers is not without problems. Many of these materials exhibit toxic gases when combusted. PVC plastic, for instance, releases HCl gas when burned.


10/39


Degradable Plastics

About half of our waste plastic comes from packaging. Expect to see more biodegradable and photodegradable plastics used for packaging in the near future.


10/40


Recycling

Over the long term, recycling may be the best way of dealing with waste plastics. Recycled plastics can be separated into the various types, chopped into flakes, melted, and remolded or spun into fibers.


10/41

Plastics and Fire Hazards

Many people are injured each year due to accidental ignition of plastics. Federal regulations require that children’s sleepwear be made of flame retardant materials.

Some plastics release toxic gases during combustion. Firefighters must protect themselves from toxic gases.


10/42

Plasticizers and Pollution

Certain plastics, such as vinyl polymers, are stiff and brittle; plasticizers are used to make the materials more flexible. Many of these plasticizers have low volatility. Eventually these materials can become stiff and brittle as the plasticizers vaporize.


10/43


Early plasticizers were polychlorinated biphenyls (PCB).


10/44


More recent plasticizers are less toxic phthalate esters.


10/45

Plastics and the Future

It is difficult to imagine the world without synthetic polymers and plastics. Many are made from petroleum or natural gas. Much research is being conducted on developing synthetic polymers from renewable resources. These materials represent both hope and challenge for our future.

Chemistry for Changing Times 12 th Edition Hill and Kolb Chapter 10 Polymers: Giants among Molecules...

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Transcript of Chemistry for Changing Times 12 th Edition Hill and Kolb Chapter 10 Polymers: Giants among Molecules...