ChemInform Abstract: Triallylmanganate-Mediated Cyclization of Diyne, Enyne, and Diene. An...

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1998 ring closure reactions ring closure reactions O 0130 21 - 046 Triallylmanganate-Mediated Cyclization of Diyne, Enyne, and Diene. An Unprecedented Bicyclization Reaction into Bicyclo[5.3.0]decane and Bicyclo[4.3.0]nonane Skeletons. — Treatment of diynes with triallylmanganate, generated from MnCl 2 and allylmagnesium chloride at 0 ◦ C, provides bicyclized products containing a seven-membered ring. In these reactions the terminal substituents of the diyne effect the outcome of the cyclization products. Corresponding reactions of enynes and dienes lead only to cyclized products [mechanisms]. — (TANG, J.; SHINOKUBO, H.; OSHIMA, K.; Organometallics 17 (1998) 3, 290-292; Dep. Mater. Chem., Grad. Sch. Eng., Kyoto Univ., Sakyo, Kyoto 606, Japan; EN) 1

Transcript of ChemInform Abstract: Triallylmanganate-Mediated Cyclization of Diyne, Enyne, and Diene. An...

Page 1: ChemInform Abstract: Triallylmanganate-Mediated Cyclization of Diyne, Enyne, and Diene. An Unprecedented Bicyclization Reaction into Bicyclo[5.3.0]decane and Bicyclo[4.3.0]nonane Skeletons.

1998 ring closure reactions

ring closure reactionsO 0130

21 - 046Triallylmanganate-Mediated Cyclization of Diyne, Enyne, and Diene.An Unprecedented Bicyclization Reaction into Bicyclo[5.3.0]decaneand Bicyclo[4.3.0]nonane Skeletons. — Treatment of diynes withtriallylmanganate, generated from MnCl2 and allylmagnesium chloride at0 ◦C, provides bicyclized products containing a seven-membered ring. In thesereactions the terminal substituents of the diyne effect the outcome of thecyclization products. Corresponding reactions of enynes and dienes lead only tocyclized products [mechanisms]. — (TANG, J.; SHINOKUBO, H.; OSHIMA,K.; Organometallics 17 (1998) 3, 290-292; Dep. Mater. Chem., Grad. Sch.Eng., Kyoto Univ., Sakyo, Kyoto 606, Japan; EN)

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Ring closing enyne metathesis: A powerful tool for the synthesis

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New Synthetic Methodologies Using Enyne Olefin Metathesis ...

Ouverture de Bicyclo, la Maison du vélo!

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Alkynyl-functionalised and linked bicyclo[1.1.1]pentanes of ...1 Electronic Supplementary Information Alkynyl-functionalised and linked bicyclo[1.1.1]pentanes of group 14 Timo Augenstein,

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In silico analysis of compounds characterized from ethanolic ...eprints.covenantuniversity.edu.ng/10478/1/20420-74354-2...1 25.637 1.16 Bicyclo[3.1.1]heptane, 2,6,6-trimethyl-138.24992

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Diene, Enyne, and Diyne Metathesis in Natural Product Synthesis

Diene, Enyne, and Diyne Metathesis in Natural Product Synthesis

Enantioselective Synthesis of Bicyclo[1.1.0]butanesccc.chem.pitt.edu/wipf/Topics/Yongzhao.pdf · 2011. 12. 29. · 1. Background . 2. Synthesis of Bicyclo[1.1.0]butane 3. Enantioselective

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