ChemInform Abstract: Synthesis of ortho-Alkoxy-aryl Carboxamides via Palladium-Catalyzed...

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ChemInform 2009, 40, issue 37 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Carbonylation O 0305 Synthesis of ortho-Alkoxy-aryl Carboxamides via Palladium-Catalyzed Amino- carbonylation. — The aminocarbonylation of aryl iodides such as (I), (VI) or (IX) us- ing an in situ generated palladium(0) catalyst is described. The preferential formation of carboxamides or ketocarboxamides depending on the CO pressure is observed in the case of (I). — (TAKACS, A.; ABREU, A. R.; PEIXOTO, A. F.; PEREIRA, M.; KOLLAR*, L.; Synth. Commun. 39 (2009) 9, 1534-1548; Dep. Inorg. Chem., Janus Pannonius Univ., H-7624 Pecs, Hung.; Eng.) — M. Bohle 37- 041

Transcript of ChemInform Abstract: Synthesis of ortho-Alkoxy-aryl Carboxamides via Palladium-Catalyzed...

Page 1: ChemInform Abstract: Synthesis of ortho-Alkoxy-aryl Carboxamides via Palladium-Catalyzed Aminocarbonylation.

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CarbonylationO 0305 Synthesis of ortho-Alkoxy-aryl Carboxamides via Palladium-Catalyzed Amino-

carbonylation. — The aminocarbonylation of aryl iodides such as (I), (VI) or (IX) us-ing an in situ generated palladium(0) catalyst is described. The preferential formation of carboxamides or ketocarboxamides depending on the CO pressure is observed in the case of (I). — (TAKACS, A.; ABREU, A. R.; PEIXOTO, A. F.; PEREIRA, M.; KOLLAR*, L.; Synth. Commun. 39 (2009) 9, 1534-1548; Dep. Inorg. Chem., Janus Pannonius Univ., H-7624 Pecs, Hung.; Eng.) — M. Bohle

37- 041

ChemInform 2009, 40, issue 37 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim