ChemInform Abstract: Synthesis of Optically Pure vic-Sulfanyl Amines Mediated by a Remote Sulfinyl...
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Transcript of ChemInform Abstract: Synthesis of Optically Pure vic-Sulfanyl Amines Mediated by a Remote Sulfinyl...
AminesQ 0120 DOI: 10.1002/chin.201201053
Synthesis of Optically Pure vic-Sulfanyl Amines Mediated by a Remote Sulfinyl Group. — Treatment of the sulfoxide (I) with N-phenyl and N-methoxyphenyl aldi-mines allows highly stereoselective access to syn-sulfanyl amines. The reaction with N-cyanophenyl aldimines, however, leads to syn- and/or anti-sulfanyl amines depend-ing on the electronic nature of the arylidene moiety. — (ARROYO*, Y.; SANZ-TEJEDOR, M. A.; ALONSO, I.; GARCIA-RUANO, J. L.; Org. Lett. 13 (2011) 17, 4534-4537, http://dx.doi.org/10.1021/ol201696y ; Dep. Quim. Org., Fac. Cienc., Univ. Valladolid, E-47011 Valladolid, Spain; Eng.) — Jannicke
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ChemInform 2012, 43, issue 01 © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim