ChemInform Abstract: Synthesis of Optically Pure vic-Sulfanyl Amines Mediated by a Remote Sulfinyl...

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ChemInform 2012, 43, issue 01 © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Amines Q 0120 DOI: 10.1002/chin.201201053 Synthesis of Optically Pure vic-Sulfanyl Amines Mediated by a Remote Sulfinyl Group. — Treatment of the sulfoxide (I) with N-phenyl and N-methoxyphenyl aldi- mines allows highly stereoselective access to syn-sulfanyl amines. The reaction with N-cyanophenyl aldimines, however, leads to syn- and/or anti-sulfanyl amines depend- ing on the electronic nature of the arylidene moiety. — (ARROYO*, Y.; SANZ-TEJEDOR, M. A.; ALONSO, I.; GARCIA-RUANO, J. L.; Org. Lett. 13 (2011) 17, 4534-4537, http://dx.doi.org/10.1021/ol201696y ; Dep. Quim. Org., Fac. Cienc., Univ. Valladolid, E-47011 Valladolid, Spain; Eng.) — Jannicke 01- 053

Transcript of ChemInform Abstract: Synthesis of Optically Pure vic-Sulfanyl Amines Mediated by a Remote Sulfinyl...

AminesQ 0120 DOI: 10.1002/chin.201201053

Synthesis of Optically Pure vic-Sulfanyl Amines Mediated by a Remote Sulfinyl Group. — Treatment of the sulfoxide (I) with N-phenyl and N-methoxyphenyl aldi-mines allows highly stereoselective access to syn-sulfanyl amines. The reaction with N-cyanophenyl aldimines, however, leads to syn- and/or anti-sulfanyl amines depend-ing on the electronic nature of the arylidene moiety. — (ARROYO*, Y.; SANZ-TEJEDOR, M. A.; ALONSO, I.; GARCIA-RUANO, J. L.; Org. Lett. 13 (2011) 17, 4534-4537, http://dx.doi.org/10.1021/ol201696y ; Dep. Quim. Org., Fac. Cienc., Univ. Valladolid, E-47011 Valladolid, Spain; Eng.) — Jannicke

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ChemInform 2012, 43, issue 01 © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim