ChemInform Abstract: Synthesis of Bridged Bicyclic Ethers and Fused Oxetanes from Pyran-4-ones via...

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1999 photochemistry, radiation chemistry, chemoluminescence photochemistry, radiation chemistry, chemoluminescence O 0160 33 - 064 Synthesis of Bridged Bicyclic Ethers and Fused Oxetanes from Pyran-4-ones via Tandem Solvent Trapping and Norrish Type II Cyclization. Irradiation of the pyranones (I) in the presence of methanol or ethanol leads to products of type (III) which smoothly undergo cyclization to fused oxetanes and bicyclic ethers. This process represents a simple and facile route to the latter compounds. — (FLEMING, MIKE; BASTA, REHAN; FISHER, PETER V.; MITCHELL, SCOTT; WEST, F. G.; J. Org. Chem. 64 (1999) 5, 1626-1629; Dep. Chem., Univ. Utah, Salt Lake City, UT 84112, USA; EN) 1

Transcript of ChemInform Abstract: Synthesis of Bridged Bicyclic Ethers and Fused Oxetanes from Pyran-4-ones via...

1999 photochemistry, radiation chemistry, chemoluminescence

photochemistry, radiation chemistry, chemoluminescenceO 0160

33 - 064Synthesis of Bridged Bicyclic Ethers and Fused Oxetanes fromPyran-4-ones via Tandem Solvent Trapping and Norrish Type IICyclization. — Irradiation of the pyranones (I) in the presence of methanolor ethanol leads to products of type (III) which smoothly undergo cyclization tofused oxetanes and bicyclic ethers. This process represents a simple and facileroute to the latter compounds. — (FLEMING, MIKE; BASTA, REHAN;FISHER, PETER V.; MITCHELL, SCOTT; WEST, F. G.; J. Org. Chem. 64(1999) 5, 1626-1629; Dep. Chem., Univ. Utah, Salt Lake City, UT 84112, USA;EN)

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