ChemInform Abstract: Structure and Electrochemical Performance of FeF3/V2O5 Composite Cathode...

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ChemInform 2010, 41, issue 05 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Electrodes F 3000 DOI: 10.1002/chin.201005009 Structure and Electrochemical Performance of FeF 3 /V 2 O 5 Composite Cathode Material for Lithium-Ion Battery. — FeF3/V2O5 composites are prepared by milling of mixtures of V2O5 and as-prepared FeF3 (obtained from aqueous solutions of FeCl3, NaOH, and HF in a sealed bottle for 12 h at 70 °C). The products are characterized by XRD, SEM, galvanostatic charge/discharge measurements, and cyclic voltammetry. The addition of V 2 O 5 significantly improves the electrochemical performance of FeF 3 . The FeF3/V2O5 composite milled for 3 h exhibits the highest discharge voltage plateau, highest capacity, and highest capacity retention rate. Therefore, it is a promising next-generation cathode material for lithium ion batteries. — (WU, W.; WANG, Y.; WANG*, X.; CHEN, Q.; WANG, X.; YANG, S.; LIU, X.; GUO, J.; YANG, Z.; J. Alloys Compd. 486 (2009) 1-2, 93-96; Inst. Chem., Xiangtan Univ., Xiangtan, Hunan 411105, Peop. Rep. China; Eng.) — W. Pewestorf 05- 009

Transcript of ChemInform Abstract: Structure and Electrochemical Performance of FeF3/V2O5 Composite Cathode...

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ElectrodesF 3000 DOI: 10.1002/chin.201005009

Structure and Electrochemical Performance of FeF3/V2O5 Composite Cathode Material for Lithium-Ion Battery. — FeF3/V2O5 composites are prepared by milling of mixtures of V2O5 and as-prepared FeF3 (obtained from aqueous solutions of FeCl3, NaOH, and HF in a sealed bottle for 12 h at 70 °C). The products are characterized by XRD, SEM, galvanostatic charge/discharge measurements, and cyclic voltammetry. The addition of V2O5 significantly improves the electrochemical performance of FeF3. The FeF3/V2O5 composite milled for 3 h exhibits the highest discharge voltage plateau, highest capacity, and highest capacity retention rate. Therefore, it is a promising next-generation cathode material for lithium ion batteries. — (WU, W.; WANG, Y.; WANG*, X.; CHEN, Q.; WANG, X.; YANG, S.; LIU, X.; GUO, J.; YANG, Z.; J. Alloys Compd. 486 (2009) 1-2, 93-96; Inst. Chem., Xiangtan Univ., Xiangtan, Hunan 411105, Peop. Rep. China; Eng.) — W. Pewestorf

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ChemInform 2010, 41, issue 05 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim