ChemInform Abstract: [Cu(mim)4]2[α-Mo8O26] — A Layer-Type Octamolybdate Framework.

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ChemInform 2010, 41, issue 26 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Molybdenum I 5600 DOI: 10.1002/chin.201026016 [Cu(mim) 4 ] 2 [α-Mo 8 O 26 ] — A Layer-Type Octamolybdate Framework. — Blue, rectangular shaped crystals of the title compound are hydrothermally prepared from a mixture of Cu(NO3)2, (NH4)6Mo7O24, 1-methylimidazole (mim), HCl, and H2O (auto- clave, 80 °C, 5 d). [Cu(mim)4]2[Mo8O26] crystallizes in the monoclinic space group P21/n with Z = 4 (single crystal XRD). The structure consists of a two-dimensional framework formed by [α-Mo 8 O 26 ] 4- octamolybdate units as framework nods and the [Cu(mim)4] 2+ complex as a linker. — (ALAM, N.; FELDMANN*, C.; Solid State Sci. 12 (2010) 4, 471-475; Inst. Anorg. Chem., Univ. Karlsruhe, D-76128 Karlsruhe, Germany; Eng.) — W. Pewestorf 26- 016

Transcript of ChemInform Abstract: [Cu(mim)4]2[α-Mo8O26] — A Layer-Type Octamolybdate Framework.

Page 1: ChemInform Abstract: [Cu(mim)4]2[α-Mo8O26] — A Layer-Type Octamolybdate Framework.

www.cheminform.wiley-vch.de

MolybdenumI 5600 DOI: 10.1002/chin.201026016

[Cu(mim)4]2[α-Mo8O26] — A Layer-Type Octamolybdate Framework. — Blue, rectangular shaped crystals of the title compound are hydrothermally prepared from a mixture of Cu(NO3)2, (NH4)6Mo7O24, 1-methylimidazole (mim), HCl, and H2O (auto-clave, 80 °C, 5 d). [Cu(mim)4]2[Mo8O26] crystallizes in the monoclinic space group P21/n with Z = 4 (single crystal XRD). The structure consists of a two-dimensional framework formed by [α-Mo8O26]

4- octamolybdate units as framework nods and the [Cu(mim)4]

2+ complex as a linker. — (ALAM, N.; FELDMANN*, C.; Solid State Sci. 12 (2010) 4, 471-475; Inst. Anorg. Chem., Univ. Karlsruhe, D-76128 Karlsruhe, Germany; Eng.) — W. Pewestorf

26- 016

ChemInform 2010, 41, issue 26 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

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