ChemInform Abstract: An Easy and Versatile Approach for the Regioselective De-O-benzylation of...
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ChemInform 2011, 42, issue 38 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Carbohydrates U 0500 DOI: 10.1002/chin.201138187 An Easy and Versatile Approach for the Regioselective De-O-benzylation of Pro- tected Sugars Based on the I2/Et3SiH Combined System. — Only one benzyl group of a highly O-benzylated mono- or disaccharide (23 examples) is removed depending on the nature of the carbohydrate. The regioselectivity appears to be mainly controlled by steric effects. — (PASTORE, A.; VALERIO, S.; ADINOLFIN, M.; IADONISI*, A.; Chem. Eur. J. 17 (2011) 21, 5881-5889, http://dx.doi.org/10.1002/chem.201003332 ; Dip. Chim. Org. Biochim., Univ. Studi "Federico II", I-80126 Napoli, Italy; Eng.) — Klein 38- 187
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Transcript of ChemInform Abstract: An Easy and Versatile Approach for the Regioselective De-O-benzylation of...
CarbohydratesU 0500 DOI: 10.1002/chin.201138187
An Easy and Versatile Approach for the Regioselective De-O-benzylation of Pro-tected Sugars Based on the I2/Et3SiH Combined System. — Only one benzyl group of a highly O-benzylated mono- or disaccharide (23 examples) is removed depending on the nature of the carbohydrate. The regioselectivity appears to be mainly controlled by steric effects. — (PASTORE, A.; VALERIO, S.; ADINOLFIN, M.; IADONISI*, A.; Chem. Eur. J. 17 (2011) 21, 5881-5889, http://dx.doi.org/10.1002/chem.201003332 ; Dip. Chim. Org. Biochim., Univ. Studi "Federico II", I-80126 Napoli, Italy; Eng.) — Klein
38- 187
ChemInform 2011, 42, issue 38 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
ChemInform 2011, 42, issue 38 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
