Chemical Selection Guide_V5

CHEMICAL SELECTION GUIDELINE

Field Name DescriptionName Alpha name of chemical

CAS Number Chemical Abstact Service

Green Chemistry Classification

Chemical Formula Chemical FormulaGreen Chemistry Classification Reason(s) Rationale for Green Chemistry Classification

HHM (PSM) TQ Highly Hazardous Material Threshold Quantity in pounds (based on OSHA PSM List 1910.119 App A)

HHM (Seveso) TQ Highly Hazardous Material Threshold Quantity in tonnes (based on EU Seveso II)

FOR SORTING PURPOSE ONLY

CAS1 First Segment of CAS number.

CAS2 Second Segment of CAS number

CAS3 Third Segment of CAS number

NAMEINDEX Alpha name of chemical for sorting purpose. Sort by this column for alpha sorting.

Density Density in g/mL

Solubility Solubility in Water, wt%. M = completely miscible in water

LogPoct Log P octanol: < 2 - Not likely to bioaccumulate, 2 to 4 - Some bioaccumulation, > 4 - Likely to bioaccumulate

ThOD Theoretical Oxygen Demand

Flash Point Flash Point, °C

NFPA Health, Flammability, Reactivity, Other

Biodegradability

Aquatic Toxicity

Carcinogen

S-P HHC Schering-Plough's Health Hazard Category: 1 = Lowest hazard, 4 = Highest hazard

Notation for HHC

EG Regulated by Effluent Guidelines

HAP Hazardous Air Pollutant

CERCLA RQ Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Reportable Quantity in pounds

CAA 112(r) TQ Reportable Quantity from Clean Air Act 112(r) in pounds

NJAC 7:27-8 Table B HAPS New Jersey HAPs Table: T = < 200 lb (toxic) X = > 200 lb (less toxic)

NJAC 7:27-17 TXS New Jersey Specific TXS

EU List European Union Chemical List: B = Black List G = Grey List

Purpose: Guideline for chemical selection based on environmental impact.

G(reen): Environmentally acceptableY(ellow): Conditionally acceptable. Discussion with GSE recommended.R(ed): Use caution. If possible consider alternative. Discussion with GSE required.

Level of biodegradation in a biological Wastewater Treatment Plant. H > 80% removal, M - 50 to 80% removal, L < 50% removal

Aquatic toxicity in algae, fish, protozoaH - LC50 < 10 mg/L M - LC50 = 10 - 100 mg/L L - LC50 > 100 mg/L

RC = Recognized carcinogen SC = Suspected carcinogen

A- Immediate hypersensitivity reactions or anaphylaxis C- Corrosive,E- Systemic toxicity resulting from eye exposure P- Phototoxic, Photosensitizing, or PhotoallergicR- Respiratory sensitizer S- Systemic toxicity resulting from dermal absorptionZ- Skin sensitizer

CHEMICAL SELECTION GUIDELINE 3/13/2007

Is the compound

regulated by CERCLA and RQ < = 100 lb

or listed as NJ TXS?

Is thecompound

medium to high biodegradable

AND exhibits low aquatic

toxicity ?

No

Is the solubility

of the compound > 0.1 wt% and exhibits

high aquatic toxicity?

No

Is the compound regulated

by the listed environmental

regulation?

Yes

No

Is the compound

a recognized carcinogen, mutagen, or

reprotox?

Yes

No

REDCompound

YELLOWCompound

GREENCompound

No

Yes

JudgmentCall

document.xls/SummaryGuide

3 of 22 09-Dec-2009

NAME CAS Green Chemistry Classification Reason(s)ACETALDEHYDE R 75-07-0 C2H4O Carcinogen 2500ACETIC ACID G 64-19-7 C2H4O2 High biodeg, low to med aq toxicity, upgraded to greenACETIC ANHYDRIDE G 108-24-7 C4H6O3 Follows Acetic Acid classificationACETONE G 67-64-1 C3H6O High biodeg, low to med aq toxicity, upgraded to greenACETONE CYANOHYDRIN R 75-86-5 C4H7NO CERCLA RQ, high aq toxicity1,3-ACETONEDICARBOXYLIC ACID Y 542-05-2 C5H6O5 No available environmental dataACETONE OXIME Y 127-06-0 C3H7NO No available environmental dataACETONITRILE Y 75-05-8 C2H3N High biodeg, low aq toxicity, metabolizes to CN-ALLYL ALCOHOL R 107-18-6 C3H6O Low CERCLA RQ, high fish toxicityALLYL BROMIDE R 106-95-6 C3H5Br High aq toxicityALUMINUM CHLORIDE ANYDROUS Y 7446-70-0 AlCl3 Follow classification of HCl(1R,2S)-(+)-CIS-1-AMINO-2-INDANOL Y 136030-00-7 C9H11NO N compound, no env data2-AMINO-4,6-DIHYDROXYPYRIMIDINE Y 56-09-7 C4H5N3O2 No available environmental data

2-AMINO-4-CHLOROPHENOL Y 95-85-2 C6H6ClNO Nitrogen compound, no available environmental data2-AMINO-4-NITROPHENOL Y 99-57-0 C6H6N2O3 No available environmental data5-AMINO-4-CYANO-1-(2-HYDROXYETHYL)-PYRAZOLE Y 5346-53-2 C6H8ON4 No available environmental data2-(2-AMINOETHYLAMINO)ETHANOL Y 111-41-1 C4H12N2O Low to med biodeg, low aq toxicity5-AMINOIMIDAZOLE-4-CARBOXIMIDE HYDROCHLO Y 72-40-2 C4H6N4O.HCl No available environmental dataN-(3-AMINOPROPYL)-1,3-PROPANEDIAMINE Y 56-18-8 C6H17N3 No available environmental dataAMMONIA (ANHYDROUS) R 7664-41-7 NH3 Low CERCLA RQ 10000AMMONIUM ACETATE Y 631-61-8 C2H7NO2 High biodeg, low aq toxicity, N compoundAMMONIUM CHLORIDE R 12125-02-9 NH4Cl High aq toxicityAMMONIUM FORMATE Y 540-69-2 CH5NO2 No available environmental dataAMMONIUM HYDROXIDE Y 1336-21-6 NH4OH Limited use onlyAMMONIUM SULFATE Y 7783-20-2 N2H6SO4 Nitrogen compoundAMYL ACETATE Y 628-63-7 C7H14O2 Low to med aq toxicityISO-AMYL ACETATE Y 123-92-2 C7H14O2 Low to med aq toxicityTERT-AMYL ACETATE Y 625-16-1 C7H14O2 Follow classification of other amyl acetatesT-AMYL ALCOHOL Y 75-85-4 C5H12O Low biodegANILAZINE R 101-05-3 C9H5Cl3N4 High aq toxicityANILINE R 62-53-3 C6H7N CarcinogenP-ANISALDEHYDE Y 123-11-5 C8H8O2 High biodeg, low to med aq toxicityANISOLE G 100-66-3 C7H8O Insoluble in water, bioaccumulates, biodeg in soilANISYL ALCOHOL Y 105-13-5 C8H10O2 No available environmental dataN-T-BOC-ASPARAGINE Y 7536-55-2 C9H16N2O5 Nitrogen compound, no available environmental dataBARBITURIC ACID Y 67-52-7 C4H4N2O3 No available environmental dataBARIUM SULFATE Y 7727-43-7 BaSO4 European Grey List, bariumBENZALDEHYDE R 100-52-7 C7H6O High aq toxicityBENZENE R 71-43-2 C6H6 Carcinogen

GC Class

Chemical Formula

HHM(PSM)TQ, lb

HHM(Seveso)

TQ, T


4 of 22 09-Dec-2009

NAME CAS Green Chemistry Classification Reason(s)GC

ClassChemical Formula

HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TBENZENESULFONYL CHLORIDE R 98-09-9 C6H5ClO2S Low CERCLA RQBENZOYL CHLORIDE Y 98-88-4 C7H5ClO Halogenated, low to med aq toxicityBENZOYL PEROXIDE R 94-36-0 C14H10O4 Mutagen 7,500BENZYL ALCOHOL Y 100-51-6 C7H8O Medium biodeg, low to med aq toxicityBENZYL AMINE R 100-46-9 C7H9N Inhibitory to biomass, high aq toxicityBENZYL CHLOROFORMATE R 501-53-1 C8H7ClO2 Halogenated, very toxic to aquatic life (R50/53)(S)-N-BENZYL-ALPHA-METHYLBENZYLAMINE R 17480-69-2 C15H17N High aq toxicityN-BENZYL-N-(METHOXYMETHYL)-N-TRIMETHYLSI Y 93102-05-7 C13H23NOSi N, Si compound, no env dataN-BENZYL NORTROPINONE HYDROCHLORIDE Y 83393-23-1 No available environmental dataBENZYLTRIMETHYLALUMINUM DICHLOROIODATE Y 114971-52-7 C10H16Cl2IN No available environmental data1,1'-BIS(DIPHENYLPHOSPHINE) FERROCENE PAL R 95464-05-4 PdCl4C36H30FeP2 Follow classification for MeCl2BIS(TRIPHENYLPHOSPHINE) PALLADIUM (II) CHLO Y 13965-03-2 C36H30Cl12P2Pd No available environmental data

BIS(2-CHLOROETHYL)AMINE HCL R 821-48-7 C4H9Cl2N.HCl MutagenBISPHENOL A DICYANATE Y 1156-51-0 C17H14N2O2 Nitrogen compound, no available environmental dataBIS-TRIMETHYLSILYLACETAMIDE (BSA) Y 10416-59-8 C8H21NOSi2 Nitrogen compound, no available environmental dataN-BOC-L-ALANINE Y 15761-38-3 C8H15NO4 Nitrogen compound, no available environmental dataBORANE DIMETHYL SULFIDE Y 13292-87-0 C2H6S.BH3 B compound, no env dataBORANE TETRAHYDROFURAN COMPLEX R 14044-65-6 C4H11BO Follows THF classificationBORON TRICHLORIDE R 10294-34-5 BCl3 Hallogenated, environmentally regulatedBORON TRIFLUORIDE Y 7637-07-2 BF3 Halogenated, boron compoundBORON TRIFLUORIDE DIETHYL ETHERATE Y 109-63-7 C4H10BF3O Medium aq toxicity2-BROMO-5-FLUORO-BENZYL ALCOHOL Y 202865-66-5 C7H6BrFO Medium aq toxicityBROMOBENZENE Y 108-86-1 C6H5Br Halogenated. Med fish toxicity3-BROMOBENZOTRIFLUORIDE Y 401-78-5 C7H4BrF3 No available environmental data3-BROMOCHLOROBENZENE Y 108-37-2 C6H4BrCl No available environmental data2-BROMOETHANOL R 540-21-2 C2H5BrO Genotoxic. Toxic to microorganisms(2-BROMOETHOXY)-T-BUTYLDIMETHYLSILANE Y 86864-60-0 C8H19BrOSi Hallogenated, silicon compoundBROMOFLUOROMETHANE Y 373-52-4 CH2BrF Halogenated, no available environmental data5-BROMO-2-HYDROXYMETHYLPYRIDINE (BHMP) Y 88139-91-7 C6H6BrNO No available environmental dataBROMOPROPYLAMINE HYDROBROMIDE Y 5003-71-4 C3H8BrN.HBr Halogenated, no available environmental data2-BROMOPYRIMIDINE Y 4595-60-2 C4H3BrN2 N, Br compound, no env dataN-BROMOSUCCINIMIDE Y 128-08-5 C4H4BrNO2 N compound, no env data

BROMOTRIMETHYLSILANE Y 2857-97-8 C3H9BrSi Silicon compound1,3-BUTANEDIOL Y 107-88-0 C4H10O2 Miscible, low biodeg1,4-BUTANEDIOL G 110-63-4 C4H10O2 High biodeg, low aq toxicity1-BUTANOL R 71-36-3 C4H10O Medium biodeg, high protozoa toxicity2-BUTANOL G 78-92-2 C4H10O High biodeg, low aq toxicityT-BUTANOL Y 75-65-0 C4H10O Low biodeg, low aq toxicity2-BUTOXYETHANOL Y 111-76-2 C6H14O2 Low to med aq toxicity, may form explosive peroxide


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HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TN-BUTYL ACETATE Y 123-86-4 C6H12O2 Medium biodeg, low to med aq toxicitySEC-BUTYL ACETATE Y 105-46-4 C6H12O2 Follow classification of other butyl acetatesT-BUTYL ACETATE Y 540-88-5 C6H12O2 Low aq toxicityBUTYLAMINE R 109-73-9 C4H11N Miscible, med to high aq toxicityN-BUTYL CHLORIDE Y 109-69-3 C4H9Cl Halogenated, med biodeg, low aq toxicityBUTYL ETHER Y 142-96-1 C8H18O Bioaccumulates, med aq toxicityN-BUTYLLITHIUM Y 109-72-8 C4H9Li No available environmental data2-BUTYONIC ACID HYDRAZINE P-TOLUENE-SULFON Y 494793-39-4 No available environmental dataISO-BUTYRIC ACID Y 79-31-2 C4H8O2 Medium biodeg, med aq toxicityCALCIUM CARBONATE G 471-34-1 CaCO3 No known environmental issues(1R,3S)-(+)CAMPHORIC ACID Y 124-83-4 C10H16O4 No available environmental dataCAMPHORSULFONIC ACID Y 5872-08-2 C10H16O4S No available environmental data(1S)-(+)-(-10-CAMPHORSULFONYL)-OXAZIRIDINE Y 104322-63-6 C10H15NO3S Nitrogen compound, no available environmental dataCARBON TETRACHLORIDE R 56-23-5 CCl4 CarcinogenN,N-CARBONYL DIIMIDAZOLE G 530-62-1 C7H6N4O Medium biodeg, low aq toxicityCATALASE (CATAZYME) G 9001-05-2 CAT BiologicalCELITE (HYFLO SUPER-CEL) G 61790-53-2 SiO2 Applies only if the material is not airborne.CELITE G 68855-54-9 SiO2 Applies only if the material is not airborne.CESIUM CARBONATE Y 534-17-8 Cs2O3 No available environmental dataCETYL ALCOHOL G 36653-82-4 C16H34O No known environmental issues

1-CHLORO-2,4-DINITROBENZENE Y 97-00-7 C6H3ClN2O4 Halogenated compound1-CHLORO-2-IODOBENZENE Y 615-41-8 C6H4ClI No available environmental data

1-CHLORO-2-NITROBENZENE Y 88-73-3 C6H4ClNO2 Halogenated, nitrogen compound

4-CHLORO-2-NITROTOLUENE Y 89-59-8 C7H6ClNO2 Halogenated, nitrogen compound2-CHLORO-3-CHLOROMETHYL QUINOLINE Y 90097-52-2 C10H8Cl2N No available environmental dataCHLOROACETIC ACID R 79-11-8 C2H3ClO2 Low CERCLA RQ3-CHLOROACETOPHENONE Y 99-02-5 C8H7ClO No available environmental dataCHLOROACETYL CHLORIDE Y 79-04-9 C2H2Cl2O Halogenated, no available environmental data

2-CHLOROANILINE R 95-51-2 C6H6ClN High aq toxicityO-CHLOROBENZALDEHYDE Y 89-98-5 C7H5Cl Medium biodeg, med aq toxicityCHLOROBENZENE R 108-90-7 C6H5Cl Low CERCLA RQ, high fish toxicity4-CHLOROBENZENESULFONYL CHLORIDE Y 98-60-2 C6H4Cl2O5S No available environmental data4-CHLOROBENZOYL CHLORIDE Y 104-83-6 C7H6Cl2 No available environmental data

2-CHLOROETHANOL Y 107-07-3 C2H5ClO Low biodegCHLOROFORM R 67-66-3 CHCl3 Carcinogen(4-CHLORO-2-METHYLPHENOXY) ACETIC ACID Y 94-74-6 C9H9ClO3 Low solubility, med to high aq toxicity

1-CHLORONAPHTHALENE Y 90-13-1 C10H7Cl Halogenated compound2-CHLOROPHENOL R 95-57-8 C6H5ClO Low CERCLA RQ2-CHLOROPROPANE Y 75-29-6 C3H7Cl Halogenated, SC


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HHM(PSM)TQ, lb

HHM(Seveso)

TQ, T2-CHLOROPYRIMIDINE Y 1722-12-9 C4H3ClN2 Halogenated, no available environmental dataCHLOROSULFONYL ISOCYANATE R 1189-71-5 CClNO3S Decomposes to HCl, HCN, SOx4-CHLOROTHIOPHENOL Y 106-54-7 ClC6H4SH No available environmental dataCHLOROTRIMETHYL SILANE Y 75-77-4 C3H9ClSi Halogenated, no available environmental dataCHOLINE HYDROXIDE Y 123-41-1 C5H15NO2 No available environmental dataCINCHONINE Y 118-10-5 C19H22N2O No available environmental dataCITRIC ACID ANHYDROUS G 77-92-9 C6H8O7 High biodeg, low aq toxicityCITRIC ACID MONOHYDRATE G 5949-29-1 C6H8O7 High biodeg, low aq toxicityCOPPER CHLORIDE R 7758-89-6 CuCl High aq toxicityCOPPER IODIDE R 7681-65-4 CuI High aq toxicity18-CROWN-6 Y 17455-13-9 C12H24O6 No available environmental dataCYANOGEN BROMIDE R 506-68-3 BrCN High aq toxicity2-CYANO-3-METHYLPYRIDINE Y C7H6N2 Nitrogen compound, no available environmental data2-CYANOPYRIDINE R 100-70-9 C6H4N2 High aq toxicityCYCLOHEXANE Y 110-82-7 C6H12 Medium CERCLA RQ, almost insoluble, high fish toxicityCYCLOHEXANE CARBOXALDEHYDE Y 2043-61-0 C7H12O No available environmental dataCYCLOHEXANOL G 108-93-0 C6H12O High biodeg, med to low aq toxicity, upgraded to greenCYCLOHEXANONE G 108-94-1 C6H10O High biodeg, low aq toxicity, CERCLA RQ, upgraded to greenCYCLOPENTANE Y 287-92-3 C5H10 Low fish tox, no additional info availableCYCLOPENTENE OXIDE Y 285-67-6 C5H8O No available environmental dataCYCLOPENTYL METHYL ETHER (CPME) G 5614-37-9 C6H12O Low aq toxicityCYCLOPROPYLAMINE Y 765-30-0 C3H7N Nitrogen compound, no available environmental data4-CYCLOPROPYL BUTANEOIC ACID Y 5687-84-3 C7H12O2 No available environmental data1,4-DIAZABICYCLO (2,2,2)-OCTANE (DABCO) Y 280-57-9 C6H12N2 Low biodeg, low to med aq toxicityDARCO G-60 G 7440-44-0 C No known environmental issues1,8-DIAZABICYCLO[5,4,0]UNDEC-7-ENE (DBU) Y 6674-22-2 C9H16N2 Low biodeg, low to med aq toxicityDIBUTYL PHTHALATE R 84-74-2 C16H22O4 Low CERCLA RQ1,2-DICHLOROBENZENE R 95-50-1 C6H4Cl2 Low CERCLA RQ, high fish toxicity1,2-DICHLOROETHANE (DCE) R 107-06-2 C2H4Cl2 CarcinogenDICHLOROMETHANE R 75-09-2 CH2Cl2 CarcinogenDICHLOROMETHYLSILANE Y 75-74-7 CH4Cl2Si Halogenated, silicon compound

ALPHA, ALPHA-DICHLOROTOLUENE R 98-87-3 C7H6Cl2 CarcinogenDICYCLOHEXYLAMINE R 101-83-7 C12H23N High aq toxicity2-DICYCLOHEXYLPHOSPHINO-2'-(N,N-DIMETHYLAM Y 213697-53-1 C16H36NP Nitrogen and organic phosphorus compoundDIETHOXYMETHANE (DEM) G 462-95-3 C5H12O2 Low fish/protozoa tox, no additional info availableDIETHYL 2,2-DIETHOXYETHYL PHOSPHONATE Y 7598-61-0 C10H23O5P No available environmental dataDIETHYLAMINE (DEA) R 109-89-7 C4H11N Low CERCLA RQ, high algal toxicity, low biodegDIETHYLENE GLYCOL R 111-46-6 C4H10O3 High aq toxicityDIETHYLENE GLYCOL BUTYL ETHER G 112-34-5 C8H18O3 No known environmental issues


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HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TDIETHYLENE GLYCOL DIETHYL ETHER Y 112-36-7 C8H18O3 Low biodegDIETHYLENE GLYCOL ETHYL ETHER G 111-90-0 C6H14O3 High biodeg, low aq toxicityDIETHYLENE GLYCOL ETHYL ETHER ACETATE Y 112-15-2 C8H16O4 Medium biodegDIETHYLENE GLYCOL HEXYL ETHER Y 112-59-4 C10H22O3 No available environmental dataDIETHYLENE GLYCOL METHYL ETHER R 111-77-3 C5H12O3 ReprotoxDI(2-ETHYLHEXYL) PHTHALATE R 117-81-7 C24H38O4 CarcinogenDIETHYL PHOSPHITE R 762-04-9 C4H11O3P Organophosphorus compoundDIETHYL SQUARATE Y 5231-87-8 C8H10O4 No available environmental data2,4-DIFLUOROPHENYLACETONITRILE Y 656-35-9 C8H5F2N F, N compound, no env data[3,4]-DIHYDRO-2H-PYRAN (DHP) Y 110-87-2 C5H8O Not readily biodegradableDIISOBUTYL ALUMINUM HYDRIDE Y 1191-15-7 C8H19Al No available environmental dataDIISOBUTYL KETONE Y 108-83-8 C9H18O No available environmental dataN,N-DIISOPROPYLETHYLAMINE Y 7087-68-5 C8H19N Readily biodeg, med aq tox, N compound2,5-DIMETHOXY TETRAHYDROFURAN Y 696-59-3 C6H12O3 No available environmental data1,2-DIMETHOXYETHANE (DME) R 110-71-4 C4H10O2 ReprotoxDIMETHOXYMETHANE (DMM) G 109-87-5 C3H8O2 High biodeg, low aq toxicity1,3-DIMETHYL-2-IMIDAZOLIDINONE Y 80-73-9 C5H10N2O No available environmental dataDIMETHYL ACETAMIDE (DMAC) R 127-19-5 C4H9NO ReprotoxDIMETHYLAMINE Y 124-40-3 C2H7N Medium aq toxicityN-METHYL-METHANAMINE Y 124-40-3 C2H7N Medium aq toxicity

4-DIMETHYLAMINO PYRIDINE R 1122-58-3 C7H10N2 Low biodeg, high aq toxicityN,N-DIMETHYLANILINE Y 121-69-7 C8N11N Low biodeg, low to med aq toxicityDIMETHYL CARBONATE Y 616-38-6 C3H6O3 No available environmental dataN,N-DIMETHYLCYCLOHEXYLAMINE R 98-94-2 C8H17N High aq toxicityN,N-DIMETHYLFORMAMIDE (DMF) R 68-12-2 C3H7NO Teratogen, low CERCLA RQ1,1-DIMETHYL HYDRAZINE R 57-14-7 C2H8N2 Carcinogen 1000DIMETHYL MALONATE Y 108-59-8 C5H8O4 Medium aq toxicityDIMETHYL SQUARATE Y 5222-73-1 C6H6O4 No available environmental dataDIMETHYL SULFATE (DMS) R 77-78-1 C6H6O4S CarcinogenDIMETHYL SULFOXIDE (DMSO) G 67-68-5 C2H6OS High biodeg, low aq toxicityDIMETHYL SULFIDE Y 75-18-3 C2H6S Odor1,4-DIOXANE R 123-91-1 C4H8O2 CarcinogenDIPHENYLCARBAMOYL CHLORIDE Y 83-01-2 C13H10ClNO No available environmental dataDIPHENYL ETHER Y 101-84-8 C12H10O Almost insoluble, high biodeg, high aq toxicityDIPHENYLPHOSPHORYL AZIDE R 26386-88-9 C12H10N3O3P N and P compound, toxic by inhalationDIPROPYLENE GLYCOL Y 25265-71-8 C6H14O3 No available environmental dataDIPROPYLENE GLYCOL METHYL ETHER G 34590-94-8 C7H16O3 High biodeg, low aq toxicityDI-P-TOLUOYL-D-TARTARIC ACID Y 71607-31-3 C20H18O8.H2O No available environmental dataDI-P-TOLUOYL-D-TARTARIC ACID ANHYDROUS Y 32634-68-7 C20H18O8 No available environmental data


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HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TN,N-DISUCCINIMIDYL CARBONATE Y 74124-79-1 C9H8N2O7 N compound, no env data2-DI-T-BUTYLPHOSPHINO-2-(N,N-DIMETHYLAMINO Y 224311-49-3 C22H32NP BioaccumulatesDI-TERT-BUTYL DICARBONATE Y 24424-99-5 C10H18O5 No available environmental dataECOSORB G C Follow classification for other carbonsEDCI HCL Y 25952-53-8 C8H18N3Cl No available environmental dataEPICHLOROHYDRIN R 106-89-8 C3H5ClO Carcinogen, low CERCLA RQETHANOL G 64-17-5 C2H6O No known environmental issuesETHANOLAMINE R 141-43-5 C2H7NO Medium biodeg, high aq toxicity2-ETHOXYETHANOL R 110-80-5 C4H10O2 Teratogen, low CERCLA RQETHYL(4-FLUOROBENZOYL)FORMATE Y 1813-94-1 C10H9FO3 No available environmental data(2S,4R)-ETHYL-1-BOC-4-(CYCLOPROPANECARBOX Y C16H26N2O4 No available environmental dataETHYL ACETATE (ETOAC) G 141-78-6 C4H8O2 CERCLA RQ, med algal toxicity, upgraded to greenETHYLAMINE R 75-04-7 C2H7N High aq toxicity 7,500ETHYLBENZENE R 100-41-4 C8H10 CarcinogenETHYL CHLORIDE R 75-00-3 C2H5Cl Carcinogen, low CERCLA RQETHYL CHLOROFORMATE R 541-41-3 C3H5ClO2 High aq toxicityETHYL DIFLUOROACETATE Y 454-31-9 C4H6F2O2 Halogenated, no available environmental dataETHYLENE CARBONATE Y 96-49-1 C3H4O3 High biodeg, low aq tox. However, it converts to ethylene glycol in boETHYLENE GLYCOL R 107-21-1 C2H6O2 Teratogen, mutagenETHYLENE GLYCOL DIETHYL ETHER Y 629-14-1 C6H14O2 Low biodegETHYL ETHER R 60-29-7 C4H10O Low CERCLA RQ, low biodeg2-ETHYLHEXANOL Y 104-76-7 C8H18O No available environmental dataETHYL ISOCYANATE Y 109-90-0 No available environmental dataETHYLMAGNESIUM BROMIDE Y 925-90-6 C2H5BrMg No available environmental dataETHYLMAGNESIUM CHLORIDE Y 2386-64-3 C2H5ClMg No available environmental dataETHYL METHANESULFONATE R 62-50-0 C3H8O3S Carcinogen2,4-D 2-ETHYL-4-METHYLPENTYL ESTER Y 53404-37-8 No known environmental issuesETHYL P-TOLUENESULFONATE Y 80-40-0 C9H12O3S Sulfur compound, no env info availableETHYL-TERT BUTYL ETHER Y 637-92-3 C6H14O N compound, no env data3-FLUORO-4-METHYLANILINE Y 452-77-7 C7H9FN Halogenated, no available environmental data3-FLUOROPHENYLBORONIC ACID Y 768-35-4 C6H6BFO2 Halogenated, no available environmental data4-FLUOROPHENYLMAGNESIUM BROMIDE Y 352-13-6 C6H4BrFMg No available environmental dataFORMALDEHYDE R 50-00-0 CH2O Carcinogen 1000 5 - 50FORMAMIDE R 75-12-7 CH3NO Teratogen, miscible and low biodegFORMIC ACID Y 64-18-6 CH2O2 High biodeg, low to med aq toxicityFORMIC ACID, SODIUM SALT G 141-53-7 CHNaO2 High biodeg, low aq toxicityFORMIC HYDRAZINE Y 624-84-0 CH4N2O No available environmental dataFUMARIC ACID Y 110-17-8 C4H4O4 Low to med aq toxicityFURFURAL R 98-01-1 C5H4O2 Suspected carcinogen, high aq toxicity


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HHM(PSM)TQ, lb

HHM(Seveso)

TQ, T

2-FUROIC HYDRAZIDE Y 3326-71-4 C6H6N2O2 Nitrogen compound, no available environmental data2-FUROYL CHLORIDE Y 527-69-5 C5H3ClO2 Halogenated, no available environmental dataGLYCEROL G 56-81-5 C3H8O3 No known environmental issuesGLYOXYLIC ACID G 298-12-4 C2H2O3 High biodeg, low aq toxicityN-HEPTANE Y 142-82-5 C7H16 Almost insoluble, low biodegHEPTANES Y 64742-49-0 C7H16 Almost insoluble, high biodeg, high aq toxicityHEXAFLUOROPROPENE DIETHYLAMINE Y C7H11NF6 Halogenated, no available environmental dataHEXAMETHYLDISILAZANE (HMDS) Y 999-97-3 C6H19NSi2 Silicon compoundHEXAMETHYLDISILOXANE (HMDSO) Y 107-46-0 C6H8OSi2 Silicon compoundHEXAMETHYLENE TETRAMINE Y 100-97-0 C6H12N4 Low biodegN-HEXANE Y 110-54-3 C6H14 High aq toxicity, but almost insoluble1-HEXANOL Y 111-27-3 C6H14O Medium biodeg, low to med aq toxicity1-HEXENE Y 592-41-6 C6H12 No available environmental dataHEXYLENE GLYCOL Y 107-41-5 C6H14O2 Miscible, low biodeg, low aq toxicityHEXYLLITHIUM, 2.5M IN HEXANE Y 21369-64-2 C6H13Li No available environmental dataHOVEYDA-GRUBBS 2ND GENERATION CATALYST Y 301224-40-8 C31H38Cl2ORU No available environmental dataHYDRAZINE (AND SALTS) R 302-01-2 H4N2 Nitrogen compound, follow classif. for other hydrazine saltsHYDRAZINE HYDRATE R 7803-57-8 H6N2O High aq toxicityHYDRIODIC ACID R 10034-85-2 HI High aq toxicityHYDROBROMIC ACID Y 10035-10-6 HBr Halogenated, no available environmental data 5000HYDROCHLORIC ACID Y 7647-01-0 HCl Inorganic, med aq toxicity, chlorinated 5000HYDROFLUORIC ACID R 7664-39-3 HF Low CERCLA RQ 1000HYDROGEN G 1333-74-0 H2 Atom economical 5 - 50HYDROGEN PEROXIDE (>52%) Y 7722-84-1 H2O2 Limited use only 75002-HYDROXY-1-NAPHTHOIC ACID Y 2283-08-1 C11H8O3 No available environmental data1-HYDROXY-2-NAPHTHOIC ACID Y 86-48-6 C11H9O3 No available environmental dataP-HYDROXYACETOPHENONE Y 99-93-4 C8H8O2 No available environmental data1-HYDROXYBENZOTRIAZOLE HYDRATE (HOBT) Y 123333-53-9 C6H5N3O.xH2O Nitrogen compound, no available environmental dataHYDROXYLAMINE HYDROCHLORIDE R 5470-11-1 ClH4NO High aq toxicityHYFLO G 91053-39-3 SiO2 Applies only if the material is not airborne.IMIDAZOLE-4-CARBOXALDEHYDE Y 3034-50-2 C4H4N2O No available environmental dataIODINE FLAKES R 7553-56-2 I2 High aq toxicityN-IODOSUCCINIMIDE Y 516-12-1 C4H4INO2 Halogenated, no available environmental dataIODOTRIMETHYLSILANE R 16029-98-4 C3H9ISi Releases HI, follow HI classificationISOAMYL ALCOHOL Y 123-51-3 C5H12O Low biodeg, low aq toxicityISOBUTANOL G 78-83-1 C4H10O Toxic, high biodeg, low aq toxicity, upgraded to greenISOBUTYL ACETATE (IBUOAC) G 110-19-0 C6H12O CERCLA RQ, upgraded to greenISOHEXANE Y 107-83-5 C6H14 Toxic to aquatic life (R51/53)ISOPROPYL ACETATE (IPAC) G 108-21-4 C5H10O2 Low half-life, low aq toxicity


10 of 22 09-Dec-2009



HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TISOPROPYL ALCOHOL (IPA) G 67-63-0 C3H8O No known environmental issuesISOPROPYLAMINE R 75-31-0 C3H9N High aq toxicity 5000ISOPROPYL ETHER Y 108-20-3 C6H14O Low solubility, low biodeg, low to med aq toxicityISOPROPYL METHANESULFONATE Y 926-06-7 C4H10O3S Sulfur compound, no env info available, SCLITHIUM ALUMINUM HYDRIDE Y 16853-85-3 LiAlH4 No available environmental dataLITHIUM BIS(TRIMETHYLSYL)AMIDE Y 4039-32-1 C6H18NSi2Li No available environmental dataLITHIUM BROMIDE Y 7550-35-8 LiBr HalogenatedLITHIUM CARBONATE Y 554-13-2 LiCO3 Medium aq toxicityLITHIUM DIISOPROPYLAMIDE R 4111-54-0 C6H15NLi CarcinogenLITHIUM HYDROXIDE MONOHYDRATE Y 1310-66-3 LiOH No available environmental dataLITHIUM TRI-T-BUTOXYALUMINUM HYDRIDE Y 17476-04-9 LiC12H28AlO3 No available environmental data2,6-LUTIDINE Y 108-48-5 C7H9N Nitrogen compound, no available environmental data

MAGNESIUM CARBONATE G 546-93-0 MgCO3 No known environmental issuesMAGNESIUM CHLORIDE R 7786-30-3 MgCl2 MutagenMAGNESIUM HYDROXIDE Y 1309-42-8 MgH2O2 FlocculantMAGNESIUM SULFATE ANHYDROUS G 7487-88-9 MgSO4 No known environmental issuesMAGNESIUM SULFATE HEPTAHYDRATE G 10034-99-8 MgSO4.7H2O Low aq toxicityMALEIC ACID Y 110-16-7 C4H4O4 Low biodeg, low aq toxicityMALONIC ACID Y 141-82-2 C3H4O4 Low biodeg, low aq toxicity2-MERCAPTOBENZOTHIAZOLE R 149-30-4 C7H5NS2 High aq toxicityMERCAPTOETHANOL R 60-24-2 C2H7OS High aq toxicityMETHANESULFONIC ACID Y 75-75-2 CH4O3S High biodeg, med aq toxicityMETHANESULFONIC-(2-METHOXY-ETHYL ESTER) Y 16427-44-4 C4H10O4S No available environmental dataMETHANESULFONYL CHLORIDE Y 124-63-0 CH3ClO2S High biodeg, med aq toxicityMETHANOL Y 67-56-1 CH4O Toxic, med biodeg 500 - 50002-METHOXY-3-PYRIDINE BORONIC ACID Y 163105-90-6 C8H8BNO3 No available environmental data4-METHOXYBENZENE SULFONYL CHLORIDE Y 98-68-0 C7H7ClO3S No available environmental data2-METHOXYETHANOL R 109-86-4 C3H8O2 Teratogen, miscible and low biodeg2-METHOXYETHYL ACETATE Y 110-49-6 C5H10O3 Low biodeg2-METHOXYETHYL ETHER R 111-96-6 C6H14O3 Reprotox3-METHOXYPROPYLAMINE Y 5332-73-0 C4H11NO N compound, no available environmental dataMETHYL 4-(TRIFLUOROMETHYL)-BENZOATE Y 2967-66-0 C9H7F3O2 No available environmental dataMETHYL METHOXYACETATE Y 6290-49-9 C4H8O3 No available environmental dataMETHYL 1-METHYLCYCLOPROPYL KETONE Y 1567-75-5 C6H10O No available environmental dataMETHYL 2-CHLORO-3-METHYLPYRAZINE-5-CARBO Y C7H7ClN2O2 No available environmental dataMETHYL-7-METHYL-3-OXO-OCTANOATE Y 128651-36-5 No available environmental dataMETHYL ACETATE Y 79-20-9 C3H6O2 Follows methanol classificationMETHYLAMINE R 74-89-5 CH5N Low CERCLA RQ 1,000METHYLAMINE HYDROCHLORIDE Y 593-51-1 CH5N.HCl No available environmental data


11 of 22 09-Dec-2009



HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TMETHYL BROMIDE Y 74-83-9 CH3Br Halogenated, hydrolyzes to methanol 2500(S)-2-METHYL-CBS-OXAZABOROLIDINE (MECBS) I R 112022-81-8 C18H20BNO Low biodeg, potential reprotoxMETHYL CHLORIDE R 74-87-3 CH3Cl Low CERCLA RQ 15000METHYL CHLOROFORMATE R 79-22-1 C2H3ClO2 Low CERCLA RQ 500METHYL CYCLOHEXANE Y 108-87-2 C7H14 Almost insoluble, med aq toxicity, follow cyclohexaneMETHYL DICHLOROACETATE Y 116-54-1 C3H4Cl2O2 No available environmental dataMETHYLENE BROMIDE Y 74-95-3 CH2Br2 CERCLA RQ, halogenatedMETHYL ETHYL KETONE (MEK) Y 78-93-3 C4H8O Medium biodeg, low aq toxicity, CERCLA RQ5-METHYLEXANOIC ACID Y 628-46-6 C7H14O2 No available environmental dataMETHYL FORMATE Y 107-31-3 C2H4O2 High biodeg, low aq toxicity, CAA5-METHYLFURFURAL Y 620-02-0 C6H6O2 No available environmental dataMETHYL HYDRAZINE R 60-34-4 CH6N2 Carcinogen 100METHYL IODIDE R 74-88-4 CH3I Carcinogen 7500METHYL ISOBUTYL KETONE (MIBK) Y 108-10-1 C6H12O Medium biodeg, low aq toxicity, CERCLA RQMETHYL ISOPROPYL KETONE (MIPK) Y 563-80-4 C5H10O Low biodegradationMETHYLMAGNESIUM BROMIDE Y 75-16-1 CH3BrMg Halogenated, no available environmental dataMETHYLMAGNESIUM CHLORIDE Y 676-58-4 CH3ClMg No available environmental dataMETHYL MERCAPTAN R 74-93-1 CH4S Low CERCLA RQ 5000METHYL METHANESULFONATE R 66-27-3 C2H6O3S CarcinogenN-METHYLMORPHOLINE Y 109-02-4 C5H11NO N compound, med biodeg, low aq toxicity2-METHYLPROPENE R 115-11-7 C4H8 Low CERCLA RQ2-METHYL-5-PROPYONYL FURAN Y 10599-69-6 C8H10O2 No available environmental dataMETHYL P-TOLUENESULFONATE Y 80-48-8 C8H10O3S Sulfur compound, no env info available1-METHYLPYRROLIDINE R 120-94-5 C5H11N High aq toxicityN-METHYL-2-PYRROLIDONE (NMP) R 872-50-4 C5H9NO ReprotoxMETHYL TERT-BUTYL ETHER (MTBE) R 1634-04-4 C5H12O Mutagen2-METHYL TETRAHYDROFURAN G 96-47-9 C5H10O Almost insoluble, no known env impact, upgrade to greenMETHYL TRIPHENYL PHOSPHONIUM BROMIDE Y 1779-49-3 C19H18BrP Organophosphorus cmpd, med aq toxMETHYL VINYL KETONE R 78-94-4 C4H6O High aq toxicity 100MALONAMIDE Y 108-13-4 C3H6N2O2 No available environmental dataMONOMETHYL MALONATE POTASSIUM SALT Y 38330-80-2 KC4H6O4 No available environmental dataN-ETHYL PYRROLIDONE (NEP) Y 2687-91-4 C6H11NO Nitrogen compound, no available environmental dataNITROBENZENE R 98-95-3 C6H5NO2 CarcinogenNITROMETHANE R 75-52-5 CH3NO2 Carcinogen 2500M-NITROPHENOL R 554-84-7 C6H5NO3 CERCLA RQ3-NITROSALICYLIC ACID Y 85-38-1 C7H5NO5 No available environmental dataNOVOZYME 435 G 9001-62-1 Enzyme Low aq toxicity1-OCTANOL R 111-87-5 C8H18O Some bioaccumulation, high aq toxicity, low solubilityOXALIC ACID ANHYDROUS Y 144-62-7 C2H2O4 High bioded, low to med aq toxicity


12 of 22 09-Dec-2009



HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TOXALYL CHLORIDE Y 79-37-8 C2Cl2O2 Chlorinated, toxicPALLADIUM ACETATE Y 3375-31-3 PdC4H6O4 Metal, no env info availablePALLADIUM ON CARBON (50% WATER WET) Y 7440-05-3 Pd No available environmental dataN-PENTANE Y 109-66-0 C5H12 Some bioaccumulation, almost insoluble, high aq toxicity1-PENTANOL G 71-41-0 C5H12O High biodeg, low to med aq toxicity, upgraded to green3-PENTANONE G 96-22-0 C5H10O Medium biodeg, low aq toxicity1,2,3,4,5-PENTAPHENYL-1-(DI-T-BUTYLPHOSPHIN Y 312959-21-3 C45H47FeP No available environmental dataPERACETIC ACID Y 79-21-0 C2H4O3 High biodeg, low to med aq toxicity 1,000

PHENYLETHYL ALCOHOL G 60-12-8 C8H10O High biodeg, low aq toxicity(S)-1-PHENYLETHYLAMINE Y 2627-86-3 C8H11N High biodeg, medium aq toxicityPHENYLHYDRAZINE R 100-63-0 C6H8N2 CarcinogenPHENYLHYDRAZINE R 59-88-1 C6H8N2 CarcinogenPHOSPHORIC ACID G 7664-38-2 H3PO4 Inorganic, low aq toxicityPHOSPHORUS OXYCHLORIDE Y 10025-87-3 Cl3OP Enhances eutrophicationPIPERIDINE Y 110-89-4 C5H11N Miscible, med aq toxicityPIPERIDINE-4-CARBOXYLIC ACID ETHYL ESTER Y No known environmental issues4-PIPERIDONE HYDRATE HYDROCHLORIDE Y 40064-34-4 C5H10ClNO.H2O No available environmental dataPIPERONYL BUTOXIDE Y 51-03-6 C19H30O5 Medium biodeg, med aq toxicityPIP-PHOSPHONATE Y 216870-24-5 No known environmental issuesPIVALDEHYDE Y 630-19-3 C5H10O No available environmental dataPOLYETHYLENE GLYCOL (PEG) G 25322-68-3 (C2H4O)nH2O No known environmental issuesPOLYPROPYLENE GLYCOL (PPG) G 25322-69-4 C3H8O2 No known environmental issuesPOTASSIUM ACETATE G 127-08-2 C2H3KO2 Medium biodeg, low aq toxicityPOTASSIUM BICARBONATE G 298-14-6 KHCO3 No known environmental issuesPOTASSIUM BOROHYDRIDE Y 13762-51-1 KBH4 Boron compoundPOTASSIUM BROMIDE Y 7758-02-3 KBr Halogenated, no available environmental dataPOTASSIUM CARBONATE G 584-08-7 K2CO3 No known environmental issuesPOTASSIUM CYANIDE R 151-50-8 KCN Low CERCLA RQPOTASSIUM HYDROXIDE (SOLIDS) Y 1310-58-3 KOH CERCLA RQPOTASSIUM PERMANGANATE R 7722-64-7 KMnO4 High aq toxicityPOTASSIUM PEROXYMONOSULFATE SULFATE Y 70693-62-8 2HKO5S.HKO4.K2O4S Medium aq toxicityPOTASSIUM PERSULFATE G 7727-21-1 K2S2O8 Low aq toxicityPOTASSIUM PHOSPHATE, DIBASIC Y 7758-11-4 K2HPO4 Enhances eutrophicationPOTASSIUM PHOSPHATE, MONOBASIC Y 7778-77-0 KH2PO4 Enhances eutrophicationPOTASSIUM PHOSPHATE, TRIBASIC Y 7778-53-2 K3PO4 Phosphorus compound, low aq toxicityPOTASSIUM PHOSPHATE TRIBASIC MONOHYDRAT Y 27176-10-9 K3O4P.H2O Enhances eutrophicationPOTASSIUM SODIUM TARTRATE Y 6381-59-5 C4H4KNaO6 No available environmental dataPOTASSIUM SULFATE G 7778-80-5 K2SO4 No known environmental issuesPOTASSIUM TERT-BUTOXIDE G 865-47-4 KC4H9O High biodeg, low aq toxicity


13 of 22 09-Dec-2009



HHM(PSM)TQ, lb

HHM(Seveso)

TQ, T1-PROPANOL G 71-23-8 C3H8O High biodeg, low to med aq toxicity, upgraded to greenBETA-PROPIOLACTONE R 57-57-8 C3H4O2 Carcinogen, low CERCLA RQPROPIONIC ACID Y 79-09-4 C3H6O2 Medium biodeg, med aq toxicityPROPYL ACETATE Y 109-60-4 C5H12O2 Medium aq toxicityPROPYLENE CARBONATE G 108-32-7 C3H6O3 High biodeg, low aq toxicityPROPYLENE GLYCOL G 57-55-6 C3H8O2 Medium biodeg, low aq toxicityPROPYLENE GLYCOL METHYL ETHER G 107-98-2 C4H10O2 High biodeg, low aq toxicityPROPYLENE GLYCOL METHYL ETHER ACETATE G 108-65-6 C6H12O2 Medium biodeg, low aq toxicityPROPYLENE OXIDE R 75-56-9 C3H6O Carcinogen 5 - 50PYRIDINE R 110-86-1 C5H5N CarcinogenL-PYROGLUTAMIC ACID Y 98-79-3 C5H7NO3 Nitrogen compound, no available environmental dataPYRROLIDINE Y 123-75-1 C4H9NO Low aq toxicity2-PYRROLIDONE R 616-45-5 C4H7N High aq toxicityPYRUVIC ACID Y 127-17-3 C3H4O3 Low fish tox, no additional info availableQUINIDINE, ANHYDROUS Y 56-54-2 C20H24N2O2 No available environmental data

SILICA GEL G 63231-67-4 SiO2 Applies only if the material is not airborne.SILICA GEL GRADE 62 G 112926-00-8 SiO2 Applies only if the material is not airborne.SILVER NITRATE R 7761-88-8 AgNO3 Low CERCLA RQSODIUM ACETATE ANHYDROUS G 127-09-3 C2H3NaO2 High biodeg, low aq toxicitySODIUM ACETATE TRIHYDRATE G 6131-90-4 C2H3NaO2.3H2O Follow classification of its anhydrous cmpdSODIUM ASCORBATE Y 134-03-2 C6H7NaO6 No available environmental dataSODIUM BICARBONATE G 144-55-8 NaHCO3 No known environmental issuesSODIUM BISULFITE Y 7631-90-5 NaHSO3 Medium aq toxicitySODIUM BOROHYDRIDE Y 16940-66-2 NaBH4 Boron compoundSODIUM CARBONATE ANHYDROUS G 497-19-8 Na2CO3 No known environmental issuesSODIUM CARBONATE MONOHYDRATE G 5968-11-6 Na2CO3 No known environmental issuesSODIUM CHLORIDE G 7647-14-5 NaCl No known environmental issuesSODIUM CITRATE G 68-04-2 NaC6H8O7 High biodeg, low aq toxicitySODIUM CYANIDE R 143-33-9 NaCN Low CERCLA RQ, high toxicity

SODIUM HEXAMETHYLDISILIZANE Y 1070-89-9 C6H18NNaSi2SODIUM HYDROXIDE SOLUTION 25% G 1310-73-2 NaOH Limited use onlySODIUM HYPOCHLORITE SOLUTION (5 - 15%) Y 7681-52-9 NaOCl Limited use onlySODIUM METABISULFITE Y 7681-57-4 Na2S2O5 Medium aq toxicitySODIUM METHYLATE Y 124-41-4 NaCH3O Decomposes to methanolSODIUM PERIODATE Y 7790-28-5 NaIO4 No available environmental dataSODIUM PERMANGANATE R 79048-36-5 MnNaO4 Follow classification for other permanganatesSODIUM PHOSPHATE, DIBASIC Y 10039-32-4 Na2HPO4.12H2O Enhances eutrophicationSODIUM PHOSPHATE, DIBASIC Y 10140-65-5 Na2HPO4.2H2O Enhances eutrophicationSODIUM PHOSPHATE MONOBASIC MONOHYDRATE Y 10049-21-5 NaH2PO4.H2O P compound, low aq toxicity


14 of 22 09-Dec-2009



HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TSODIUM PHOSPHATE, TRIBASIC Y 7601-54-9 Na3O4P Enhances eutrophicationSODIUM PHOSPHATE, TRIBASIC Y 7758-29-4 Na5P3O10 Enhances eutrophicationSODIUM PHOSPHATE, TRIBASIC Y 10124-56-8 Na3O4P.12H2O Enhances eutrophicationSODIUM SULFATE G 7757-82-6 Na2O4S Low aq toxicitySODIUM SULFATE DECAHYDRATE G 7727-73-3 Na2O4S No known environmental issuesSODIUM SULFITE ANHYDROUS G 7757-83-7 Na2SO3 Low aq toxicitySODIUM THIOSULFATE ANHYDROUS G 7772-98-7 Na2S2O3 Follow class for 10102-17-7SODIUM THIOSULFATE PENTAHYDRATE G 10102-17-7 Na2S2O3.5H2O Low aq toxicitySODIUM TRIACETOXYBOROHYDRIDE Y 56553-60-7 C6H10BNa2O6 No known environmental issuesSQUARIC ACID Y 2892-51-5 C4H2O4 No available environmental dataSULFAMIC ACID Y 5329-14-6 SH3NO3 Sulfur compound, med aq toxicitySULFURIC ACID G 7664-93-9 H2SO4 Limited use onlyD-TARTARIC ACID G 147-71-7 C4H6O6 Used as food additiveL-TARTARIC ACID G 87-69-4 C4H6O High biodeg, used as food additiveTEMPO Y 2564-83-2 C9H18NO N compound, med aq toxicityTERT-BUTYL N-(2-AMINOETHYL)CARBAMATE Y 57260-73-8 C7H16N2O2 N compound, no available environmental dataTETRABUTYLAMMONIUM FLUORIDE TRIHYDRATE Y 87749-50-6 C16H36FN.3H2O N, F compound, no env dataTETRABUTYLAMMONIUM HYDROGEN SULFATE Y 32503-27-8 C16H37NO4S Nitrogen and sulfur compound, no available environmental dataTETRACHLOROETHYLENE R 127-18-4 C2Cl4 CarcinogenTETRAETHYLENE GLYCOL Y 112-60-7 C8H18O5 No available environmental dataTETRAETHYL SILICATE Y 78-10-4 C8H20O4Si Silicon compoundTETRAHYDROFURAN (THF) R 109-99-9 C4H8O Mutagen/ReprotoxTETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM Y 14221-01-3 C72H60P4Pd Pd and P compound, no env dataTETRAMETHYLENE SULFONE Y 126-33-0 C4H8O2S Low biodeg, low aq toxicityTETRAMETHYL ETHYLENEDIAMINE Y 110-18-9 C6H16N2 No available environmental dataTHIOANISOLE Y 100-68-5 C7H8S Sulfur compound, no env info availableTHIONYL CHLORIDE Y 7719-09-7 Cl2OS Halogenated, no available environmental data 250TITANIUM TETRACHLORIDE R 7550-45-0 TiCl4 High aq toxicity, heavy metalTOLUENE Y 108-88-3 C7H8 Some bioaccumulation, CERCLA RQP-TOLUENE SULFONIC ACID Y 104-15-4 C7H8O3S Sulfur compound. Follow classification of 6192-52-5P-TOLUENE SULFONIC ACID MONOHYDRATE Y 6192-52-5 C7H78O3S.H2O Sulfur compoundP-TOLUENESULFONYL CHLORIDE Y 98-59-9 C7H7ClO2S Sulfur compoundTRICHLOROACETIC ACID (TCA) R 76-03-9 C2HCl3O2 High aq toxicity1,1,1-TRICHLOROETHANE R 71-55-6 C2H3Cl3 CarcinogenTRICHLOROETHYLENE (TCE) R 79-01-6 C2HCl3 CarcinogenTRICHLOROPHENYLSILANE Y 98-13-5 C6H5Cl3Si Halogenated, silicon compoundTRIETHYLAMINE (TEA) R 121-44-8 C6H15N High aq toxicityTRIETHYLENE GLYCOL G 112-27-6 C6H14O4 High biodeg, low aq toxicityTRIETHYL ORTHOFORMATE G 122-51-0 C7H16O3 Medium biodeg, low aq toxicity


15 of 22 09-Dec-2009



HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TTRIETHYL PHOSPHITE Y 122-52-1 C6H15O3P Medium biodeg, low to med aq toxicity, organophosphorusTRIETHYLSILANE Y 617-86-7 C6H16Si Silicon compound, no env dataTRIFLUOROACETIC ACID Y 76-05-1 C2H3F3O2 Halogenated, not biodegradableTRIFLUOROACETIC ANHYDRIDE Y 407-25-0 C4F6O3 Halogenated, no available environmental dataTRIFLUOROMETHANESULFONIC ANHYDRIDE Y 358-23-6 C2F6O5S2 Halogenated, no available environmental data3-(TRIFLUOROMETHYL)-BENZENAMINE R 98-16-8 C7H6F3N Low biodeg, high aq toxicity

Y 98-08-8 C7H5F3 Medium aq toxicityTRIISOPROPYL BORATE Y 5419-55-6 C19H21BO3 No available environmental dataTRIMETHYLACETIC ACID Y 75-98-9 C3H10O2 Low biodeg, low aq toxicity

TRIMETHYLACETYL CHLORIDE Y 3282-30-2 C5H9ClO High biodeg, medium aq toxicityTRIMETHYLALUMINUM Y 75-24-1 C3H9Al No available environmental dataTRIMETHYLBOROXINE Y 823-96-1 C3H9B3O3 B compound, no env dataTRIETHYLENE GLYCOL DIMETHYL ETHER (TGDME) R 112-49-2 C8H18O4 TeratogenTRIMETHYL ORTHOFORMATE G 149-73-5 C4H10O3 Medium biodeg, low aq toxicity2,2,4-TRIMETHYLPENTANE Y 540-84-1 C8H18 Regulated, low aq toxicityTRIMETHYLSILYL TRIFLUOROMETHANE SULFONA Y 27607-77-8 C4H9F3O3SSi Si, F, S compound, no env dataTRIMETHYLSYLNITRILE R 7677-24-9 C4H9NSi Decomposes to HCN TRI-N-ETHYL-ORTHOPROPIONATE Y 115-80-0 C9H20O3 No available environmental dataTRIPHENYL METHYL CHLORIDE Y 76-83-5 C19H15Cl High aq toxicity, but insolubleTRIPHENYLPHOSPHINE HYDROBROMIDE Y 6399-81-1 C18H15P.BrH Phosphorus compound, no env info availableTRIPHOSGENE Y 32315-10-9 C3Cl6O3 No available environmental dataTRITHIOCYANURIC ACID Y 638-16-4 C3H3N3S3 No available environmental dataUREA HYDROGEN PEROXIDE Y 124-43-6 CH4N2O.H2O2 Suspected carcinogen, no env data

VALDERALDEHYDE Y 110-62-3 C5H10O Low biodegVINYL ACETATE Y 108-05-4 C4H6O2 SC, med biodeg, medium aq toxicityVINYL BUTYRATE Y 123-20-6 C6H10O2 No available environmental dataASCORBIC ACID G 50-81-7 C6H8O6 No known environmental issuesWATER G 7732-18-5 H2O No known environmental issuesXYLENE (MIXED ISOMERS) R 1330-20-7 C8H10 High aq toxicityO-XYLENE R 95-47-6 C8H10 High aq toxicityZINC (POWDER) Y 7440-66-6 Zn Insoluble as element, high aq toxicity in soluble formZINC CHLORIDE R 7646-85-7 ZnCl2 High aq toxicity

α-α-α-TRIFLUOROTOLUENE

document.xls/FullGuide

16 of 22 09-Dec-2009

NAME CAS ThOD Drivers ( EG HAPFORMALDEHYDE R 50-00-0 CH2O Carcinogen 1000 5 - 50 1.04 M 0 1.068 56.11 3 4 0 M H M M RC 4 C,Z Human carcinog X 100 15,000 XASCORBIC ACID G 50-81-7 C6H8O6 No known environmental issues 1.65 0.33 -1.85 None 0 0 1 1 Practically non-toxicPIPERONYL BUTOXIDE Y 51-03-6 C19H30O5 Medium biodeg, med aq toxicity 1.059 0.000143 4.7 130 2 1 1 M M SC 2 Carcinogen classification (IARC-3); irritating to eyes, skin and mucous membranes; reprod2-AMINO-4,6-DIHYDROXYPY Y 56-09-7 C4H5N3O2No available environmental data 1.65 0.02N-(3-AMINOPROPYL)-1,3-P Y 56-18-8 C6H17N3 No available environmental data 0.938 79 3 2 0CARBON TETRACHLORIDE R 56-23-5 CCl4 Carcinogen 1.59 0.116 2.64 0.21 None 3 0 0 L L L L RC X 10 T X BQUINIDINE, ANHYDROUS Y 56-54-2 C20H24N2 No available environmental data 2 0 1GLYCEROL G 56-81-5 C3H8O3 No known environmental issues 1.261 M -2.66 1.217 160 1 1 0 H L L L 1 Practically non-irritating and non-toxic1,1-DIMETHYL HYDRAZINE R 57-14-7 C2H8N2 Carcinogen 1000 0.785 M -17 4 3 1 M RC X 10 15,000 TPROPYLENE GLYCOL G 57-55-6 C3H8O2 Medium biodeg, low aq toxicity 1.036 M -1.41 1.685 107 0 1 0 M L L L 1 Practically non-irritating and non-toxicBETA-PROPIOLACTONE R 57-57-8 C3H4O2 Carcinogen, low CERCLA RQ 1.146 37 0.46 70 4 2 1 RC 4 C,S Highly toxic X 10 TPHENYLHYDRAZINE R 59-88-1 C6H8N2 Carcinogen 1.09 -2.27 3 0 0

PHENYLETHYL ALCOHOL G 60-12-8 C8H10O High biodeg, low aq toxicity 1.02 2 1.38 102 2 1 0 H L L L 3 S Severely irritating to eyes and mucous membranes; toxicity from skin absorptionMERCAPTOETHANOL R 60-24-2 C2H7OS High aq toxicity 1.12 M -0.056 77 3 2 1 L M L HETHYL ETHER R 60-29-7 C4H10O Low CERCLA RQ, low biodeg 0.706 6.9 0.77 2.6 -40 1 4 1 L L L L 3 Acute toxicity (inhala 100 10,000METHYL HYDRAZINE R 60-34-4 CH6N2 Carcinogen 100 0.86 M 21 3 4 0 H RC X 10 15,000 TETHYL METHANESULFONA R 62-50-0 C3H8O3S Carcinogen 1.17 0.09 100 2 1 1 RC 1ANILINE R 62-53-3 C6H7N Carcinogen 1.022 3.8 0.9 3.09 70 3 2 0 L M H M RC X 5,000 XETHANOL G 64-17-5 C2H6O No known environmental issues 0.794 M -0.32 2.1 16 0 3 0 H L L L 2 Eye irritation, Repro/Developmental effects at high dosesFORMIC ACID Y 64-18-6 CH2O2 High biodeg, low to med aq toxicity 1.22 M -0.54 0.35 68 3 2 0 H M M L 5,000ACETIC ACID G 64-19-7 C2H4O2 High biodeg, low to med aq toxicity, upgraded to green 1.049 M -0.31 1.07 40 3 2 0 H L M L 5,000METHYL METHANESULFON R 66-27-3 C2H6O3S Carcinogen 1.3 104 2 0 0 RCBARBITURIC ACID Y 67-52-7 C4H4N2O3No available environmental data 1.145 -1.47 2 1 0METHANOL Y 67-56-1 CH4O Toxic, med biodeg 500 - 5000 0.791 M -0.82 1.5 11 1 3 0 M L L L 3 S Toxic (R23 X X 5,000 XISOPROPYL ALCOHOL (IPA) G 67-63-0 C3H8O No known environmental issues 0.785 M -0.16 2.4 11 1 3 0 H L L L 2 CarcinogenXACETONE G 67-64-1 C3H6O High biodeg, low to med aq toxicity, upgraded to green 0.791 M -0.24 2.2 -17 1 3 0 H L L M 2 Irritant (R X 5,000CHLOROFORM R 67-66-3 CHCl3 Carcinogen 1.492 0.82 1.97 0.33 None 2 0 0 M L M L RC 4 S CarcinogenX X 10 20,000 T X BDIMETHYL SULFOXIDE (DM G 67-68-5 C2H6OS High biodeg, low aq toxicity 1.101 M -2.03 85 0 2 1 H L L L 2 Irritatin XSODIUM CITRATE G 68-04-2 NaC6H8O7High biodeg, low aq toxicity 1.7 0.0425 -0.28 0 0 0 H LN,N-DIMETHYLFORMAMIDE R 68-12-2 C3H7NO Teratogen, low CERCLA RQ 0.944 M -0.85 1.863 57 1 2 0 H L L L RC 3 Developmental X 100 X1-PROPANOL G 71-23-8 C3H8O High biodeg, low to med aq toxicity, upgraded to green 0.804 M 0.35 2.4 15 1 3 0 H L L M1-BUTANOL R 71-36-3 C4H10O Medium biodeg, high protozoa toxicity 0.81 7.45 0.88 2.59 35 1 3 0 M L L H 4 C Corrosivity 5,0001-PENTANOL G 71-41-0 C5H12O High biodeg, low to med aq toxicity, upgraded to green 0.811 2.6 1.4 2.73 48 1 3 0 H M L LBENZENE R 71-43-2 C6H6 Carcinogen 0.874 1.78 2.13 3.1 -11 2 3 0 H H L L RC 4 S Cancer; a X X 10 T X G1,1,1-TRICHLOROETHANE R 71-55-6 C2H3Cl3 Carcinogen 1.338 0.13 2.47 None 2 1 0 H M L RC X 1,000 T X G5-AMINOIMIDAZOLE-4-CAR Y 72-40-2 C4H6N4O.HNo available environmental data 0.0188 1.02 0 0 0 3METHYL BROMIDE Y 74-83-9 CH3Br Halogenated, hydrolyzes to methanol 2500 1.73 0.09 M X 1,000 XMETHYL CHLORIDE R 74-87-3 CH3Cl Low CERCLA RQ 15000 0.99 0.4 0.91 L L L SC X 100 10,000 XMETHYL IODIDE R 74-88-4 CH3I Carcinogen 7500 2.28 1.4 1.68 None 3 0 1 RC X 100 XMETHYLAMINE R 74-89-5 CH5N Low CERCLA RQ 1,000 0.77 1.1539 0.57 M M L 3 S Acute toxicity (inhala 100 10,000METHYL MERCAPTAN R 74-93-1 CH4S Low CERCLA RQ 5000 0.87 17 4 4 0 H 100 10,000METHYLENE BROMIDE Y 74-95-3 CH2Br2 CERCLA RQ, halogenated 2.477 0.0001 None 2 1 0 1,000ETHYL CHLORIDE R 75-00-3 C2H5Cl Carcinogen, low CERCLA RQ 0.92 0.574 1.54 -50 2 4 0 L H M RC X 100 10,000 XETHYLAMINE R 75-04-7 C2H7N High aq toxicity 7,500 0.71 M -0.27 -37 2 4 1 H M M 100 10,000ACETONITRILE Y 75-05-8 C2H3N High biodeg, low aq toxicity, metabolizes to CN- 0.786 M -0.34 6 2 3 0 H L L L 3 S Rat LD50; X X 5,000 XACETALDEHYDE R 75-07-0 C2H4O Carcinogen 2500 0.783 M 0.43 1.82 L M M RC X 1,000 10,000 XDICHLOROMETHANE R 75-09-2 CH2Cl2 Carcinogen 1.325 2 1.25 None 2 1 1 H L L RC 3 S CarcinogenX X 1,000 T X GFORMAMIDE R 75-12-7 CH3NO Teratogen, miscible and low biodeg 1.134 M -1.51 154 2 1 1 L 3 S Severely irritating to eyes and mucous membranes; reproductive or developmental toxicity;METHYLMAGNESIUM BROM Y 75-16-1 CH3BrMg Halogenated, no available environmental data 1.018 3 2DIMETHYL SULFIDE Y 75-18-3 C2H6S Odor 0.846 0.63 -36 2 4 0TRIMETHYLALUMINUM Y 75-24-1 C3H9Al No available environmental data 0.81 M 4 3 3 4 W 4 C,S Corrosive; toxicity from skin absorption2-CHLOROPROPANE Y 75-29-6 C3H7Cl Halogenated, SC 0.86 0.31 -21 2 3 1 SC 10,000ISOPROPYLAMINE R 75-31-0 C3H9N High aq toxicity 5000 0.694 M -0.03 -32 3 4 0 M H M M 10,000NITROMETHANE R 75-52-5 CH3NO2 Carcinogen 2500 1.127 10 0.17 35 1 3 4 M L L RCPROPYLENE OXIDE R 75-56-9 C3H6O Carcinogen 5 - 50 0.83 40.5 -37 3 4 2 M RC X 100 10,000 XT-BUTANOL Y 75-65-0 C4H10O Low biodeg, low aq toxicity 0.775 M 0.37 2.59 11 1 3 0 L L L L 2 S Harmful (inhalation); irritating to eyes, skin and respiratory system; carcinogen classificaDICHLOROMETHYLSILANE Y 75-74-7 CH4Cl2Si Halogenated, silicon compound 1.105 M -26METHANESULFONIC ACID Y 75-75-2 CH4O3S High biodeg, med aq toxicity 1.481 M -2.38 189 3 1 0 H M M MCHLOROTRIMETHYL SILAN Y 75-77-4 C3H9ClSi Halogenated, no available environmental data 0.856 M -27 3 3 2 SCT-AMYL ALCOHOL Y 75-85-4 C5H12O Low biodeg 0.805 9 0.89 21 1 3 0 L L L LACETONE CYANOHYDRIN R 75-86-5 C4H7NO CERCLA RQ, high aq toxicity 0.93 75 4 2 2 H 4 S Acute toxicity (inhala 10 GTRIMETHYLACETIC ACID Y 75-98-9 C3H10O2 Low biodeg, low aq toxicity 0.889 1.559 1.5 2.04 64 3 2 0 L L L LTRICHLOROACETIC ACID (T R 76-03-9 C2HCl3O2 High aq toxicity 1.617 93 1.645 113 3 0 1 M H L L SC 4 C Corrosive, Note: Carcinogen classification (TLV-A3, EPA-C)TRIFLUOROACETIC ACID Y 76-05-1 C2H3F3O2 Halogenated, not biodegradable 1.48 M -2.1 None 3 0 1 L M 4 C Corrosive TRIPHENYL METHYL CHLO Y 76-83-5 C19H15Cl High aq toxicity, but insoluble 0 3 1 0DIMETHYL SULFATE (DMS) R 77-78-1 C6H6O4S Carcinogen 1.33 2.8 0.032 83 4 2 0 M M H M RC X 100 TCITRIC ACID ANHYDROUS G 77-92-9 C6H8O7 High biodeg, low aq toxicity 1.542 M -1.72 0.686 None 2 0 0 H L L L 3 Severe eye irritantTETRAETHYL SILICATE Y 78-10-4 C8H20O4SiSilicon compound 0.933 M 37 2 3 1ISOBUTANOL G 78-83-1 C4H10O Toxic, high biodeg, low aq toxicity, upgraded to green 0.803 8.7 0.65 2.6 27 1 3 0 H L L L 5,0002-BUTANOL G 78-92-2 C4H10O High biodeg, low aq toxicity 0.808 19.8 0.61 2.59 26 1 3 0 H L LMETHYL ETHYL KETONE (M Y 78-93-3 C4H8O Medium biodeg, low aq toxicity, CERCLA RQ 0.805 26 0.26 2.44 -3 1 3 0 M L L L 2 S Harmful (inhalat X 5,000 XMETHYL VINYL KETONE R 78-94-4 C4H6O High aq toxicity 100 0.864 10 0.12 -7 3 3 0 L HTRICHLOROETHYLENE (TCE R 79-01-6 C2HCl3 Carcinogen 1.463 0.11 2.42 None 2 1 0 H L M L RC X 100 T X BCHLOROACETYL CHLORID Y 79-04-9 C2H2Cl2O Halogenated, no available environmental data 1.4 M 41 4 C,S Corrosive; toxic by chronic exposure (inhalation); TLV qairborne exposure limit; toxicity b

GC Class

Chemical Formula

Green Chemistry Classification Reason(s)

HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TDensity

g/mL

Solub. in Waterwt%

Log Poct

Flash Point

°CNFPA Health

NFPA Flamm

NFPA React

NFPA Other

BiodegH > 80%

M - 50 - 80%L < 50%

Aq. Tox AlgaeH < 10 mg/L

Aq Tox FishM = 10 - 100

mg/L

Aq Tox ProtozoaL > 100

mg/L

CarcinogenRC = Recog.SC = Susp.

S-P HHC

Notation (HHC)

CERCLA RQ

CAA 112(r) TQ

NJAC 7:27-8 Table B HAPST < 200 lb RQX > 200 lb RQ

NJAC 7:27-7TXS

EUG = GreyB = Black


17 of 22 09-Dec-2009

NAME CAS ThOD Drivers ( EG HAPGC



HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TDensity

g/mL

Solub. in Waterwt%

Log Poct

Flash Point

°CNFPA Health

NFPA Flamm

NFPA React

NFPA Other

BiodegH > 80%

M - 50 - 80%L < 50%



mg/L


mg/L


S-P HHC

Notation (HHC)

CERCLA RQ

CAA 112(r) TQ


NJAC 7:27-7TXS

EUG = GreyB = Black

PROPIONIC ACID Y 79-09-4 C3H6O2 Medium biodeg, med aq toxicity 0.992 M 0.25 54 3 2 0 M M M M 5,000CHLOROACETIC ACID R 79-11-8 C2H3ClO2 Low CERCLA RQ 1.58 M 0.2 126 H H M H X 100 T GMETHYL ACETATE Y 79-20-9 C3H6O2 Follows methanol classification 0.932 24.5 0.18 -9 1 3 0 H L L LPERACETIC ACID Y 79-21-0 C2H4O3 High biodeg, low to med aq toxicity 1,000 1.09 M 41 4 2 4 H M L 4 C Corrosivity 10,000METHYL CHLOROFORMATE R 79-22-1 C2H3ClO2 Low CERCLA RQ 500 1.228 10 3 3 0 1,000 5,000ISO-BUTYRIC ACID Y 79-31-2 C4H8O2 Medium biodeg, med aq toxicity 0.949 16 0.88 55 3 2 0 M M L M 5,000OXALYL CHLORIDE Y 79-37-8 C2Cl2O2 Chlorinated, toxic 1.455 M <1 None 3 0 2 W 4 C Acute toxicity; corrosiveETHYL P-TOLUENESULFON Y 80-40-0 C9H12O3S Sulfur compound, no env info available 1.174 158 2 0 0METHYL P-TOLUENESULFO Y 80-48-8 C8H10O3S Sulfur compound, no env info available 1.23 113 3 1 01,3-DIMETHYL-2-IMIDAZOL Y 80-73-9 C5H10N2O No available environmental data 102 2 1 0DIPHENYLCARBAMOYL CHL Y 83-01-2 C13H10ClNNo available environmental data 3 0 1DIBUTYL PHTHALATE R 84-74-2 C16H22O4 Low CERCLA RQ 1.05 0.04 4.57 2.24 160 H H H H 3 Reproductive or X 10 X3-NITROSALICYLIC ACID Y 85-38-1 C7H5NO5 No available environmental data 2 0 01-HYDROXY-2-NAPHTHOIC Y 86-48-6 C11H9O3 No available environmental data 150L-TARTARIC ACID G 87-69-4 C4H6O High biodeg, used as food additive 1.76 M -0.76 None 1 1 0 H 2 Irritating to eyes, skin and respiratory system1-CHLORO-2-NITROBENZE Y 88-73-3 C6H4ClNO Halogenated, nitrogen compound 1.348 0 2.24 124 2 1 0 H G

4-CHLORO-2-NITROTOLUE Y 89-59-8 C7H6ClNO Halogenated, nitrogen compound 0.0109 120 2 1 0 GO-CHLOROBENZALDEHYDE Y 89-98-5 C7H5Cl Medium biodeg, med aq toxicity 1.25 0.1117 2.33 87 3 2 0 M M

1-CHLORONAPHTHALENE Y 90-13-1 C10H7Cl Halogenated compound 1.194 121 2 1 0 H GBENZOYL PEROXIDE R 94-36-0 C14H10O4 Mutagen 7,500 2 4 4 OX(4-CHLORO-2-METHYLPHEN Y 94-74-6 C9H9ClO3 Low solubility, med to high aq toxicity 0.073 2 0 0 H M GO-XYLENE R 95-47-6 C8H10 High aq toxicity 0.88 0.0175 2.77 3.125 31 2 3 0 M H L 2 S Irritant ( X X 1,000 X G1,2-DICHLOROBENZENE R 95-50-1 C6H4Cl2 Low CERCLA RQ, high fish toxicity 1.306 0.01 3.38 2.92 65 2 2 1 M H M X 100 G

2-CHLOROANILINE R 95-51-2 C6H6ClN High aq toxicity 1.212 0.8165 1.9 104 H H H G2-CHLOROPHENOL R 95-57-8 C6H5ClO Low CERCLA RQ 1.24 2.85 2.15 85 3 2 0 H M H H 100 G

2-AMINO-4-CHLOROPHENO Y 95-85-2 C6H6ClNO Nitrogen compound, no available environmental data 2 1 1 G3-PENTANONE G 96-22-0 C5H10O Medium biodeg, low aq toxicity 0.813 5 0.85 2.6 6 2 3 0 M L L L2-METHYL TETRAHYDROF G 96-47-9 C5H10O Almost insoluble, no known env impact, upgrade to green 0.853 0.0000641 -12 0 3 0ETHYLENE CARBONATE Y 96-49-1 C3H4O3 High biodeg, low aq tox. However, it converts to ethylene g 1.321 5.56 -0.339 143 2 1 1 H L

1-CHLORO-2,4-DINITROBE Y 97-00-7 C6H3ClN2OHalogenated compound 1.52 0.036 2.1 194 H H GFURFURAL R 98-01-1 C5H4O2 Suspected carcinogen, high aq toxicity 1.16 8.3 0.41 1.66 58 3 2 0 H H H H SC 5,000

Y 98-08-8 C7H5F3 Medium aq toxicity 1.19 12 3 3 1 MBENZENESULFONYL CHLOR R 98-09-9 C6H5ClO2SLow CERCLA RQ 1.377 132 3 1 1 100TRICHLOROPHENYLSILANE Y 98-13-5 C6H5Cl3Si Halogenated, silicon compound 1.3213-(TRIFLUOROMETHYL)-BE R 98-16-8 C7H6F3N Low biodeg, high aq toxicity 1.3 0.5 2.3 87 L M H GP-TOLUENESULFONYL CHL Y 98-59-9 C7H7ClO2SSulfur compound 0 128 3 0 1 L 4 C Corrosivity4-CHLOROBENZENESULFON Y 98-60-2 C6H4Cl2O5No available environmental data 0.7 0 107 3 1 24-METHOXYBENZENE SULF Y 98-68-0 C7H7ClO3SNo available environmental data M 112L-PYROGLUTAMIC ACID Y 98-79-3 C5H7NO3 Nitrogen compound, no available environmental data 47.6 -0.72 2 0 0

ALPHA, ALPHA-DICHLORO R 98-87-3 C7H6Cl2 Carcinogen 1.254 88 SC 5,000 GBENZOYL CHLORIDE Y 98-88-4 C7H5ClO Halogenated, low to med aq toxicity 1.22 M 2.2 72 2 1 2 H M L SC 1,000N,N-DIMETHYLCYCLOHEXY R 98-94-2 C8H17N High aq toxicity 0.849 2 2.01 39 M H M MNITROBENZENE R 98-95-3 C6H5NO2 Carcinogen 1.2 0.19 1.85 1.95 87 3 2 1 H M M M RC X 1,000 X3-CHLOROACETOPHENONE Y 99-02-5 C8H7ClO No available environmental data 1.198 1052-AMINO-4-NITROPHENOL Y 99-57-0 C6H6N2O3No available environmental data 100 2 0 0P-HYDROXYACETOPHENO Y 99-93-4 C8H8O2 No available environmental data 1.109 1 1 0ETHYLBENZENE R 100-41-4 C8H10 Carcinogen 0.867 0.0152 3.15 3.17 22 2 3 0 L H M L RC 3 Carcinogen clas X 1,000 X GBENZYL AMINE R 100-46-9 C7H9N Inhibitory to biomass, high aq toxicity 0.98 M 1.09 60 2 2 1 L H L MBENZYL ALCOHOL Y 100-51-6 C7H8O Medium biodeg, low to med aq toxicity 1.045 3.5 1.1 2.52 93 2 1 0 M M L 3 Acute toxicity (inhalation); severely irritating to eyes and mucous membranesBENZALDEHYDE R 100-52-7 C7H6O High aq toxicity 1.044 3.3 1.48 2.42 62 2 2 0 H M H H 3 S,Z WEEL airborne standard; toxicity from skin absorption; skin sensitizer (moderate)PHENYLHYDRAZINE R 100-63-0 C6H8N2 Carcinogen 1.098 14.5 1.9 86 2 2 0 H H H RCANISOLE G 100-66-3 C7H8O Insoluble in water, bioaccumulates, biodeg in soil 0.995 0 2.04 2.52 51 1 2 0 LTHIOANISOLE Y 100-68-5 C7H8S Sulfur compound, no env info available 1.057 72 1 2 02-CYANOPYRIDINE R 100-70-9 C6H4N2 High aq toxicity 1.081 5.12 0.23 89.4 2 2 0 H LHEXAMETHYLENE TETRAM Y 100-97-0 C6H12N4 Low biodeg 1.33 89.5 -2.84 2.054 250 3 2 0 L L L LANILAZINE R 101-05-3 C9H5Cl3N4High aq toxicity 1.7 0 3.88 None 2 0 0 H H HDICYCLOHEXYLAMINE R 101-83-7 C12H23N High aq toxicity 0.91 0.1 -0.4 95 3 1 H H M MDIPHENYL ETHER Y 101-84-8 C12H10O Almost insoluble, high biodeg, high aq toxicity 1.07 0.0018 4.21 115 2 1 0 H H HP-TOLUENE SULFONIC ACI Y 104-15-4 C7H8O3S Sulfur compound. Follow classification of 6192-52-5 M 0.9 H L L L 3 Severe irritation2-ETHYLHEXANOL Y 104-76-7 C8H18O No available environmental data 0.853 81 2 2 04-CHLOROBENZOYL CHLOR Y 104-83-6 C7H6Cl2 No available environmental data 1.377 108ANISYL ALCOHOL Y 105-13-5 C8H10O2 No available environmental data 1.108 113 1 1 0SEC-BUTYL ACETATE Y 105-46-4 C6H12O2 Follow classification of other butyl acetates 0.872 3 16 X 5,0004-CHLOROTHIOPHENOL Y 106-54-7 ClC6H4SH No available environmental data 1.1911 > 110 3 2 0EPICHLOROHYDRIN R 106-89-8 C3H5ClO Carcinogen, low CERCLA RQ 1.18 6.6 0.45 28 3 2 1 M H M M RC X 100 20,000 X GALLYL BROMIDE R 106-95-6 C3H5Br High aq toxicity 1.43 0.4 1.79 -1 3 3 1 H1,2-DICHLOROETHANE (DC R 107-06-2 C2H4Cl2 Carcinogen 1.256 0.869 1.45 0.97 15 2 3 0 M L H L RC 4 CarcinogenX X 100 T X

2-CHLOROETHANOL Y 107-07-3 C2H5ClO Low biodeg 1.202 M 1.09 55 4 2 2 L GALLYL ALCOHOL R 107-18-6 C3H6O Low CERCLA RQ, high fish toxicity 0.854 M 0.17 2.2 22 4 3 1 M H 100 15,000ETHYLENE GLYCOL R 107-21-1 C2H6O2 Teratogen, mutagen 1.113 M -1.93 1.26 111 2 1 1 H L L L RC 2 Carcinogen classX 5,000 XMETHYL FORMATE Y 107-31-3 C2H4O2 High biodeg, low aq toxicity, CAA 0.974 33 -0.21 -26 1 4 1 H L L L X 10,000HEXYLENE GLYCOL Y 107-41-5 C6H14O2 Miscible, low biodeg, low aq toxicity 0.925 M -0.14 2.3 93 1 1 0 L L L 3 Severe eye irritationHEXAMETHYLDISILOXANE Y 107-46-0 C6H8OSi2 Silicon compound 0.764 3.1 0.6 0 3 1ISOHEXANE Y 107-83-5 C6H14 Toxic to aquatic life (R51/53) 0.653 -7 2 3 0

α-α-α-TRIFLUOROTOLUENE


18 of 22 09-Dec-2009




HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TDensity

g/mL

Solub. in Waterwt%

Log Poct

Flash Point

°CNFPA Health

NFPA Flamm

NFPA React

NFPA Other

BiodegH > 80%

M - 50 - 80%L < 50%



mg/L


mg/L


S-P HHC

Notation (HHC)

CERCLA RQ

CAA 112(r) TQ


NJAC 7:27-7TXS

EUG = GreyB = Black

1,3-BUTANEDIOL Y 107-88-0 C4H10O2 Miscible, low biodeg 1.005 M -0.29 121 0 1 1 L L LPROPYLENE GLYCOL METH G 107-98-2 C4H10O2 High biodeg, low aq toxicity 0.962 M -0.437 33 0 3 0 H L LVINYL ACETATE Y 108-05-4 C4H6O2 SC, med biodeg, medium aq toxicity 0.9317 2.3 0.21 -8 M M M M SC X 5,000 15,000 XMETHYL ISOBUTYL KETONE Y 108-10-1 C6H12O Medium biodeg, low aq toxicity, CERCLA RQ 0.8017 1.9 1.31 2.72 13 1 2 0 M L L L 2 S Harmful by X X 5,000 XMALONAMIDE Y 108-13-4 C3H6N2O2No available environmental dataISOPROPYL ETHER Y 108-20-3 C6H14O Low solubility, low biodeg, low to med aq toxicity 0.725 1.2 -1.52 2.833 -12 1 3 1 L M L L XISOPROPYL ACETATE (IPAC G 108-21-4 C5H10O2 Low half-life, low aq toxicity 0.872 2.9 1.03 16 1 3 0 L L L 2 Irritating XACETIC ANHYDRIDE G 108-24-7 C4H6O3 Follows Acetic Acid classification 1.082 M -0.2 54 3 2 1 W H L L L 4 C Corrosivity 5,000PROPYLENE CARBONATE G 108-32-7 C3H6O3 High biodeg, low aq toxicity 1.189 21 -0.48 132 2 1 1 H L L L3-BROMOCHLOROBENZEN Y 108-37-2 C6H4BrCl No available environmental data 1.63 0 80 1 2 02,6-LUTIDINE Y 108-48-5 C7H9N Nitrogen compound, no available environmental data 0.923 1.6 37 2 S Harmful (inhalation, dermal, oral); irritating to eyes, skin and respiratory system; toxicity DIMETHYL MALONATE Y 108-59-8 C5H8O4 Medium aq toxicity 1.154 9 0.2 90 MPROPYLENE GLYCOL METH G 108-65-6 C6H12O2 Medium biodeg, low aq toxicity 0.968 19.8 0.43 43 2 2 0 M L LDIISOBUTYL KETONE Y 108-83-8 C9H18O No available environmental data 0.808 0.05 45 2 2 0BROMOBENZENE Y 108-86-1 C6H5Br Halogenated. Med fish toxicity 1.491 0.05 2.99 51 2 2 0 MMETHYL CYCLOHEXANE Y 108-87-2 C7H14 Almost insoluble, med aq toxicity, follow cyclohexane 0.77 0.0014 -3 2 3 0 MTOLUENE Y 108-88-3 C7H8 Some bioaccumulation, CERCLA RQ 0.865 0.0515 2.69 3.13 4 2 3 0 H L M L 3 S Harmful by X X 1,000 X GCHLOROBENZENE R 108-90-7 C6H5Cl Low CERCLA RQ, high fish toxicity 1.107 0.049 2.84 2.06 23 2 3 0 L H L X X 100 X GCYCLOHEXANOL G 108-93-0 C6H12O High biodeg, med to low aq toxicity, upgraded to green 0.948 4.3 1.25 2.83 68 2 2 0 H M L LCYCLOHEXANONE G 108-94-1 C6H10O High biodeg, low aq toxicity, CERCLA RQ, upgraded to gre 0.947 2.3 0.81 2.6 46 1 2 0 H L L L 5,000N-METHYLMORPHOLINE Y 109-02-4 C5H11NO N compound, med biodeg, low aq toxicity 0.92 M -0.33 14 2 3 0 M L LPROPYL ACETATE Y 109-60-4 C5H12O2 Medium aq toxicity 0.888 2.3 1.39 12 1 3 0 M M LBORON TRIFLUORIDE DIET Y 109-63-7 C4H10BF3 Medium aq toxicity 1.13 0.77 64 3 2 1 M M MN-PENTANE Y 109-66-0 C5H12 Some bioaccumulation, almost insoluble, high aq toxicity 0.626 0.004 2.36 -49 1 4 0 H 10,000N-BUTYL CHLORIDE Y 109-69-3 C4H9Cl Halogenated, med biodeg, low aq toxicity 0.886 0.66 2.66 -17 2 3 0 M L L LN-BUTYLLITHIUM Y 109-72-8 C4H9Li No available environmental data 0.68 M -12.22 3 4 2 W 4 C,SBUTYLAMINE R 109-73-9 C4H11N Miscible, med to high aq toxicity 0.74 M 0.81 -14 3 3 0 M H M H 1,0002-METHOXYETHANOL R 109-86-4 C3H8O2 Teratogen, miscible and low biodeg 0.965 M -0.8 46 2 2 0 L L L L X XDIMETHOXYMETHANE (DMM G 109-87-5 C3H8O2 High biodeg, low aq toxicity 0.86 33 0 -17 1 3 0 H LDIETHYLAMINE (DEA) R 109-89-7 C4H11N Low CERCLA RQ, high algal toxicity, low biodeg 0.707 M 0.43 -28 3 3 0 L H M M 4 C,S Corrosivit X 100 GETHYL ISOCYANATE Y 109-90-0 No available environmental data 0.898TETRAHYDROFURAN (THF) R 109-99-9 C4H8O Mutagen/Reprotox 0.899 M 2.44 -17 2 3 3 L L L RC 3 S CarcinogenX 1,000MALEIC ACID Y 110-16-7 C4H4O4 Low biodeg, low aq toxicity 1.59 79 -0.79 0.83 100 2 0 0 L L L L 5,000FUMARIC ACID Y 110-17-8 C4H4O4 Low to med aq toxicity 1.635 0.7 0.33 0.827 273 2 0 0 M L M 5,000TETRAMETHYL ETHYLENED Y 110-18-9 C6H16N2 No available environmental data 0.77 M < 3 17.22 4 C Corrosive ISOBUTYL ACETATE (IBUOA G 110-19-0 C6H12O CERCLA RQ, upgraded to green 0.868 0.63 21 1 3 0 L L L 2 S Irritating X 5,0002-METHOXYETHYL ACETAT Y 110-49-6 C5H10O3 Low biodeg 1.009 M 0.121 43 2 2 0 LN-HEXANE Y 110-54-3 C6H14 High aq toxicity, but almost insoluble 0.659 0.00095 4 3.52 -23 1 3 0 H H H H 3 S Harmful by X X 5,000 X

VALDERALDEHYDE Y 110-62-3 C5H10O Low biodeg 0.82 M 1.4 4 2 3 0 L 3 Severely irritating to eyes and mucous membranes; positive mutagenicity/genotoxicity1,4-BUTANEDIOL G 110-63-4 C4H10O2 High biodeg, low aq toxicity 1.017 M 0.88 110 1 1 0 H L1,2-DIMETHOXYETHANE (D R 110-71-4 C4H10O2 Reprotox 0.867 M SC 3 S Reproductive or developmental toxicity (R60, R61); toxicity from skin absorption2-ETHOXYETHANOL R 110-80-5 C4H10O2 Teratogen, low CERCLA RQ 0.93 M -0.43 1.95 44 2 2 0 M L L L RC 1,000 XCYCLOHEXANE Y 110-82-7 C6H12 Medium CERCLA RQ, almost insoluble, high fish toxicity 0.779 0.0055 3.44 3.42 -18 2 3 0 H H M 2 Irritating to eyes, sk 1,000PYRIDINE R 110-86-1 C5H5N Carcinogen 0.978 M 0.64 2.23 20 3 3 0 M H H RC 3 S,P Carcinogen classifica 1,000[3,4]-DIHYDRO-2H-PYRAN ( Y 110-87-2 C5H8O Not readily biodegradable 0.922 2 0.69 -18 2 3 0 LPIPERIDINE Y 110-89-4 C5H11N Miscible, med aq toxicity 0.8622 M 0.84 16 3 3 0 M M 15,0001-HEXANOL Y 111-27-3 C6H14O Medium biodeg, low to med aq toxicity 0.814 0.58 2.03 60 1 2 0 M M L M2-(2-AMINOETHYLAMINO)E Y 111-41-1 C4H12N2O Low to med biodeg, low aq toxicity 1.03 M 132 3 1 0 L - M L L LDIETHYLENE GLYCOL R 111-46-6 C4H10O3 High aq toxicity 1.118 M -1.98 1.51 143 1 1 0 H L L H2-BUTOXYETHANOL Y 111-76-2 C6H14O2 Low to med aq toxicity, may form explosive peroxide 0.903 M 0.83 2.3 60 2 2 0 M L L XDIETHYLENE GLYCOL MET R 111-77-3 C5H12O3 Reprotox 1.01 M -1.14 83 2 2 0 H L L L SC 2 Reproductive or developmental toxicity (R63); irritating to eyes, skin and respiratory syst1-OCTANOL R 111-87-5 C8H18O Some bioaccumulation, high aq toxicity, low solubility 0.827 0.6 2.85 2.95 81 1 2 0 H H H MDIETHYLENE GLYCOL ETHY G 111-90-0 C6H14O3 High biodeg, low aq toxicity 0.999 M -0.43 1.91 96 1 1 0 H L L L 2 Irritating to eyes, skin and mucous membranes; reproductive or developmental toxicity; po2-METHOXYETHYL ETHER R 111-96-6 C6H14O3 Reprotox 0.937 M >2 70 1 2 1 M 3 S Reproductive or developmental toxicity (R60/R61); toxicity from skin absorptionDIETHYLENE GLYCOL ETHY Y 112-15-2 C8H16O4 Medium biodeg 1.012 M 95 1 1 0 MTRIETHYLENE GLYCOL G 112-27-6 C6H14O4 High biodeg, low aq toxicity 1.125 M -1.24 1.6 165 0 1 0 H L L LDIETHYLENE GLYCOL BUTY G 112-34-5 C8H18O3 No known environmental issues 0.953 0.56 99 2 0 0 L L LDIETHYLENE GLYCOL DIET Y 112-36-7 C8H18O3 Low biodeg 0.909 M 71 2 2 0 LTRIETHYLENE GLYCOL DIM R 112-49-2 C8H18O4 Teratogen 0.986 M -0.48 110 1 1 0 RCDIETHYLENE GLYCOL HEXY Y 112-59-4 C10H22O3 No available environmental data 0.935 M 140 2 1 0TETRAETHYLENE GLYCOL Y 112-60-7 C8H18O5 No available environmental data 1.125 M -1.38 2.23 176 1 1 02-METHYLPROPENE R 115-11-7 C4H8 Low CERCLA RQ 0.594 0.0263 2.11 -80 1 4 0 M 10,000TRI-N-ETHYL-ORTHOPROP Y 115-80-0 C9H20O3 No available environmental data 0.876 M 1.97 60 LMETHYL DICHLOROACETA Y 116-54-1 C3H4Cl2O2No available environmental data 1.378 64 4 C CorrosivityDI(2-ETHYLHEXYL) PHTHAL R 117-81-7 C24H38O4 Carcinogen 0.99 0.0000285 7.86 207 0 1 0 M L H H RC X 100 XCINCHONINE Y 118-10-5 C19H22N2 No available environmental data 0 2 0 11-METHYLPYRROLIDINE R 120-94-5 C5H11N High aq toxicity 0.819 M 3 3 3 0 HTRIETHYLAMINE (TEA) R 121-44-8 C6H15N High aq toxicity 0.726 13.3 1.44 -6 3 3 0 H M L 4 C,S Corrosivit X X 5,000 XN,N-DIMETHYLANILINE Y 121-69-7 C8N11N Low biodeg, low to med aq toxicity 0.96 0.12 2.31 2.64 75 L L M MTRIETHYL ORTHOFORMAT G 122-51-0 C7H16O3 Medium biodeg, low aq toxicity 0.89 0.135 1.2 29.44 2 3 0 M L 2 Irritating to eyes, skin and respiratory systemTRIETHYL PHOSPHITE Y 122-52-1 C6H15O3P Medium biodeg, low to med aq toxicity, organophosphorus 0.96 M 0.66 1.83 54 1 3 1 M L M 2 Harmful (inhalation, oral); irritating to eyes and skin BP-ANISALDEHYDE Y 123-11-5 C8H8O2 High biodeg, low to med aq toxicity 1.119 0.2 108 2 1 0 H M L MVINYL BUTYRATE Y 123-20-6 C6H10O2 No available environmental data 0.899 20CHOLINE HYDROXIDE Y 123-41-1 C5H15NO2No available environmental data 1.023 M 3 0 0

Note: Harmful by chronic exposure (inhalation, R48)


19 of 22 09-Dec-2009




HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TDensity

g/mL

Solub. in Waterwt%

Log Poct

Flash Point

°CNFPA Health

NFPA Flamm

NFPA React

NFPA Other

BiodegH > 80%

M - 50 - 80%L < 50%



mg/L


mg/L


S-P HHC

Notation (HHC)

CERCLA RQ

CAA 112(r) TQ


NJAC 7:27-7TXS

EUG = GreyB = Black

ISOAMYL ALCOHOL Y 123-51-3 C5H12O Low biodeg, low aq toxicity 0.809 3 1.16 2.74 45 2 2 0 L L L L 2 Harmful (inhalation, oral); irritating to eyes, skin and respiratory systemPYRROLIDINE Y 123-75-1 C4H9NO Low aq toxicity 0.866 M 0.22 3 3 3 0 L 4 C,S Corrosive; toxicity from skin absorption; MAK skin notationN-BUTYL ACETATE Y 123-86-4 C6H12O2 Medium biodeg, low to med aq toxicity 0.882 14 1.81 2.207 22 1 3 0 M L M L 3 Severely X 5,0001,4-DIOXANE R 123-91-1 C4H8O2 Carcinogen 1.034 M -0.42 12 2 3 1 L L L L RC 3 S Carcinogen clas X 100 T XISO-AMYL ACETATE Y 123-92-2 C7H14O2 Low to med aq toxicity 0.871 0.2 2.05 36 2 3 0 L M M X 5,000DIMETHYLAMINE Y 124-40-3 C2H7N Medium aq toxicity 0.68 M -0.38 2.006 -17 3 4 0 M M M 4 C,S Corrosive; toxicity f 1,000 10,000 GN-METHYL-METHANAMINE Y 124-40-3 C2H7N Medium aq toxicity 0.68 M -0.38 2.006 -17 3 4 0 M M M 4 C,S Corrosive; toxicity f 1,000 10,000 GSODIUM METHYLATE Y 124-41-4 NaCH3O Decomposes to methanol 0.97 33 3 4 2 W L L L 1,000UREA HYDROGEN PEROXI Y 124-43-6 CH4N2O.H Suspected carcinogen, no env data 1.4 easily sol 3 1 0 OX SCMETHANESULFONYL CHLO Y 124-63-0 CH3ClO2S High biodeg, med aq toxicity 1.48 0 -4.98 113 4 1 2 W H M 4 C,S Acute toxicity (inhalation); corrosive, toxicity from skin absorption(1R,3S)-(+)CAMPHORIC ACI Y 124-83-4 C10H16O4 No available environmental data 2.326 1 0 0TETRAMETHYLENE SULFO Y 126-33-0 C4H8O2S Low biodeg, low aq toxicity 1.26 M 177 1 1 0 L L LACETONE OXIME Y 127-06-0 C3H7NO No available environmental data 0.901 1 1 0POTASSIUM ACETATE G 127-08-2 C2H3KO2 Medium biodeg, low aq toxicity 1.8 0.253 -3.72 > 250 M L L 1 Practically non-irritating and non-toxicSODIUM ACETATE ANHYD G 127-09-3 C2H3NaO2High biodeg, low aq toxicity 1.528 M > 250 1 0 1 H L L 1 Practically non-irritating and non-toxicPYRUVIC ACID Y 127-17-3 C3H4O3 Low fish tox, no additional info available 1.265 M 82 LTETRACHLOROETHYLENE R 127-18-4 C2Cl4 Carcinogen 1.623 0.015 3.4 0.39 None 2 0 0 L H M RC X 100 T X BDIMETHYL ACETAMIDE (DM R 127-19-5 C4H9NO Reprotox 0.937 M -0.77 70 2 2 0 M L L L SC 3 S Reprotox (R61); skin notation on TLV and PELN-BROMOSUCCINIMIDE Y 128-08-5 C4H4BrNO N compound, no env data 2.098 slight -1.19 2 1 1SODIUM ASCORBATE Y 134-03-2 C6H7NaO6No available environmental data None 0 0 1ETHANOLAMINE R 141-43-5 C2H7NO Medium biodeg, high aq toxicity 1.012 M -1.31 1.3 93 3 2 0 M H L LFORMIC ACID, SODIUM SAL G 141-53-7 CHNaO2 High biodeg, low aq toxicity 1.92 55 2 1 0 H L L LETHYL ACETATE (ETOAC) G 141-78-6 C4H8O2 CERCLA RQ, med algal toxicity, upgraded to green 0.902 7.7 0.66 1.82 -3 1 3 0 H M L L 2 LC50; Irri X 5,000MALONIC ACID Y 141-82-2 C3H4O4 Low biodeg, low aq toxicity 1.619 73.5 -0.91 0.615 157 2 1 0 L L LN-HEPTANE Y 142-82-5 C7H16 Almost insoluble, low biodeg 0.684 0.0003 4.66 3.5 -1 2 3 0 L L L H 2 Irritant ( XBUTYL ETHER Y 142-96-1 C8H18O Bioaccumulates, med aq toxicity 0.764 0.03 >4 25 2 3 1 M MSODIUM CYANIDE R 143-33-9 NaCN Low CERCLA RQ, high toxicity 1.6 37 -1.69 None 4 0 1 H H H 4 C,S Corrosivity; highly to 10 T GSODIUM BICARBONATE G 144-55-8 NaHCO3 No known environmental issues 2.16 8.6 None 0 0 1 NA L L 1 Practically non-toxic; mildly irritating to eyesOXALIC ACID ANHYDROUS Y 144-62-7 C2H2O4 High bioded, low to med aq toxicity 1.65 9.5 -0.81 0.18 2 1 1 H M LD-TARTARIC ACID G 147-71-7 C4H6O6 Used as food additive 1.76 M None 2 0 02-MERCAPTOBENZOTHIAZ R 149-30-4 C7H5NS2 High aq toxicity 1.5 0 2.41 243 3 0 0 H H H SCTRIMETHYL ORTHOFORMA G 149-73-5 C4H10O3 Medium biodeg, low aq toxicity 0.97 1 0.09 13 2 3 0 M L 2 Irritation to skin, eyes and mucous membranesPOTASSIUM CYANIDE R 151-50-8 KCN Low CERCLA RQ 1.55 71.6 0.44 None 3 0 0 H H H 10 T1,4-DIAZABICYCLO (2,2,2) Y 280-57-9 C6H12N2 Low biodeg, low to med aq toxicity 1.14 > 0 L L MCYCLOPENTENE OXIDE Y 285-67-6 C5H8O No available environmental data 0.964 10CYCLOPENTANE Y 287-92-3 C5H10 Low fish tox, no additional info available 0.751 -37 2 3 0 LGLYOXYLIC ACID G 298-12-4 C2H2O3 High biodeg, low aq toxicity 1.342 10 -1.4 115 3 0 0 H L LPOTASSIUM BICARBONATE G 298-14-6 KHCO3 No known environmental issues 2.17 3.5714 None 0 0 0 NA 1 Practically non-irritating and non-toxicHYDRAZINE (AND SALTS) R 302-01-2 H4N2 Nitrogen compound, follow classif. for other hydrazine salts 1.01 M > 100 2 1 24-FLUOROPHENYLMAGNES Y 352-13-6 C6H4BrFM No available environmental data 1.021 -20 3 3 0TRIFLUOROMETHANESULFO Y 358-23-6 C2F6O5S2 Halogenated, no available environmental data 1.677 M None 3 0 3 WBROMOFLUOROMETHANE Y 373-52-4 CH2BrF Halogenated, no available environmental data 03-BROMOBENZOTRIFLUORI Y 401-78-5 C7H4BrF3 No available environmental data 1.613 43TRIFLUOROACETIC ANHYD Y 407-25-0 C4F6O3 Halogenated, no available environmental data 1.487 M None 2 1 2 G3-FLUORO-4-METHYLANILI Y 452-77-7 C7H9FN Halogenated, no available environmental data 1.093 88 2 1 1ETHYL DIFLUOROACETATE Y 454-31-9 C4H6F2O2 Halogenated, no available environmental data 1.18 23.9 3 3 0DIETHOXYMETHANE (DEM) G 462-95-3 C5H12O2 Low fish/protozoa tox, no additional info available 0.839 4.2 0.84 -5 1 3 0 L LCALCIUM CARBONATE G 471-34-1 CaCO3 No known environmental issues 2.93 0.0012 2 2 0 1 Practically non-irritating and non-toxicSODIUM CARBONATE ANH G 497-19-8 Na2CO3 No known environmental issues 2.533 22 None 2 0 1 L L 2 Z Eye irritation; possible skin sensitizationBENZYL CHLOROFORMATE R 501-53-1 C8H7ClO2 Halogenated, very toxic to aquatic life (R50/53) 1.195 reacts 92 2 1 2 HCYANOGEN BROMIDE R 506-68-3 BrCN High aq toxicity 2.015 M 3 1 2 H 1,000 GN-IODOSUCCINIMIDE Y 516-12-1 C4H4INO2 Halogenated, no available environmental data 2.245 2 0 02-FUROYL CHLORIDE Y 527-69-5 C5H3ClO2 Halogenated, no available environmental data 1.326 85 3 2 1 4 C CorrosivityN,N-CARBONYL DIIMIDAZO G 530-62-1 C7H6N4O Medium biodeg, low aq toxicity 3 0 1 M L L LCESIUM CARBONATE Y 534-17-8 Cs2O3 No available environmental data 4.072 M None 1 0 12-BROMOETHANOL R 540-21-2 C2H5BrO Genotoxic. Toxic to microorganisms 1.763 M > 110 2 1 1AMMONIUM FORMATE Y 540-69-2 CH5NO2 No available environmental data 2 0 12,2,4-TRIMETHYLPENTANE Y 540-84-1 C8H18 Regulated, low aq toxicity 0.69 0.000056 4.5 -12 2 3 0 L X 1,000 XT-BUTYL ACETATE Y 540-88-5 C6H12O2 Low aq toxicity 0.862 0 1.38 L LETHYL CHLOROFORMATE R 541-41-3 C3H5ClO2 High aq toxicity 1.135 M 10 3 3 1 M H H 4 C Corrosivity1,3-ACETONEDICARBOXYLI Y 542-05-2 C5H6O5 No available environmental data 0 0 0

MAGNESIUM CARBONATE G 546-93-0 MgCO3 No known environmental issues 2.16 0 None 0 0 0 1 Practically non-irritating and non-toxicLITHIUM CARBONATE Y 554-13-2 LiCO3 Medium aq toxicity 2.11 1.3 None 2 0 0 M M 2 Irritating to eyes and respiratory systemM-NITROPHENOL R 554-84-7 C6H5NO3 CERCLA RQ 1.28 1.35 2 0 0 L M M M 100METHYL ISOPROPYL KETON Y 563-80-4 C5H10O Low biodegradation 0.804 0.5 2.6 -3 1 3 0 L LPOTASSIUM CARBONATE G 584-08-7 K2CO3 No known environmental issues 2.29 M None 2 0 0 NA 3 Severely irritating and possibly corrosive to eyes, GI tract and mucous membranes1-HEXENE Y 592-41-6 C6H12 No available environmental data 0.673 0.005 -25 2 3 0 2 Harmful; irritating to eyes, skin and respiratory system; TLV airborne standardMETHYLAMINE HYDROCHL Y 593-51-1 CH5N.HCl No available environmental data 2 0 11-CHLORO-2-IODOBENZEN Y 615-41-8 C6H4ClI No available environmental data 1.952 112 1 1 1DIMETHYL CARBONATE Y 616-38-6 C3H6O3 No available environmental data 1.069 0 18 3 3 02-PYRROLIDONE R 616-45-5 C4H7N High aq toxicity 1.12 M 129 2 1 0 H L L HTRIETHYLSILANE Y 617-86-7 C6H16Si Silicon compound, no env data 0.728 -3 0 3 05-METHYLFURFURAL Y 620-02-0 C6H6O2 No available environmental data 1.105 72 2 2 0FORMIC HYDRAZINE Y 624-84-0 CH4N2O No available environmental data 112 2 0 1 2 Irritating to eyes, skin and respiratory system


20 of 22 09-Dec-2009




HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TDensity

g/mL

Solub. in Waterwt%

Log Poct

Flash Point

°CNFPA Health

NFPA Flamm

NFPA React

NFPA Other

BiodegH > 80%

M - 50 - 80%L < 50%



mg/L


mg/L


S-P HHC

Notation (HHC)

CERCLA RQ

CAA 112(r) TQ


NJAC 7:27-7TXS

EUG = GreyB = Black

TERT-AMYL ACETATE Y 625-16-1 C7H14O2 Follow classification of other amyl acetates 2 0 3 0 X 5,0005-METHYLEXANOIC ACID Y 628-46-6 C7H14O2 No available environmental data 0.912 M 2.4 101.7AMYL ACETATE Y 628-63-7 C7H14O2 Low to med aq toxicity 0.876 0.18 <1 2.34 23 1 3 0 M L L 5,000ETHYLENE GLYCOL DIETHY Y 629-14-1 C6H14O2 Low biodeg 0.842 34 20 1 3 0 LPIVALDEHYDE Y 630-19-3 C5H10O No available environmental data 0.775 0 1.2 -16AMMONIUM ACETATE Y 631-61-8 C2H7NO2 High biodeg, low aq toxicity, N compound 1.07 7.7 0 0 0 H L 2 Irritating to eyes and 5,000ETHYL-TERT BUTYL ETHER Y 637-92-3 C6H14O N compound, no env data 0.736 1.2 -19 2 3 0TRITHIOCYANURIC ACID Y 638-16-4 C3H3N3S3 No available environmental data 1 0 02,4-DIFLUOROPHENYLACET Y 656-35-9 C8H5F2N F, N compound, no env data 1.249 1.695 93 1 0 0METHYLMAGNESIUM CHLO Y 676-58-4 CH3ClMg No available environmental data 1.013 M None 3 4 3 W 4 C,S Corrosivity; absorbed through skin2,5-DIMETHOXY TETRAHY Y 696-59-3 C6H12O3 No available environmental data 1.023 38DIETHYL PHOSPHITE R 762-04-9 C4H11O3P Organophosphorus compound 1.073 0 82 2 2 1 BCYCLOPROPYLAMINE Y 765-30-0 C3H7N Nitrogen compound, no available environmental data 0.824 0.07 1 3 3 03-FLUOROPHENYLBORONIC Y 768-35-4 C6H6BFO2Halogenated, no available environmental data 0 0 0 2 Irritating to eyes, skin and respiratory system G

BIS(2-CHLOROETHYL)AMIN R 821-48-7 C4H9Cl2N. Mutagen -1.79 2 0 0 4 C Corrosive. Positive mutagenicity/genotoxicity GTRIMETHYLBOROXINE Y 823-96-1 C3H9B3O3 B compound, no env data 0.898 -9 3 3 0POTASSIUM TERT-BUTOXI G 865-47-4 KC4H9O High biodeg, low aq toxicity M 3 3 2 W H L LN-METHYL-2-PYRROLIDONE R 872-50-4 C5H9NO Reprotox 1.033 M -0.46 86 2 2 0 H L L L SC 2 S Irritating to eyes, skin and mucous membranes; reproductive or developmental toxicity; toETHYLMAGNESIUM BROMI Y 925-90-6 C2H5BrMg No available environmental data 1.03 3 4 2 4 C,SISOPROPYL METHANESUL Y 926-06-7 C4H10O3S Sulfur compound, no env info available, SC 1.145 SCHEXAMETHYLDISILAZANE ( Y 999-97-3 C6H19NSi2Silicon compound 0.76 0 14 1 3 1 M M M

SODIUM HEXAMETHYLDISIL Y 1070-89-9 C6H18NNaSi2 3 0 0

4-DIMETHYLAMINO PYRIDI R 1122-58-3 C7H10N2 Low biodeg, high aq toxicity 0.76 1.34 110 L H 3 S Acute toxicity (inhalation, dermal, oral); severely irritating to eyes, skin and mucous membBISPHENOL A DICYANATE Y 1156-51-0 C17H14N2 Nitrogen compound, no available environmental data 1.83CHLOROSULFONYL ISOCY R 1189-71-5 CClNO3S Decomposes to HCl, HCN, SOx 1.626 3 0 2 WDIISOBUTYL ALUMINUM HY Y 1191-15-7 C8H19Al No available environmental data 0.798 -18 3 3 3 WMAGNESIUM HYDROXIDE Y 1309-42-8 MgH2O2 Flocculant 2.36 0.0009 -0.87 None 2 0 0 1 Practically non-irritating and non-toxicPOTASSIUM HYDROXIDE (S Y 1310-58-3 KOH CERCLA RQ 2.04 M None NA M 4 C Corrosive 1,000LITHIUM HYDROXIDE MON Y 1310-66-3 LiOH No available environmental data 1.51 M None 3 0 2 NA 4 C CorrosiveSODIUM HYDROXIDE SOLU G 1310-73-2 NaOH Limited use only 1.27 M None 3 0 2 NA L 4 C CorrosivityXYLENE (MIXED ISOMERS) R 1330-20-7 C8H10 High aq toxicity 0.86 0.02 3.15 3.125 29 2 3 0 H H L X X 100 X GHYDROGEN G 1333-74-0 H2 Atom economical 5 - 50 0.069 0.00016 0 4 0 10,000AMMONIUM HYDROXIDE Y 1336-21-6 NH4OH Limited use only 0.96 M None 3 0 0 NA H 4 C Corrosive 1,000 20,000METHYL 1-METHYLCYCLOP Y 1567-75-5 C6H10O No available environmental data 0.895 24 2 3 1METHYL TERT-BUTYL ETHE R 1634-04-4 C5H12O Mutagen 0.74 4.3 1.06 -32 2 3 0 L L L L SC 3 ACGIH Classifi X 1,000 X2-CHLOROPYRIMIDINE Y 1722-12-9 C4H3ClN2 Halogenated, no available environmental data 0.5 98 2 0 0METHYL TRIPHENYL PHOS Y 1779-49-3 C19H18BrPOrganophosphorus cmpd, med aq tox 40 -0.7 1 0 0 METHYL(4-FLUOROBENZOYL Y 1813-94-1 C10H9FO3 No available environmental data 1.199 hydrolizes 2 1 1CYCLOHEXANE CARBOXAL Y 2043-61-0 C7H12O No available environmental data 0.932 41 2 2 02-HYDROXY-1-NAPHTHOIC Y 2283-08-1 C11H8O3 No available environmental dataETHYLMAGNESIUM CHLORI Y 2386-64-3 C2H5ClMg No available environmental data 1.03TEMPO Y 2564-83-2 C9H18NO N compound, med aq toxicity 0.912 9.7 2.1 67 3 2 0 M(S)-1-PHENYLETHYLAMINE Y 2627-86-3 C8H11N High biodeg, medium aq toxicity 0.94 1.49 70 H M M 4 C CorrosivityN-ETHYL PYRROLIDONE (N Y 2687-91-4 C6H11NO Nitrogen compound, no available environmental data 0.992 76 2 2 0

BROMOTRIMETHYLSILANE Y 2857-97-8 C3H9BrSi Silicon compound 1.16 M 32 3 3 0 4 C CorrosiveSQUARIC ACID Y 2892-51-5 C4H2O4 No available environmental data 1.82 0.25 190 3 Default; adequate data not availableMETHYL 4-(TRIFLUOROMET Y 2967-66-0 C9H7F3O2 No available environmental data 1.268 82 2 0 0IMIDAZOLE-4-CARBOXALD Y 3034-50-2 C4H4N2O No available environmental data 2 2 0

TRIMETHYLACETYL CHLOR Y 3282-30-2 C5H9ClO High biodeg, medium aq toxicity 0.98 1.8 8 3 3 2 H M L L 4 C Corrosive2-FUROIC HYDRAZIDE Y 3326-71-4 C6H6N2O2Nitrogen compound, no available environmental data 1 0 0PALLADIUM ACETATE Y 3375-31-3 PdC4H6O4 Metal, no env info available 0 2 0 0LITHIUM BIS(TRIMETHYLSY Y 4039-32-1 C6H18NSi2No available environmental data 0.891 3 3 4 WLITHIUM DIISOPROPYLAMI R 4111-54-0 C6H15NLi Carcinogen 0.812 -12 3 4 3 W RC 4 C,S2-BROMOPYRIMIDINE Y 4595-60-2 C4H3BrN2 N, Br compound, no env data 0 2 0 0BROMOPROPYLAMINE HYD Y 5003-71-4 C3H8BrN.HHalogenated, no available environmental data 2 0 0DIMETHYL SQUARATE Y 5222-73-1 C6H6O4 No available environmental data 3 0 0 3 R,Z Default; adequate data not available; possible respiratory and skin sensitizerDIETHYL SQUARATE Y 5231-87-8 C8H10O4 No available environmental data 1.15 110SULFAMIC ACID Y 5329-14-6 SH3NO3 Sulfur compound, med aq toxicity 2.151 -4.34 3 0 0 M3-METHOXYPROPYLAMINE Y 5332-73-0 C4H11NO N compound, no available environmental data 0.871 M -0.5 32 3 3 15-AMINO-4-CYANO-1-(2-HY Y 5346-53-2 C6H8ON4 No available environmental data 2.3 3 Default; adequate data not availableTRIISOPROPYL BORATE Y 5419-55-6 C19H21BO No available environmental data 0.815 M 17HYDROXYLAMINE HYDROC R 5470-11-1 ClH4NO High aq toxicity 1.67 83 -2.66 3 0 0 H H HCYCLOPENTYL METHYL ET G 5614-37-9 C6H12O Low aq toxicity 0.86 1.1 1.59 -1 2 3 1 L4-CYCLOPROPYL BUTANEOI Y 5687-84-3 C7H12O2 No available environmental data 1 0 0CAMPHORSULFONIC ACID Y 5872-08-2 C10H16O4 No available environmental data slight 3 0 0CITRIC ACID MONOHYDRA G 5949-29-1 C6H8O7 High biodeg, low aq toxicity 1.542 M -1.72 0.686 H L L L 3 IrritationSODIUM CARBONATE MON G 5968-11-6 Na2CO3 No known environmental issues 2.25 21 None 2 0 0 L L 2 Z Eye irritation; possible skin sensitizationSODIUM ACETATE TRIHYD G 6131-90-4 C2H3NaO2Follow classification of its anhydrous cmpd 1.45 61.3 -4.22 0 0 0 H L LP-TOLUENE SULFONIC AC Y 6192-52-5 C7H78O3S Sulfur compound 1.23 75 -0.62 180 3 0 1 H L L L 4 C CorrosiveMETHYL METHOXYACETAT Y 6290-49-9 C4H8O3 No available environmental data 1.052 35POTASSIUM SODIUM TART Y 6381-59-5 C4H4KNaONo available environmental data 63 1 0 0TRIPHENYLPHOSPHINE H Y 6399-81-1 C18H15P.BPhosphorus compound, no env info available 3 0 11,8-DIAZABICYCLO[5,4,0]U Y 6674-22-2 C9H16N2 Low biodeg, low to med aq toxicity 1.018 M -2.2 116 3 1 0 L L M 4 C CorrosivityN,N-DIISOPROPYLETHYLAM Y 7087-68-5 C8H19N Readily biodeg, med aq tox, N compound 0.742 4 <1 10.6 3 3 0 M M 4 C Corrosivity

Note: Carcinogen classification (TLV-A3)

Corrosive; toxicity from skin absorption


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HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TDensity

g/mL

Solub. in Waterwt%

Log Poct

Flash Point

°CNFPA Health

NFPA Flamm

NFPA React

NFPA Other

BiodegH > 80%

M - 50 - 80%L < 50%



mg/L


mg/L


S-P HHC

Notation (HHC)

CERCLA RQ

CAA 112(r) TQ


NJAC 7:27-7TXS

EUG = GreyB = Black

PALLADIUM ON CARBON (5 Y 7440-05-3 Pd No available environmental data 12.02 0 1 3 0 4 Z Carcinogen classification (IARC-2A); reproductive or developmental toxicity (R61, R62); tarDARCO G-60 G 7440-44-0 C No known environmental issues 2.26 0 1 1 0 2 Irritation to eyes and mucous membranesZINC (POWDER) Y 7440-66-6 Zn Insoluble as element, high aq toxicity in soluble form 7.133 liberates gas 0 1 1 W H H 1,000 GALUMINUM CHLORIDE ANY Y 7446-70-0 AlCl3 Follow classification of HCl 2.44 M 3 0 2 H M MMAGNESIUM SULFATE AN G 7487-88-9 MgSO4 No known environmental issues 1.07 0.00005 0 0 0 L 1 Practically non-irritating and non-toxicN-T-BOC-ASPARAGINE Y 7536-55-2 C9H16N2O Nitrogen compound, no available environmental data 1 1 0LITHIUM BROMIDE Y 7550-35-8 LiBr Halogenated 3.464 L L LTITANIUM TETRACHLORIDE R 7550-45-0 TiCl4 High aq toxicity, heavy metal 1.726 liberates gas 4 C Acute toxicity ( X 1,000 2,500 TIODINE FLAKES R 7553-56-2 I2 High aq toxicity 4.93 0.03 2.49 3 0 0 H HDIETHYL 2,2-DIETHOXYET Y 7598-61-0 C10H23O5 No available environmental data 1.052 > 110 1 1 1SODIUM PHOSPHATE, TRIB Y 7601-54-9 Na3O4P Enhances eutrophication 8.8 L 5,000SODIUM BISULFITE Y 7631-90-5 NaHSO3 Medium aq toxicity 1.32 39 3 0 0 M M 2 A Harmful by ingestion; 5,000BORON TRIFLUORIDE Y 7637-07-2 BF3 Halogenated, boron compound M M 4 C Acute toxicity (inhalation); corro 5,000 GZINC CHLORIDE R 7646-85-7 ZnCl2 High aq toxicity 2.91 0.432 H M H 1,000 GHYDROCHLORIC ACID Y 7647-01-0 HCl Inorganic, med aq toxicity, chlorinate 5000 1.2 M None 3 0 1 NA M 4 C Corrosivity 5,000 15,000 XSODIUM CHLORIDE G 7647-14-5 NaCl No known environmental issues 2.163 35.7 None 0 0 0 0 NA L L 2 Irritation, eyePHOSPHORIC ACID G 7664-38-2 H3PO4 Inorganic, low aq toxicity 1.71 M None 3 0 0 NA 4 C Corrosivity 5,000 GHYDROFLUORIC ACID R 7664-39-3 HF Low CERCLA RQ 1000 1.16 M None 4 0 1 NA 4 C,S Corrosivity; ab X 100 T GAMMONIA (ANHYDROUS) R 7664-41-7 NH3 Low CERCLA RQ 10000 0.59 M 132 3 2 1 4 C Corrosive 100 10,000SULFURIC ACID G 7664-93-9 H2SO4 Limited use only 1.84 M None 3 0 2 NA M 4 C 1,000TRIMETHYLSYLNITRILE R 7677-24-9 C4H9NSi Decomposes to HCN 0.744 1 3 3 1SODIUM HYPOCHLORITE SOLY 7681-52-9 NaOCl Limited use only 1.22 M NA 4 C CorrosivitySODIUM METABISULFITE Y 7681-57-4 Na2S2O5 Medium aq toxicity 1.48 64 -3.7 None 2 0 1 M M M 4 C,A Irreversible eye damage (R41); allergic respiratory reactionCOPPER IODIDE R 7681-65-4 CuI High aq toxicity 5.62 0 None 2 0 1 HTHIONYL CHLORIDE Y 7719-09-7 Cl2OS Halogenated, no available environme 250 1.635 M 4 0 2 W 4 C CorrosivePOTASSIUM PERMANGANA R 7722-64-7 KMnO4 High aq toxicity 2.7 6.4 H HHYDROGEN PEROXIDE (>52 Y 7722-84-1 H2O2 Limited use only 7500 1.11 M None 3 0 0 H H M H 4 C CorrosivityPOTASSIUM PERSULFATE G 7727-21-1 K2S2O8 Low aq toxicity 2.48 5.2 None 2 0 0 L LBARIUM SULFATE Y 7727-43-7 BaSO4 European Grey List, barium 4.5 < 0.1 None 1 0 0 NA GSODIUM SULFATE DECAHY G 7727-73-3 Na2O4S No known environmental issues 1.46 14.2 0 0 0WATER G 7732-18-5 H2O No known environmental issues 1 M None 0 0 0SODIUM SULFATE G 7757-82-6 Na2O4S Low aq toxicity 2.7 20 L LSODIUM SULFITE ANHYDR G 7757-83-7 Na2SO3 Low aq toxicity 2.633 13.9 -4 L L 2 A Irritation, anaphylaxis in asthmaticsPOTASSIUM BROMIDE Y 7758-02-3 KBr Halogenated, no available environmental data 2.75 M None 2 0 1 NAPOTASSIUM PHOSPHATE, D Y 7758-11-4 K2HPO4 Enhances eutrophication 2.44 M None 2 0 1 L 1 Practically non-irritating and non-toxicSODIUM PHOSPHATE, TRIB Y 7758-29-4 Na5P3O10 Enhances eutrophication 1.1 M None 2 0 1 L L 5,000 GCOPPER CHLORIDE R 7758-89-6 CuCl High aq toxicity 4.14 2 0 1 HSILVER NITRATE R 7761-88-8 AgNO3 Low CERCLA RQ 4.35 M 0.19 None 3 0 3 H H H H 1SODIUM THIOSULFATE AN G 7772-98-7 Na2S2O3 Follow class for 10102-17-7 1.667 M None 2 0 0 1 Practically non-irritating and non-toxicPOTASSIUM PHOSPHATE, T Y 7778-53-2 K3PO4 Phosphorus compound, low aq toxicity 2.564 2 0 1 LPOTASSIUM PHOSPHATE, Y 7778-77-0 KH2PO4 Enhances eutrophication 2.338 33 None 0 0 1 L 1 Practically non-irritating and non-toxicPOTASSIUM SULFATE G 7778-80-5 K2SO4 No known environmental issues 2.66 11.1 None 1 0 0 L L LAMMONIUM SULFATE Y 7783-20-2 N2H6SO4 Nitrogen compound 1.769 75.4 -5.1 0 0 0 L LMAGNESIUM CHLORIDE R 7786-30-3 MgCl2 Mutagen 2.33 54.2 1 0 0 L L LSODIUM PERIODATE Y 7790-28-5 NaIO4 No available environmental data 3.865 9.1 2 3 0 OXHYDRAZINE HYDRATE R 7803-57-8 H6N2O High aq toxicity 1.032 M < 1 96 2 1 2 M H H SC 4 C,S,Z Carcinogen classification (NTP-R, MAK-2, EU-Cat 2); positive mutagenicity/genotoxicity; corCATALASE (CATAZYME) G 9001-05-2 CAT Biological 1 0 0 0NOVOZYME 435 G 9001-62-1 Enzyme Low aq toxicity slight 1 1 0 L L LPHOSPHORUS OXYCHLORI Y 10025-87-3 Cl3OP Enhances eutrophication 1.645 None 3 0 3 4 C Acute toxicity (inhala 1,000 5,000HYDRIODIC ACID R 10034-85-2 HI High aq toxicity 1.7 M 3 0 0 HMAGNESIUM SULFATE HEP G 10034-99-8 MgSO4.7H Low aq toxicity 1.68 71 L L L 1 Practically non-irritating and non-toxicHYDROBROMIC ACID Y 10035-10-6 HBr Halogenated, no available environme 5000 1.49 M None 3 0 0 4 C CorrosivitySODIUM PHOSPHATE, DIBA Y 10039-32-4 Na2HPO4. Enhances eutrophication 1.52 21.8 -5.8 L L 1 Mild irritation (skin/ey 5,000SODIUM PHOSPHATE MON Y 10049-21-5 NaH2PO4. P compound, low aq toxicity 2.04 85 0 0 0 L 1 Practically non-irritating and non-toxic GSODIUM THIOSULFATE PE G 10102-17-7 Na2S2O3.5Low aq toxicity 1.74 M None 0 0 0 L L 1 Practically non-irritating and non-toxicSODIUM PHOSPHATE, TRIB Y 10124-56-8 Na3O4P.12Enhances eutrophication 1.62 28.5 L 5,000SODIUM PHOSPHATE, DIBA Y 10140-65-5 Na2HPO4. Enhances eutrophication 1.67 1 0 0 5,000BORON TRICHLORIDE R 10294-34-5 BCl3 Hallogenated, environmentally regulated 1.349 3 0 2 5,000 GBIS-TRIMETHYLSILYLACETA Y 10416-59-8 C8H21NOSiNitrogen compound, no available environmental data 0.82 42 3 2 2 W 3 Default2-METHYL-5-PROPYONYL Y 10599-69-6 C8H10O2 No available environmental data 1 0 0AMMONIUM CHLORIDE R 12125-02-9 NH4Cl High aq toxicity 1.54 37.2 -4.37 H L 2 Harmful (oral); irrit 5,000BORANE DIMETHYL SULFID Y 13292-87-0 C2H6S.BH3B compound, no env data 0.801 18 2 3 2 WPOTASSIUM BOROHYDRID Y 13762-51-1 KBH4 Boron compound 1.18 > 0 3 0 2 W 3 Severe irritation to eyes, skin and respiratory system GBIS(TRIPHENYLPHOSPHINE) Y 13965-03-2 C36H30Cl1 No available environmental data 0 0 0 0BORANE TETRAHYDROFUR R 14044-65-6 C4H11BO Follows THF classification 0.896 -17 2 3 2 W 3 S Carcinogen classification (TLV-A3); positive mutagenicity/genotoxicity; toxicit GTETRAKIS(TRIPHENYLPHOS Y 14221-01-3 C72H60P4PPd and P compound, no env data 0 0 0 0N-BOC-L-ALANINE Y 15761-38-3 C8H15NO4Nitrogen compound, no available environmental data 1 1 0IODOTRIMETHYLSILANE R 16029-98-4 C3H9ISi Releases HI, follow HI classification 1.408 -31 3 3 2 WMETHANESULFONIC-(2-MET Y 16427-44-4 C4H10O4S No available environmental data 3 Default; adequate data not availableLITHIUM ALUMINUM HYDRI Y 16853-85-3 LiAlH4 No available environmental data 0.92 3 2 2 WSODIUM BOROHYDRIDE Y 16940-66-2 NaBH4 Boron compound 1.07 55 3 3 2 W L18-CROWN-6 Y 17455-13-9 C12H24O6 No available environmental data 1.237 7.49 -0.68 113 2 0 0LITHIUM TRI-T-BUTOXYAL Y 17476-04-9 LiC12H28A No available environmental data 1.03 3 4 2 W(S)-N-BENZYL-ALPHA-MET R 17480-69-2 C15H17N High aq toxicity 1 < 0.1 3 66 L H H H


22 of 22 09-Dec-2009




HHM(PSM)TQ, lb

HHM(Seveso)

TQ, TDensity

g/mL

Solub. in Waterwt%

Log Poct

Flash Point

°CNFPA Health

NFPA Flamm

NFPA React

NFPA Other

BiodegH > 80%

M - 50 - 80%L < 50%



mg/L


mg/L


S-P HHC

Notation (HHC)

CERCLA RQ

CAA 112(r) TQ


NJAC 7:27-7TXS

EUG = GreyB = Black

HEXYLLITHIUM, 2.5M IN HE Y 21369-64-2 C6H13Li No available environmental data 0.69 4.11 -26DI-TERT-BUTYL DICARBON Y 24424-99-5 C10H18O5 No available environmental data 0.95 84 3 3 0DIPROPYLENE GLYCOL Y 25265-71-8 C6H14O3 No available environmental data 1.023 M 137 1 1 1POLYETHYLENE GLYCOL (P G 25322-68-3 (C2H4O)nHNo known environmental issues 1.127 M 270 0 1 0 1 Practically non-irritating and non-toxicPOLYPROPYLENE GLYCOL G 25322-69-4 C3H8O2 No known environmental issues 1.01 0 112.8 0 0 0 1 Practically non-irritating and non-toxicEDCI HCL Y 25952-53-8 C8H18N3ClNo available environmental data M None 2 0 1 2 Harmful (inhalation, dermal, oral); possible sensitizerDIPHENYLPHOSPHORYL AZ R 26386-88-9 C12H10N3 N and P compound, toxic by inhalation 1.277 110 4 1 0POTASSIUM PHOSPHATE T Y 27176-10-9 K3O4P.H2 Enhances eutrophication 2.5 2 0 0TRIMETHYLSILYL TRIFLU Y 27607-77-8 C4H9F3O3SSi, F, S compound, no env data 1.15 25 3 3 0 WTRIPHOSGENE Y 32315-10-9 C3Cl6O3 No available environmental data 3 0 1 4 CTETRABUTYLAMMONIUM H Y 32503-27-8 C16H37NO Nitrogen and sulfur compound, no available environmental 1.01 >> 0 0.96 3 1 0DI-P-TOLUOYL-D-TARTARI Y 32634-68-7 C20H18O8 No available environmental dataDIPROPYLENE GLYCOL ME G 34590-94-8 C7H16O3 High biodeg, low aq toxicity 0.951 M -0.06 74 0 2 0 H L LCETYL ALCOHOL G 36653-82-4 C16H34O No known environmental issues 0.818 0 113 2 1 0 L 2 Irritating to eyes, skin and respiratory systemMONOMETHYL MALONATE P Y 38330-80-2 KC4H6O4 No available environmental data > 0 -0.6314-PIPERIDONE HYDRATE Y 40064-34-4 C5H10ClNONo available environmental data 2 0 02,4-D 2-ETHYL-4-METHYLP Y 53404-37-8 No known environmental issuesSODIUM TRIACETOXYBOR Y 56553-60-7 C6H10BNa No known environmental issues 3 1 2 GTERT-BUTYL N-(2-AMINOE Y 57260-73-8 C7H16N2O N compound, no available environmental data 1.012 113CELITE (HYFLO SUPER-CEL G 61790-53-2 SiO2 Applies only if the material is not airborne. 2.3 0 2 0 0 2 Carcinogen classification (IARC-3); MAK airborne standardSILICA GEL G 63231-67-4 SiO2 Applies only if the material is not airborne. 0.5 0 0 0 0HEPTANES Y 64742-49-0 C7H16 Almost insoluble, high biodeg, high aq toxicity 0.7 0.00026 3.77 -7.8 1 3 0 H H H H XCELITE G 68855-54-9 SiO2 Applies only if the material is not airborne. 0 0 0 0 2 Carcinogen classification (IARC-3); MAK airborne standardPOTASSIUM PEROXYMONO Y 70693-62-8 2HKO5S.H Medium aq toxicity 1.25 25.6 3 3 3 Ox MDI-P-TOLUOYL-D-TARTARIC Y 71607-31-3 C20H18O8.No available environmental data 0 0 0N,N-DISUCCINIMIDYL CAR Y 74124-79-1 C9H8N2O7N compound, no env data 2 0 0SODIUM PERMANGANATE R 79048-36-5 MnNaO4 Follow classification for other permanganates 2.47 0.2 2 1 2N-BENZYL NORTROPINONE Y 83393-23-1 No available environmental data(2-BROMOETHOXY)-T-BUTY Y 86864-60-0 C8H19BrOSHallogenated, silicon compound 1.115 73TETRABUTYLAMMONIUM FL Y 87749-50-6 C16H36FN.N, F compound, no env data 0.047 3 0 05-BROMO-2-HYDROXYMETH Y 88139-91-7 C6H6BrNO No available environmental data 3 Default; adequate data not available2-CHLORO-3-CHLOROMETH Y 90097-52-2 C10H8Cl2NNo available environmental dataHYFLO G 91053-39-3 SiO2 Applies only if the material is not airborne. 2.3 0 0 0 0N-BENZYL-N-(METHOXYMET Y 93102-05-7 C13H23NOSN, Si compound, no env data 0.928 66 2 2 01,1'-BIS(DIPHENYLPHOSP R 95464-05-4 PdCl4C36HFollow classification for MeCl2 0 1 1 1(1S)-(+)-(-10-CAMPHORSUL Y 104322-63-6 C10H15NO Nitrogen compound, no available environmental data(S)-2-METHYL-CBS-OXAZAB R 112022-81-8 C18H20BN Low biodeg, potential reprotox 0.925 partly 4.39 4 2 3 0 LSILICA GEL GRADE 62 G 112926-00-8 SiO2 Applies only if the material is not airborne. 1 0 0BENZYLTRIMETHYLALUMIN Y 114971-52-7 C10H16Cl2 No available environmental data > 01-HYDROXYBENZOTRIAZOL Y 123333-53-9 C6H5N3O. Nitrogen compound, no available environmental data 0.5 2 1 0 1 Practically non-toxic; mildly irritating to eyesMETHYL-7-METHYL-3-OXO Y 128651-36-5 No available environmental data(1R,2S)-(+)-CIS-1-AMINO-2 Y 136030-00-7 C9H11NO N compound, no env data 2 0 02-METHOXY-3-PYRIDINE B Y 163105-90-6 C8H8BNO3No available environmental data 0.716 0 0 02-BROMO-5-FLUORO-BENZ Y 202865-66-5 C7H6BrFO Medium aq toxicity 2.201 2 0 0 M2-DICYCLOHEXYLPHOSPHIN Y 213697-53-1 C16H36NP Nitrogen and organic phosphorus compound 0 2 0 1PIP-PHOSPHONATE Y 216870-24-5 No known environmental issues2-DI-T-BUTYLPHOSPHINO-2 Y 224311-49-3 C22H32NP Bioaccumulates 7.447 2 0 0HOVEYDA-GRUBBS 2ND GE Y 301224-40-8 C31H38Cl No available environmental data 0 0 11,2,3,4,5-PENTAPHENYL-1 Y 312959-21-3 C45H47FePNo available environmental data 02-BUTYONIC ACID HYDRAZI Y 494793-39-4 No available environmental data2-CYANO-3-METHYLPYRIDI Y C7H6N2 Nitrogen compound, no available environmental data < 37.2 2 0 0ECOSORB G C Follow classification for other carbons 1.25 0(2S,4R)-ETHYL-1-BOC-4- Y C16H26N2 No available environmental dataHEXAFLUOROPROPENE DI Y C7H11NF6 Halogenated, no available environmental data 1.23 4 C Corrosivity GMETHYL 2-CHLORO-3-MET Y C7H7ClN2ONo available environmental dataPIPERIDINE-4-CARBOXYLIC Y No known environmental issues 1.02

Note: Acute exposure may cause delayed pulmonary edema

Chemical Selection Guide_V5

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Transcript of Chemical Selection Guide_V5