Chemical engineering thermo 2
-
Upload
30gm-unilorin -
Category
Documents
-
view
96 -
download
1
Transcript of Chemical engineering thermo 2
![Page 1: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/1.jpg)
1
Chemical Engineering Thermodynamics
Fulbright Visiting Professor David J. Dixong gChemical and Biological Engineering DepartmentSouth Dakota School of Mines and Technology
WS 2009/2010
![Page 2: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/2.jpg)
Overview2
• Introduction• Chemical Engineering HistoryChemical Engineering History• Today’s Chemical Engineering• Chemical Engineering Thermodynamics Course Overview
![Page 3: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/3.jpg)
Introduction3
Dr David DixonDr. David DixonProfessor of Chemical Engineering Chemical and Biological Engineering DepartmentSouth Dakota School of Mines and Technology
Rapid City, South Dakota, USAp y, ,
![Page 4: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/4.jpg)
Introduction4
Rapid City near Black HillsRapid City near Black Hills
![Page 5: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/5.jpg)
Introduction5
Rapid City near Black Hills (P h S L k t f “hill th t bl k”)Rapid City near Black Hills (Paha Sapa, Lakota for “hills that are black”)
![Page 6: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/6.jpg)
Introduction6
Rapid City ( 60 000)Rapid City (~60,000)
Looking East
Looking West
![Page 7: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/7.jpg)
Introduction7
![Page 8: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/8.jpg)
Introduction8
SD School of Mines and Technology (SDSMT.edu)gy ( )
![Page 9: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/9.jpg)
Introduction9
SD School of Mines and Technology (SDSMT.edu)gy ( )
![Page 10: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/10.jpg)
Introduction10
MyselfMyself….
•BS/MS/PhD Chemical EngineeringSDSMT/SDSMT/U i i f T A i•SDSMT/SDSMT/University of Texas at Austin
•Dow Corning Corporation (Process Engineering)•Overseas military service (Darmstadt)y ( )•Professor SDSMT (16 yrs)
![Page 11: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/11.jpg)
Introduction11
![Page 12: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/12.jpg)
Chemical Engineering History12
United States:United States:•J. Willard Gibbs 1st PhD in Engineering in the U.S. (1863)• L. M. Norton, MIT first ChE course (1888)1 t BS i Ch i l E i i U P l i (1892)•1st BS program in Chemical Engineering, U Pennsylvania (1892)
•American Institute of Chemical Engineers (AIChE) formed 1908
“The chemical industry had a central position in the changing industrial y p g gworld of the late 19th century. This industry did not hatch fully grown; it
was based on nearly a century’s worth of scientific advances in the universities – particularly German universities.”
N.A. Peppas, “The First Century of Chemical Engineering”, Chemical Heritage Newsmagazine, Vol. 26, No. 3, Fall 2008
Europe:•Justus von Liebig (1803 – 1873) Giessen•Göttingen, Heidelberg, and other top universities.g , g, p
![Page 13: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/13.jpg)
Chemical Engineering History13
South Dakota: 1803 4South Dakota: 1803-4
* "Discovered a Village of S ll i l th t bSmall animals that burrow in the grown... except the ears which is Shorter, his tail like a ground squirel g qwhich they shake & whistle when allarmd. the toe nails long, they have fine fur."
* W. Clark - Friday, September 7, 1804
![Page 14: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/14.jpg)
Today’s Chemical Engineering14
* Wikipedia, Chemical Engineering
![Page 15: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/15.jpg)
Today’s Engineering15
Darmstadt (BS 3yrs – MS 2yrs)( y y )
![Page 16: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/16.jpg)
Today’s Chemical Engineering16
USA system (BS 4 yrs)y ( y )•Programming and Numerical solutions to ChE problems•Material and energy balances
•ChE laboratory experiences•Freshman modeling intro•Fluid flowMaterial and energy balances
•Fluid flow •Heat transfer•Mass transfer U it O ti / ti
Fluid flow•Process control intro•Heat transfer•SeparationsEl ti l b•Unit Operations/separations
•Thermodynamics I and II•Chemical kinetics and reactor design •Senior design courses and project
•Elective lab•Elective ChE courses
•Advanced separations•Advanced reactor designg p j
•Process control•Microbiology•Global and contemporary issues in ChE
g•System dynamics and modeling•Polymer engineering•Organosilicone chemistry•Biochemical engineeringChE •Biochemical engineering•Design of experiments for ChEs•Coop experiences•Undergraduate research
![Page 17: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/17.jpg)
Today’s Chemical Engineering17
USA system (BS 4 yrs)USA system (BS 4 yrs)-Professional organizations (AIChE, ACS, other)
![Page 18: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/18.jpg)
Today’s Chemical Engineering18
Why study Thermo of mixtures: MotivationWhy study Thermo of mixtures: Motivation-Example, i.e. SCF measurements, others?-UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc)-Simulators: AspenPlus, Fluent, Comsol, ChemSep, others.
![Page 19: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/19.jpg)
Today’s Chemical Engineering19
Why study Thermo of mixtures: MotivationWhy study Thermo of mixtures: Motivation-Example, i.e. SCF measurements, others?-UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc)-Simulators: AspenPlus, Fluent, Comsol, ChemSep, others.
![Page 20: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/20.jpg)
Today’s Chemical Engineering20
Why study Thermo of mixtures: MotivationWhy study Thermo of mixtures: Motivation-Example, i.e. SCF measurements, others?-UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc)-Simulators: AspenPlus, Fluent, Comsol, ChemSep, others.
![Page 21: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/21.jpg)
Today’s Chemical Engineering21
Why study Thermo of mixtures: MotivationWhy study Thermo of mixtures: Motivation-Example, i.e. SCF measurements, others?-UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc)-Simulators: AspenPlus, Fluent, Comsol, ChemSep, others.
![Page 22: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/22.jpg)
Today’s Chemical Engineering22
Why study Thermo of mixtures: MotivationWhy study Thermo of mixtures: Motivation-Example, i.e. SCF measurements, others?
Supercritical Fluid Extraction (2nd), M. McHugh & V. Krukonis, Elsevier (1994)
![Page 23: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/23.jpg)
Today’s Chemical Engineering23
Why study Thermo of mixtures: MotivationWhy study Thermo of mixtures: Motivation-Example, i.e. SCF measurements, others?
Supercritical Fluid Extraction (2nd), M. McHugh & V. Krukonis, Elsevier (1994)
![Page 24: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/24.jpg)
Today’s Chemical Engineering24
Why study Thermo of mixtures: MotivationWhy study Thermo of mixtures: Motivation-Example, i.e. SCF measurements, others?-UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc)-Simulators: AspenPlus, Fluent, Comsol, ChemSep, others.
![Page 25: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/25.jpg)
Today’s Chemical Engineering25
Why study Thermo of mixtures: MotivationWhy study Thermo of mixtures: Motivation-Example, i.e. SCF measurements, others?-UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc)-Simulators: AspenPlus, Fluent, Comsol, ChemSep, others.
![Page 26: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/26.jpg)
Today’s Chemical Engineering26
Why study Thermo of mixtures: MotivationWhy study Thermo of mixtures: Motivation-Example, i.e. SCF measurements, others?-UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc)-Simulators: AspenPlus, Fluent, Comsol, ChemSep, others.
![Page 27: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/27.jpg)
Course Overview27
![Page 28: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/28.jpg)
Course Overview28
![Page 29: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/29.jpg)
Course Overview29
![Page 30: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/30.jpg)
Course Overview30
Chapter 5- Thermodynamic Web- Departure Functions- Review Equations of state (chapter 4, briefly)
Chapter 6Chapter 6- Equilibrium (chemical potential)
* Pure Component* Mixtures
Ch t 7Chapter 7- Fugacity (chemical potential fugacity equilibrium calculations)
* Vapor (overview), liquid, solids- Activity Coefficients [Fugacity Coefficients (overview)]y [ g y ( )]
Chapter 8- Phase Equilibrium
* Diagrams* Vapor Liquid (VLE)* Vapor – Liquid (VLE)* Liquid – Liquid (LLE)* Solid – Liquid (SLE)
Chapter 9- Reaction Equilibria
![Page 31: Chemical engineering thermo 2](https://reader030.fdocuments.net/reader030/viewer/2022020110/558fcfd61a28ab4b1b8b4611/html5/thumbnails/31.jpg)
Questions?31