Chemical and Physical Features of Seawater and the World Ocean
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Transcript of Chemical and Physical Features of Seawater and the World Ocean
Chemical and Physical Features of Seawater and the World Ocean
“If there is magic on this planet, it is contained in water.”Loren Eiseley
“Well, me don’t swim too tough so me don’t go in the water too deep.”Bob Marley
What is Water ?
Introduction – the stuff covers 70% of the Earth Brainstorming activity Chemical & Physical Properties of Water Categorization activity Defend your categories If time permits… why the answer to life is
104.5º
Chemical & Physical Properties Physical property – properties that describe a
substance without changing the identity of the substance.
Physical change – change that does not result in the production of a new substance, only the appearance of the substance
Chemical property – properties that describe how a substance changes into a completely different substance
Chemical change – change that results in the production of another substance
Common Properties of WaterPhysical Properties Chemical PropertiesCohesion/Surface tensionFound in all three states on the earth
Universal Solvent – dissolves more substances than any other common liquid
Conduction of heat – highest of all liquids (except for mercury)
pH – water dissociates into anions (OH-) and cations (H+)
Latent heat of vaporization – highest of all common substances
Polarity – water has positive and negative ‘ends’
Latent heat of fusion – high for a molecule of its size (melting/freezing)
Hydrophobic effect
Heat capacity – highest of all common solids & liquids
Density – max at 4ºC for pure water
Viscosity –relatively low for a liquid
ReferencesCastellano, A. (2006) “Victoria Beach”Castro, P. & M.E. Huber (2005) Marine Biology, 5th ed. McGraw-Hill Higher
Education, Boston, MA.“Chemical Properties of Water” PlanetWater.au.com Retrieved on Feb 3, 2007
from www.ozh2o.com/index.html“floating water 5” (2006) westerLower, S. (2007) “H2O a gentle introduction to the structure of water.” Retrieved
on Feb 3, 2007 from http://www.chem1.com/acad/sci/aboutwater.htmlNybakken, J.W. & M.D. Bertness (2005) Marine Biology, An Ecological
Approach, 6th ed. Pearson Education, Inc., San Francisco.Perlman, H. (2006) “Water properties” Water Science for Schools. USGS.
Retrieved on Feb 3, 2007 from http://ga.water.usgs.gov/edu/waterproperties.html
Petrucci, R.H. (1982) General Chemistry Principles and Modern Applications, Macmillan Publishing Co. Inc., New York.
The Water Molecule
Two hydrogen atoms, one oxygen atom
H atoms form 105º angle This angle produces an
asymmetrical dipole. Slight (+) charge on the H atoms and slight (-) charge on the O atoms.
O
HH
105º
The Water Molecule These slight charges cause the
(+) H atoms of one water molecule to attract the (-) O atoms of other water molecules.
These weak bonds are called hydrogen bonds.
Water can hydrogen bond with other substances aside from itself.O
H
H
O
HH
O
H
H
Why does ice float? Density-Temperature Relationship
Background Temperature is a measure of kinetic energy (KE). As
KE decreases, hydrogen bonds stay formed and break less. Water molecules stay closer together until…
Explanation As the temperature approaches 4ºC, less dense ice
clusters begin to form in the liquid. At 0ºC when all water molecules become locked in
the rigid ice lattice, the hydrogen bonds actually hold molecules farther apart than at 4ºC. This creates spaces making the water less dense.
Why does ice float? Density-Temperature Relationship Graph
The cohesion or mutual attraction of water molecules creates a flexible barrier on the surface of water.
This helps support aquatic insects such as water striders (Halobates sp.)
How can water bugs “stride” across water without breaking the surface?Surface tension and cohesion
www.nps.gov/olym/insect/gerridae.jpg
Why do fish not get electrocuted when lightning strikes the ocean? Conductivity
Explanation Conductivity is a property that measures the ability of a
substance to transmit heat, electricity, or sound. Pure water is not a good conductor of electricity. Its
conductivity is about 20 dS/m. (Compare with silver – the highest conductivity with 63 x 106 S/m)
In addition, the electrical charge of lightning usually spreads instantaneously along the surface of the water from the location of the strike and to a lesser degree below the surface at the strike site. Fish in other areas are not affected.
Background Heat – energy of molecular motion Water can absorb or give up heat by
conduction (molecular exchange of heat) or convection (mixing)
Explanation Water can hold heat longer and
release heat more slowly than land. Temperature differential between land
and ocean will cause uneven heating of air masses which drive winds and moderate any drastic temperature changes.
Why do coastal areas have slower temperature changes than inland areas?Heat capacity
Off-shore breeze
On-shore breeze
Fats and oils are nonpolar molecules.
These compounds do not have slight regions of charge like water does.
Therefore water molecules are not attracted to nonpolar molecules and actually can be repelled by them.
Basis for cell membranes and the water repellency of marine mammals and birds.
Why don’t fats and oils dissolve in water?Polarity
Because water is polar, it dissolves most substances, especially other polar molecules and compounds composed of ions, atoms or molecules that carry an electrical charge.
These ionic compounds are often called salts.
NaCl (salt) most common dissolved salt in ocean. There are many others.
Seawater is a solution of these salts.
Why does water dissolve more substances than any other common liquid?The Universal Solvent
Salt crystal
SeawaterSources of salts and dissolved solids: Erosion of rocks and soil Solutes released from rivers Breakdown of organisms Condensation of rain from the atmosphere Releases from hydrothermal vents
Seawater is 96.5% water 3.5% dissolved compounds
Salinity
Measured in parts per thousand (ppt) Grams of salt left behind when 1000g of water evaporate
Average value 35 ppt or 35‰ Range from 0‰ near river mouths to 40% in the dead sea. Globally, seawater salinity remains constant. Rule of
constant proportions states that the percentage of various ions in seawater remains constant.
Total amount of dissolved salts in seawater.
Surface Salinities of the Oceans
Dissolved compounds in seawater Inorganic substances (salts, nutrients) Dissolved gases Organic compounds (fats, oils, vitamins,
amino acids, proteins) Nitrates and phosphates (usually in
excess as pollution) Pollution (DDT, PCBs, chlorinated
hydrocarbons that are synthetic)
Dissolved Gases
Primarily nitrogen, carbon dioxide, oxygen N2 biologically inert. CO2 needed for photosynthesis and pH
buffering. O2 required for respiration.
Factors that Affect Salinity Salinity increases due to…
freezing of seawater. evaporation.
Salinity decreases due to… melting of icebergs and sea ice. precipitation. run-off from rivers.
pH The amount of hydrogen ions in a
substance is referred to as pH. pH = (pondus hydrogeni or “power of
hydrogen” pH = -log10 [H+] Scales ranges from 0 to 14.
Therefore, a pH of 14 means that the water is very alkaline (basic) while pH 1 means it is acidic. A pH of 7 is neutral.
http://bangordailynews.com/2011/10/07/environment/shellfish-harvesters-plagued-by-acidic-%E2%80%98dead-muds%E2%80%99/
Seawater pH The carbonic acid – bicarbonate – carbonate system
keeps seawater at a pH value between 7.5 and 8.4. The oceans are an enormous “sink” for atmosphere
CO2
The Carbon Buffering System
Seawater has an unusually large capacity to absorb CO2.CO2 + H2O H2CO3 (carbonic acid)
H2CO3 H+ + HCO3 – (bicarbonate ion)
HCO3 – H+ + CO32- (carbonate ion)
Ocean Acidification
http://www.nrdc.org/oceans/acidification/aboutthefilm.asp
http://bangordailynews.com/2011/10/07/environment/shellfish-harvesters-plagued-by-acidic-%E2%80%98dead-muds%E2%80%99/
Work Cited
Kreger, Chris. "Acid Mine Drainage: Alkalinity." Exploring the Environment: Water Quality. 2004. Wheeling Jesuit University. 2 Oct 2008 <http://www.cotf.edu/ete/modules/waterq/wqalkalinity.html>.
Lower, Stephen. "A gentle introduction to water and its structure." H2O. 2008. 1 Oct 2008 <http://www.chem1.com/acad/sci/aboutwater.html>.
"October 2006 Archives." [Weblog The Marine Electronics Weblog] Oct 2006. Panbo . 1 Oct 2008 <http://www.panbo.com/archives/2006_10.html>.
Water Conductivity. 2008. Lenntech Water Treatment & Purification B.V.. 1 Oct 2008 <http://www.lenntech.com/water-conductivity.htm>.
Woodruff, Steve W.. "Water & Weather." Los Angeles Pierce College Weather Station. 1 Oct 2008 <http://data.piercecollege.edu/weather/water.html>.