Characterization of indoor and outdoor sub-micron...
Transcript of Characterization of indoor and outdoor sub-micron...
Characterization of indoor and outdoor sub-micron particles (PM1) in Edmonton homes
AWMA CPANS Edmonton LuncheonUniversity of Alberta Faculty Club, Edmonton, AB
April 1, 2016
Md. Aynul Bari, Dr.-Ing.School of Public Health, University of Alberta
Edmonton, AB
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Levels of air pollution exposure measurement
(Ambient)
Street Level Backyard
(Indoor)
(Personal)
IV III II I
(Near-field outdoor)
3Background
Indoor air quality is an important determinant of health.
Several studies have been conducted across Canada (e.g., Quebec City, Windsor, Regina, Halifax etc.) in order to compare baseline data and upgrade Health Canada’s Indoor Air Quality Guidelines.
Most epidemiological studies assume outdoor air as a risk factor and are not free from bias because they ignore exposure from indoor air quality.
4Indoor Environment and Time-Activity –Mean Amounts of Time Spent in Various
Microenvironments for North American Adults
87% total time indoors69% time at home
88% total time indoors64% time at home
Leech et al. 2002. J. Exp. Anal. Environ. Epidemiol., 12, 427-432
5Emission sources of sub-micron particles
Biomass burning (wood stoves/fireplaces)
Particle diameter (µm)
0
20
40
60
80
100
Par
ticle
mas
s (%
)
<0.50.5–0.6
0.6–1.01.0–2.1
2.1–3.33.3–4.8
4.8–7.17.1–11.4
>11.4
Manually-fed chimney stovePM: 284 – 338 mg/m³
Modern pellet stove, PM: 17 mg/m³
More than 80% of emitted PM has a size fraction of < 1 µm
Bari et al., 2011. Atmospheric Environment 45, 7627-7634
Vehicle emissions
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Objective
Characterize indoor and outdoor levels and sources of
sub-micron particles (PM1) at Edmonton homes.
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Bari et al., 2015. Environmental Science & Technology 49, 6419–6429
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National Pollutant Release Inventory, 2015 (http://www.ec.gc.ca/inrp-npri/)
Industrial sources reporting to Environment Canada’sNational Pollutant Release Inventory (NPRI)–
Edmonton and Surrounding Region
Google Earth (Image IBCAO © 2013 Google)
Wabamun Lake
Fort Saskatchewan
Edmonton
Lehigh cement plant
Imperial oil
SUNCOR
Industrial Heartland of Alberta
Coal combustion sources related to power generation
Generating Plants
9Methodology: Indoor/outdoor sampling
Winter: Jan–Apr (n =50) Summer: Jul – Aug (n = 50) 74 non-smoking homes
Nine consecutive 7-day sampling period per season (5-6 homes per period).
OX- Oxford
WM-Westmount
SA-Spruce Avenue
PD-Parkdale
TC-Thorncliff
GB-Gold Bar
OT-Ottewell
ST-Strathearn
FH-Falconer Heights
TT-Terwillegar Towne
TS-Terwillegar South
Homes sampled were stratified by age – residences grouped into five construction year strata.
≤ 19461946 – 1960 1961 – 1980 1981 – 2000 ≥ 2001
NAPS: National Air Pollution Surveillance
OX
TC
FH
TS
TT
PDSAWM
ST OT
GB
Winter
NAPS
2010
10
Baseline Questionnaire data:• Year of construction.• Heating and cooking systems.• Attached or detached garage.• Supplemental heating-wood stoves/fireplace.• Carpets in bed rooms and living rooms.• Nearby outdoor sources.
Daily Diary Questionnaire data:• Environmental Tobacco Smoke (ETS); burning of candles,
incense.• Window opening and air conditioner use • Any cleaning activities e.g., vacuuming, dusting, sweeping.• Car idling in the garage.• Cooking (type, duration) and use of exhaust fan.• Barbeque use.• Use of stoves to fry, grill, burn foods.
Methodology – Questionnaires
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Seven consecutive 24 h PM sampling (PM1, PM1-2.5, M10-2.5) using Harvard coarse mode impactor (HCI)
Outdoor
Methodology – PM1 sampling and analysis
Chemical analysis
34 heavy and trace metals
Energy dispersive X-ray fluorescence (ED-XRF)
Inductively coupled plasma mass spectrometry (ICP-MS)
Indoor/outdoor sampling
Harvard coarse impactor
12Results: Data quality
Winter SummerN = 27 Indoor Outdoor Indoor Outdoor
BDL (%) BDL (%) BDL (%) BDL (%)PM1 8 4 20 10
Silver (Ag) 0 12 5 24Aluminum (Al) 19 17 13 11Arsenic (As) 3 1 0 0
Boron (B) 27 19 0 0Barium (Ba) 11 7 14 8Bismuth (Bi) 17 8 27 27Calcium (Ca) 5 4 19 27
Cadmium (Cd) 39 34 19 12Chlorine (Cl) 36 26 29 18Cobalt (Co) 19 11 41 40
Chromium (Cr) 47 66 41 47Copper (Cu) 40 50 18 19
Iron (Fe) 0 0 6 4Potassium (K) 7 1 7 4
Magnesium (Mg) 2 1 22 24Manganese (Mn) 0 0 0 0
Molybdenum (Mo) 19 7 5 3Sodium (Na) 12 17 46 50Nickel (Ni) 60 70 48 46Lead (Pb) 24 4 14 8Sulfur (S) 0 0 0 0
Antimony (Sb) 1 1 0 0Silicon (Si) 9 2 14 29
Tin (Sn) 22 61 2 58Thallium (Tl) 23 6 24 16Vanadium (V) 7 1 3 1
Zinc (Zn) 7 2 16 8
No blank correction (>50% of blanks are below detection limit (BDL).
First four 7-day sampling periods in winter were invalid and excluded.
13Results – Data quality (precision)
y = 0.997x + 0.09R² = 0.9917
0
25
50
75
100
0 25 50 75 100N
APS
2 co
ncen
trat
ion
(µg/
m3 )
NAPS1 concentration (µg/m3)
Summer (n =60)
y = 0.854x + 0.67R² = 0.8863
0
10
20
30
40
50
0 10 20 30 40 50
NA
PS2
conc
entr
atio
n (µ
g/m
3 )
NAPS1 concentration (µg/m3)
Winter (n = 33)
% difference: Median 14.7 (IQR: 6.8, 49.0)
% difference: Median 15.4 (IQR: 4.4, 38.2)
• Duplicate sampling (~10% of total sampling) at NAPS station.
14Home characteristics
Characteristics Winter (n = 26)
Summer (n = 50)
Attached home 3 (12%) 3 (6%)
Attached garage with connecting door to home 8 (32%) 17 (34%)
Detached garage 17 (65%) 32 (64%)
Air conditioning operation – 13 (26%)
Carpet in home 25 (100%) 46 (98%)
Windows open at least one day during monitoring 23 (88%) 50 (100%)Visitor smoking at home at least one day during monitoring 3 (12%) 1 (2%)Visitor smoking outside home at least one day during monitoring 8 (32%) 9 (18%)Barbeque use – 31 (62%)Anyone left cars idling at least one day during monitoring 6 (24%) 9 (18%)Electric cooking stove use 22 (88%) 41 (42%)Anyone used stove to sauté, fry or grill 23 (88%) 45 (90%)Anyone burned food at least one day during monitoring 7 (27%) 14 (28%)
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Characterization of PM1
16Results – PM1 levels-Box Plot
0.1
1
10
100
PM1
(µg/
m3 )
Indoor(n = 173)
Indoor(n = 329)
Outdoor (n = 319)
Outdoor(n = 177)
Maximum
75th percentile
Median
25th percentile
Minimum
Winter SummerPM1 2010
17Temporal profiles of indoor and outdoor PM1
05-A
ug
25-F
eb
09-M
ar
20-M
ar
31-M
ar
09-A
pr
03-J
un
24-J
un
14-J
un
05-J
ul
16-J
ul
26-J
ul
17-A
ug
26-A
ug
0.1
1
10
100
1000
PM1
(µg/
m3 )
Outdoor Indoor2010 PM1SummerWinter
Maximum
75th percentile
Median
25th percentile
Minimum
Geometric mean
18
0
50
100
150
200
24h
conc
entr
atio
n (µ
g/m
3 )
PM1OutdoorIndoor 2010 IAQ study
Influence of wildfires smoke on indoor and outdoor air quality in Edmonton
Edmonton, August 19, 2010, 2:16 pm
Edmonton, March 12, 2010
BC wildfiresAugust 18, 2010
19Variability in indoor/outdoor (I/O) ratios by home
0.01
0.1
1
10
100
1000
25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
Dai
ly I/
O ra
tio
Home ID
0.01
0.1
1
10
100
1000
19 49 51 5 34 31 11 21 10 43 52 53 55 57 56 54 33 7 4 6 25 20 58 59 40 15 27 28 37 36 30 63 61 62 65 64 66 23 50 69 42 68 70 18 67 71 73 74 72
Dai
ly I/
O ra
tio
Home ID
February
Summer
March April
Winter
June March April
Median = 0.62
Median = 1.24
20Influence of particle infiltration
0.0
0.5
1.0
1.5
2.0
2.5
25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 46 48 49 50
F inf
Home
0.0
0.5
1.0
1.5
2.0
2.5
4 5 6 7 10 11 15 18 19 20 21 23 25 27 28 30 31 33 34 36 37 40 42 43 49 50 51 53 55 56 58 59 61 63 65 66 67 68 69 71 72 73
F inf
Home
SummerMedian = 0.78
WinterMedian = 0.45
Infiltration factor, Finf P = particle penetration coefficienta = air exchange rate (per hour) k = particle loss rate (per hour)
Estimates of FinfTracer-based method (e.g., using sulfur ratio)
21
Source apportionment of PM1 elements
22Analytical Approach for PM1 Source
Identification/Verification
Source Identification: multivariate analysis…US EPA positive matrix factorization (PMF)
Source Verification: ‘local’ source influence…conditional probability function (CPF) plots
‘regional’ source influence…air parcel backward trajectories w/NOAA HYSPLIT[potential source contribution function (PSCF) plots]
statistical correlation w/measured air pollutants…Pearson correlations
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Source-compositions
Source-impacts
Receptor Model(e.g., PMF, PCA, CMB)
Receptor (monitor)
Multivariate analysis: Receptor modeling
U.S. EPA Positive matrix
factorization (EPA PMF3.0).
based on analysis on correlation between measured chemical species in a number of samples (n >100).
oPCA: Principal component analysis
oPMF: Positive matrix factorization
CMB: Chemical mass balance
Edmonton IAQ study: Indoors (n = 254) Outdoors (n = 275) Pooled (n = 529) No. of elements: 27
Source Identification
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Sources Outdoor contributions
Factor 1 Secondary sulfate 42.8%
Factor 2 Soil 18.7%
Factor 3 Biomass smoke & ETS 17.1%
Factor 4 Traffic 4.3%
Factor 5 Settled and mixed dust 3.7%
Factor 6 Coal combustion 3.6%
Factor 7 Oil and gas industry 2.4%
Factor 8 Road salt/ road dust 2.6%
Factor 9 Urban mixture 5.0%
Sources of elements in PM1 mass in Edmonton homes
Indoor contributions
43.9%
15.8%
17.8%
2.9%
3.9%
2.7%
2.1%
1.2%
2.0%
Factor 10 Carpet dust Indoor
Factor 11 Cu-factor Indoor
Factor 12 Ag-factor Indoor
4.3%
1.7%
1.6%
Outdoor model Pooled indoor/outdoor model
Source Identification
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Con
cent
ratio
ns o
f spe
cies
app
ortio
ned
to fa
ctor
% o
f spe
cies
app
ortio
ned
to fa
ctor
PMF-derived source profile
Secondary sulfate
0
40
80
0.00010.0010.010.1
1EM
-PM
1A
g Al
As B Ba Bi
Ca
Cd Cl
Co Cr
Cu Fe K
Mg
Mn
Mo Na Ni
Pb S Sb Si Sn Tl V Zn
Indoor concentration of species Outdoor concentration of speciesindoor % of species Outdoor % of species
0
40
80
0.0001
0.001
0.01
0.1
1
EM-P
M1
Ag Al
As B Ba Bi
Ca
Cd Cl
Co Cr
Cu Fe K
Mg
Mn
Mo Na Ni
Pb S Sb Si Sn Tl V Zn
Secondary sulfate
Oil and gas industry
0
40
80
0.00010.001
0.010.1
1
EM-P
M1
Ag Al
As B Ba Bi
Ca
Cd Cl
Co Cr
Cu Fe K
Mg
Mn
Mo Na Ni
Pb S Sb Si Sn Tl V Zn
Cu-factor
Source Identification
26Performance of PMF model
y = 0.72x + 0.08R² = 0.82p = 0.03
0
0.5
1
1.5
2
2.5
0 0.5 1 1.5 2 2.5
Mod
eled
tota
l PM
1 el
emen
ts (µ
g/m
3 )
Measured total PM1 elements (µg/m3)
Indoor
y = 0.82x + 0.08R² = 0.87p = 0.04
0
0.5
1
1.5
2
2.5
0 0.5 1 1.5 2
Mod
eled
tota
l PM
1 el
emen
ts (µ
g/m
3 )
Measured total PM1 elements (µg/m3)
Outdoor
Source Identification
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Local sources are likely to be located in the directions that have high conditional probability values.
Local source identification: Conditional probability function (CPF)
Uses hourly wind direction data along with daily averaged source contributions to identify the likely sources contributing to a given factor.
Edmonton
Wind rose
0.10.2
0.30.4
0.50.6
probability
CPF
Wind directions corresponding to the highest source contributions.
Threshold criterion: highest 25% (i.e, 75th percentile) of the contributions.
Source Verification
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Secondary nitrate
Example of analysis for local source identificationConditional probability function (CPF)Industrial Heartland of Alberta
Oil and gas industryTraffic
Edmonton
Imperial oil
SUNCOR
Source Verification
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Backward trajectoryNational Oceanic and Atmospheric Administration (NOAA) Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT)48 to 96-hr backward trajectories
Potential Source Contribution Function (PSCF)
0.5˚ x 0.5˚ latitude and longitude
72-hr backward trajectories
Threshold criterion: 75th percentile (highest 25%) of the contributions
Example of analysis for potential long-range sourcesSource Verification
30Example of analysis for long-range sourcesBackward trajectory
Biomass smoke & ETS
Williams Lake, BCAugust 18-22, 2010
PSCF
Edmonton
BC wildfiresAugust 18, 2010
Source Verification
31Correlation (Pearson coefficient) of outdoor sourceswith other pollutants and meteorological parameters
Possible sources OC EC NO2 SO2 Benzene Toluene Acetaldehyde Temperature
Secondary sulfate 0.06 0.06 0.05 0.03 0.05 -0.08 -0.08 -0.13*
Soil -0.23* -0.18** 0.40** 0.08 0.006 -0.01 -0.19** -0.40**
Biomass smoke & ETS 0.73** 0.71** -0.26** -0.26** 0.51** 0.001 0.29** 0.58**
Traffic 0.16* 0.05 0.47** 0.01 0.40** 0.15* -0.06 -0.11
Settled and mixed dust -0.08 -0.08 -0.05 -0.06 -0.08 -0.02 -0.03 0.05
Coal combustion 0.001 0.08 0.26** -0.001 0.28** 0.05 0.07 0.05
Oil and gas industry -0.01 -0.04 0.04 0.16** -0.02 -0.02 0.06 0.08
Road salt/road dust -0.1 -0.10 0.79** 0.08 0.34** 0.08 -0.16** -0.40**
Urban mixture 0.76** 0.79** 0.28** -0.18** 0.74** 0.07 -0.09 -0.15*
**Correlation significant at p = 0.01 *correlation significant at p = 0.05
Source Verification
32Influence of particle infiltration (slopes)
y = 0.44x - 0.01R² = 0.72
y = 0.70x - 0.06R² = 0.58
0
1
2
3
4
5
0 1 2 3 4 5
Secondary sulfate
winter summer
y = 1.06x + 0.23R² = 0.05
y = 1.9x - 0.07R² = 0.63
0
5
10
15
20
25
0 5 10 15 20 25
Biomass smoke and ETS
y = 0.24x + 0.13R² = 0.79
y = 0.69x + 0.01R² = 0.79
0
5
10
15
0 5 10 15
Traffic
y = 0.40x + 0.001R² = 0.92
y = 0.45x + 0.17R² = 0.84
0
5
10
15
20
25
0 5 10 15 20 25
Oil and gas industry
Indo
or c
ontri
butio
ns (µ
g/m
3 )
Outdoor contributions (µg/m3)
33Variability in outdoor sources across different neighborhoods
(p-values, one-way Wilcoxon score)Secondary sulfate Biomass smoke & ETS
TS' WM SA' ST GB' OX TS' WM SA' ST GB' OXTC 0.53 0.27 0.13 0.93 0.93 0.25 0.07 0.38 0.98 0.29 <0.01 0.14TS' 0.64 0.06 0.15 0.30 0.12 <0.01 <0.01 0.22 <0.01 <0.01WM 0.03 0.84 0.15 0.08 0.69 0.07 0.04 0.20SA' 0.02 0.36 0.70 0.27 0.01 0.03ST 0.73 0.25 <0.01 0.06GB' 0.59 0.81
Traffic Oil and gas industryTS' WM SA' ST GB' OX TS' WM SA' ST GB' OX
TC 0.84 <0.01 <0.01 <0.01 0.99 0.91 0.48 0.56 0.12 0.59 0.40TS' 0.96 0.02 <0.01 <0.01 0.70 0.50 0.41 0.23 0.48 0.33WM <0.01 <0.01 <0.01 0.35 0.77 0.13 0.21 0.14SA' 0.34 0.42 <0.01 0.20 0.59 0.85ST 0.70 <0.01 0.30 0.35GB' <0.01 0.61
OX- Oxford
WM-Westmount
SA-Spruce Avenue
OT-Ottewell
FH-Falconer Heights
TT-Terwillegar Towne
TS-Terwillegar South
PD-Parkdale
TC-Thorncliff
GB-Gold Bar
ST-Strathearn
Significant variation, p < 0.01
34Summary
The major sources of PM1 elements (more than two-third) were made up of secondary sulfate, soil and biomass smoke & ETS.
Secondary sulfate signal is multi-component.
Other minor outdoor sources contributed to one-quarter of elemental PM1 mass. These include: traffic, mixed dust, oil and gas industry, coal combustion, road-salt, and urban mixture.
Indoor-generated sources of PM1 elements: carpet dust, Cu-rich, Ag-rich.
Larger particle infiltration was observed during summer than winter.
35SPECIAL THANKS
University of Alberta Dr. Warren Kindzierski
Alberta Innovates-Technology Transfer (AITF)
Dr. Lance Wallace, Consultant, Santa Rosa, CA, USA
Thank You for your kind attention!
Health CanadaMarie-Ève HérouxDr. Amanda A. J. Wheeler Morgan MacNeillKeith Van RyswykMélissa St-JeanTae Maen Shin
36
Questions?