Chapter 16 Thermal Energy and Heat. 16.1 Thermal Energy and MatterThermal Energy and Heat 16.1...

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Chapter 16 Chapter 16 Thermal Energy Thermal Energy and Heat and Heat

Transcript of Chapter 16 Thermal Energy and Heat. 16.1 Thermal Energy and MatterThermal Energy and Heat 16.1...

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Chapter 16Chapter 16

Thermal Energy Thermal Energy and Heatand Heat

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16.1 Thermal Energy and 16.1 Thermal Energy and MatterMatter

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Work and HeatWork and Heat

Heat is the transfer of thermal Heat is the transfer of thermal energy from one object to another energy from one object to another because of a difference in because of a difference in temperature. temperature.

Heat flows spontaneously from hot Heat flows spontaneously from hot objects to cold objects. objects to cold objects.

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TemperatureTemperature

Temperature is a measure of how Temperature is a measure of how hot or how cold an object is hot or how cold an object is compared to a reference point. compared to a reference point.

Temperature is related to the Temperature is related to the average kinetic energy of the average kinetic energy of the particles in an object due to their particles in an object due to their random motions through space. random motions through space.

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As an object heats up, its particles As an object heats up, its particles move faster, on average. move faster, on average.

As a result, the average KE of the As a result, the average KE of the particles and the temperature particles and the temperature increase. increase.

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Why does heat flow from high to low Why does heat flow from high to low temperature? temperature?

Heat flow is by the transfer of energy Heat flow is by the transfer of energy in collisions. in collisions.

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High-energy particles lose energy, High-energy particles lose energy, and low-energy particles gain energy and low-energy particles gain energy during collisions. during collisions.

The collisions transfer thermal The collisions transfer thermal energy from hot to cold objects. energy from hot to cold objects.

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Thermal EnergyThermal Energy

Thermal energy is the total potential Thermal energy is the total potential and kinetic energy of all the particles and kinetic energy of all the particles in an object. in an object.

Thermal energy depends on mass, Thermal energy depends on mass, temperature, and phase of an object. temperature, and phase of an object.

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Figure 2 shows the particles in a cup Figure 2 shows the particles in a cup of hot tea and in a pitcher of of hot tea and in a pitcher of lemonade. lemonade.

The tea is at a higher temperature, The tea is at a higher temperature, but the pitcher of lemonade has but the pitcher of lemonade has many more particles. many more particles.

The pitcher of lemonade actually has The pitcher of lemonade actually has more thermal energy.more thermal energy.

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Thermal Contraction and Thermal Contraction and ExpansionExpansion

Thermal expansion is an increase in Thermal expansion is an increase in the volume of a material due to a the volume of a material due to a increase in temperature. increase in temperature.

Thermal expansion occurs when Thermal expansion occurs when particles of matter move farther apart particles of matter move farther apart as temperature increases. as temperature increases.

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Gases expand more than liquids and Gases expand more than liquids and liquids usually expand more than liquids usually expand more than solids. solids.

A gas expands more easily because A gas expands more easily because the forces of attraction in a gas are the forces of attraction in a gas are weaker.weaker.

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Specific HeatSpecific Heat

Specific heat is the amount of heat Specific heat is the amount of heat needed to raise the temperature of one needed to raise the temperature of one gram of a material by one degree gram of a material by one degree Celsius. Celsius.

The lower a material’s specific heat, the The lower a material’s specific heat, the more its temperature rises when a given more its temperature rises when a given amount of energy is absorbed by a given amount of energy is absorbed by a given mass. mass.

Specific heat is measured in joules per Specific heat is measured in joules per gram per degree Celsius (J/ggram per degree Celsius (J/gooC). C).

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The heat (Q) absorbed by a material The heat (Q) absorbed by a material equals the product of the mass, the equals the product of the mass, the specific heat, and the change in specific heat, and the change in temperature. temperature.

Q=mc∆tQ=mc∆t

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Specific HeatSpecific Heat

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Specific HeatSpecific Heat

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Specific HeatSpecific Heat

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Specific HeatSpecific Heat

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Q=mc∆tQ=mc∆t

m=Q/c∆tm=Q/c∆t

c=Q/m∆tc=Q/m∆t

∆∆t=Q/mct=Q/mc

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Measuring Heat ChangesMeasuring Heat Changes

A calorimeter is an instrument used A calorimeter is an instrument used to measure changes in thermal to measure changes in thermal energy. energy.

A calorimeter uses the principle that A calorimeter uses the principle that heat flows from hotter object to a heat flows from hotter object to a colder object until both reach the colder object until both reach the same temperature. same temperature.

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According to the law of conservation According to the law of conservation of energy, the thermal energy of energy, the thermal energy released by a test sample is equal to released by a test sample is equal to the thermal energy absorbed by its the thermal energy absorbed by its surroundings. surroundings.

Figure 4 shows how a calorimeter Figure 4 shows how a calorimeter can be used to measure specific can be used to measure specific heat.heat.

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16.2 Heat and 16.2 Heat and ThermodynamicsThermodynamics

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ConductionConduction Conduction is the transfer of thermal Conduction is the transfer of thermal

energy with no overall transfer of energy with no overall transfer of matter. matter.

Conduction occurs within a material Conduction occurs within a material or between materials that are or between materials that are touching. touching.

In conduction, collisions between In conduction, collisions between particles transfer thermal energy. particles transfer thermal energy.

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Conduction in gases is slower than in Conduction in gases is slower than in liquids and solids because the liquids and solids because the particles in a gas collide less often. particles in a gas collide less often.

In metals, conduction is faster In metals, conduction is faster because the electrons are free to because the electrons are free to move about. move about.

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Thermal ConductorsThermal Conductors

A thermal conductor is a material A thermal conductor is a material that conducts thermal energy well. that conducts thermal energy well.

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Thermal InsulatorsThermal Insulators

A material that conducts thermal A material that conducts thermal energy poorly is called a thermal energy poorly is called a thermal insulator. insulator.

Air is a very good insulator.Air is a very good insulator.

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ConvectionConvection

Convection is the transfer of thermal Convection is the transfer of thermal energy when particles in a fluid move energy when particles in a fluid move from one place to another. from one place to another.

A convection current occurs when a A convection current occurs when a fluid circulates in a loop as it fluid circulates in a loop as it alternately heats up and cools down. alternately heats up and cools down.

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RadiationRadiation

Radiation is the transfer of energy by Radiation is the transfer of energy by waves moving through space. waves moving through space.

All objects radiate energy. All objects radiate energy. As an object’s temperature As an object’s temperature

increases, the rate at which it increases, the rate at which it radiates energy increases.radiates energy increases.

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ThermodynamicsThermodynamics

The study of conversions between The study of conversions between thermal energy and other forms of thermal energy and other forms of energy is called thermodynamics. energy is called thermodynamics.

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Joule carefully measured the energy Joule carefully measured the energy changes in a system which included changes in a system which included a falling weight that turned a paddle a falling weight that turned a paddle wheel in a container of water. wheel in a container of water.

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As the weight fell, the paddle As the weight fell, the paddle churned a known mass of water. churned a known mass of water.

The water heated up due to friction The water heated up due to friction from the paddle. from the paddle.

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Joule found the work done by the Joule found the work done by the falling weight almost exactly equaled falling weight almost exactly equaled the thermal energy gained by the the thermal energy gained by the water. water.

The law of conservation applied to The law of conservation applied to work, heat, and thermal energy.work, heat, and thermal energy.

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First Law of First Law of ThermodynamicsThermodynamics

The first law of thermodynamics The first law of thermodynamics states that energy is conserved. states that energy is conserved.

If energy is added to a system, it can If energy is added to a system, it can either increase the thermal energy of either increase the thermal energy of the system or do work on the the system or do work on the system. system.

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Second Law of Second Law of ThermodynamicsThermodynamics

The second law of thermodynamics The second law of thermodynamics states that thermal energy can flow states that thermal energy can flow from colder objects to hotter objects from colder objects to hotter objects only if work is done on the system. only if work is done on the system.

A heat engine is any device that A heat engine is any device that converts heat into work. converts heat into work.

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One consequence of the second law One consequence of the second law is that the efficiency of a heat engine is that the efficiency of a heat engine is always less than 100%.is always less than 100%.

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The best an engine can do is to The best an engine can do is to convert most of the input energy into convert most of the input energy into useful work. useful work.

Thermal energy that is not converted Thermal energy that is not converted into work is called waste heat. into work is called waste heat.

A heat engine can do work only if A heat engine can do work only if some waste heat flows to a colder some waste heat flows to a colder environment outside the engine. environment outside the engine.

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Spontaneous changes will always Spontaneous changes will always make a system less orderly, unless make a system less orderly, unless work is done on the system. work is done on the system.

Disorder in the universe is always Disorder in the universe is always increasing. increasing.

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Third Law of Third Law of ThermodynamicsThermodynamics

The third law of thermodynamics The third law of thermodynamics states that absolute zero cannot be states that absolute zero cannot be reached. reached.