Chapter 01 Structure Determines...
Transcript of Chapter 01 Structure Determines...
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©2012 Gregory R Cook
Chapter 01Structure Determines
Properties
CHEM 341: Spring 2012
Prof. Greg Cook
cook.chem.ndsu.nodak.edu/chem341
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©2012 Gregory R Cook
Structure Determines Properties
• Mostly a review of general chemistry
• Atomic and Molecular Structure
• Bonding
• Polarity and Properties
• Acid/Base concepts
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©2012 Gregory R Cook
Structure
• The sequence of connections that defines a molecule, including the spatial orientation of these connections
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©2012 Gregory R Cook
Atoms, Electrons and Orbitals
Section 1.1
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©2012 Gregory R Cook
Subatomic Particles
• Nucleus is made up of Protons and Neutrons
• mass of Proton = 1.6726 x 10-27 kg
• mass of Neutron = 1.6760 x 10-27 kg
• Surrounding the Nucleus are electrons
• mass of Electron = 9.1096 x 10-31 kg << proton
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©2012 Gregory R Cook
Atomic Structure
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+-
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©2012 Gregory R Cook
Atomic Structure
• Electrons surround nucleus in orbitals
• Atomic Number (Z) = # protons in nucleus
• Mass Number (A) = # protons + # neutrons
• Atomic Weight = average mass of a large number of atoms
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+
-
XAZ H11 C12612.01071.0079
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©2012 Gregory R Cook
Wave Function
• Electrons have properties of both Particles and Waves
• Quantum Mechanics help us understand the structure and behavior of electrons
• Schrödinger Wave Equation
• Describes the energy of anelectron in an atom
• Wave functions ψ (psi)
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©2012 Gregory R Cook
Heisenberg uncertainty principle
• We can’t tell exactly where an electron is
• but we can tell where it will most likely be
• Probability of finding an electron at a particular spot relative to the nucleus is given by ψ2 (psi)2
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+
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©2012 Gregory R Cook
Orbitals
• Wave functions are also called orbitals
• each orbital characterized by 3 quantum numbers
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• n : principle quantum number
• l : angular momentum quantum number
• ml : magnetic quantum number
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©2012 Gregory R Cook
Quantum Numbers
• principle quantum number n
• an integer
• determines major part of orbital energy - the shell
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©2012 Gregory R Cook
s orbitals
• s orbitals are spherical in shape
• energy increases with n
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©2012 Gregory R Cook
Quantum Numbers
• Angular momemtum l determines the shape of the orbital
• for a given value of n : l = 0, 1, 2, , , n - 1
• l = 0 : s
• l = 1: p
• l = 2 : d
• l = 3 : f
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©2012 Gregory R Cook
p Orbitals
• p orbitals are shaped like dumbells with a node in between the lobes (n = 2 and higher)
• Three orbitals with the same energy
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©2012 Gregory R Cook
4th Quantum Number - Spin
• Each electron also has a spin quantum number ms
• +½ and -½
• Pauli Exclusion Principle - two electrons may occupy the same orbital only when they have opposite or “paired” spins.
• No orbital can contain more than 2 electrons
• H, He, Li
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©2012 Gregory R Cook
Electron Configuration
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©2012 Gregory R Cook
Periodic Table - Periods
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©2012 Gregory R Cook
Second Period Electron Configurations
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Z
Li 3
1s 2s 2p
C 6
N 7
O 8
Ne 10
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©2012 Gregory R Cook
Second Period Electron Configurations
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Z
Li 3
1s 2s 2p
C 6
N 7
O 8
Ne 10
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©2012 Gregory R Cook
Ionic BondsSection 1.2
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©2012 Gregory R Cook
Ions
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1s22s1 1s22s22p5
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Ionization
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1s22s1 1s22s22p5
Na Cl• ••• •• •
•
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©2012 Gregory R Cook
Ionization
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1s22s0 1s22s22p6
Na Cl• ••• •• ••+ -
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©2012 Gregory R Cook
Ionic Bond
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Na Cl• ••• •• ••+ -
• An ionic bond is a force of attraction between oppositely charged species (ions).
• Ionic bonds are common in inorganic compounds but are more rare in organic compounds.
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©2012 Gregory R Cook
Ionic Bond
24
Na Cl• ••• •• ••+ -
• An ionic bond is a force of attraction between oppositely charged species (ions).
• Ionic bonds are common in inorganic compounds but are more rare in organic compounds.
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©2012 Gregory R Cook
Ionization
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1s22s1 1s22s22p5
1s22s22p2
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©2012 Gregory R Cook
Covalent Bonds, Lewis Structures and the Octet
RuleSection 1.3
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©2012 Gregory R Cook
Covalent Bonds
• In 1916 G. N. Lewis proposed that atoms combine in order to achieve a more stable electron configuration.
• Maximum stability results when an atom is isoelectronic with a noble gas.
• An electron pair that is shared between two atoms constitutes a covalent bond.
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1s22s0 1s22s22p6
Na Cl• ••• •• ••+ -
He Ne
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©2012 Gregory R Cook
Covalent Bonding in H2
• Two hydrogen atoms each have one electron
• Instead of ionizing, they come together to share both electrons between them
• Sharing the electron pair allows both hydrogen atoms to have a filled orbital
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•H • H
•H • H
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©2012 Gregory R Cook
Covalent Bonding in F2
• Two fluorine atoms each have 7 valence electrons
• They can share them in a covalent bond
• Each fluorine atom has the same electron configuration as Ne (8 electrons)
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•F • F
F •• F••••• •
• •• •
• •
••
• •• • ••
• •• •
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©2012 Gregory R Cook
Octet Rule
• When forming compounds, atomswill gain, lose or share electrons togive a stable electron configurationcharacterized by 8 valence electrons
• The octet rule is most useful in cases involving covalent bonds to C, N, O and F
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F •• F••••• •
• •• •
• •
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©2012 Gregory R Cook
Example with CF4
• Carbon has 4 valence electrons, F has 7
• The Lewis structure for CF4
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•C • F•
•• ••
• •• •
•C •F••
• ••
• •• •
••F••• •
•
••F••
•• •
••F•• •
• •
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©2012 Gregory R Cook
Example with CF4
• It is more common to represent a covalent bond (shared pair of electrons) with a line
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•C •F•
•• ••
• •• •
••F••
• ••
••F••
•• •
••F•
• •• • F C F
F
F=
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©2012 Gregory R Cook
Example with CF4
• It is more common to represent a covalent bond (shared pair of electrons) with a line
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•C •F•
•• ••
• •• •
••F••
• ••
••F••
•• •
••F•
• •• • F C F
F
F=
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©2012 Gregory R Cook
Example with CF4
• We often don’t write the lone pairs (Kekulé structures)
• You should know how many lone pairs an atom should have!
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F C F
F
F
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©2012 Gregory R Cook
Double and Triple BondsSection 1.4
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Inorganic Examples
35
O C OO C O
H C NH C N
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Organic Examples
36
C CH
H
H
H
C C HH
Ethylene (Ethene)
Acetylene (Ethyne)
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©2012 Gregory R Cook
Polar Covalent Bonds, Electronegativity, and
DipolesSection 1.5
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©2012 Gregory R Cook
Electronegativity
• Electrons are not always shared equally between atoms in a covalent bond
• Electronegativity is a measure of the ability of an element to attract electrons toward itself when bonded to another element
• An electronegative element attracts electrons gathering negative charge
• An electropositive element releases electrons gathering a positive charge
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Pauling Electronegativity Scale
39
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©2012 Gregory R Cook
Electronegativity
• Increases from left to right and bottom to top (decreases going down a group)
40
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©2012 Gregory R Cook
EN Generality
• The greater the difference in EN between two bonded atoms, the more polar the bond
• Nonpolar bonds connect atoms with the same EN
41
H H Cl Cl O O
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©2012 Gregory R Cook
Polar Covalent Bonds
• Polar Covalent Bonds connect atoms that have different EN
• partial negative charges on atoms with higher EN and partial positive charges on atoms with lower EN
• Bond dipoles pointing from ∂+ toward ∂-
42
H F H O H O C Oδ+ δ- δ- δ- δ-δ+ δ+ δ+
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Electrostatic Potential Maps
• Electrostatic potential maps show the charge distribution within a molecule
43
H Fδ+ δ-
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Polar vs Ionic Bonds
44
A A A B A Bδ+ δ-
Covalent Ionicpolar covalent
δEN >2 IONIC BONDSδEN <2 COVALENT BONDS
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©2012 Gregory R Cook
Formal ChargeSection 1.6
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©2012 Gregory R Cook
Formal Charge
• The Formal Charge is the calculated charge for an atom in a Lewis structure on the basis of an equal sharing of bonded electron pairs
• When atoms have more or less number of bonds than their valency requires, they must have a charge that is not zero
• A formal charge is a way of keeping track of electrons and who owns them in a molecule
FC = (# valence electrons) - (# bonds) - (# nonbonded electrons)
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©2012 Gregory R Cook
Example HNO3
47
O N
O
OH
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More Examples
48
N
H
H
H
H
B
F
F
F
F
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©2012 Gregory R Cook
Structural Formula of Organic Molecules
Section 1.7
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Constitution
• The order in which the atoms of a molecule are connected is called its constitution or connectivity
• The constitution of a molecule must be determined in order to write a Lewis (or Kekulé) structure
• Isomers are different compounds with the same molecular formula
• Constitutional (structural) isomers differ in the order that atoms are connected
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Constitutional Isomers
• Take, for example, a compound with the formula C2H6O
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©2012 Gregory R Cook
Constitutional Isomers
• Take, for example, a compound with the formula C2H6O
51
C C O
H
H
H
H
H
H
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©2012 Gregory R Cook
Constitutional Isomers
• Take, for example, a compound with the formula C2H6O
51
C C O
H
H
H
H
H
H C O C
H
H
H
H
H
H
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Constitutional Isomers
• How many isomers of C3H7Cl are there?
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Constitutional Isomers
• How many isomers of CH3NO2 are there?
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