Cervantes 1 Conventional Oil Exploration Well Environment ...

Document Number: RCMA-02-EM-PLN-001SUMv5

Cervantes 1

Conventional

Oil Exploration Well

Environment Plan Summary

26/11/2020

RCMA-02-EM-PLN-001SUMv5 PAGE | 2 of 17

1. Terms & Abbreviations

Abbreviation Description

ALARP As low as reasonably practicable

ASL Above Sea Level

BKNR Beekeepers Nature Reserve

BOP Blow Out Preventer

DBCA Department of Biodiversity, Conservation and Attractions (formerly Department of Parks and Wildlife (DPaW))

DFES Department of Fire and Emergency Services

DMIRS Department of Mines, Industry Regulation and Safety (formerly Department of Mines and Petroleum (DMP))

EP Environment Plan

HSE Health, Safety and Environment

JPF Jingemia Production Facilities

Lead Contractor Contractor whose RCMA approved HSEMS will be utilised at the Project Location for management of the relevant phase of the Project

OSCP Oil Spill Contingency Plan

PEC Priority Ecological Community

RCMA RCMA Australia Pty Ltd

SDS Safety Data Sheet

SMART Specific, Measurable, Attainable, Relevant, Time-bound (Criteria)

VSP Vertical Seismic Profile

WBM Water Based Muds


2. Contact RCMA Project Manager PO Box 86 WEST PERTH WA 6872 E: [email protected]

3. Introduction RCMA Australia Pty Ltd (RCMA) proposes to drill the Cervantes 1 exploration well, 11 km south of Dongara/Port Denison in Production Licence L14 (Figure 1). The proposed site is located within the vegetated Beekeepers Nature Reserve (BKNR) in the northern Perth Basin (Figure 2). The proposed well will be deviated to avoid environmental sensitivities and will be drilled to a planned depth of 2,562 mTVD (true vertical depth). The well pad will occupy an area of approximately 2.6 ha with 4.1 km of existing road and tracks utilised for access. Site preparation operations are planned to commence in early quarter 1 CY2022, with drilling operations commencing late quarter 1 CY2022. RCMA is an Australian upstream oil and gas company that own and operate the Jingemia Production Facility (JPF), an onshore Perth Basin oil production facility situated in Petroleum Production Licence L14, 3 km from the Cervantes 1 Conventional Oil Exploration Drill Site. A Cervantes 1 Development would utilise the existing JPF Facilities.

3.1 Purpose The purpose of this document is to provide a summary of the Cervantes 1 Conventional Oil Exploration Well Environment Plan (EP) [RCMA-02-EM-PLN-001]. This summary document has been prepared to in accordance with the requirements of the Petroleum and Geothermal Energy Resources (Environment) Regulations 2012.

3.2 Environment Plan Implementation RCMA is the custodian of this EP and has overall responsibility for its implementation, compliance and revision.

mailto:[email protected]

Project Area

290000

290000

300000

300000

310000

310000

320000

320000

330000

330000

340000

340000

350000

350000 6690

000

6700

000

6700

000

6710

000

6710

000

6720

000

6720

000

6730

000

6730

000

6740

000

6740

000

6750

000

6750

000

6760

000

6760

000

6770

000

6770

000

Drawn: CAD Resources ~ www.cadresources.com.au Tel: (08) 9246 3242 ~ Fax (08) 9246 3202

Author: A. Wills, 0417993734, [email protected]

Date: Jan 2020 Rev: 0 A3CAD Ref: a2750_f04_01

Scale: 1:250,000MGA94 (Zone 50)

Figure:

.Cervantes 1 Regional Location 1

0 3,000 6,000mNotesImage: GSA

LegendDevelopment Envelope

!(

!(

LOCALITY

PROJECT AREA

WESTERNAUSTRALIA

PerthKalgoorlie

Acce

ss Tr

ack

Railway Crossing

Wellpad Including:Mud SumpTurkeys NestFlare PitGroundwater Monitoring BoreAbandonment Plaque

Hamersley Rd

Dong

ara - E

neab

ba R

ailwa

y

Jingemia

L 14

L 2 R1303000

303000

304000

304000

305000

305000

6750

000

6750

000

6751

000

6751

000

6752

000

6752

000

6753

000

6753

000

Drawn: CAD Resources ~ www.cadresources.com.au Tel: (08) 9246 3242 ~ Fax (08) 9246 3202Date: Mar 2021 A3

CAD Ref: a2750_f09_01

Scale: 1:12,500MGA94 (Zone 50)

Figure:

. 20 150 300mNotes

Image: Landgate (Nov 2016)Petroleum Data: DMIRS

LegendSite AccessSite B Swale Access Site B Swale Access ExitDrill Site and Fire BreaksProduction Licence


Rev: A

Cervantes 1 Conventional WellDrill Site & Access


4. Description of the Activity RCMA plan to drill the Cervantes 1 exploration well in late Q1 CY2022. The project will include the following key stages: • Site preparation:

o Establishment of hygiene station as per Hygiene Procedure [RCMA-02-EM-PRO-001] o Clearing and preparation of access tracks and drill site o Levelling, sheeting and preparation of surfaces to support compressive loads and

limit erosion to the existing landscape o Conductor drilling o Construction of lined mud sump, turkey’s nest, vertical seismic profile (VSP) pit and

well cellar o Baseline monitoring (soil and groundwater)

• Mobilisation of drilling package, ancillary services, site office, personnel and supplies • Drilling exploration program:

o Conducting the exploration drilling activities o Completion (and test) or abandonment of well

• Demobilisation of drilling package, ancillary services, site office, personnel and supplies • Decommissioning and rehabilitation:

o Restoration of the site following the completion of activities, if not considered commercially viable

o Handover site to operations for care and maintenance o Rehabilitation of decommissioned infrastructure

4.1 Timeframe and Schedule The indicative project timeframe and schedule is presented in Table 1.

Table 1: Proposed Timeline

Activity Approximate Duration Indicative Timing

Site Preparation ~30 days Early Quarter 1 CY2022

Mobilisation ~10 days Quarter 1 CY2022

Drilling 22 to 40 days Late Quarter 1 CY2022

Demobilisation ~10 days Quarter 2 2022

*The timeframe and schedules for subsequent phases of the Project (well completion, well testing, well intervention, development, care & maintenance, decommissioning, rehabilitation) will be determined based on drilling results.

Table 2 provides an overview of the activity detailed further in the remainder of Section 2.


Table 2: Cervantes 1 Well Summary

Feature Description

Site location ~300 km North of Perth and 11 km South of Dongara/Port Denison within the vegetated Beekeepers Nature Reserve

Permit L14

Approximate Well Surface Coordinates

Within development envelope shown in Figure 2: ~303 231 mE ~6 749 511 mN

Proposed mobilisation route

Truck movements via JPF and an upgrade to the access track along the railway line

Drilling timing Late Q1 CY2022

Estimate project duration 60 to 90 days

Planned total depth TD: ~2,562 mTVD

Project footprint

Access road: <4.0 ha (based on 4.1 km and 9 m cleared width) Workpad: <2.6 ha

Total Footprint: <6.6 ha (<4.5 ha requires clearing)

Drilling mud type Water-based mud (WBM)

Disposal of muds and cuttings

WBM and cuttings discharged into a lined sump during drilling and allowed to evaporate. Soil testing will determine appropriate method of disposal/reuse offsite

Accommodation Main camp located at an externally owned and operated camp on Pye Road, Dongara. On site camp will accommodate immediate response personnel

Hygiene Station

One vehicle and equipment hygiene station will be established on commencement of site preparation activities at the JPF. All vehicles, equipment and personnel will be required to undertake inspections when travelling to the Cervantes 1 clean on entry point

Water Supply Water will be supplied from the JPF ground water bore GWL202619(1)

Performance Bonds

• A Rehabilitation Performance Bond shall be in place prior to the implementation of the proposal until the rehabilitation has been completed

• A Post Rehabilitation Performance Bond shall be in place from rehabilitation until completion criteria are achieved

• A P&A Performance Bond shall be in place on commercial discovery of hydrocarbons until the well has been P&A


4.2 Site Preparation Access will be provided via upgrades to existing tracks from the JPF along the railway easement track and existing railway crossing (Figure 2). The well pad will be located within the development envelope and will possibly be located in the southern end as per Figure 2. The well site will include the following elements: • Cellar for drilling rig • Flare pit • Residual drilling fluid and cuttings storage pond (sump) • Water holding pond (turkey nest) / water storage tanks • Shallow groundwater monitoring bore • Workshop area and office space • VSP pit • Smoko shack • Generator set and pump skid unit • Toilet block and sewage holding tank • Parking for light vehicles, trucks and trailers • Fuel and chemical storage areas.

The overall cleared area is approximately 2.6 ha. This includes the well site (2 ha) that will be compacted along with an external area to cater for soil stockpiling and a fire break around the perimeter. Measures will be in place to reduce impacts of the operation on native fauna: • Installing fauna egress matting within the ponds (mud sump and turkey’s nest) • Installing fencing to deter ground-dwelling native fauna accessing the mud sump, turkey’s

nest and VSP pit. Fencing will remain around the drilling sump and turkey nest and be erected around the wellhead following completion of drilling operations until the infrastructure is decommissioned.

4.3 Vehicle Movement The drilling rig, ancillary services, personnel and supplies will be mobilised by road to the project area. Access is via the JPF utilising the Brand Highway. Vehicle and equipment movement will be restricted to the designated access tracks. There will be approximately 70-80 trailer loads moved during mobilisation and demobilisation. A crew change bus will be used to move personnel between Perth and the project location for rotational crew changes and between the offsite accommodation and drill site for shift changes. Utilisation of shared vehicles and a crew change bus will minimise vehicle movement to and from the site as much as practicable, minimising local traffic and vehicle-related safety and environment risks.

4.4 Drilling Once the drill rig is assembled on location, all activities associated with drilling (e.g. refuelling, mixing of drilling muds and cement) occur on the well pad. The project involves the following key stages: • Drilling the well with a rotary drilling rig using recirculated WBM (primarily (>97%) water,

and non-toxic additives; barite, potassium chloride, calcium carbonate, sodium chloride and bentonite)

• Conducting wireline logging evaluation of the formations drilled • Cementing well steel casing strings in place


• Plug and abandonment of the well (in a dry hole case) Rotary drilling is the process of utilising a drill string and drill bit to break small pieces of rock and remove these pieces of rock from the hole by circulating a fluid (drilling mud) down the drill string and up the annulus between the drill string and drilled hole. A blow out preventer (BOP) is installed once drilling is at a depth where it is possible for hydrocarbons to be intersected. The BOP (secondary well control) provides a mechanical means by which the well can be closed and secure the contents of the well should the mud system fail to maintain a positive pressure on the drilled hole. If hydrocarbons are intersected, and flow to surface is not prevented by the drilling mud, the BOP will be closed allowing a controlled release of these hydrocarbons to the flare pit. The flare pit and any firebreaks are constructed in compliance with any specific DFES permit requirements. All drilling fluids will be contained within the mud system. This system is constantly monitored by personnel and pit level sensors for volume changes. The chemicals proposed for use in the Cervantes 1 program are disclosed within Appendix A. The disclosure tables have been prepared in accordance with the guideline and the Chemical Disclosure Reporting template provided for within the guideline. The chemical disclosure tables cover the following ‘down-hole’ activities: • Drilling (WBMs) • Cementing

The Safety Data Sheets (SDSs) for the chemicals associated with the Cervantes 1 activities are provided in Appendix B.

4.5 Chemicals and Materials Storage, Handling and Transfers All chemicals and hazardous materials required for the project will be appropriately packaged and delivered to the rig site in tanks, pails or drums, sealed bags and where appropriate stacked and secured on pallets. All chemicals and hazardous materials will be transported as required by regulation according to the material class and associated specific transportation advice. All transported materials shall be accompanied by a current SDS. Oil, fuel, and hazardous liquid chemicals will be stored in the bunded chemical storage area on the well pad. All chemicals will be stored in accordance with the requirements of their relevant SDS. SDSs for each chemical used and stored onsite are held in the site office. On site oil, fuel, and hazardous liquid chemicals will be bunded to contain not less than 110% of the volume of the largest vessel and at least 25% of the total substance stored (where more than one storage is connected to a common compound, drainage tank or similar storage vessel)). This includes waste hydrocarbon products. Dry chemicals will be stored off the ground on pallets and covered with tarpaulins to maintain product integrity during wet conditions. Empty hazardous liquid chemical containers or drums will be stored within the waste storage area.

4.6 Well Testing If the Cervantes 1 well proves successful and further evaluation through well testing is required, the additional evaluation phases of the Cervantes 1 well operations would commence as soon as reasonably possible. These would be expected to continue over a period of 1 month during Q3 2022 with actual duration determined based on the acquired evaluation data. This would include operations such as wellbore clean out, completion installation, well test operations, production logging evaluation, and other associated well intervention activities as specified in the well completion and testing programme to complete this evaluation phase of the project.

4.7 Waste Management Waste will be segregated and stored within designated areas and disposed via an approved waste disposal contractor in accordance with Table 3. Waste receptacles will be clearly labelled and have


adequate covering (noting that the steel recycling skip bin does not need to be covered). Records will be retained for all waste disposal events.

Table 3: Waste Disposal Details

Waste Product Method of Disposal

Casing protectors (plastic) Placed into rubbish skip and removed off site by waste contractor.

Batteries Stored in central location and removed offsite to nearest recycling centre by waste contractor.

Cigarettes Disposed to dedicated receptacle and removed off site by waste contractor.

Contaminated Soil Contained on site and removed by a licensed contractor to a licensed facility in accordance with Landfill Waste Classification and Waste Definitions 1996 (as amended) (DEC 2009).

Cuttings/mud

Drilling muds and cuttings will be taken for offsite reuse or disposal. The water within the muds and cuttings in the drill sump will be allowed to evaporate and soil testing undertaken to determine appropriate method of disposal or reuse.

Drilling line Placed into rubbish skip and removed off site by waste contractor.

Food waste Placed into rubbish skip and removed off site by waste contractor.

Hazardous waste (solid)

Placed in appropriately labelled receptacles within a bunded area and removed off site for disposal by a licensed contractor at a licensed facility in accordance with Landfill Waste Classification and Waste Definitions 1996 (as amended) (DEC 2009).

Metal drums Placed in central location and removed off site by waste contractor.

Mud sacks Placed into rubbish skip and removed off site by waste contractor.

Mud sump liner Taken by truck to landfill.

Plastic products Placed into rubbish skip and removed off site by waste contractor.

Refrigeration gas Recovered by licensed refrigeration electrician/mechanic and returned to authorised agent for disposal.

Sewage (greywater and black water)

Rig: Septic holding tank for offsite disposal by waste contractor.

Camp: On-site septic system (as per existing)

Steel scrap (including steel casing protectors and drill line)

Placed in one central area after use/removal. Then placed into steel bin and removed off site by waste/recycling contractor.

Tyres & rubber products Placed into rubbish skip and removed off site by waste contractor.


Waste Product Method of Disposal

Waste oil Placed into empty oil drums and removed from site by a licensed waste contractor. While stored on site, waste oil will be stored within a bunded area.

Wooden pallets Placed into rubbish skip and removed off site by waste/recycling contractor.

4.8 Care and Maintenance If the Cervantes 1 well is successful, it will be suspended while development plans and approvals are sought. In the period prior to start-up of a new development, the Cervantes 1 well will be handed over to JPF personnel. The project area will be inspected weekly and any actions that cannot be addressed immediately will be tracked to completion. Weed control will be undertaken as part of Care and Maintenance (C&M) Activities. As per Table 4, Cervantes 1 will be under Care and Maintenance (C&M) Activities from rig demobilisation until rehabilitation has met completion criteria.

Table 4: Cervantes 1 Future Timeframe

Activity Indicative Timing

Demobilisation of Rig Q2 CY2022

Well Testing1 Quarter 3 / Quarter 4 CY2022

Commence decommissioning of the railway access track3 Quarter 4 CY2022

Well (Future) Decision for Development1 Quarter 4 CY2022

Well (Future) Decision for P&A Quarter 4 CY2022

Undertake P&A of well2 Dependent on rig availability (within 12 months from decision to P&A)

Finalise Rehabilitation Plan First summer following P&A (eg Quarter 1 CY20233)

Mud Sump Decommissioning Quarter 1 CY2023

Rehabilitation First autumn following P&A (eg Late Quarter 1 / Early Quarter 2 CY20233)

Remove marl

Deep ripping and surface cultivation

Complete, topsoil return and vegetation material spreading (March CY2023)

Initial establishment monitoring for erosion, weeds and plant establishment

(June/July CY2023)


Activity Indicative Timing

Conduct weed control if required (August CY2023)

Establish rehabilitation performance monitoring quadrats and assess (September/October CY2023)

Year 2 Post Rehabilitation Activity – Monitoring Program

Year 3 Post Rehabilitation Activity – Monitoring Program

Year 4 Post Rehabilitation Activity

Anticipate completion criteria achieved in Year 3 Contingency for rectification and further monitoring

1 If well is suspended at time of drilling rather than P&A 2 If decision is made to P&A well 3 If well is P&A at time of drilling

4.9 Decommissioning and Rehabilitation Decommissioning will involve the removal of the mud sump contents, mud sump, flare pit and Turkey’s Nest liners and back fill of the mud sump, flare pit, VSP pit and Turkey’s Nest. The project area is to be returned to Nature Reserve with the access tracks and firebreaks reinstated, including the railway corridor access track. Activities to be undertaken during rehabilitation activities are presented in Table 5.

Table 5: Rehabilitation Activities

Activity Method

Vehicle and equipment hygiene offsite inspection and clean down

Weed control vehicle and hand spraying, hand pulling

Removal of marl from well pad and portions of track not required or to be narrowed for future DBCA access mechanical means

Respreading of topsoil then stockpiled vegetation mechanical means

Propagule introduction hand scatter

Fertilisation hand spread

Monitoring visual

Remedial Works method determined if required

Progressive decommissioning will commence based on the following factors: • provisional on prospect forecast (ie future utilisation of well) • site conditions (eg mud sump status) • ensuring resource optimisation (eg minimising mobilisation operations)


Rehabilitation planning has been undertaken in accordance with the DMIRS Guidance Note – Decommissioning, rehabilitation, and closure of petroleum activities [DMIRSNOV19_6259] and a site-specific rehabilitation plan has been developed based on appropriate objectives, standards and methods to ensure that all disturbed areas are decommissioned and rehabilitated within a specified timeframe and in an ecologically sustainable manner such that the post disturbance environment is commensurate with the ecological and landscape values of BKNR, avoiding any significant long-term detrimental risks, impacts and liabilities. The rehabilitation plan outlines the following aspects:

o Current Conditions and Issues o Risk Assessment o Earthworks and Site Preparation to be undertaken o Propagule Introduction and Fertilising o Closure and Specific Completion Criteria consistent with specific, measurable,

attainable, relevant, time-bound (SMART) criteria o Thresholds and Triggers o Responsibility and Accountability o Supervision & Schedule o Monitoring and Maintenance o Reporting and Review

The completion criteria and performance indicators included in the rehabilitation plan have been agreed by DBCA to ensure that rehabilitation achieves a stable and functioning landform and ecological system consistent with pre-existing and surrounding landscape and environmental values. DBCA and EPA have approved the Cervantes 1 Rehabilitation Plan. Rehabilitation will be monitored annually with inspections of the rehabilitating site undertaken monthly until completion criteria are achieved. The projected timeline for decommissioning and rehabilitation is presented in Table 4. It is projected in an unsuccessful drilling case that Cervantes 1 will achieve its completion criteria in 2026.


5. Description of the Environment Table 6 summarises the existing environment in the project area and Figure 3 presents the Environmental Sensitivities.

Table 6: Description of the Environment

Aspect Description

Landform Drill pad within development envelope 4 m ASL

Soil Quindalup dunes - sands

Surface water Nil

Groundwater Superficial aquifer approx 10 m below ground level (bgl) with 3,000 to 7,000 mg/L salinity

Conservation area Within the Beekeepers Nature Reserve

Vegetation • Two individual priority flora plants avoided outside project area • Widely mapped Priority 1 (P1) Priority Ecological Community

(PEC) in Project Area

Weeds 5 significant weeds known to occur in the region

Dieback Very low risk

Fauna • 19 conservation significant fauna species in region • No Carnaby’s Black Cockatoo breeding or roosting habitat • Negligible Carnaby’s Black Cockatoo quality foraging habitat

Aboriginal Heritage Nil

European Heritage Nil

Socio-economic

• Beekeeping • Lime sand extraction • Recreational fishing access • 11 km from twin towns of Dongara / Port Denison • Inactive freight-only railway line

Dongara - Eneabba Railway

Jingemina

Brand Highway

DONGARA

PORTDENISON

Irwin River

BeekeepersNature

Reserve

BeekeepersNature

Reserve

BeekeepersNature

Reserve

BeekeepersNature

ReserveYardanogo

NatureReserve

YardanogoNature

Reserve

Allanooka - Dongara-DenisonWater Reserve

DongaraNatureReserve

300000

300000

305000

305000

310000

310000

315000

315000

6745

000

6745

000

6750

000

6750

000

6755

000

6755

000

6760

000

6760

000

6765

000

6765

000

Drawn: CAD Resources ~ www.cadresources.com.au Tel: (08) 9246 3242 ~ Fax (08) 9246 3202Date: Jan 2020 A3

CAD Ref: a2750_f04_03

Scale: 1:75,000MGA94 (Zone 50)

Figure:

. 30 900 1,800m

NotesProject within Arrowsmith Groundwater Area and the Shire of Irwin

LegendDevelopment EnvelopeEnvironmentally Sensitive AreaPublic Drinking Water Source AreasRed Book - Northern Sandheaths

WaterwaysDBCA Estate


Rev: 0

Environmental Sensitivities

Source: Image: Landgate (Nov 2016), Petroleum Data: DMIRS, ESA, Red Book, PDWSA, Waterways: DWER, DBCA Estate: DBCA


6. Environmental Risk Assessment and Methodology An Environmental Risk Assessment consistent with the Australian Standard for Risk Management (AS/NZS ISO 31000:2009) was undertaken for the Cervantes 1 project. Appendix C presents the moderate and above risks identified during the risk assessment.

7. Implementation Strategy The objective of the implementation strategy is to describe how all aspects of the activity will be directed, reviewed and managed to ensure that all potential impacts and risks are continuously reduced to ALARP. The specific implementation objectives include:

1. Ensure that the agreed environmental performance objectives and standards are met

2. Identify specific systems, practices and procedures to be used to ensure that environmental risks and effects are reduced to ALARP

3. Establish a commitment to the protection of the environment

4. Establish a clear chain of command that sets out the roles and responsibilities of personnel in relation to the implementation, management and review of the EP

5. Ensure that each employee or contractor working on or in connection with the activity has the appropriate skills and training

6. Monitor, audit and review environmental performance and the Implementation Strategy

7. Maintain quantitative records

8. Develop and implement emergency and spill preparedness planning and response capability

9. Report on environmental performance

10. Provide for appropriate consultation with relevant government authorities and other interested persons or organisations

Details of RCMA systems, practices and procedures relating to the management of all potential impacts and risks of the activity are detailed in Table 7. The objective of these are to continuously reduce the potential impacts and risks of the activity to ALARP.

8. Stakeholder Engagement RCMA has consulted with key stakeholders in relation to its Cervantes 1 exploration activities. These stakeholders have included: • DMIRS • Environmental Protection Authority (EPA) • DBCA • Shire of Irwin • ARC Infrastructure • Public Transport Authority • Yamatji Marlpa Aboriginal Corporation (YMAC) • Yamatji Southern Regional Corporation • Neighbouring hydrocarbon facility and permit owners

RCMA will continue to engage with stakeholders for the life of the Cervantes 1 Project.


Table 7: Systems, Practices and Procedures

Item Objective to achieve ALARP Document Name Location

Code of Practice for RCMA sites

To outline the main HSE criteria to be observed by RCMA and its contractors

RCMA HSE Policy [RCMA-01-PO-POL-001]

Rig Office Crib Room

Environment Plan To document environmental management of activities Cervantes 1 Conventional Well EP [RCMA-02-EM-PLN-001]

Rig Office Well Site Manager Office Drilling Project Manager Computer HSE Advisor Computer

Environment Plan Summary

To provide a public summary of the details in the Environment Plan

RCMA-02-EM-PLN-001SUM EARS2 DMIRS Website

Oil Spill Preparedness and Response To provide guidance on the management of a spill

Cervantes 1 Conventional Well OSCP [RCMA-02-EM-PLN-002]

Rig Office Well Site Manager Office Drilling Project Manager Computer

Emergency Response Plan To provide guidance on the management of an emergency situation

Cervantes 1 Civils Emergency Response Plan [RCMA-02-SAF-PLN-001]

Earthworks Supervisor Drilling Project Manager Computer

Cervantes 1 Drilling Phase Emergency Management Plan [RCMA-02-SAF-PLN-004]

Rig Office Well Site Manager Office Drilling Project Manager Computer

RCMA Australia Safety Management System

To provide a framework comprising a set of expectations and guidelines for effective management of HSE aspects and impacts of operations

[RCMA-02-SAF-SYS-001] or drilling specific subsidiary document

Well Site Manager Office Drilling Project Manager Computer RCMA Project Manager Computer HSE Advisor Computer

Hazard and Incident Reporting

To outline the processes and requirements for hazard and incident reporting

Incident Reporting & Investigation Standard [OMS-0224]

Drilling Project Manager Computer

Hygiene Management To document the completion of hygiene inspections for personnel entrance into BKNR

Cervantes 1 Hygiene Management Plan [RCMA-02-EM-PLN-003]

Earthworks Supervisor Rig Office Well Site Manager Office Drilling Project Manager Computer

Standard Operating Procedures

To guide personnel on how to conduct tasks to meet environmental performance throughout operations

Contractor Management Systems Electronic Filing System

Permit to Work System To ensure drill site is in a safe and environmentally acceptable condition before works commence and is kept in this condition until all personnel involved in the work have signed off completion

Permit to Work System Rig Office

Clearing Vegetation Recording

To guide and document the conditions, approval and details of clearing activities to ensure compliance with clearing permits and legislation

Cervantes 1 Vegetation Management Plan [RCMA-02-EM-PLN-004]

Earthworks Supervisor Office Environmental Advisor Computer

Cervantes 1 Clearing Vegetation Record [RCMA-02-EM-FM-002]

Earthworks Supervisor Vehicle Environmental Advisor Computer

Fauna Management To provide a practical guide on fauna management measures associated with the Cervantes 1 Project

Cervantes 1 Fauna Management Plan [RCMA-02-EM-PLN-007]

Earthworks Supervisor Office Drilling Project Manager Computer HSE Advisor Computer

Waste Management A guide on the segregation, handling and disposal of wastes associated with the Cervantes 1 drilling project

Cervantes 1 Waste Management Plan [RCMA-02-EM-PLN-009]

Earthworks Supervisor Office Rig Office Well Site Manager Office Drilling Project Manager Computer

RCMA-02-EM-PLN-001SUMv5 APPENDIX A

Chemical Disclosure

A.1 Drilling Fluid and Completion Brine Chemical Disclosure

A. SYSTEM DETAILS OPERATOR: RCMA Australia Pty Ltd PROJECT / WELL: Cervantes 1 SYSTEM: Drilling Fluid & Completion Brine TOTAL VOLUME OF SYSTEM (m3) 1,870 m3 (includes 100% contingency volume)

B. PRODUCT LIST

# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in

system fluid (mass %)

SDS Attached

1. Water Onsite water bore Base fluid 78.37%

2. Barite / Newbar Newpark Weighting agent

Low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Toxicity Data: Toxicity data available for ingredient: QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) Aquatic toxicity: Fish Toxicity LC50 (Rainbow trout) > 7500 ppm/96hrs. LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs. Biodegradation/bioaccumulation: Barium sulphate (major ingredient of barite (60-100%) is insoluble in water and not biodegradable. Not expected to bioaccumulate. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. OCNS Rated E - 24310, Exp 09/08/2021

7.12% 06/02/2020

3. Potassium Chloride Newpark

Shale swelling inhibition (smectite & illite clays)

Acute Toxicity: LD50 (Ingestion): 1500 mg/kg (mouse) LD50 (Intraperitoneal): 620 mg/kg (mouse) LD50 (Intravenous): 117 mg/kg (mouse) LDLo(Ingestion): 20 mg/kg (man) LDLo (Intraperitoneal):900 mg/kg (guinea pig) LDLo (Intravenous): 77 mg/kg (guinea pig) LDLo (Subcutaneous): 2120 mg/kg (frog) TDLo(Ingestion): 60 mg/kg/days (woman) Ecotoxicty Data: In short-term acute toxicity tests with fish, daphnia and algae the following results were found (lowest test result values): Ictalurus punctulus 48h-LC50 = 720 mg/l; Daphnia magna: 48h-LC50 = 177 mg/l; Nitzschia linearis: 120 h-EC50 = 1337 mg/l. A chronic reproductive test with the invertebrate Daphnia magna gave a LOEC of 101 mg/l. All the studies compiled on the acute and chronic aquatic toxicity were > 100 mg/L. Thus it is concluded that KCl is not hazardous to freshwater organisms. Taking into considerations the background concentrations of KCl in seawater (380 mg/l K+ and 19,000 mg/l Cl-), it is concluded that there is no reason for further investigations of KCl on marine species. The low concern for the environment is supported by the absence of a bioaccumulation potential for the substance. Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. Mobile in Soil: No impact if small amount is released to the soil. OCNS Rated E - 24330, Exp 11/03/2021

4.34% 03/02/2020


B. PRODUCT LIST



SDS Attached

4.

Calcium Carbonate (including various grades) Circal 60/16, Circal Y, Circal 1000, Stonedust, Limestone LSC Calcium Carbonate (including various grades) Omyacarb 10, 20 & 40

Newpark Bridging & weighting agent

This product is expected to be of low toxicity. Based on available data, the classification criteria are not met. Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse environmental effects. Acute Toxicity: LD50 (Ingestion): 6450 mg/kg (rat) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. Dissolved calcium carbonate dissociates into calcium and carbonate ions. Calcium ions will be assimilated by living organisms in the water and the carbonate will become part of the carbon cycle. This product does not bioaccumulate

3.50% 02/06/2021

5. Salt (Sodium Chloride all grades)

Newpark Weighting agent

Acute Toxicity: LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Skin): > 10000 mg/kg (rabbit) Ecotoxicity: LC50 (water flea) is 2122 mg/L/48 hours LC50 (fathead minnow) is 6.57 g/L/96 hours This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate.

2.87% 10/03/2017

6. Bentonite / NewGel NT / API Bentonite

Newpark Viscosifier

The main component/s of this product are not anticipated to cause any adverse effects to plants or animals. Toxicity Data: Toxicity data available for ingredient: QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) BENTONITE (1302-78-9) LD50 (intravenous) 35 mg/kg (rat) LD50 (oral): >2000mg/kg (rat) LDLo (intravenous) 10 mg/kg (dog) Inhalation LC 50: >5.27 mg/L, 4hr (rat) Ecotoxicity Data: Bentonite (1302-78-9) EC50 Daphnia > 100 mg/l, 48 hours EC50 Freshwater algae > 100 mg/l, 72 hours LC50 Freshwater fish 16000 mg/l, 96 hours LC 50 Marine water fish 2800 - 3200 mg/l, 24 hours EC50 Coon stripe shrimp (Pandalus danae) 24.8 mg/l, 96 hours EC 50 Dungeness or edible crab (Cancer magister) 81.6 mg/l, 96 hours LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 19000 mg/l, 96 hours

1.16% 20/10/2020

Persistence and degradability: Not relevant for inorganic substances Mobility: Low water solubility, expected to sink and migrate into the sediment. Expected to partition to sediment and wastewater solids. Bioaccumulation: Will not bio-accumulate. Other adverse effects: No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. OCNS Rated E - 26210 Exp 01/02/2021


B. PRODUCT LIST



SDS Attached

7. NewPac LV / Drispac SL

Newpark / Newpark (Drilling Specialties Company)

Fluid loss

Acute Toxicity: Toxicity data available for ingredients: SODIUM CARBOXYMETHYL CELLULOSE (9004-32-4) LD50 (Ingestion): 16000 mg/kg (guinea pig) LD50 (Skin): > 2000 mg/kg (rabbit) TDLo (Ingestion): 140 mg/kg (rat) SODIUM CHLORIDE (7647-14-5) LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human) SODIUM GLYCOLATE (2836-32-0) LD50 (Ingestion): 6700 mg/kg (mouse) LDLo (Ingestion): 500 mg/kg (cat)

0.78% 25/11/2020 / 30/07/2020

Ecotoxicity: LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. NewPac LV - OCNS Rated E - 28129, Exp 18/05/2021

8. NewZan D (Xanthan Gum) Newpark Vicosifier

Acute Toxicity: LD50 (oral) > 1000 mg/kg (mouse) LD50 (oral) > 45,000 mg/kg (rat) LD50 (oral) > 20,000 mg/kg (dog) LD50 (intraperitoneal): > 50 mg/kg (mouse) LD50 (intravenous): 100-250 mg/kg (mouse) This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. OCNS Rated E - 26280, Exp 22/02/2021

0.57% 11/02/2020

9. AvaPolymer 5050 Newpark

Encapsulating Agent - provides shale inhibition

CONSTITUENT 1 (95%) Acute toxicity: Acute oral toxicity (LD50): 9380 mg/kg [Rat]. Ecological Information: Ecotoxicity in water (LC50): 100 mg/l 96 hours [Fish]. Possibly hazardous short-term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic.

0.40% 02/08/2017

CONSTITUENT 2 (5%) Acute toxicity: Dermal LD50 Albino rabbit - > 2000 mg/kg, 14 days At this dose no death occurred. LD50 Oral Albino Sprague-Dawley rat > 10000 mg/kg, 14 days At this dose no death occurred. Ecotoxicity: The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results Tall Oil Fatty Acids EC50 Bacteria (Pseudomonas putida) > 10000 mg/l, 16 hr Aquatic Algae EL50 > 1000 mg/l, 72 hr Growth rate; OECD 201 Green algae (Selenastrum capricornutum) Crustacea EL50 Water flea (Daphnia magna) > 1000 mg/l, 48 hr OECD 202 Fish LL50 Zebra danio (Danio rerio) > 10000 mg/l, 96 hr


B. PRODUCT LIST



SDS Attached

Biodegradability: Percent degradation (Aerobic biodegradation) Tall Oil Fatty Acids 88 - 100 % CO2 Evolution Test Species: Activated sewage sludge Test Duration: 28 d Product Information: Product does not present an acute toxicity hazard based on known or supplied information. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 10,010.00 mg/kg 95 % of the mixture consists of component(s) of unknown hazards to the aquatic environment. OCNS category and registration number Gold - 27915

10. Sodium Sulphite Newpark Oxygen scavenger

Acute Toxicity: LD50 (Ingestion): 820 mg/kg (mouse) LD50 (Intraperitoneal): 950 mg/kg (mouse) LD50 (Intravenous): 175 mg/kg (mouse) LDLo (Ingestion): 2825 mg/kg (rabbit) LDLo (Intravenous): 400 mg/kg (cat) LDLo (Subcutaneous): 600 mg/kg (rabbit) SODIUM CARBONATE (497-19-8) LC50 (inhalation) 800 mg/m³/2 hours (guinea pig) LD50 (ingestion) 4090 mg/kg (rat) LD50 (intraperitoneal) 117 mg/kg (mouse) LD50 (subcutaneous) 2210 mg/kg (mouse) SODIUM SULPHATE (7757-82-6) LD50 (ingestion) 5989 mg/kg (mouse) LD50 (intravenous) 1220 mg/kg (rabbit) LDLo (intravenous) 1220 mg/kg (mouse) TDLo (ingestion) 14 g/kg (mouse - 8-12 days pregnant) TDLo (subcutaneous) 806 mg/kg/26 weeks intermittently (mouse) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. OCNS category and registration number E - 26232

0.23% 28/04/2021

11. FlexFirm KA Newpark Provides shale inhibition

Toxicological Information: Acute toxicity Information available for the product: No known toxicological effects from this product. Based on available data, the classification criteria are not met. Skin Irritating to the skin. Contact may result in irritation, redness, pain, rash, dermatitis and possible skin burns. Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain, redness, conjunctivitis and possible burns. Sensitization This product is not classified as causing skin or respiratory sensitisation. Irritating to the respiratory system. Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result in breathing difficulties. STOT – single exposure Aspiration This product does not present an aspiration hazard. Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodular lung disease caused deposition in the lungs of fine respirable particles of crystalline silica. Principal symptoms of silicosis are coughing and breathlessness. STOT – repeated exposure Reproductive Insufficient data available to classify as a reproductive toxin. Carcinogenicity Insufficient data available to classify as a carcinogen. This product contains crystalline silica which is classified as carcinogenic to humans (IARC Group 1). However, there is sufficient information to conclude that the relative risk of lung cancer is increased in persons with silicosis. Therefore, preventing the onset of silicosis will also reduce the cancer risk. Mutagenicity Insufficient data available to classify as a mutagen. Ecotoxicity Information: The ecotoxicity of potassium silicate has not been tested. The following data is reported for chemically similar sodium silicates on a 100% solids basis: A 96 hour median tolerance for fish (Gambusia affnis) of 2320 ppm; a 96 hour median tolerance of water fleas (Daphnia magna) of 247 ppm; a 96 hour median tolerance for snail eggs (Lymnea) of 632 ppm; and a 96 hour median tolerance for Amphipoda of 160 ppm. Toxicity: The high pH when undiluted or unneutralized is acutely harmful to aquatic life. The following data is reported for chemically similar Sodium Silicates on a 100% solids basis: A 96 hour median tolerance for fish (Gambusia affnis) of 2320 ppm; a 96 hour median tolerance for water fleas (Daphnia magna) of 247 ppm; a 96 hour median tolerance for snail eggs (Lymnea) of 632 ppm; and a 96 hour median tolerance for Amphipoda of 160 ppm.

0.15% 06/02/2020


B. PRODUCT LIST



SDS Attached

Persistence and degradability: This material is not persistent in aquatic systems. Mobility in soil: Expected to be mobile in soil. Diluted material rapidly depolymerizes to yield dissolved silica in a form that is indistinguishable from natural dissolved silica. Bioaccumulative potential Neither silica nor potassium will appreciably bio-concentrate up the food chain.

12. Citric Acid Newpark pH buffer

Acute Toxicity: LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 290 mg/kg (rat) LD50 (Intravenous): 42 mg/kg (mouse) LDLo (Ingestion): 7000 mg/kg (rabbit) Ecotoxicity: LC50 (Leuciscus idus melanotus): 440 mg/L - 48 h LC 50 Daphnia magna (Water flea) - 1.535 mg/L - 24 h Biodegradation/Bioaccumulation: Readily Biodegradability. Does not bioaccumulate. If citric acid is released to water, it is expected to biodegrade rapidly. May be toxic to fish at moderately high levels (120 ppm is fatal to daphnia; 894 ppm with pH 4 is fatal to goldfish) due to acidic nature. Fairly high biological oxygen demand (BOD) which may cause oxygen depletion in large spills. Citric acid occurs naturally in many plants. OCNS category and registration number E - 24317

0.11% 05/02/2020

13. Idcide-20 Newpark

Biocide/Prevents bacterial contamination of the mud

Toxicity: Toxicity data available for ingredient: TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8) LD50 (ingestion) 248 mg/kg (rat) TDLo (ingestion) 650 mg/kg/13 weeks - intermittent (rat) Ecotoxicity: 75% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8): LC50 (Rainbow Trout) = 119 mg/L/96 hr LC50(Bluegill Sunfish) = 93 mg/L/ 96 hr EC50 (Daphnia Magna) = 19 mg/L/48 hr LC50 (Brown Shrimp) = 340 mg/L/96 hr LC50 (Mysid Shrimp ) = 9.5 mg/L/96 hr LC50 (Sheepshead Minnow) = 94 mg/L/96 hr LC50 (Jevenile Plaice) = 86 mg/L/96 hr Wastewater management EC50 (Activated Sludge) = 24 mg/L/3 hr Persistence and degradability: This product is readily biodegradable. http://www.inchem.org/documents/ehc/ehc/ehc218.htm

0.11% 16/08/2019

14. Caustic Soda Newpark pH Control – prevents bacteria & corrosion

Toxicity Data: Toxicity Data available for the ingredients: SODIUM HYDROXIDE (1310-73-2): LD50 (Intraperitoneal): 40 mg/kg (mouse) LDLo (Ingestion): 1.57 mg/kg (human) SILICA, AMORPHOUS (7631-86-9): LD50 (ingestion): 3160 mg/kg (rat)

0.09% 05/02/2020


B. PRODUCT LIST



SDS Attached

Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11 (goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Not expected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out. OCNS category and registration number E - 24316

15. AVADEFOAM NS Newpark Defaomer suitable for WBM

CONSTITUENT 1 (95%) Acute toxicity: Acute oral toxicity (LD50): 9380 mg/kg [Rat]. Ecological Information: Ecotoxicity in water (LC50): 100 mg/l 96 hours [Fish]. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic.

0.08% 28/03/2019

CONSTITUENT 2 (5%) Acute toxicity: Dermal LD50 Albino rabbit - > 2000 mg/kg, 14 days At this dose no death occurred. LD50 Oral Albino Sprague-Dawley rat > 10000 mg/kg, 14 days At this dose no death occurred. Ecotoxicity: The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results Tall Oil Fatty Acids EC50 Bacteria (Pseudomonas putida) > 10000 mg/l, 16 hr Aquatic Algae EL50 > 1000 mg/l, 72 hr Growth rate; OECD 201 Green algae (Selenastrum capricornutum) Crustacea EL50 Water flea (Daphnia magna) > 1000 mg/l, 48 hr OECD 202 Fish LL50 Zebra danio (Danio rerio) > 10000 mg/l, 96 hr

Biodegradability: Percent degradation (Aerobic biodegradation) Tall Oil Fatty Acids 88 - 100 % CO2 Evolution Test Species: Activated sewage sludge Test Duration: 28 d Product Information: Product does not present an acute toxicity hazard based on known or supplied information. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 10,010.00 mg/kg 95 % of the mixture consists of component(s) of unknown hazards to the aquatic environment. OCNS category and registration number Gold - 27915 Product Information: Product does not present an acute toxicity hazard based on known or supplied information. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 10,010.00 mg/kg 95 % of the mixture consists of component(s) of unknown hazards to the aquatic environment. OCNS category and registration number Gold - 27915

16. Soda Ash Newpark pH / hardness control

Toxicity: LD50 (Ingestion): 4090 mg/kg (rat) LC50 (Inhalation): 800 mg/m3/2 hours (guinea pig) LD50 (Intraperitoneal): 117 mg/kg (mouse) LD50 (Subcutaneous): 2210 mg/kg (mouse) Ecotoxicity: Fishes, Lepomis macrochirus, LC50, 96 h, 300 mg/l Crustaceans, Ceriodaphnia dubia, EC50, 48 h, 200 - 227 mg/l Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11 (goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above.

0.07% 05/02/2020


B. PRODUCT LIST



SDS Attached

ATMOSPHERE: Not expected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out. OCNS category and registration number E - 26180

17. Sodium Bicarbonate Newpark

pH buffer, contamination treatment

Acute Toxicity: LD50 (Ingestion): 3360 mg/kg (mouse) LC50 (inhalation): 4.74 mg/L (rat) Ecotoxicity: Fishes, Lepomis macrochirus, LC50, 96 h, 300 mg/l Crustaceans, Ceriodaphnia dubia, EC50, 48 h, 200 - 227 mg/l Ecotoxicity Data: LC50 (Oncorhynchus mykiss), 96 h, 7.700 mg/l LC50 (Lepomis macrochirus), 96 h, 7.100 mg/l EC50 (Crustaceans, Daphnia magna) 48 h, 4.100 mg/l LOEC (Crustaceans, Daphnia magna) 48 h, 3.100 mg/l Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. OCNS category and registration number E - 26175

0.05% 03/02/2020

100% 18. Barite / Newbar Newpark Weighting agent See above 5.29% 06/02/2020 19. Salt (Sodium

Chloride all grades)

Newpark Weighting agent Acute Toxicity: LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Skin): > 10000 mg/kg (rabbit) Ecotoxicity: LC50 (water flea) is 2122 mg/L/48 hours; LC50 (fathead minnow) is 6.57 g/L/96 hours. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate.

5.29% 10/03/2017

20. NDFT 376 & NDFT 377 (Dynafiber)

Newpark LCM / well bore strengthening

Acute toxicity: This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effects are not anticipated. Oral Toxicity (LD50) > 5000 mg/kg (rat) Dermal Toxicity (LD50) > 2000 mg/kg (rabbit)

1.59% 26/08/2019

21. Quickseal M/C Newpark LCM / well bore strengthening

This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated Acute Toxicity: Acute Oral Toxicity: LD50 (oral) > 5000 mg/kg (rats). Acute Dermal Toxicity: LD50 (dermal) > 2000 mg/kg (rats). Acute Inhalation Toxicity: LC50 (Inhalation) = 5800 mg/m3/4hrs (rat). Low toxicity to aquatic organisms. This product is readily biodegradable. This product is not expected to bioaccumulate.

1.14% 03/02/2020

22. MEG Newpark Agent to free differentially stuck pipe

Toxicity Data: Toxicity data available for ingredient: ETHYLENE GLYCOL (107-21-1) LC50 (inhalation) 10 876 mg/kg (rat) LD50 (ingestion) 1650 mg/kg (cat) LD50 (skin) 9530 ug/kg (rabbit) LDLo (ingestion) 398 mg/kg (human) TCLo (inhalation) 10,000 mg/m³ (human - cough) TDLo (ingestion) 5500 mg/kg (child - anaesthesia)

0.85% 01/03/2019


B. PRODUCT LIST



SDS Attached

Ethylene glycol will mainly exist in the vapour phase in the ambient atmosphere where it will be degraded by reaction with hydroxyl radicals. Expected to be very highly mobile in soil. Not anticipated to volatilise from moist soil or water surfaces. Biodegradation in both soil and water is expected to be a major fate process for this compound. Not expected to bioconcentrate in aquatic organisms. Ecotoxicity LC50 (Aquatic species): >100mg/L/96hrs. Non-hazardous to aquatic organisms. Safework Australia Exposure Standards: http://hsis.ascc.gov.au/DocumentationES.aspx?ID=722 http://hsis.ascc.gov.au/DocumentationES.aspx?ID=271 CICADS Available: http://inchemsearch.ccohs.ca/inchem/jsp/search/search.jsp?inchemcasreg=1&Coll=inchemall&serverSpec=charlie.ccohs.ca%3A9900&QueryText1=107-21-1&QueryText2=&Search.x=52&Search.y=10

23. AvaGreenLube Newpark Lubricant LC50 (Fish) 48 h: > 10000 μg / L LC50 (Mollusc ) 48 h: > 10000 μg /L LC50 (Amphibious) 48 h: > 7600 μg/L Low potential for bío-accumulation in aquatic organisms or terrestrial even after repeated exposure.

0.42% 14/07/2017

24. AVAPERM NF Newpark Prevent swelling clays by blocking the site for water hydration

An equivalent product to AVAPERM NF has been registered on the CEFAS Offshore Chemical Notification Scheme with a ‘Gold’ rating & Registration # 24780 Skin corrosion/irritation: Not corrosive (B.40 Bis - Reg. 440/2008/EC). Skin contact: Harmful and irritant. Eye contact: Irritant. Inhalation: Irritant. Ingestion: Harmful. Acute oral toxicity on rats (LD50): > 500 < 1000 mg/kg.* (based on components)

0.42% 08/02/2018

Following information is confidential: Biodegradation Seawater test OECD 306 75% Bioaccumulation OECD 117 LogPow ≤ 1.36 EC 50 (Skeletonema costatum) 54.4 mg/l LC50 (Acartia tonsa) 52.4 mg/l LC50 (Scophthalmus maximus juvenile) >51.0 mg/l

25. Calcium Carbonate (including various grades) Circal 60/16, Circal Y, Circal 1000, Omyacarb 10, 20 & 40, Stonedust, Limestone LSC

Newpark Bridging agent & loss circulation material

See above 0.25% 24/02/2017

26. JK-161LV / JK-261 / JK-261HP

Newpark Encapsulating agent - provides shale inhibition

Toxicological Information: This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 401). Ecological Information: (10000 ppm test concentration) (EPA-821-R-02-012) Mysidopsis bahia = 48hr LC50 = 16.2 mg/L. Menidia beryllina = 48hr LC50 = 34.2 mg/L. Scophthalmus Maximus = 96hr LC50 > 1000 mg/L. Skeletonemia costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L] Acartia tonsa = 48 hr EC50 = 393 mg/L [NOEC = 112 mg/L] Corophium Volutator = 10 Day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg]

0.21% 03/02/2020

27. Gagetrol Newpark HT Fluid Loss Additive

This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.

0.19% 15/03/2017


B. PRODUCT LIST



SDS Attached

Low toxicity - low irritant. Under normal conditions of use, adverse health effects are not anticipated. OCNS category and registration number Gold - 27759

28. Strata-Vanguard Newpark Bridging agent Toxicity Data: Toxicity data available for ingredient: CRISTOBALITE (14464-46-1) TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis) QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) CELLULOSE (9004-34-6) LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit) POLYETHYLENE (9002-88-4) LDLo (ingestion) 3000 mg/kg (rat) MAGNESIUM OXIDE (1309-48-4) TCLo (inhalation) 400 mg/kg (human)

0.19% 03/02/2020

This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. This product has low mobility in soil.

29. TEA Newpark Polymer stabiliser which effectively reduces the degradation of polymers at high temperatures

CONSTITUENT 1 (>60%) Oral Toxicity (LD50) 2200 mg/kg (rabbit) Dermal Toxicity (LD50) > 20 mL/kg (rabbit)

0.14% 09/06/2017

CONSTITUENT 2 (10 - 30%) Oral Toxicity (LD50) 620 uL/kg (rat), Dermal Toxicity (LD50) > 20 mL/kg (rabbit) CONSTITUENT 3 (<10%) Component is naturally occurring and not intrinsically hazardous. Environment In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil, residual triethanolamine may leach to groundwater. LC50 (shrimp): > 100 ppm.

30. FlexFirm KA Newpark Inhibits dispersion of drilled shale cuttings

See above 0.13% 06/02/2020

31. Magnesium Oxide

Newpark pH buffer This product is expected to be of low toxicity. OCNS category and registration number E - 28127

0.13% 03/02/2020

32. Calcium Chloride (94% Powder)

Newpark Weighting Agent Based on available data, the classification criteria are not met. Toxicity Data available for the ingredients: Acute Toxicity: CALCIUM CHLORIDE ANHYDROUS (10043-52-4) LD50 (Ingestion): 1000 mg/kg (rat) LD50 (Intraperitoneal): 210 mg/kg (mouse) LD50 (Intravenous): 42 mg/kg (mouse) LD50 (Subcutaneous): 823 mg/kg (mouse) LDLo (Ingestion): 1384 mg/kg (rabbit) LDLo (Intravenous): 150 mg/kg (guinea pig) LDLo (Subcutaneous): 249 mg/kg (cat) TDLo (Intravenous): 20 mg/kg/1 hour (woman) SODIUM CHLORIDE (7647-14-5) LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse)

0.11% 05/02/2020


B. PRODUCT LIST



SDS Attached

LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate.

33. SAPP Newpark Deflocculate or disperse bentonite muds or fluids with high levels of low gravity solids

Acute Toxicity: Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation. Ingestion of large quantities may also result in serious disturbances in calcium metabolism. LD50 (Ingestion): 2650 mg/kg (mouse) LD50 (Intraperitoneal): 1 g/kg (mouse) LD50 (Intravenous): 59 mg/kg (mouse) LD50 (Subcutaneous): 480 mg/kg (mouse) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. OCNS category (actual or equivalent chemical) and Registration number. E-2449

0.11% 03/02/2020

34. Zinc Oxide Newpark H2S Scavenger Acute toxicity Information available for the product: This product is expected to be of low toxicity. LC50 (inhalation): 2500 mg/m³ (mouse) LD50 (intraperitoneal) 240 mg/kg (rat) LDLo (oral) 500 mg/kg (human) TCLo (inhalation) 600 mg/m³ (human) LD50 (oral): 7950 mg/kg (mouse) Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. This product is not readily biodegradable

0.11% 03/02/2020

35. Driscal D Newpark (Drilling Specialties Company)

High temperature fluid loss control agent

LCLo (Inhalation): 300 ug/m3/10 years (human), LDLo (Intratracheal): 200 mg/kg (rat) LDLo (Intravenous): 20 mg/kg (dog), TCLo (Inhalation): 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis)

0.10% 20/09/2018

36. Frac Attack Newpark Prevents lost circulation

Toxicity Data: Toxicity data available for ingredient: CALCIUM HYDROXIDE (1305-62-0) LD50 (ingestion) 7300 mg/kg (mouse) CRISTOBALITE (14464-46-1) TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis) QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) CELLULOSE (9004-34-6) LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit) MAGNESIUM OXIDE (1309-48-4) TCLo (inhalation) 400 mg/kg (human)

0.08% 05/02/2020

The manufacturer reports that this product is harmful to aquatic life. 37. Defoam-AP400 Newpark Defaomer

suitable for high temperatures

Eye Low to moderate irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Low to moderate irritant. Over exposure to vapours may result in irritation of the nose and throat, with coughing. High level exposure may result in dizziness, nausea and headache. Due to the low vapour pressure, an inhalation hazard is not anticipated with normal use. Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis. Ingestion Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation.

0.07% 03/02/2020


B. PRODUCT LIST



SDS Attached

Low toxicity - low irritant. This product has the potential to irritate mucous membranes. Use safe work practices to avoid eye or skin contact and inhalation. Chronic exposure to some glycols may result in liver and kidney damage. Health hazard summary 11.1 Information on toxicological effects Toxicity data POLYETHYLENE GLYCOL (25322-68-3) LD50 (ingestion) 33750 mg/kg (rat)

38. DSCO™ Defoam Newpark Defoamer Constituent 1 – (>60%) Oral Toxicity: An oral LD50 300 - 57000 mg/kg (range) This product is not expected to bioaccumulate

0.06% 08/06/2018

Constituent 2 – (remainder) No Hazard

39. Microflow Newpark Stimulation Additive

This product is not expected to bioaccumulate. 0.06% 29/01/2020 Constituent 1 – (20-60%) No Hazard Constituent 2 – (15-50%) Oral Toxicity: An oral LD50 in mice of 3600 mg/kg

40. TrueScav HD Newpark Oxygen scavenger (non-sulphur based)

Constituent 1 – (>99%) The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 5,005.00 mg/kg Oral LD50 > 5 g/kg ( Rat ) Unknown aquatic toxicity 100% of the mixture consists of component(s) of unknown hazards to the aquatic environment. Ecotoxicity: The environmental impact of this product has not been fully investigated. Persistence/Degradability: Possibly hazardous short-term degradation products are not likely; However, long term degradation products may arise.

0.03% 29/08/2018

16.95%


C. CHEMICAL LIST

Chemicals within products in Part B CAS # Maximum Mass

Fraction in System (%)

Water 7732-18-5 79.58% Barium Sulphate 7727-43-7 6.34% Potassium Chloride 7447-40-7 4.21% Calcium Carbonate 471-34-1 3.52% Sodium Chloride 7647-14-5 2.88% Bentonite 1302-78-9 1.09% Sodium carboxymethy Cellulose 9004-32-4 0.89% Xanthan Gum 11138-66-2 0.42% Quartz (Silica Crystalline) 14808-60-7 0.25% Sodium Sulphite 7757-83-7 0.22% Potassium Silicate 1312-76-1 0.15% Citric Acid, Anhydrous 77-92-9 0.11% Sodium Hydroxide 1310-73-2 0.09% Sodium Carbonate 497-19-8 0.08% Sodium Bicarbonate 144-55-8 0.05% Polyethylene Glycol 25322-68-3 0.04% OCTAN-2-OL 123-96-6 0.04% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE(2:1) 55566-30-8 0.03% Sodium Sulphate 7757-82-6 0.01% 100% Water 7732-18-5 83.72% Sodium Chloride 7647-14-5 5.10% Barium Sulphate 7727-43-7 4.71% Cellulose 9004-34-6 2.24% Polyglycerol 25618-55-7 0.84% Methyl A-D-Glucopyranoside 97-30-3 0.84% Formic Acid 64-18-6 0.23% Hydrochloric acid 7647-01-0 0.21% Calcium Carbonate 1317-65-3 0.20% Carboxymethyl starch 9057-06-1 0.17% D-glucurono-6-deoxy-l-manno-d-glucan, Acetate, calcium magnesium potassium sodium Salt 595585-15-2 0.15% Sulphonated organic polymer 28210-41-5 0.15% Triethanolamine 102-71-6 0.14% Ethylene Glycol 107-21-1 0.13% Isopropyl Alcohol 67-63-0 0.11% Disodium Pyrophosphate 7758-16-9 0.11% Calcium Chloride 10043-52-4 0.10% Acrylamide, Sodium Acrylate Copolymer 25987-30-8 0.10% Cristobalite 14464-46-1 0.08% Zinc Oxide 1314-13-2 0.06% Methyl Oxirane Polymer 9003-11-6 0.06% Hexamethylenediamine 124-09-4 0.05% Polyethylene Glycol 25322-68-3 0.04% Octan-2-Ol 123-96-6 0.04% 2-Propenenitrile, polymer with 1,3-butadiene Rubber 9003-18-3 0.04% Calcium Oxide 1305-78-8 0.04% Methyl esters of fatty acids 68990-52-3 0.04% Natural Rubber 9006-04-6 0.03% Polyisoprene 9003-31-0 0.03% Rubber - SBR elastomers (derived from recycled automotive tyres) 9003-55-8 0.03% Organic fibres 9004-34-6 0.03% Calcium Hydroxide 1305-62-0 0.03% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE(2:1) 55566-30-8 0.02% Diatomaceous Earth 68855-54-9 0.02% Magnesium oxide 1309-48-4 0.02% Dazomet (iso)[tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione] 533-74-4 0.02% Sweet Orange Oil 68647-72-3 0.02% Sodium Bicarbonate 144-55-8 0.01% Quartz (Silica Crystalline) 14808-60-7 0.01% Fuller's earth 8031-18-3 0.01% Tall Oil Fatty Acid 61790-12 0.01% Polyethylene 9002-88-4 0.01% 100%


A.2 Cementing Chemical Disclosure (Option A)

A. SYSTEM DETAILS OPERATOR: RCMA Australia Pty Ltd PROJECT / WELL: Cervantes 1 SYSTEM: Cementing (Halliburton) TOTAL VOLUME OF SYSTEM (m3) 176 m3

B. PRODUCT LIST (OPTION A)

# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)

SDS Attached

1. Freshwater Onsite Water Bore Mix Water 48.511 N/A

2. Cement Class G Halliburton Cement

Constituent 1 (≤100%): After hardening with water or moister, cement presents no ecotoxicity risks. (Source: IUCLID 2000) Static Acute Aquatic Toxicity- Freshwater and Marine Fish:- 96 hour LC50: >1,500 mg/L Static Acute Aquatic Toxicity -Freshwater and Marine Invertebrates:- 48 hour LC50: >1,000 mg/L Static Acute Aquatic Toxicity - Freshwater and Marine Algae:- 72 hour EC50: >1,000 mg/L Partition Coefficient, n-Octanol/Water: Not Applicable for inorganics Oxygen Demand, Chemical Oxygen Demand: Not Applicable for inorganics Biodegradability, Seawater – Indigenous microbes: Not Applicable for inorganics

36.073 02/08/2018

Constituent 2 (≤10%): Carcinogenicity: Classified as a human carcinogen (IARC Group 1)

3. Silicalite Liquid Halliburton Light weight cement additive

Silicalite Liquid is OCNS Group: E

5.853 30/04/2020

Constituent 1 (≤60%): Water Constituent 2 (≤60%): "SiO2" is a stable substance. In the environment it occurs in different modifications and it is one of the most abundant materials on the Earth's surface. Biodegrability is "not applicable" for silica since it is inorganic. Additionally, "bioaccumulation is not expected." Acute Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum); Acute Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia); Acute Fish Toxicity 96h LC50 5000 mg/L (Brachydanio rerio); Source: IUCLID 2000 Constituent 3 (≤1%): LC50(96h): > 1000 mg/L (Brachydanio rerio) LC50(24h): >1000 mg/L (Daphnia magna) LC50(10d): 50566 mg/kg (Corophium)

4. Gascon 469 Halliburton Cement Additive Stabiliser

Gason 469 is OCNS Group E

3.831 30/04/2020

Constituent 1 (≤100%): Water Constituent 2 (≤60%): "SiO2" is a stable substance. In the environment it occurs in different modifications and it is one of the most abundant materials on the Earth's surface. Biodegrability is "not applicable" for silica since it is inorganic. Additionally, "bioaccumulation is not expected." Acute Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum); Acute Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia); Acute Fish Toxicity 96h LC50 5000 mg/L (Brachydanio rerio); Source: IUCLID 2000 PLONOR Constituent 3 (≤1%): The inorganic substance has a high water solubility and is not expected to bioconcentrate in organisms; "Biodegradation is not applicable." Algae toxicity (i.e. mortality) has been shown at pH >8.5. Concentration-based toxicity values were not available. Acute Fish Toxicity 96h LC50: 45.4 mg/L (Oncorhynchus mykiss); Source: IUCLID 2000 Included on the OSPAR List of Substances Used and Discharged Offshore which are considered to pose Little or No Risk to the Environment

5. Halad-413L Halliburton Fluid Loss Additive Acute Toxicity: Oral Toxicity LD50: > 5,000 mg/kg (Rat) 3.357 07/05/2018




SDS Attached

Dermal Toxicity LD50: > 2,000 mg/kg (Rabbit) Humic acids, sodium salts, polymers with N,N-dimethyl-2-propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-propanesulfonate (1:1) and 2-propenenitrile, sodium bisulfite-terminated as an ingredient (10-30%) Algae Toxicity EC50 (72h): 1,102 mg/L (Skeletonema costatum) Crustacean Toxicity LC50 (48h): >2,000 mg/L (Acartia tonsa) Fish Toxicity LC50 (96h): >1,000 mg/L (Scophthalmus maximus) (juvenile turbot) Water makes up the remainder of this product. Chronic Toxicity: No data available to indicate product or components present at greater than 1% are chronic health hazards. Biodegradation/bioaccumulation: Slowly biodegradable. Humic acids, sodium salts, polymers with N,N-dimethyl-2-propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-propanesulfonate (1:1) and 2-propenenitrile, sodium bisulfite-terminated As an ingredient (10-30%) Log Pow: <0 (OECD 117) Biodegradation (28 Days): 6.1% (OECD 306)

6. SCR-100L Halliburton Cement Retarder

Acute Toxicity: Acrylic acid polymer with Sodium AMPS, sodium salt as an ingredient (60-100%): Algae EC50(72h): >3300mg/L (Skeletonema costatum) Crustacean LC50(48h): >2000mg/L (Acartia tonsa) Fish LC50(96h): >1000mg/L (Scophthalmus maximus juvenile) 2-Bromo-2- (bromomethyl) pentanedinitrile as an ingredient(<0.1%): LD50 Rat (male) oral 0.77 g/kg. FD&C Blue 1 as an ingredient (0.1%) Rat LD50 (oral) >5000 mg/kg. Water makes up the remainder of the product at percentages less than 100%. Biodegradation/bioaccumulation: Acrylic acid polymer with Sodium AMPS, sodium salt (60-100%) as an ingredient: Biodegradation (28 days): 39% (OECD306); CHARM Category: GOLD

0.671 28/01/2020

7. WellLife 734 Halliburton Cement Enhancer

Product is an inert, man-made substance and not intrinsically hazardous.

0.561 30/04/2020

Ecotoxicological Information: Acute Crustaceous Toxicity: TLM96: > 1,000,000 ppm (Mysidopsis bahia) Biodegradation: Readily Biodegradable (classified in the PLONOAR list) CHARM Category: GOLD

8. CFR-3L Halliburton Friction Reducer

CFR-3L is CFR-3 in solution

0.402 09/09/2020

Acute Toxicity : Retarder Algae Toxicity EC50 (72h): >100 mg/L (Skeletonema costatum) [Halliburton Funded Study] Fish Toxicity LC50 (48h): 7478 mg/L (Aphyosemion bivittatum) [SKW Trostberg] Crustacean Toxicity LC50 (48h): 1687 mg/L (Acartia tonsa) [Halliburton Funded Study] Chronic Toxicity: No data available to indicate product or components present at greater than 1% are chronic health hazards. Biodegradation/bioaccumulation: Slowly biodegradable Bioaccumulation Log Pow: < 0 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 0% [Halliburton Funded Study]; CHARM Category - GOLD

9. HR-25L Halliburton Cement Retarder

Acute Toxicity: Algae: EC50(72h): 791.25 mg/L (Skeletonema costatum) Crustacean: LC50(48h): 3753.85 mg/L (Acartia tonsa) Fish: LC50(96h): 250 mg/L (Scophthalmus maximus juvenile) Biodegradation/bioaccumulation: Log Pow: 0 - 4.7 (OECD 117) Biodegradation(28 Days): 77% (OECD 306) CHARM Category: GOLD

0.336 01/02/2021

10. Econolite Liquid Halliburton Cement Additive Stabiliser

Constituent 1 (≤100%): Water

0.191 03/12/2020 Constituent 2 (≤60%):

Crustracean Toxicity 100h EC50: 247 mg/L (Daphnia magna); Acute Fish Toxicity 96h LC50: 301-478 mg/L (Lepomis macrochirus);




SDS Attached

LD50:2000-3000 mg/kg (Rat) Component is an inorganic substance with "No bioaccumulation potential"; "studies on biodegradation are not applicable." Source: IUCLID 2000 PLONOR Bioassay testing where LC50/ EC50: >100mg/L Readily biodegradable

11. Barite Newpark Weighting Agent See above 0.125 06/02/2020

12. NF-6 Halliburton Reduces air entrainment into cement slurry

Acute Toxicity: Not determined for Fish, Crustaceans and Algae as a complete mix.

0.072 11/02/2021

Acute Toxicity: Rape oil as an ingredient (60-100%) Oral Toxicity LD50: >5,000 mg/kg (Rat) Dermal Toxicity LD50: >5,000 mg/kg (Rabbit) Fish Toxicity LC50: >5,600 mg/L Algae Toxicity EC50: >3,200 mg/L Acute Toxicity: Monopropylene glycol monooleate as an ingredient (5-10%) Fish Toxicity LC50: 3,200 mg/L Algae Toxicity EC50: 990 mg/L Acute Toxicity: Sorbitan, monopalmitate as an ingredient (1-5%) Fish Toxicity LC50: >,1800 mg/L Algae Toxicity EC50: 41 mg/L Acute Toxicity: Aluminium stearate as an ingredient (1-5%) Fish Toxicity LC50: >5,600 mg/L EC50: 6,500 mg/L Water makes up the remainder of this product. Chronic Toxicity: No data available to indicate product or components present at greater than 1% are chronic health hazards. Biodegradation/bioaccumulation: Readily biodegradable. Low bioaccumulation potential due to rapid degradation.

13. Tuned Spacer E+ Halliburton Mud / Cement Spacer

Acute Toxicity: Bentonite as an ingredient (60-100%) Oral Toxicity LD50: 5,000 mg/kg (Rat) Fish Toxicity (Marine) 96h LC50: 8-19 g/L (Salmo gairdneri) Fish Toxicity TLM96: 10,000 ppm (Oncorhynchus mykiss)

0.016 08/01/2019

Acute Toxicity: Crystalline silica, quartz as an ingredient (1-5%) Oral Toxicity LD50: 500 mg/kg (Rat) Fish Toxicity LC50: >10,000 mg/l Algae Toxicity EC50: >5,000 mg/l Acute Toxicity: Crystalline silica, cristobalite as an ingredient (0-1%) As for Crystalline silica, quartz. Acute Toxicity: Crystalline silica, tridymite as an ingredient (0-1%) As for Crystalline silica, quartz. Acute Toxicity: Sodium Lignosulfonate as an ingredient (10-30%) Oral Toxicity LD50 Rat: >6,000 mg/kg Acute Toxicity: Welan gum as an ingredient (5-10%) Fish Toxicity LC50: >750 mg/l Algae Toxicity EC50: 1240 mg/l




SDS Attached

Chronic Toxicity: Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling, and sometimes- fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function. Individuals with silicosis are predisposed to develop tuberculosis. Cancer Status: The International Agency for Research on Cancer (IARC) has determined that crystalline Yes silica inhaled in the form of quartz or cristobalite from occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to humans) and has determined that there is sufficient evidence in experimental animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to humans). Biodegradation/bioaccumulation: Silica is a naturally occurring, insoluble component of soil. Biodegradation is "not applicable" for crystalline silica since it is inorganic. Concentration-based toxicity values were not available.

100%


C. CEMENTING CHEMICAL LIST (OPTION A)

Chemicals within products in Part B

CAS # Maximum Mass Fraction in System (%)

Water 732-18-5 48.5120 Portland Cement 65997-15-1 20.8703 Water in Product 732-18-5 11.4850 Crystalline silica, quartz 14808-60-7 11.13258 Silica, amorphous 7732-18-5 4.27905 Silica, amorphous – fumed 7631-86-9 1.41988 Humic acids, sodium salts, polymers with N,N-dimethyl-2-propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-propanesulfonate (1:1) and 2-propenenitrile, sodium bisulfiteterminated

473268-27-8 0.80556

Glass, oxide 7440-44-0 0.46427 Acrylic acid polymer with sodium AMPS, sodium salt 37350-42-8 0.34665 Sulfurous acid, monosodium salt, polymer with formaldehyde and acetone 40104-76-5 0.22253 Tartaric acid 7732-18-5 0.16515 Barite 13462-86-7 0.09168 Sodium silicate 1344-09-8 0.08395 Rape oil 8002-13-9 0.06062 Sodium hydroxide 1310-73-2 0.03156 Bentonite 1302-78-9 0.01140 Monopropylene glycol monooleate 1330-80-9 0.00576 Sodium lignosulfonate 8061-51-6 0.00342 Sorbitan, monopalmitate 26266-57-9 0.00286 Aluminium steareate 637-12-7 0.00286 Welan gum 72121-88-1 0.00114 FD&C Blue 1 1330-80-9 0.00061 2-Bromo-2-(bromomethyl)pentanedinitrile 35691-65-7 0.00061 Crystalline silica, tridymite 15468-32-3 0.00011 Crystalline silica, cristobalite 14464-46-1 0.00011


F.2 Cementing Chemical Disclosure (Option B)

A. SYSTEM DETAILS OPERATOR: RCMA Australia Pty Ltd PROJECT / WELL: Cervantes 1 SYSTEM: Cementing (Schlumberger) TOTAL VOLUME OF SYSTEM (m3) 176 m3

B. PRODUCT LIST (OPTION B)


SDS Attached

1. Freshwater Mix Water 36.472% N

2. D901 Schlumberger Cement

Constituents: PORTLAND CEMENT Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be mutagens, or carcinogens. Can be come skin sensitizing if stored improperly. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Not applicable – Inorganic chemical.

26.66% 08/06/2021

3. D907 Schlumberger Cement

Constituents: PORTLAND CEMENT CLINKER The product contains other ingredients which do not contribute to the overall classification. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be mutagens, or carcinogens. Can be come skin sensitizing if stored improperly. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Not applicable – Inorganic chemical

15.692% 01/08/2018

4. D066 Schlumberger Silica

Constituents: QUARTZ (CRYSTALLINE SILICA) Toxicity: Acute toxicity: Quartz, Crystalline Silica: LD50 Oral (Rat): = 500 mg/kg Chronic toxicity: Product contains no components known to be sensitizing or mutagens. Crystalline silica dust is listed by IARC as Group 1 carcinogen. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. This product is not considered toxic to algae, fish, or invertebrates Biodegradation/Bioaccumulation: Not applicable – Inorganic chemical.

5.492% 02/03/2020

5. B421 Schlumberger Slag Cement Acute Toxicity: None. Chronic Toxicity: Product contains no components known to be sensitizing or mutagens. Crystalline silica dust is listed by IARC as Group 1 carcinogen. Product does not contain any known or suspected reproductive or developmental hazards.

5.492% 15/05/2020




SDS Attached

Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulaiton: Not applicable, inorganic chemical

6. D031 Newpark Weighting Agent

Constituents: BARIUM SULPHATE QUARTZ (CRYSTALLINE SILICA) Toxicity: Low toxicity. Under normal conditions of use, adverse health effects are not anticipated. QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) Aquatic toxicity: Fish Toxicity LC50 (Rainbow trout) > 7500 ppm/96hrs. LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water StickleBack) > 56,000 ppm/96hrs. Biodegradation/bioaccumulation: Barium sulphate (major ingredient of barite (60-100%) is insoluble in water and not biodegradable. Not expected to bioaccumulate. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. OCNS Rated E - 24310, Exp 09/08/2021

3.376% 29/08/2018

7. D020 Newpark Extender

Constituents: BENTONITE QUARTZ (CRYSTALLINE SILICA) SODA ASH Toxicity: The main component/s of this product are not anticipated to cause any adverse effects to plants or animals. QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) BENTONITE (1302-78-9) LD50 (intravenous) 35 mg/kg (rat) LD50 (oral): >2000mg/kg (rat) LDLo (intravenous) 10 mg/kg (dog) Inhalation LC 50: >5.27 mg/L, 4hr (rat) Ecotoxicity Data: Bentonite (1302-78-9) EC50 Daphnia > 100 mg/l, 48 hours EC50 Freshwater algae > 100 mg/l, 72 hours LC50 Freshwater fish 16000 mg/l, 96 hours LC 50 Marine water fish 2800 - 3200 mg/l, 24 hours EC50 Coon stripe shrimp (Pandalus danae) 24.8 mg/l, 96 hours EC 50 Dungeness or edible crab (Cancer magister) 81.6 mg/l, 96 hours LC50 Rainbow trout, donaldson trout (Oncorhynchus mykiss) 19000 mg/l, 96 hours Persistence and degradability: Not relevant for inorganic substances Mobility: Low water solubility, expected to sink and migrate into the sediment. Expected to partition to sediment and wastewater solids. Bioaccumulation: Will not bio-accumulate. Other adverse effects: No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. OCNS Rated E - 26210 Exp 01/02/2021

2.280% 11/10/2018

8. D600G Schlumberger Gas Control Agent Constituents: DODECYL SULFATE, SODIUM SALT 1.574% 26/04/2021




SDS Attached

1,4-DIOXANE The product contains other ingredients which do not contribute to the overall classification. Toxicity: Acute toxicity : 1,4-Dioxane (Impurity) LD50 Oral (Rat): > 4200 mg/kg Ld50 Dermal (Rabbit): >7600mg/kg LC50 Inhalation (Rat): > 46 mg/L (2h) Chronic Toxicity: May cause allergic reactions in very susceptible persons. Contains a known or suspected carcinogen. Is not known to have reproductive, or mutagenic effects. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: 1,4-Dioxane (impurity) Toxicity to Fish: LC50 (Pimpehales promelas): = 9850 mg/L (96 h) Toxicity to Invertebrates: EC50 (Daphnia magna) = 163 mg/L (48 h) Biodegradation/Bioaccumulation: Not readily biodegradable. Does not bioaccumulate.

9. D110 Schlumberger Cement Retarder

Constituents: Not applicable – no classified ingredients, or those having occupational exposure limits, present above the level of disclosure. Classified as Non-Hazardous according to the criteria of NOHSC. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Product is biodegradable, does not bioaccumulate.

0.553% 06/06/2018

10. S001 Schlumberger Accelerator

Acute Toxicity: Calcium Chloride LD50 Oral (Rat): > 1000 mg/kg LD50 Dermal (Rabbit): >5000mg/kg Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae. Toxicity to Fish: LC50(Lepomis macrochirus): = 10,650 mg/L (96 h) Toxicity to Invertebrates: EC50 (Daphnia magna) = 2,400 mg/L (48 h) Contains no substance considered to be bioaccumulating or toxic.

0.553% 09/10/2018

11. D161 Schlumberger Retarder

Constituents: SODIUM PENTABORATE This product contains other ingredients which do not contribute to the overall classification. Toxicity: Acute toxicity: Sodium Pentaborate Ld50 Dermal: >2 g/kg LC50 Inhalation: > 2.03 mg/L Chronic Toxicity: No known sensitizing, carcinogenic, reproductive, or mutagenic effects. Product is or contains a chemical which is a known or suspected reproductive hazard. Not known to cause birth defects or have a deleterious effect on a foetus. Ecotoxicity: Sodium Pentaborate: Toxicity to Fish: LC50: = 600 mg/L (96 h) Toxicity to Invertebrates: EC50= 86 mg/L (48 h)

0.460% 15/03/2021




SDS Attached

Biodegradation/Bioaccumulation: The organic portion of this material is not biodegradable. Contains no substance considered to be bioaccumulating or toxic.

12. D080 Schlumberger Dispersant

Constituents: SODIUM POLYNAPHTALENE SULFONATE Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: Toxic to aquatic life with long lasting effects. Sodium polynaphthalene sulfonate: EC50 (48 hours) 1.8 mg/l Product is not considered toxic to fish or invertebrates. Biodegradation/Bioaccumulation: Product is not biodegradable. Bioaccumulation is unlikely.

0.343% 10/02/2021

13. D186 Schlumberger Accelerator

Acute Toxicity: 2,2’-oxydiethanol (Impurity) LD50 Oral (Rat): > 12,565 mg/kg LD50 Dermal (Rabbit): >11890 mg/kg LC50 Inhalation (Rat): > 4600 mg/m3 (4h) Acute Toxicity: Calcium Bromide (Impurity) LD50 Oral (Rat): > 4,100 mg/kg Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. The product component(s) are not classified as environmentally hazardous. The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms. Toxicity to Fish: LC50(Pimpehales promelas): = 75,200 mg/L (96 h) Toxicity to Invertebrates: EC50 (Daphnia magna) = 84,000 mg/L (48 h)

0.343% 23/08/2019

14. D182 Schlumberger Spacer

Constituents: Not applicable – no classified ingredients, or those having occupational exposure limits, present above the level of disclosure. Not classified as PBY/vPvB by current EU criteria. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Bioaccumulation is unlikely.

0.125% 06/07/2020

15. D256 Schlumberger Mid-Range liquid FLAC D256

Constituents: Not applicable – no classified ingredients, or those having occupational exposure limits, present above the level of disclosure. No classified hazards. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Not readily biodegradable, bioaccumulation is unlikely.

0.092% 11/09/2019

16. D255 Schlumberger Mid-Range FLAC D255

Constituents: 2-METHYLPROPAN-2-OL The product contains other ingredients which do not contribute to the overall classification. Suspended dust may present a dust explosion hazard. Toxicity: Acute toxicity :

0.084% 11/07/2019




SDS Attached

2-methylpropan-2-ol LD50 Oral (Rat): > 2200 mg/kg Ld50 Dermal (Rabbit): >2 g/kg LC50 Inhalation (Rat): > 10000 ppm, (4h) Chronic Toxicity: No known sensitizing, carcinogenic, reproductive, or mutagenic effects. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: 2-methylpropan-2-ol Toxicity to Fish: LC50 (Pimpehales promelas): = 6130-6700 mg/L (96 h) Toxicity to Algae: EC50 (Desmodesmus subspicatus): >1000 mg/L (120 h) Toxicity to Invertebrates: EC50 (Daphnia magna) = 4607-6577 mg/L (48 h) Biodegradation/Bioaccumulation: Not readily biodegradable. Does not bioaccumulate.

17. D168 Schlumberger Fluid Loss Additive

Constituents: Not applicable – no classified ingredients, or those having occupational exposure limits, present above the level of disclosure. Classified as Non-Hazardous according to the criteria of NOHSC. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Product is biodegradable, does not bioaccumulate.

0.076% 23/03/2018

18. D065 Schlumberger Dispersant

Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Product not readily biodegradable. Bioaccumulation is unlikely. The product is water soluble, and may spread in water systems

0.056% 08/06/2021

19. D075 Schlumberger Extender

Constituents: Not applicable – this product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits. Classified as Non-Hazardous according to the criteria of NOHSC. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Contains no substance considered to be bioaccumulating or toxic.

0.053% 19/09/2018


Constituents: Not applicable – this product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits. Classified as Non-Hazardous according to the criteria of NOHSC. Toxicity: Acute toxicity: None.

0.053% 12/02/2019




SDS Attached

Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Contains no substance considered to be bioaccumulating or toxic.

21. D047 Schlumberger AntiFoam Agent

Constituents: Not applicable - No classified ingredients, or those having occupational exposure limits, present above the level of disclosure. Classified as Non-Hazardous according to the criteria of NOHSC, Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Readily biodegradable, bioaccumulation is unlikely.

0.052% 03/03/2021

22. D095 Schlumberger Lost Circulation Material

Acute Toxicity: None. Chronic toxicity Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Not readily biodegradeable, bioaccumulation is unlikely.

0.052% 30/05/2018


Constituents: Not applicable – this product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits. Classified as Non-Hazardous according to the criteria of NOHSC. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Does not bioaccumulate

0.031% 12/05/2020

24. D175A Schlumberger AntiFoam Agent

Constituents (mixtures): NON-CRYSTALLINE SILICA The product has no classified ingredients, or those having occupational exposure limits, present above the level of disclosure. The product contains other ingredients which do not contribute to the overall classification. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Contains no substance considered to be bioaccumulating or toxic.

0.031% 29/04/2020

25. D013 Schlumberger Retarder D013 Constituents: Not applicable. No classified ingredients, or those having occupational exposure limits, present above the level of disclosure. Classified as Non-Hazardous according to the criteria of NOHSC.

0.004% 15/01/2020




SDS Attached

Toxicity: Acute toxicity: aromatic polymer sulfonated derivative: LD50 oral (Rat) >40g/kg. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, or invertebrates. Toxicity to Fish: LC50: aromatic polymer sulfonated derivative = 7300 mg/L Biodegradation/Bioaccumulation: No product level data available. The product is water soluble, and may spread in water systems.

100%


C. CEMENTING CHEMICAL LIST (OPTION B) Chemicals within products in Part B CAS number Max Mass fraction

in System (%) Portland cement 65997-15-1 ~ 66 Water (Including Mix Water Supplied by Client)* - ~ 12 Crystalline silica (impurity) 14808-60-7 ~ 9 Blast furnace slag 65996-69-2 ~ 5 Barium sulfate 7727-43-7 ~ 5 Bentonite 1302-78-9 ~ 3 Styrene butadiene copolymer 9003-55-8 ~ 1 Sulfuric acid, calcium salt 7778-18-9 ~ 1 Sodium polynaphthalene sulfonate 9008-63-3 < 1 Calcium glucoheptonate 17140-60-2 < 1 Polypropylene glycol 25322-69-4 < 1 Sulfurous acid, monosodium salt, polymer 40104-76-5 < 1 2-Propenoic acid, ammonium salt, polymer with 2- methyl-2-[(1-oxo-2-propeny)amino]-1-propanesulfonic acide moniammonium salt and 2-propenamide

99716-31-1 < 1

Sodium lignosulfonate 8061-51-6 < 1 Propane-1,2-diol 57-55-6 < 0.1 Polysaccharide biopolymer 72121-88-1 < 0.1 Sodium pentaborate 12007-92-0 < 0.1 Sodium chloride (impurity) 7647-14-5 < 0.1 C12-15 alcohol ethyoxylated 68131-39-5 < 0.1 Calcium lignosulfonate 8061-52-7 < 0.1 Silicic acid, sodium salt 1344-09-8 < 0.1 Alkyl glyceryl ether sulfonate 246867-88-9 < 0.1 2-Propenoic acid, polymer with 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid and 2-propenamide, ammonium salt.

1857271-55-6 < 0.1

Sodium sulfate 7757-82-6 < 0.1 Dimethyl siloxanes and silicones 63148-62-9 < 0.1 Vinylamide/vinylsulfonated polymer 110897-64-8 < 0.1 Calcium Nitrate 10124-37-5 < 0.1 Pentasodium EDTMP 7651-99-2 < 0.01 2-methylpropan-2-ol 75-65-0 < 0.01 Sodium gluconate 527-07-1 < 0.01 Sorbitan stearate 1338-41-6 < 0.01 Tartaric Acid 87-69-4 < 0.01 Calcium chloride 10043-52-4 < 0.01 Sodium dodecyl sulphate 151-21-3 < 0.01 1,4-Dioxane (Impurity) 123-91-1 < 0.01 Sodium hydroxide 1310-73-2 < 0.01 Polyoxyethylene (40) stearic acid (monoester) 9004-99-3 < 0.01 Silicon Dioxide 7631-86-9 < 0.01 2-bromo-2-nitropropane-1,3-diol 52-51-7 < 0.001 Phosphonic acid (impurity) 13598-36-2 < 0.001 Phosphoric acid (impurity) 7664-38-2 < 0.001 2-Propenamid (impurity) 79-06-1 < 0.001 3,3'-methylenebis[5-methyloxazolidine] 66204-44-2 < 0.001 2,2' -oxydiethanol 111-46-6 < 0.001 Calcium Bromide 7789-41-5 < 0.001 2,2'-Methyliminodiethanol 105-59-9 < 0.001 Sorbic acid 110-44-1 < 0.0001


C. CEMENTING CHEMICAL LIST (OPTION B) Chemicals within products in Part B CAS number Max Mass fraction

in System (%) 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one

55965-84-9 < 0.0001

Total ~100.00%

RCMA-02-EM-PLN-001SUMv4 APPENDIX B

Safety Data Sheets

AVADEFOAM NS

EN

SAFETY DATA SHEET

Issue Date 18-Apr-2017 Revision Date 28-Mar-2019 Version 1

Section 1: IDENTIFICATION: PRODUCT INDENTIFIER AND CHEMICAL IDENTITY1

Product identifier

Product Name AVADEFOAM NS

Product Code NDF00251

Other means of identification

Pure substance/mixture Mixture

Recommended use of the chemical and restrictions on use

Recommended Use Defoamer

Uses advised against No information available

Details of manufacturer or importer

For further information, please contact

Contact Point Telephone: +61 8 9410 8200Fax: +61 8 9410 8299Website: www.newpark.com

Emergency telephone number

Emergency telephone number +(61)-290372994 (Australia); +(64)-98010034 (New Zealand)

Section 2: HAZARD(S) IDENTIFICATION

GHS - Classification

Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)

Label elements

Hazard statementsNot a dangerous substance or mixture according to the Globally Harmonized System (GHS)

_____________________________________________________________________________________________

UGHS Page 1 / 8

SupplierNewpark Drilling Fluids (Australia) LTD11 Alacrity PlaceHenderson, WA, 6166Australia

_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019

Other hazards General HazardsNo information available

Section 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITHSCHEDULE 8

Substance

Not applicable

Mixture

Section 4: FIRST AID MEASURES

Description of first aid measures

Emergency telephone number Poisons Information Center, Australia: 13 11 26Poisons Information Center, New Zealand: 0800 764 766

Inhalation Remove to fresh air.

Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.

Skin contact Wash skin with soap and water.

Ingestion Clean mouth with water and drink afterwards plenty of water.

Most important symptoms and effects, both acute and delayed

Symptoms No information available.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

Section 5: FIREFIGHTING MEASURESSuitable Extinguishing Media

Suitable extinguishing media Water. Carbon dioxide (CO2).

Unsuitable extinguishing media No information available.

Specific hazards arising from the chemical

Thermal decomposition can lead to release of irritating and toxic gases and vapors. Do not allow run-off from fire-fighting to enterdrains or water courses.

Hazardous combustion products Carbon oxides.

Special protective actions for fire-fighters

Special protective equipment forfire-fighters

Firefighters should wear self-contained breathing apparatus and full firefighting turnoutgear. Use personal protection equipment.

Chemical name CAS No Weight-%Non-hazardous ingredients Proprietary

_____________________________________________________________________________________________

UGHS Page 2 / 8


Hazchem code Not Listed.

Section 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation.

For emergency responders Use personal protection recommended in Section 8.

Environmental precautions

Environmental precautions See Section 12 for additional Ecological Information. Do not flush into surface water orsanitary sewer system. Prevent product from entering drains.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

Precautions to prevent secondary hazards

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

Section 7: HANDLING AND STORAGE, INCLUDING HOW THE CHEMICAL MAY BE SAFELYUSED

Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Wash thoroughlyafter handling. Wash contaminated clothing before reuse.

General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and afterwork.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible materials None known

Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION

Control parameters

Exposure Limits This product, as supplied, does not contain any hazardous materials with occupationalexposure limits established by the region specific regulatory bodies.

Biological occupational exposure limits Not applicable

Appropriate engineering controls

Engineering controls ShowersEyewash stationsVentilation systems.

Individual protection measures, such as personal protective equipment

_____________________________________________________________________________________________

UGHS Page 3 / 8


Eye/face protection Tight sealing safety goggles.

Skin and body protection Wear suitable protective clothing.

Respiratory protection In case of inadequate ventilation wear respiratory protection.

Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties Physical state Liquid

Other Information Softening point No information availableMolecular weight No information availableVOC Content (%) No information availableLiquid Density 0.95-0.97 g/cm3Bulk density No information availableParticle Size No information availableParticle Size Distribution No information available

Section 10: STABILITY AND REACTIVITY

Reactivity

Reactivity No information available.

Chemical stability

Stability Stable under normal conditions.

Explosion dataSensitivity to Mechanical Impact None.Sensitivity to Static Discharge None.

Possibility of Hazardous Reactions

Appearance liquid Odor Slight.Color clear Odor threshold No information available

Property Values Remarks • Method pH No data availableMelting point / freezing point No data availableBoiling point / boiling range No data availableFlash point > 100 °CEvaporation rate No data availableFlammability (solid, gas) Not applicableFlammability Limit in Air No information available

Upper flammability limit: No data availableLower flammability limit: No data available

Vapor pressure No data availableVapor density No data availableRelative density 0.95-0.97Water solubility Insoluble in waterSolubility(ies) No data availablePartition coefficient No data availableAutoignition temperature No data availableDecomposition temperature No data availableKinematic viscosity No data availableDynamic viscosity No data available

_____________________________________________________________________________________________

UGHS Page 4 / 8


Possibility of hazardous reactions None under normal processing.

Conditions to avoid

Conditions to avoid None known based on information supplied.

Incompatible materials

Incompatible materials None known.

Hazardous Decomposition Products

Hazardous Decomposition Products None known based on information supplied.

Section 11: TOXICOLOGICAL INFORMATION

Acute toxicity

Information on likely routes of exposure

Product Information .

Inhalation Specific test data for the substance or mixture is not available.

Eye contact Specific test data for the substance or mixture is not available.

Skin contact Specific test data for the substance or mixture is not available.

Ingestion Specific test data for the substance or mixture is not available


Numerical measures of toxicity - Product Information

The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 10,010.00 mg/kg

Unknown acute toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity95 % of the mixture consists of ingredient(s) of unknown acute oral toxicity100 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)

See section 16 for terms and abbreviations

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation No information available.

Serious eye damage/eye irritation No information available.

Respiratory or skin sensitization No information available.

Germ cell mutagenicity No information available.

Carcinogenicity No information available.

Reproductive toxicity No information available.

_____________________________________________________________________________________________

UGHS Page 5 / 8


STOT - single exposure No information available.

STOT - repeated exposure No information available.

Aspiration hazard No information available.

Section 12: ECOLOGICAL INFORMATION

Ecotoxicity

Ecotoxicity The environmental impact of this product has not been fully investigated.

Unknown aquatic toxicity 95 % of the mixture consists of component(s) of unknown hazards to the aquaticenvironment.

Persistence and degradability

Persistence and degradability No information available.

Bioaccumulative potential

Bioaccumulation No information available.

Mobility

Mobility in soil No information available.

Mobility No information available.

Other adverse effects

Other adverse effects No information available.

Section 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste from residues/unusedproducts

Dispose of in accordance with local regulations. Dispose of waste in accordance withenvironmental legislation.

Contaminated packaging Do not reuse empty containers.

Section 14: TRANSPORT INFORMATION

ADG Not regulated

IATA Not regulated

IMDG Not regulated

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNo information available

_____________________________________________________________________________________________

UGHS Page 6 / 8


Section 15: REGULATORY INFORMATION

Regulatory information

National regulations

Australia See section 8 for national exposure control parameters

Standard for Uniform Scheduling of Medicines and Poisons (SUSMP)No poisons schedule number allocated

International Inventories TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesENCS Does not complyIECSC CompliesKECL CompliesPICCS Does not complyAICS CompliesNZIoC Complies

Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals

International Regulations

Ozone-depleting substances (ODS) Not applicable

Persistent Organic Pollutants Not applicable

Export Notification requirements Not applicable

Section 16: ANY OTHER RELEVANT INFORMATION

Issue Date 18-Apr-2017

Revision Date 28-Mar-2019

Revision NoteNo information available.

Key or legend to abbreviations and acronyms used in the safety data sheet

Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Disclaimer

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)Ceiling Maximum limit value * Skin designationC Carcinogen

_____________________________________________________________________________________________

UGHS Page 7 / 8


This document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.

End of Safety Data Sheet

_____________________________________________________________________________________________

UGHS Page 8 / 8

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

AVA GREEN LUBE ● GREEN LUBESynonym(s)

DRILLING FLUID ● LUBRICANTUse(s)1.2 Uses and uses advised against

1.3 Details of the supplier of the product

NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name

11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress

+61 8 9410 8200Telephone

+61 8 9410 8299Fax

1800 127 406 (Australia); +64 4 917 9888 (International)Emergency

1.4 Emergency telephone number(s)

www.newpark.comWebsite

1.1 Product identifier

AVAGREEN LUBEProduct name

2. HAZARDS IDENTIFICATION

NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA

2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.

No information provided.2.3 Other hazards

2.1 Classification of the substance or mixture

3. COMPOSITION/ INFORMATION ON INGREDIENTS

Ingredient CAS Number EC Number Content

100%68990-52-3 273-606-8METHYL ESTERS OF FATTY ACIDS

3.1 Substances / Mixtures

4. FIRST AID MEASURES

If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.

4.1 Description of first aid measures

Eye

If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation

If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.

Skin

For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).Ingestion

Eye wash facilities and safety shower should be available.First aid facilities

Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed

SDS Date: 14 Jul 2017

Version No: 1ofPage 1 6

www.newpark.com

AVAGREEN LUBEPRODUCT NAME

4.3 Immediate medical attention and special treatment neededTreat symptomatically.

5. FIRE FIGHTING MEASURES

Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture

Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.

5.3 Advice for firefighters

None allocated.

5.4 Hazchem code

Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.5.1 Extinguishing media

6. ACCIDENTAL RELEASE MEASURES

Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.

6.1 Personal precautions, protective equipment and emergency procedures

Prevent product from entering drains and waterways.6.2 Environmental precautions

Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.

6.3 Methods of cleaning up

See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections

7. HANDLING AND STORAGE

Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should haveappropriate ventilation systems. Store as a Class C2 Combustible Liquid (AS1940).

7.2 Conditions for safe storage, including any incompatibilities

No information provided.7.3 Specific end use(s)

7.1 Precautions for safe handling

Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters

Exposure standards

No exposure standards have been entered for this product.

Biological limitsNo biological limit values have been entered for this product.

Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.

8.2 Exposure controlsEngineering controls




PPE

Eye / Face Wear splash-proof goggles.

Hands Wear PVC or rubber gloves.

Body When using large quantities or where heavy contamination is likely, wear coveralls.

Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical propertiesYELLOW LIQUIDAppearanceSWEET VEGETABLE ODOUROdourCLASS C2 COMBUSTIBLEFlammability180°CFlash point> 300°CBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density0.91 to 0.92Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficient260°CAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

10. STABILITY AND REACTIVITY

10.2 Chemical stability

Stable under recommended conditions of storage.

10.4 Conditions to avoid

Avoid heat, sparks, open flames and other ignition sources.

10.5 Incompatible materials

Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.

May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products

Polymerization is not expected to occur.

10.3 Possibility of hazardous reactions

10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.

11. TOXICOLOGICAL INFORMATION

This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsAcute toxicity

11.1 Information on toxicological effects




are not anticipated.

Not classified as a skin irritant. Contact may cause temporary mild skin irritation.Skin

Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.Eye

Not classified as causing skin or respiratory sensitisation.Sensitisation

Not classified as causing organ damage from single exposure.STOT - singleexposure

This product does not present an aspiration hazard.Aspiration

Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure

No relevant or reliable studies were identified.Reproductive

No evidence of carcinogenic effects.Carcinogenicity

No evidence of mutagenic effects.Mutagenicity

12. ECOLOGICAL INFORMATION

12.1 Toxicity

LC50 (Fish) 48 h: > 10000 μg / LLC50 (Mollusc ) 48 h: > 10000 μg /LLC50 (Amphibious) 48 h: > 7600 μg/L

12.2 Persistence and degradability70% 28 days (method OECD 301 B

12.4 Mobility in soil

It is not volatile and not expected to persist in the environment.

No information provided.

12.5 Other adverse effects

12.3 Bioaccumulative potentialLow potential for bioaccumulation.

13. DISPOSAL CONSIDERATIONS

For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Forlarge quantities, contact the manufacturer/supplier for additional information.

13.1 Waste treatment methods

Waste disposal

Dispose of in accordance with relevant local legislation.Legislation

14. TRANSPORT INFORMATION

LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)

None allocated.

None allocated. None allocated.


None allocated.14.3 Transporthazard class

14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number

14.2 ProperShipping Name


14.5 Environmental hazards

None allocated.Hazchem code

14.6 Special precautions for user

NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA

15. REGULATORY INFORMATION




A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Poison schedule

None allocated.Risk phrases

AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.

Inventory listing(s)

None allocated.Safety phrases

None allocated.Hazard codes

Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.

The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].

Classifications

16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.

ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous

Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly

alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average

Abbreviations

Additional information




This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').

It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.

While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.

Report status

Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au

Prepared by

[ End of SDS ]



AVAPERM NF

EN

SAFETY DATA SHEET

Issue Date 29-Jul-2016 Revision Date 08-Feb-2018 Version 1

Section 1: IDENTIFICATION: PRODUCT INDENTIFIER AND CHEMICAL IDENTITY

Product identifier

Product Name AVAPERM NF





Recommended Use shale inhibitor






Emergency telephone number 1800 127 406 (Australia); +64 4 917 9888 (International)



Acute toxicity - Oral Category 4 - (H302)Acute toxicity - Dermal Category 4 - (H312)Skin corrosion/irritation Category 2 - (H315)Serious eye damage/eye irritation Category 1 - (H318)Skin sensitization Category 1B - (H317)Specific target organ toxicity (single exposure) Category 3 - (H335)

Label elements

_____________________________________________________________________________________________

UGHS Page 1 / 9


_____________________________________________________________________________________________NDF00185 AVAPERM NF Revision Date 08-Feb-2018

Signal wordDanger

Hazard statementsH302 - Harmful if swallowedH312 - Harmful in contact with skinH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritation

Precautionary Statements - PreventionWash face, hands and any exposed skin thoroughly after handlingDo not eat, drink or smoke when using this productWear protective gloves/protective clothing/eye protection/face protectionAvoid breathing dust/fume/gas/mist/vapors/sprayContaminated work clothing should not be allowed out of the workplaceUse only outdoors or in a well-ventilated areaIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingImmediately call a POISON CENTER or doctor/physicianIF ON SKIN: Wash with plenty of soap and waterCall a POISON CENTER or doctor/physician if you feel unwellTake off contaminated clothing and wash before reuseIf skin irritation or rash occurs: Get medical advice/attentionIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingCall a POISON CENTER or doctor/physician if you feel unwellIF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellRinse mouthPrecautionary Statements - StorageStore in a well-ventilated place. Keep container tightly closedStore locked upPrecautionary Statements - DisposalDispose of contents/container to an approved waste disposal plant

Other hazards May be harmful in contact with skinGeneral HazardsNo information available


Substance

Not applicable

Mixture

Chemical Name CAS No Weight-%Hexanedinitrile, hydrogenated, high-boiling fraction 68411-90-5 30-50Hydrochloric acid 7647-01-0 <15Non-hazardous ingredients Proprietary

_____________________________________________________________________________________________

UGHS Page 2 / 9

Balance







Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. If skin irritation or rash occurs: Get medical advice/attention.

Ingestion Do not induce vomiting without medical advice. Get medical attention if symptoms occur.






Suitable extinguishing mediaDry chemical, CO2, water spray or alcohol-resistant foam.




Hazardous combustion products Carbon oxides. Nitrogen oxides (NOx). Hydrogen chloride.











_____________________________________________________________________________________________

UGHS Page 3 / 9









Advice on safe handling Wash contaminated clothing before reuse. Handle in accordance with good industrialhygiene and safety practice. Wash thoroughly after handling.




Incompatible materials Strong oxidizing agents Aldehydes Halogens Acids Ketone Nitrates Halogenatedcompounds Phenols Isocyanates


Control parameters

Exposure Limits .

Chemical Name AustraliaHydrochloric acid

7647-01-05 ppm Peak

7.5 mg/m3 Peak







Hand protection Wear suitable gloves tested to EN 374.



_____________________________________________________________________________________________

UGHS Page 4 / 9



Information on basic physical and chemical properties Physical state Liquid

Other Information Softening point No information availableMolecular weight No information availableVOC Content (%) No information availableDensity 1.00-1.10 g/cm3Bulk density No information availableParticle Size No information availableParticle Size Distribution No information available


Reactivity

Reactivity Stable under normal conditions.

Chemical stability





Conditions to avoid



Appearance liquid Odor Pungent.Color brown Odor threshold No information available

Property Values Remarks • Method pH 9 - 10Melting point / freezing point No information availableBoiling point / boiling range 100 °CFlash point > 100 °CEvaporation rate No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air Not applicable

Upper flammability limit: Not applicableLower flammability limit: Not applicable

Vapor pressure No data availableVapor density No data availableRelative density 1.00-1.10Water solubility Soluble in waterSolubility(ies) No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosityDynamic viscosity

_____________________________________________________________________________________________

UGHS Page 5 / 9


Incompatible materials Strong oxidizing agents. Aldehydes. Halogens. Acids. Ketone. Nitrates. Halogenatedcompounds. Phenols. Isocyanates.




Acute toxicity









The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 768.00 mg/kgATEmix (dermal) 2,985.00 mg/kgATEmix (inhalation-gas) 2,859.84 ppmATEmix (inhalation-dust/mist) 2.54 mg/l


Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50Hexanedinitrile, hydrogenated,

high-boiling fraction= 1500 mg/kg ( Rat ) > 200 mg/kg ( Rabbit ) -

Hydrochloric acid 238 - 277 mg/kg ( Rat ) > 5010 mg/kg ( Rabbit ) = 1.68 mg/L ( Rat ) 1 hSee section 16 for terms and abbreviations


Skin corrosion/irritation Irritating to skin.

Serious eye damage/eye irritation Risk of serious damage to eyes.

Respiratory or skin sensitization May cause an allergic skin reaction.

Germ cell mutagenicity None known.

Carcinogenicity None known.

Reproductive toxicity None known._____________________________________________________________________________________________

UGHS Page 6 / 9


STOT - single exposure Target Organs. Respiratory system.

STOT - repeated exposure None known.

Aspiration hazard None known.


Ecotoxicity



Chemical Name Algae/aquatic plants Fish Toxicity tomicroorganisms

Crustacea

Hydrochloric acid - 282: 96 h Gambusiaaffinis mg/L LC50 static

- -





Mobility











ADG Not regulated

IATA Not regulated

IMDG Not regulated

_____________________________________________________________________________________________

UGHS Page 7 / 9

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code


No information available






International Inventories TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesENCS Does not complyIECSC CompliesKECL Does not complyPICCS Does not complyAICS CompliesNZIoC Complies







Issue Date 29-Jul-2016

Revision Date 08-Feb-2018



_____________________________________________________________________________________________

UGHS Page 8 / 9



DisclaimerThis document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.



_____________________________________________________________________________________________

UGHS Page 9 / 9

AVAPOLYMER 5050

EN

SAFETY DATA SHEET

Issue Date 12-Apr-2017 Revision Date 02-Aug-2017 Version 1


Product identifier

Product Name AVAPOLYMER 5050





Recommended Use shale stabilizer










Label elements


Other hazards

_____________________________________________________________________________________________

UGHS Page 1 / 8


_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017

May be harmful in contact with skinGeneral HazardsNo information available


Substance

Not applicable

Mixture

Additional informationThe product contains no substances which at their given concentration, are considered to be hazardous to health













Suitable extinguishing mediaWater spray (fog). Carbon dioxide (CO2).








_____________________________________________________________________________________________

UGHS Page 2 / 8
















Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid generation ofdust. Wash thoroughly after handling. Wash contaminated clothing before reuse.




Incompatible materials None known


Control parameters





_____________________________________________________________________________________________

UGHS Page 3 / 8








Information on basic physical and chemical properties Physical state Solid

Other Information Softening point No information availableMolecular weight No information availableVOC Content (%) No information availableDensity No information availableBulk density No information availableParticle Size No information availableParticle Size Distribution No information available


Reactivity

Reactivity Stable.

Chemical stability



Appearance powder Odor Slight.Color No information available Odor threshold No information available

Property Values Remarks • Method pH 8.0 - 11.0 20 g/L solutionMelting point / freezing point No data availableBoiling point / boiling range No data availableFlash point Not applicableEvaporation rate No data availableFlammability (solid, gas) No data availableFlammability Limit in Air No data available


Vapor pressure No data availableVapor density No data availableRelative density No data availableWater solubility Soluble in waterSolubility(ies) No information availablePartition coefficient No information availableAutoignition temperature No data availableDecomposition temperature No data availableKinematic viscosity Not applicableDynamic viscosity Not applicable

_____________________________________________________________________________________________

UGHS Page 4 / 8




Conditions to avoid



Incompatible materials None known.




Acute toxicity









The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 27,000.00 mg/kgATEmix (dermal) 2,002.00 mg/kg









_____________________________________________________________________________________________

UGHS Page 5 / 8







Ecotoxicity







Mobility











ADG Not regulated

IATA Not regulated

IMDG Not regulated


_____________________________________________________________________________________________

UGHS Page 6 / 8







International Inventories TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesENCS CompliesIECSC CompliesKECL CompliesPICCS CompliesAICS CompliesNZIoC Complies







Issue Date 12-Apr-2017

Revision Date 02-Aug-2017



Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONTWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)Ceiling Maximum limit value * Skin designationC Carcinogen

_____________________________________________________________________________________________

UGHS Page 7 / 8


DisclaimerThis document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.


_____________________________________________________________________________________________

UGHS Page 8 / 8


BARITE (API 13A SECTION 7) ● NEWBAR ● RHEOBARSynonyms

DRILLING FLUID ADDITIVE ● WEIGHTING AGENTUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax


1.4 Emergency telephone numbers



BARITE POWDERProduct name



2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.

This product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystallinesilica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis. IARC Monographs, Vol. 68,1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz or cristobalite from occupationalsources causes cancer in humans. IARC Classification Group I.

2.3 Other hazards




>89%7727-43-7 231-784-4BARIUM SULPHATE

<3%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)





Eye



Skin


Eye wash facilities should be available.First aid facilities

SDS Date: 06 Feb 2020

Revision No: 3.3ofPage 1 6

www.newpark.com

BARITE POWDERPRODUCT NAME

Repeated exposure to crystalline silica may result in lung fibrosis (silicosis). Principal symptoms of silicosis are coughing andbreathlessness. Crystalline silica is classified as carcinogenic to humans (IARC Group 1).

4.2 Most important symptoms and effects, both acute and delayed



Non flammable. May evolve toxic gases (sulphur oxides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code

Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media


Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures






Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.


No information provided.7.3 Specific end uses








Exposure standards

Ingredient ReferenceTWA STEL

ppm mg/m³ ppm mg/m³

Barium sulphate SWA [AUS] -- 10 -- --

Barium sulphate (inhalable) SWA [Proposed] -- 4 -- --

Barium sulphate (respirable) SWA [Proposed] -- 1.35 -- --

Quartz (respirable dust) SWA [AUS] -- 0.1 -- --Quartz (respirable dust) SWA [Proposed] -- 0.05 -- --Quartz (respirable dust) WorkSafe VIC -- 0.05 -- --

No Biological Limit Value allocated.Biological limits

PPE

Eye / Face Wear dust-proof goggles.



Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.




9.1 Information on basic physical and chemical propertiesOFF-WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT RELEVANTBoiling point> 1300°CMelting pointNOT RELEVANTEvaporation rate8.2 (20% Slurry)pHNOT RELEVANTVapour density4.20Specific gravityINSOLUBLESolubility (water)NOT RELEVANTVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT RELEVANTPartition coefficientNOT RELEVANTAutoignition temperatureNOT RELEVANTDecomposition temperatureNOT RELEVANTViscosityNOT EXPLOSIVEExplosive propertiesNON OXIDISINGOxidising propertiesNOT RELEVANTOdour threshold

9.2 Other information~1.5 kg/LBulk density










Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), alkalis (e.g. sodium hydroxide), heat and ignitionsources.

May evolve toxic gases (sulphur oxides) when heated to decomposition.10.6 Hazardous decomposition products





Based on available data, the classification criteria are not met.Acute toxicity

Information available for the ingredients:

IngredientOral LD50 Dermal LD50 Inhalation LC50

> 5000 mg/kg (rat) > 2000 mg/kg (rat) --BARIUM SULPHATE

Contact may result in irritation, redness, pain and rash.Skin

Contact may result in irritation, lacrimation, pain, redness and blurring or dimness of vision.Eye


Over exposure may result in irritation of the nose and throat, coughing, dizziness, drowsiness and headache.STOT - singleexposure

Not classified as causing aspiration.Aspiration

Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodularlung disease caused by deposition in the lungs of fine respirable particles of crystalline silica. Principalsymptoms of silicosis are coughing and breathlessness.

STOT - repeatedexposure

Not classified as a reproductive toxin.Reproductive

Crystalline silica is classified as carcinogenic to humans (IARC Group 1). However, there is a body ofevidence supporting the fact that increased cancer risk would be limited to people already suffering fromsilicosis.

Carcinogenicity

Not classified as a mutagen.Mutagenicity



12.1 Toxicity

Fish Toxicity: LC50 (Rainbow trout) > 7500 ppm/96hrs; LC50 (Fresh Water Trout) > 21,000 ppm/96hrs; LC50 (Salt Water StickelBack) > 56,000 ppm/96hrs.

12.2 Persistence and degradabilityBarium sulphate (major ingredient of barite (60-100%)) is insoluble in water and not biodegradable.



This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.


12.3 Bioaccumulative potentialNot expected to bioaccumulate.





Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additionalinformation (if required).


Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number










Poison schedule


Inventory listings


Classifications

16. OTHER INFORMATION

RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.









Abbreviations




Report status

Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com

Prepared by

[ End of SDS ]




AVAGEL ● BENTONIL HR ● HISWELL ● MAXIGEL ● NATURALGEL ● NEWGEL ● RHEOBEN ● RHEOBENNT ● SODIUM BENTONITE ● SODIUM MONTMORILLONITE

Synonyms

DRILLING FLUIDUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





BENTONITE POWDERProduct name


CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA

2.2 GHS Label elements

Signal word WARNING

Storage statementsNone allocated.

Get medical advice/attention if you feel unwell.P314Response statements

Do not breathe dust/fume/gas/mist/vapours/spray.P260Prevention statements

May cause damage to organs through prolonged or repeated exposure.H373Hazard statements

Pictograms

Physical Hazards

Not classified as a Physical Hazard

Health Hazards

Specific Target Organ Toxicity (Repeated Exposure): Category 2

Environmental Hazards

Not classified as an Environmental Hazard


SDS Date: 20 Oct 2020


www.newpark.com

BENTONITE POWDERPRODUCT NAME


Dispose of contents/container in accordance with relevant regulations.P501Disposal statements



90 to 98%1302-78-9 215-108-5BENTONITE

2 to 10%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)

2 to 4%- -SODA ASH





Eye


If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Skin

For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due toproduct form and application, ingestion is considered unlikely.

Ingestion


Repeated exposure to crystalline silica may result in lung fibrosis (silicosis). Principal symptoms of silicosis are coughing andbreathlessness. Crystalline silica is classified as carcinogenic to humans (IARC Group 1).

4.2 Most important symptoms and effects, both acute and delayed



Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture

Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.


None allocated.

5.4 Hazchem code





Moisten with water to prevent a dust hazard and place in sealable containers for disposal.6.3 Methods of cleaning up






Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure packaging are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.







Exposure standards



Quartz (respirable dust) SWA [AUS] -- 0.05 -- --Quartz (respirable dust) WorkSafe VIC -- 0.05 -- --


PPE








9.1 Information on basic physical and chemical propertiesBROWN POWDERAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point1100°C to 1200°C (Fusion Point)Melting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density2.7Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limit




9.1 Information on basic physical and chemical propertiesNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT EXPLOSIVEExplosive propertiesNON OXIDISINGOxidising propertiesNOT AVAILABLEOdour threshold

9.2 Other information~ 0.9 kg/LBulk density







Incompatible with acids (e.g. nitric acid) and alkalis (e.g. sodium hydroxide).

May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products





Toxicity Data available for the ingredients:QUARTZ (SILICA CRYSTALLINE) (14808-60-7):LCLo (inhalation) = 300 ug/m³/10 years (human)TCLo (inhalation) = 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis)BENTONITE (1302-78-9):LD50 (intravenous) = 35 mg/kg (rat)LD50 (oral): > 2000mg/kg (rat)LDLo (intravenous) = 10 mg/kg (dog)Inhalation LC 50: > 5.27 mg/L, 4hr (rat)

Acute toxicity

Not classified as a skin irritant. Contact may result in mild irritation and dermatitis.Skin




Not expected to present an aspiration hazard.Aspiration



Insufficient data available to classify as a reproductive toxin.Reproductive

This product contains crystalline silica which is classified as carcinogenic to humans (IARC Group 1).However, there is sufficient information to conclude that the relative risk of lung cancer is increased inpersons with silicosis. Therefore, preventing the onset of silicosis will also reduce the cancer risk.

Carcinogenicity

Insufficient data available to classify as a mutagen.Mutagenicity

Additional ingredient toxicity values:

BENTONITE (1302-78-9)LD50 (intravenous) 35 mg/kg (rat)LDLo (intravenous) 10 mg/kg (dog)






12.1 Toxicity

Bentonite (1302-78-9):EC50 Daphnia > 100 mg/l, 48 hoursEC50 Freshwater algae > 100 mg/l, 72 hoursLC50 Freshwater fish = 16000 mg/l, 96 hoursLC50 Marine water fish = 2800 - 3200 mg/l, 24 hoursEC50 Coon stripe shrimp (Pandalus danae) = 24.8 mg/l, 96 hoursEC50 Dungeness or edible crab (Cancer magister) = 81.6 mg/l, 96 hoursLC50 Rainbow trout, donaldson trout (Oncorhynchus mykiss) = 19000 mg/l, 96 hours

12.2 Persistence and degradabilityNot relevant for inorganic substances.


Low water solubility, expected to sink and migrate into the sediment. Expected to partition to sediment and wastewater solids.

The main component/s of this product are not anticipated to cause any adverse effects to plants or animals.


12.3 Bioaccumulative potentialWill not bioaccumulate.


Reuse where possible. No special precautions are normally required when handling this product.


Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number










Poison schedule

AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals)All components are listed on AIIC, or are exempt.

Inventory listings


Classifications









Abbreviations




Report status


Prepared by


[ End of SDS ]




ABGRIT ● CIRCAL ● LIMESTONE ● MARBLE ● NEWCARB, AG LIMESTONE, UNICAL 20 ● OMYACARB ●STONEDUST ● TRUECARB

Synonyms

DRILLING FLUID ADDITIVE ● WEIGHTING AGENTUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





CALCIUM CARBONATEProduct name








>96%1317-65-3 215-279-6LIMESTONE (CALCIUM CARBONATE)






Eye



For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.

Ingestion


SDS Date: 02 Jun 2021


www.newpark.com

CALCIUM CARBONATEPRODUCT NAME

May cause irritation to the eyes, skin and respiratory system.4.2 Most important symptoms and effects, both acute and delayed




No fire or explosion hazard exists.5.3 Advice for firefighters

None allocated.

5.4 Hazchem code





If spilt, collect and reuse where possible. If reuse is not possible, contain spillage, then collect and place in suitable containers fordisposal. Avoid generating dust.











Exposure standards



Calcium carbonate (Limestone, Marble, Whiting) SWA [AUS] -- 10 -- --

Quartz (respirable dust) SWA [AUS] -- 0.05 -- --

Quartz (respirable dust) (Precautionary advice) WorkSafe VIC -- 0.02 -- --





PPE


Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves.



Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.



9.1 Information on basic physical and chemical propertiesOFF-WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point840°C (Decomposes)Boiling point825°CMelting pointNOT AVAILABLEEvaporation rate9pHNOT AVAILABLEVapour density2.7Relative densityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold







Incompatible with acids (e.g. nitric acid), fluorine, aluminium (hot) and ammonium salts. Incompatible with oxidising agents (e.g.hypochlorites).


Polymerization will not occur.


10.1 ReactivityCalcium carbonate reacts with acids and acidic salts to generate gaseous carbon dioxide with effervescence (bubbling). The reactionwith concentrated solutions of acids is rapid and exothermic. The effervesence can create extensive foaming. Ignites on contact withfluorine.





This product is expected to be of low toxicity. Based on available data, the classification criteria are not met.LD50 (Ingestion) = 6450 mg/kg (rat).

Acute toxicity



> 5000 mg/kg (rat) -- --LIMESTONE (CALCIUM CARBONATE)

Not classified as a skin irritant. Contact may result in mild irritation, redness and rash.Skin

Contact may result in irritation, lacrimation, pain and redness.Eye




Not classified as causing organ damage from repeated exposure. Chronic exposure to respirable silica mayresult in pulmonary fibrosis (silicosis). However, given the low levels present, over exposure is notanticipated.



Insufficient data available to classify as a carcinogen.Carcinogenicity




12.1 Toxicity

Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated tocause adverse environmental effects.

12.2 Persistence and degradabilityDissolved calcium carbonate dissociates into calcium and carbonate ions. Calcium ions will be assimilated by living organisms in thewater and the carbonate will become part of the carbon cycle.


Due to its limited solubility, calcium carbonate precipitates and deposits on the sediment.

Avoid contamination of drains and waterways.


12.3 Bioaccumulative potentialThis product does not bioaccumulate.


Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).


Waste disposal








None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number









Poison schedule


Inventory listings

Safe Work Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals (GHS Revision 7).

Classifications



EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. Ifnot used in a closed system, local exhaust ventilation is recommended to control exposure. Provideeye wash and safety shower in close proximity to points of potential exposure. Where the potentialfor an inhalation risk exists, an approved respirator may be required. Do not eat, store, consumefood, tobacco or drink in areas where product is used.










Abbreviations




Report status


Prepared by

[ End of SDS ]




CALCIUM CHLORIDE ANHYDRATESynonyms

CONCRETE CONDITIONER ● DESICCANT ● DUST CONTROL AGENT ● FOOD ADDITIVE ● INDUSTRIALAPPLICATIONS

Uses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





CALCIUM CHLORIDE POWDER 94-97%Product name




Signal word WARNING

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.

P305 + P351 + P338

If eye irritation persists: Get medical advice/attention.P337 + P313

Response statements

Wash thoroughly after handling.P264Wear protective gloves/protective clothing/eye protection/face protection.P280

Prevention statements

Causes serious eye irritation.H319Hazard statements

Pictograms

Physical Hazards


Health Hazards

Serious Eye Damage / Eye Irritation: Category 2A






www.newpark.com

CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME


Disposal statementsNone allocated.




94 to 97%10043-52-4 233-140-8CALCIUM CHLORIDE ANHYDROUS

1 to 5%7647-14-5 231-598-3SODIUM CHLORIDE

1%7732-18-5 231-791-2WATER





Eye



Skin


Ingestion


Irritating to the eyes and skin.4.2 Most important symptoms and effects, both acute and delayed



Non flammable. May evolve toxic gases (chlorides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code



Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.






Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up



Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use.




Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminatedareas.



Exposure standards



PPE








9.1 Information on basic physical and chemical propertiesWHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point> 1600°CBoiling point772°CMelting pointNOT RELEVANTEvaporation rate7.0 to 9.0pHNOT AVAILABLEVapour density2.15Specific gravity590 kg/m³ (Approximately)Solubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limit




9.1 Information on basic physical and chemical propertiesNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold





Avoid contact with incompatible substances.


Incompatible with acids (e.g. nitric acid), methyl vinyl ether, zinc/ galvanised metals, bromine trifluoride, boron oxide and calciumoxide. May react exothermically with water (i.e. releasing heat).

May evolve toxic gases (chlorides) when heated to decomposition.10.6 Hazardous decomposition products





Based on available data, the classification criteria are not met. Toxicity Data available for the ingredients:CALCIUM CHLORIDE ANHYDROUS (10043-52-4): LD50 (Ingestion): 1000 mg/kg (rat) LD50 (Intraperitoneal): 210 mg/kg (mouse) LD50 (Intravenous): 42 mg/kg (mouse) LD50 (Subcutaneous): 823 mg/kg (mouse) LDLo (Ingestion): 1384 mg/kg (rabbit) LDLo (Intravenous): 150 mg/kg (guinea pig) LDLo (Subcutaneous): 249 mg/kg (cat) TDLo (Intravenous): 20 mg/kg/1 hour (woman)SODIUM CHLORIDE (7647-14-5): LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human)

Acute toxicity



2301 mg/kg (rat) > 5000 mg/kg (rabbit) --CALCIUM CHLORIDE ANHYDROUS

3000 mg/kg (rat) > 10000 mg/kg (rabbit) > 42000 mg/m³/1 hour(rat)

SODIUM CHLORIDE





Not classified as a skin irritant. Contact may result in mechanical irritation, redness and rash.Skin

Causes serious eye irritation. Contact may result in irritation, lacrimation, pain and redness.Eye









SODIUM CHLORIDE (7647-14-5)LD50 (intraperitoneal) 2602 mg/kg (mouse)LD50 (intravenous) 645 mg/kg (mouse)LD50 (subcutaneous) 3000 mg/kg (mouse)LDLo (intravenous) 300 mg/kg (guinea pig)LDLo (oral) 8000 mg/kg (rabbit)LDLo (subcutaneous) 2160 mg/kg (guinea pig)TDLo (oral) 12357 mg/kg (human)


12.1 Toxicity


12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.









Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number













Poison schedule


Inventory listings


Classifications








Abbreviations







While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the information containedin this SDS.

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[ End of SDS ]




SODIUM HYDROXIDE SOLIDSynonyms

MANUFACTURE OF CHEMICALS ● REAGENT ● SCRUBBING AGENTUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





CAUSTIC SODAProduct name




Signal word DANGER

Do not breathe dust/fume/gas/mist/vapours/spray.P260Wash thoroughly after handling.P264Wear protective gloves/protective clothing/eye protection/face protection.P280


Causes severe skin burns and eye damage.H314Hazard statements

Pictograms

Physical Hazards


Health Hazards

Skin Corrosion/Irritation: Category 1A






www.newpark.com

CAUSTIC SODAPRODUCT NAME



Store locked up.P405Storage statements

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.P301 + P330 + P331IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin withwater/shower.

P303 + P361 + P353

IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.

P305 + P351 + P338

Immediately call a POISON CENTER or doctor/physician.P310Specific treatment is advised - see first aid instructions.P321Wash contaminated clothing before reuse.P363

Response statements



>99%1310-73-2 215-185-5SODIUM HYDROXIDE





Eye

If inhaled, remove from contaminated area. To protect rescuer, use an Air-line respirator where an inhalationrisk exists. Apply artificial respiration if not breathing.

Inhalation


Skin


Ingestion


Causes severe skin burns and eye damage.4.2 Most important symptoms and effects, both acute and delayed

4.3 Immediate medical attention and special treatment neededCORROSIVE POISONING TREATMENT: Immediate treatment preferably in a hospital is mandatory. In treating corrosive poisoning,DO NOT INDUCE VOMITING; DO NOT ATTEMPT GASTRIC LAVAGE; and DO NOT ATTEMPT TO NEUTRALISE THE CORROSIVESUBSTANCE. Vomiting will increase the severity of damage to the oesophagus as the corrosive substance will again come incontact with it. Attempting gastric lavage may result in perforating either the oesophagus or stomach. Immediately dilute the corrosivesubstance by having the patient drink milk or water. If the trachea has been damaged tracheostamy may be required. Foroesophageal burns begin broad-spectrum antibiotics and corticosteroid therapy. Intravenous fluids will be required if oesophageal orgastric damage prevents ingestion of liquids. Long-range therapy will be directed toward preventing or treating oesophageal scarsand strictures.


Non flammable. May evolve flammable hydrogen gas in contact with some metals. Direct contact with water can produce a violentexothermic reaction.

5.2 Special hazards arising from the substance or mixture

Use an extinguishing agent suitable for the surrounding fire. Use carbon dioxide or suitable dry chemical extinguisher. Do NOT usewater.

5.1 Extinguishing media






2X2 Fine Water Spray.X Wear liquid-tight chemical protective clothing and breathing apparatus. Contain spill and run-off.

5.4 Hazchem code


Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Allow only trained personnel wearing appropriateprotective equipment to be involved in spill response. Avoid accidents, clean up immediately. Increase ventilation. Avoid walkingthrough spilled product as it is slippery when spilt. Isolate the danger area. Use clean, non-sparking tools and equipment. Shut off allpossible sources of ignition.



Mechanically collect as much of the spill as possible. Absorb with sand, earth or clay. Transfer to suitable, labelled,corrosion-resistant containers and dispose of promptly as hazardous waste. Spill on areas other than pavement, dirt or sand may behandled by removing the affected soils and placing into approved containers.




Store in a cool, dry, well-ventilated area. Keep containers tightly closed when not in use. Inspect regularly for deficiencies such asdamage or leaks. Protect against physical damage. Store away from incompatible materials as listed in section 10. Store away fromaluminium, tin, zinc and alloys (bronzes), chrome and lead. Protect from damp and kept apart from acids, halogenated hydrocarbons,nitroparaffins, etc. The floor must be waterproof and anti-slip. A water supply or source must be provided in the place of storage.Emergency showers and eye-washes must be available. Special conditions: Prevent the product from becoming damp or erated.Hygroscopic product. Becomes carbonated in contact with the air or moisture.




Ensure an eye bath and safety shower are available and ready for use. Observe good personal hygiene practices and recommendedprocedures. Wash thoroughly after handling. Take precautionary measures against static discharges by bonding and groundingequipment. Avoid contact with eyes, skin and clothing. Do not inhale product vapours. Avoid prolonged or repeated exposure. Do notsmoke, eat or drink when handling product. Product can react violently with water and acids. Caustic solution generates heat whenfurther diluted with water. Concentrations greater than 40%, the heat generated can raise temperatures above the boiling pointresulting in sporadic, violent eruptions or spattering. Emergency showers and eye-washes must be available. When used in itsvarious applications, the product must be prevented from coming into uncontrolled direct contact with other products such as acidsand metals. Never neutralise the solid product.



Exposure standards



Sodium hydroxide (peak limitation) SWA [AUS] -- 2 (Peak) -- --

Biological limits

No biological limit values have been entered for this product.




PPE

Eye / Face Wear a faceshield and dust-proof goggles.


Body Wear coveralls and rubber boots and a PVC apron.

Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear anAir-line respirator or a Full-face Class P3 (Particulate) respirator.




9.1 Information on basic physical and chemical propertiesWHITE DELIQUESCENT PEARLSAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point1390°CBoiling point318°CMelting pointNOT AVAILABLEEvaporation rate13.5 (1 % solution)pHNOT AVAILABLEVapour density2.12Specific gravity1110 kg/m³ @ 20°CSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold








10.1 ReactivityHighly exothermal reaction with strong acids. Reacts dangerously with acetic acid, allyl chloride, chlorine trifluoride, chloroform,methylic alcohol, chloronitrotoluene, chlorosulphonic acid, glyoxal, cyanohydrin, hydrochloric acid, hydrofluoric acid, hydroquinone,nitric acid, sulphuric acid and oleum, nitropropane, phosphorous, propiolactone, phosphorous pentoxide, tetrachlorobenzene,tetrahydrofuran, etc. Caustic soda forms salts with nitromethane and nitroparaffins that explode on impact. Heat is generated whenmixed with water. Spattering and boiling can occur. Caustic soda solution reacts readily with various reducing sugars (ie: fructose,glactose, maltose, dry whey solids) to produce carbon monoxide. Caustic soda forms salts with nitromethane and nitroparaffins thatexplode on impact. Reacts with aluminium, tin, zinc and their alloys, copper, lead, etc. giving off hydrogen.





Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), metals, heat and ignition sources.

Reacts with aluminium, tin, zinc and their alloys, copper, lead, etc. giving off hydrogen. When the product decomposes, toxic sodiumoxide gases are evolved.

10.6 Hazardous decomposition products


Highly corrosive. This product has the potential to cause serious adverse health effects. Use safe workpractices to avoid eye or skin contact and inhalation. Over exposure may result in severe burns withcorrosive tissue damage. Upon dilution, the potential for corrosive effects may be reduced.

SODIUM HYDROXIDE (1310-73-2):LD50 (Intraperitoneal): 40 mg/kg (mouse)LDLo (Ingestion): 1.57 mg/kg (human)

Acute toxicity

Causes severe burns. Contact may result in irritation, redness, pain, rash, dermatitis and skin burns.Skin

Causes severe burns. Contact may result in irritation, lacrimation, pain, redness and corneal burns withpossible permanent eye damage.

Eye


Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may resultin breathing difficulties.

STOT - singleexposure



Not classified as a reproductive toxin. Insufficient data available to classify as a reproductive toxin. Thesubstance is not expected to be systemically available in the body under normal handling and use conditionsand for this reason it can be stated that the substance will not reach the foetus nor reach male and femalereproductive organs. The substance is not expected to be systemically available in the body under normalhandling and use conditions and for this reason additional testing is considered unnecessary.

Reproductive

Not classified as a carcinogen. Insufficient data available to classify as a carcinogen. Systemiccarcinogenicity is not expected to occur because the substance is not expected to be systemically availablein the body under normal handling and use conditions.

Carcinogenicity

Insufficient data available to classify as a mutagen. Both the in vitro and the in vivo genetic toxicity testsindicated no evidence of mutagenic activity. Furthermore the substance is not expected to be systemicallyavailable in the body under normal handling and use conditions and for this reason additional testing isconsidered unnecessary (EU RAR, 2007).

Mutagenicity


SODIUM HYDROXIDE (1310-73-2)LD50 (intraperitoneal) 40 mg/kg (mouse)LDLo (oral) 500 mg/kg (rabbit)



12.1 Toxicity

EC50 Ceriodaphnia: 40 mg/L.

No other valid studies available. The hazard of NaOH for the environment is caused by the hydroxyl ion (pH effect). For this reason theeffect of NaOH on the organisms depends on the buffer capacity of the aquatic or terrestrial ecosystem (see also 3.1.2). Also thevariation in acute toxicity for aquatic organisms can be explained for a significant extent by the variation in buffer capacity of the testmedium. LC50 values ranged between 33 and 189 mg/L.

12.2 Persistence and degradabilityReadily biodegradable. NaOH is a strong alkaline substance that dissociates completely in water to Na+ and OH-. High watersolubility and low vapour pressure indicate that NaOH will be found predominantly in aquatic environment. This implies that it will notadsorb on particulate matter or surfaces. Atmospheric emissions as aerosols are rapidly neutralized by carbon dioxide and the saltswill be washed out by rain.





High water solubility and mobility

WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11(goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Notexpected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out.


12.3 Bioaccumulative potentialDoes not bioaccumulate. Considering its high water solubility, NaOH is not expected to bioconcentrate in organisms. In addition,sodium is a naturally-occurring element that is prevalent in the environment and to which organisms are exposed regularly, for whichthey have some capacity to regulate the concentration in the organism.


Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information (if required). The product can be neutralisedusing highly diluted hydrochloric acid, which should be added very slowly by specialised personnel wearingproper protection. Never neutralise the solid product.


Waste disposal




II

8 8

II II

814.3 Transporthazard class

14.4 Packing Group

SODIUM HYDROXIDE, SOLID

1823


1823 1823


14.1 UN Number




2XHazchem code

F-A, S-BEmS

8A1GTEPG


CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE


Classified as a Schedule 6 (S6) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Poison schedule


Inventory listings


Classifications









Abbreviations




Report status


Prepared by


[ End of SDS ]




2-HYDROXY-1,2,3-PROPANETRICARBOXYLIC ACID ● CITRIC ACID ANHYDROUS ● CITRIC ACIDMONOHYDRATE

Synonyms

INDUSTRIAL APPLICATIONSUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





CITRIC ACIDProduct name




Signal word WARNING

Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280


Causes skin irritation.H315Causes serious eye irritation.H319May cause respiratory irritation.H335

Hazard statements

Pictograms

Physical Hazards


Health Hazards

Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 2ASpecific Target Organ Toxicity (Single Exposure): Category 3 (Respiratory Irritation)






www.newpark.com

CITRIC ACIDPRODUCT NAME



Store in a well-ventilated place. Keep container tightly closed.P403 + P233Store locked up.P405

Storage statements

IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.

P305 + P351 + P338

Call a POISON CENTER or doctor/physician if you feel unwell.P312Specific treatment is advised - see first aid instructions.P321Take off contaminated clothing and wash before re-use.P362

Response statements



>99%77-92-9 201-069-1CITRIC ACID

<1%7732-18-5 231-791-2WATER





Eye



Skin


Ingestion


Irritating to the eyes, skin and respiratory system.4.2 Most important symptoms and effects, both acute and delayed






None allocated.

5.4 Hazchem code

Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.5.1 Extinguishing media





Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures


Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up



Store in a cool, dry, well ventilated area, removed from moisture, incompatible substances and foodstuffs. Ensure containers areadequately labelled, protected from physical damage and sealed when not in use.







Exposure standards



PPE




Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.




9.1 Information on basic physical and chemical propertiesWHITE CRYSTALLINE POWDERAppearanceODOURLESSOdourCOMBUSTIBLEFlammability174°CFlash point175°C (Decomposes)Boiling point153°CMelting point




9.1 Information on basic physical and chemical propertiesNOT AVAILABLEEvaporation rate2.2 (0.1M Solution)pHNOT AVAILABLEVapour density1.665Specific gravity1330 kg/m³ @ 20°CSolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficient345°CAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold







Incompatible with oxidising agents (e.g. hypochlorites) and alkalis (e.g. sodium hydroxide).






Based on available data, the classification criteria are not met. LD50 (Ingestion): 3000 mg/kg (rat)LD50 (Intraperitoneal): 290 mg/kg (rat)LD50 (Intravenous): 42 mg/kg (mouse)LDLo (Ingestion): 7000 mg/kg (rabbit)

Acute toxicity



3000 mg/kg (rat) > 2000 mg/kg (rat) --CITRIC ACID

Irritating to the skin. Contact may result in irritation, redness, rash and dermatitis.Skin

Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness. May result in burns withprolonged contact.

Eye

Not classified as causing skin or respiratory sensitisation. However, citric acid has the potential to causeallergic effects.

Sensitisation



CITRIC ACID (77-92-9)LD50 (intraperitoneal) 290 mg/kg (rat)LD50 (intravenous) 42 mg/kg (mouse)LDLo (oral) 7000 mg/kg (rabbit)





Irritating to the respiratory system. Over exposure may result in irritation of the nose and throat, withcoughing.







12.1 Toxicity

LC50 (Leuciscus idus melanotus): 440 mg/L/48hrs.LC50 (Daphnia magna (Water flea)): 1.535 mg/L/24hrs.

12.2 Persistence and degradabilityThis product is readily biodegradable.


Citric acid is expected to have very high mobility in soil (HSDB).





Neutralise with lime, anion exchanger or similar. For small amounts, absorb with sand or similar anddispose of to an approved landfill site. Contact the manufacturer/supplier for additional information (ifrequired).


Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number










Poison schedule


Classifications





Inventory listings






Abbreviations




Report status


Prepared by





[ End of SDS ]




DEFOAMERSynonyms

TREATMENT OF FOAMING IN DRILLING FLUIDSUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





DEFOAM AP 400Product name








45 to 60%25322-68-3 500-038-2POLYETHYLENE GLYCOL

40 to 55%123-96-6 204-667-0OCTAN-2-OL





Eye



Skin


None allocated.First aid facilities


Revision No: 2ofPage 1 6

www.newpark.com

DEFOAM AP 400PRODUCT NAME




Non flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code






Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal. Eliminate all sources of ignition.




Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Large storage areas should have appropriate ventilation systems.







Exposure standards






PPE





Avoid inhalation. Use in well ventilated areas.8.2 Exposure controlsEngineering controls


9.1 Information on basic physical and chemical propertiesCLEAR COLOURLESS LIQUIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point100°C to 102°CBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate7 to 8pHNOT AVAILABLEVapour density1.00 to 1.17Specific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

9.2 Other information-7°C to 0°CFreezing point
















This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated.

Acute toxicity



> 15,000 mg/kg (rat) > 20,000 mg/kg (rabbit) --POLYETHYLENE GLYCOL

-- 2000 mg/kg (rat) --OCTAN-2-OL








Not classified as a carcinogen.Carcinogenicity




12.1 Toxicity


12.2 Persistence and degradabilityNo information provided.





12.3 Bioaccumulative potentialNo information provided.




Waste disposal








None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number









Poison schedule


Inventory listings


Classifications










Abbreviations




Report status


Prepared by

[ End of SDS ]



SAFETY DATA SHEET

Driscal® D Polymer Version 1.10 Revision Date 2018-09-20

SDS Number:100000066569 1/9

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product information

Product Name : Driscal® D Polymer Material : 1112534, 1016818

Company : Chevron Phillips Chemical Company LP

Drilling Specialties Company LLC 10001 Six Pines Drive The Woodlands, TX 77380

Local : Chevron Phillips Chemicals Australia Pte Ltd

Suite 409 685 Burke Road Camberwell, Victoria Australia 3124 Hours of Operation: 9:00 a.m. - 5:00 p.m. SDS Requests: 61 3 8080 5700 Technical Information: 61 3 8080 5700 Responsible Party: Product Safety Group Email:[email protected]

Emergency telephone:

Health: 866.442.9628 (North America) 1.832.813.4984 (International) 61 3 8080 5700 (Australia) Transport: CHEMTREC 800.424.9300 or 703.527.3887(int'l) Asia: CHEMWATCH (+612 9186 1132) China: 0532 8388 9090 EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) Mexico CHEMTREC 01-800-681-9531 (24 hours) South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600 Argentina: +(54)-1159839431

SAFETY DATA SHEET


SDS Number:100000066569 2/9

Responsible Department : Product Safety and Toxicology Group E-mail address : [email protected] Website : www.CPChem.com

SECTION 2: Hazards identification

Classification of the substance or mixture Model Work Health and Safety Regulations 2011, Model Code of Practice for the Labelling of Workplace Hazardous Chemicals (2011), Guidance on the Classification of Hazardous Chemicals under the WHS Regulations (2012) (GHS 2009)

Classification

Not a hazardous substance or mixture.

Labeling

Not a hazardous substance or mixture.

SECTION 3: Composition/information on ingredients

Synonyms : High Temperature Polymer

Contains no hazardous ingredients according to GHS. SECTION 4: First aid measures

General advice : No hazards which require special first aid measures. If inhaled : If unconscious, place in recovery position and seek medical

advice. If symptoms persist, call a physician. In case of eye contact : Remove contact lenses. Protect unharmed eye. If eye

irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Never give anything by mouth to

an unconscious person. If symptoms persist, call a physician.

SECTION 5: Firefighting measures

Flash point : Not applicable Autoignition temperature : No data available

Specific hazards during fire fighting

: Risks of ignition followed by flame propagation or secondary explosions can be caused by the accumulation of dust, e.g. on floors and ledges.

Special protective equipment for fire-fighters

: Wear self-contained breathing apparatus for firefighting if necessary.

Further information : Standard procedure for chemical fires. Use extinguishing

measures that are appropriate to local circumstances and the surrounding environment.

SAFETY DATA SHEET


SDS Number:100000066569 3/9

Fire and explosion protection

: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Provide appropriate exhaust ventilation at places where dust is formed.

Hazardous decomposition products

: No data available.

SECTION 6: Accidental release measures

Personal precautions : Avoid dust formation. Environmental precautions : If the product contaminates rivers and lakes or drains inform

respective authorities. Methods for cleaning up : Pick up and arrange disposal without creating dust. Clean up

promptly by sweeping or vacuum. Keep in suitable, closed containers for disposal.

Additional advice : Contaminated surfaces will be extremely slippery. Avoid

spillage on floor as the product can become very slippery when wet. Sweep up to prevent slipping hazard. Dust deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air).

SECTION 7: Handling and storage

Handling

Advice on safe handling : For personal protection see section 8. Smoking, eating and

drinking should be prohibited in the application area. Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary, but may not by themselves be sufficient.

Advice on protection against fire and explosion


Storage

Requirements for storage areas and containers

: Electrical installations / working materials must comply with the technological safety standards.

Advice on common storage : No materials to be especially mentioned.

SECTION 8: Exposure controls/personal protection

Engineering measures

SAFETY DATA SHEET


SDS Number:100000066569 4/9

Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances.

Personal protective equipment

Respiratory protection : Wear a supplied-air NIOSH approved respirator unless

ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under normal atmospheric pressure. Wear a NIOSH approved respirator that provides protection when working with this material if exposure to harmful levels of airborne material may occur, such as:. Air-Purifying Respirator for Dusts and Mists / P100. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection.

Hand protection : The suitability for a specific workplace should be discussed

with the producers of the protective gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Eye protection : Eye wash bottle with pure water. Safety glasses. Skin and body protection : Choose body protection in relation to its type, to the

concentration and amount of dangerous substances, and to the specific work-place. Wear as appropriate:. Protective suit. Safety shoes.

Hygiene measures : General industrial hygiene practice.

SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties

Appearance

Form : Powder Physical state : Solid Color : White Odor : No odor Odor Threshold : No data available

Safety data

Flash point : Not applicable

Lower explosion limit : No data available

Upper explosion limit : No data available

SAFETY DATA SHEET


SDS Number:100000066569 5/9

Oxidizing properties : No

Autoignition temperature : No data available

Thermal decomposition : No data available

Molecular weight : Not applicable

pH : Not applicable

Pour point : No data available

Boiling point/boiling range : No data available

Vapor pressure : No data available

Relative density : 1.44

Density : No data available

Water solubility : Soluble

Partition coefficient: n-octanol/water

: Pow: < 3

Viscosity, kinematic : No data available

Relative vapor density : No data available

Evaporation rate : No data available

SECTION 10: Stability and reactivity

Chemical stability : This material is considered stable under normal ambient and

anticipated storage and handling conditions of temperature and pressure.

Possibility of hazardous reactions

Hazardous reactions : Hazardous reactions: Hazardous polymerization does not

occur.

Further information: Stable under recommended storage conditions., No hazards to be specially mentioned.

Conditions to avoid : Generation of Dusts. Thermal decomposition : No data available

Hazardous decomposition products

: No data available

SAFETY DATA SHEET


SDS Number:100000066569 6/9

Other data : No decomposition if stored and applied as directed.

SECTION 11: Toxicological information

Driscal® D Polymer Further information : The product contains no substances classified as hazardous

to health in concentrations which should be taken into account.

SECTION 12: Ecological information

Biodegradability : Taking into consideration the properties of several ingredients,

the product is estimated not to be readily biodegradable according to OECD classification.

Elimination information (persistence and degradability) Bioaccumulation : Accumulation in aquatic organisms is unlikely.

Additional ecological information

: This material is not expected to be harmful to aquatic organisms.

Ecotoxicology Assessment

SECTION 13: Disposal considerations

The information in this SDS pertains only to the product as shipped.

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility.

Contaminated packaging : Empty containers should be taken to an approved waste

handling site for recycling or disposal.

SECTION 14: Transport information

The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition).

Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the SDS and the bill of lading.

US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION)

SAFETY DATA SHEET


SDS Number:100000066569 7/9

NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE)) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE))


ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS)



SECTION 15: Regulatory information

National legislation

Standard for the Uniform Scheduling of Medicines and Poisons

: No poison schedule number allocated

Notification status Europe REACH : On the inventory, or in compliance with the inventory Switzerland CH INV : On the inventory, or in compliance with the inventory United States of America (USA) TSCA

: On TSCA Inventory

Canada DSL : All components of this product are on the Canadian DSL

Australia AICS : On the inventory, or in compliance with the inventory New Zealand NZIoC : On the inventory, or in compliance with the inventory Japan ENCS : Not in compliance with the inventory Korea KECI : Not in compliance with the inventory Philippines PICCS : Not in compliance with the inventory China IECSC : This product contains one or more substances that

have been notified under New Substances Notification

SAFETY DATA SHEET


SDS Number:100000066569 8/9

laws. However, only CPChem and other independent notifiers are approved to be the importers of record.

SECTION 16: Other information

Further information

Legacy SDS Number : 244990

Significant changes since the last version are highlighted in the margin. This version replaces all previous versions. The information in this SDS pertains only to the product as shipped.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportat ion, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of

Government Industrial Hygienists LD50 Lethal Dose 50%

AICS Australia, Inventory of Chemical Substances

LOAEL Lowest Observed Adverse Effect Level

DSL Canada, Domestic Substances List

NFPA National Fire Protection Agency

NDSL Canada, Non-Domestic Substances List

NIOSH National Institute for Occupational Safety & Health

CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZloC New Zealand Inventory of

Chemicals EC50 Effective Concentration NOAEL No Observable Adverse Effect

Level EC50 Effective Concentration 50% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure

Scenario Tool OSHA Occupational Safety & Health

Administration EOSCA European Oilfield Specialty

Chemicals Association PEL Permissible Exposure Limit

EINECS European Inventory of Existing Chemical Substances

PICCS Philippines Inventory of Commercial Chemical Substances

MAK Germany Maximum Concentration Values

PRNT Presumed Not Toxic

GHS Globally Harmonized System RCRA Resource Conservation Recovery Act

>= Greater Than or Equal To STEL Short-term Exposure Limit IC50 Inhibition Concentration 50% SARA Superfund Amendments and

Reauthorization Act. IARC International Agency for Research

on Cancer TLV Threshold Limit Value

IECSC Inventory of Existing Chemical Substances in China

TWA Time Weighted Average

ENCS Japan, Inventory of Existing and New Chemical Substances

TSCA Toxic Substance Control Act

KECI Korea, Existing Chemical Inventory

UVCB Unknown or Variable Composition, Complex Reaction Products, and Biological Materials

<= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System

LC50 Lethal Concentration 50%

SAFETY DATA SHEET


SDS Number:100000066569 9/9

SAFETY DATA SHEET

Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30

SDS Number:100000014007 1/11

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product information

Product Name : Drispac® (Regular and Superlo®) Polymer Material : 1016806, 1016803, 1116045

Use : Drilling Mud Additive Company : Chevron Phillips Chemical Company LP

Drilling Specialties Company LLC 10001 Six Pines Drive The Woodlands, TX 77380

Emergency telephone:

Health: 866.442.9628 (North America) 1.832.813.4984 (International) Transport: CHEMTREC 800.424.9300 or 703.527.3887(int'l) Asia: CHEMWATCH (+612 9186 1132) China: 0532 8388 9090 EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) Mexico CHEMTREC 01-800-681-9531 (24 hours) South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600 Argentina: +(54)-1159839431

Responsible Department : Product Safety and Toxicology Group E-mail address : [email protected] Website : www.CPChem.com

SECTION 2: Hazards identification

Classification of the substance or mixture This product has been classified in accordance with the hazard communication standard 29 CFR 1910.1200; the SDS and labels contain all the information as required by the standard.

Classification : Combustible dust

Labeling

Signal Word : Warning

SAFETY DATA SHEET


SDS Number:100000014007 2/11

Hazard Statements : May form combustible dust concentrations in air.

Carcinogenicity:

IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

SECTION 3: Composition/information on ingredients

Synonyms : Viscosifier, Water loss control agent

Component CAS-No. Weight % Sodium Carboxymethylcellulose 9004-32-4 98 - 100

SECTION 4: First aid measures

General advice : No hazards which require special first aid measures. If inhaled : If unconscious, place in recovery position and seek medical

advice. If symptoms persist, call a physician. In case of eye contact : Remove contact lenses. Protect unharmed eye. If eye

irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Do not give milk or alcoholic

beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.

SECTION 5: Firefighting measures

Flash point : Not applicable Autoignition temperature : Not applicable

Unsuitable extinguishing media

: High volume water jet.

Specific hazards during fire fighting

: Risks of ignition followed by flame propagation or secondary explosions shall be prevented by avoiding accumulation of dust, e.g. on floors and ledges.


: Wear self-contained breathing apparatus for firefighting if necessary.

SAFETY DATA SHEET


SDS Number:100000014007 3/11

Further information : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Fire and explosion protection


SECTION 6: Accidental release measures

Personal precautions : Avoid dust formation. Environmental precautions : Prevent further leakage or spillage if safe to do so. If the

product contaminates rivers and lakes or drains inform respective authorities.

Methods for cleaning up : Pick up and arrange disposal without creating dust. Sweep up

and shovel. Keep in suitable, closed containers for disposal. Additional advice : Contaminated surfaces will be extremely slippery. Avoid

spillage on floor as the product can become very slippery when wet. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air).

SECTION 7: Handling and storage

Handling

Advice on safe handling : For personal protection see section 8. Smoking, eating and

drinking should be prohibited in the application area. Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary, but may not by themselves be sufficient.

Advice on protection against fire and explosion


Storage

Requirements for storage areas and containers

: Electrical installations / working materials must comply with the technological safety standards.

Advice on common storage : No materials to be especially mentioned. Use : Drilling Mud Additive

SECTION 8: Exposure controls/personal protection

Engineering measures

Adequate ventilation to control airborned concentrations below the exposure guidelines/limits.

SAFETY DATA SHEET


SDS Number:100000014007 4/11

Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances.


Respiratory protection : Wear a supplied-air NIOSH approved respirator unless

ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under normal atmospheric pressure. Wear a NIOSH approved respirator that provides protection when working with this material if exposure to harmful levels of airborne material may occur, such as:. Air-Purifying Respirator for Dusts and Mists / P100. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection.

Hand protection : The suitability for a specific workplace should be discussed

with the producers of the protective gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Eye protection : Eye wash bottle with pure water. Safety glasses. Skin and body protection : Choose body protection in relation to its type, to the

concentration and amount of dangerous substances, and to the specific work-place. Wear as appropriate:. Protective suit. Safety shoes.

Hygiene measures : General industrial hygiene practice.

SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties

Appearance

Form : Powder Physical state : Solid Color : White to off-white Odor : Slight Odor Threshold : No data available

Safety data

Flash point : Not applicable

Lower explosion limit : Not applicable

Upper explosion limit : Not applicable

SAFETY DATA SHEET


SDS Number:100000014007 5/11

Flammability (solid, gas) : May form combustible dust concentrations in air.

Oxidizing properties : no

Autoignition temperature : Not applicable

Thermal decomposition : No data available

Molecular weight : No data available

pH : Not applicable

Pour point : No data available

Melting point/range No data available

Boiling point/boiling range : No data available

Vapor pressure : Not applicable

Relative density : Not applicable

Density : 1.5 g/cm3

Water solubility : Completely Soluble

Partition coefficient: n-octanol/water

: No data available

Solubility in other solvents : No data available

Viscosity, kinematic : No data available

Relative vapor density : Not applicable

Evaporation rate : No data available

SECTION 10: Stability and reactivity

Reactivity : Stable at normal ambient temperature and pressure.

Chemical stability : This material is considered stable under normal ambient and

anticipated storage and handling conditions of temperature and pressure.

Possibility of hazardous reactions

Hazardous reactions : Further information: Stable under recommended storage

conditions., No hazards to be specially mentioned.

SAFETY DATA SHEET


SDS Number:100000014007 6/11

Conditions to avoid : Generation of Dusts. Materials to avoid : No data available. Thermal decomposition : No data available

Other data : No decomposition if stored and applied as directed.

SECTION 11: Toxicological information

Acute oral toxicity

Sodium Carboxymethylcellulose

: LD50: 27,000 mg/kg Species: Rat

Acute inhalation toxicity


: LC50: > 5800 mg/m3Exposure time: 4 h Species: Rat Test atmosphere: dust/mist

Drispac® (Regular and Superlo®) Polymer Further information : No data available.

SECTION 12: Ecological information

Ecotoxicity effects Toxicity to fish : This material is not expected to be harmful to aquatic

organisms.

Toxicity to daphnia and other aquatic invertebrates


Toxicity to algae : This material is not expected to be harmful to aquatic

organisms.

Biodegradability Sodium Carboxymethylcellulose

: This material is expected to be readily biodegradable.

Bioaccumulation Sodium Carboxymethylcellulose

: This material is not expected to bioaccumulate.

Mobility

SAFETY DATA SHEET


SDS Number:100000014007 7/11


: No data available

Additional ecological information

: No data available

Ecotoxicology Assessment

Short-term (acute) aquatic hazard Sodium Carboxymethylcellulose


Long-term (chronic) aquatic hazard Sodium Carboxymethylcellulose


SECTION 13: Disposal considerations

The information in this SDS pertains only to the product as shipped.

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility.

Contaminated packaging : Empty containers should be taken to an approved waste

handling site for recycling or disposal.

SECTION 14: Transport information

The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition). Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the SDS and the bill of lading.

US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

SAFETY DATA SHEET


SDS Number:100000014007 8/11

ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE)) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE))


ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS)



SECTION 15: Regulatory information

National legislation

SARA 311/312 Hazards : Combustible dust

CERCLA Reportable Quantity

: This material does not contain any components with a CERCLA RQ.

SARA 302 Reportable Quantity

: This material does not contain any components with a SARA 302 RQ.

SARA 302 Threshold Planning Quantity

: This material does not contain any components with a section 302 EHS TPQ.

SARA 304 Reportable Quantity

: This material does not contain any components with a section 304 EHS RQ.

SARA 313 Components : This material does not contain any chemical components with

known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

Clean Air Act

SAFETY DATA SHEET


SDS Number:100000014007 9/11

Ozone-Depletion Potential

: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): : Sodium Carboxymethylcellulose - 9004-32-4

US State Regulations

Pennsylvania Right To Know : Sodium Carboxymethylcellulose - 9004-32-4 California Prop. 65 Components

: This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.

Notification status Europe REACH : This product is in full compliance according to REACH

regulation 1907/2006/EC. Switzerland CH INV : Not in compliance with the inventory United States of America (USA) TSCA

: On or in compliance with the active portion of the TSCA inventory

Canada DSL : All components of this product are on the Canadian DSL

Australia AICS : On the inventory, or in compliance with the inventory New Zealand NZIoC : On the inventory, or in compliance with the inventory Japan ENCS : On the inventory, or in compliance with the inventory Korea KECI : A substance(s) in this product was not registered,

notified to be registered, or exempted from registration by CPChem according to K-REACH regulations. Importation or manufacture of this product is still permitted provided the Korean Importer of Record has themselves notified the substance.

Philippines PICCS : On the inventory, or in compliance with the inventory China IECSC : On the inventory, or in compliance with the inventory Taiwan TCSI : On the inventory, or in compliance with the inventory

SAFETY DATA SHEET


SDS Number:100000014007 10/11

SECTION 16: Other information

NFPA Classification : Health Hazard: 0 Fire Hazard: 2 Reactivity Hazard: 0

Further information

Legacy SDS Number : 25950

Significant changes since the last version are highlighted in the margin. This version replaces all previous versions. The information in this SDS pertains only to the product as shipped.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of

Government Industrial Hygienists LD50 Lethal Dose 50%

AICS Australia, Inventory of Chemical Substances

LOAEL Lowest Observed Adverse Effect Level

DSL Canada, Domestic Substances List

NFPA National Fire Protection Agency

NDSL Canada, Non-Domestic Substances List

NIOSH National Institute for Occupational Safety & Health

CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZloC New Zealand Inventory of

Chemicals EC50 Effective Concentration NOAEL No Observable Adverse Effect

Level EC50 Effective Concentration 50% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure

Scenario Tool OSHA Occupational Safety & Health

Administration EOSCA European Oilfield Specialty

Chemicals Association PEL Permissible Exposure Limit

EINECS European Inventory of Existing Chemical Substances

PICCS Philippines Inventory of Commercial Chemical Substances

MAK Germany Maximum Concentration Values

PRNT Presumed Not Toxic

GHS Globally Harmonized System RCRA Resource Conservation Recovery Act

>= Greater Than or Equal To STEL Short-term Exposure Limit IC50 Inhibition Concentration 50% SARA Superfund Amendments and

Reauthorization Act. IARC International Agency for Research

on Cancer TLV Threshold Limit Value

IECSC Inventory of Existing Chemical Substances in China

TWA Time Weighted Average

ENCS Japan, Inventory of Existing and TSCA Toxic Substance Control Act

0

2

0

SAFETY DATA SHEET


SDS Number:100000014007 11/11

New Chemical Substances KECI Korea, Existing Chemical

Inventory UVCB Unknown or Variable Composition,

Complex Reaction Products, and Biological Materials

<= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System

LC50 Lethal Concentration 50%


1093242, 1016819 - MATERIAL NUMBERSynonyms

DEFOAMER ● DEFOAMING AGENTUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





DSCO DEFOAMProduct name








>60%25322-69-4 500-039-8POLYPROPYLENE GLYCOL





Eye



Skin






www.newpark.com

DSCO DEFOAMPRODUCT NAME






None allocated.

5.4 Hazchem code










Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should haveappropriate ventilation systems. Store as a Class C2 Combustible Liquid (AS1940).







Exposure standards








PPE



Body When using large quantities or where heavy contamination is likely, wear coveralls. In a laboratory situation,wear a laboratory coat.



9.1 Information on basic physical and chemical propertiesCLEAR TO LIGHT AMBER LIQUIDAppearanceSLIGHT ODOUROdourCLASS C2 COMBUSTIBLEFlammability185°CFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density1.00Specific gravitySLIGHTLY SOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising properties













This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsAcute toxicity





are not anticipated.



300 - 57000 mg/kg(range)

-- --POLYPROPYLENE GLYCOL











12.1 Toxicity









For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Forlarge quantities, contact the manufacturer/supplier for additional information.


Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number













Poison schedule

AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.NEW ZEALAND: NZIoC (New Zealand Inventory of Chemicals)All components are listed on the NZIoC inventory, or are exempt.

Inventory listings


Classifications






Abbreviations








Report status


Prepared by

[ End of SDS ]




POTASSIUM SILICATE POWDERSynonyms

DRILLING AIDUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





FLEXFIRM KAProduct name




Signal word WARNING

Harmful if swallowed.H302Causes skin irritation.H315Causes serious eye irritation.H319May cause respiratory irritation.H335May cause damage to organs through prolonged or repeated exposure.H373

Hazard statements

Pictograms

Physical Hazards


Health Hazards

Acute Toxicity: Oral: Category 4Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 2ASpecific Target Organ Toxicity (Single Exposure): Category 3 (Respiratory Irritation)Specific Target Organ Toxicity (Repeated Exposure): Category 2






www.newpark.com

FLEXFIRM KAPRODUCT NAME




Storage statements

IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.P301 + P312IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.

P305 + P351 + P338

Get medical advice/attention if you feel unwell.P314Specific treatment is advised - see first aid instructions.P321Rinse mouth.P330If skin or eye irritation occurs: Get medical advice/ attention.P332 + P337 + P313Take off contaminated clothing and wash before re-use.P362

Response statements

Do not breathe dust/fume/gas/mist/vapours/spray.P260Wash thoroughly after handling.P264Do not eat, drink or smoke when using this product.P270Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280




99%1312-76-1 215-199-1POTASSIUM SILICATE

0.1 to 1%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)





Eye



Skin


Ingestion












None allocated.

5.4 Hazchem code







Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.







Exposure standards









PPE






9.1 Information on basic physical and chemical propertiesWHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate11.3 (50 % solution) (Approximately)pHNOT AVAILABLEVapour densityNOT AVAILABLESpecific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold







Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).






Harmful if swallowed.Acute toxicity







1600 mg/kg (rat) -- --POTASSIUM SILICATE

Contact may result in irritation, redness, rash and dermatitis.Skin



Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result inbreathing difficulties.







Carcinogenicity



12.1 Toxicity

The high pH when undiluted or unneutralized is acutely harmful to aquatic life. The following data is reported for chemically similarSodium Silicates on a 100% solids basis: A 96 hour median tolerance for fish (Gambusia affnis) of 2320 ppm; a 96 hour mediantolerance for water fleas (Daphnia magna) of 247 ppm; a 96 hour median tolerance for snail eggs (Lymnea) of 632 ppm; and a 96 hourmedian tolerance for Amphipoda of 160 ppm.

12.2 Persistence and degradabilityThis material is not persistent in aquatic systems.


Expected to be mobile in soil. Diluted material rapidly depolymerizes to yield dissolved silica in a form that is indistinguishable fromnatural dissolved silica.



12.3 Bioaccumulative potentialNeither silica nor potassium will appreciably bio-concentrate up the food chain.


Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information (if required).


Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number












Poison schedule


Inventory listings


Classifications






Abbreviations








Report status


Prepared by

[ End of SDS ]




FRAC-ATTACKSynonyms

LOST CIRCULATION MATERIALUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





FRAC ATTACKProduct name




Signal word DANGER

Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280


Causes skin irritation.H315Causes serious eye damage.H318May cause respiratory irritation.H335

Hazard statements

Pictograms

Physical Hazards


Health Hazards

Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 1Specific Target Organ Toxicity (Single Exposure): Category 3 (Respiratory Irritation)






www.newpark.com

FRAC ATTACKPRODUCT NAME




Storage statements


P305 + P351 + P338

Immediately call a POISON CENTER or doctor/physician.P310Specific treatment is advised - see first aid instructions.P321If skin irritation occurs: Get medical advice/ attention.P332 + P313Take off contaminated clothing and wash before re-use.P362

Response statements



<30%9004-34-6 232-674-9CELLULOSE

<15%61790-53-2 612-383-7DIATOMACEOUS EARTH

<12%8031-18-3 617-052-0FULLERS EARTH

<10%1305-78-8 215-138-9CALCIUM OXIDE

<5%1305-62-0 215-137-3CALCIUM HYDROXIDE

<5%14464-46-1 238-455-4CRISTOBALITE


<2%1309-48-4 215-171-9MAGNESIUM OXIDE

<50%9003-55-8 618-370-21,3 BUTADIENE/STYRENE COPOLYMERS

<50%9003-18-3 618-357-12-PROPENENITRILE-1,3-BUTADIENE RUBBER

<50%9006-04-6 232-689-0NATURAL RUBBER

<50%9003-31-0 618-362-9POLYISOPRENE





Eye



Skin


Ingestion








Non flammable.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code















Exposure standards



Calcium hydroxide SWA [AUS] -- 5 -- --Calcium hydroxide SWA [Proposed] -- 1 -- --

Calcium oxide SWA [AUS] -- 2 -- --Calcium oxide SWA [Proposed] -- 1 -- --

Cellulose (paper fibre) (a) SWA [AUS] -- 10 -- --

Cristobalite SWA [AUS] -- 0.1 -- --

Diatomaceous earth (uncalcined) (a) SWA [AUS] -- 10 -- --

Magnesium oxide (fume) SWA [AUS] -- 10 -- --





Biological limits


PPE





Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposurestandard.



9.1 Information on basic physical and chemical propertiesBROWN/GREY POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT RELEVANTBoiling pointNOT AVAILABLEMelting pointNON VOLATILEEvaporation rateALKALINEpHNOT AVAILABLEVapour density2.10Specific gravityNEGLIGIBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

9.2 Other informationNOT RELEVANT% Volatiles














May evolve Fluorine, Oxygen Difluoride, Chlorine, Trifluoride and Hydrofluoric Acid when heated to decomposition.10.6 Hazardous decomposition products


Toxicity Data available for the ingredients:CALCIUM HYDROXIDE (1305-62-0): LD50 (ingestion): 7300 mg/kg (mouse)CRISTOBALITE (14464-46-1): TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis)QUARTZ (SILICA CRYSTALLINE) (14808-60-7): LCLo (inhalation): 300 ug/m³/10 years (human) TCLo (inhalation): 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis)CELLULOSE (9004-34-6): LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit)MAGNESIUM OXIDE (1309-48-4): TCLo (inhalation): 400 mg/kg (human)

Acute toxicity



> 5000 mg/kg (rat) > 2000 mg/kg (rabbit) > 5800 mg/m³/4 hours(rat)

CELLULOSE

> 5000 mg/kg (rat) > 5000 mg/kg (rabbit) --DIATOMACEOUS EARTH

7300 mg/kg (mouse) -- --CALCIUM HYDROXIDE

Irritating to the skin. Contact may result in irritation, redness, pain, rash, dermatitis and possible skin burns.Skin

Irritating to the eyes. Contact may result in irritation, lacrimation, pain, redness, conjunctivitis and possibleburns.

Eye


Irritating to the respiratory system. Over exposure may result in irritation of the nose and throat, withcoughing.


Not classified as causing aspiration. Not relevant.Aspiration

Not classified as causing organ damage from repeated exposure. Repeated exposure to crystalline silicamay cause lung fibrosis (silicosis), however due to the low levels of respirable crystalline silica in thisproduct, adverse health effects are not anticipated with normal use.




Carcinogenicity



CELLULOSE (9004-34-6)LD50 (intraperitoneal) > 31600 mg/kg (rat)

CRISTOBALITE (14464-46-1)TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis)



12.1 Toxicity

The manufacturer reports that this product is harmful to aquatic life.













Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number










Poison schedule


Inventory listings


Classifications










Abbreviations




Report status


Prepared by

[ End of SDS ]




FRACSEAL F ● FRACSEAL FINE ● FRACSEAL M ● FRACSEAL MEDIUMSynonyms

DRILLING FLUID ADDITIVEUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





FRACSEAL FINE/MEDIUMProduct name








100%9004-34-6 232-674-9CELLULOSE





Eye


Exposure is considered unlikely. Skin irritation is not anticipated.Skin


Ingestion


This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated.4.2 Most important symptoms and effects, both acute and delayed


Version No: 3.3ofPage 1 6

www.newpark.com

FRACSEAL FINE/MEDIUMPRODUCT NAME



Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may formexplosive mixtures with air.




None allocated.

5.4 Hazchem code








Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for damage tocontainers.







Exposure standards








PPE

Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles.




Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposurestandard.



9.1 Information on basic physical and chemical propertiesYELLOW TO BROWN SOLIDAppearanceODOURLESSOdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling point500°C to 518°CMelting pointNOT AVAILABLEEvaporation rate6.5 to 7.5pHNOT AVAILABLEVapour density0.9Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold







Incompatible with oxidising agents (e.g. hypochlorites).









This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated. Oral LD50 (rat) is > 5000 mg/kg.Dermal LD50 (rabbit) is > 2000 mg/kg.LC50 (rat) is 510 mg/m³/2 hours.

Acute toxicity




CELLULOSE

Not classified as a skin irritant.Skin

Not classified as an eye irritant. Contact may cause mild discomfort.Eye



Not relevant.Aspiration









12.1 Toxicity











Waste disposal








None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number









Poison schedule


Inventory listings


Classifications










Abbreviations




Report status


Prepared by

[ End of SDS ]



GageTrolÔ

EN

SAFETY DATA SHEET

Issue Date 15-Mar-2017 Revision Date 15-Mar-2017 Version 1


Product identifier

Product Name GageTrolÔ



Pure substance/mixture Substance


Recommended Use filtration control agent










Label elements


Other hazards

_____________________________________________________________________________________________

UGHS Page 1 / 8


_____________________________________________________________________________________________NDF00018 GageTrolÔ Revision Date 15-Mar-2017

General HazardsThis substance does not meet the PBT/vPvB criteria of REACH, annex XIII


Substance













Suitable extinguishing media Dry chemical, CO2, water spray or regular foam.











Non-hazardous ingredients Proprietary

_____________________________________________________________________________________________

UGHS Page 2 / 8

>99

















Incompatible materials Strong oxidizing agents Strong acids


Control parameters









_____________________________________________________________________________________________

UGHS Page 3 / 8





Other Information Softening point No information availableMolecular weight No information availableVOC Content (%) No information availableLiquid Density No information availableBulk density 30-45 lb/ft3 (480-720 kg/m3)Particle Size No information availableParticle Size Distribution No information available


Reactivity

Reactivity No information available.

Chemical stability





Conditions to avoid

Appearance Powder Odor Slight.Color Off-white Odor threshold No information available

Property Values Remarks • Method pH 9.0-10.5 4% solutionMelting point / freezing point Not applicableBoiling point / boiling range Not applicableFlash point Not applicableEvaporation rate No information availableFlammability (solid, gas) No information availableFlammability Limit in Air No information available


Vapor pressure No data availableVapor density No data availableRelative density 1.5Water solubility Soluble in waterSolubility(ies) No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity Not applicableDynamic viscosity Not applicable

_____________________________________________________________________________________________

UGHS Page 4 / 8




Incompatible materials Strong oxidizing agents. Strong acids.




Acute toxicity












Skin corrosion/irritation None known.

Serious eye damage/eye irritation None known.

Respiratory or skin sensitization None known.



Reproductive toxicity None known.

STOT - single exposure None known.


Aspiration hazard Not applicable.

_____________________________________________________________________________________________

UGHS Page 5 / 8



Ecotoxicity







Mobility











ADG Not Regulated

IATA Not Regulated

IMDG Not Regulated





_____________________________________________________________________________________________

UGHS Page 6 / 8

Australia


See section 8 for national exposure control parameters





The Montreal Protocol on Substances that Deplete the Ozone Layer Not applicable

The Stockholm Convention on Persistent Organic Pollutants Not applicable

The Rotterdam Convention Not applicable


Issue Date 15-Mar-2017





DisclaimerThis document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individuals


_____________________________________________________________________________________________

UGHS Page 7 / 8


or situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.


_____________________________________________________________________________________________

UGHS Page 8 / 8


IDCIDE 20Synonyms

BIOCIDE ● DRILLING FLUID ADDITIVE ● WATER TREATMENTUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





IDCIDE-20Product name




Signal word WARNING

Harmful if swallowed.H302Causes skin irritation.H315May cause an allergic skin reaction.H317Causes serious eye irritation.H319

Hazard statements

Pictograms

Physical Hazards


Health Hazards

Acute Toxicity: Oral: Category 4Skin Corrosion/Irritation: Category 2Skin Sensitisation: Category 1Serious Eye Damage / Eye Irritation: Category 2A




SDS Date: 16 Aug 2019


www.newpark.com

IDCIDE-20PRODUCT NAME




IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.P301 + P312IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.

P305 + P351 + P338

Specific treatment is advised - see first aid instructions.P321Rinse mouth.P330If skin irritation or rash occurs: Get medical advice/attention.P333 + P313Take off contaminated clothing and wash before re-use.P362

Response statements

Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Do not eat, drink or smoke when using this product.P270Contaminated work clothing should not be allowed out of the workplace.P272Wear protective gloves/protective clothing/eye protection/face protection.P280




18 to 25%55566-30-8 259-709-0TETRAKIS(HYDROXYMETHYL)PHOSPHONIUMSULPHATE(2:1)

Remainder7732-18-5 231-791-2WATER





Eye

If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator oran Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing.

Inhalation


Skin



See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed



Non flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition. May evolve carbon oxides, sulphuroxides and phosphates when heated to decomposition.








None allocated.

5.4 Hazchem code









Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should haveappropriate ventilation systems.







Exposure standards



PPE



Body Wear coveralls. In a laboratory situation, wear a laboratory coat.








9.1 Information on basic physical and chemical propertiesCOLOURLESS TO PALE YELLOW LIQUIDAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point> 100°CBoiling point< 0°CMelting pointAS FOR WATEREvaporation rate3.0 to 3.5pHNOT AVAILABLEVapour density1.08Specific gravitySOLUBLESolubility (water)18 mm Hg @ 20°CVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

9.2 Other information> 60 % (Water)% Volatiles
















248 mg/kg (rat) > 2000 mg/kg (rat) 5.5 mg/L/4hrs (rat)TETRAKIS(HYDROXYMETHYL)PHOSPHONIUMSULPHATE(2:1)

Contact may result in irritation, redness, pain and rash.Skin


TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE(2:1) (55566-30-8)TDLo (oral) 650 mg/kg/13 weeks - intermittent (rat)






May cause an allergic skin reaction. This product is not classified as a respiratory sensitiser.Sensitisation

Over exposure may result in respiratory irritation, nausea, dizziness, drowsiness and headache.STOT - singleexposure










12.1 Toxicity

75% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8):LC50 (Rainbow Trout) = 119 mg/L/96 hrLC50(Bluegill Sunfish) = 93 mg/L/ 96 hrEC50 (Daphnia Magna) = 19 mg/L/48 hrLC50 (Brown Shrimp) = 340 mg/L/96 hrLC50 (Mysid Shrimp ) = 9.5 mg/L/96 hrLC50 (Sheepshead Minnow) = 94 mg/L/96 hrLC50 (Jevenile Plaice) = 86 mg/L/96 hr

Waste Water managementEC50 (Activated Sludge) = 24 mg/L/3 hr








For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Forlarge quantities, contact the manufacturer/supplier for additional information. Prevent contamination of drainsand waterways as aquatic life may be threatened and environmental damage may result.


Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number










Poison schedule


Classifications





Inventory listings








Abbreviations




Report status






Prepared by

[ End of SDS ]




JK - 161 LV ● LOW MOLECULAR WEIGHT PHPA ● PARTIALLY HYDROLYZED POLYACRYLAMIDE ●PHPA

Synonyms

ENCAPSULATING AGENT ● HIGH PERFORMANCE WBMUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





JK-161 LVProduct name








>90%25085-02-3 607-529-1ACRYLAMIDE, SODIUM ACRYLATE COPOLYMER

Remainder7732-18-5 231-791-2WATER





Eye




Ingestion




www.newpark.com

JK-161 LVPRODUCT NAME




Non flammable. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code









Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled and tightly closed when not in use.







Exposure standards



Acrylamide SWA [AUS] -- 0.03 -- --





PPE








9.1 Information on basic physical and chemical propertiesWHITE GRANULAR SOLIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density0.8Specific gravity10 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold








May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.10.6 Hazardous decomposition products








This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated. LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 401).

Acute toxicity

Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis.Skin

Low to moderate irritant. Contact may result in mild irritation, lacrimation and redness.Eye

Not classified as causing skin or respiratory sensitisation. However, allergic reactions are possible.Sensitisation





This product may contain trace amounts of residual acrylamide, which is classified as a probable humancarcinogen (IARC Group 2A). However, due to the very low levels present, adverse health effects are notanticipated with normal use.

Carcinogenicity




12.1 Toxicity

(10000 ppm test concentration) (EPA-821-R-02-012) Mysidopsis bahia = 48hr LC50 = 16.2 mg/L. Menidia beryllina = 48hr LC50 = 34.2 mg/L. Scophthalmus Maximus = 96hr LC50 > 1000 mg/L. Skeletonemia costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L] Acartia tonsa = 48 hr EC50 = 393 mg/L [NOEC = 112 mg/L] Corophium Volutator = 10 Day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg

12.2 Persistence and degradabilityNot readily biodegradable (by OECD criteria).





12.3 Bioaccumulative potentialBased on its structural properties, the polymer is not biologically available. Accumulation in organisms is not to be expected.




Waste disposal








None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number









Poison schedule


Inventory listings


Classifications


ACRYLIC - ACRYLAMIDE RESINS: These resins are generally of low toxicity. Toxicity increases withpresence of significant concentrations of acrylic - acrylamide monomers. These monomers havebeen linked with the development of skin sensitisation.











Abbreviations




Report status


Prepared by

[ End of SDS ]




CALCINED MAGNESIA ● MAGNESIA ● MAGOXI16 / 27 - PRODUCT CODESynonyms

DRILLING FLUID ADDITIVE ● PH INDICATORUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





MAGNESIUM OXIDEProduct name








>94%1309-48-4 215-171-9MAGNESIUM OXIDE

<3.5%1305-78-8 215-138-9CALCIUM OXIDE

<2.5%7631-86-9 231-545-4SILICON DIOXIDE (SILICA, AMORPHOUS)





Eye



Skin


Ingestion




www.newpark.com

MAGNESIUM OXIDEPRODUCT NAME




Non flammable. May evolve magnesium oxides when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code








Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure product is adequatelylabelled, protected from physical damage and sealed when not in use.







Exposure standards



Calcium oxide SWA [AUS] -- 2 -- --Calcium oxide SWA [Proposed] -- 1 -- --

Fumed silica (respirable dust) SWA [AUS] -- 2 -- --






PPE



Body Not required under normal conditions of use.





9.1 Information on basic physical and chemical propertiesWHITE GRANULESAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point3600°CBoiling point2800°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density3.6 - 3.7Specific gravitySLIGHTLY SOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

9.2 Other information0 %% Volatiles













Incompatible (violently) with interhalogens (e.g. bromine pentafluoride, chlorine trifluoride) and phosphorus pentachloride. May igniteor explode when heated with aluminium powder. Also incompatible with acids (e.g. nitric acid) and dampness as material hydrates.

May evolve magnesium oxides when heated to decomposition.10.6 Hazardous decomposition products


Based on available data, the classification criteria are not met.Acute toxicity



3160 mg/kg (rat) -- --SILICON DIOXIDE (SILICA, AMORPHOUS)




Not classified as causing organ damage from single exposure. However, over exposure may result inirritation of the nose and throat, with coughing.









12.1 Toxicity


12.2 Persistence and degradabilityThe methods for determining the biological degradability are not applicable to inorganic substances.







For small amounts, cover with moist sand, vermiculite or similar to avoid dust hazard and dispose of to anapproved landfill site. Contact the manufacturer/supplier for additional information if disposing of largequantities (if required).


Waste disposal








None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number









Poison schedule


Inventory listings


Classifications


EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established onthe premise of an 8 hour work period of normal intensity, under normal climatic conditions and wherea 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In thefollowing circumstances, exposure standards must be reduced: Strenuous work conditions; hot,humid climates; high altitude conditions; extended shifts (which increase the exposure period andshorten the period of recuperation).











Abbreviations




Report status


Prepared by

[ End of SDS ]



Monoethylene Glycol (MEG)

SAFETY DATA SHEET

NDF00270 Revision Date 01-Mar-2019 Version 1.1

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THECOMPANY/UNDERTAKING

1.1. Product identifier

Product Code NDF00270Product Name Monoethylene Glycol (MEG)

Contains Ethylene glycol

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended Use hydrate-control additive


1.3. Details of the supplier of the safety data sheet



1.4. Emergency telephone number


Section 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008Acute toxicity - Oral Category 4 - (H302)Specific target organ toxicity (repeated exposure) Category 2 - (H373)

Classification according to Directive 67/548/EEC or 1999/45/ECFull text of R-phrases: see section 16

Hazard symbolsXn - Harmful

R-code(s)Xn;R22

2.2. Label elements Product identifier203-473-3Contains Ethylene glycol

Supplier Newpark Drilling Fluids (Australia) LTD11 Alacrity PlaceHenderson, WA, 6166Australia

_____________________________________________________________________________________________

Page 1 / 9

_____________________________________________________________________________________________NDF00270 Monoethylene Glycol (MEG) Revision Date 01-Mar-2019

Signal wordWarning

Hazard statementsH302 - Harmful if swallowedH373 - May cause damage to organs through prolonged or repeated exposure

Precautionary Statements - EU (§28, 1272/2008)P260 - Do not breathe dust/fume/gas/mist/vapors/sprayP314 - Get medical advice/attention if you feel unwellP501 - Dispose of contents/container to industrial incineration plant

2.3. Other hazards Harmful to aquatic life

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances

Chemical Name CAS No Weight-% Classification according toDirective 67/548/EEC or

1999/45/EC

Classificationaccording to

Regulation (EC) No.1272/2008 [CLP]

Ethylene glycol 107-21-1 100 Xn; R22 Acute Tox. 4 (H302)STOT RE 2 (H373)

Full text of R-phrases: see section 16

Full text of H- and EUH-phrases: see section 16


4.1. Description of first aid measures

General advice If symptoms persist, call a physician. Do not breathe dust/fume/gas/mist/vapors/spray. Donot get in eyes, on skin, or on clothing.

Inhalation Remove to fresh air. Call a physician. If breathing is irregular or stopped, administerartificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouthresuscitation.

Skin contact Wash skin with soap and water. Remove contaminated clothing and shoes. Washcontaminated clothing before reuse. Get medical attention if irritation develops and persists.

Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses andcontinue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptomspersist, call a physician.

Ingestion Rinse mouth. Drink plenty of water. If symptoms persist, call a physician. Do NOT inducevomiting.

Self-protection of the first aider Use personal protective equipment as required.

_____________________________________________________________________________________________

Page 2 / 9


4.2. Most important symptoms and effects, both acute and delayed


4.3. Indication of any immediate medical attention and special treatment needed


Section 5: FIRE FIGHTING MEASURES5.1. Extinguishing media

Suitable extinguishing mediaDry chemical, CO2, alcohol-resistant foam or water spray.

Unsuitable extinguishing mediaNo information available

5.2. Special hazards arising from the substance or mixture

Thermal decomposition can lead to release of irritating and toxic gases and vapors

Hazardous combustion productsCarbon oxides.

5.3. Advice for firefighters

Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.


6.1. Personal precautions, protective equipment and emergency procedures

Personal precautionsEnsure adequate ventilation, especially in confined areas. Keep people away from and upwind of spill/leak.

For emergency respondersIn the case of vapor formation use a respirator with an approved filter.

6.2. Environmental precautions

Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. SeeSection 12 for additional Ecological Information.

6.3. Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so. Dike to collect large liquid spills.

Methods for cleaning up Use personal protective equipment as required. Use a non-combustible material likevermiculite or sand to soak up the product and place into a container for later disposal. Useclean non-sparking tools to collect absorbed material.

6.4. Reference to other sections

See section 13 for more information.

Section 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

_____________________________________________________________________________________________

Page 3 / 9

Advice on safe handlingWash contaminated clothing before reuse. Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly


after handling.

General Hygiene ConsiderationsHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Storage ConditionsKeep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children.

7.3. Specific end use(s)

Risk Management Methods (RMM)The information required is contained in this Material Safety Data Sheet.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Chemical Name Australia EuropeanUnion

UnitedKingdom

France Spain Germany

Ethylene glycol 107-21-1

10 mg/m3

20 ppm52 mg/m3

40 ppm STEL104 mg/m3

STEL

TWA 20 ppmTWA 52 mg/m3

STEL 40 ppmSTEL 104

mg/m3

*

TWA: 10 mg/m3

TWA: 20 ppmTWA: 52 mg/m3

STEL: 40 ppmSTEL: 104

mg/m3

STEL: 30 mg/m3

Sk*



mg/m3

*



mg/m3

vía dérmica*


Ceiling / Peak:20 ppm

Ceiling / Peak:52 mg/m3

Skin

Chemical Name Italy Portugal Netherlands Finland DenmarkEthylene glycol

107-21-1TWA: 20 ppm

TWA: 52 mg/m3

STEL: 40 ppmSTEL: 104 mg/m3

pelle*



Ceiling: 100 mg/m3

P*

TWA: 52 mg/m3

TWA: 10 mg/m3

STEL: 104 mg/m3

H*



iho*


TWA: 10 mg/m3

H*

Chemical Name Austria Switzerland Poland Norway IrelandEthylene glycol

107-21-1TWA: 10 ppm

TWA: 26 mg/m3

STEL 20 ppmSTEL 52 mg/m3

H*



H*

STEL: 50 mg/m3

TWA: 15 mg/m3TWA: 20 ppm

TWA: 52 mg/m3

STEL: 104 mg/m3

STEL: 40 ppmH*

TWA: 10 mg/m3



STEL: 104 mg/m3

Sk*

Derived No Effect Level (DNEL) No information available

Predicted No Effect Concentration(PNEC)

No information available.

8.2. Exposure controls

Engineering Controls Ensure adequate ventilation, especially in confined areas.

_____________________________________________________________________________________________

Page 4 / 9




Skin and body protection Suitable protective clothing.



9.1. Information on basic physical and chemical properties Physical state Liquid

Explosive properties Not an explosiveOxidizing properties Not applicable

9.2. Other information Softening point Not applicableMolecular weight No data availableVOC Content (%) Not applicableDensity No data availableBulk density Not applicable


10.1. Reactivity

10.2. Chemical stability

Stable under normal conditions.

Explosion data Sensitivity to Mechanical Impact None.Sensitivity to Static Discharge None.

Appearance liquid Odor No information availableColor colorless Odor threshold No data available

Property Values Remarks • Method pH No data availableMelting point / freezing point -13 °C / 9 °FBoiling point / boiling range 196 °C / 385 °FFlash point 111 °C / 232 °FEvaporation rate 1Flammability (solid, gas) No data availableFlammability Limit in Air


Vapor pressure No data availableVapor density No data availableSpecific Gravity 1.11Water solubility Miscible in waterSolubility(ies) No information availablePartition coefficient No data availableAutoignition temperature 400 °C / 752 °FDecomposition temperature No data availableKinematic viscosity No data availableDynamic viscosity No data available

No data available.

_____________________________________________________________________________________________

Page 5 / 9


10.3. Possibility of hazardous reactions

Possibility of Hazardous ReactionsNone under normal processing.

10.4. Conditions to avoid

Extremes of temperature and direct sunlight. Incompatible materials.

10.5. Incompatible materials

Strong oxidizing agents. Strong acids. Strong bases. Aldehydes. Aluminum.

10.6. Hazardous decomposition products

None under normal use conditions.


11.1. Information on toxicological effects

Acute toxicity

Product InformationProduct does not present an acute toxicity hazard based on known or supplied information.

National Regulations No data available.Eye contact No data available.Skin contact No data available.Ingestion No data available.

Unknown acute toxicity 0 % of the mixture consists of ingredient(s) of unknown toxicity.

The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 500.00 mg/kg

Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50Ethylene glycol = 4700 mg/kg ( Rat ) = 10600 mg/kg ( Rat ) = 9530 µL/kg

( Rabbit )



Sensitization None known.





STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure if swallowed.

Target Organ Effects kidney.


_____________________________________________________________________________________________

Page 6 / 9



12.1. Toxicity

0 % of the mixture consists of component(s) of unknown hazards to the aquatic environmentChemical Name Algae/aquatic plants Fish CrustaceaEthylene glycol 6500 - 13000: 96 h

Pseudokirchneriella subcapitatamg/L EC50

14 - 18: 96 h Oncorhynchus mykissmL/L LC50 static 40000 - 60000: 96h Pimephales promelas mg/L LC50static 16000: 96 h Poecilia reticulata

mg/L LC50 static 27540: 96 hLepomis macrochirus mg/L LC50static 40761: 96 h Oncorhynchus

mykiss mg/L LC50 static 41000: 96h Oncorhynchus mykiss mg/L LC50

46300: 48 h Daphnia magna mg/LEC50

12.2. Persistence and degradability


12.3. Bioaccumulative potential

.

Chemical Name Partition coefficientEthylene glycol -1.93

12.4. Mobility in soil

Mobility in soilNo information available.

12.5. Results of PBT and vPvB assessment


12.6. Other adverse effects



13.1. Waste treatment methods


Disposal should be in accordance with applicable regional, national and local laws andregulations.

Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal.

Other Information Waste codes should be assigned by the user based on the application for which the productwas used.


IMDG 14.1 UN/ID no Not regulated14.2 Proper shipping name Not regulated_____________________________________________________________________________________________

Page 7 / 9


14.3 Hazard Class Not regulated14.4 Packing Group Not regulated14.5 Marine pollutant Not applicable14.6 Special Provisions None14.7 Transport in bulk according toAnnex II of MARPOL 73/78 and theIBC Code


RID 14.1 UN/ID no Not regulated14.2 Proper shipping name Not regulated14.3 Hazard Class Not regulated14.4 Packing Group Not regulated14.5 Environmental hazard Not applicable14.6 Special Provisions None

ADR 14.1 UN/ID no Not regulated14.2 Proper shipping name Not regulated14.3 Hazard Class Not regulated14.4 Packing Group Not regulated14.5 Environmental hazard Not applicable14.6 Special Provisions None

ICAO (air) 14.1 UN/ID no Not regulated14.2 Proper shipping name Not regulated14.3 Hazard Class Not regulated14.4 Packing Group Not regulated14.5 Environmental hazard Not applicable14.6 Special Provisions None

IATA 14.1 UN/ID no Not regulated14.2 Proper shipping name Not regulated14.3 Hazard Class Not regulated14.4 Packing Group Not regulated14.5 Environmental hazard Not applicable14.6 Special Provisions None

HAZCHEM Emergency Action CodeNo information available


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture


AustraliaSee section 8 for national exposure control parameters

Carcinogenicity

International Inventories TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS Complies

_____________________________________________________________________________________________

Page 8 / 9


ENCS CompliesIECSC CompliesKECL CompliesPICCS CompliesAICS CompliesNZIoC Complies


15.2. Chemical safety assessment


Section 16: OTHER INFORMATION

Full text of R-phrases referred to under sections 2 and 3R22 - Harmful if swallowed

Full text of H-Statements referred to under section 3H302 - Harmful if swallowedH373 - May cause damage to organs through prolonged or repeated exposure if inhaled

Issue Date 18-May-2017


This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

DisclaimerAccording to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 onclassification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and1999/45/EC, and amending Regulation (EC) No 1907/2006, as amended by Regulation (EU) No. 2015/830.This document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.


_____________________________________________________________________________________________

Page 9 / 9


MICRO FLOWSynonyms





+61 8 9410 8200Telephone

+61 8 9410 8299Fax





MICROFLOWProduct name




Signal word WARNING

Flammable liquid and vapour.H226May cause an allergic skin reaction.H317Causes serious eye irritation.H319May cause drowsiness or dizziness.H336

Hazard statements

Pictograms

Physical Hazards

Flammable Liquids: Category 3

Health Hazards

Skin Sensitisation: Category 1BSerious Eye Damage / Eye Irritation: Category 2ASpecific Target Organ Toxicity (Single Exposure): Category 3 (Narcotic Effects)




SDS Date: 29 Jan 2020


www.newpark.com

MICROFLOWPRODUCT NAME



Store in a well-ventilated place. Keep cool. Keep container tightly closed.P403 + P233 + P235Store locked up.P405

Storage statements

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.P303 + P361 + P353IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.

P305 + P351 + P338

Call a POISON CENTER or doctor/physician if you feel unwell.P312Specific treatment is advised - see first aid instructions.P321If skin irritation or rash occurs: Get medical advice/attention.P333 + P313If eye irritation persists: Get medical advice/attention.P337 + P313Wash contaminated clothing before reuse.P363In case of fire: Use appropriate media for extinction.P370 + P378

Response statements

Keep away from heat/sparks/open flames/hot surfaces. No smoking.P210Keep container tightly closed.P233Ground/bond container and receiving equipment.P240Use explosion-proof electrical/ventilating/lighting equipment.P241Take precautionary measures against static discharge.P243Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Use only outdoors or in a well-ventilated area.P271Contaminated work clothing should not be allowed out of the workplace.P272Wear protective gloves/protective clothing/eye protection/face protection.P280




20 to 60%68647-72-3 614-678-6SWEET ORANGE OIL

15 to 50%67-63-0 200-661-7ISOPROPYL ALCOHOL

Terpenes (Sweet Orange Oil) may appear as CAS# 94266-47-4.Ingredient Notes





Eye



Skin


Ingestion


Irritating to the eyes. Vapours may cause drowsiness and dizziness.4.2 Most important symptoms and effects, both acute and delayed






Flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition. Eliminate all ignition sources includingcigarettes, open flames, spark producing switches/tools, heaters, naked lights, pilot lights, mobile phones, etc when handling. Earthcontainers when dispensing fluids.




●3Y●3 Alcohol Resistant Foam is the preferred firefighting medium but, if it is not available, normal foam can be used.Y Risk of violent reaction or explosion. Wear full fire kit and breathing apparatus. Contain spill and run-off.

5.4 Hazchem code










Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should bebunded and have appropriate ventilation systems.







Exposure standards



Isopropyl alcohol SWA [AUS] 400 983 500 1230

Biological limits

Ingredient Determinant BEISampling Time

40 mg/LEnd of shift atend of workweek

Acetone in urineISOPROPYL ALCOHOL

Reference: ACGIH Biological Exposure Indices




PPE


Hands Wear nitrile or neoprene gloves.


Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-ClassP1 (Organic gases/vapours and Particulate) respirator.

Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proofextraction ventilation is recommended. Flammable/explosive vapours may accumulate in poorly ventilatedareas. Vapours are heavier than air and may travel some distance to an ignition source and flash back.Maintain vapour levels below the recommended exposure standard.



9.1 Information on basic physical and chemical propertiesCLEAR TO OPAQUE MILKY WHITE LIQUIDAppearanceCITRUS ODOUROdourFLAMMABLEFlammability25°CFlash point154.4°CBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density0.917 - 0.977Specific gravitySOLUBLESolubility (water)18 mm Hg @ 20°CVapour pressure6.1 %Upper explosion limit0.7 %Lower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

9.2 Other information55 - 75 %% Volatiles







Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), metals, heat and ignition sources.








May be harmful if swallowed. Oral Toxicity: An oral LD50 in mice of 3600 mg/kg has been reported forisopropanol.

Acute toxicity



> 2000 mg/kg (rat)(NICNAS)


> 20 mg/L (rat)(NICNAS)

ISOPROPYL ALCOHOL

Not classified as a skin irritant. Prolonged or repeated contact may result in irritation, rash and dermatitis.Skin

Causes serious eye irritation. Contact may result in irritation, lacrimation, pain and redness.Eye

May cause an allergic skin reaction. This product is not classified as a respiratory sensitiser.Sensitisation

Over exposure may result in irritation of the nose and throat, coughing and headache. High level exposuremay result in nausea, dizziness and drowsiness.



Not classified as causing organ damage from repeated exposure. However, repeated exposure to somesolvents have been reported to cause adverse effects to the central nervous system (CNS), liver and kidney.


Not classified as a reproductive toxin. Insufficient data available to classify as a reproductive toxin.Reproductive

Isopropyl alcohol is not classifiable as to its carcinogenicity to humans (IARC Group 3).Carcinogenicity




12.1 Toxicity

Not expected to be dangerous to the aquatic environment.



Relatively volatile and would therefore readily evaporate from dry soil and surfaces.



12.3 Bioaccumulative potentialThis product is not expected to bioaccumulate.


For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information if disposing of large quantities (if required).Prevent contamination of drains and waterways as aquatic life may be threatened and environmentaldamage may result.


Waste disposal








III

3 3

III III


14.4 Packing Group

FLAMMABLE LIQUID, N.O.S.(Contains isopropyl alcohol)

1993


1993 1993


14.1 UN Number


Not a Marine Pollutant


●3YHazchem code

F-E, S̲-̲E̲EmS

3A1GTEPG





Poison schedule


Inventory listings


Classifications










Abbreviations




Report status


Prepared by

[ End of SDS ]




NDFT 376 ● NDFT 377Synonyms

LOST CIRCULATION MATERIALUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





DYNAFIBER (TM) AP (F, M, C)Product name








100%9004-34-6 232-674-9ORGANIC FIBRE(S)





Eye



Skin


Ingestion





www.newpark.com

DYNAFIBER (TM) AP (F, M, C)PRODUCT NAME






None allocated.

5.4 Hazchem code









Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Large storage areas should have appropriate ventilation systems.







Exposure standards








PPE





Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proofextraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.



9.1 Information on basic physical and chemical propertiesYELLOW TO BROWN SOLIDAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate7 to 8pHNOT AVAILABLEVapour density0.9 to 1.2Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

















Acute toxicity




ORGANIC FIBRE(S)

Not classified as a skin irritant. Skin irritation is not anticipated under normal conditions of use.Skin

Not classified as an eye irritant. Eye irritation is not anticipated under normal conditions of use.Eye










12.1 Toxicity









Reuse or recycle where possible. Alternatively, ensure product is covered with moist soil to prevent dustgeneration and dispose of to an approved landfill site. Contact the manufacturer/supplier for additionalinformation (if required).


Waste disposal








None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number









Poison schedule


Inventory listings


Classifications


EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established onthe premise of an 8 hour work period of normal intensity, under normal climatic conditions and wherea 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In thefollowing circumstances, exposure standards must be reduced: Strenuous work conditions; hot,humid climates; high altitude conditions; extended shifts (which increase the exposure period andshorten the period of recuperation).

COMBUSTIBLE - EXPLOSIVE CARBONACEOUS DUST: Carbonaceous/organic dusts have thepotential, with dispersion, to present an explosion hazard if an ignition source exists. All equipmentused to handle, transfer or store this product MUST BE cleaned thoroughly prior to cutting, welding,drilling or exposure to any other form of heat or ignition sources. If bulk stored, containers should beventilated on a routine basis to avoid vapour accumulation (where applicable, eg for flocculants).










Abbreviations




Report status


Prepared by

[ End of SDS ]



NewPacÔÔÔÔÔ LV

SAFETY DATA SHEET

Issue Date 02-Aug-2017 Revision Date 25-Nov-2020 Version 1.1

1. Identification 1

1.1. Product identifier


Product Name NewPacÔ LV

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended Use filtration control agent


1.3. Details of the supplier of the safety data sheet

For further information, please contact Contact Point Telephone: + 39 06 8856111

Fax: +39 06 8889363 Website: www.newpark.com

E-mail address [email protected] 1.4. Emergency telephone number

Emergency Telephone - §45 - (EC)1272/2008 Europe 112 Austria +(43)-13649237 France +(33)-975181407 Germany 0800-181-7059; +(49)- 69643508409 Hungary +(36)-18088425 Italy 800-789-767; +(39)-0245557031

Milano 24/24 Ospedale Niguarda Ca'grande Piazza ospedale maggiore 3 +39 0266101029

Roma 24/24 Policlinico Gemelli Largo Agostino Gemelli 8 +39 063054343

Netherlands +(31)-858880596 Romania (+40)-37-6300026 Spain 900-868538; +(34)-931768545 Switzerland 145; (+41) 435082011 United Kingdom +(44)-870-8200418

SupplierNewpark Drilling Fluids Via Salaria 1313/C 00138 ROMA (Italy)

_____________________________________________________________________________________________

Page 1 / 10

_____________________________________________________________________________________________ NDF00012 - NewPacÔÔÔÔÔ LV Revision Date 25-Nov-2020

2. Hazard(s) identification

2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [CLP]

2.2. Label elements This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [CLP] Hazard statements This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [CLP]

2.3. Other hazards This substance does not meet the PBT/vPvB criteria of REACH, annex XIIIMay form combustible dust concentrations in air

3. Composition/information on ingredients

3.1 Substances

Not applicable

3.2 Mixtures

The product contains no substances which at their given concentration, are considered to be hazardous to health

Full text of H- and EUH-phrases: see section 16

4. First-aid measures

4.1. Description of first aid measures


Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.

Skin contact Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician.




4.3. Indication of any immediate medical attention and special treatment needed


5. Fire-fighting measures 5.1. Extinguishing media

_____________________________________________________________________________________________

Page 2 / 10


Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.

Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.



Avoid generation of dust. Fine dust dispersed in air may ignite.

Hazardous combustion products Carbon oxides. Sodium oxides.

5.3. Advice for firefighters


Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.

6. Accidental release measures




6.2. Environmental precautions

Environmental precautions See Section 12 for additional Ecological Information.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.


6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

7. Handling and storage


Advice on safe handling Ensure adequate ventilation. Avoid generation of dust. Fine dust dispersed in air, in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep container tightly closed in a dry and well-ventilated place.

7.3. Specific end use(s)

_____________________________________________________________________________________________

Page 3 / 10

Identified Uses


Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

8. Exposure controls/personal protection

8.1. Control parameters

Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.

Derived No Effect Level (DNEL) No information available.

Predicted No Effect Concentration (PNEC)


8.2. Exposure controls


Eye/face protection Wear safety glasses with side shields (or goggles). Use eye protection according to EN 166, designed to protect against spray mists.

Skin and body protection Wear suitable protective clothing. (EN 340).

Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. (EN 136, EN 140, EN 141, EN 143, EN 149, EN 405).

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls No information available.

9. Physical and chemical properties

9.1. Information on basic physical and chemical properties Physical state Solid Appearance Powder Color White to Pale yellow Odor Odorless. Odor threshold No information available

Property Values Remarks • Method pH 6.0 - 8.5 0.5% solution Melting point / freezing point No data available Boiling point / boiling range No data available Flash point No data available Evaporation rate No data available Flammability (solid, gas) No data available Flammability Limit in Air No data available

Upper flammability limit: Lower flammability limit:

Vapor pressure No data available Vapor density No data available Relative density 1.6 _____________________________________________________________________________________________

Page 4 / 10


Explosive properties Fine dust dispersed in air, in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard

Oxidizing properties Not applicable

9.2. Other information Softening point No information available Molecular weight No information available VOC Content (%) No information available Liquid Density No information available Bulk density No information available

10. Stability and reactivity

10.1. Reactivity

Reactivity Not reactive under normal conditions.

10.2. Chemical stability


Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions


10.4. Conditions to avoid

Conditions to avoid dust formation.

10.5. Incompatible materials

Incompatible materials Strong oxidizing agents.

10.6. Hazardous decomposition products


11. Toxicological information

11.1. Information on toxicological effects





Water solubility Soluble in water Solubility(ies) No data available Partition coefficient No data available Autoignition temperature No data available Decomposition temperature No data available Kinematic viscosity Not applicable Dynamic viscosity

_____________________________________________________________________________________________

Page 5 / 10

Not applicable



Ingestion Specific test data for the substance or mixture is not available.

Information on toxicological effects


Numerical measures of toxicity

Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 13,636.40 mg/kg

Unknown acute toxicity 90.6 % of the mixture consists of ingredient(s) of unknown toxicity. 0.6 % of the mixture consists of ingredient(s) of unknown acute oral toxicity. 90.6 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity. 90.6 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas). 90.6 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor). 90.6 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist).











12. Ecological information

12.1. Toxicity

Ecotoxicity

Unknown Aquatic Toxicity Contains 0.6 % of components with unknown hazards to the aquatic environment.




_____________________________________________________________________________________________

Page 6 / 10





12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment The product does not contain any substance(s) classified as PBT or vPvB.



13. Disposal considerations

13.1. Waste treatment methods

Waste from residues/unused products

Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.


Waste codes / waste designations according to EWC / AVV

Waste codes should be assigned by the user based on the application for which the product was used.

14. Transport information

IMDG 14.1 UN/ID no Not Regulated 14.2 Proper shipping name Not Regulated 14.3 Hazard Class Not Regulated 14.4 Packing Group Not Regulated 14.5 Marine pollutant Not applicable 14.6 Special Provisions None 14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code


RID 14.1 UN/ID no Not Regulated 14.2 Proper shipping name Not Regulated 14.3 Hazard Class Not Regulated 14.4 Packing Group Not Regulated 14.5 Environmental hazard Not applicable 14.6 Special Provisions None

ADR 14.1 UN/ID no Not Regulated 14.2 Proper shipping name Not Regulated 14.3 Hazard Class Not Regulated 14.4 Packing Group Not Regulated 14.5 Environmental hazard Not applicable 14.6 Special Provisions None

IATA Not Regulated

_____________________________________________________________________________________________

Page 7 / 10


14.1 UN/ID no Not Regulated 14.2 Proper shipping name Not Regulated 14.3 Hazard Class Not Regulated 14.4 Packing Group Not Regulated 14.5 Environmental hazard Not applicable 14.6 Special Provisions None

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture


Germany Water hazard class (WGK) slightly hazardous to water (WGK 1)

Italy -D. LGs. 81/2008 (single text on the protection of health and safety in the workplace) and subsequent amendments and Directive 2009/161/EU-assessment of chemical risk under title IX-Legislative Decree 3 April 2006, no 152 (environmental standards)-"Seveso III Directive" – Legislative Decree of 26 June 2015, n° 105 (Implementation of the Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances)

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work

Authorizations and/or restrictions on use:This product does not contain substances subject to authorization (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)

Persistent Organic PollutantsNot applicable

Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable

International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies NZIoC Complies

Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances

_____________________________________________________________________________________________

Page 8 / 10


KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals

15.2. Chemical safety assessment

Chemical Safety Report None

16. Other information


Legend SVHC: Substances of Very High Concern for Authorization:


Classification procedure Classification according to Regulation (EC) No. 1272/2008 [CLP] Method Used Acute oral toxicity Calculation method Acute dermal toxicity Calculation method Acute inhalation toxicity - gas Calculation method Acute inhalation toxicity - vapor Calculation method Acute inhalation toxicity - dust/mist Calculation method Skin corrosion/irritation Calculation method Serious eye damage/eye irritation Calculation method Respiratory sensitization Calculation method Skin sensitization Calculation method Mutagenicity Calculation method Carcinogenicity Calculation method Reproductive toxicity Calculation method STOT - single exposure Calculation method STOT - repeated exposure Calculation method Acute aquatic toxicity Calculation method Chronic aquatic toxicity Calculation method Aspiration hazard Calculation method Health hazards not otherwise classified (HHNOC) Calculation method

Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID)

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value *

_____________________________________________________________________________________________

Page 9 / 10

Skin designation


Organization for Economic Co-operation and Development Environment, Health, and Safety Publications Organization for Economic Co-operation and Development High Production Volume Chemicals Program Organization for Economic Co-operation and Development Screening Information Data Set RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization

Issue Date 02-Aug-2017

Revision Date 25-Nov-2020

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

DisclaimerAccording to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006, as amended by Regulation (EU) No. 2015/830.This document is provided as an information resource relating exclusively to the product or material described herein. The information contained herein may not be applicable to other products/ materials or processes and may not be valid when this product/material is used in combination with any other product/material or process. The information provided in this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources including manufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated date of preparation. As the conditions under which this product could be used will vary and may not be within the control of Newpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individuals or situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state, provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.


_____________________________________________________________________________________________

Page 10 / 10


NEWZAN D ● XANTHAN GUM (BIOPOLYMER) ● XANTHAN GUM (P)Synonyms

DRILLING FLUID ADDITIVE ● VISCOSITY MODIFIERUses1.2 Uses and uses advised against


NEWPARK DRILLING FLUIDS (NEW ZEALAND) LTDSupplier name

PO BOX 6092, Moturoa, New Plymouth, TARANAKI, 4310, NEW ZEALANDAddress

0204 0234 734Telephone

+61 8941 08299Fax

0800 243 622 (New Zealand); +64 4 917 9888 (International)Emergency




NEWZAN DProduct name


NON HAZARDOUS ACCORDING TO NZ ENVIRONMENTAL PROTECTION AUTHORITY CRITERIA






>90%11138-66-2 234-394-2XANTHAN GUM





Eye



Skin

For advice, contact the National Poisons Centre on 0800 764 766 (0800 POISON) or +643 479 7248 or adoctor (at once). If swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form.

Ingestion





www.newpark.com

NEWZAN DPRODUCT NAME



Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may formexplosive mixtures with air.




None allocated.

5.4 Hazchem code
















Exposure standards







PPE




Respiratory Wear a Class P1 (Particulate) respirator. Where an inhalation risk exists, wear a Class P1 (Particulate)respirator.


9.1 Information on basic physical and chemical propertiesLIGHT BEIGE POWDERAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density1.5Specific gravityMISCIBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold








May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition.10.6 Hazardous decomposition products










Acute toxicity

Not classified as a skin irritant. Contact may result in mild irritation.Skin










12.1 Toxicity











Waste disposal



LAND TRANSPORT (NZS 5433) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)

None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number


No information provided.14.5 Environmental hazards



NOT CLASSIFIED AS A DANGEROUS GOOD ACCORDING TO LAND TRANSPORT RULE: DANGEROUS GOODS 2005; NZS5433:2012, UN, IMDG OR IATA





NEW ZEALAND: NZIoC (New Zealand Inventory of Chemicals)All components are listed on the NZIoC inventory, or are exempt.

Inventory listings


Approval code NON HAZARDOUS

NON HAZARDOUSGroup standard





ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCCID Chemical Classification and Information Database (HSNO)CNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous

Goods)EPA Environmental Protection Authority [New Zealand]GHS Globally Harmonized SystemHSNO Hazardous Substances and New OrganismsIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly

alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)TLV Threshold Limit ValueTWA Time Weighted Average

Abbreviations








Report status


Prepared by

[ End of SDS ]




KCL ● MURIATE OF POTASH ● POTASH ● SYLVITESynonyms

DRILLING FLUID ADDITIVE ● FERTILISER ● INHIBITORUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





POTASSIUM CHLORIDEProduct name








>97%7447-40-7 231-211-8POTASSIUM CHLORIDE





Eye



Skin


Ingestion





www.newpark.com

POTASSIUM CHLORIDEPRODUCT NAME



Non flammable. May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code















Exposure standards








PPE

Eye / Face At high dust levels, wear dust-proof goggles.

Hands With prolonged use, wear PVC or rubber or cotton gloves.

Body With prolonged use, wear coveralls.

Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.


9.1 Information on basic physical and chemical propertiesWHITE SOLIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point1413°CBoiling point773°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density2.0Specific gravity340 g/L @ 20°CSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold







Potassium chloride is not in general strongly reactive. Violent reaction with BrF3 and with a mixture of sulfuric acid potassiumpermanganate mixture (NTP, 1992). Reacts with concentrated sulfuric acid to generate fumes of hydrogen chloride. Incompatible withoxidising agents.

May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.10.6 Hazardous decomposition products

Polymerization will not occur.




May be harmful if swallowed in large quantities. Additional toxicity data for potassium chloride:LD50 (Intraperitoneal): 620 mg/kg (mouse)LD50 (Intravenous): 117 mg/kg (mouse)LDLo (Ingestion): 20 mg/kg (man)LDLo (Intraperitoneal): 900 mg/kg (guinea pig)LDLo (Intravenous): 77 mg/kg (guinea pig)

Acute toxicity





LDLo (Subcutaneous): 2120 mg/kg (frog)TDLo (Ingestion): 60 mg/kg/days (woman)



2600 mg/kg (rat) -- --POTASSIUM CHLORIDE

Not classified as a skin irritant. Contact may result in mild irritation and rash.Skin

Contact may cause discomfort, lacrimation and redness.Eye


Acute potassium poisoning via ingestion is rare as a large single dose usually induces vomiting, andpotassium is rapidly excreted by the body, however this product does have the potential to causecardiovascular disorders.








12.1 Toxicity

In short-term acute toxicity tests with fish, daphnia and algae the following results were found (lowest test result values): Ictaluruspunctulus 48h-LC50 = 720 mg/l; Daphnia magna: 48h-LC50 = 177 mg/l; Nitzschia linearis: 120 h-EC50 = 1337 mg/l. A chronicreproductive test with the invertebrate Daphnia magna gave a LOEC of 101 mg/l. All the studies compiled on the acute and chronicaquatic toxicity were > 100 mg/L. Thus it is concluded that KCl is not hazardous to freshwater organisms. Taking into considerationsthe background concentrations of KCl in seawater (380 mg/l K+ and 19,000 mg/l Cl-), it is concluded that there is no reason for furtherinvestigations of KCl on marine species. The low concern for the environment is supported by the absence of a bioaccumulationpotential for the substance.



No impact if small amount is released to the soil.



12.3 Bioaccumulative potentialDoes not bioaccumulate.


Collect and place in sealable containers and dispose of to an approved landfill site. Contact themanufacturer/supplier for additional information (if required).


Waste disposal








None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number









Poison schedule


Inventory listings


Classifications












Abbreviations




Report status


Prepared by

[ End of SDS ]




QUICKSEALSynonyms





+61 8 9410 8200Telephone

+61 8 9410 8299Fax





QUICKSEAL (F,M,C)Product name








100%9004-34-6 232-674-9CELLULOSE





Eye




Ingestion





www.newpark.com

QUICKSEAL (F,M,C)PRODUCT NAME



Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition. Dust may form explosive mixtures with air.5.2 Special hazards arising from the substance or mixture

Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire.Difficult to extinguish once burning.


None allocated.

5.4 Hazchem code








Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are labelled, protected from light, freezing or physical damage and tightly sealed when not in use. Keep out of reach ofchildren.







Exposure standards









PPE






9.1 Information on basic physical and chemical propertiesYELLOW TO BROWN SOLIDAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT RELEVANTBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate7 to 8pHNOT AVAILABLEVapour density0.9 - 1.2Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold







Incompatible with calcium oxides, bleaching powder, perchlorates, perchloric acid, sodium chlorate, fluorine, nitric acid, sodium nitrateand sodium nitrite.










This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated. Acute Oral Toxicity: LD50 (oral) > 5000 mg/kg (rats).Acute Dermal Toxicity: LD50 (dermal) > 2000 mg/kg (rats).Acute Inhalation Toxicity: LC50 (Inhalation) = 5800 mg/m3/4hrs (rat).

Acute toxicity




CELLULOSE

Not classified as a skin irritant. Contact may result in mechanical irritation, redness and rash.Skin

Not classified as an eye irritant. However, this product may cause mechanical eye irritation with redness andlacrimation.

Eye











12.1 Toxicity

Low toxicity to aquatic organisms.










Waste disposal








None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number









Poison schedule


Inventory listings


Classifications










Abbreviations




Report status


Prepared by

[ End of SDS ]




BUTCHERS SALT ● FLOSSY SALT ● HALITE ● NACL ● SODIUM CHLORIDESynonym(s)

CHLORIDE SOURCE ● DRILLING FLUID ADDITIVEUse(s)1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





SALTProduct name



2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.





>98%7647-14-5 231-598-3SODIUM CHLORIDE

<0.8%- -INORGANIC SALT(S)

<0.8%7732-18-5 231-791-2WATER





Eye



Skin


Ingestion


SDS Date: 10 Mar 2017


www.newpark.com

SALTPRODUCT NAME

Under normal conditions of use, adverse health effects are not anticipated. This product is generally considered to be of low toxicity.4.2 Most important symptoms and effects, both acute and delayed






None allocated.

5.4 Hazchem code









Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Large storage areas should have appropriate fire protection systems.







Exposure standards


Biological limits




SALTPRODUCT NAME

PPE








9.1 Information on basic physical and chemical propertiesTRANSLUCENT TO WHITE GRANULES OR POWDERAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point1413°CBoiling point801°CMelting pointNOT AVAILABLEEvaporation rate7 (1 % Solution)pHNOT AVAILABLEVapour density2.163Specific gravity357 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold







Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid) and alkalis (e.g. sodium hydroxide).

May evolve toxic gases when strongly heated.10.6 Hazardous decomposition products






SALTPRODUCT NAME


May be harmful if swallowed in large quantities. Repeated ingestion of excessive amounts of sodiumchloride may cause disturbance of body electrolyte and fluid balance. LC50 (Inhalation): > 42000 mg/m3/1 hour (rat)LD50 (Ingestion): 3000 mg/kg (rat)LD50 (Skin): > 10000 mg/kg (rabbit)

Acute toxicity

Information available for the ingredient(s):

IngredientOral Toxicity (LD50) Dermal Toxicity (LD50) Inhalation Toxicity

(LC50)

3000 mg/kg (rat) > 10000 mg/kg (rabbit) > 42000 mg/m³/1 hourSODIUM CHLORIDE

Contact may result in mild irritation and rash.Skin

Contact may cause discomfort, lacrimation and redness.Eye








Additional ingredient toxicity value(s):

SODIUM CHLORIDE (7647-14-5)LD50 (intraperitoneal) 2602 mg/kg (mouse)LD50 (intravenous) 645 mg/kg (mouse)LD50 (subcutaneous) 3000 mg/kg (mouse)LDLo (intravenous) 300 mg/kg (guinea pig)LDLo (oral) 8000 mg/kg (rabbit)LDLo (subcutaneous) 2160 mg/kg (guinea pig)TDLo (oral) 12357 mg/kg (human)



12.1 Toxicity

Aquatic Toxicity: LC50 (water flea) is 2122 mg/L/48 hours; LC50 (fathead minnow) is 6.57 g/L/96 hours.










Waste disposal




SALTPRODUCT NAME



None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number










Poison schedule

None allocated.Risk phrases



None allocated.Safety phrases

None allocated.Hazard codes



Classifications






SALTPRODUCT NAME




Abbreviations




Report status


Prepared by

[ End of SDS ]




DISODIUM DIHYDROGEN PYROPHOSPHATE ● DISODIUM PYROPHOSPHATESynonyms

ACIDIFIER ● BUFFERING AGENTUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





SAPPProduct name








100%7758-16-9 231-835-0DISODIUM PYROPHOSPHATE





Eye








www.newpark.com

SAPPPRODUCT NAME



Non flammable. May evolve toxic gases (phosphorus oxides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code















Exposure standards



Nuisance dust SWA [AUS] -- 10 -- --





SAPPPRODUCT NAME

PPE






9.1 Information on basic physical and chemical propertiesWHITE POWDERAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point> 600°CMelting pointNOT AVAILABLEEvaporation rate4 - 5 (10% Solution)pHNOT AVAILABLEVapour density1.35 - 1.41Specific gravity119 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold








May evolve toxic gases (phosphorus oxides) when heated to decomposition.10.6 Hazardous decomposition products





Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation.Acute toxicity




SAPPPRODUCT NAME

Ingestion of large quantities may also result in serious disturbances in calcium metabolism.

LD50 (Ingestion): 2650 mg/kg (mouse)LD50 (Intraperitoneal): 1 g/kg (mouse)LD50 (Intravenous): 59 mg/kg (mouse)LD50 (Subcutaneous): 480 mg/kg (mouse)



2650 mg/kg (mouse) > 2000 mg/kg (rat) > 0.58 mg/L/4hrs (rat)DISODIUM PYROPHOSPHATE

Low to moderate irritant. Prolonged or repeated contact may result in irritation and rash.Skin

Low to moderate irritant. Contact may result in mild irritation, lacrimation and redness.Eye


Low irritant. Over exposure may result in irritation of the nose and throat, with coughing.STOT - singleexposure







DISODIUM PYROPHOSPHATE (7758-16-9)LD50 (intraperitoneal) 1 g/kg (mouse)LD50 (intravenous) 59 mg/kg (mouse)LD50 (subcutaneous) 480 mg/kg (mouse)


12.1 Toxicity











Waste disposal






SAPPPRODUCT NAME


None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number









Poison schedule


Inventory listings


Classifications






SAPPPRODUCT NAME




Abbreviations




Report status


Prepared by

[ End of SDS ]




SODA ASH DENSE ● SODIUM CARBONATESynonyms

DRILLING AIDUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





SODA ASHProduct name




Signal word DANGER

Avoid breathing dust/fume/gas/mist/vapours/spray.P261Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280


Causes serious eye damage.H318May cause respiratory irritation.H335

Hazard statements

Pictograms

Physical Hazards


Health Hazards

Serious Eye Damage / Eye Irritation: Category 1Specific Target Organ Toxicity (Single Exposure): Category 3 (Respiratory Irritation)






www.newpark.com

SODA ASHPRODUCT NAME




Storage statements

IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.

P305 + P351 + P338

Immediately call a POISON CENTER or doctor/physician.P310

Response statements



>97%497-19-8 207-838-8SODIUM CARBONATE





Eye



Skin


Ingestion








None allocated.

5.4 Hazchem code


















Exposure standards



Sodium Carbonate (total dust) SWA [AUS] -- 10 -- --

Biological limits


PPE







9.1 Information on basic physical and chemical propertiesWHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point854°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpH




9.1 Information on basic physical and chemical propertiesNOT AVAILABLEVapour density2.533Specific gravity170 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold













May be harmful if swallowed.Acute toxicity





> 2000 mg/m³ (rat)(NICNAS)

SODIUM CARBONATE


Contact may result in irritation, lacrimation, pain, redness and possible permanent damage.Eye


Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may resultin breathing difficulties.


Not classified as causing organ damage from repeated exposure. Carbonate ions are neutralised underphysiological conditions to form bicarbonate ions and/or carbon dioxide, which are major products of allhuman metabolic activities; therefore, systemic toxicity is not expected.






SODIUM CARBONATE (497-19-8)LD50 (intraperitoneal) 117 mg/kg (mouse)LD50 (subcutaneous) 2210 mg/kg (mouse)







12.1 Toxicity

Fishes, Lepomis macrochirus, LC50, 96 h, 300 mg/l. Crustaceans, Ceriodaphnia dubia, EC50, 48 h, 200 - 227 mg/l.

12.2 Persistence and degradabilityNot applicable for inorganic substances. The methods for determining the biological degradability are not applicable to inorganicsubstances.


If sodium carbonate is emitted to soil it can escape to atmosphere as carbon dioxide, precipitate as a metal carbonate, formcomplexes or stay in solution.

WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11(goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Notexpected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out.






Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number










Poison schedule


Inventory listings


Classifications









Abbreviations




Report status


Prepared by


[ End of SDS ]




BAKING SODA ● BICARBONATE OF SODA ● CARBONIC ACID, MONOSODIUM SALT ● MONOSODIUMCARBONATE ● SODIUM ACID CARBONATE ● SODIUM HYDROGEN CARBONATE

Synonyms

PH CONTROLUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





SODIUM BICARBONATEProduct name








>99%144-55-8 205-633-8SODIUM BICARBONATE





Eye





No adverse health effects expected if the product is handled in accordance with the SDS and the product label.4.2 Most important symptoms and effects, both acute and delayed



www.newpark.com

SODIUM BICARBONATEPRODUCT NAME



Non flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code








Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure packages are adequatelylabelled, protected from physical damage and sealed when not in use.







Exposure standards



Sodium Bicarbonate (total dust) SWA [AUS] -- 10 -- --







PPE

Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles.

Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves.




9.1 Information on basic physical and chemical propertiesWHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point854°CMelting pointNOT AVAILABLEEvaporation rate8 (1% Solution)pHNOT AVAILABLEVapour density2.533Specific gravity170 g/L @ 25°CSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold







Incompatible with acids (e.g. nitric acid).






This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated. Sodium bicarbonate can neutralise the gastric juices in the stomach. Duringneutralisation, carbon dioxide gas is evolved and may cause stretching of the stomach, and with very largedoses possible damage or rupture.

LD50 (Ingestion): 3360 mg/kg (mouse)LC50 (inhalation): 4.74 mg/L (rat)

Acute toxicity







> 4000 mg/kg (rat) -- > 4.74 mg/L/4.5hrs (rat)SODIUM BICARBONATE

Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation.Skin

Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness.Eye









12.1 Toxicity

LC50 (Oncorhynchus mykiss) = 7.700 mg/l/96hrs.LC50 (Lepomis macrochirus) = 7.100 mg/l/96hrs.EC50 (Crustaceans, Daphnia magna) = 4.100 mg/l/48hrsLOEC (Crustaceans, Daphnia magna) = 3.100 mg/l/48hrs.



High mobility in water and soil/sediments.







Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number













Poison schedule


Inventory listings


Classifications






Abbreviations








Report status


Prepared by

[ End of SDS ]




SODIUM SULFITESynonyms

ANTIOXIDANT ● FOOD PRESERVATIVE ● LABORATORY REAGENT ● PAPER INDUSTRY ●PHOTOGRAPHIC DEVELOPER ● REDUCING AGENT ● WATER TREATMENT

Uses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





SODIUM SULPHITEProduct name




Signal word DANGER

Wash thoroughly after handling.P264Do not eat, drink or smoke when using this product.P270Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.P280


Contact with acids liberates toxic gas.AUH031Harmful if swallowed.H302Causes serious eye damage.H318

Hazard statements

Pictograms

Physical Hazards


Health Hazards

Acute Toxicity: Oral: Category 4Serious Eye Damage / Eye Irritation: Category 1Contact with acids liberates toxic gas.




SDS Date: 28 Apr 2021


www.newpark.com

SODIUM SULPHITEPRODUCT NAME




IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.

P305 + P351 + P338

Immediately call a POISON CENTRE or doctor/physician.P310Rinse mouth.P330

Response statements



>97%7757-83-7 231-821-4SODIUM SULPHITE

<2.5%7757-82-6 231-820-9SODIUM SULPHATE

<0.1%497-19-8 207-838-8SODIUM CARBONATE

<0.1%7732-18-5 231-791-2WATER





Eye



Skin

For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Urgenthospital treatment is likely to be needed. If swallowed, do not induce vomiting.

Ingestion

Eye wash facilities and safety shower are recommended.First aid facilities




Non flammable. May evolve sulphur oxides and sodium oxides when heated to decomposition.5.2 Special hazards arising from the substance or mixture

Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire.


None allocated.

5.4 Hazchem code



















Exposure standards



Sodium Carbonate (total dust) SWA [AUS] -- 10 -- --

Biological limits


PPE




Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear aFull-face Class P3 (Particulate) respirator.




9.1 Information on basic physical and chemical propertiesWHITE CRYSTALLINE SOLIDAppearanceODOURLESSOdourNON FLAMMABLEFlammability




9.1 Information on basic physical and chemical propertiesNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate9.0 to 10.5pHNOT AVAILABLEVapour density2.6Relative densitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold





Avoid heat, sparks, open flames and other ignition sources. Avoid exposure to air and moisture. Sensitive to air and moisture.


Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid). Strong reducing agent.

May evolve sulphur oxides and sodium oxides when heated to decomposition.10.6 Hazardous decomposition products



10.1 ReactivityContact with acids liberates toxic gas.





820 mg/kg (mouse);3560 mg/kg (rat)

> 2000 mg/kg (rat) > 5500 mg/m3/4hrs (rat)SODIUM SULPHITE

5989 mg/kg (mouse) -- --SODIUM SULPHATE

> 2000 mg/kg (rat)(AICIS)

> 2000 mg/kg (rat)(AICIS)

> 2000 mg/m³ (rat)(AICIS)

SODIUM CARBONATE






Contact may result in irritation, lacrimation, pain, redness and possible serious eye damage.Eye

Some individuals are hypersensitive to sulphites and may experience adverse reactions following exposure.Individuals known to be hypersensitive or with existing respiratory problems (eg asthma) are advised to avoidexposure.

Sensitisation

Over exposure may result in mucous membrane irritation of the respiratory tract, with coughing.STOT - singleexposure







SODIUM SULPHITE (7757-83-7)LD50 (intraperitoneal) 950 mg/kg (mouse)LD50 (intravenous) 175 mg/kg (mouse)LDLo (intravenous) 400 mg/kg (cat)LDLo (oral) 2825 mg/kg (rabbit)LDLo (subcutaneous) 600 mg/kg (rabbit)

SODIUM SULPHATE (7757-82-6)LD50 (intravenous) 1220 mg/kg (rabbit)LDLo (intravenous) 1220 mg/kg (mouse)TDLo (oral) 14 g/kg (mouse - 8-12 days pregnant)TDLo (subcutaneous) 806 mg/kg/26 weeks intermittently (mouse)

SODIUM CARBONATE (497-19-8)LD50 (intraperitoneal) 117 mg/kg (mouse)LD50 (subcutaneous) 2210 mg/kg (mouse)


12.1 Toxicity





Avoid contamination of drains and waterways.




Cover spill with soda ash or sodium bicarbonate. Mix and spray with water, may be effervescent. Wait untilreaction is complete, scoop into a large beaker and cautiously add equal volume of sodium hypochlorite(reaction may be vigorous). Add more water, stir and allow to stand (~1hr). Dilute and neutralise. Absorbwith sand/similar dispose of to an approved landfill site, or alternatively (for small amounts) flush to sewerwith large excess of water.


Waste disposal








None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number









Poison schedule


Inventory listings

Safe Work Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals (GHS Revision 7).

Classifications



WORKPLACE CONTROLS AND PRACTICES: Unless a less toxic chemical can be substituted for ahazardous substance, ENGINEERING CONTROLS are the most effective way of reducing exposure.The best protection is to enclose operations and/or provide local exhaust ventilation at the site ofchemical release. Isolating operations can also reduce exposure. Using respirators or protectiveequipment is less effective than the controls mentioned above, but is sometimes necessary.










Abbreviations




Report status


Prepared by

[ End of SDS ]




STRATA VANGUARDSynonyms





+61 8 9410 8200Telephone

+61 8 9410 8299Fax





STRATA-VANGUARDProduct name








<30%9004-34-6 232-674-9CELLULOSE

<15%68855-54-9 272-489-0DIATOMACEOUS EARTH, FLUX CALCINED

<10%8031-18-3 617-052-0FULLERS EARTH

<10%1317-65-3 215-279-6LIMESTONE (CALCIUM CARBONATE)

<5%14464-46-1 238-455-4CRISTOBALITE


<1%1309-48-4 215-171-9MAGNESIUM OXIDE

<50%9003-55-8 618-370-21,3 BUTADIENE/STYRENE COPOLYMERS

<50%9003-18-3 618-357-12-PROPENENITRILE-1,3-BUTADIENE RUBBER

<50%9006-04-6 232-689-0NATURAL RUBBER

<50%9003-31-0 618-362-9POLYISOPRENE

<3%9002-88-4 618-339-3POLYETHYLENE




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STRATA-VANGUARDPRODUCT NAME




Eye



Skin


Ingestion






No fire or explosion hazard exists.5.3 Advice for firefighters

None allocated.

5.4 Hazchem code



















Exposure standards



Calcium carbonate (Limestone, Marble, Whiting) SWA [AUS] -- 10 -- --


Cristobalite SWA [AUS] -- 0.1 -- --




PPE




Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear aPowered Air Purifying Respirator (PAPR) with Class P3 (Particulate) filter or a Full-face Class P3(Particulate) respirator.




9.1 Information on basic physical and chemical propertiesTAN COLOURED POWDERAppearanceMILD ODOUROdourNON FLAMMABLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate6.3 (5% Suspension)pHNOT AVAILABLEVapour density2.1Specific gravityINSOLUBLESolubility (water)1 mm Hg @ 20°CVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold








Avoid contact with incompatible substances.


Incompatible with acids (e.g. nitric acid). Also incompatible with oxygen difluoride, chlorine and trifluoride.






Toxicity Data available for the ingredients:CRISTOBALITE (14464-46-1): TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis)QUARTZ (SILICA CRYSTALLINE) (14808-60-7): LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis)CELLULOSE (9004-34-6): LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit)POLYETHYLENE (9002-88-4): LDLo (ingestion) 3000 mg/kg (rat)MAGNESIUM OXIDE (1309-48-4): TCLo (inhalation) 400 mg/kg (human)

Acute toxicity




CELLULOSE

> 5000 mg/kg (rat) -- --LIMESTONE (CALCIUM CARBONATE)

Not classified as a skin irritant. Contact may result in mechanical irritation.Skin

Not classified as an eye irritant. Contact may result in mechanical irritation.Eye


No known effects from this product.STOT - singleexposure


Not classified as a carcinogen. Crystalline silica is classified as carcinogenic to humans (IARC Group 1).However, there is a body of evidence supporting the fact that increased cancer risk would be limited topeople already suffering from silicosis.

Carcinogenicity




CRISTOBALITE (14464-46-1)TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis)

POLYETHYLENE (9002-88-4)LDLo (oral) 3000 mg/kg (rat)






Not classified as causing organ damage from repeated exposure. Adverse health effects associated withsilica, such as the development of silicosis (lung fibrosis), is not anticipated unless prolonged and repeatedexposure to respirable silica quartz dust occurs.



12.1 Toxicity


12.2 Persistence and degradabilityNot applicable.


This product has low mobility in soil.







Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number










Poison schedule


Inventory listings


Classifications











Abbreviations




Report status


Prepared by


[ End of SDS ]




TEASynonym(s)

CHEMICAL INTERMEDIATE ● LABORATORY REAGENT ● SOLVENTUse(s)1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





TRIETHANOLAMINEProduct name



2.2 Label elements

DANGERSignal word

Do not breathe dust/fume/gas/mist/vapours/spray.P260Wash thoroughly after handling.P264Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280

Prevention statement(s)

Causes skin irritation.H315Causes serious eye damage.H318May cause respiratory irritation.H335May cause damage to organs through prolonged or repeated exposure.H373

Hazard statement(s)

Pictogram(s)

Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 1Specific Target Organ Systemic Toxicity (Single Exposure): Category 3Specific Target Organ Systemic Toxicity (Repeated Exposure): Category 2

GHS classification(s)




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TRIETHANOLAMINEPRODUCT NAME


Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)


Storage statement(s)


P305 + P351 + P338

Immediately call a POISON CENTER or doctor/physician.P310Get medical advice/attention if you feel unwell.P314Specific treatment is advised - see first aid instructions.P321If skin irritation occurs: Get medical advice/ attention.P332 + P313Take off contaminated clothing and wash before re-use.P362

Response statement(s)



>60%102-71-6 203-049-8TRIETHANOLAMINE

>=10 to <=30%111-42-2 203-868-0DIETHANOLAMINE





Eye

If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator oran Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing.

Inhalation


Skin

For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting. Rinse mouth out with water and give plenty of water to drink.

Ingestion


Over exposure may result in irritation to the eyes, nose and respiratory system. May cause allergic contact dermatitis.4.2 Most important symptoms and effects, both acute and delayed



Combustible. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code

Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.5.1 Extinguishing media












Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Store as a Class C2 Combustible Liquid (AS1940).







Exposure standards



Diethanolamine (h) SWA (AUS) 3 13 -- --

Triethanolamine SWA (AUS) -- 5 -- --


PPE



Body Wear coveralls.

Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-ClassP1 (Organic gases/vapours and Particulate) respirator.

Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain vapour levels below the recommended exposure standard.






9.1 Information on basic physical and chemical propertiesCLEAR LIQUIDAppearanceMILD AMMONIACAL ODOUROdourCLASS C2 COMBUSTIBLEFlammability190°C (cc)Flash point335°CBoiling point12°CMelting point< 0.01 (n-Butyl acetate = 1)Evaporation rate10.5 (1 % Solution)pH4.80 (Air = 1)Vapour densityNOT AVAILABLESpecific gravitySOLUBLESolubility (water)< 1 kPa @ 20°CVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperature450 mPa·s @ 25°CViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

9.2 Other information1.123Relative density







Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), nitrites, heat and ignition sources. Also incompatiblewith organic anhydrides, isocyanates, vinyl acetate, acrylates, substituted allyls, alkylene oxides, epichlorohydrin, aldehydes, copper,brass and aluminium.

May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.10.6 Hazardous decomposition products

Hazardous polymerization is not expected to occur.




May be harmful if swallowed, in contact with skin, and/or if inhaled.Acute toxicity

Information available for the ingredient(s):

IngredientOral Toxicity (LD50) Dermal Toxicity (LD50) Inhalation Toxicity

(LC50)

2200 mg/kg (rabbit) > 20 mL/kg (rabbit) --TRIETHANOLAMINE

620 uL/kg (rat) 7640 uL/kg (rabbit) --DIETHANOLAMINE





Contact may result in irritation, redness and rash.Skin


Triethanolamine has been reported to cause allergic contact dermatitis. It is not known to cause respiratorysensitisation.

Sensitisation

Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result inbreathing difficulties.


Not expected to present an aspiration hazard.Aspiration

Diethanolamine may cause damage to organs (liver) through prolonged and repeated exposure.STOT - repeatedexposure


Triethanolamine and diethanolamine are not classifiable as to carcinogenicity to humans (IARC Group 3).Carcinogenicity


Additional ingredient toxicity value(s):

TRIETHANOLAMINE (102-71-6)LD50 (intraperitoneal) 1450 mg/kg (mouse)TDLo (oral) 16 g/kg/64 weeks (mouse - cancer)

DIETHANOLAMINE (111-42-2)LD50 (intramuscular) 1500 mg/kg (rat)LD50 (intraperitoneal) 120 mg/kg (rat)LD50 (intravenous) 778 mg/kg (rat)LD50 (subcutaneous) 2200 mg/kg (rat)LDLo (oral) 3 g/kg (rat)


12.1 Toxicity





In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil,residual triethanolamine may leach to groundwater. LC50 (shrimp): > 100 ppm.




Reduce with sodium thiosulphate/ bisulphite (not strong reducing agent), acidify with 3M sulphuric acid.Scoop into a container of water and neutralise with soda ash. Absorb with sand or similar and dispose of toan approved landfill site. Contact the manufacturer/supplier for additional information (if required).


Waste disposal







None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number









Poison schedule

R37/38 Irritating to respiratory system and skin.R41 Risk of serious damage to eyes.R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.

Risk phrases



S25 Avoid contact with eyes.S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS39 Wear eye/face protection.

Safety phrases

Xi IrritantXn Harmful

Hazard codes



Classifications












Abbreviations




Report status


Prepared by

[ End of SDS ]



TrueScavÔ HD

EN

SAFETY DATA SHEET

Issue Date 29-Aug-2018 Revision Date 29-Aug-2018 Version 1


Product identifier

Product Name TrueScavÔ HD




Recommended Use oxygen scavenger










Label elements


Other hazards General HazardsNo information available

_____________________________________________________________________________________________

UGHS Page 1 / 8


_____________________________________________________________________________________________NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018


Substance













Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment.











Non-hazardous ingredients Proprietary

_____________________________________________________________________________________________

UGHS Page 2 / 8

>99

















Incompatible materials Strong oxidizing agents


Control parameters









_____________________________________________________________________________________________

UGHS Page 3 / 8





Other Information Softening point No information availableMolecular weight No information availableVOC Content (%) No information availableLiquid Density No information availableBulk density No information availableParticle Size No information availableParticle Size Distribution No information available


Reactivity

Reactivity Stable under normal conditions.

Chemical stability





Conditions to avoid


Appearance Powder Odor No information available.Color White Odor threshold No information available

Property Values Remarks • Method pH 5 - 8Melting point / freezing point 160 °CBoiling point / boiling range No information availableFlash point No information availableEvaporation rate No information availableFlammability (solid, gas) No information availableFlammability Limit in Air No information available


Vapor pressure No data availableVapor density No data availableRelative density 1.2-1.7Water solubility Soluble in waterSolubility(ies) No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity Not applicableDynamic viscosity

_____________________________________________________________________________________________

UGHS Page 4 / 8

Not applicable



Incompatible materials Strong oxidizing agents.




Acute toxicity









The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 5,005.00 mg/kg







Respiratory or skin sensitization None known.






_____________________________________________________________________________________________

UGHS Page 5 / 8




Ecotoxicity







Mobility











ADG Not Regulated

IATA Not Regulated

IMDG Not Regulated



_____________________________________________________________________________________________

UGHS Page 6 / 8









The Montreal Protocol on Substances that Deplete the Ozone Layer Not applicable

The Stockholm Convention on Persistent Organic Pollutants Not applicable

The Rotterdam Convention Not applicable


Issue Date 29-Aug-2018

Revision Date 29-Aug-2018




DisclaimerThis document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources including


_____________________________________________________________________________________________

UGHS Page 7 / 8


manufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.


_____________________________________________________________________________________________

UGHS Page 8 / 8


ZINC WHITESynonyms

SCAVENGERUses1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





ZINC OXIDEProduct name




Signal word WARNING


Collect spillage.P391Response statements

Avoid release to the environment.P273Prevention statements

Very toxic to aquatic life with long lasting effects.H410Hazard statements

Pictograms

Physical Hazards


Health Hazards

Not classified as a Health Hazard


Aquatic Toxicity (Chronic): Category 1




www.newpark.com

ZINC OXIDEPRODUCT NAME





>99%1314-13-2 215-222-5ZINC OXIDE





Eye



Skin


Ingestion





Non flammable. May evolve zinc oxides when heated to decomposition.5.2 Special hazards arising from the substance or mixture

Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipmentincluding Self Contained Breathing Apparatus (SCBA) when combating fire.


2Z2 Fine Water Spray.Z Wear full fire kit and breathing apparatus. Contain spill and run-off.

5.4 Hazchem code


















Exposure standards



Zinc oxide (dust) SWA [AUS] -- 10 -- --

Zinc oxide (fume) SWA [AUS] -- 5 -- 10


PPE





Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proofextraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.



9.1 Information on basic physical and chemical propertiesWHITE TO YELLOW-WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point1975°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour densityNOT AVAILABLESpecific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperature




9.1 Information on basic physical and chemical propertiesNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold







Incompatible with metals if heated and with acids (e.g. nitric acid).

May evolve zinc oxides when heated to decomposition.10.6 Hazardous decomposition products





This product is expected to be of low toxicity. Based on available data, the classification criteria are not met.Acute toxicity



7950 mg/kg (mouse) -- 2500 mg/m³ (mouse)ZINC OXIDE

Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation.Skin

Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness.Eye


Not classified as causing organ damage from single exposure. Inhalation of freshly formed zinc oxide fumesmay result in the development of a flu-like illness termed metal fume fever.








ZINC OXIDE (1314-13-2)LD50 (intraperitoneal) 240 mg/kg (rat)LDLo (oral) 500 mg/kg (human)TCLo (inhalation) 600 mg/m³ (human)



12.1 Toxicity

Very toxic to aquatic life with long lasting effects.

12.2 Persistence and degradabilityThis product is not readily biodegradable.








12.3 Bioaccumulative potentialAll living organisms have homeostasis mechanisms that actively regulate zinc uptake and absorption/excretion from the body; due tothis regulation, zinc and zinc compounds do not bioaccumulate or biomagnify.


Collect and place in sealable containers and dispose of to an approved landfill site. Contact themanufacturer/supplier for additional information (if required).


Waste disposal




III

9 9

III III


14.4 Packing Group

ENVIRONMENTALLYHAZARDOUS SUBSTANCE,

SOLID, N.O.S.

3077


SOLID, N.O.S.

3077 3077


SOLID, N.O.S.

14.1 UN Number


Marine Pollutant


2ZHazchem code

F-A, S-FEmS

The environmentally hazardous substance mark is not required when transported in packages of lessthan 5 kg/L (UN Model Regulations: Special Provision 375; IATA: Special Provision A197; IMDG:Special Provision 969) or less than 500 kg/L by Australian Road and Rail.

Other information

9C1GTEPG






Poison schedule


Inventory listings


Classifications











Abbreviations




Report status


Prepared by





[ End of SDS ]



SAFETY DATA SHEET

CEMENT - CLASS GRevision Date: 02-Aug-2018 Revision Number: 38

1. Product Identifier & Identity for the Chemical

Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.

1.1. Product Identifier Product Name CEMENT - CLASS G

Other means of Identification Synonyms NoneHazardous Material Number: HM001839

Recommended use of the chemical and restrictions on use Recommended Use CementUses advised against No information available

Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.

15 Marriott Road, Jandakot, WA 6164AustraliaACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300

E-mail Address [email protected]

Emergency phone number + 61 1 800 686 951Global Incident Response Access Code: 334305Contract Number: 14012

Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100

2. Hazard Identification


Classification of the hazardous chemical Skin Corrosion/Irritation Category 2 - H315Serious Eye Damage/Irritation Category 1 - H318Skin Sensitization Category 1 - H317Carcinogenicity Category 1A - H350Specific Target Organ Toxicity - (Single Exposure) Category 3 - H335Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373

Label elements, including precautionary statements

_____________________________________________________________________________________________Page 1 / 9

_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 02-Aug-2018

Hazard Pictograms

Signal Word DANGER

Hazard Statements: H315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritationH350 - May cause cancer by inhalationH373 - May cause damage to organs through prolonged or repeated exposure if inhaled

Precautionary Statements

Prevention P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP280 - Wear protective gloves/eye protection/face protectionP281 - Use personal protective equipment as required

Response P302 + P352 - IF ON SKIN: Wash with plenty of water.P333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash before reuseP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a positioncomfortable for breathingP312 - Call a POISON CENTER/doctor/physician if you feel unwellP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell

Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closedP405 - Store locked up

Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations

ContainsSubstances CAS NumberPortland cement 65997-15-1Crystalline silica, quartz 14808-60-7

Other hazards which do not result in classification This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).

For the full text of the H-phrases mentioned in this Section, see Section 16

3. Composition/information on Ingredients

Substances CAS Number PERCENT (w/w) GHS Classification -Australia

Portland cement 65997-15-1 60 - 100% Skin Irrit. 2 (H315)

_____________________________________________________________________________________________Page 2 / 9


Eye Corr. 1 (H318)Skin Sens. 1 (H317)STOT SE 3 (H335)

Crystalline silica, quartz 14808-60-7 1 - 5% Carc. 1A (H350)STOT RE 1 (H372)

4. First aid measures

Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory

irritation develops or if breathing becomes difficult.Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek

prompt medical attention.Skin In case of contact, immediately flush skin with plenty of soap and water for at least

15 minutes. Get medical attention.Ingestion Under normal conditions, first aid procedures are not required.

Symptoms caused by exposure Causes severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. Maycause respiratory irritation. Breathing crystalline silica can cause lung disease, including silicosis and lung cancer.Crystalline silica has also been associated with scleroderma and kidney disease.

Medical Attention and Special Treatment Notes to Physician Treat symptomatically

5. Fire Fighting Measures

Suitable extinguishing equipment Suitable Extinguishing MediaNone - does not burn.Extinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical Special exposure hazards in a fireNot applicable

Special protective equipment and precautions for fire fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation. Evacuate all persons from the area.

6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.

6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated withcontaminating substances and use appropriate methods for collection, storage and disposal.



_____________________________________________________________________________________________Page 3 / 9

Handling Precautions


Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite, and/or tridymite which may become airbornewithout a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keepexposure below recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator whenusing this product. Material is slippery when wet. Wash hands after use. Launder contaminated clothing before reuse.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a cool well ventilated area. Keep container closed when not in use. Store locked up. Store in a cool, dry location. Use goodhousekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Product has a shelf lifeof 24 months.Other GuidelinesNo information available

8. Exposure Controls/Personal Protection

Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAPortland cement 65997-15-1 TWA: 10 mg/m3 TWA: 1 mg/m3

Crystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3

Appropriate engineering controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures

below applicable exposure limits.

Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the

selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, orequivalent respirator when using this product.

Hand Protection Impervious rubber gloves.Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be laundered

before reuse. Use precautionary measures to avoid creating dust when removing orlaundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls Do not allow material to contaminate ground water system

9. Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Property Values Remarks/ - Method pH: 12.4Freezing Point / Range No data availableMelting Point / Range No data availablePour Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 3.14

Physical State: Solid Color GrayOdor: Odorless Odor Threshold:

_____________________________________________________________________________________________Page 4 / 9



Water Solubility No data availableSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) No data available

10. Stability and Reactivity

10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid Keep away from any contact with water.10.5. Incompatible materials Hydrofluoric acid.

10.6. Hazardous decomposition products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).

11. Toxicological Information

Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.

Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. Maycause respiratory irritation. Breathing crystalline silica can cause lung disease, including silicosis and lung cancer.Crystalline silica has also been associated with scleroderma and kidney disease.

Toxicology data for the components

Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation

Portland cement 65997-15-1 > 2000 mg/kg (Rat) > 2000 mg/kg > 1 mg/L (Rat) 4h

Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No data available No data available

Immediate, delayed and chronic health effects from exposure Inhalation Causes moderate respiratory irritation. Inhaled crystalline silica in the form of quartz or

cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1). There issufficient evidence in experimental animals for the carcinogenicity of tridymite (IARC, Group2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanent lungdamage may be occurring. Inhalation of dust may also have serious chronic health effects(See "Chronic Effects/Carcinogenicity" subsection below).

Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact Causes skin irritation. May cause alkali burns with confined contact. May cause an allergic

skin reaction. Can dry skin.Ingestion Causes burns of the mouth, throat and stomach.

_____________________________________________________________________________________________Page 5 / 9


Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause aprogressive, disabling, and sometimes-fatal lung disease called silicosis.Symptoms include cough, shortness of breath, wheezing, non-specific chestillness, and reduced pulmonary function. This disease is exacerbated by smoking.Individuals with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (Group 2A - possible carcinogen tohumans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres(June 1997) in conjunction with the use of these minerals. The National ToxicologyProgram classifies respirable crystalline silica as "Known to be a humancarcinogen". Refer to the 9th Report on Carcinogens (2000). The AmericanConference of Governmental Industrial Hygienists (ACGIH) classifies crystallinesilica, quartz, as a suspected human carcinogen (A2). There is some evidencethat breathing respirable crystalline silica or the disease silicosis is associated withan increased incidence of significant disease endpoints such as scleroderma (animmune system disorder manifested by scarring of the lungs, skin, and otherinternal organs) and kidney disease.

Exposure LevelsNo data available

Interactive effects Individuals with respiratory disease, including but not limited to asthma and bronchitis, or subject to eye irritation, should not beexposed to quartz dust.

Data limitationsNo data available

Substances CAS Number Skin corrosion/irritationPortland cement 65997-15-1 Irritating to skin. (Rabbit)Crystalline silica, quartz 14808-60-7 Non-irritating to the skin

Substances CAS Number Serious eye damage/irritationPortland cement 65997-15-1 Corrosive to eyesCrystalline silica, quartz 14808-60-7 Non-irritating to the eye No information available

Substances CAS Number Skin SensitizationPortland cement 65997-15-1 May cause sensitization by skin contactCrystalline silica, quartz 14808-60-7 No information available.

Substances CAS Number Respiratory SensitizationPortland cement 65997-15-1 No information availableCrystalline silica, quartz 14808-60-7 No information available

Substances CAS Number Mutagenic EffectsPortland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.

Substances CAS Number Carcinogenic EffectsPortland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The

IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure.

Substances CAS Number Reproductive toxicity

_____________________________________________________________________________________________Page 6 / 9


Portland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 No information available

Substances CAS Number STOT - single exposurePortland cement 65997-15-1 May cause respiratory irritation.Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number STOT - repeated exposurePortland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)

Substances CAS Number Aspiration hazardPortland cement 65997-15-1 Not applicableCrystalline silica, quartz 14808-60-7 Not applicable

12. Ecological Information

Ecotoxicity

Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to

MicroorganismsToxicity to Invertebrates

Portland cement 65997-15-1 No information available No information available No information available No information available

Crystalline silica,quartz

14808-60-7 EC50(72 h)=440 mg/L(Pseudokirchneriella

subcapitata)

LL0(96 h)=10000 mg/L(Danio rerio)

No information available LL50(24 h)>10000 mg/L(Daphnia magna)


Substances CAS Number Persistence and DegradabilityPortland cement 65997-15-1 The methods for determining biodegradability are

not applicable to inorganic substances.Crystalline silica, quartz 14808-60-7 The methods for determining biodegradability are

not applicable to inorganic substances.


Substances CAS Number Bioaccumulation

Portland cement 65997-15-1 No information available

Crystalline silica, quartz 14808-60-7 No information available


Substances CAS Number MobilityPortland cement 65997-15-1 No information availableCrystalline silica, quartz 14808-60-7 No information available

12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors

13. Disposal Considerations

Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations. Substance should NOT be deposited into a sewagefacility.

Disposal of any contaminated packaging

_____________________________________________________________________________________________Page 7 / 9

Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapableof containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial waste collection.


Environmental regulationsNot applicable

14. Transport Information

Transportation Information Australia ADG

UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable

IMDG/IMO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable

IATA/ICAO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable

Special precautions during transport None

HazChem Code None Allocated

15. Regulatory Information

Safety, health and environmental regulations specific for the product

International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or

assessment certificate.New Zealand Inventory ofChemicals

All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.

US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)

All components listed on inventory or are exempt.

Poisons Schedule number None Allocated

International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply.Stockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not apply.Basel Convention - Hazardous Waste: Does not apply.


Date of preparation or review

_____________________________________________________________________________________________Page 8 / 9


Revision Date: 02-Aug-2018

Revision NoteSDS sections updated:2

Full text of H-Statements referred to under sections 2 and 3H315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritationH350 - May cause cancer by inhalationH372 - Causes damage to organs through prolonged or repeated exposure if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled

Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.

For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.

Key abreviations or acronyms used bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day

Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID

Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.


_____________________________________________________________________________________________Page 9 / 9

SAFETY DATA SHEET

SILICALITE LIQUID


Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.

1.1. Product Identifier Product Name SILICALITE LIQUID

Other means of Identification Synonyms: NoneProduct Code: HM001274

Recommended use of the chemical and restrictions on use Recommended Use Light Weight Cement AdditiveUses Advised Against No information available


15 Marriott RoadJandakotWA 6164Australia

ACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300

E-Mail address: [email protected]

Emergency phone number + 61 1 800 686 951

Australian Poisons Information Centre24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100



Classification of the hazardous chemical Not classified


Hazard Pictograms

Signal Word Not Hazardous

_____________________________________________________________________________________________Page 1 / 8

Revision Date: 22-Sep-2015 Revision Number: 20

_____________________________________________________________________________________________

Hazard Statements Not Classified


Prevention None

Response None

Storage None

Disposal None

ContainsSubstances CAS NumberContains no hazardous substances in concentrations abovecut-off values according to the competent authority

NA

Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).

Australia ClassificationFor the full text of the H-phrases mentioned in this Section, see Section 16

Classification Not ClassifiedRisk Phrases None



Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority

NA 60 - 100% Not Applicable



irritation develops or if breathing becomes difficult.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15

minutes and get medical attention if irritation persists.Skin Wash with soap and water.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.

Symptoms caused by exposure No significant hazards expected.



Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting mediaExtinguishing media which must not be used for safety reasons

_____________________________________________________________________________________________Page 2 / 8

Revision Date: 22-Sep-2015SILICALITE LIQUID

_____________________________________________________________________________________________None known.

Specific hazards arising from the chemical Special Exposure HazardsNot applicable.

Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing.

6.2. Environmental precautions None known. Prevent from entering sewers, waterways, or low areas.

6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.


7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Ensure adequate ventilation. Wash hands after use. Launder contaminated clothingbefore reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationKeep container closed when not in use. Product has a shelf life of 24 months.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAContains no hazardous substances inconcentrations above cut-off values according tothe competent authority

NA Not applicable Not applicable

Appropriate engineering controls Engineering Controls Use in a well ventilated area.

Personal protective equipment (PPE) Respiratory Protection Not normally necessary.

Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls No information available


_____________________________________________________________________________________________Page 3 / 8


_____________________________________________________________________________________________


Property Values Remarks/ - Method pH: 6- 8Freezing Point/Range 0 °CMelting Point/Range No data availableBoiling Point/Range 100 °C / 212 °FFlash Point 100 °C / > 212 °FEvaporation rate No data availableVapor Pressure 22.9Vapor Density No data availableSpecific Gravity 1.37Water Solubility Miscible with waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) No data availableLiquid Density 11.64 lbs/gal


10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials None known.10.6. Hazardous Decomposition Products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).


Information on routes of exposure Principle Route of Exposure Eye and skin contact.

Sympotoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.




Contains no hazardoussubstances inconcentrations abovecut-off values according

NA No data available No data available No data available

_____________________________________________________________________________________________Page 4 / 8

Odor Threshold: No information availablePhysical State: Liquid

SILICALITE LIQUID

Color: Dark gray

Revision Date: 22-Sep-2015

Odor: Odorless

_____________________________________________________________________________________________to the competentauthority

Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact May cause mechanical irritation to eye.Skin Contact Practically Non-toxic by Skin Contact.Ingestion None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.


Interactive effects None known.


Substances CAS Number Skin corrosion/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable.

Substances CAS Number Eye damage/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable.

Substances CAS Number Skin SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Respiratory SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Mutagenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Carcinogenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Reproductive toxicityContains no hazardous NA Not applicable

_____________________________________________________________________________________________Page 5 / 8

SILICALITE LIQUID Revision Date: 22-Sep-2015

_____________________________________________________________________________________________substances inconcentrations above cut-offvalues according to thecompetent authority

Substances CAS Number STOT - single exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number STOT - repeated exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Aspiration hazardContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable


Ecotoxicity Product Ecotoxicity DataNo data available



Contains nohazardous substancesin concentrationsabove cut-off valuesaccording to thecompetent authority

NA No information available No information available No information available No information available


Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according tothe competent authority

NA No information available


Substances CAS Number Log Pow

Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority



Substances CAS Number MobilityContains no hazardous substances in concentrationsabove cut-off values according to the competent authority


12.6. Other adverse effects Endocrine Disruptor Information

_____________________________________________________________________________________________Page 6 / 8


_____________________________________________________________________________________________This product does not contain any known or suspected endocrine disruptors


Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations.

Disposal of any contaminated packaging Follow all applicable national or local regulations.



Transportation Information UN Number: Not restrictedUN Proper Shipping Name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable





International Inventories Australian AICS Inventory All components listed on inventory or are exempt.New Zealand Inventory ofChemicals


EINECS Inventory This product, and all its components, complies with EINECSUS TSCA Inventory All components listed on inventory or are exempt.Canadian DSL Inventory All components listed on inventory or are exempt.





Revision NoteSDS sections updated: 2

Full text of R-phrases referred to under Sections 2 and 3None

Full text of H-Statements referred to under sections 2 and 3None

Additional information For additional information on the use of this product, contact your local Halliburton

_____________________________________________________________________________________________Page 7 / 8


_____________________________________________________________________________________________representative.


Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50– Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed EffectConcentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL –Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 -milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day

Key literature references and sources for datawww.ChemADVISOR.com/



_____________________________________________________________________________________________Page 8 / 8


SAFETY DATA SHEET

GASCON 469



1.1. Product Identifier Product Name GASCON 469


Recommended use of the chemical and restrictions on use Recommended Use Cement AdditiveUses Advised Against No information available











Hazard Pictograms


_____________________________________________________________________________________________Page 1 / 8


_____________________________________________________________________________________________



Prevention None

Response None

Storage None

Disposal None


NA










irritation develops or if breathing becomes difficult.Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of

water for at least 15 minutes and get medical attention immediately after flushing.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.





_____________________________________________________________________________________________Page 2 / 8

Revision Date: 22-Sep-2015GASCON 469

_____________________________________________________________________________________________None known.




6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.




7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a cool well ventilated area. Keep from excessive heat. Keep from freezing. Keep container closed when not in use. Store innon-rusting containers. Product has a shelf life of 12 months.Other GuidelinesNo information available







Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.

_____________________________________________________________________________________________Page 3 / 8

GASCON 469 Revision Date: 22-Sep-2015

_____________________________________________________________________________________________Dust/mist respirator. (N95, P2/P3)

Hand Protection None known.Skin Protection Normal work coveralls.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system



Property Values Remarks/ - Method pH: 10Freezing Point/Range No data availableMelting Point/Range No data availableBoiling Point/Range 100 °C / 212 °FFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.1Water Solubility Soluble in water (10g/100ml)Solubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) 80


10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials Strong oxidizers. Strong acids.10.6. Hazardous Decomposition Products None known.





_____________________________________________________________________________________________Page 4 / 8

Odor: Odorless


Odor Threshold: No information availablePhysical State: Liquid Color: Transparent

GASCON 469

_____________________________________________________________________________________________



Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority


Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact May cause mild eye irritation.Skin Contact May cause mild skin irritation.Ingestion Irritation of the mouth, throat, and stomach.






NA Not applicable.


NA Not applicable.


NA Not applicable


NA Not applicable


NA Not applicable

_____________________________________________________________________________________________Page 5 / 8


_____________________________________________________________________________________________Substances CAS Number Carcinogenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Reproductive toxicityContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable


NA Not applicable


NA Not applicable


NA Not applicable














_____________________________________________________________________________________________Page 6 / 8


_____________________________________________________________________________________________






Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations. Incineration recommended in approvedincinerator according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.

Disposal of any contaminated packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapableof containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial waste collection.














_____________________________________________________________________________________________Page 7 / 8


_____________________________________________________________________________________________Revision Date: 22-Sep-2015










_____________________________________________________________________________________________Page 8 / 8


SAFETY DATA SHEET

HALAD® 413L CEMENT ADDITIVERevision Date: 07-May-2018 Revision Number: 26



1.1. Product Identifier Product Name HALAD® 413L CEMENT ADDITIVE


Recommended use of the chemical and restrictions on use Recommended Use Fluid Loss AdditiveUses advised against No information available










Hazard Pictograms


Hazard Statements: Not Classified

_____________________________________________________________________________________________Page 1 / 8

_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018


Prevention NoneResponse NoneStorage NoneDisposal None


NA






NA 60 - 100% Not classified




minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Under normal conditions, first aid procedures are not required.




Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting mediaExtinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical Special exposure hazards in a fireDecomposition in fire may produce harmful gases.


_____________________________________________________________________________________________Page 2 / 8



6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors.




7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothing beforereuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Product has a shelf life of 24 months.Other GuidelinesNo information available







Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Not normally needed. But if significant exposures are possible then the following respiratoris recommended:Dust/mist respirator. (N95, P2/P3)

Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system

_____________________________________________________________________________________________Page 3 / 8




Property Values Remarks/ - Method pH: 7.5Freezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.1Water Solubility Miscible with waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Oxides of nitrogen. Carbon monoxide and carbon dioxide.



Symptoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.





Physical State: Liquid Color Brown-blackOdor: Sweet Odor Threshold: No information available

_____________________________________________________________________________________________Page 4 / 8


Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact None known.Skin Contact None known.Ingestion None known.






Ecotoxicity















_____________________________________________________________________________________________Page 5 / 8



















EINECS (European Inventory ofExisting Chemical Substances)

This product, and all its components, complies with EINECS


Product contains one or more components not listed on the inventory.

_____________________________________________________________________________________________Page 6 / 8






Revision Date: 07-May-2018







_____________________________________________________________________________________________Page 7 / 8




_____________________________________________________________________________________________Page 8 / 8

SAFETY DATA SHEET

SCR-100L



1.1. Product Identifier Product Name SCR-100L


Recommended use of the chemical and restrictions on use Recommended Use RetarderUses Advised Against No information available











Hazard Pictograms


_____________________________________________________________________________________________Page 1 / 8


_____________________________________________________________________________________________



Prevention None

Response None

Storage None

Disposal None


NA










irritation develops or if breathing becomes difficult.Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.





_____________________________________________________________________________________________Page 2 / 8

Revision Date: 21-Sep-2015SCR-100L

_____________________________________________________________________________________________None known.

Specific hazards arising from the chemical Special Exposure HazardsDecomposition in fire may produce harmful gases.







7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Store in a dry location. Keep container closed when not in use.Other GuidelinesNo information available





Personal protective equipment (PPE) Respiratory Protection Not normally needed. But if significant exposures are possible then the following respirator

is recommended:Dust/mist respirator. (N95, P2/P3)


_____________________________________________________________________________________________Page 3 / 8

SCR-100L Revision Date: 21-Sep-2015

_____________________________________________________________________________________________



Property Values Remarks/ - Method pH: 3 - 4 (28%)Freezing Point/Range -4 °CMelting Point/Range No data availableBoiling Point/Range No data availableFlash Point > 93 °C / > 200 °F PMCCEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.16Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature 520 °CDecomposition Temperature No data availableViscosity 15-30 cP @ 25°CExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) ~60%Liquid Density 9.66


10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials Strong oxidizers.10.6. Hazardous Decomposition Products Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.







Contains no hazardoussubstances in


_____________________________________________________________________________________________Page 4 / 8

Odor Threshold: No information availablePhysical State: Liquid


Color: BlueOdor: Odorless

SCR-100L

_____________________________________________________________________________________________concentrations abovecut-off values accordingto the competentauthority

Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact May cause mild eye irritation.Skin Contact May cause mild skin irritation.Ingestion Irritation of the mouth, throat, and stomach.



Interactive effects Skin disorders.



NA Not applicable.


NA Not applicable.


NA Not applicable


NA Not applicable


NA Not applicable

Substances CAS Number Carcinogenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

_____________________________________________________________________________________________Page 5 / 8


_____________________________________________________________________________________________Substances CAS Number Reproductive toxicityContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable


NA Not applicable


NA Not applicable


NA Not applicable

















_____________________________________________________________________________________________Page 6 / 8


_____________________________________________________________________________________________12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors


Safe handling and disposal methods Bury in a licensed landfill or burn in an approved incinerator according to federal, state, and local regulations. Substance shouldNOT be deposited into a sewage facility.


















_____________________________________________________________________________________________Page 7 / 8


_____________________________________________________________________________________________








_____________________________________________________________________________________________Page 8 / 8


SAFETY DATA SHEET

WellLife™ 734



1.1. Product Identifier Product Name WellLife™ 734


Recommended use of the chemical and restrictions on use Recommended Use Cement EnhancerUses Advised Against No information available

Supplier's name, address and phone number Manufacturer/Supplier Halliburton/Baroid Australia Pty. Ltd.


ACN Number: 009 000 775Telephone Number: 61 (08) 9455 8300Fax Number: 61 (08) 9455 5300

Product Emergency TelephoneAustralia: + 61 1 800 686 951Papua New Guinea: + 61 1 800 686 951NewZealand: +64 800 451719

Fire, Police & Ambulance - Emergency TelephoneAustralia: 000Papua New Guinea: 000New Zealand: 111






_____________________________________________________________________________________________Page 1 / 7

Revision Number: 18Revision Date: 30-Sep-2015

_____________________________________________________________________________________________Classification of the hazardous chemical Not classified


Hazard Pictograms




Prevention None

Response None

Storage None

Disposal None


NA

Other hazards which do not result in classification This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).








Description of necessary first aid measures Inhalation Under normal conditions, first aid procedures are not required.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15

minutes and get medical attention if irritation persists.Skin Under normal conditions, first aid procedures are not required.Ingestion Under normal conditions, first aid procedures are not required.



_____________________________________________________________________________________________Page 2 / 7

WellLife™ 734 Revision Date: 30-Sep-2015

_____________________________________________________________________________________________






6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Ensure adequate ventilation. Avoid contact with skin,eyes and clothing.


6.3. Methods and material for containment and cleaning up Scoop up and remove.


7.1. Precautions for Safe Handling Handling PrecautionsMaterial is slippery underfoot. Keep floors clean of spills. Avoid creating or inhaling dust. Avoid dust accumulations. Ensureadequate ventilation. Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder contaminated clothing beforereuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a dry location. Product has a shelf life of 60 months.Other GuidelinesNo information available




Appropriate engineering controls Engineering Controls None known.

Personal protective equipment (PPE) Respiratory Protection Not normally necessary.

_____________________________________________________________________________________________Page 3 / 7


_____________________________________________________________________________________________




Property Values Remarks/ - Method pH: No data availableFreezing Point/Range 1200 °CMelting Point/Range No data availableBoiling Point/Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 2.6Water Solubility Insoluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) No data availableBulk Density 44 lbs/ft3 @ 20 C


10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials None known.10.6. Hazardous Decomposition Products None known.




_____________________________________________________________________________________________Page 4 / 7

Odor: Odorless


Odor Threshold: No information availablePhysical State: Solid Color: White to Variable

WellLife™ 734

_____________________________________________________________________________________________Numerical measures of toxicity





Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact May cause mechanical irritation to eye.Skin Contact None known.Ingestion None known.












Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according to


_____________________________________________________________________________________________Page 5 / 7

Revision Date: 30-Sep-2015WellLife™ 734

_____________________________________________________________________________________________the competent authority










Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations. Substance should NOT be deposited into a sewagefacility.












_____________________________________________________________________________________________Page 6 / 7


_____________________________________________________________________________________________Poisons Schedule number None Allocated













_____________________________________________________________________________________________Page 7 / 7

Revision Date: 30-Sep-2015WellLife™ 734

SAFETY DATA SHEET

CFR-3LRevision Date: 16-Sep-2016 Revision Number: 20



1.1. Product Identifier Product Name CFR-3L


Recommended use of the chemical and restrictions on use Recommended Use Friction ReducerUses advised against No information available










Hazard Pictograms


_____________________________________________________________________________________________Page 1 / 7

_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016





NA

Other hazards which do not result in classification None known









minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.




Suitable extinguishing equipment Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.Extinguishing media which must not be used for safety reasonsNone known.


Special protective equipment and precautions for fire fighters

_____________________________________________________________________________________________Page 2 / 7

Special protective equipment for firefighters


Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.




7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Store in a cool well ventilated area. Keep container closed when not in use.Other GuidelinesNo information available







Respiratory Protection Dust/mist respirator. (N95, P2/P3)Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions None known.Environmental Exposure Controls No information available



Property Values

Physical State: Liquid Color RedOdor: Musty Odor Threshold: No information available

_____________________________________________________________________________________________Page 3 / 7


Remarks/ - Method pH: 7Freezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point > 98 °C / > 210 °F PMCCEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.17Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Oxides of sulfur. Carbon monoxide and carbon dioxide.



Symptoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.






Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact Non-irritating to rabbit's eye

_____________________________________________________________________________________________Page 4 / 7


Skin Contact Not irritating to skin in rabbits.Ingestion None known.






Ecotoxicity
















_____________________________________________________________________________________________Page 5 / 7

Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors



Safe handling and disposal methods Bury in a licensed landfill or burn in an approved incinerator according to federal, state, and local regulations. Substance shouldNOT be deposited into a sewage facility.



















Poisons Schedule number

_____________________________________________________________________________________________Page 6 / 7

None Allocated


International Agreements Montreal Protocol - Ozone Depleting Substances: Does not applyStockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply












_____________________________________________________________________________________________Page 7 / 7

SAFETY DATA SHEET

HR-25LRevision Date: 09-Mar-2016 Revision Number: 30



1.1. Product Identifier Product Name HR-25L

Other means of Identification Synonyms NoneProduct Code: HM000893

Recommended use of the chemical and restrictions on use Recommended Use Cement RetarderUses advised against No information available









Classification of the hazardous chemical Serious Eye Damage/Irritation Category 1 - H318Acute Aquatic Toxicity Category 3 - H402


Hazard pictograms

_____________________________________________________________________________________________Page 1 / 8

_____________________________________________________________________________________________HR-25L Revision Date: 09-Mar-2016

Signal Word Danger

Hazard Statements H318 - Causes serious eye damageH402 - Harmful to aquatic life


Prevention P273 - Avoid release to the environmentP280 - Wear eye protection/face protection

Response P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician

Storage NoneDisposal P501 - Dispose of contents/container in accordance with

local/regional/national/international regulations

ContainsSubstances CAS NumberTartaric acid 87-69-4





Tartaric acid 87-69-4 30 - 60% Eye Corr. 1 (H318)Aquatic Acute 3 (H402)




water for at least 15 minutes and get medical attention immediately after flushing.Skin In case of contact, immediately flush skin with plenty of soap and water for at least

15 minutes. Get medical attention. Remove contaminated clothing and launderbefore reuse.

Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medicalattention.

Symptoms caused by exposure Causes severe eye irritation which may damage tissue.

_____________________________________________________________________________________________Page 2 / 8










6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Neutralize to pH of 6-8. Scoop up andremove.


7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from alkalis. Store away from oxidizers. Store in a cool well ventilated area. Keep container closed when not in use.Product has a shelf life of 60 months.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWATartaric acid 87-69-4 Not applicable Not applicable


_____________________________________________________________________________________________Page 3 / 8




Respiratory Protection Dust/mist respirator. (N95, P2/P3)Hand Protection Impervious rubber gloves.Skin Protection Rubber apron.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls Do not allow material to contaminate ground water system



Property Values Remarks/ - Method pH: 1.7Freezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range 103 °C / 219 °FFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.2Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers. Strong alkalis.10.6. Hazardous decomposition products Carbon monoxide and carbon dioxide.



Physical State: Liquid Color Light yellow-greenOdor: Odorless Odor Threshold:

_____________________________________________________________________________________________Page 4 / 8



Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue.




Tartaric acid 87-69-4 2000 - 5000 mg/kg (Rat) > 2000 mg/kg (Rat) No data available

Immediate, delayed and chronic health effects from exposure Product Information Under certain conditions of use, some of the product ingredients may cause the following:Inhalation May cause mild respiratory irritation.Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact May cause mild skin irritation.Ingestion Irritation of the mouth, throat, and stomach.





Substances CAS Number Skin corrosion/irritationTartaric acid 87-69-4 Non-irritating to the skin (Rabbit) (in vitro)

Substances CAS Number Serious eye damage/irritationTartaric acid 87-69-4 Causes severe eye irritation (Rabbit)

Substances CAS Number Skin SensitizationTartaric acid 87-69-4 Did not cause sensitization on laboratory animals (mouse)

Substances CAS Number Respiratory SensitizationTartaric acid 87-69-4 No information available

Substances CAS Number Mutagenic EffectsTartaric acid 87-69-4 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.

Substances CAS Number Carcinogenic EffectsTartaric acid 87-69-4 Did not show carcinogenic effects in animal experiments (Rat) (similar substances)

Substances CAS Number Reproductive toxicityTartaric acid 87-69-4 Did not show teratogenic effects in animal experiments.

Substances CAS Number STOT - single exposureTartaric acid 87-69-4 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number STOT - repeated exposureTartaric acid 87-69-4 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number Aspiration hazardTartaric acid 87-69-4 Not applicable

_____________________________________________________________________________________________Page 5 / 8






Tartaric acid 87-69-4 E(B)C50 2575.2 mg/L(Skeletonema costatum)

E(R)C50 1198 mg/L(Skeletonema costatum)

EC50 791.25 mg/L(Skeletonema costatum)

EC50 (72h) 51.4043 mg/L(Pseudokirchnerella

subcapitata)

LC50 250 mg/L(Scophthalmus maximus)LC50 (96h) > 100 mg/L

(Danio rerio)

EC50 (3h) > 1000 mg/L(Activated sludge)

TLM96 330-1000 ppm(Crangon crangon)

EC50 46.04 - 165.37mg/L (Ceriodaphnia

dubia)LC50 3753.85 (Acartia

tonsa)EC50 (48h) 93.313 mg/L

(Daphnia magna)

12.2. Persistence and degradability Readily biodegradableSubstances CAS Number Persistence and DegradabilityTartaric acid 87-69-4 Readily biodegradable (85% @ 28d)

12.3. Bioaccumulative potential Does not bioaccumulate.Substances CAS Number Log Pow

Tartaric acid 87-69-4 -1


Substances CAS Number MobilityTartaric acid 87-69-4 No information available



Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations. Incineration recommended in approvedincinerator according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.




Transportation Information UN Number Not restrictedUN proper shipping name Not restrictedTransport Hazard Class(es) Not applicablePacking Group: Not applicableEnvironmental Hazards Not applicable

_____________________________________________________________________________________________Page 6 / 8

Special precautions during transport


None






All components are listed on the AICS or are subject to a relevant exemption, permit, orassessment certificate.






International Agreements Montreal Protocol - Ozone Depleting Substances: Does not applyStolkhom Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply



Revision Date: 09-Mar-2016


Full text of H-Statements referred to under sections 2 and 3H318 - Causes serious eye damage



Key abreviations or acronyms used

_____________________________________________________________________________________________Page 7 / 8

bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per million


STEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day




_____________________________________________________________________________________________Page 8 / 8

SAFETY DATA SHEET

ECONOLITE LIQUIDRevision Date: 14-Oct-2015 Revision Number: 34



1.1. Product Identifier Product Name ECONOLITE LIQUID

Other means of Identification Synonyms NoneProduct Code: HM000478

Recommended use of the chemical and restrictions on use Recommended Use Light Weight Cement AdditiveUses advised against No information available









Classification of the hazardous chemical Skin Corrosion/Irritation Category 2 - H315Serious Eye Damage/Irritation Category 1 - H318


Hazard pictograms

_____________________________________________________________________________________________Page 1 / 8

_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 14-Oct-2015

Signal Word Danger

Hazard Statements H315 - Causes skin irritationH318 - Causes serious eye damage


Prevention P264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/eye protection/face protection

Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician

Storage NoneDisposal None

ContainsSubstances CAS NumberSodium silicate 1344-09-8





Sodium silicate 1344-09-8 30 - 60% Skin Irrit. 2 (H315)Eye Corr. 1 (H318)




water for at least 15 minutes and get medical attention immediately after flushing.Skin In case of contact, immediately flush skin with plenty of soap and water for at least

15 minutes. Get medical attention. Remove contaminated clothing and launderbefore reuse.

Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medicalattention.

Symptoms caused by exposure

_____________________________________________________________________________________________Page 2 / 8


Causes severe eye irritation which may damage tissue. Causes skin irritation.









6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Neutralize to pH of 6-8. Scoop up andremove. Do NOT spread spilled product with water.


7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Wash hands after use. Launder contaminated clothing before reuse. Avoid breathingvapors. Avoid breathing mist. Ensure adequate ventilation. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from acids. Store in a cool well ventilated area. Keep container closed when not in use.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWASodium silicate 1344-09-8 Not applicable Not applicable

Appropriate engineering controls Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without

_____________________________________________________________________________________________Page 3 / 8


good cross ventilation.



Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, direct contact(recommended: protection index 6, corresponding to > 480 minutes permeation time as perEN 374): (>= 0.4 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerably shorterthan the permeation time determined in accordance with EN 374 as a result of the manyinfluencing factors (e.g. temperature). If signs of wear and tear are noticed then the glovesshould be replaced. Manufacturer's directions for use should be observed because of greatdiversity of types.

Skin Protection Full protective chemical resistant clothing.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls Do not allow material to contaminate ground water system



Property Values Remarks/ - Method pH: 11.2Freezing Point / Range -1 °CMelting Point / Range No data availableBoiling Point / Range 101 °C / 214 °FFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.4Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.

Physical State: Liquid Color Clear to hazyOdor: Slightly soapy Odor Threshold: No information available

_____________________________________________________________________________________________Page 4 / 8


10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong acids. Amphoteric metals such as aluminum, magnesium, lead, tin, or zinc.10.6. Hazardous decomposition products Toxic fumes.



Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation.




Sodium silicate 1344-09-8 3400 mg/kg (Rat) > 5000 mg/kg (Rat) (similarsubstance)

> 2.06 mg/L (Rat) 4h (similarsubstance – Potassium silicate)

Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact Causes skin irritation.Ingestion Irritation of the mouth, throat, and stomach.





Substances CAS Number Skin corrosion/irritationSodium silicate 1344-09-8 Causes moderate skin irritation. (Rabbit)

Substances CAS Number Serious eye damage/irritationSodium silicate 1344-09-8 Causes severe eye irritation which may damage tissue. (Rabbit)

Substances CAS Number Skin SensitizationSodium silicate 1344-09-8 Did not cause sensitization on laboratory animals (mouse) (similar substances)

Substances CAS Number Respiratory SensitizationSodium silicate 1344-09-8 No information available

Substances CAS Number Mutagenic EffectsSodium silicate 1344-09-8 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.

Substances CAS Number Carcinogenic Effects

_____________________________________________________________________________________________Page 5 / 8


Sodium silicate 1344-09-8 No information available

Substances CAS Number Reproductive toxicitySodium silicate 1344-09-8 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal

experiments. (similar substances)

Substances CAS Number STOT - single exposureSodium silicate 1344-09-8 No information available.

Substances CAS Number STOT - repeated exposureSodium silicate 1344-09-8 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number Aspiration hazardSodium silicate 1344-09-8 Not applicable





Sodium silicate 1344-09-8 EC50 (72h) > 345 mg/L(growth rate)

(Scenedesmussubspicatus)

EC0 (72h) 35 mg/L(growth rate)

(Scenedesmussubspicatus)

LC50 (96h) 1108 mg/L(Danio rerio)

LC50 (96h) 260 – 310mg/L (Oncorhynchus

mykiss)

EC0 (0.5h) 3454 mg/L(Pseudomonas putida)

EC50 (48h) 1700 mg/L(Daphnia magna)


Substances CAS Number Persistence and DegradabilitySodium silicate 1344-09-8 The methods for determining biodegradability are




Sodium silicate 1344-09-8 No information available


Substances CAS Number MobilitySodium silicate 1344-09-8 No information available





_____________________________________________________________________________________________Page 6 / 8




Transportation Information UN Number Not restrictedUN proper shipping name Not restrictedTransport Hazard Class(es) Not applicablePacking Group: Not applicableEnvironmental Hazards Not applicable







All components are listed on the AICS or are subject to a relevant exemption, permit, orassessment certificate.





Poisons Schedule number S5

International Agreements Montreal Protocol - Ozone Depleting Substances: Does not applyStolkhom Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply



Revision Date: 14-Oct-2015


Full text of H-Statements referred to under sections 2 and 3H315 - Causes skin irritationH318 - Causes serious eye damage



_____________________________________________________________________________________________Page 7 / 8






_____________________________________________________________________________________________Page 8 / 8

SAFETY DATA SHEET

NF-6Revision Date: 16-Aug-2016 Revision Number: 28



1.1. Product Identifier Product Name NF-6


Recommended use of the chemical and restrictions on use Recommended Use DefoamerUses advised against No information available










Hazard Pictograms


_____________________________________________________________________________________________Page 1 / 8

_____________________________________________________________________________________________NF-6 Revision Date: 16-Aug-2016





NA










minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.




Suitable extinguishing equipment Suitable Extinguishing MediaCarbon dioxide, dry chemical, foam.Extinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical Special exposure hazards in a fireUse water spray to cool fire exposed surfaces. Decomposition in fire may produce harmful gases.

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Special protective equipment and precautions for fire fighters


Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.






7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Keep container closed when not in use.Other GuidelinesNo information available




Appropriate engineering controls Engineering Controls A well ventilated area to control dust levels. Local exhaust ventilation should be used in

areas without good cross ventilation.



Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Organic vapor respirator with a dust/mist filter. (A2P2/P3)

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, direct contact(recommended: protection index 6, corresponding to > 480 minutes permeation time as perEN 374): Polyvinylchloride gloves. (>= 0.7 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerably shorter

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than the permeation time determined in accordance with EN 374 as a result of the manyinfluencing factors (e.g. temperature). If signs of wear and tear are noticed then the glovesshould be replaced. Manufacturer's directions for use should be observed because of greatdiversity of types.

Skin Protection Normal work coveralls.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system



Property Values Remarks/ - Method pH: No data availableFreezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range 182 °C / 360 °FFlash Point > 170 °C / > 340 °FEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 0.93Water Solubility DispersibleSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature 385 °C / 725 °FDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Hydrocarbons. Carbon monoxide and carbon dioxide.



Symptoms related to exposure Most Important Symptoms/Effects

Physical State: Liquid Color YellowOdor: Mild Odor Threshold:

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No significant hazards expected.






Immediate, delayed and chronic health effects from exposure Product Information Under certain conditions of use, some of the product ingredients may cause the following:Inhalation May cause mild respiratory irritation.Eye Contact None known.Skin Contact None known.Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.






Ecotoxicity Product Ecotoxicity Data






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Safe handling and disposal methods Incineration recommended in approved incinerator according to federal, state, and local regulations. Substance should NOT bedeposited into a sewage facility.








_____________________________________________________________________________________________Page 6 / 8

Special precautions during transport


None












International Agreements Montreal Protocol - Ozone Depleting Substances: Does not applyStockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply



Revision Date: 16-Aug-2016





Key abreviations or acronyms used

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bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per million


STEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day

Key literature references and sources for datawww.ChemADVISOR.com/NZ CCIDCosmetic Ingredient Review



_____________________________________________________________________________________________Page 8 / 8

SAFETY DATA SHEET

TUNED SPACER E+Revision Date: 08-Jan-2019 Revision Number: 40



1.1. Product Identifier Product Name TUNED SPACER E+


Recommended use of the chemical and restrictions on use Recommended Use Cement SpacerUses advised against No information available








Classification of the hazardous chemical Carcinogenicity Category 1A - H350Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373


Hazard Pictograms

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_____________________________________________________________________________________________TUNED SPACER E+ Revision Date: 08-Jan-2019

Signal Word DANGER

Hazard Statements: H350 - May cause cancer by inhalationH373 - May cause damage to organs through prolonged or repeated exposure if inhaled


Prevention P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP281 - Use personal protective equipment as required

Response P308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell

Storage P405 - Store locked upDisposal P501 - Dispose of contents/container in accordance with

local/regional/national/international regulations

ContainsSubstances CAS NumberCrystalline silica, quartz 14808-60-7





Crystalline silica, quartz 14808-60-7 1 - 5% Carc. 1A (H350)STOT RE 1 (H372)




minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Under normal conditions, first aid procedures are not required.

Symptoms caused by exposure Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has alsobeen associated with scleroderma and kidney disease.


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6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust.

6.2. Environmental precautions None known.

6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated withcontaminating substances and use appropriate methods for collection, storage and disposal.


7.1. Precautions for safe handling Handling PrecautionsThis product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathingdust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits.Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery whenwet.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationUse good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Do not reuseempty container.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWACrystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3

Appropriate engineering controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures

below applicable exposure limits.

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Personal protective equipment (PPE)


Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, theselection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, orequivalent respirator when using this product.

Hand Protection Normal work gloves.Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be laundered

before reuse. Use precautionary measures to avoid creating dust when removing orlaundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls No information available



Property Values Remarks/ - Method pH: No data availableFreezing Point / Range No data availableMelting Point / Range No data availablePour Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.88 - 2.05Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Oxides of sulfur. Carbon monoxide and carbon dioxide. Amorphous silica may transform at elevated temperatures to tridymite (870C) or cristobalite (1470 C).

Physical State: Solid Color White to light strawOdor: Odorless Odor Threshold:

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Symptoms related to exposure Most Important Symptoms/EffectsBreathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has alsobeen associated with scleroderma and kidney disease.



Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No data available No data available

Immediate, delayed and chronic health effects from exposure Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is

carcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanent lungdamage may be occurring. Inhalation of dust may also have serious chronic health effects(See "Chronic Effects/Carcinogenicity" subsection below).

Eye Contact May cause mechanical irritation to eye.Skin Contact None known.Ingestion None known.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause aprogressive, disabling, and sometimes-fatal lung disease called silicosis.Symptoms include cough, shortness of breath, wheezing, non-specific chestillness, and reduced pulmonary function. This disease is exacerbated by smoking.Individuals with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (Group 2A - possible carcinogen tohumans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres(June 1997) in conjunction with the use of these minerals. The National ToxicologyProgram classifies respirable crystalline silica as "Known to be a humancarcinogen". Refer to the 9th Report on Carcinogens (2000). The AmericanConference of Governmental Industrial Hygienists (ACGIH) classifies crystallinesilica, quartz, as a suspected human carcinogen (A2). There is some evidencethat breathing respirable crystalline silica or the disease silicosis is associated withan increased incidence of significant disease endpoints such as scleroderma (animmune system disorder manifested by scarring of the lungs, skin, and otherinternal organs) and kidney disease.


Interactive effects Individuals with respiratory disease, including but not limited to asthma and bronchitis, or subject to eye irritation, should not beexposed to quartz dust.

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Substances CAS Number Skin corrosion/irritationCrystalline silica, quartz 14808-60-7 Non-irritating to the skin

Substances CAS Number Serious eye damage/irritationCrystalline silica, quartz 14808-60-7 Non-irritating to the eye No information available

Substances CAS Number Skin SensitizationCrystalline silica, quartz 14808-60-7 No information available.

Substances CAS Number Respiratory SensitizationCrystalline silica, quartz 14808-60-7 No information available

Substances CAS Number Mutagenic EffectsCrystalline silica, quartz 14808-60-7 Not regarded as mutagenic.

Substances CAS Number Carcinogenic EffectsCrystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The

IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure.

Substances CAS Number Reproductive toxicityCrystalline silica, quartz 14808-60-7 No information available

Substances CAS Number STOT - single exposureCrystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number STOT - repeated exposureCrystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)

Substances CAS Number Aspiration hazardCrystalline silica, quartz 14808-60-7 Not applicable


Ecotoxicity



Crystalline silica,quartz

14808-60-7 EC50(72 h)=440 mg/L(Pseudokirchneriella

subcapitata)

LL0(96 h)=10000 mg/L(Danio rerio)

No information available LL50(24 h)>10000 mg/L(Daphnia magna)

12.2. Persistence and degradability Expected to be readily biodegradableSubstances CAS Number Persistence and DegradabilityCrystalline silica, quartz 14808-60-7 The methods for determining biodegradability are



Substances CAS Number Bioaccumulation

Crystalline silica, quartz 14808-60-7 No information available


Substances CAS Number MobilityCrystalline silica, quartz 14808-60-7 No information available

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Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations.

















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Poisons Schedule number


None Allocated




Revision Date: 08-Jan-2019


Full text of H-Statements referred to under sections 2 and 3H350 - May cause cancer by inhalationH372 - Causes damage to organs through prolonged or repeated exposure if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled






_____________________________________________________________________________________________Page 8 / 9



_____________________________________________________________________________________________Page 9 / 9

SDS no. D901 Version 6 Revision date 08-Jun-2021 Supersedes Date: 13-Apr-2016

Safety Data Sheet Cement Class A D901

1. Identification of the substance/mixture and of the company/undertaking


Product name Cement Class A D901 Product code D901

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Used as a cementing additive in oilfield applications

Uses advised against Consumer use

1.3 Details of the supplier of the safety data sheet

1.4 Emergency Telephone Number

Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada 001 613 996 6666

2. Hazards Identification


GHS Classification

Health hazards Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Skin sensitization Category 1B Specific target organ toxicity - Single exposure Category 3

Environmental hazards Not classified

Physical Hazards Not classified

2.2 Label elements

SupplierSchlumberger Australia Pty Ltd ABN: 74 002 459 225 ACN: 002 459 225 Level 5, 10 Telethon Avenue Perth WA 6000

[email protected]

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_____________________________________________________________________________________________

Cement Class A D901 SDS no. D901 Revision date 08-Jun-2021

Signal wordDANGER

Hazard StatementsH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritation

Precautionary statements P271 - Use only outdoors or in a well-ventilated areaP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP310 - Immediately call a POISON CENTER or doctor/physician

Supplementary precautionary statements P261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP272 - Contaminated work clothing should not be allowed out of the workplaceP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

Contains Portland cement

2.3 Other hazards

Not classified as PBT/vPvB by current EU criteria

Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.


3.1 Substances

Chemical Name EC No CAS No Weight-% Portland cement 266-043-4 65997-15-1 60-100

3.2 Mixtures

Not applicable

4. First Aid Measures

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_____________________________________________________________________________________________


4.1 First aid measures

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.

Ingestion Rinse mouth. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if irritation persists.

Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.


General advice The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible.

Symptoms

Inhalation Please see Section 11. Toxicological Information for further information.

Ingestion Please see Section 11. Toxicological Information for further information.

Skin contact Please see Section 11. Toxicological Information for further information.

Eye contact Please see Section 11. Toxicological Information for further information.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. Fire-Fighting Measures


Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.

Extinguishing media which must not be used for safety reasonsNone known.


Unusual fire and explosion hazardsNone known.

Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors React with hydrofluoric acid (HF) forming toxic gas (SiF4).


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_____________________________________________________________________________________________


As in any fire, wear self-contained breathing apparatus and full protective gear.

Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.

6. Accidental Release Measures


Avoid contact with the skin and the eyes. Avoid dust formation. Use personal protective equipment. See also section 8.

6.2 Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and material for containment and cleaning up

Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry.

Methods for cleaning upDo not dry sweep dust. Wet dust with water before sweeping or use a vacuum to collect dust. Pick up and transfer to properly labeled containers. Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. After cleaning, flush away traces with water.

6.4 Reference to other sections


7. Handling and Storage


HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation. Persons susceptible to allergic reactions should not handle this product. May produce an allergic reaction.

Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Do not eat, drink or smoke when using this product Wash hands and face before breaks and immediately after handling the product Remove contaminated clothing


Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Provide appropriate exhaust ventilation at places where dust is formed.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid heat, flames and other sources of ignition. Protect from moisture Avoid contact with: Oxidizing agents Strong acids Aluminum Hydrofluoric acid (HF)

Storage class Chemical storage.

Packaging materials Use specially constructed containers only.

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_____________________________________________________________________________________________



Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.

Chemical Name Arabic Australia Egypt Portland cement 10 mg/m3 TWA 10mg/m3TWAinhalable dust Not determined Chemical Name India Indonesian Japan Portland cement 10 mg/m3 TWA 10 mg/m3 TWA 4 mg/m3 OEL

1 mg/m3 OEL Chemical Name Kazakhstan Kuwait New Zealand Portland cement Not determined 10.0 mg/m3 TWA

5.0 mg/m3 TWA 10 mg/m3 TWA

Chemical Name Malaysia Philippines Russia Portland cement 10 mg/m3 TWA Not determined Not determined Chemical Name Thailand Vietnam Turkey Portland cement Not determined Not determined Not determined

NotesNo biological limit allocated

8.2 Exposure controls

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation.

Engineering ControlsEnsure adequate ventilation Provide appropriate exhaust ventilation at places where dust is formed

Personal protective equipment Eye protection Use eye protection according to EN 166, designed to protect against dusts Safety glasses

with side-shields Tightly fitting safety goggles Hand protection Wear gloves according to EN 374 to protect against skin effects from powders

Impervious gloves made of: PVC disposable gloves Rubber gloves Frequent change is advisable

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Half mask with a particle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.

Skin and body protection Wear appropriate personal protective clothing to prevent skin contact Eye wash and emergency shower must be available at the work place.

Hygiene Measures Wash hands before breaks and immediately after handling the product Remove and wash contaminated clothing before re-use

8.2.3 Environmental exposure controls

Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for more information

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_____________________________________________________________________________________________



9.1 Information on basic physical and chemical properties

Appearance Powder Odor Odorless Color Gray or White

Density and/or Relative Density 2.75 - 3.20

Explosive properties Not applicable Oxidizing properties Not applicable

9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) No information available

CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.


10.1 Reactivity

React with hydrofluoric acid (HF) forming toxic gas (SiF4).


Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerizationHazardous polymerization does not occur.

Physical state Solid

Property Values Remarks pH Not applicable pH @ dilution 11 - 13 @10% sol Melting / freezing point > 1250 °C / 2282 °F Boiling point/range No information available Flash point Does not flash Evaporation rate (BuAc =1) Not applicable Flammability Not applicable Explosion limits:

Upper explosion limit No information available Lower explosion limit No information available

Vapor pressure No information available Relative Vapor Density No information available Specific gravity No information available Bulk density 0.9 - 1.5 g/cm³ Water solubility Slightly soluble in water. Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Partition Coefficient (n-octanol/water)


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_____________________________________________________________________________________________



Protect from moisture. Avoid dust formation. Avoid heat, flames and other sources of ignition.


Oxidizing agents. Hydrofluoric acid (HF). Strong acids. Aluminium.


See Section 5.2.


11.1 Information on toxicological effects Acute toxicity Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat and

cough. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Contact with moist mucous membranes of the respiratory system can cause caustic condition resulting in burns.

Eye contact Causes serious eye damage.

Skin contact Causes skin irritation. May cause an allergic skin reaction.

Ingestion Ingestion may cause irritation to mucous membranes.

Unknown acute toxicity Not applicable.


Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Portland cement No data available No data available No data available

Sensitization May cause allergic skin reaction.

Mutagenic effects This product does not contain any known or suspected mutagens.

Carcinogenicity This product does not contain any known or suspected carcinogens.

Reproductive toxicity This product does not contain any known or suspected reproductive hazards.

Routes of Exposure Skin contact. Inhalation. Eye contact.

Routes of entry Inhalation. Skin contact. Eye contact.

Specific target organ toxicity - Single exposure

Category 3

Specific target organ toxicity - Repeated exposure

Not classified.

Target organ effects Respiratory system. Lungs.


11.2 Information on other hazards

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_____________________________________________________________________________________________


Other information Key literature references and sources for data. See Section 16 for more information.


12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquatic organisms

Toxicity to algaeThis product is not considered toxic to algae.

Toxicity to fishThis product is not considered toxic to fish.

Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.

Toxicology data for the components Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other

aquatic invertebrates Portland cement No information available No information available No information available

12.2 Persistence and degradability

Not Applicable - Inorganic chemical.

12.3 Bioaccumulative potential


12.4 Mobility

MobilitySlightly soluble in water.



None known.

12.6 Other information.

Key literature references and sources for data. See Section 16 for more information.




Dispose of in accordance with local regulations.

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_____________________________________________________________________________________________


Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.


14.1. UN number Not regulated

14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods

14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated IMDG/ANTAQ Hazard class Not regulated ICAO/ANAC Hazard class/division Not regulated

14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated IMDG/ANTAQ Packing group Not regulated ICAO/ANAC Packing group Not regulated

14.5 Environmental hazard No

14.6 Special precautions None

14.7 Maritime transport in bulk according to IMO instruments Please contact [email protected] for info regarding transport in Bulk.



This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)

Australian Standard for the Uniform Scheduling of Drugs and Poisons Portland cement Schedule 4 Schedule 6 Schedule 5

Safe Work Australia.

Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).

Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG)

International inventories

USA (TSCA) Complies

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


Canada (DSL) Complies Philippines (PICCS) Complies Japan (ENCS) Complies China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Complies New Zealand (NZIoC) Complies Eurasian Economic Union: Russian Inventory

Complies

16. Other Information

Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam

Supersedes Date: 13-Apr-2016

Revision date 08-Jun-2021

Version 6

This SDS has been revised in the following section(s)

All sections No changes with regard to classification have been made.

Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits

HMIS classification

Health 3* Flammability 1 Physical hazard 0 PPE E

DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon on measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate agreement between the parties. This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.

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SDS no. D907Version 5Revision date 01-Aug-2018Supersedes Date: 05-Mar-2014

Safety Data SheetCement Class G D907



Product name Cement Class G D907Product code D907Country Limitations This SDS is not for use in the European Union (EU).






Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518



GHS Classification

Health hazardsSkin corrosion/irritation Category 2Serious eye damage/eye irritation Category 1Skin sensitization Sub-Category 1BSpecific target organ toxicity - Single exposure Category 3



SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424

[email protected]

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_____________________________________________________________________________________________

Cement Class G D907 SDS no. D907Revision date 01-Aug-2018

2.2 Label elements

Signal wordDANGER


Precautionary statements P261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician

Supplementary precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP362 - Take off contaminated clothing and wash before reuseP332 + P313 - If skin irritation occurs: Get medical advice/attentionP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

ContainsPortland Cement Clinker

2.3 Other hazards




3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC No CAS No Weight-%Portland Cement Clinker 266-043-4 65997-15-1 60-100

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_____________________________________________________________________________________________


CommentsThe product contains other ingredients which do not contribute to the overall classification.



Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.

Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation occurs.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention if irritation persists.

Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.


General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.

Symptoms













Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors React with hydrofluoric acid (HF) forming toxic gas(SiF4).

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_____________________________________________________________________________________________



Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.




Use personal protective equipment. See also section 8. Avoid dust formation. Avoid breathing dust; if exposed to high dustconcentration, leave area immediately. Avoid contact with the skin and the eyes.





Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading and keeppowder dry.

Methods for cleaning upDo not dry sweep dust. Wet dust with water before sweeping or use a vacuum to collect dust. Pick up and transfer to properlylabeled containers. Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. After cleaning, flushaway traces with water.





HandlingHandle in accordance with good industrial hygiene and safety practice. Do not breathe vapors/dust. Avoid contact with skin andeyes. Avoid handling causing generation of dust. Persons susceptible to allergic reactions should not handle this product.

Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing


Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dustis formed. Keep airborne concentrations below exposure limits.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Protect from moistureStore away from incompatibles, Powdered aluminum Acids Oxidizing agents Hydrofluoricacid (HF)

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_____________________________________________________________________________________________







No biological limit allocated


Chemical Name Arabic Australia EgyptPortland Cement Clinker 10 mg/m3 TWA 10 mg/m3 TWA Not determined

Chemical Name India Indonesian JapanPortland Cement Clinker 10 mg/m3 TWA 10 mg/m3 TWA 4 mg/m3 OEL

1 mg/m3 OELChemical Name Kazakhstan Kuwait New Zealand

Portland Cement Clinker Not determined Not determined 10 mg/m3 TWAChemical Name Malaysia Philippines Russia

Portland Cement Clinker 10 mg/m3 TWA Not determined Not determinedChemical Name Thailand Vietnam Turkey

Portland Cement Clinker Not determined Not determined Not determined


All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.


Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against powders and dusts

Tightly fitting safety goggles Safety glasses with side-shieldsHand protection Wear gloves according to EN 374 to protect against skin effects from powders Impervious

gloves made of: PVC disposable gloves Rubber gloves Frequent change is advisableRespiratory protection In case of insufficient ventilation wear suitable respiratory equipment Effective dust mask.

Type P2/P3 At work in confined or poorly ventilated spaces, respiratory protection with airsupply must be used.

Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.

Hygiene Measures Wash hands before breaks and immediately after handling the product Remove and washcontaminated clothing before re-use


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_____________________________________________________________________________________________


Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation



Appearance PowderOdor OdorlessColor Gray or WhiteOdor threshold Not applicable

Explosive properties Not applicableOxidizing properties Not applicable

9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) Not applicableDensity No information available



10.1 Reactivity





Property Values Remarks pH Not applicablepH @ dilution 11 - 13 @10% solMelting / freezing point > 1250 °C / 2282 °FBoiling point/range No information availableFlash point Not applicableEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air

Upper flammability limit Not applicableLower flammability limit Not applicable

Vapor pressure No information availableVapor density No information availableSpecific gravity ~ 3Bulk density 0.9 - 1.5 g/cm³Relative density 2.75 - 3.20Water solubility 0.1-1.5 g/L @ 20 °CSolubility in other solvents No information availableAutoignition temperature Not applicableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available

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_____________________________________________________________________________________________





Protect from moisture. Avoid dust formation.


Acids. Powdered aluminum. Strong oxidizing agents. Hydrofluoric acid (HF).


See Section 5.2.



Acute toxicity

Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Contactwith moist mucous membranes of the respiratory system can cause caustic conditionresulting in burns.






Chemical Name LD50 Oral LD50 Dermal LC50 InhalationPortland Cement Clinker No data available No data available No data available





Routes of exposure Skin contact. Inhalation. Eye contact.


Specific target organ toxicity -Single exposure

Category 3

Specific target organ toxicity - Not classified.

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_____________________________________________________________________________________________


Repeated exposure





12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganisms




Toxicology data for the componentsChemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other

aquatic invertebratesPortland Cement Clinker No information available No information available No information available



Chemical Name Persistence and degradabilityPortland Cement Clinker Inorganic compound



Chemical Name BioaccumulationPortland Cement Clinker Product/Substance is inorganic

12.4 Mobility

MobilitySlightly soluble in water.


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_____________________________________________________________________________________________


12.5 Results of PBT and vPvB assessment

Not classified as PBT/vPvB by current EU criteria.

12.6 Other adverse effects.

None known.

12.7 Other information Key literature references and sources for data. See Section 16 for more information.









14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated

14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated



14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.


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_____________________________________________________________________________________________


The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)

Australian Standard for the Uniform Scheduling of Drugs and Poisons

Portland Cement ClinkerSchedule 4Schedule 6Schedule 5New Zealand Hazard Classification Classified

HSNO approval no. 6.5B, 6.3A, 8.3A

Group number HSR002544

National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].

National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].

National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].



Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)

Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)


USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies


Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel

Supersedes Date: 05-Mar-2014

Revision date 01-Aug-2018

Version 5

This SDS has been revised in thefollowing section(s)


_____________________________________________________________________________________________

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_____________________________________________________________________________________________



HMIS classification

Health 3 *Flammability 1Physical hazard 0PPE E

DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.

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SDS no. D066Version 3Revision date 02-Mar-2020Supersedes Date: 13-Jul-2017

Safety Data SheetSilica Flour D66



Product name Silica Flour D66Product code D066






Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518Malaysian Local emergency number; +603 2161 7655



GHS Classification

Health hazardsSpecific target organ toxicity - Repeated exposure Category 2



2.2 Label elements


[email protected]

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_____________________________________________________________________________________________

Silica Flour D66 SDS no. D066Revision date 02-Mar-2020

Signal wordWARNING

Hazard StatementsH373 - May cause damage to organs through prolonged or repeated exposure

Precautionary statements P260 - Do not breathe dust/fume/gas/mist/vapors/sprayP314 - Get medical advice/attention if you feel unwellP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

ContainsQuartz, Crystalline silica

Respirable Crystalline Silica (Quartz)

2.3 Other hazards




3.1 Substances

Chemical Name EC No CAS No Weight-%Quartz, Crystalline silica 238-878-4 14808-60-7 60-100

Respirable Crystalline Silica (Quartz) 238-878-4 14808-60-7 <10

3.2 Mixtures

Not applicable

CommentsThis product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystallinesilica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis. IARC Monographs, Vol.68, 1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz or cristobalite fromoccupational sources causes cancer in humans. IARC Classification Group I.




Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.

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_____________________________________________________________________________________________


Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.

Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.



Symptoms












Unusual fire and explosion hazardsReact with hydrofluoric acid (HF) forming toxic gas (SiF4).

Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors






Use personal protective equipment. See also section 8.

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_____________________________________________________________________________________________






Methods for containmentCover powder spill with plastic sheet or tarp to minimize spreading. Prevent further leakage or spillage if safe to do so.

Methods for cleaning upAvoid dust formation. Sweep up and shovel into suitable containers for disposal. After cleaning, flush away traces with water.





HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.



Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid contact with:Hydrofluoric acid (HF) Strong oxidizing agents





Exposure limits No biological limit allocated


Chemical Name Arabic Australia EgyptQuartz, Crystalline silica 0.1 mg/m3 TWA 0.1mg/m3TWArespirable dust Not determined

Respirable Crystalline Silica(Quartz)

0.1 mg/m3 TWA 0.1mg/m3TWArespirable dust Not determined

Chemical Name India Indonesian JapanQuartz, Crystalline silica Not determined 0.1 mg/m3 TWA 0.03 mg/m3 OEL


Not determined 0.1 mg/m3 TWA 0.03 mg/m3 OEL

Chemical Name Kazakhstan Kuwait New ZealandQuartz, Crystalline silica 1 mg/m3 MAC 0.1 mg/m3 TWA 0.1 mg/m3 TWA

Confirmed carcinogen

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_____________________________________________________________________________________________



1 mg/m3 MAC 0.1 mg/m3 TWA 0.1 mg/m3 TWAConfirmed carcinogen

Chemical Name Malaysia Philippines RussiaQuartz, Crystalline silica 0.1 mg/m3 TWA Not determined 3 mg/m3 STEL

1 mg/m3 TWAFibrogenic substance 1177, 1178


0.1 mg/m3 TWA Not determined 3 mg/m3 STEL1 mg/m3 TWA

Fibrogenic substance 1177, 1178Chemical Name Thailand Vietnam Turkey

Quartz, Crystalline silica 0.025 mg/m3 TWA Not determined Not determinedRespirable Crystalline Silica

(Quartz)0.025 mg/m3 TWA Not determined Not determined



Engineering ControlsEnsure adequate ventilation Keep airborne concentrations below exposure limits

Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against dusts Safety glasses

with side-shields Tightly fitting safety gogglesHand protection Wear gloves according to EN 374 to protect against skin effects from powders Repeated or

prolonged contact Use protective gloves made of: Nitrile Neoprene gloves Frequent changeis advisable

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Suitable mask withparticle filter P3 (European Norm 143) At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.

Skin and body protection Wear appropriate personal protective clothing to prevent skin contact Eye wash andemergency shower must be available at the work place.

Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use





Appearance PowderOdor OdorlessColor Tan or White

Physical state

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Solid

_____________________________________________________________________________________________


Odor threshold Not applicable

Explosive properties Not applicableOxidizing properties None known.

9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) No information availableDensity No information available



10.1 Reactivity






Hazardous ReactionsNone known.


Avoid dust formation.

Property Values Remarks pH Not applicablepH @ dilution No information availableMelting / freezing point > 1700 °C / 3092 °FBoiling point/range No information availableFlash point Not applicableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 2.50 - 2.70 @20 °CBulk density 1100- 1600 kg/m3

Relative density No information availableWater solubility Insoluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available

_____________________________________________________________________________________________

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_____________________________________________________________________________________________



Hydrofluoric acid (HF). Strong oxidizing agents.


See Section 5.2.



Acute toxicity

Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough. May cause respiratory irritation. Repeated or prolonged inhalation of crystallinesilica dust can cause delayed lung injury, and other diseases, including silicosis and lungcancer.

Eye contact Dust may cause mechanical irritation.

Skin contact Repeated exposure may cause skin dryness or cracking.

Ingestion Ingestion may cause stomach discomfort.



Chemical Name LD50 Oral LD50 Dermal LC50 InhalationQuartz, Crystalline silica No data available No data available No data available

Respirable Crystalline Silica (Quartz) No data available No data available No data available

Sensitization This product does not contain any components suspected to be sensitizing.


Carcinogenicity Contains a known or suspected carcinogen. Crystalline silica dust is listed by IARC inGroup 1 as known to cause lung cancer in humans, if inhaled.


Routes of Exposure Inhalation. Skin contact. Eye contact.

Routes of entry Inhalation.


Not classified

Specific target organ toxicity -Repeated exposure

Category 2.




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_____________________________________________________________________________________________



12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.





aquatic invertebratesQuartz, Crystalline silica No information available No information available No information available


No information available No information available No information available



Chemical Name Persistence and degradabilityQuartz, Crystalline silica Inorganic compound



Chemical Name BioaccumulationQuartz, Crystalline silica Product/Substance is inorganic

12.4 Mobility

MobilityThe product is insoluble and sinks in water.

Chemical Name MobilityQuartz, Crystalline silica Insoluble in water


Chemical Name Mobility in soilQuartz, Crystalline silica Not expected to adsorb on soil

_____________________________________________________________________________________________

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_____________________________________________________________________________________________




None known.













14.6 Special precautions Not applicable




_____________________________________________________________________________________________

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This safety data sheet complies with the requirements of:

_____________________________________________________________________________________________



Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated












Supersedes Date: 13-Jul-2017

Revision date 02-Mar-2020

Version 3




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_____________________________________________________________________________________________


HMIS classification

Health 1*Flammability 1Physical hazard 0PPE E


_____________________________________________________________________________________________

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SDS no. B421Version 3Revision date 15-May-2020Supersedes Date: 12-Jan-2016

Safety Data SheetSlag Cement B421



Product name Slag Cement B421Product code B421Country Limitations This SDS is not for use in the European Union (EU).






Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518Malaysian Local emergency number; +603 2161 7655



GHS Classification

Health hazardsSkin corrosion/irritation Category 2Serious eye damage/eye irritation Category 1Skin sensitization Category 1Specific target organ toxicity - Single exposure Category 3




[email protected]

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_____________________________________________________________________________________________

Slag Cement B421 SDS no. B421Revision date 15-May-2020

2.2 Label elements

Signal wordDANGER


Precautionary statements P261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician

Supplementary precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP332 + P313 - If skin irritation occurs: Get medical advice/attentionP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

ContainsBlast furnace slag

Portland cement

Quartz, Crystalline silica

2.3 Other hazards




3.1 Substances

Not applicable

3.2 Mixtures

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_____________________________________________________________________________________________


Chemical Name EC No CAS No Weight-%Blast furnace slag 266-002-0 65996-69-2 60-100Portland cement 266-043-4 65997-15-1 30-60

Quartz, Crystalline silica 238-878-4 14808-60-7 <1

CommentsThis product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystallinesilica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis.IARC Monographs, Vol. 68, 1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz orcristobalite from occupational sources causes cancer in humans. IARC Classification Group I.





Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.

Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get immediate medical attention.



Symptoms









Suitable extinguishing mediaThe product itself does not burn, Use extinguishing media appropriate for surrounding material.


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_____________________________________________________________________________________________


Unusual fire and explosion hazardsReact with hydrofluoric acid (HF) forming toxic gas (SiF4).







Use personal protective equipment. See also section 8. Avoid breathing dust; if exposed to high dust concentration, leave areaimmediately. Avoid contact with the skin and the eyes.


The product should not be allowed to enter drains, water courses or the soil. Prevent entry into sewage.




Methods for cleaning upDo not dry sweep dust. Wet dust with water before sweeping or use a vacuum to collect dust. Pick up and transfer to properlylabeled containers. Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. After cleaning, flushaway traces with water.





HandlingHandle in accordance with good industrial hygiene and safety practice. Do not breathe vapors/dust. Avoid contact with skin andeyes. Avoid handling causing generation of dust. Persons susceptible to allergic reactions should not handle this product.

Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately afterhandling the product Remove contaminated clothing Do not eat, drink or smoke when using this product


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_____________________________________________________________________________________________


Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dustis formed. Keep airborne concentrations below exposure limits.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Protect from moistureStore away from incompatibles, Acids Strong oxidizing agents Hydrofluoric acid (HF)


Packaging materials Use specially constructed containers only. Bag with moisture barrier






Chemical Name Arabic Australia EgyptBlast furnace slag Not determined Not determined Not determinedPortland cement 10 mg/m3 TWA 10mg/m3TWAinhalable dust Not determined

Quartz, Crystalline silica 0.1 mg/m3 TWA 0.1mg/m3TWArespirable dust Not determinedChemical Name India Indonesian JapanBlast furnace slag Not determined Not determined Not determinedPortland cement 10 mg/m3 TWA 10 mg/m3 TWA 4 mg/m3 OEL

1 mg/m3 OELQuartz, Crystalline silica Not determined 0.1 mg/m3 TWA 0.03 mg/m3 OEL

Chemical Name Kazakhstan Kuwait New ZealandBlast furnace slag Not determined Not determined Not determinedPortland cement Not determined 10.0 mg/m3 TWA

5.0 mg/m3 TWA10 mg/m3 TWA

Quartz, Crystalline silica 1 mg/m3 MAC 0.1 mg/m3 TWA 0.1 mg/m3 TWAConfirmed carcinogen

Chemical Name Malaysia Philippines RussiaBlast furnace slag Not determined Not determined Not determinedPortland cement 10 mg/m3 TWA Not determined Not determined

Quartz, Crystalline silica 0.1 mg/m3 TWA Not determined 3 mg/m3 STEL1 mg/m3 TWA

Fibrogenic substance 1177, 1178Chemical Name Thailand Vietnam TurkeyBlast furnace slag Not determined Not determined Not determinedPortland cement Not determined Not determined Not determined

Quartz, Crystalline silica 0.025 mg/m3 TWA Not determined Not determined





Tightly fitting safety goggles Safety glasses with side-shields

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_____________________________________________________________________________________________


Hand protection Wear gloves according to EN 374 to protect against skin effects from powders Imperviousgloves made of: PVC disposable gloves Rubber gloves Frequent change is advisable

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Effective dust mask.Type P2/P3 At work in confined or poorly ventilated spaces, respiratory protection with airsupply must be used.







Appearance PowderOdor NoneColor GrayOdor threshold Not applicable

Explosive properties No information availableOxidizing properties No information available


Property Values Remarks pH No information availablepH @ dilution No information availableMelting / freezing point No information availableBoiling point/range No information availableFlash point Not applicableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity No information availableBulk density No information availableRelative density 3.0 - 3.1Water solubility Miscible with water.Solubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available

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_____________________________________________________________________________________________





10.1 Reactivity







Protect from moisture.


Acids. Strong oxidizing agents. Hydrofluoric acid (HF).


See Section 5.2.



Acute toxicity

Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Contactwith moist mucous membranes of the respiratory system can cause caustic conditionresulting in burns.






Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

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_____________________________________________________________________________________________


Blast furnace slag No data available No data available No data availablePortland cement No data available No data available No data available

Quartz, Crystalline silica No data available No data available No data available



Carcinogenicity Crystalline silica dust is listed by IARC in Group 1 as known to cause lung cancer inhumans, if inhaled.


Routes of Exposure Skin contact. Eye contact. Inhalation.

Routes of entry Inhalation. Eye contact. Skin contact.


Category 3


Not classified.





12.1 Toxicity






aquatic invertebratesBlast furnace slag No information available No information available No information availablePortland cement No information available No information available No information available

Quartz, Crystalline silica No information available No information available No information available



Chemical Name Persistence and degradability

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


Quartz, Crystalline silica Inorganic compound



Chemical Name BioaccumulationQuartz, Crystalline silica Product/Substance is inorganic

12.4 Mobility

MobilityThe product is miscible with water. May spread in water systems.

Chemical Name MobilityQuartz, Crystalline silica Insoluble in water


Chemical Name Mobility in soilQuartz, Crystalline silica Not expected to adsorb on soil




None known.









14.2. UN proper shipping name

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The product is not covered by international regulation on the transport of dangerous goods

_____________________________________________________________________________________________











Blast furnace slagSchedule 4Schedule 6Schedule 5Portland cementSchedule 4Schedule 6Schedule 5







_____________________________________________________________________________________________

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_____________________________________________________________________________________________



USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) Does not complyChina (IECSC) Does not complyAustralia (AICS) CompliesKorean (KECL) Does not complyNew Zealand (NZIoC) Complies

This SDS is not for use in the European Union (EU).



Supersedes Date: 12-Jan-2016

Revision date 15-May-2020

Version 3





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SDS no. D031Version 3Revision date 29-Aug-2018Supersedes Date: 29-Jul-2015

Safety Data SheetBARITE 4,1 D31



Product name BARITE 4,1 D31Product code D031


Recommended Use Weighting agent. Used as a cementing additive in oilfield applications







GHS Classification

Health hazards Not classified



2.2 Label elements

Signal wordNone


[email protected]

_____________________________________________________________________________________________

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_____________________________________________________________________________________________

BARITE 4,1 D31 SDS no. D031Revision date 29-Aug-2018

Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.

Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.

ContainsCrystalline silica (impurity)

2.3 Other hazards


Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.


3.1 Substances

Chemical Name EC No CAS No Weight-%Crystalline silica (impurity) 238-878-4 14808-60-7 <5

3.2 Mixtures

Not applicable


This product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystallinesilica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis.

IARC Monographs, Vol. 68, 1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz orcristobalite from occupational sources causes cancer in humans. IARC Classification Group I.






Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.



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Symptoms













Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx).











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Methods for cleaning upAvoid generating or breathing dust. Take up mechanically and collect in suitable container for disposal. After cleaning, flush awaytraces with water.





HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid dust formation. Do not breathe dust. Avoid contactwith skin and eyes.



Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Provideappropriate exhaust ventilation at places where dust is formed.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid extremetemperatures Store away from incompatibles, Hydrofluoric acid (HF) Strong oxidizingagents








Chemical Name Arabic Australia EgyptCrystalline silica (impurity) 0.1 mg/m3 TWA 0.1mg/m3TWArespirable dust Not determined

Chemical Name India Indonesian JapanCrystalline silica (impurity) Not determined 0.1 mg/m3 TWA Not determined

Chemical Name Kazakhstan Kuwait New ZealandCrystalline silica (impurity) 1 mg/m3 MAC Not determined 0.1 mg/m3 TWA

Confirmed carcinogenChemical Name Malaysia Philippines Russia

Crystalline silica (impurity) 0.1 mg/m3 TWA Not determined 3 mg/m3 STEL1 mg/m3 TWA

Fibrogenic substanceglass;regulated under Quartz 1123,

1124Chemical Name Thailand Vietnam Turkey

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Crystalline silica (impurity) 0.025 mg/m3 TWA Not determined Not determined



Engineering ControlsEnsure adequate ventilation Mechanical ventilation or local exhaust ventilation is required.

Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against dusts Tightly fitting

safety goggles Safety glasses with side-shieldsHand protection Wear gloves according to EN 374 to protect against skin effects from powders Impervious

gloves made of: Rubber Nitrile Neoprene gloves Frequent change is advisableRespiratory protection Use the indicated respiratory protection if the occupational exposure limit is exceeded

and/or in case of product release (dust) Half mask with a particle filter P2 (European NormEN 143 = former DIN 3181) At work in confined or poorly ventilated spaces, respiratoryprotection with air supply must be used.







Appearance PowderOdor OdorlessColor Light tan - Light grayOdor threshold Not applicable


Property Values Remarks pH Not applicablepH @ dilution No information availableMelting / freezing point No information availableBoiling point/range No information availableFlash point Not applicableEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air

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9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information available



10.1 Reactivity

No specific reactivity hazards associated with this product.






Avoid extreme temperatures. Avoid dust formation.


Hydrofluoric acid (HF). Strong oxidizing agents.


See Section 5.2.



Acute toxicity


Vapor pressure Not applicableVapor density Not applicableSpecific gravity 4.1Bulk density No information availableRelative density No information availableWater solubility Insoluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available

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Product information This product contains a small quantity of quartz, crystalline silica. Prolonged and repeatedexposure to concentrations of crystalline silica exceeding the workplace exposure limit(WEL) may lead to chronic lung disease such as silicosis.

Inhalation Inhalation of dust in high concentration may cause irritation of respiratory system.


Skin contact Prolonged contact may cause redness and irritation.




Chemical Name LD50 Oral LD50 Dermal LC50 InhalationCrystalline silica (impurity) = 500 mg/kg ( Rat ) No data available No data available



Carcinogenicity Contains a known or suspected carcinogen. Crystalline silica dust is listed by IARC inGroup 1 as known to cause lung cancer in humans, if inhaled.


Routes of exposure Inhalation. Skin contact. Eye contact.



Not classified


Not classified.




12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Listed on PLONOR list of OSPAR


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aquatic invertebratesCrystalline silica (impurity) LC50 Danio rerio (zebra fish) : >

10000 mg/l 96hEC50: > 1000 mg/l 72h LC50 Daphnia manga (Water flea):

> 10000 mg/l 24h



Chemical Name Persistence and degradabilityCrystalline silica (impurity) Inorganic compound



Chemical Name BioaccumulationCrystalline silica (impurity) Product/Substance is inorganic

12.4 Mobility

MobilityInsoluble in water.

Chemical Name MobilityCrystalline silica (impurity) Insoluble in water


Chemical Name Mobility in soilCrystalline silica (impurity) Not expected to adsorb on soil




None known.



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Version 3




HMIS classification

Health 1*Flammability 0Physical hazard 0PPE E

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SDS no. D020Version 6Revision date 11-Oct-2018Supersedes Date: 19-Oct-2015

Safety Data SheetBentonite Extender D20



Product name Bentonite Extender D20Product code D020









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

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Bentonite Extender D20 SDS no. D020Revision date 11-Oct-2018



ContainsCrystalline silica (impurity)

2.3 Other hazards

Not classified as PBT/vPvB by current EU criteriaProduct dust may be irritating to eyes, skin and respiratory system



3.1 Substances

3.2 Mixtures

Not applicableChemical Name EC No CAS No Weight-%

Crystalline silica (impurity) 238-878-4 14808-60-7 1-5

CommentsNaturally occuring mineral.This product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystallinesilica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis. IARC Monographs, Vol.68, 1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz or cristobalite fromoccupational sources causes cancer in humans. IARC Classification Group I.

The product contains other ingredients which do not contribute to the overall classification.






Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if any discomfort continues.



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Symptoms










Extinguishing media which must not be used for safety reasonsDo not use water jet.



Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors Nitrogen oxides (NOx).






Use personal protective equipment. See also section 8. Material becomes slippery when wet. Use caution if wet.





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Methods for cleaning upSweep up and shovel into suitable containers for disposal. After cleaning, flush away traces with water.





HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.Material becomes slippery when wet. Use caution if wet.




Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid wet and humidconditions.





Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.No biological limit allocated


Chemical Name Arabic Australia EgyptCrystalline silica (impurity) 0.1 mg/m3 TWA 0.1mg/m3TWArespirable dust Not determined

Chemical Name India Indonesian JapanCrystalline silica (impurity) Not determined 0.1 mg/m3 TWA Not determined

Chemical Name Kazakhstan Kuwait New ZealandCrystalline silica (impurity) 1 mg/m3 MAC Not determined 0.1 mg/m3 TWA

Confirmed carcinogenChemical Name Malaysia Philippines Russia

Crystalline silica (impurity) 0.1 mg/m3 TWA Not determined 3 mg/m3 STEL1 mg/m3 TWA

Fibrogenic substanceglass;regulated under Quartz 1123,

1124Chemical Name Thailand Vietnam Turkey

Crystalline silica (impurity) 0.025 mg/m3 TWA Not determined Not determined

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Tightly fitting safety goggles Safety glasses with side-shieldsHand protection Wear gloves according to EN 374 to protect against skin effects from powders

Use protective gloves made of: Neoprene NitrileFrequent change is advisable

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Suitable mask withparticle filter P3 (European Norm 143) At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.







Appearance PowderOdor OdorlessColor Cream - GrayOdor threshold Not applicable


Property Values Remarks pH 9-10pH @ dilution No information availableMelting / freezing point > 450 °C / 842 °FBoiling point/range No information availableFlash point Not applicableEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure No information availableVapor density No information available

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10.1 Reactivity







Avoid wet and humid conditions. Avoid dust formation.


No materials to be especially mentioned.


See Section 5.



Acute toxicity

Product information This product contains a small quantity of quartz, crystalline silica. Prolonged and repeatedexposure to concentrations of crystalline silica exceeding the workplace exposure limit(WEL) may lead to chronic lung disease such as silicosis.

Specific gravity 2.3 - 2.6 20 °CBulk density 750 – 950 kg/m³Relative density No information availableWater solubility Insoluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature > 500 °C / 932°FKinematic viscosity Not applicableDynamic viscosity . Not applicablelog Pow No information available

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Chemical Name LD50 Oral LD50 Dermal LC50 InhalationCrystalline silica (impurity) = 500 mg/kg ( Rat ) No data available No data available



Carcinogenicity Crystalline silica dust is listed by IARC in Group 1 as known to cause lung cancer inhumans, if inhaled.


Routes of exposure Inhalation.



Not classified


Not classified.




12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.Listed on PLONOR list of OSPAR





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aquatic invertebratesCrystalline silica (impurity) LC50 Danio rerio (zebra fish) : >

10000 mg/l 96hEC50: > 1000 mg/l 72h LC50 Daphnia manga (Water flea):

> 10000 mg/l 24h



Chemical Name Persistence and degradabilityCrystalline silica (impurity) Inorganic compound



Chemical Name BioaccumulationCrystalline silica (impurity) Product/Substance is inorganic

12.4 Mobility

MobilityInsoluble in water.

Chemical Name MobilityCrystalline silica (impurity) Insoluble in water

Mobility in soilSee component information below.

Chemical Name Mobility in soilCrystalline silica (impurity) Not expected to adsorb on soil




None known.







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Supersedes Date: 19-Oct-2015

Revision date 11-Oct-2018

Version 6





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SDS no. D600G Version 4 Revision date 26-Apr-2021 Supersedes Date: 15-Jul-2016

Safety Data Sheet D600G GASBLOK* Gas Migration Control Additive



Product name D600G GASBLOK* Gas Migration Control Additive Product code D600G


Recommended Use Gas control agent Used as a cementing additive in oilfield applications







GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

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D600G GASBLOK* Gas Migration Control Additive

SDS no. D600G Revision date 26-Apr-2021



Contains C12-15 alcohol ethyoxylated

Sodium dodecyl sulphate

1,4-Dioxane (Impurity)

5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one

2.3 Other hazards




3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC No CAS No Weight-% C12-15 alcohol ethyoxylated 500-195-7 68131-39-5 1-<5

Sodium dodecyl sulphate 205-788-1 151-21-3 >= 0.1 - <0.3 1,4-Dioxane (Impurity) 204-661-8 123-91-1 <=0.1


mixture 55965-84-9 < 0.0015





Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Seek medical attention if irritation occurs.

Skin contact Wash off immediately with soap and plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.


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Symptoms









Suitable extinguishing mediaWater spray, dry chemical, carbon dioxide (CO2), or foam.

Extinguishing media which must not be used for safety reasonsHigh volume water jet.


Unusual fire and explosion hazardsHeating of containers may cause pressure rise, with risk of bursting.

Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Sulphur oxides, Sodium oxides.









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Environmental exposure controls

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Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.


Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.

Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush away traces with water.





HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Avoid spills and splashing during use. Repeated or prolonged contact may cause allergic reactions in very susceptible persons. Persons susceptible to allergic reactions should not handle this product.

Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and face before breaks and immediately after handling the product Remove contaminated clothing



Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Store away from heat and sources of ignition Avoid frost. Incompatible with materials which react with water. Avoid contact with: Strong acids Strong bases Strong oxidizing agents Strong reducing agents





Exposure limits No biological limit allocated


Chemical Name Arabic Australia Egypt C12-15 alcohol ethyoxylated Not determined Not determined Not determined

Sodium dodecyl sulphate Not determined Not determined Not determined 1,4-Dioxane (Impurity) 90 ppm STEL

135 mg/m3 STEL 25 ppm TWA

90 mg/m3 TWA

10ppmTWA 36mg/m3TWA

Skin designation Suspected Human Carcinogen

20 ppm TWA 72 mg/m3 TWA

5-chloro-2-methyl-4-isothiazolin-3-one and

2-methyl-4-isothiazolin-3-one

Not determined Not determined Not determined

Chemical Name India Indonesian Japan

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C12-15 alcohol ethyoxylated Not determined Not determined Not determined Sodium dodecyl sulphate Not determined Not determined Not determined

1,4-Dioxane (Impurity) Not determined 20 ppm TWA 90 mg/m3 TWA Skin notation

May cause substantial skin absorption

10 ppm ACL 1 ppm OEL

3.6 mg/m3 OEL 5-chloro-2-methyl-4-isothiazolin-3-o

ne and 2-methyl-4-isothiazolin-3-one


Chemical Name Kazakhstan Kuwait New Zealand C12-15 alcohol ethyoxylated Not determined Not determined Not determined

Sodium dodecyl sulphate Not determined Not determined Not determined 1,4-Dioxane (Impurity) 10 mg/m3 MAC 90.0 mg/m3 TWA

25.0 ppm TWA Skin notation

3.6 mg/m3 STEL


Confirmed carcinogen Possibility of significant uptake

through the skin 5-chloro-2-methyl-4-isothiazolin-3-o



Chemical Name Malaysia Philippines Russia C12-15 alcohol ethyoxylated Not determined Not determined Not determined

Sodium dodecyl sulphate Not determined Not determined Not determined 1,4-Dioxane (Impurity) 20 ppm TWA

72.1 mg/m3 TWA Skin notation

skin - potential for cutaneous absorption


Skin notation 10 mg/m3 MAC

Skin




Chemical Name Thailand Vietnam Turkey C12-15 alcohol ethyoxylated Not determined Not determined Not determined

Sodium dodecyl sulphate Not determined Not determined Not determined 1,4-Dioxane (Impurity) 100 ppm TWA 10 mg/m3 TWA 20 ppm TWA

73 mg/m3 TWA 5-chloro-2-methyl-4-isothiazolin-3-o






Personal protective equipment Eye protection Eye protection must conform to standard EN 166 Tightly fitting safety goggles Safety

glasses with side-shields Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee

training Use protective gloves made of: Neoprene Nitrile PVC Be aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection No personal respiratory protective equipment normally required In case of insufficient ventilation wear suitable respiratory equipment Respirator with combination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.

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Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at the work place.

Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothing before re-use





Appearance Viscous Odor Slight Color Milky white

Density and/or Relative Density No information available

Explosive properties No information available Oxidizing properties No information available

9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) No information available

Physical state Liquid

Property Values Remarks pH 6 - 8 pH @ dilution No information available Melting / freezing point No information available Boiling point/range 100 °C / 212 °F Flash point > 100 °C / > 212 °F Closed cup Evaporation rate (BuAc =1) No information available Flammability Not applicable Explosion limits:

Upper explosion limit 12.60 %(V) Lower explosion limit 2.60 %(V)

Vapor pressure < 23.5 mmgHg (31.33 hPa) @ 25 °C Relative Vapor Density No information available Specific gravity 1.01 - 1.02 @ 20 °C Bulk density No information available Water solubility Dispersible Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Partition Coefficient (n-octanol/water)


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10.1 Reactivity







Do not freeze. Store away from heat and sources of ignition.


Incompatible with materials which react with water. Strong acids. Strong bases. Strong oxidizing agents. Strong reducing agents.


See Section 5.2.


11.1 Information on toxicological effects Acute toxicity Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.

Eye contact May cause slight irritation.





Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation C12-15 alcohol ethyoxylated 2.500- 5.000 mg/kg = 2500 mg/kg ( Rabbit ) No data available

Sodium dodecyl sulphate = 1288 mg/kg ( Rat ) = 200 mg/kg ( Rabbit ) > 3900 mg/m3 ( Rat ) 1 h 1,4-Dioxane (Impurity) = 4200 mg/kg ( Rat ) = 5170

mg/kg ( Rat ) = 7600 mg/kg ( Rabbit ) = 46 mg/L ( Rat ) 2 h


= 53 mg/kg ( Rat ) No data available = 1.23 mg/L ( Rat ) 4 h = 0.11 mg/L ( Rat ) 4 h

Sensitization EUH208 - Contains ( 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one ). May produce an allergic reaction.

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Carcinogenicity Contains a known or suspected carcinogen.



Routes of entry Skin contact.


Not classified


Not classified.





12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Toxicity to algaeSee component information below.

Toxicity to fishSee component information below.

Toxicity to daphnia and other aquatic invertebratesSee component information below.


aquatic invertebrates C12-15 alcohol ethyoxylated 3.1 mg/L LC50 (Scophthalmus

maximus) = 96 h 1 - 3.2 mg/L EC50 (Skeletonema

costatum) = 72 h 0.88 mg/L LC50 (Acartia tonsa) = 48

h

Sodium dodecyl sulphate = 1.31 mg/L LC50 Cyprinus carpio 96 h 10.8 - 16.6 mg/L LC50 Poecilia

reticulata 96 h 13.5 - 18.3 mg/L LC50 Poecilia reticulata 96 h 6.2 -

9.6 mg/L LC50 Pimephales promelas 96 h 10.2 - 22.5 mg/L

LC50 Pimephales promelas 96 h 5.8 - 7.5 mg/L LC50 Pimephales promelas 96 h = 4.5 mg/L LC50

Lepomis macrochirus 96 h 4.2 - 4.8 mg/L LC50 Lepomis macrochirus 96

h 4.06 - 5.75 mg/L LC50 Lepomis macrochirus 96 h 9.9 - 20.1 mg/L

LC50 Brachydanio rerio 96 h = 7.97 mg/L LC50 Brachydanio rerio 96 h =

4.2 mg/L LC50 Oncorhynchus mykiss 96 h = 4.62 mg/L LC50

Oncorhynchus mykiss 96 h 4.3 - 8.5

= 42 mg/L EC50 Desmodesmus subspicatus 96 h = 117 mg/L EC50 Pseudokirchneriella subcapitata 96 h = 53 mg/L EC50 Desmodesmus subspicatus 72 h 30 - 100 mg/L

EC50 Desmodesmus subspicatus 96 h 3.59 - 15.6 mg/L EC50

Pseudokirchneriella subcapitata 96 h

= 1.8 mg/L EC50 Daphnia magna 48 h = 21.2 mg/L EC50 Daphnia

magna 24 h

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mg/L LC50 Oncorhynchus mykiss 96 h 22.1 - 22.8 mg/L LC50

Pimephales promelas 96 h 15 - 18.9 mg/L LC50 Pimephales promelas

96 h 8 - 12.5 mg/L LC50 Pimephales promelas 96 h = 4.1 mg/L LC50 Leuciscus idus 48 h

1,4-Dioxane (Impurity) = 9850 mg/L LC50 Pimephales promelas 96 h 10306 - 14742 mg/L LC50 Pimephales promelas 96 h >

10000 mg/L LC50 Lepomis macrochirus 96 h

No information available = 163 mg/L EC50 water flea 48 h



= 1.6 mg/L LC50 Oncorhynchus mykiss 96 h

0.11 - 0.16 mg/L EC50 Pseudokirchneriella subcapitata 72

h 0.03 - 0.13 mg/L EC50 Pseudokirchneriella subcapitata 96

h = 0.31 mg/L EC50 Anabaena flos-aquae 120 h

0.12 - 0.3 mg/L EC50 Daphnia magna 48 h 0.71 - 0.99 mg/L EC50 Daphnia magna 48 h = 4.71 mg/L

EC50 Daphnia magna 48 h


See component information below.

Chemical Name Persistence and degradability C12-15 alcohol ethyoxylated Readily degradable in marine screening test


See component information below.

Chemical Name Bioaccumulation C12-15 alcohol ethyoxylated Not likely to bioaccumulate

12.4 Mobility

MobilityDispersible in water. See component information below.

Chemical Name Mobility C12-15 alcohol ethyoxylated Soluble in water


Chemical Name Mobility in soil C12-15 alcohol ethyoxylated No information available


None known. Check for additional information in sect. 7.







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Marine pollutantNo






Australian Standard for the Uniform Scheduling of Drugs and Poisons 1,4-Dioxane (Impurity) Schedule 6 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one Schedule 6

New Zealand Hazard Classification Not classified

HSNO approval no. Not required

Group number Not required


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Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013 [P.U.(A) 310/2013] (CLASS Regulations) The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)


USA (TSCA) Complies Canada (DSL) Does not comply Philippines (PICCS) Does not comply Japan (ENCS) Does not comply China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Does not comply New Zealand (NZIoC) Complies Eurasian Economic Union: Russian Inventory

Complies




Revision date 26-Apr-2021

Version 4




HMIS classification

Health 1 Flammability 1 Physical hazard 0 PPE B

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DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon on measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no

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responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate agreement between the parties. This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.

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SDS no. D110Version 3Revision date 06-Jun-2018Supersedes Date: 20-Feb-2015

Safety Data SheetCement Retarder D110



Product name Cement Retarder D110Product code D110









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

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Cement Retarder D110 SDS no. D110Revision date 06-Jun-2018



Contains No hazardous components2.3 Other hazards


Thermal decomposition can lead to release of irritating gases and vapors



3.1 Substances

Not applicable

3.2 Mixtures

No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.









Symptoms




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Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Harmful organic chemical fumes.












Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.

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HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.

Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product



Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Do not freeze Storeabove 0°C Store away from incompatibles, Strong oxidizing agents


Packaging materials Use specially constructed containers only. High density polyethylene (HDPE) drum



Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.




Engineering ControlsEnsure adequate ventilation

Personal protective equipmentEye protection It is good practice to wear goggles when handling any chemical Use eye protection

according to EN 166, designed to protect against liquid splashes Tightly fitting safetygoggles

Hand protection Wear chemical resistant gloves such as nitrile or neoprene. Repeated or prolonged contactRubber gloves Neoprene NitrileBreak through time >480 minutesGlove thickness 0.5 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection No personal respiratory protective equipment normally required In case of insufficient

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ventilation wear suitable respiratory equipment Respirator with combination filter forvapour/particulate (EN 141) Type A/P2







Appearance OpaqueOdor SweetColor BrownOdor threshold Not applicable

Explosive properties None knownOxidizing properties None known.

9.2 Other information Pour point No information availableMolecular weight No information available


Property Values Remarks pH 6 - 9pH @ dilution No information availableMelting / freezing point -4 °C / 24.8 °FBoiling point/range 100 °C / 212 °FFlash point > 100 °C / > 212 °FEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 1.14 20 °CBulk density No information availableRelative density No information availableWater solubility SolubleSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature >242°C / >467.6 °FKinematic viscosity No information availableDynamic viscosity 1.5cst @ 40 °Clog Pow Does not bioaccumulate

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_____________________________________________________________________________________________


VOC content(%) NoneDensity No information available



10.1 Reactivity







Do not freeze. Store above 0°C.


Strong oxidizing agents.


See Section 5.2.



Acute toxicity

Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.








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Routes of exposure Skin contact. Eye contact.

Routes of entry No route of entry noted.


Not classified


Not classified.




12.1 Toxicity



Toxicity to fishNot considered toxic to fish.

Toxicity to daphnia and other aquatic invertebratesNot considered toxic.


Product is biodegradable.


Does not bioaccumulate.

12.4 Mobility

MobilityThe product is water soluble, and may spread in water systems.


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None known.




Waste from residues / unusedproducts













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USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) CompliesChina (IECSC) Does not complyAustralia (AICS) CompliesKorean (KECL) Does not complyNew Zealand (NZIoC) Does not comply


Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Ingrid Helland

Supersedes Date: 20-Feb-2015


Version 3


1, 2, 7, 8, 9, 10, 11, 15, 16No changes with regard to classification have been made.


HMIS classification

Health 1Flammability 1Physical hazard 0PPE E

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DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.

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SDS no. S001Version 3Revision date 09-Oct-2018Supersedes Date: 13-Mar-2015

Safety Data SheetCalcium Chloride S1



Product name Calcium Chloride S1Product code S001









GHS Classification

Health hazardsSerious eye damage/eye irritation Category 2



2.2 Label elements


[email protected]

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Calcium Chloride S1 SDS no. S001Revision date 09-Oct-2018

Signal wordWARNING

Hazard StatementsH319 - Causes serious eye irritation

Precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves and eye/face protectionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP308 + P313 - IF exposed or concerned: Get medical advice/attentionP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

ContainsCalcium chloride

2.3 Other hazards




3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC No CAS No Weight-%Calcium chloride 233-140-8 10043-52-4 60 - 100






Skin contact Wash off immediately with soap and plenty of water while removing all contaminated

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clothes and shoes. Get medical attention if irritation persists.

Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Continue to rinse for at least 15 minutes. Get medical attention.



Symptoms




















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Methods for cleaning upAvoid generating or breathing dust. Sweep up and shovel into suitable containers for disposal. After cleaning, flush away traceswith water.









Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid: Hightemperatures. Avoid contact with water and moist air - product is hygroscopic. SteelBromine trifluoride. Furan-2-peroxycarboxylic acid. Acids






Chemical Name Arabic Australia EgyptCalcium chloride Not determined Not determined Not determinedChemical Name India Indonesian JapanCalcium chloride Not determined Not determined Not determinedChemical Name Kazakhstan Kuwait New ZealandCalcium chloride Not determined Not determined Not determinedChemical Name Malaysia Philippines RussiaCalcium chloride Not determined Not determined 2 mg/m³ MAC (aerosol)Chemical Name Thailand Vietnam TurkeyCalcium chloride Not determined Not determined Not determined

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Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against dusts It is good

practice to wear goggles when handling any chemical Tightly fitting safety gogglesHand protection Wear gloves according to EN 374 to protect against skin effects from powders Use

protective gloves made of: polyvinyl alcohol or nitrile-butyl rubber gloves Frequent changeis advisable

Respiratory protection No personal respiratory protective equipment normally required In case of insufficientventilation wear suitable respiratory equipment Effective dust mask. Half mask with aparticle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.







Appearance GranulesOdor OdorlessColor WhiteOdor threshold Not applicable


Property Values Remarks pH No information availablepH @ dilution 9 - 10.5 (100 g/l soln @20°C)Melting / freezing point No information availableBoiling point/range > 1600 °CFlash point Not applicableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air

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10.1 Reactivity

Hygroscopic.






Avoid dust formation. Avoid contact with water and moist air - product is hygroscopic. High temperatures.


Water. Bromine trifluoride. Furan-2-peroxycarboxylic acid. Acids. Steel.


See Section 5.2.



Acute toxicity


Vapor pressure No information availableVapor density No information availableSpecific gravity No information availableBulk density 800 mg/m3

Relative density 2.2 @ 20°C.Water solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature >772°CKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available

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Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough.

Eye contact Causes serious eye irritation.

Skin contact May cause skin irritation and/or dermatitis.

Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.



Chemical Name LD50 Oral LD50 Dermal LC50 InhalationCalcium chloride = 1000 mg/kg ( Rat ) > 5000 mg/kg ( Rabbit ) No data available





Routes of exposure Eye contact. Inhalation.

Routes of entry Eye contact. Inhalation.


Not classified


Not classified.

Aspiration hazard No hazard from product as supplied.



12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Listed on PLONOR list of OSPAR




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aquatic invertebratesCalcium chloride = 10650 mg/L LC50 Lepomis

macrochirus 96 hNo information available 2,400 mg/L EC50 (Daphnia magna)

= 48 h



Chemical Name Persistence and degradabilityCalcium chloride Inorganic compound



Chemical Name BioaccumulationCalcium chloride Product/Substance is inorganic

12.4 Mobility


Chemical Name MobilityCalcium chloride Soluble in water


Chemical Name Mobility in soilCalcium chloride After release, disperses through ground water




None known.




Waste from residues/unused Dispose of in accordance with local regulations.

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products













Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocatedNew Zealand Hazard Classification Classified

HSNO approval no. HSR003389

Group number 6.1D, 6.1E, 6.3A, 6.4A, 9.3C




USA (TSCA) Complies

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Canada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies




Revision date 09-Oct-2018

Version 3


1, 7, 8, 12, 15, 16No changes with regard to classification have been made.



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SDS no. D161 Version 6 Revision date 15-Mar-2021 Supersedes Date: 11-Feb-2016

Safety Data Sheet Multi-Temperature Cement Retarder D161



Product name Multi-Temperature Cement Retarder D161 Product code D161









GHS Classification

Health hazards Reproductive toxicity Category 2



2.2 Label elements

SupplierSchlumberger Oilfield Australia Pty Ltd ABN: 74 002 459 225 ACN: 002 459 225 256 St. Georges Terrace, Perth WA 6000 +47 5157 7424

[email protected]

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Multi-Temperature Cement Retarder D161

SDS no. D161 Revision date 15-Mar-2021

Signal wordWARNING

Hazard StatementsH361 - Suspected of damaging fertility or the unborn child

Precautionary statements P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP280 - Wear protective gloves/protective clothing/eye protection/face protectionP308 + P313 - IF exposed or concerned: Get medical advice/attentionP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

Contains Sodium pentaborate

2.3 Other hazards




3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC No CAS No Weight-% Sodium pentaborate 234-522-7 12007-92-0 5-10





Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical attention.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Seek medical attention if irritation occurs.

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Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.



Symptoms









Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.

Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire.



Hazardous combustion productsFire or high temperatures create: Oxides of phosphorus, Carbon oxides (COx), Harmful organic chemical fumes.







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HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Avoid spills and splashing during use. Not to be used by pregnant workers and workers who have recently given birth or who are breastfeeding.

Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately after handling the product Remove contaminated clothing Do not eat, drink or smoke when using this product


Technical measures/precautions Ensure adequate ventilation.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Store away from heat and sources of ignition Avoid extreme temperatures Store above 0°C Store away from incompatibles, Strong reducing agents Strong oxidizing agents





Exposure limits Contains no substances with occupational exposure limit values


Chemical Name Arabic Australia Egypt Sodium pentaborate Not determined Not determined Not determined

Chemical Name India Indonesian Japan Sodium pentaborate Not determined Not determined Not determined

Chemical Name Kazakhstan Kuwait New Zealand Sodium pentaborate Not determined Not determined Not determined

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Chemical Name Malaysia Philippines Russia Sodium pentaborate Not determined Not determined Not determined

Chemical Name Thailand Vietnam Turkey Sodium pentaborate Not determined Not determined Not determined




Engineering ControlsEnsure adequate ventilation Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into work environment.

Personal protective equipment Eye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety

glasses with side-shields Tightly fitting safety goggles Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee

training Impervious gloves made of: Nitrile PVA PVC Be aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection No personal respiratory protective equipment normally required In case of insufficient ventilation wear suitable respiratory equipment Respirator with a vapor filter (EN 141) Chemical respirator with inorganic vapour cartridge (Grey B). At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.

Skin and body protection Wear appropriate personal protective clothing to prevent skin contact Eye wash and emergency shower must be available at the work place.






Appearance Clear Odor Slight Color Colorless Odor threshold Not applicable

Physical state

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Liquid

_____________________________________________________________________________________________



Explosive properties Not applicable Oxidizing properties None known.

9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) None Density 1.073 - 1.077 g/ml @ 20 °C



10.1 Reactivity







Avoid heat, flames and other sources of ignition. Avoid extreme temperatures. Do not freeze.


Strong oxidizing agents. Strong reducing agents.


Property Values Remarks pH 6.9 pH @ dilution No information available Melting / freezing point ~0 °C / 32 °F Boiling point/range 100 °C / 212 °F Flash point Non-flammable Evaporation rate (BuAc =1) No information available Flammability (solid, gas) Not applicable Flammability Limit in Air

Upper flammability limit Not applicable Lower flammability limit Not applicable

Vapor pressure No information available Vapor density No information available Specific gravity No information available Bulk density No information available Relative density No information available Water solubility Soluble in water Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available log Pow No information available

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_____________________________________________________________________________________________



See Section 5.2.



Acute toxicity




Ingestion Ingestion may cause stomach discomfort. May cause damage to organs through prolonged or repeated exposure.



Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium pentaborate No data available LD50 > 2000 mg/kg bw LC50 > 2.03 mg/l




Reproductive toxicity Product is or contains a chemical which is a known or suspected reproductive hazard.

Routes of Exposure Skin contact. Eye contact. Ingestion.

Routes of entry Ingestion.


Not classified


Not classified.




12.1 Toxicity


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aquatic invertebrates Sodium pentaborate LC50: 600 mg/l 96h No information available LC50: 86 mg/l 48h


No product level data available.



12.4 Mobility

MobilitySoluble in water.





None known.




Waste from residues/unused Dispose of in accordance with local regulations.

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products


















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USA (TSCA) Complies Canada (DSL) Complies Volume restriction. Philippines (PICCS) Complies Japan (ENCS) Complies China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Does not comply Eurasian Economic Union: Russian Inventory

Complies


Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Poh Yue Cheong



Version 6





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SDS no. D080 Version 4 Revision date 10-Feb-2021 Supersedes Date: 22-Jan-2016

Safety Data Sheet Cement Liquid Dispersant D80



Product name Cement Liquid Dispersant D80 Product code D080









GHS Classification


Environmental hazards Chronic aquatic toxicity Category 2


2.2 Label elements


[email protected]

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Cement Liquid Dispersant D80 SDS no. D080 Revision date 10-Feb-2021

Signal wordNone

Hazard StatementsH411 - Toxic to aquatic life with long lasting effects

Precautionary statements P273 - Avoid release to the environmentP391 - Collect spillageP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

Contains Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde

2.3 Other hazards


Australian statement of hazardous/dangerous natureHAZARDOUS SUBSTANCE. DANGEROUS GOODS.Classified as Hazardous according to the criteria of NOHSC.


3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC No CAS No Weight-% Naphthalenesulfonic acid, sodium salt, polymer with

formaldehyde Polymer 9008-63-3 30-60






Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if symptoms occur.

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Symptoms













Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Sulphur oxides.




Hazchem code ADG 3Z



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Methods for cleaning upContain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations (see Section 13). After cleaning, flush away traces with water.





HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid spills and splashing during use. Do not breathe vapors or spray mist.

Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately after handling the product Do not eat, drink or smoke when using this product Remove contaminated clothing



Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Do not freeze Store above 0°C Avoid contact with: Oxidizing agents Acids





Exposure limits The product does not contain any hazardous materials with occupational exposure limits established.


Chemical Name Arabic Australia Egypt Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde


Chemical Name India Indonesian Japan Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde


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Chemical Name Kazakhstan Kuwait New Zealand Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde


Chemical Name Malaysia Philippines Russia Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde


Chemical Name Thailand Vietnam Turkey Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde





Engineering ControlsEnsure adequate ventilation, especially in confined areas

Personal protective equipment Eye protection Use eye protection according to EN 166, designed to protect against liquid splashes Tightly

fitting safety goggles Safety glasses with side-shields Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee

training Wear chemical resistant gloves such as nitrile or neoprene. Be aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection No personal respiratory protective equipment normally required In case of insufficient ventilation wear suitable respiratory equipment Respirator with combination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.







Appearance Opaque Odor Pungent

Physical state

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Liquid

_____________________________________________________________________________________________


Color Dark brown Odor threshold Not applicable

Explosive properties No information available Oxidizing properties No information available

9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) No information available Density No information available



10.1 Reactivity







Do not freeze. Store above 0°C.

Property Values Remarks pH 6 - 8 pH @ dilution No information available Melting / freezing point - 2 °C/ 28 °F

Boiling point/range 100 °C / 212 °F

Flash point Does not flash Evaporation rate (BuAc =1) No information available Flammability (solid, gas) Not applicable Flammability Limit in Air


Vapor pressure No information available Vapor density > 1 (air = 1) Specific gravity 1.2 g/cm3 20 °C Bulk density No information available Relative density No information available Water solubility Soluble in water Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity 60 mPa s log Pow No information available

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Oxidizing agents. Acids.


See Section 5.2.



Acute toxicity







Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Naphthalenesulfonic acid, sodium salt, polymer

with formaldehyde No data available No data available No data available





Routes of Exposure None known.



Not classified


Not classified.




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_____________________________________________________________________________________________


12.1 Toxicity

Toxic to aquatic life with long lasting effects

Toxicity to algaeEC50 1.46 mg/l Skeletonema Costatum 48 h.

Toxicity to fishNot considered toxic to fish.

Toxicity to daphnia and other aquatic invertebratesLC50 > 100 mg/l Acartia tonsa 48 h.


aquatic invertebrates Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde

No information available No information available No information available


Product is not biodegradable.


Bioaccumulation is unlikely.

12.4 Mobility






None known.


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14.1. UN number UN/ID No. (ADR/RID/ADN/ADG) UN3082 UN No. (IMDG/ANTAQ) UN3082 UN No. (ICAO/ANAC) UN3082

14.2. UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Sodium polynaphthalene sulfonate)

14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class 9 IMDG/ANTAQ Hazard class 9 ICAO/ANAC Hazard class/division 9

14.4 Packing group ADR/RID/ADN/ADG Packing group III IMDG/ANTAQ Packing group III ICAO/ANAC Packing group III

14.5 Environmental hazard Yes

14.6 Special precautions Hazard identification no (ADR) 90 EmS (IMDG) F-A, S-F Emergency Action Code (EAC) 3Z Tunnel restriction code (-) Hazchem code ADG 3Z



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New Zealand Hazard Classification Construction Products (Subsidiary Hazard) Group Standard 2020

HSNO approval no. HSR002544

Group number 9.1B



ADG Code – Australian Dangerous Goods Code


USA (TSCA) Complies Canada (DSL) Complies Philippines (PICCS) Complies Japan (ENCS) Complies China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Complies New Zealand (NZIoC) Complies Eurasian Economic Union: Russian Inventory

Complies




Revision date 10-Feb-2021

Version 4




HMIS classification

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SDS no. D186Version 8Revision date 23-Aug-2019Supersedes Date: 10-Feb-2016

Safety Data SheetLow Temperature Cement Set Enhancer D186



Product name Low Temperature Cement Set Enhancer D186Product code D186









GHS Classification

Health hazardsAcute toxicity - Oral Category 4Serious eye damage/eye irritation Category 1



2.2 Label elements


[email protected]

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Low Temperature Cement SetEnhancer D186

SDS no. D186Revision date 23-Aug-2019

Signal wordDANGER

Hazard StatementsH302 - Harmful if swallowedH318 - Causes serious eye damage

Precautionary statements P270 - Do not eat, drink or smoke when using this productP280 - Wear protective gloves/protective clothing/eye protection/face protectionP301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

Supplementary precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP330 - Rinse mouthP391 - Collect spillage

ContainsCalcium nitrate

2,2' -oxydiethanol

Calcium Bromide

2,2'-Methyliminodiethanol

2.3 Other hazards




3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC No CAS No Weight-%Calcium nitrate 233-332-1 10124-37-5 10-30

2,2' -oxydiethanol 203-872-2 111-46-6 1-5Calcium Bromide 232-164-6 7789-41-5 1-5

2,2'-Methyliminodiethanol 203-312-7 105-59-9 1-5


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Ingestion Rinse mouth. Do not induce vomiting. If conscious, give 2 glasses of water. Get immediatemedical attention. Never give anything by mouth to an unconscious person.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Seek medical attention if irritation occurs.

Eye Contact Remove contact lenses, if worn. Immediately flush eyes with water for 15 minutes whileholding eyelids open. Seek medical attention.



Symptoms












Unusual fire and explosion hazardsThermal decomposition can lead to release of irritating gases and vapors.

Hazardous combustion productsFire or high temperatures create: Ammonia, Nitrogen oxides (NOx), Carbon oxides (COx).


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Wear protective gloves/clothing and eye/face protection. Avoid contact with eyes. Do not get on skin or clothing. Wash thoroughlyafter handling. See also section 8.


Prevent further leakage or spillage. The product should not be allowed to enter drains, water courses or the soil.









Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Do not eat, drink or smoke when using this product Washthoroughly with soap and water after handling and before eating, drinking, or using tobacco. Remove contaminated clothing



Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid contact with:Acids Bases Strong reducing agents






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_____________________________________________________________________________________________



Chemical Name Arabic Australia EgyptCalcium nitrate Not determined Not determined Not determined

2,2' -oxydiethanol Not determined 23ppmTWA100mg/m3TWA

Not determined

Calcium Bromide Not determined Not determined Not determined2,2'-Methyliminodiethanol Not determined Not determined Not determined

Chemical Name India Indonesian JapanCalcium nitrate Not determined Not determined Not determined

2,2' -oxydiethanol Not determined Not determined Not determinedCalcium Bromide Not determined Not determined Not determined

2,2'-Methyliminodiethanol Not determined Not determined Not determinedChemical Name Kazakhstan Kuwait New ZealandCalcium nitrate Not determined Not determined Not determined

2,2' -oxydiethanol 10 mg/m3 MAC Not determined 23 ppm TWA101 mg/m3 TWA

Calcium Bromide Not determined Not determined Not determined2,2'-Methyliminodiethanol Not determined Not determined Not determined

Chemical Name Malaysia Philippines RussiaCalcium nitrate Not determined Not determined Not determined

2,2' -oxydiethanol Not determined Not determined 10 mg/m3 MACCalcium Bromide Not determined Not determined Not determined

2,2'-Methyliminodiethanol Not determined Not determined Not determinedChemical Name Thailand Vietnam TurkeyCalcium nitrate Not determined Not determined Not determined

2,2' -oxydiethanol Not determined Not determined Not determinedCalcium Bromide Not determined Not determined Not determined

2,2'-Methyliminodiethanol Not determined Not determined Not determined



Engineering ControlsEnsure adequate ventilation Local exhaust ventilation

Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Tightly

fitting safety goggles Safety glasses with side-shieldsHand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee

trainingImpervious gloves made of: Nitrile PVCBreak through time >480 minutesGlove thickness 0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Respirator with avapor filter (EN 141) Use respirator with organic vapor/acid gas protection (E, yellow) Atwork in confined or poorly ventilated spaces, respiratory protection with air supply must beused.


Hygiene Measures Wash hands before breaks and immediately after handling the product

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_____________________________________________________________________________________________







Appearance No information availableOdor NoneColor Light greenOdor threshold Not applicable






Property Values Remarks pH 8 - 10pH @ dilution No information availableMelting / freezing point < -21 °C / -7 °FBoiling point/range ~ 108 °C / 226 °FFlash point No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure ~2 kPa @ 25 °CVapor density 1 (air = 1)Specific gravity 1.4Bulk density No information availableRelative density 1.4Water solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature 538 °C / 1000 °F

Kinematic viscosity No information availableDynamic viscosity 2 mPa s @ 15.5 °Clog Pow No information available

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_____________________________________________________________________________________________



10.1 Reactivity





Hazardous polymerizationNone under normal processing.


Do not allow liquid to evaporate. Dry material is a strong oxidizer.


Acids. Bases. Strong reducing agents.


See Section 5.2.



Acute toxicity

Inhalation Vapors may irritate throat and respiratory system.


Skin contact Irritating to skin. Substance may cause slight skin irritation.

Ingestion Harmful if swallowed.



Chemical Name LD50 Oral LD50 Dermal LC50 InhalationCalcium nitrate No data available No data available No data available

2,2' -oxydiethanol = 12565 mg/kg ( Rat ) = 11890 mg/kg ( Rabbit ) > 4600 mg/m3 ( Rat ) 4 hCalcium Bromide = 4100 mg/kg ( Rat ) No data available No data available

2,2'-Methyliminodiethanol No data available No data available No data available




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Routes of Exposure Skin contact. Eye contact. Inhalation. Ingestion.

Routes of entry Skin contact. Eye contact. Inhalation. Ingestion.


Not classified


Not classified.




12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.





aquatic invertebratesCalcium nitrate No information available No information available No information available

2,2' -oxydiethanol = 75200 mg/L LC50 Pimephalespromelas 96 h

No information available = 84000 mg/L EC50 Daphniamagna 48 h

Calcium Bromide No information available No information available No information available2,2'-Methyliminodiethanol No information available No information available No information available


Not readily biodegradable.



12.4 Mobility

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_____________________________________________________________________________________________







None known.














_____________________________________________________________________________________________

Page 9 / 11

_____________________________________________________________________________________________








2,2' -oxydiethanolSchedule 6Schedule 5Calcium BromideSchedule 4









USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies





_____________________________________________________________________________________________

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_____________________________________________________________________________________________



Version 8


All sections No changes with regard to classification have been made. Updated accordingto GHS/CLP.


HMIS classification

Health 3Flammability 1Physical hazard 0PPE X


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SDS no. D182Version 3Revision date 06-Jul-2020Supersedes Date: 05-Apr-2017

Safety Data SheetMUDPUSH* II Spacer D182



Product name MUDPUSH* II Spacer D182Product code D182









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

_____________________________________________________________________________________________

Page 1 / 10

_____________________________________________________________________________________________

MUDPUSH* II Spacer D182 SDS no. D182Revision date 06-Jul-2020







3.1 Substances

Not applicable

3.2 Mixtures










Symptoms





_____________________________________________________________________________________________

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_____________________________________________________________________________________________








Unusual fire and explosion hazardsDust may form explosive mixture in air.

Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Sulphur oxides.






Use personal protective equipment. See also section 8. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking.






Methods for cleaning upSweep up and shovel into suitable containers for disposal. Take precautionary measures against static discharges. After cleaning,flush away traces with water.



_____________________________________________________________________________________________

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_____________________________________________________________________________________________



HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.Material becomes slippery when wet. Use caution if wet.



Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Takeprecautionary measures against static discharges.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away from openflames, hot surfaces and sources of ignition Keep away from direct sunlight. Incompatiblewith oxidizing agents









Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against dusts Safety glasses

with side-shields Tightly fitting safety gogglesHand protection Wear gloves according to EN 374 to protect against skin effects from powders

Use protective gloves made of: Rubber Neoprene NitrileFrequent change is advisable

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Half mask with aparticle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.



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_____________________________________________________________________________________________






Appearance PowderOdor Mild SweetColor Red brownOdor threshold Not applicable

Explosive properties Suspended dust may present a dust explosion hazardOxidizing properties None known.




Property Values Remarks pH No information availablepH @ dilution ~8 650g/l (Soln)Melting / freezing point No information availableBoiling point/range Not applicableFlash point Not applicableEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure Not applicableVapor density Not applicableSpecific gravity 1.3 @ 20 °CBulk density No information availableRelative density No information availableWater solubility Partly soluble Gel in contact with

waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature > 242 °C / 468 °F

Kinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available

_____________________________________________________________________________________________

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_____________________________________________________________________________________________



10.1 Reactivity

Dust may form explosive mixture in air.






Avoid dust formation. Keep away from open flames, hot surfaces and sources of ignition. Keep away from direct sunlight. Takeprecautionary measures against static charges.


Oxidizing agents.


See Section 5.2.



Acute toxicity


Eye contact Dust contact with the eyes can lead to mechanical irritation.









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_____________________________________________________________________________________________




Not classified


Not classified.




12.1 Toxicity









12.4 Mobility

MobilityPartly soluble. Gel in contact with water.




_____________________________________________________________________________________________

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_____________________________________________________________________________________________



None known.


















_____________________________________________________________________________________________

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_____________________________________________________________________________________________


No poisons schedule number allocated








USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) CompliesChina (IECSC) Does not complyAustralia (AICS) CompliesKorean (KECL) Does not complyNew Zealand (NZIoC) Complies




Revision date 06-Jul-2020

Version 3




_____________________________________________________________________________________________

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DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon on

_____________________________________________________________________________________________


measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.

_____________________________________________________________________________________________

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SDS no. D256Version 2Revision date 11-Jul-2019Supersedes Date: 11-Apr-2016

Safety Data SheetMid-Range liquid FLAC D256



Product name Mid-Range liquid FLAC D256Product code D256









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

_____________________________________________________________________________________________

Page 1 / 10

_____________________________________________________________________________________________

Mid-Range liquid FLAC D256 SDS no. D256Revision date 11-Jul-2019







3.1 Substances

Not applicable

3.2 Mixtures

This product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits.









Symptoms





_____________________________________________________________________________________________

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_____________________________________________________________________________________________









Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Nitrogen oxides (NOx), Ammonia, Sulfur oxides, Hydrogen cyanide(hydrocyanic acid) may be produced in the event of combustion in an oxygen deficient atmosphere.






Use personal protective equipment. See also section 8. Contaminated surfaces will be extremely slippery.









_____________________________________________________________________________________________

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_____________________________________________________________________________________________




HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use. If spilled, take caution, as material can cause surfaces to become very slippery.Repeated or prolonged contact may cause allergic reactions in very susceptible persons.




Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away fromdirect sunlight. Avoid excessive heat for prolonged periods of time. Protect from freezingAvoid contact with: Oxidizing agents





Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished. No biological limit allocated




Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety

glasses with side-shields Tightly fitting safety gogglesHand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee

training Impervious gloves made of: Butyl Neoprene Nitrile RubberBreak through time >480 minutesGlove thickness >=0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection No personal respiratory protective equipment normally required In case of insufficientventilation wear suitable respiratory equipment Respirator with a vapor filter (EN 141) Userespirator with organic vapor protection (A, brown) At work in confined or poorly ventilatedspaces, respiratory protection with air supply must be used.

Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at the

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_____________________________________________________________________________________________


work place.





Appearance ClearOdor SlightColor Light yellowOdor threshold Not applicable




Property Values Remarks pH 3 - 7pH @ dilution No information availableMelting / freezing point < 5 °C / 41 °FBoiling point/range > 100 °C / 212 °FFlash point Does not flashEvaporation rate (BuAc =1) Similar to water.Flammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure 2.3 kPa @ 20°CVapor density Similar to water.Specific gravity 1.0 - 1.3Bulk density No information availableRelative density 1.0-1.3Water solubility Miscible with water.Solubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature > 100°C / 212°F

Kinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available

_____________________________________________________________________________________________

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_____________________________________________________________________________________________




10.1 Reactivity







Protect from freezing. Keep away from direct sunlight. Avoid excessive heat for prolonged periods of time.


Incompatible with oxidizing agents.


See Section 5.2.



Acute toxicity






Sensitization This product does not contain any components suspected to be sensitizing >0.1%.


Carcinogenicity Contains a known or suspected carcinogen.

Reproductive toxicity This product does not contain any known or suspected reproductive hazards atconcentrations >0.1%.

_____________________________________________________________________________________________

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_____________________________________________________________________________________________





Not classified


Not classified.




12.1 Toxicity








Product has a low potential to bioconcentrate.

12.4 Mobility



_____________________________________________________________________________________________

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_____________________________________________________________________________________________




None known.

















_____________________________________________________________________________________________

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This safety data sheet complies with the requirements of:

_____________________________________________________________________________________________





HSNO approval no. not required









USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) Does not complyChina (IECSC) Does not complyAustralia (AICS) CompliesKorean (KECL) Does not complyNew Zealand (NZIoC) Complies





Version 2



_____________________________________________________________________________________________

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_____________________________________________________________________________________________


HMIS classification

Health 0Flammability 0Physical hazard 0PPE B


_____________________________________________________________________________________________

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SDS no. D255 Version 3 Revision date 11-Jul-2019 Supersedes Date: 04-Jan-2018

Safety Data Sheet Mid-Range FLAC D255



Product name Mid-Range FLAC D255 Product code D255






Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518



GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

_____________________________________________________________________________________________

Page 1 / 10

_____________________________________________________________________________________________

Mid-Range FLAC D255 SDS no. D255 Revision date 11-Jul-2019



Contains 2-methylpropan-2-ol

2.3 Other hazards


Suspended dust may present a dust explosion hazard



3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC No CAS No Weight-% 2-methylpropan-2-ol 200-889-7 75-65-0 <5





Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention immediately if symptoms occur.

Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn. Get medical attention if any discomfort continues.



_____________________________________________________________________________________________

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_____________________________________________________________________________________________


Symptoms












Unusual fire and explosion hazardsDust may form explosive mixture in air.

Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Nitrogen oxides (NOx), Ammonia, Hydrogen cyanide (hydrocyanic acid).






Use personal protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. See also section 8.





_____________________________________________________________________________________________

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Methods for containment

_____________________________________________________________________________________________


Prevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading.

Methods for cleaning upAvoid generating or breathing dust. Take precautionary measures against static discharges. Take up mechanically and collect in suitable container for disposal. After cleaning, flush away traces with water.





HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation. Do not breathe dust. Material becomes slippery when wet. Use caution if wet.



Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Take precautionary measures against static discharges.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away from open flames, hot surfaces and sources of ignition Avoid excessive heat for prolonged periods of time. Keep away from direct sunlight. Incompatible with oxidizing agents Strong acids





Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust. No biological limit allocated


Chemical Name Arabic Australia Egypt 2-methylpropan-2-ol 100 ppm TWA

303 mg/m3 TWA 150ppmSTEL

455mg/m3STEL 100ppmTWA

303mg/m3TWA


Chemical Name India Indonesian Japan 2-methylpropan-2-ol Not determined 100 ppm TWA

303 mg/m3 TWA 50 ppm OEL

150 mg/m3 OEL Chemical Name Kazakhstan Kuwait New Zealand

2-methylpropan-2-ol 10 mg/m3 MAC Not determined 150 ppm STEL 455 mg/m3 STEL


Chemical Name Malaysia Philippines Russia 2-methylpropan-2-ol 100 ppm TWA

303 mg/m3 TWA 100 ppm TWA

300 mg/m3 TWA 10 mg/m3 MAC

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


Chemical Name Thailand Vietnam Turkey 2-methylpropan-2-ol 100 ppm TWA Not determined Not determined




Personal protective equipment Eye protection Use eye protection according to EN 166, designed to protect against dusts Safety glasses

with side-shields Tightly fitting safety goggles Hand protection Wear gloves according to EN 374 to protect against skin effects from powders Impervious

gloves made of: Rubber gloves Butyl Neoprene Nitrile Frequent change is advisable Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Half mask with a

particle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.







Appearance Granules Odor None Color White Odor threshold Not applicable


Property Values Remarks pH Not applicable pH @ dilution 4 - 9 @ 5 g/l Melting / freezing point > 250 °C / 482 °F Boiling point/range Not applicable Flash point Not applicable Evaporation rate (BuAc =1) Not applicable Flammability (solid, gas) Not applicable Flammability Limit in Air

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


Explosive properties Suspended dust may present a dust explosion hazard Oxidizing properties None known.

9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) No information available Density No information available



10.1 Reactivity







Avoid dust formation. Keep away from direct sunlight. Avoid excessive heat for prolonged periods of time. Keep away from open flames, hot surfaces and sources of ignition.


Incompatible with oxidizing agents. Strong acids.


See Section 5.2.




Vapor pressure Not applicable Vapor density Not applicable Specific gravity 1.15 - 1.35 Bulk density ~ 0.20 - 0.40 Relative density No information available Water solubility Soluble in water Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature >150°C / >302° F Kinematic viscosity No information available Dynamic viscosity No information available log Pow No information available

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


Acute toxicity







Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation 2-methylpropan-2-ol = 2200 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) > 10000 ppm ( Rat ) 4 h








Not classified


Not classified.




12.1 Toxicity





_____________________________________________________________________________________________

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_____________________________________________________________________________________________



aquatic invertebrates 2-methylpropan-2-ol 6130 - 6700 mg/L LC50 Pimephales

promelas 96 h > 1000 mg/L EC50 Desmodesmus

subspicatus 72 h 4607 - 6577 mg/L EC50 Daphnia

magna 48 h = 933 mg/L EC50 Daphnia magna 48 h





log Pow<0

12.4 Mobility






None known.







_____________________________________________________________________________________________

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_____________________________________________________________________________________________





















USA (TSCA) Does not comply

_____________________________________________________________________________________________

Page 9 / 10

_____________________________________________________________________________________________


Canada (DSL) Complies Philippines (PICCS) Philippine PICCS - Components are listed or exempt from listing. Japan (ENCS) Does not comply China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Does not comply New Zealand (NZIoC) Complies





Version 3


15. Regulatory Information No changes with regard to classification have been made.


HMIS classification

Health 1 Flammability 1 Physical hazard 0 PPE E


_____________________________________________________________________________________________

Page 10 / 10

SDS no. D168Version 4Revision date 23-Mar-2018Supersedes Date: 19-Feb-2015

Safety Data SheetUNIFLAC* L D168



Product name UNIFLAC* L D168Product code D168









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

_____________________________________________________________________________________________

Page 1 / 10

_____________________________________________________________________________________________

UNIFLAC* L D168 SDS no. D168Revision date 23-Mar-2018



2.3 Other hazards




3.1 Substances

Not applicable

3.2 Mixtures










Symptoms





_____________________________________________________________________________________________

Page 2 / 10


_____________________________________________________________________________________________









Hazardous combustion productsThermal decomposition can lead to release of toxic and corrosive gases/vapors Nitrogen oxides (NOx), Sulphur oxides.






Use personal protective equipment. Contaminated surfaces will be extremely slippery. See also section 8.









_____________________________________________________________________________________________

Page 3 / 10


_____________________________________________________________________________________________



HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use. If spilled, take caution, as material can cause surfaces to become very slippery.

Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product


Technical measures/precautions Ensure adequate ventilation. Provide sufficient air exchange and/or exhaust in work rooms.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Store above freezingtemperature Store away from incompatibles, Oxidizing agents









Engineering ControlsProvide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into work environment.



training Impervious gloves made of: Butyl Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Respirator withcombination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.

Skin and body protection Wear appropriate personal protective clothing to prevent skin contact Eye wash andemergency shower must be available at the work place.

_____________________________________________________________________________________________

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_____________________________________________________________________________________________







Appearance Aqueous solutionOdor OdorlessColor White - Light yellowOdor threshold Not applicable

Explosive properties No information availableOxidizing properties Not applicable

9.2 Other information Pour point -6°C / 21.2 °F

Molecular weight No information availableVOC content(%) NoneDensity 1.06 g/cm³ (20°C)

Comments


Property Values Remarks pH 7 @ 20 °CpH @ dilution 10 g/lMelting / freezing point 0 °C / 32 °FBoiling point/range 100 °C / 212 °FFlash point Not applicableEvaporation rate (BuAc =1) Similar to water.Flammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure 2.34 kPa @ 20 °CVapor density No information availableSpecific gravity 1.06 g/cm3 @ 20 °CBulk density No information availableRelative density No information availableWater solubility Miscible with water.Solubility in other solvents No information availableAutoignition temperature 500 °C / 932 °FDecomposition temperature 260 °C / 500 °F

Kinematic viscosity No information availableDynamic viscosity 2000 - 4000 mPa slog Pow No information available

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


The data listed above are typical physical and chemical properties and should not be construed as product specification.


10.1 Reactivity







Do not freeze.


Oxidizing agents.


See Section 5.2.



Acute toxicity










Routes of exposure Skin contact. Eye contact. Inhalation.

_____________________________________________________________________________________________

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_____________________________________________________________________________________________




Not classified


Not classified.




12.1 Toxicity






Biodegradable.



12.4 Mobility





_____________________________________________________________________________________________

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_____________________________________________________________________________________________



None known.


















_____________________________________________________________________________________________

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_____________________________________________________________________________________________



HSNO approval no. Not applicable

Group number Not applicable









USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) Does not complyNew Zealand (NZIoC) Complies





Version 4




_____________________________________________________________________________________________

Page 9 / 10

_____________________________________________________________________________________________



_____________________________________________________________________________________________

Page 10 / 10

SDS no. D065 Version 6 Revision date 08-Jun-2021 Supersedes Date: 18-Jun-2014

Safety Data Sheet TIC* D65 Dispersant



Product name TIC* D65 Dispersant Product code D065 Country Limitations This SDS is not for use in the European Union (EU).









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

_____________________________________________________________________________________________

Page 1 / 10

_____________________________________________________________________________________________

TIC* D65 Dispersant SDS no. D065 Revision date 08-Jun-2021



Contains Sodium sulfate (Impurity)

2.3 Other hazards


Combustible dust

Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.


3.1 Substances

Chemical Name EC No CAS No Weight-% Sodium sulfate (Impurity) 231-820-9 7757-82-6 1-5

3.2 Mixtures

Not applicable





Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Seek medical attention if irritation occurs.




Symptoms

_____________________________________________________________________________________________

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_____________________________________________________________________________________________













Unusual fire and explosion hazardsSuspended dust may present a dust explosion hazard.

Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Sulfur dioxide.






Avoid dust formation. Keep away from combustible material. Avoid contact with heat, sparks, open flame, and static discharge. Use personal protective equipment. See also section 8.





_____________________________________________________________________________________________

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Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading.

_____________________________________________________________________________________________


Methods for cleaning upAvoid dust formation. Do not dry sweep dust. Wet dust with water before sweeping or use a vacuum to collect dust. Take precautionary measures against static discharges. Use non-sparking tools and equipment. After cleaning, flush away traces with water.





HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid handling causing generation of dust. All equipment used when handling the product must be grounded. Avoid breathing dust; if exposed to high dust concentration, leave area immediately. Fine dust dispersed in air may ignite. Take precautionary measures against static discharges.

Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Do not eat, drink or smoke when using this product Wash hands and face before breaks and immediately after handling the product Remove contaminated clothing


Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dust is formed. Keep airborne concentrations below exposure limits. Take precautionary measures against static discharges. Ensure all equipment is electrically grounded before beginning transfer operations.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away from direct sunlight. Protect from moisture





Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust. Control as an ACGIH particulate not otherwise specified (PNOS): 10 mg/m3 (Inhalable); 3 mg/m3 (Respirable) and an OSHA particulate not otherwise regulated (PNOR): 15 mg/m3 (Total); 5 mg/m3 (Respirable).


Chemical Name Arabic Australia Egypt Sodium sulfate (Impurity) Not determined Not determined Not determined

Chemical Name India Indonesian Japan Sodium sulfate (Impurity) Not determined Not determined Not determined

Chemical Name Kazakhstan Kuwait New Zealand Sodium sulfate (Impurity) 10 mg/m3 MAC Not determined Not determined

Chemical Name Malaysia Philippines Russia Sodium sulfate (Impurity) Not determined Not determined 10 mg/m3 MAC

Chemical Name Thailand Vietnam Turkey Sodium sulfate (Impurity) Not determined Not determined Not determined

_____________________________________________________________________________________________

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_____________________________________________________________________________________________






Personal protective equipment Eye protection Tightly fitting safety goggles Safety glasses with side-shields Hand protection Use protective gloves made of: Nitrile Neoprene

Frequent change is advisable Respiratory protection No personal respiratory protective equipment normally required In case of insufficient

ventilation wear suitable respiratory equipment Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust) Half mask with a particle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.







Appearance Powder Odor Faint Color Tan


Property Values Remarks pH Approximately 10 pH @ dilution No information available Melting / freezing point No information available Boiling point/range Not applicable Flash point Does not flash Evaporation rate (BuAc =1) Not applicable Flammability Not applicable Explosion limits:

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


Density and/or Relative Density No information available

Explosive properties Suspended dust may present a dust explosion hazard Oxidizing properties None known.

9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) None



10.1 Reactivity







Avoid dust formation. Avoid contact with heat, sparks, open flame, and static discharge. Protect from moisture. Keep away from direct sunlight.




See Section 5.2.


11.1 Information on toxicological effects Acute toxicity

Upper explosion limit No information available Lower explosion limit No information available

Vapor pressure Not applicable Relative Vapor Density Not applicable Specific gravity 0.8 20 °C Bulk density No information available Water solubility Soluble in water Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Partition Coefficient (n-octanol/water)


_____________________________________________________________________________________________

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_____________________________________________________________________________________________








Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium sulfate (Impurity) > 10000 mg/kg ( Rat ) > 4 g/kg ( Rabbit ) No data available








Not classified


Not classified.

Aspiration hazard Not classified.




12.1 Toxicity






aquatic invertebrates Sodium sulfate (Impurity) = 13500 mg/L LC50 Lepomis No information available = 630 mg/L EC50 Daphnia magna

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


macrochirus 96 h 3040 - 4380 mg/L LC50 Lepomis macrochirus 96 h >

6800 mg/L LC50 Pimephales promelas 96 h 13500 - 14500 mg/L LC50 Pimephales promelas 96 h

96 h = 2564 mg/L EC50 Daphnia magna 48 h





12.4 Mobility




None known.












14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


IMDG/ANTAQ Packing group Not regulated ICAO/ANAC Packing group Not regulated
















Complies

This SDS is not for use in the European Union (EU).



_____________________________________________________________________________________________

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_____________________________________________________________________________________________


Supersedes Date: 18-Jun-2014


Version 6




HMIS classification

Health 1 Flammability 1 Physical hazard 0 PPE E


_____________________________________________________________________________________________

Page 10 / 10

SDS no. D075Version 4Revision date 19-Sep-2018Supersedes Date: 09-Apr-2014

Safety Data SheetSilicate Additive D75



Product name Silicate Additive D75Product code D075









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

_____________________________________________________________________________________________

Page 1 / 10

_____________________________________________________________________________________________

Silicate Additive D75 SDS no. D075Revision date 19-Sep-2018







3.1 Substances

Not applicable

3.2 Mixtures










Symptoms





_____________________________________________________________________________________________

Page 2 / 10


_____________________________________________________________________________________________








Unusual fire and explosion hazardsContact with metals may evolve flammable hydrogen gas.

Hazardous combustion productsThermal decomposition can lead to release of toxic and corrosive gases/vapors
















_____________________________________________________________________________________________

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_____________________________________________________________________________________________



HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid spills andsplashing during use. Do not breathe vapors or spray mist.




Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep at temperaturesabove > 32F /0°C Avoid contact with: Strong acids Metals Aluminum Zinc Steel



Packaging materials to be avoided Metal Aluminium Zinc Steel



Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.No biological limit allocated






training Impervious gloves made of: PVC Rubber Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Chemical respiratorwith inorganic vapour cartridge (Grey B). At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.


_____________________________________________________________________________________________

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_____________________________________________________________________________________________






Appearance Aqueous solutionOdor OdorlessColor ColorlessOdor threshold Not applicable





Property Values Remarks pH 11pH @ dilution No information availableMelting / freezing point - 1 °C / 30 °F

Boiling point/range 101 °C / 214 °F

Flash point Not applicableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure <1 kPaVapor density No information availableSpecific gravity 1.3 - 1.6 @ 20 °CBulk density No information availableRelative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity 10-10000 mPa slog Pow No information available

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10.1 Reactivity

Contact with metals may evolve flammable hydrogen gas.






Keep at temperatures above > 32°F / 0°C.


Aluminum. Zinc. Metals. Strong acids. Steel.


See Section 5.2.



Acute toxicity











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Routes of entry None known.


Not classified


Not classified.




12.1 Toxicity









12.4 Mobility




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None known.


















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Revision date 19-Sep-2018

Version 4


15, 16 There have been changes with regard to classification.


HMIS classification

Health 1Flammability 1Physical hazard 0PPE B

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SDS no. D194Version 3Revision date 12-Feb-2019Supersedes Date: 03-Jun-2015

Safety Data SheetLiquid Trifunctional Additive D194



Product name Liquid Trifunctional Additive D194Product code D194









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

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Liquid Trifunctional Additive D194 SDS no. D194Revision date 12-Feb-2019



2.3 Other hazards

Not classified as PBT/vPvB by current EU criteriaThermal decomposition can lead to release of irritating gases and vapors



3.1 Substances

Not applicable

3.2 Mixtures










Symptoms





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Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid contact with:Strong oxidizing agents





Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished. No biological limit allocated






training Impervious gloves made of: Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Respirator withcombination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.



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Appearance No information availableOdor MildColor BrownOdor threshold No information available






Property Values Remarks pH 10pH @ dilution No information availableMelting / freezing point -2 °C / 28.4 °FBoiling point/range 104 °C / 219.2 °FFlash point No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure 14.2 mmHg @ 20 °CVapor density No information availableSpecific gravity 1.30Bulk density No information availableRelative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity <600 cstDynamic viscosity No information availablelog Pow No information available

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10.1 Reactivity







None known.


Strong oxidizing agents.


See Section 5.2.



Acute toxicity










Routes of Exposure Skin contact. Inhalation. Ingestion. Eye contact.

Routes of entry Ingestion. Inhalation.

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Not classified


Not classified.




12.1 Toxicity









12.4 Mobility





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None known.








14.1. UN number











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Revision date 12-Feb-2019

Version 3




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DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no

_____________________________________________________________________________________________


responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.

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SDS no. D047 Version 3 Revision date 03-Mar-2021 Supersedes Date: 21-Feb-2016

Safety Data Sheet Antifoam Agent D47



Product name Antifoam Agent D47 Product code D047


Recommended Use Antifoam in oilfield applications




Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600



GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

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Antifoam Agent D47 SDS no. D047 Revision date 03-Mar-2021



Contains No hazardous components 2.3 Other hazards




3.1 Substances


3.2 Mixtures

Not applicable




Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur.

Skin contact Wash skin thoroughly with soap and water. Seek medical attention if irritation occurs.

Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn. Get medical attention if any discomfort continues.



Symptoms





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Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Harmful organic chemical fumes.














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HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Avoid spills and splashing during use.




Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid excessive heat for prolonged periods of time. Avoid contact with: Strong acids Strong bases Strong oxidizing agents





Exposure limits The product does not contain any hazardous materials with occupational exposure limits established.





Personal protective equipment Eye protection Eye protection must conform to standard EN 166 Tightly fitting safety goggles Safety

glasses with side-shields Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee

training Repeated or prolonged contact Use protective gloves made of: Butyl Gloves- Neoprene, Nitrile Unless Specified Be aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection No personal respiratory protective equipment normally required In case of insufficient ventilation wear suitable respiratory equipment Respirator with combination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorly ventilated spaces,

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_____________________________________________________________________________________________


respiratory protection with air supply must be used. Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at the

work place.






Appearance Viscous Odor Odorless Color Colorless Odor threshold Not applicable

Explosive properties Not applicable Oxidizing properties None known.

9.2 Other information Pour point <0°C/32°F Molecular weight No information available


Property Values Remarks pH No data available pH @ dilution No information available Melting / freezing point < -35 °C / -31 °F Boiling point/range No information available Flash point 229 °C / 444.2 °F ASTM D-93 Evaporation rate (BuAc =1) No information available Flammability (solid, gas) Not applicable Flammability Limit in Air


Vapor pressure Not applicable Vapor density No information available Specific gravity 1 Bulk density No information available Relative density 1 @ 21.1°C. Water solubility Insoluble in water Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity 414 - 496 cst Dynamic viscosity No information available log Pow Not determined

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VOC content(%) None Density No information available



10.1 Reactivity







Avoid excessive heat for prolonged periods of time.


Strong acids. Strong bases. Strong oxidizing agents.


See Section 5.2.



Acute toxicity









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Routes of Exposure None known.



Not classified


Not classified.




12.1 Toxicity






Readily biodegradable.



12.4 Mobility

MobilityThe product is insoluble and floats on water.


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None known.















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Complies





Version 3




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HMIS classification



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SDS no. D095Version 5Revision date 30-May-2018Supersedes Date: 09-May-2016

Safety Data SheetD095 Cement Additive



Product name D095 Cement AdditiveProduct code D095









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

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_____________________________________________________________________________________________

D095 Cement Additive SDS no. D095Revision date 30-May-2018





Thermal decomposition can lead to release of irritating gases and vapors


3.1 Substances

Not applicable

3.2 Mixtures Not applicable






Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention if irritation persists.




Symptoms





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_____________________________________________________________________________________________
















Use personal protective equipment identified in Section 8.





Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading.

Methods for cleaning upAvoid generating or breathing dust. Sweep up and shovel into suitable containers for disposal. After cleaning, flush away traceswith water.



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Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dustis formed.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid dust formation








Personal protective equipmentEye protection Tightly fitting safety goggles Safety glasses with side-shieldsHand protection Use protective gloves made of: PVC Neoprene Nitrile Rubber Frequent change is advisableRespiratory protection In case of insufficient ventilation wear suitable respiratory equipment Effective dust mask.

Type P1 At work in confined or poorly ventilated spaces, respiratory protection with airsupply must be used.




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Appearance FibersOdor NoneColor WhiteOdor threshold Not applicable

Explosive properties None knownOxidizing properties No information available




10.1 Reactivity





Property Values Remarks pH No information availablepH @ dilution No information availableMelting / freezing point > 500 °C / 932 °FBoiling point/range No information availableFlash point No information availableEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 2.6 20 °CBulk density No information availableRelative density No information availableWater solubility InsolubleSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available

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Avoid dust formation.




See Section 5.2.



Acute toxicity













Not classified


Not classified.



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12.1 Toxicity






Not applicable.


Not applicable.

12.4 Mobility

MobilityThe product is insoluble and sinks in water.





None known.


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_____________________________________________________________________________________________



















USA (TSCA) Does not complyCanada (DSL) Does not complyPhilippines (PICCS) Does not complyJapan (ENCS) Does not complyChina (IECSC) CompliesAustralia (AICS) Does not complyKorean (KECL) Does not complyNew Zealand (NZIoC) Complies

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_____________________________________________________________________________________________




Supersedes Date: 09-May-2016


Version 5


1, 7, 8, 15, 16 No changes with regard to classification have been made.



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SDS no. D081Version 4Revision date 12-May-2020Supersedes Date: 27-Mar-2018

Safety Data SheetLiquid Retarder D81



Product name Liquid Retarder D81Product code D081









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

_____________________________________________________________________________________________

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_____________________________________________________________________________________________

Liquid Retarder D81 SDS no. D081Revision date 12-May-2020







3.1 Substances

Not applicable

3.2 Mixtures










Symptoms





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HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid breathing vapors ormists. Avoid spills and splashing during use.




Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away fromdirect sunlight. Store away from incompatibles, Strong acids Strong oxidizing agents









Engineering ControlsEnsure adequate ventilation Local exhaust ventilation



training Impervious gloves made of: Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Use respirator withorganic vapor protection (A, brown) At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.


Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothing

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_____________________________________________________________________________________________


before re-use





Appearance Aqueous solutionOdor Of burnt sugar / SlightColor Dark brownOdor threshold Not applicable





Property Values Remarks pH 3.5 - 5.1pH @ dilution No information availableMelting / freezing point No information availableBoiling point/range No information availableFlash point Does not flashEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure Not applicableVapor density No information availableSpecific gravity 1.24 - 1.26 @ 27 °CBulk density No information availableRelative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature 400 °C / 752 °FDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity 350 mPa.s @ 20 °Clog Pow No information available

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_____________________________________________________________________________________________



10.1 Reactivity







Keep away from direct sunlight.


Strong oxidizing agents. Strong acids.


See Section 5.2.



Acute toxicity












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_____________________________________________________________________________________________



Not classified


Not classified.




12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganismsListed on PLONOR list of OSPAR








12.4 Mobility





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_____________________________________________________________________________________________



None known.


















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Version 4


9, 12, No changes with regard to classification have been made.

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Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory information

_____________________________________________________________________________________________


National occupational exposure limits


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SDS no. D175AVersion 4Revision date 29-Apr-2020Supersedes Date: 19-Jun-2015

Safety Data SheetAntifoam Agent D175A



Product name Antifoam Agent D175AProduct code D175A









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

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Antifoam Agent D175A SDS no. D175ARevision date 29-Apr-2020



ContainsNon-crystalline silica

2.3 Other hazards




3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name EC No CAS No Weight-%Non-crystalline silica Listed Proprietary 1 - 5

CommentsNo classified ingredients, or those having occupational exposure limits, present above the level of disclosure.









Symptoms



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Suitable extinguishing mediaExtinguish with carbon dioxide, dry chemical, foam or waterspray.










Use personal protective equipment. See also section 8. Solutions extremely slippery when spilled.







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_____________________________________________________________________________________________





HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid breathing vapors ormists. Avoid spills and splashing during use.




Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep at atemperature not exceeding 25 °C Store away from incompatibles, Strong oxidizing agentsUV or Ionising Radiation. Steel





Exposure limits Because this product is a liquid, the dust-related Workplace Exposure Limits for thecomponents do not apply.


Chemical Name Arabic Australia EgyptNon-crystalline silica Not determined 2mg/m3TWArespirable dust Not determined

Chemical Name India Indonesian JapanNon-crystalline silica 10 mg/m3 TWA Not determined Not determined

Chemical Name Kazakhstan Kuwait New ZealandNon-crystalline silica 1 mg/m3 MAC

2 mg/m3 MAC6.0 mg/m3 TWA Not determined

Chemical Name Malaysia Philippines RussiaNon-crystalline silica Not determined Not determined 3 mg/m3 STEL

6 mg/m3 STEL1 mg/m3 TWA2 mg/m3 TWA

Fibrogenic substance also vitreous,in the form of disintegration aerosol

1177Fibrogenic substance in the form ofcondensation aerosol, containing>=10% Silicon dioxide 1175, 1176

Chemical Name Thailand Vietnam TurkeyNon-crystalline silica Not determined Not determined Not determined


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_____________________________________________________________________________________________






trainingImpervious gloves made of: Neoprene Nitrile Butyl RubberBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Respirator withcombination filter for vapor/particulate Type A/P2 At work in confined or poorly ventilatedspaces, respiratory protection with air supply must be used.







Appearance Aqueous solutionOdor SlightColor Milky whiteOdor threshold Not applicable


Property Values Remarks pH ~ 5pH @ dilution No information availableMelting / freezing point ~ 0 °C / 32 °FBoiling point/range 100 °C / 212 °FFlash point Not applicableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air

Upper flammability limit Not applicable

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_____________________________________________________________________________________________






10.1 Reactivity







Avoid heat, flames and other sources of ignition.


Strong oxidizing agents. UV or Ionising Radiation. Steel.


See Section 5.2.



Acute toxicity

Lower flammability limit Not applicableVapor pressure 2.3 kPa @ 20 °CVapor density No information availableSpecific gravity ~ 1 @ 25 °CBulk density No information availableRelative density No information availableWater solubility DispersibleSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity ~ 100 mPa s @ 25 °Clog Pow No information available

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Chemical Name LD50 Oral LD50 Dermal LC50 InhalationNon-crystalline silica = 7900 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 2.2 mg/L ( Rat ) 1 h





Routes of Exposure Skin contact. Inhalation. Ingestion. Eye contact.



Not classified


Not classified.




12.1 Toxicity


Toxicity to algaeThis product is not considered toxic to algae. See component information below.

Toxicity to fishThis product is not considered toxic to fish. See component information below.

Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates. See component information below.


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aquatic invertebratesNon-crystalline silica = 5000 mg/L LC50 Brachydanio

rerio 96 h= 440 mg/L EC50

Pseudokirchneriella subcapitata 72h

= 7600 mg/L EC50 Ceriodaphniadubia 48 h


The product is not expected to be biodegradable. See component information below.

Chemical Name Persistence and degradabilityNon-crystalline silica No information available


The product does not contain any substances expected to be bioaccumulating. See component information below.

Chemical Name BioaccumulationNon-crystalline silica Not likely to bioaccumulate

12.4 Mobility

MobilityDispersible in water.





None known.







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_____________________________________________________________________________________________





















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USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) Does not complyChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies




Revision date 29-Apr-2020

Version 4


8, 11, 12, 15, 16 No changes with regard to classification have been made.



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SDS no. D013Version 6Revision date 15-Jan-2020Supersedes Date: 17-Nov-2015

Safety Data SheetRetarder D013



Product name Retarder D013Product code D013









GHS Classification




2.2 Label elements

Signal wordNone


[email protected]

_____________________________________________________________________________________________

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_____________________________________________________________________________________________

Retarder D013 SDS no. D013Revision date 15-Jan-2020







3.1 Substances

Not applicable

3.2 Mixtures










Symptoms





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_____________________________________________________________________________________________








Unusual fire and explosion hazardsSuspended dust may present a dust explosion hazard.

Hazardous combustion productsFire or high temperatures create: Sulphur oxides, Carbon oxides (COx), Heating or fire can release toxic gas.






Use personal protective equipment. See also section 8. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking.






Methods for cleaning upSweep up and shovel into suitable containers for disposal. Take precautionary measures against static discharges. After cleaning,flush away traces with water.



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_____________________________________________________________________________________________






Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Takeprecautionary measures against static discharges.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away from openflames, hot surfaces and sources of ignition Avoid contact with: Strong oxidizing agentsStrong acids Strong alkalies.









Personal protective equipmentEye protection Eye protection must conform to standard EN 166 Tightly fitting safety goggles Safety

glasses with side-shieldsHand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee

training Impervious gloves made of: Neoprene Nitrile Rubber Frequent change is advisableRespiratory protection In case of insufficient ventilation wear suitable respiratory equipment Half mask with a

particle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.



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_____________________________________________________________________________________________






Appearance PowderOdor FaintColor BrownOdor threshold Not applicable






Property Values Remarks pH No information availablepH @ dilution 4 - 5Melting / freezing point No information availableBoiling point/range No information availableFlash point No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 1.2 20 °CBulk density 480 kg/m3

Relative density No information availableWater solubility SolubleSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available

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_____________________________________________________________________________________________


10.1 Reactivity







Avoid dust formation. Take precautionary measures against static charges. Avoid heat, flames and other sources of ignition.


Strong oxidizing agents. Strong acids. Strong alkalies.


See Section 5.2.



Acute toxicity

Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough. May cause irritation of respiratory tract.











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_____________________________________________________________________________________________



Not classified


Not classified.




12.1 Toxicity









12.4 Mobility





_____________________________________________________________________________________________

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_____________________________________________________________________________________________



None known.



















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_____________________________________________________________________________________________















Supersedes Date: 17-Nov-2015

Revision date 15-Jan-2020

Version 6




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RCMA-02-EM-PLN-001SUMv4 APPENDIX C

Risk Assessment Aspects ranked ‘MODERATE’ and above

Risk Identification Pre-treatment Risk Assessment Risk Treatment (Safeguards / Management Methods)

Post-treatment Risk Assessment # Aspect Source of Risk Potential Impact Consequence Likelihood Risk Ranking Consequence Likelihood Risk Ranking Site Preparation

1. Soil and Landform

Significant change in landform resulting in erosion/loss of topsoil

Increased risk of erosion due to change in drainage patterns

3 C C3 Medium

• Ongoing routine monitoring and maintenance throughout operations to address erosion or loss of landform

• Storage of topsoil lightly compacted to a height of no more than 2m and covered with brushto minimise erosion potential

• Drainage control implemented such as erosion berms

3 B B3 Medium

3. Vegetation

Clearing of access track and well pad impacts flora

Impacts to conservation significant flora and native vegetation, resulting in significant loss of species or community, significant fauna habitat

3 C C3 Medium

• Use of existing tracks to reduce areas of clearing • Desktop 1 Flora and Vegetation study undertaken with reconnaissance survey • Cleared vegetation to be stockpiled separately from topsoil (covered in brush)

and in windrows less than 2 m high • Areas to be cleared will be clearly demarcated • Induction of construction personnel on areas approved for clearing • Vehicles and equipment movement will be restricted to the designated tracks.

3 B B3 Medium

Clearing outside permitted footprint

3 C C3 Medium

• Site plan prepared in accordance with EP requirements • Areas to be cleared will be clearly demarcated • Induction of construction personnel on areas approved for clearing

3 A A3 Low

4. Weeds

Equipment presence on site results in spread of invasive species

Weed invasion or introduction of dieback

4 C C4 High

• Flora reconnaissance survey identifies general level of weed cover • Earthmoving equipment will be inspected and cleaned down prior to

mobilisation to site • Sheeting materials (marl to minimise dieback risk) brought to site are sourced

locally. The borrow pit is managed to minimise risk of weeds (topsoil exclusion) • Hygiene station is established during site preparation activities (including lined

pad with drainage sump, brushes/brooms and weatherproof container for inspection register)

• Vehicles and equipment are to arrive on site in a clean state and conduct inspection on site in accordance with the Hygiene Procedure including sign off on the hygiene inspection checklist

• Controlled access to site reduces the potential for weed invasion • Personnel are required to complete the induction which outlines weed and

dieback management

4 B B4 Medium

5. Dieback

6. Soil Contamination

Ruptured fuel / oil tank during clearing vegetation activities

Localise soil contamination 2 C C2

Medium

• Refuelling vehicle to have refuelling drip tray, spill kit and contaminated soil bunding tarp (for segregation of material if a spill occurs prior to disposal)

• Vehicles preferentially refuel offsite • OSCP in place and induction includes the requirements of personnel • Contaminated material is taken offsite for reuse or disposal • Refuelling vehicle is on site during daylight hours only • Construction vehicles are left locked when unattended

2 B B2 Low

Spill while refuelling construction vehicle Sabotage of equipment present on site during construction activities (overnight)



Post-treatment Risk Assessment # Aspect Source of Risk Potential Impact Consequence Likelihood Risk Ranking Consequence Likelihood Risk Ranking

7. Indigenous Heritage

Clearing of access track and initial earthworks for well pad construction and potential impacts to heritage values

Loss of heritage value due to disturbance of heritage site.

3 C C3 Medium

• Cervantes heritage and archaeological survey undertaken • Induction of site personnel to identify potential risk of encountering artefacts of

heritage value, and required actions and reporting if items identified 3 B B3

Medium

8. Emissions (Dust)

Localised generation of dust significantly impacting air quality (vegetation disturbance activities, vehicle movements)

Reduced air quality 1 E E1 Medium

• Speed limits for vehicle traffic imposed across Project area • Induction of site personnel on vehicle speed limits • The application of water (or appropriate suppressants) to access roads, working

surfaces and stockpiles (as required)

1 E E1 Medium

Mobilisation / Demobilisation

10. Emissions (Dust)

Localised generation of dust significantly impacting air quality


• Water spray on soil and /or access track as required • Speed limits adhered to in order to reduce dust emissions • Induction includes vehicle speed limits

1 D D1 Low

11. Emissions (Noise)

Noise from vehicles, equipment, and general setup activities

Noise impacts native fauna 2 D D2

Medium

• Maintenance of equipment and vehicles per manufacturer recommendations • Vehicles and equipment to be used only within the approved project footprint,

i.e. hygiene station, access tracks, campsites and well pad, to minimise disturbance of fauna.

• The activities are short term and not located within a noise sensitive locality

2 C C2 Medium

13.

Weeds Equipment and vehicle presence on site results in significant spread of weed species and soil pathogens


4 C C4 High

• No dieback symptoms identified during field survey • Vehicles and equipment arrive to site in a clean state - hygiene inspection

checklist completed • Hygiene station in place and managed, as a minimum the hygiene station will

include a lined pad with drainage sump, brushes/brooms and weatherproof box for inspection register).

• Controlled access to site reduces potential for weed invasion • Induction process to educate personnel on weed and dieback

4 B B4 Medium Dieback

Drilling / Well Testing




• Water spray on well pad and /or access track as required • Speed limits in place for vehicle traffic • Induction includes vehicle speed limits

1 D D1 Low

16. Emissions (Noise)

Noise from vehicles and equipment being a nuisance, noise from drilling / well testing

Noise impacts native fauna 2 D D2

Medium

• Maintenance of equipment and vehicles per manufacturer recommendations • Vehicles and equipment to be used only within the approved project footprint,

i.e. hygiene station, access tracks, campsites and well pad, to minimise disturbance of fauna

• The drilling / well testing activities are short term and not located within a noise sensitive locality

• Consultation with near-by neighbours

2 C C2 Medium




19. Weeds Presence of

infrastructure on site


4 C C4 High

• Vehicles and equipment arrive to site in a clean state • Hygiene station in place and managed in accordance with Hygiene Procedure

[RCMA-02-EM-PRO-001] • Induction process to educate personnel on weed and dieback requirements

4 B B4 Medium

Dieback

20. Landowner / Socioeconomic

Operations disturb neighbouring landowner or nearby stakeholders

Noise, aesthetics, land use change, traffic

3 C C3 Medium

• Stakeholder engagement prior to commencement of activity • Noise and aesthetic impacts are anticipated to be negligible when considering

the remote location, duration of activity and distance to nearest sensitive receptors.

• The nearby stakeholders would be engaged on timing of the activity and key periods of traffic flow to minimise disruption.

• Consultation as part of self-referral to EPA

3 B B3 Medium

21. Ground water

Mud/cutting spills Mud/cuttings leaching from sump

Localised soil or groundwater impact 4 C C4

High

• Maintaining 0.5 m freeboard within the sump to minimise potential for overflow • The mud sump will be lined with Enviro Liner 6030HD liner (hereafter referred to

as ‘Enviro Liner’) (Thickness: 0.75 mm; Water Vapour Permeability 3 x 10-13 cm/sec)

• Benign water-based muds • Baseline monitoring to characterise groundwater prior to commencement of

activity

4 B B4 Medium

Groundwater extraction

Contribution to depletion of groundwater resources

0 E E0 Negligible

• Flow meter to monitor usage • Quantities of water required for drilling operations unlikely to drawdown aquifer • 26D licence to construct in place • 5C licence to take water in place

0 E E0 Negligible


Incorrect management of sewage treatment (on site)

Local soil contamination 2 C C2

Medium

• Septic holding tanks pumped out and taken offsite by Controlled Waste Carrier for disposal

• Level alarm on holding tank 2 B B2

Low

Care and Maintenance

27. Weeds Equipment presence on site results in spread of invasive species


4 B B4 Medium

• Vehicles and equipment will be inspected and cleaned down prior to mobilisation to site in accordance with Hygiene Procedure including sign off on the hygiene inspection checklist

• Personnel are required to complete the induction which outlines weed and dieback management

• JPF personnel undertake inspections of well pad and access track during C&M (weekly) and rehabilitation (monthly) phases of project which include observations for weed infestations

• Bi-annual weed control program in place during C&M and Rehabilitation phases of project

4 A B4 Low

28. Dieback


Security Issues associated with suspended wells and associated infrastructure remaining at site

Sabotage resulting in infrastructure damage and product or waste release to the environment

3 C C3 Medium

• Well cellar is fenced and locked with signage demarcating the name of the well, responsible entity, contact number and hazards associated with the well

• All non-fixed equipment is taken offsite at demobilisation unless brought onsite under supervision / securely locked

• Suspended wells are isolated via tubing plugs and/or well head back pressure valve

3 B B3 Medium

Decommissioning / Rehabilitation



Reduced air quality 2 D E1 Medium

• Water sprayed on soil and /or access track as required • Speed limits in place for vehicle traffic • Induction includes vehicle speed limits

2 D E1 Medium




25.

Vegetation

Inadequate progression to rehabilitation Poor Rehabilitation Results Increased weed invasion, erosion, dust

Land degradation/decreased in biodiversity

4 C C4 High

• Validation sampling undertaken at key stages (i.e. removal of mud sump or flare pit)

• Waste material sampled and classified in accordance with the Landfill Waste Classification and Waste Definitions 1996 (as amended) (DEC 2009)

• Reputable earthworks contractor used to undertake works in accordance with defined scope

• Well site handover form completed for Care and Maintenance; routine workplace inspections undertaken thereafter

• Rehabilitation Plan with completion criteria implemented within 2 years of well decommissioning

• Completion criteria monitoring and remedial actions where rehabilitation unsuccessful

• Vehicles and equipment arrive to site in a clean state - hygiene inspection checklist completed in accordance with Hygiene Procedure [RCMA-02-EM-PRO-001].

• Controlled access to site reduces potential for weed invasion • Induction process to educate personnel on weed and dieback management

4 B B4 Medium

Soil and Landform

Weeds

Dieback


Security Issues associated with suspended wells and associated infrastructure remaining at site

Sabotage resulting in infrastructure damage and product or waste release to the environment

3 C C3 Medium

• Well cellar is fenced and locked with signage demarcating the name of the well, responsible entity, contact number and hazards associated with the well

• All non-fixed equipment is taken offsite at demobilisation unless brought onsite under supervision / securely locked

• Suspended wells are isolated via tubing plugs and/or well head back pressure valve

3 B B3 Medium

27. Weeds Equipment presence on site results in spread of invasive species


4 C C4 High

• Earthmoving equipment will be inspected and cleaned down prior to mobilisation to site

• Vehicles and equipment are to arrive on site in a clean state and conduct inspection on site in accordance with the Hygiene Procedure including sign off on the hygiene inspection checklist

• Personnel are required to complete the induction which outlines weed and dieback management

• Rehabilitation Plan to be submitted to DMIRS will outline measures during rehabilitation and over following periods to manage and control the spread of weed species and remediation actions to be implemented if required

4 B B4 Medium

28. Dieback


Localised contamination of soil

Reduced soil quality Potential for soil contamination

2 C C2 Medium

• Drilling sump materials will be taken offsite for disposal / reuse • Validation sampling on site will confirm no potential contamination has been left

2 B B2 Low

Unplanned Event

30. Fire Uncontrolled fire due to on-site activities

Potential habitat destruction 4 C C4

High

• All project site vehicles on site (at all stages of Project) have a serviceable fire extinguisher

• A mobile water cart is available on-site during construction, drilling and rehabilitation activities

• Smoking is permitted in designated areas only • Hot work is conducted under permit • Firebreaks surrounding drill site • Fire extinguishers located around the rig • General housekeeping • Rig identified electrical zoning areas and equipment suitably rated within areas

4 B B4 Medium




32. Loss of Containment

Spill of diesel or hazardous liquid from delivery truck

Contamination of soil Contamination of Groundwater Degradation of Vegetation

4 B 4B Medium

• Standard operating procedures in place for handling and use of hazardous materials

• Spill kits are located as per OSCP • ERP and OSCP in place • Large diesel storage tank is self-bunded • Diesel transfer operations are manned • Spill trays are utilised for all diesel transfers • Drilling operations are conducted on 24-hour basis with light towers and

monitoring regime would result in prompt identification of a spill • Bunding of liquid chemicals in accordance with SDS requirements • Bunds are inspected during housekeeping inspections to determine integrity and

maintenance of capacity

4 A A4 Low

33. Well Control Situation

Worst case scenario well-blow out, fire, hydrocarbon contamination

Contamination of local environment – air, ground, noise Fire risk for Reserve

5 B B5 High

• Use Blow Out Preventor (BOP) that is operated and maintained as per OEM standard

• Double barrier philosophy • Standard well control practices implemented • Well control certificates for senior drilling personnel • Certified and tested equipment utilised • DMIRS approved drilling program • Competent and trained crew required to undertake periodic well control drills • Safe area on site to vent / flare in the case of an emergency • Pre-identified well control response contractor

5 A A5 Medium

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