Cengel ch11

13
CHAPTER 11 Thermodynamic Property Relations

description

 

Transcript of Cengel ch11

Page 1: Cengel ch11

CHAPTER

11

Thermodynamic Property Relations

Page 2: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

11-1

FIGURE 11-1The derivative of a function at a specified point represents the slope of the function at that point.

Page 3: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

FIGURE 11-3Geometric representation of partial derivative (/)y.

11-2

Page 4: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

11-3

FIGURE 11-4Geometric representation of total derivative dz for a function z (x, y).

Page 5: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

11-4

FIGURE 11-5Geometric representation of the disturbance discussed in Example 11–2.

Page 6: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

11-5

FIGURE 11-6Demonstration of the reciprocity relation for the function z + 2xy - 3y2z = 0.

Page 7: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

11-6

FIGURE 11-8Maxwell relations are extremely valuable in thermodynamic analysis.

Page 8: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

11-7

FIGURE 11-9The slope of the saturation curve on a P-T diagram is constant at a constant T or P.

Page 9: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

11-8

FIGURE 11-10The volume expansivity (also called the coefficient of volumetric expansion) is a measure of the change in volume with temperature at constant pressure.

Page 10: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

11-9

FIGURE 11-13The development of an h = constant line on a P-T diagram.

Page 11: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

11-10

FIGURE 11-14Constant-enthalpy lines of a substance on a T-P diagram.

Page 12: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

11-11

FIGURE 11-16An alternative process path to evaluate the enthalpy changes of real gases.

Page 13: Cengel ch11

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.FIGURE 11-17An alternative process path to evaluate the entropy changes of real gases during process 1-2.

11-12