纳米压印技术最新进展 - iphy.ac.cnin.iphy.ac.cn/upload/1707/201707201258172526.pdf ·...
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纳米压印技术最新进展
Obducat Technologies AB., SwedenGang Luo, 20170711
General company presentation - © Obducat 2017 CONFIDENTIAL
History
1989 Company is founded, aiming at replacing LBR mastering technology with EBR
1996 Development of Nano Imprint begins together with LTH
1997 Listing on the Stock Exchange and first working EBR is produced
1999 Soft Press Key Imprint technology is Patented by Obducat
2000 Both the first EBR and the first NIL system are sold
2002 First Asian orders for NIL and first NIL into Semiconductor area
2004 Completed the development of process for mass-production
2005 IPS® and STU ® introduced on the market
2006 Breakthrough order for NIL production system, Samsung launches products with “Obducat Inside”, SEM “Apollo” product range is launched
2007 Epistar place order on the newly launched of SINDRE ® HVM
2008 Sold the first SINDRE ® 400 for LED production and reached an commercial agreement concerning SINDRE ® HDD development
2013 Sold the first SINDRE ® production system for BIO applications
2013 Launched UV based NIL process for mass-production
2014 Launch and sell SINDRE ® 400 Gen2 system with UV based process
2016 Launch of SINDRE ® Large Area
2015 Acquire Solarsemi Gmbh
2015 Awarded by NNT for “Pioneering NIL into production”
General company presentation - © Obducat 2017 CONFIDENTIAL
One company - Two locations
Obducat AB (mother company) & Obducat Technologies AB (NIL branch)
Solarsemi Gmbh (Coating branch)
~1hr flight
• > 40 employees
• Application laboratory
• Founded 2009
• More than 35 world
wide patents
• More than 300 installed
systems
• Located in Radolfzell,
Germany
• > 30 employees
• Application laboratory
• Class 100 cleanroom
• Founded 1989
• More than 140 world
wide patents
• More than 140 installed
systems
• Located in Lund,
Sweden
General company presentation - © Obducat 2017 CONFIDENTIAL
Obducat – the Pioneer of NIL industrialization
2016 Obducat celebrate 20 years anniversary for its NIL products!
Obducat started developing materials, processes and machinery's 1996 and installed the first sold NIL system already year 2000.
Since then we have established a leading position in the market of NIL-production with an installation base far exceeding any competitor.
More than 140 customer installations world-wide
Obducat is the only NIL supplier that have sold NIL systems being used in commercial mass production.
Obducat has created the strongest Patent portfolio in the business.
More than 140 granted patents
Since the start of the NIL product range, Obducat has developed and delivered more NIL projects than any other NIL company.
For 20 years Obducat has built knowledge in the up & down stream processes required for successful NIL implementation in real production environment.
This competence is available to all our customers!
Recently Obducat acquired the company Solarsemi, supplying the highest quality coating equipment in the industry, with the purpose to supply complete and integrated production solutions.
Utilizing the IP developed in-house and the knowledge gained from application development projects the last 20 years, Obducat can offer the most comprehensive range of lithography solutions and application support for Nano and Micro patterning in the business
Application examples
Product overview – Nano Imprint Equipment
• Hard Disc • Academic R&D
• Optical Components• Lenses
• High density interconnects• Display
• LED• Solar cell
EITRE-Line
Manual R&D tools
Stand-alone
Nanoimprinters
- Eitre® 3”
- Eitre® 6”
- Eitre® 8” (8” x 8”)
EITRE-Line Large Substrates
Semiautomatic systems
NIL tool for Display standard sizes up
to Gen 5. Suitable for both Thermal,
UV and STU processes. Semi-
automatic Imprint process
– up to GEN 5 size
SINDRE-Line
Fully automated systems
Production systems with throughput
~60wph (LED) and cassette handling
- Imprint size 4” – 8” wafers
- Other sizes and applications upon
request including > Display Sizes Gen 5
Consumables
Master stamps
Silicon, Quartz & Nickel
IPS ® and STU ® materials
Polymer and resist materials
with various characteristics that
can be tailored for a specific
applications
High degree of customization possible!
By fully owned subsidiary Solarsemi, Obducat can offer a wide range of fully automatic and semiautomatic lithography equipment solutions for semiconductor, display and substrate processing applications.
Applications
Product overview – Coating and wet-processing
• Priming• Spin coating
(open bowl or RCCT)
• Spray coating• Baking• Developing
• Lift-off• Stripping
• Etching• Cleaning• Post CMP cleaning
EL-Line (easyline)
Manual lab spinner
module
– up to Ø8” (Ø200 mm)
QS-Line (quickstep) Large Substrates
Semiautomatic systems
Stand-alone spin-coater, spray-coater,
developer, wet-process spinner, hot-,
cool & HMDS-plates – manual or full
automatic robotic system
– up to GEN 5 size
QS-Line (quickstep)
Bench mounted & stand-alone
spin-coater, spray-coater,
developer, wet-process
spinner, hot-, cool & HMDS-
plates for low volume
production
– up to Ø12” (Ø300 mm)
MC-Line (microcluster)
Fully automatic production systems
Consisting of platforms with robot
handling and all lithography processes
from coating, baking to development
and cleaning application
General company presentation - © Obducat 2017 CONFIDENTIAL
All our NIL systems are based on the patented Soft Press® Technology.
Air Pressure parallelism thin and uniform residual layer!
How does Obducat NIL work?
•Independent of stamp & substrate thickness variations, bow or waviness
•Any resist thickness
•High Imprint depth uniformity
•Homogenous pressure distribution
Always full area imprint in one shot!
Possible to print on curved surfaces!
General company presentation - © Obducat 2017 CONFIDENTIAL
Obducat NIL technology: Imprint Technology
Stephen Y. Chou et al Nano Lett., Vol. 6, No. 11, 2006
General company presentation - © Obducat 2017 CONFIDENTIAL
Obducat’s patented technologies
Key words about Obducat’s NIL technology:
Soft Press® technology
– Obducat’s replication technology, using air
pressure to ensure a uniform replication with
high repeatability wafer-to-wafer.
IPS®
– The Intermadiate Polymer Stamp® is used as a
transfer step to overcome substrate unflatness.
– Extends stamp lifetime
– Reduce stamp cost per imprint
STU®
– Simultaneous Thermal and UV® imprint is
applied to the substrate in order create a
uniform resist layer and ensure a high
throughput.
Master stamp
Master stamp
Imprint Step 1:UV-transparent polymer
IPS®
STU® -polymerSubstrate
IPS®
STU® -polymer
const. working temperature
Imprint Step 2:UV-radiation
IPS®
General company presentation - © Obducat 2017 CONFIDENTIAL
Obducat NIL technology: Imprint Technology
Substrate
Hard Stampparticle
Traditional Hard Stamp IPSTM Benefits
• Eliminates “halo-defect”
Si-master
IPS
particle
• Self-cleaning of stamper
• No damage risk to stamp/substrate
• Increased master stamp lifetime Substrate
Hard Stamp
particle
Substrate
particle
IPSHard Stamp
particlevoid
Substrate
Substrate
particle
IPS
General company presentation - © Obducat 2017 CONFIDENTIAL
LED production using NIL
General company presentation - © Obducat 2017 CONFIDENTIAL
NIL Equipment Production
• Sindre® 400 G2 (Up to 4” substrate size)
• Sindre® 600 G2 (Up to 6” substrate size)
• Sindre® 800 G2 (Up to 8” substrate size)
• General lead time indication is 12-16 weeks
after purchase order
Key specifications and information
• Throughput up to 60 wph
• Edge exclusion zone is 500 µm
• Changeover time between substrate sizes is < 1 hour
• Changeover time for stamp change is < 30 min
The SINDRE tool for mass production
Nano Imprint Lithography for High Volume Manufacturing
NIL quality performance
Example Uniformity data on 4-inch substrate
Customer uniformity data shows that the Obducat NIL technology gives excellent performance;• Top diameter 1.25%• Bottom diameter 0.94%• Height 1.15%
Measurement on 4-inch PSS based on AOI
General company presentation - © Obducat 2017 CONFIDENTIAL
True imprinting to the edge of wafer
AOI example data
Defect count in FAB environment
Measurement after ICP process.
General company presentation - © Obducat 2017 CONFIDENTIAL
Increased manufacturing efficiency
• Transition to larger substrates - improves production equipment utilization
• Higher level of pattern uniformity using NIL instead of optical lithography – leads to higher amount of good dies on each wafer and thereby reduced cost
Improved device efficiency and reduced cost
• Transition from µPSS to nPSS offers opportunity to;
• Increase energy efficiency
• Increased equipment throughput
• Lower consumable costs
• With improved efficiency thermal management issues can be reduced which enables cost reduction in packaging technology
Routes for cost reduction - µPSS & nPSS
General company presentation - © Obducat 2017 CONFIDENTIAL
To use the verticalization effect – for higher light extraction
Use a more vertical light path obtained in the moth-eye layer to minimize the number of reflections in LED chips before light escapes and thereby to reduce absorption. Therefore Moth-eye Patterned Sapphire Substrate (MPSS) are suggested to be used instead of micron size patterned Sapphire substrates (PSS)
MPSS characteristics
• Submicron order period structure.
• Light diffraction - large front luminescence improvement effect.
• Thin GaN layer – lower production cost and less wafer bowing.
Next Generation LEDs – e.g nano based PSS
Diffraction at MPSS interface
GaN bottom layer
MPSS
n-layer
Emission layer
p-layer
High reflectance electrode
Sapphire
GaN
General company presentation - © Obducat 2017 CONFIDENTIAL
• The NW’s can be produce either by top-down or bottom up approach
• Irrespective of production approach, NIL is used to place the NW’s where you want them. NIL is the most suitable nano patterning method for large areas
Next Generation LEDs – e.g Nano wires
75nm Holes printed on wafer for pillar growth
General company presentation - © Obducat 2017 CONFIDENTIAL
Applications: Nanowires pattering for LED
The lifted sample can be used for MOCVD growth directly
Overview presentation © Obducat AB 2017 - All rights reserved
General company presentation - © Obducat 2017 CONFIDENTIAL
• The efficiency of nanowire based LEDs is expected to be higher compared to conventional µPSS and nPSS LEDs.
• An even bigger advantage is the expected yield improvment i.e more high performance LEDs from a wafer compared to today which will lead to higher revenues generated from a single wafer
Next Generation LEDs – e.g Nano wires
General company presentation - © Obducat 2017 CONFIDENTIAL
Bio / Medical
General company presentation - © Obducat 2017 CONFIDENTIAL
Life Science – applications
• Drug delivery
• Drug development
• Diagnostic sensors
• Electrochemical sensors
• 3D scaffold tissue engineering
• Contact lens for glucose measurement
Obducat supplied the pilot production line to Kimberly-Clark for manufacturing of the drug delivery devices in Q4 2013.
Problems with regard to maintaining the activity level of delivered agents and avoidance of foreign body and immune response can be inhibited by mimicking the cell structure.
General company presentation - © Obducat 2017 CONFIDENTIAL
Obducat supplied the first production line for manufacturing of Nanostructured Transdermal devices in Q4 2013.
Bio / Medical - Transdermal Drug Delivery
General company presentation - © Obducat 2017 CONFIDENTIAL
Bio /Medical - Bio sensor
SEM picture shows topview a Nano-Bio sensor produced by Nano-Imprint lithography supplied by Obducat
SEM picture shows topview a Nano-Bio sensor produced by Nano-Imprint lithography by Obducat
© Obducat
Bio / Medical - Nano-electrodes for Bio-chemical sensors
MATSENS : Lab-on-a-chip platforms based on microfluidic and electrochemical systems.
- NIL is used to fabricate nano-electrodes or incorporate nanostructure on the electrodes to go beyond the current level of sensor performance.
General company presentation - © Obducat 2017 CONFIDENTIAL
Bio / Medical – High aspect ratio
SEM picture shows side view of high aspect ratio features etched into Si after NIL patterning by Obducat
18
0,43,6
Stamper
Imprint on 6”-Silicon
14 m
3,5 m
Silicon
Polymer
NO residual layer
General company presentation - © Obducat 2017 CONFIDENTIAL
Displays
General company presentation - © Obducat 2017 CONFIDENTIAL
Displays
Three areas where NIL can create improvements
• Polarizer
• Color filters
• TFTs
The benefits are;
• Improved image quality
• Improved light tranmission
• Extended battery lifetime
• Reduced costs
• Thinner displays
General company presentation - © Obducat 2017 CONFIDENTIAL
Displays – various projects since many years
Al gate for organic transistor
Flexible displaysEU & Taiwan
E-paper displaysJapan
LCD displaysEU, Taiwan & China
Wire Grid PolarizersKorea, Japan, Taiwan & China
General company presentation - © Obducat 2017 CONFIDENTIAL
Large Area NIL Nickel stamp for Flat panel display
General company presentation - © Obducat 2017 CONFIDENTIAL
Industry's first large Nickel stamp for Display applications made 2008(E-paper)
General company presentation - © Obducat 2017 CONFIDENTIAL
Wire Grid Polarizer – function & pitch
Smaller Pitch ▶ Higher Extinction
Currently Display Industry plan for use of 100nm pitch
General company presentation - © Obducat 2017 CONFIDENTIAL
nWGP manufacturing for LCD
Stamp Fabrication
Metal Deposition
Residual Layer Removal- Uniform O2 RIE over large-area
Aluminum RIE & Resist Strip- Large-area nanoscale ICP RIE
NanoImprint
- Large-area stamp
- Pattern uniformity
- Residual layer uniformity
- Defect-free demolding
Resist Coating
- Thickness< 100 nm
over large area
Large-area NIL stamp
1. Step and repeat tiling2. Interference lithography
General company presentation - © Obducat 2017 CONFIDENTIAL
SEM picture shows top view of imprinted polarization pattern
SEM picture shows Cross section of imprinted polarization pattern
Large Area NIL - Nano Wire Grid Polarizer
General company presentation - © Obducat 2017 CONFIDENTIAL
Small size example from Customer project
SEM images of the final etched Al gratings, section view.
55nm linewidth, 45nm space, 248nm depth
General company presentation - © Obducat 2017 CONFIDENTIAL
• Typical lens aperture size: 10-1000 µm
• Typical lens height: 5-300 µm
Applications: Opto-Electronics
Overview presentation © Obducat AB 2017 - All rights reserved
General company presentation - © Obducat 2017 CONFIDENTIAL
Optical components
General company presentation - © Obducat 2017 CONFIDENTIAL
Optical components – Applications
• Patterning of lenses for images sensors
• Manufacturing of DFB lasers
• Reflective and diffractive patterns
• Photonic devices
• Plasmonic devices
Applications: sub-wave length grating on InP
Overview presentation © Obducat AB 2017 - All rights reserved
General company presentation - © Obducat 2017 CONFIDENTIAL
PhotoVoltaics
General company presentation - © Obducat 2017 CONFIDENTIAL
Increased manufacturing efficiency
• Transition to larger substrates - improves equipment utilization
• Transition to thinner substrates – reduce raw material costs
• Consistent manufacturing quality – reduce sorting
Improved efficiency
• Reduced reflectivity by controlled patterning
• Increase conversion efficiency by modification of PN-junction
• Increase internal reflection by controlled patterning
• Thinner conductors to reduce shadowing
Routes for improvement
General company presentation - © Obducat 2017 CONFIDENTIAL
The thin film silicon approach
• The thin film silicon approach enables a reduction of silicon used and thereby reducing manufacturing costs and weight
• Thin silicon will absorb less light, however, this can be compensated for by using a nanostructured surface
• In addition, the silicon can be produced directly on the module giving additional costsavings
• This approach will be developed further in a joint research effort between Obducat and IMEC as well as within EU-project PhotoNVolatics
An example of Emerging technologies cont.
General company presentation - © Obducat 2017 CONFIDENTIAL
Thank You for Your attention
Gang Luo
Obducat Technologies AB