camx chimere Italy def-INERIS - lmd.polytechnique.fr · Application of CAMx and CHIMERE models over...
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Transcript of camx chimere Italy def-INERIS - lmd.polytechnique.fr · Application of CAMx and CHIMERE models over...
![Page 1: camx chimere Italy def-INERIS - lmd.polytechnique.fr · Application of CAMx and CHIMERE models over Italy Guido PIROVANO Stefano Alessandrini Matteo Paolo Costa Giovanni Manzi Cesare](https://reader031.fdocuments.net/reader031/viewer/2022020319/5c71538c09d3f2e7398c5594/html5/thumbnails/1.jpg)
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Application of CAMx and CHIMERE models over Italy
Guido PIROVANO
Stefano AlessandriniMatteo Paolo CostaGiovanni ManziCesare PertotAnna Toppetti
CESI Research CentreMilan
Bertrand BessagnetCécile Honoré
INERIS
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Agenda
• CAMx - CHIMERE features
• Domain and input data
• Model results
• Comparison with observations
• Conclusions
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CAMx - CHIMERE features
CAMx - Aerosol Module
• 1 or 2 size bins• Primary PM
CRS, PRM, PEC, POA
• ISORROPIANO3
-, NH4+, SO4
=, Na, Cl
• SOAPSOA1-4
CHIMERE - V200402D
• 6 size bins• Primary PM• SOA• ISORROPIA
NO3-, NH4
+, SO4=
CHIMERE - V200501G• idem + Boundary conditions• dust (desert + erosion)• new meteo (ERA40)•new deposition (as EMEP)
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Domain Chemical stations
-400 -200 0 200 400 600 800
PSP - Km
-600
-400
-200
0
200
400
600
800
PS
P -
km
VEZZANORIVA_GAVARES_VI
DONNASLIMITOBIELLA VENEZ_PBVERON_TO
MOTTA_VITORIN_LI
JOLA_SAVMIGNANE BOLOG_GM
PIE_TECOFIREN_SE
PERUG_CO
LEONESSA
ROMA_TCFONTEC
NAPOL_AS
PALER_BF
-400 -200 0 200 400 600 800
PSP - Km
-600
-400
-200
0
200
400
600
800
PS
P -
km PESCA_TA
ROMA_MGR
FIREN_GR
PALER_BG
PERUG_FO
POTEN_FI
LIMITOMEDA
FERRA_SG
ISPRA
M_LIBRE
Background - RuralBackground - SuburbanBackground - UrbanTraffic - SuburbanTraffic - Urban
GAS (Airbase) PM (Airbase + EMEP)
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Input data
CAMx • Grid 25x25 km (PSP); 13 v.lev. (70 m);• Meteo RAMS with ECMWF analysis• Boundary CHIMERE v200402D• Emissions area: APAT2000 + EMEP; lps: APAT + EPER
CHIMERE - V200402D
CHIMERE - V200501G
• Grid 50x50 Km ; 8 vert. Levels (up to 700 Hpa)• Meteo ECMWF (50 Km)• Boundary MOZART (gas)• Emissions EMEP (1999)
• Grid 50x50 Km ; 8 vert. Levels (up to 500 Hpa)• Meteo ERA40 + MM5 (36 Km)• Boundary MOZART (gas) + GOCART (aerosol)• Emissions EMEP (1999)
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CHIMERE as Boundary Conditions for CAMx
Main features
• Grid 0.5 x 0.5 °; 8 vertical levels (from 40 m up to 3500 agl)• Temporal res. 3 hourly• Gas species O3, NO, NO2, HNO3, PAN, SO2, CO, NH3, SULF
Ethane, Ethene, n-Butane, Isoprene, HCHO, α-pin• Aerosol 6 bins (4 up to PM25; 5 up to PM10;)
PPM, ASOA, BSOA, NH4, SO4, NO3, Water
Link to CAMx
• Linear interpolation both in space and time
• VOC allocation into CB-IV classes
• Aerosol aggregation into CAMx classes
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Model results (21 June - 4 July 1999) O3
CAMx CHIMERE 2004 CHIMERE 2005
-400 -200 0 200 400 600 800
PSP - Km
500
0
500MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONATORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
Lon
0 5 10 15 20 25 30 35 40 45 50 55 60 65 70[ppb]
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Model results (21 June - 4 July 1999) CO
CAMx CHIMERE 2004 CHIMERE 2005
-400 -200 0 200 400 600 800
PSP - Km
500
0
500MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONATORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
Lon
115 140 160 180 200 220 240 260 280 300[ppb]
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Model results (21 June - 4 July 1999) NO2
CAMx CHIMERE 2004 CHIMERE 2005
-400 -200 0 200 400 600 800
PSP - Km
-500
0
500MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
[ppb]
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
Lon
1 2 4 6 8 10 12 14 16 18 20[ppb]
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Model results (21 June - 4 July 1999) HNO3
CAMx CHIMERE 2004 CHIMERE 2005
-400 -200 0 200 400 600 800
PSP - Km
00
0
00VEZZANO
RIVA_GAVARES_VIDONNAS
LIMITOBIELLA VENEZ_PBVERON_TO
MOTTA_VI
TORIN_LIJOLA_SAV
MIGNANE BOLOG_GM
PIE_TECO
FIREN_SE
PERUG_CO
LEONESSA
ROMA_TC
FONTEC
NAPOL_AS
PALER_BF
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
Lon
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5[ppb]
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Model results (21 June - 4 July 1999) NH3
CAMx CHIMERE 2004 CHIMERE 2005
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
Lon
1 5 10 15 20 25 30 35 40 45 50 55 60 65 70[ppb]
-400 -200 0 200 400 600 800
PSP - Km
500
0
500VEZZANO
RIVA_GAVARES_VIDONNAS
LIMITOBIELLA VENEZ_PBVERON_TO
MOTTA_VI
TORIN_LIJOLA_SAV
MIGNANE BOLOG_GM
PIE_TECO
FIREN_SE
PERUG_CO
LEONESSA
ROMA_TC
FONTEC
NAPOL_AS
PALER_BF
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
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Model results (21 June - 4 July 1999) PM10
CAMx CHIMERE 2004 CHIMERE 2005
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
-400 -200 0 200 400 600 800
PSP - Km
-500
0
500MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
[ug/m3]
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONATORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
Lon
[ug/m3]0 4 8 12 16 20 24 28 32 36 40
![Page 13: camx chimere Italy def-INERIS - lmd.polytechnique.fr · Application of CAMx and CHIMERE models over Italy Guido PIROVANO Stefano Alessandrini Matteo Paolo Costa Giovanni Manzi Cesare](https://reader031.fdocuments.net/reader031/viewer/2022020319/5c71538c09d3f2e7398c5594/html5/thumbnails/13.jpg)
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Model results (21 June - 4 July 1999) PPM
CAMx CHIMERE 2004 CHIMERE 2005
-400 -200 0 200 400 600 800
PSP - Km
500
0
500MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
[ug/m3]
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
Lon
[ug/m3]1 2 4 6 8 10 12 14 16 18 20
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONATORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
![Page 14: camx chimere Italy def-INERIS - lmd.polytechnique.fr · Application of CAMx and CHIMERE models over Italy Guido PIROVANO Stefano Alessandrini Matteo Paolo Costa Giovanni Manzi Cesare](https://reader031.fdocuments.net/reader031/viewer/2022020319/5c71538c09d3f2e7398c5594/html5/thumbnails/14.jpg)
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Model results (21 June - 4 July 1999) NO3-
CAMx CHIMERE 2004 CHIMERE 2005
-400 -200 0 200 400 600 800
PSP - Km
00
0
00MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
[ug/m3]
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONATORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
Lon
[ug/m3]0.1 1 2 3 4 5 6 7 8 9 10
![Page 15: camx chimere Italy def-INERIS - lmd.polytechnique.fr · Application of CAMx and CHIMERE models over Italy Guido PIROVANO Stefano Alessandrini Matteo Paolo Costa Giovanni Manzi Cesare](https://reader031.fdocuments.net/reader031/viewer/2022020319/5c71538c09d3f2e7398c5594/html5/thumbnails/15.jpg)
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Model results (21 June - 4 July 1999) NH4+
CAMx CHIMERE 2004 CHIMERE 2005
-400 -200 0 200 400 600 800
PSP - Km
-500
0
500MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
[ug/m3]
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO [ug/m3]
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
Lon
[ug/m3]0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5
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Model results (21 June - 4 July 1999) SO4=
CAMx CHIMERE 2004 CHIMERE 2005
-400 -200 0 200 400 600 800
PSP - Km
00
0
00MILANO VENEZIAVERONA
TORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONATORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO [ug/m3]
4 6 8 10 12 14 16 18 20
Lon
36
38
40
42
44
46
48
Lat
MILANO VENEZIAVERONATORINO
BOLOGNA
FIRENZE
PERUGIA
ROMA
NAPOLI
PALERMO
Lon
[ug/m3]0 2 4 6 8 10 12 14 16 18 20
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Comparison with observations O3
TORIN_LI
0
20
40
60
80
100
120
140
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ppb
]
Obs CAMx CHIM_2004 CHIM_2005
ROMA_TC
0
20
40
60
80
100
120
140
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ppb
]
Obs CAMx CHIM_2004 CHIM_2005
MOTTA_VI
0
20
40
60
80
100
120
140
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ppb
]
Obs CAMx CHIM_2004 CHIM_2005
PALER_BF
0
20
40
60
80
100
120
140
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ppb
]
Obs CAMx CHIM_2004 CHIM_2005
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Comparison with observations NO2
MOTTA_VI
0
10
20
30
40
50
60
0 2 4 6 8 10 12 14 16 18 20 22
[ppb
]
CAMx CHIM_2004 CHIM_2005 Misure
ROMA_TC
0
10
20
30
40
50
60
0 2 4 6 8 10 12 14 16 18 20 22
[ppb
]
CAMx CHIM_2004 CHIM_2005 Misure
TORIN_LI
0
10
20
30
40
50
60
0 2 4 6 8 10 12 14 16 18 20 22
[pp
b]
CAMx CHIM_2004 CHIM_2005 Misure
PALER_BF
0
10
20
30
40
50
60
1 3 5 7 9 11 13 15 17 19 21 23
[ppb
]
Misure CAMx CHIM_2004 CHIM_2005
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Mean day COMOTTA_VI
0100
200300
400500600
700800
9001000
1 3 5 7 9 11 13 15 17 19 21 23
[ppb
]
CAMx CHIM_2004 CHIM_2005
BOLOG_GM
0100200300400500600700800900
1000
1 3 5 7 9 11 13 15 17 19 21 23
[ppb
]
CAMx CHIM_2004 CHIM_2005
FONTEC
0
100
200
300
400
500
600
700
800
900
1000
1 3 5 7 9 11 13 15 17 19 21 23
[pp
b]
CAMx CHIM_2004 CHIM_2005
NAPOL_AS
0
100
200
300
400
500
600
700
800
900
1000
1 3 5 7 9 11 13 15 17 19 21 23
[pp
b]
CAMx CHIM_2004 CHIM_2005
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Comparison with observations PM10
POTEN_FI
0
10
20
30
40
50
60
70
80
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005 CHIM_2005_ant
FERRA_SG
0
10
20
30
40
50
60
70
80
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005 CHIM_2005_ant
LIMITO
0
10
20
30
40
50
60
70
80
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005 CHIM_2005_ant
MEDA
0
10
20
30
40
50
60
70
80
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005 CHIM_2005_ant
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Comparison with observations Nitrate
HNO3
M_LIBRE
0
2
4
6
8
10
12
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005
NO3-ISPRA
0
5
10
15
20
25
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005
M_LIBRE
0
0.5
1
1.5
2
2.5
3
3.5
4
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005
ISPRA
0
0.5
1
1.5
2
2.5
3
3.5
4
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005
![Page 22: camx chimere Italy def-INERIS - lmd.polytechnique.fr · Application of CAMx and CHIMERE models over Italy Guido PIROVANO Stefano Alessandrini Matteo Paolo Costa Giovanni Manzi Cesare](https://reader031.fdocuments.net/reader031/viewer/2022020319/5c71538c09d3f2e7398c5594/html5/thumbnails/22.jpg)
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Comparison with observations AmmoniumISPRA
0
2
4
6
8
10
12
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005
NH3
M_LIBRE
0
2
4
6
8
10
12
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005
NH4ISPRA
0
5
10
15
20
25
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ppb
]
Obs CAMx CHIM_2004 CHIM_2005
M_LIBRE
0
5
10
15
20
25
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ppb
]
Obs CAMx CHIM_2004 CHIM_2005
![Page 23: camx chimere Italy def-INERIS - lmd.polytechnique.fr · Application of CAMx and CHIMERE models over Italy Guido PIROVANO Stefano Alessandrini Matteo Paolo Costa Giovanni Manzi Cesare](https://reader031.fdocuments.net/reader031/viewer/2022020319/5c71538c09d3f2e7398c5594/html5/thumbnails/23.jpg)
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Comparison with observations Sulfate
SO2 SO4ISPRA
0
2
4
6
8
10
12
14
16
18
20
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005
M_LIBRE
0
2
4
6
8
10
12
14
16
18
20
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ug/
m3]
Obs CAMx CHIM_2004 CHIM_2005
ISPRA
0
2
4
6
8
10
12
14
16
18
20
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ppb
]
Obs CAMx CHIM_2004 CHIM_2005
M_LIBRE
0
2
4
6
8
10
12
14
16
18
20
21 22 23 24 25 26 27 28 29 30 1 2 3 4
[ppb
]
Obs CAMx CHIM_2004 CHIM_2005
![Page 24: camx chimere Italy def-INERIS - lmd.polytechnique.fr · Application of CAMx and CHIMERE models over Italy Guido PIROVANO Stefano Alessandrini Matteo Paolo Costa Giovanni Manzi Cesare](https://reader031.fdocuments.net/reader031/viewer/2022020319/5c71538c09d3f2e7398c5594/html5/thumbnails/24.jpg)
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Aerosol Composition
CAMx CHIMERE 2004 CHIMERE 2005ISPRA - PM10 = 15.3 [ug/m3]
16%
26%
23%
6%
14%
15%PNH4PNO3PSO4SOAPPM_NCPPM_C
ISPRA - PM10 = 21.9 [ug/m3]
0%
37%
10%
10%
19%24%
pDUSTPPMPNH4PNO3PSO4SOA
ISPRA - PM10 = 16.4 [ug/m3]
20%
28%
8%
6%
17%
21%
pDUSTPPMPNH4PNO3PSO4SOA
M_LIBRE - PM10 = 12.7 [ug/m3]
18%
16%
35%
6%
11%
14% PNH4PNO3PSO4SOAPPM_NCPPM_C
M_LIBRE - PM10 = 14.1 [ug/m3]
0%
44%
9%
3%
23%
21%
pDUSTPPMPNH4PNO3PSO4SOA
M_LIBRE - PM10 = 17.1 [ug/m3]
33%
24%
7%1%
19%
16%
pDUSTPPMPNH4PNO3PSO4SOA
![Page 25: camx chimere Italy def-INERIS - lmd.polytechnique.fr · Application of CAMx and CHIMERE models over Italy Guido PIROVANO Stefano Alessandrini Matteo Paolo Costa Giovanni Manzi Cesare](https://reader031.fdocuments.net/reader031/viewer/2022020319/5c71538c09d3f2e7398c5594/html5/thumbnails/25.jpg)
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Conclusions
• ����������������� ������������������������������������� ���� ����������� ��
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Some ideas for the future...
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Acknowledgements
CESI contribution of this paper has been supported bythe MICA (Italian Ministry of Industry, Trade andHandicraft) in the frame of Energy Research Programfor the Italian Electric System (MICA Decree ofFebruary 28, 2003), Project on SCENARI.