BS EN 14181:2004 - AST CEMs Calibration Report · 2-4 Langlands Place Business Manager Project...

CEMs Functional Checks:

Linearity of Particulates Analyser:

Linearity of Gaseous Analysers:

Comparative Measurements of Particulates:

Comparative Measurements of Gases:

LEK 10073 AST

Report By:

MCERTS Number:

MCERTS Level:

Technical Endorsements:

Report Approved By:

MCERTS Number:

Business Title:

Technical Endorsements:

Signature:

BS EN 14181:2004 - AST CEMs Calibration Report

Section 1A

Type of Process Permit Number Installation Name Permit Reference

Tel: +353 21 4862374

Email: [email protected]

24th November 2015

25th November 2015

24th November 2015

25th November 2015

24th - 26th November 2015

Report Date 1st April 2016

ESG job Number

Version 2

Cormac Dunne

MM 07 885

MCERTS Level 2 - Team Leader

TE's 1, 2, 3 & 4

MM 05 640

MCERTS Level 2 - Project Manager

TE's 1, 2 & 4

Andy Tiffen

2-4 Langlands Place Business Manager Project Manager

Kelvin South Business Park Tel: 01355 247 514 Tel: 0161 443 0982

East Kilbride Email: [email protected]

Process Operator & Address

Novartis Ringaskiddy Ltd

Ringaskiddy

County Cork

Ireland

Main Contact at Site

Noel Aherne

Incinerator P0006-03 SWI -

Date(s) of Test(s) / Sampling:

ESG Laboratory: Your Contact at ESG: For technical enquiries:

East Kilbride Laboratory Dave Hay Andy Tiffen

Email: [email protected]

G75 0YF

Tel: 01355 246 730

vD ks 0*5.1

vD ks 0*5.1

page 1 of 91

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Title Page

Contents

Section 1 - Executive Summary

UKAS and ESG Disclaimer Statement

Calibration Summary

Deviation from the Standard Reference Methods

Deviations from BS EN 14181:2004

Inpact of Deviations on the Results

Actions Required

Section 2 - Regulatory Information

Regulated Determinands, Emission Limit Values and Required Measurement Uncertainty

Process Description

Standard Reference Method (SRM) Sampling Location

Duct Characteristics

Sampling Lines and Sample Points

Sampling Platform Information

Sampling Location / Platform Improvement Recommendations

Sampling Location Compliance with BS EN 15259:2007

Diagram / Photographs of Emission Point and Platform

Information about the CEMs

Description of the CEMs

CEMs Measurement of Stack Temperature and Pressure

CEMs & CEMs Probe Location

CEMs Self Checking / Calibration Periods

Sites Reference Materials

5

7

7

7

7

7

7

7

9

10

6

7

6

6

6

Contents

Page Number

1

2

4

4

7

8

9

9

9

9

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Section 3 - Information About the Monitoring Campaign

Stack Emissions Monitoring Team

Description of the Standard Reference Method (SRM)

Standard Reference Method (SRM) Monitoring Methods

Sampling Methods with Subsequent Analysis

On Site Testing

Section 4 - Data Handling

Procedure for Selecting Datapairs.

Section 4A - Data and Calculations

12

12

13

13

14

Contents (continued)

Page Number

11

11

12

12

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Opinions and interpretations expressed herein are outside the scope of UKAS accreditation.

This test report replaces and supersedes version 1, which was issued on the 8th February 2016.

Section 1 - Executive Summary

UKAS & ESG Disclaimer Statement

This test report shall not be reproduced, except in full, without the written approval of Environmental Scientifics Group Limited.

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

.

Total Particulate Matter N/A N/A N/A N/A

AST Extended Range

20.8 20.9 N/A

Moisture y=0.961x +0.221 26.7 N/A N/A

Oxygen PASS PASS 10%

Section 1B

Hydrogen Chloride y=1.479x -1.553 2.2 8.5 N/A

VOCs y=1.015x -0.006 -2.0 10.0 N/A

Oxides of Nitrogen y=1.165x +1.437 150.3 286.4 N/A

Sulphur Dioxide y=1.010x +0.451 10.7 50.0 N/A

Carbon Monoxide y=1.007x -1.402 5.2 50.0 N/A

Calibration Summary

Novartis Ringaskiddy Ltd, Ringaskiddy

- - SWI


Parameter Calibration Function QAL2 Validated Range QAL2 Extended

%

Test

VOCs PASS PASS 30%

PASS 20%

Hydrogen Chloride PASS PASS 40%

Sulphur Dioxide PASS

Where the Operator decides to use the calibration functions, then the Environment Agency of England has asked that this

test house make the Operator aware of the following statement. "Once applied, the calibration only remains valid so long

as the CEM is not adjusted, unless any adjustments are triggered and permitted through the QAL3 procedure, in order to

return the zero and span readings to the original baselines that were in place during the QAL2 and when the calibration

function was applied."

Moisture PASS PASS

Derived of Calibration at range using of calibration at

11th - 13th June 2014 Reportable Conditions linearity Reportable Conditions

Oxygen y=0.953x +0.219

30%

(AST only)

PASS PASS 30%

Oxides of Nitrogen PASS PASS 20%

Total Particulate Matter

Carbon Monoxide PASS PASS 20%

Test Acceptance

of the of the Confidence

Parameter Outcome Outcome Legislation

Variability Calibration Interval

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Project Deviations

N/A

The CEM system has passed the requirements of the AST. The calibration function derived during the

initial QAL2 is still valid and should continue to be used. No additional actions are required

Section 1C

Deviations from the Standard Reference Methods

Actions Required

Impact of Deviations on the Results

Deviations from BS EN 14181:2004

No deviations recorded during this project

No deviations recorded during this project

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

2.2.2 Type of fuel

Fuel Type

Fuel Ratio

Is a multiple calibration function required

2.2.3 Abatement

Section 2.3.1 Stack and sampling ports

Duct Characteristics Sampling Lines & Sample Points

Section 2 - 2.1 Regulatory Information

Determinand (mg/m3) (mg/m

3) % Uncertainty

2.1.7 Regulated Determinands, Emission Limit Values and Required Measurement Uncertainty

Short Term ELV Daily ELV Virtual ELV Required

Carbon Monoxide 100 50 20%

11th - 13th June 2014 / N/A

P0006-03Waste Incineration

County Cork, Ireland

RingaskiddyNovartis Ringaskiddy Ltd2.1.1Name of the operator

2.1.2 Name of the installation

2.1.3 Address of the installation

2.1.4 Sector for the installation

2.1.5 Permit Number

2.1.6 Date of the last QAL2/AST

Sulphur Dioxide 200 50 20%

10%

Total Particulate Matter 10 30 30%

Oxides of Nitrogen as NO2 500 400 20%

Value Units TPM Gases

2.2 Operational Information and site monitoring provisions

Volatile Organic Compounds (VOCs) as C 20 10 30%

Oxygen 25

Hydrogen Chloride 60 10 40%

Water Vapour 30 30%

2.3 Monitoring provisions at the installation - perodic monitoring

Any expected variation in emissions No

Will emissions variations influence representative sampling No

Other factors that may affect monitoring results O2 offset

Are emissions at or near zero Yes

Natural Gas

N/A

No

Abatement Type Scrubber:

LinearityIf emissions are at or near zero what provisions are in place to deal with this

and does the operator know and understand the implications?

Nature of process

Percentage of Load

Continuous

Modulating according to demand

2.2.1 Process type and variations in emissions

Width - m Orientation Horizontal Horizontal

Cross Sectional Area 0.06 m2 Number Points / Line 1 1

Shape Circular - Sample Port Size 4" BSP 4" BSP

Depth 0.27 m Number Used 1 1

70 mm Filtration LocationPort Depth In-Stack In-Stack

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Diagram / Photographs of Emission Point and Platform

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Section 2.3.2 Monitoring platform and site-provisions

Sampling Location / Platform Improvement Recommendations

Section 2.3.3 Sample - how representative is it?

Sampling Location Compliance with BS EN 15259:2007

Sampling Platform Information

Type Permanent

Location Outside

Safe & Clean Working Environment Yes

Sufficient Weather Protection Exposed to elements

The sampling location meets all the requirements specified in EA Guidance Note M1.

Is there easy & Safe access to the CEM? yes

Do site have adequate reference materials? See page 10 for reference materials stocked at site

Do site hold suitable tools yes

Do site stock spare parts yes

Can ref gases be injected at inlet & probe? yes

The Standard Reference Method sampling location has been subjected to a BS EN 15259:2007 homogeneity test.

The results of which have demonstrated that the gas stream at the sampling location is homogenously distributed.

Ratio of highest to lowest flows <3:1

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

TPM

NO

NO2

CO

SO2

HCl

VOCs

Oxygen

The CEMs analyser is located in a clean safe environment with sufficient weather protection.

There is safe access to the CEMs probe / analyser head.

The CEMs sampling location has been subjected to a BS EN 15259 homogeneity test.

Section 2.4.2 Types of monitoring for peripheral determinands

CEMs System Model MCERTS Range

Actual Measurement QAL 1

Technique /

Provider Certified

2.4.1 Types of CEMs for each main determinand, oxygen and moisture

Pollutant Type of CEM Instrument Minimum

2.4 Continuous Emission Monitoring Systems (CEMs) at the installations

Range Certificate

mg/m3 Number

mg/m3

MCERTS

FTIR MC030016/04

extractive ABB ACF-NT 200 - FTIR

SIGAR2 100 - Photometer

MC030016/04

extractive ABB ACF-NT 75 250

MC060081/03

extractive ABB ACF-NT 200 600 FTIR MC030016/04

cross-duct SIGRIST

extractive ABB Multi-FID 14 15 50 FID

ACF-NT 75 300 FTIR

MC030015/02

MC030016/04

extractive ABB ACF-NT 15 90 FTIR MC030016/04

extractive ABB

ABB RGM 11 20.9% 25 Zirconia

CEMs Measurement of Stack Temperature and Pressure

MC030016/04

Water Vapour extractive ABB ACF-NT - 40 FTIR MC030016/04

extractive

The CEM system measures and records the stack temperature and pressure.

CEMs & CEMs Probe Location

The CEMs probe / analyser head is located < 3 hydraulic diameters downstream of the Standard Reference Method sampling

location.

CEMs Self Checking / Calibration Periods

Any data that is gathered across these periods will not be used as part of the datapairs used in the derivation of any calibration

function(s).

-

-

-

See below table 4.1 for each component for details of what corrections applied to data to obtain reportable conditions

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Number ppm Manufacture Life

Sites Reference Materials

Pollutant Supplier Cylinder Conc Date of Shelf

Site has the following reference materials:

CO AirProducts APE075683 84.4 17 04 14 36 months

SO2 AirProducts APE075683 74.4 17 04 14

VOC AirProducts APE1021704 16.2 15 02 11 60 months

36 months

NO AirProducts APE075683 237.1 17 04 14 36 months

Oxygen AirProducts APE0917142 0.0 20 04 12 120 months

The reference materials can be injected both at the probe and at the analyser.

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Name

Cormac Dunne

Hugh McMahon

Mar 17 Sep 16 Mar 17 Dec 16 Dec 16

MM 15 1347 Nov 20 - - - - - -

Reg Number Certification level with expiry date

Trainee L1 L2 TE1 TE2 TE3 TE4

MM 07 885 N/A N/A

Section 3 - Information About the Monitoring Campaign

3.1 Stack Emissions Monitoring Team

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Section 3.2 Standard/Alternative Reference Methods (SRMs/ARMs)

TPM

NO

NO2

CO

SO2

HCl

VOCs

Oxygen

Pollutant Standard / ESG UKAS MCERTS Limit Laboratory

Alternative Technical Accredited Accredited

~0.20 mg/m3

Oxygen BS EN 14789 AE 007 & 054 Yes Yes ~0.10 % East Kilbride

Water M22 AE 063 & 016 Yes Yes ~0.10 % East Kilbride

East KilbrideBS EN 12619 AE 056 Yes Yes

Pollutant Standard / ESG UKAS MCERTS

Alternative Technical Accredited Accredited of

Sampling Methods with Subsequent AnalysisLimit Laboratory

CO M22 AE 007 & 016 Yes Yes ~1.00 mg/m3

East Kilbride

On Site Testing

SO2 M22 AE 063 & 016 Yes Yes ~1.00 mg/m3

East Kilbride

Method Procedure(s) Test Test Detection

East Kilbride

NO M22 AE 063 & 016 Yes Yes ~1.00 mg/m3

East Kilbride

NO2 M22 AE 063 & 016 Yes Yes ~0.50 mg/m3

HCl M22 AE 063 & 016 Yes Yes ~0.50 mg/m3

East Kilbride

VOCs

0 to 75 6.1

Gasmet DX 4000 FTIR MC030014/05 0 to 75 0 to 75

Thermofid FID MC050062/00 0 to 15 0 to 15 8.7

0 to 30 -

Gasmet DX 4000 FTIR MC030014/05 0 to 15 0 to 15 7.0

M & A

Water Vapour Gasmet DX 4000 FTIR

of

East Kilbride

TPM BS EN 13284-1 AE 104 Yes Yes ~0.05 mg/m3

East Kilbride

Water BS EN 14790 AE 105 Yes Yes 0.10%

Method Procedure(s) Test Test Detection

(LOD)

Servomex Zentra 4900 Paramagnetic MC030013/06 0 to 25 0 to 25

2.0


4.8

3.5

Number mg/m3

M.U.

Range

-

Gasmet DX 4000 FTIR MC030014/05 0 to 75

Measurement QAL 1 Minimum

Certified

Certificate Range Daily

Provider MCERTS

ELV

CAE Method 5 Gravimetric - 0 to 5 -

Operating

System Model Technique /

MC030014/05 0 to 30

1.6


Description of the Standard / Alternative Reference Method (SRM / ARM)

mg/m3 of

MCERTS as %

Pollutant SRM / ARM Instrument

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Note: This report has a start point for all calibrations when the SRM value has been converted to the same units as the CEMs

reading. Therefore the actual raw SRM may not be stated in this report.

Section 4 - Data Handling

Procedure for Selecting Datapairs.

Where Environmental Scientifics Group Limited have used continuous analysers to perform the Standard or Alternative Reference

Methods monitoring, they initially average the data as follows:

BS EN 14181 states that if the sampling time is shorter than 1 hour, then the time interval between the start of each sample shall be

at least 1 hour.

When a Homogeneity Test to BS EN 15259:2007 has been carried out prior to the QAL 2 testing and the outcome of that testing

suggests that grid sampling is the best approach to use, then the timings of such samples are stated in full.

Once the data pairs have been assembled, any pairs that cover periods of either SRM / ARM and or CEMs zero / self checking are

discarded (as they are not deemed to be valid results). The remaining results are then subjected to an outlier test which is described

in detail in this report.

Data is averaged in line with the site short term ELV averaging time. i.e. For sites with half hourly ELV's, half hour averages are used.

Sites with 1 hourly ELV's, 1 hour averages are used. If the site does not have a short term ELV, then a minimum of half hour

averages are used.

When the SRM / ARM is performed using a manual extractive technique, the timing of such samples is stated in full.

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

to

to

to

Note - CEM data requires the following corrections to be expressed at STP, Dry and 11 % O2

Temperature Correction not required

Pressure Correction not required

Moisture Correction required

Oxygen Correction required

0.0

0.0

25 11 15 12:14

25 11 15 14:24

10

11

1.0

1.0

9

18.6

18.7

25 11 15 09:38

Linearity Data

(shown in mg/m3)

25 11 15 13:50

25 11 15 16:00

138.1

138.8

-

-

999.3

SRM

Measured

Value

yi

mg/m3

0.0

0.0

0.0

1.4

0.0

0.0

0.1

CEM

Water

%

--

--

--

-

-

-

-

-

137.517.212.0

13.5

13.4

--

--

--

CEM

Press.

Mbar

-

-

-

SRM

Water

%

--

--

--

--

--

--

--

--

18.9 137.025 11 15 11:16

Sample

1

2

3

not used

not used

not used

not used

not used

Section 4A - Data and Calculations

Total Particulate Matter - Raw Monitoring Data

CEM

Temp

Deg C

-

-

-

CEM

Oxygen

%

--

--

--

SRM

Temp

Deg C

SRM

Press.

Mbar

-

Zero Values (<5% ELV)

Date and Time

CEM

Measured

Value

xi

mg/m3

0.0

- -

- -

- -

- -

- -

-

- -

- -

SRM

Oxygen

%

-

-

-

Table of Results - 4.1

137.0 1001.7

138.0 1001.7

998.8

987.8

--

--

--

--

--

15.5

15.7

15.0

18.8

18.9

1001.7

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

to

to

to11 2.125 11 15 14:24 25 11 15 16:00

Sample Date and Time

SRM

Corrected

Value*

y is

mg/m3

not used

25 11 15 11:1625 11 15 09:38

25 11 15 12:14


0.0

0.0

0.0

0.1

0.0

9

10


Linearity Data

1

25 11 15 13:50

0.0

3.2

2.3

2

3

not used

not used

not used

not used

0.0

0.0

0.0

Total Particulate Matter - Standardised Monitoring Data

CEM Dry

and

corrected

for, 11%

Oxygen

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Total Particulate Matter - Plot 1 - Time series of data

The above data shows that all the parallel test results are below 30% of the ELV as was demonstrated during the QAL2. No

calibration function was determined during the QAL2 and therefore the purpose of the AST is to demonstrate that the dust

concentrations are still below 30% of the ELV. It is recommended that the CEM be set at a high gain factor, and that the installations

response to particulates be tested by a suitably trained / qualified person.

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

0 1 2 3 4

Co

nc

en

tra

tio

n (

mg

/m3)

Data Point

Comparison of SRM and CEM Standardised Data

SRM CEM

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

to

to

to

to

to

to

to

to

to

to




Oxides of Nitrogen - Raw Monitoring Data

------

24 11 15 17:3124 11 15 17:01

-- 0.0 --

-- --

--

13.2 15.3

16

18.8

12 24 11 15 20:01 24 11 15 20:31

13.3 18.7 61.8

18.9

14 24 11 15 22:01

15.4 18.9

17 25 11 15 01:01

18 25 11 15 02:01 25 11 15 02:31 39.9 13.4 18.8 71.5 15.5

35.1 15.3 18.8

13 15.3

33.0 13.2 62.2 15.215 18.8

25 11 15 00:31 36.9

1


CEM

Measured

Value

xi

mg/m3

25 11 15 00:01

19.8

not used

--

not used -- --

not used


0.0

24 11 15 22:31 38.8 12.6 18.2 64.1 15.4 18.7

18.7

0.2


--

--

3 0.1 -- -- 0.0

--

--

--

not used

not used

9

19.1

19.1 63.2 15.1 19.2

11

37.7 13.1

24 11 15 19:01

CEM

Oxygen

%

CEM Water

%

SRM

Measured

Value

yi

mg/m3

24 11 15 21:01 24 11 15 21:31 36.6 13.2 18.6 66.6

25 11 15 01:31 37.4

62.9

19.0 63.2

--

--

15.1

2 0.1 --

18.7

10 24 11 15 18:01 24 11 15 18:31

63.5

24 11 15 23:01 24 11 15 23:31

24 11 15 19:31

13.2 18.8

38.6 13.1 18.9

Linearity Data

(shown in mg/m3)

37.6 13.3 19.0 58.4 15.4

SRM Water

%

--

SRM

Oxygen

%

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

to

to

to

to

to

to

to

to

to

to

not used


1

2 0.0 0.1

3 0.0 0.1

Oxides of Nitrogen - Standardised Monitoring Data

0.2

Linearity Data

not used

not used

not used

not used

17 25 11 15 01:01 25 11 15 01:31 137.1 59.2

18 25 11 15 02:01 25 11 15 02:31 161.6 64.4

15 24 11 15 23:01


0.0


SRM

Corrected

Value

y is

mg/m3

CEM Dry

and

corrected

for, 11%

Oxygen

24 11 15 23:31 134.2 52.2

24 11 15 17:01

16 25 11 15 00:01 25 11 15 00:31 137.8 59.2

13 24 11 15 21:01 24 11 15 21:31 144.0 58.0

14 24 11 15 22:01 24 11 15 22:31 142.9 56.8

11 24 11 15 19:01 24 11 15 19:31 134.1 60.6

12 24 11 15 20:01 24 11 15 20:31 137.6 55.7

9 130.0 60.6

10 24 11 15 18:01 24 11 15 18:31 134.0 59.3

24 11 15 17:31

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Oxides of Nitrogen - Plot 1 - Time series of data

0

20

40

60

80

100

120

140

160

180

0 1 2 3 4 5 6 7 8 9 10 11

Co

nc

en

tra

tio

n (

mg

/m3)

Data Point


SRM CEM

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Note - Outliers are removed where they improve the calibration function, surrogate data outliers are not removed

Oxides of Nitrogen - Application of the Calibration Function & Outlier Test

1) Collect raw CEM data and raw SRM data expressed as the same units as CEMs measuring conditions

2) Calculate the difference between SRM and CEM values

3) Calculate the average and the standard deviation of the differences

4) If the difference is greater or smaller than the average by more than two times the standard deviation, then the pair is deemed an

outlier and is rejected.

Upper limit at 2 SD

36.9 61.8 24.9 No37.4 63.2

31.6 No

37.6 58.4

Lower limit at 2 SD

44.31

-3.35

25.9 No39.9 71.5

25.31415161718

No

Outlier test data

20.8 No37.7 63.2 25.4

33.0 62.2

The Environment Agency have produced a Guidance Note (Monitoring Quick Guide 14, Jan 2012) which deals with outliers in

monitoring data. That Guidance suggest that the following procedure is the best means of demonstrating that your data is outlier free.

No

Sample

123

not usednot usednot usednot usednot used

91011

AMS at

measured

conditions

SRM at CEMs

Measuring

conditions

DifferenceOutlier (Yes or

No)Data Source

Surrogate Zero's

Linearity Data

0.20.1

00

0.200.10

No

No

NoNo

No

No38.6 63.5 25.0 No35.1 62.9 27.8 No36.6 66.6 30.0 No38.8 64.1

No0.1 0 0.10 No

No

2Number of standard deviations used for outlier test

Average of the differences

Standard deviation of the differences

20.48

11.91

Parallel test data

29.3

1213

-10

0

10

20

30

40

50

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14

Co

nc

en

tra

tio

n (

mg

/m3)

Data Point

Comparison of SRM and CEM Data

Outlier point Upper 2 x SD Lower 2 x SD Valid point

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

to

to

to

to

to

to

to

to

to

to

63.1

18 25 11 15 02:01 25 11 15 02:31 39.9 13.4

13.3

17 25 11 15 01:01 25 11 15 01:31 37.4 13.2

14 24 11 15 22:01 24 11 15 22:31 38.8 12.6

15 24 11 15 23:01 24 11 15 23:31

0.2 --

Date and Time


Sample

2 0.1 --

3 0.1 --

CEM

Measured

Value

xi

mg/m3

CEM

Oxygen

%

33.0 13.2

12 24 11 15 20:01 24 11 15 20:31 35.1 13.2

13 24 11 15 21:01 24 11 15 21:31 36.6 13.2

Oxides of Nitrogen - Data used to calculate calibrated values

not used

CEM

calibrated,

Dry and

corrected

for, 11%

Oxygen

not used

73.0

71.4

9 37.6 13.3

0.0

0.0

18.7

19.0

18.8

0.0

18.8

CEM Water

%

1

18.6

72.8

67.2

69.9

68.3

--

--

1.6

1.6

130.0

134.0

134.1

137.6

144.0

142.9

134.2

137.8

137.1

161.6

18.9

18.2

18.8

1.67


1.55

1.55

45.25

45.41

46.38

42.27

44.07

not used

not used

11

Linearity Data

not used

24 11 15 18:01 24 11 15 18:31 37.7

71.3

SRM

Corrected

Value*

y is

mg/m3

19.1

71.3

77.4

39.87

47.92

10

-- 1.7

19.0

24 11 15 19:01 24 11 15 19:31 38.6 13.1

16 25 11 15 00:01 25 11 15 00:31 36.9

CEM

calibrated,

Dry and

corrected

for, %

Oxygen

44.45

44.97

46.64

13.1

24 11 15 17:3124 11 15 17:01

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

The calibration function is calculated based on parallel test data from an SRM and the CEM during the QAL 2.

The calibration function is described by equation y i = bx i + a , where;

xi is the result of the CEM

y i is the result from the SRM

a is the intercept

b is the slope

The calculated calibration function from the original QAL 2 was:

Calibrated Value Nox (mg/m3) = 1.165 X (CEM reading) + 1.437 mg/m3

Oxides of Nitrogen - The Calibration Function

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

161.6 84.3 31.7 1004.5

71.3 137.1 65.9 13.3 177.7

71.3 137.8 66.5 14.0 195.7

15

14

18

17

137.6 70.4 17.9 318.9

72.8 134.1

1.6 0.0 -1.6 -54.1 2928.0

13

12

11

16

67.2

77.4

74.1 21.5 464.2

Sample

CEM Dry

and

corrected

for 11%

Oxygen

SRM

Corrected

Value*

y is

mg/m3

Difference

of

measured

from

calibrated

Difference

(D - Dmean)

Square of

Difference

(D - Dmean)2


1 1.7 0.0 -1.7 -54.2 2940.7

10

9

3

2

not used

not used

not used

not used

1.6 0.0 -1.6 -54.1 2928.0

not used

73.0 130.0

61.3 8.8 76.6

71.4 134.0 62.6

57.1 4.5 20.6

10.1 101.8

63.1 134.2 71.1 18.6 344.7

68.3 142.9 74.6 22.1 487.9

69.9 144.0

Oxides of Nitrogen - Data Used for the variability test

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

The variability is accepted if: Sd ≤ 1.5 x Qo x Kv

Where

Qo is the uncertainty laid down by the Authorities at the emission limit value as a 95% confidence interval.

Qo = Daily Emission Limit Value X Measurement Uncertainty

Where Daily Emission Limit = 400 mg/m³ Measurement Uncertainty = 20%

Kv = the test parameter (for 13 Pairs of Data is 0.9721)

Variability Pass Criteria

CEM HAS PASSED VARIABILITY TEST

Oxides of Nitrogen - Variability Test

The next stage of the calibration process is to determine if the proposed calibration function passes the variability test.

Sd is the standard deviation of the differences between the SRM value at Reportable Conditions and the Calibrated CEM value at Reportable

Conditions.

1.96

31.61 < 59.52

Calibration function acceptance test

CEM HAS PASSED ACCEPTANCE TEST

52.56 < 56.44

vD ks 0*5.1

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Plot of calibrated CEM data versus SRM data, dry and corected to 11% oxygen

Valid Calibration Range is:

Oxides of Nitrogen - Plot 2 - Plot of calibrated CEM data versus SRM data

0 to 150.3 mg/m3

0

20

40

60

80

100

120

140

160

180

0 10 20 30 40 50 60 70 80 90

SR

M,

mg

/m3

(D

ry a

nd

Co

rre

cte

d f

or

Ox

yg

en

)

CEM, mg/m3 (Calibration Function Applied, Dry and Corrected for Oxygen)

SRM concentrations vs Calibrated and Corrected CEM concentrations

SRM vs CEM Linear (SRM vs CEM)

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

The allowable uncertainty at a 95% confidence interval at the emission limit value is calculated by applying the Qo

equation which is also used in the test of variability.

The valid range of the QAL2 calibrated CEMs at reportable conditions is defined during the QAL2. This is done by

finding the maximum CEM value at reportable conditions and adding 10% to that value. The QAL2 valid range was:

0 to 150.3 mg/m3

If after the parallel testing phase of the QAL 2 it was possible to derive a calibration function, but the function has a

limited valid range ie it does not extend to or beyond the emission limit value, then it may be possible to extend the valid

range of the function to which ever is the lowest of either the highest surrogate or 2 x the emission limit value. To do this

there has to be good agreement between the calibration function and the linearity data.

Good agreement is defined as when the two sets of data are overlain they lie within the allowable uncertainty at a 95%

confidence interval at the emission limit value for the parameter in question.

Oxides of Nitrogen - Valid range & range extension

0 to 286.4 mg/m3

The data from the QAL 2 provided an extended range of:

It is not possible to extend the range any further

Using the data collected from the AST, the range can be extended to:

0.0

200.0

400.0

600.0

800.0

1000.0

1200.0

1400.0

1600.0

1800.0

0.0 100.0 200.0 300.0 400.0 500.0 600.0 700.0 800.0 900.0

SR

M, m

g/m

3

Calibrated CEM, mg/m3

Range extension of calibration function based on linearity data

Min Max Linearity Data SRM v Cal'd CEM extrapolated data Linear (Linearity Data)

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

to

to

to

to

to

to

to

to

to

to




--

--

--

--

not used

CEM

Oxygen

%

CEM Water

%

SRM

Measured

Value

yi

mg/m3

Date and Time

1


Linearity Data

(shown in mg/m3)

0.0

0.0

not used

0.0

2

3

--

--

--


CEM

Measured

Value

xi

mg/m3

24 11 15 18:01

24 11 15 19:01

24 11 15 21:01

SRM

Oxygen

%

SRM Water

%

Carbon Monoxide - Raw Monitoring Data

8

Sample

24 11 15 23:01

25 11 15 00:01

25 11 15 01:01

25 11 15 02:01 18.8

25 11 15 00:31

25 11 15 01:31

25 11 15 02:31

not used

not used

4

5

6

7

24 11 15 22:31

24 11 15 23:31

106.5

84.8

-2.2

-2.2

-2.2

-2.3

-2.3

-2.3

24 11 15 17:31

not used

not used

not used

24 11 15 20:01

--

--

19.0

13.4

19.1-2.3

15.2

60.0

80.0 --

--

-2.6

-2.6

--

--

15.4

15.1

15.1

--

15.3

15.3

15.4

100.0

-3.4

18.8

18.7

19.0

18.9

18.8

18.6

18.2

18.8

19.1

13.2

24 11 15 22:01

68.0

47.6

26.6

-2.4

24 11 15 19:31

24 11 15 20:31

24 11 15 21:31

--

not used

18.7

--

--

--

--

--

--

0.0

0.0

0.0

-3.2

-3.3

-3.8

-3.3

20.0

-3.3

--

--

18.7

18.7

15.5

40.0

13.2

12.6

13.2

13.3

13.2

--

--

13.1

18.9

18.8

--

15.4

15.3

24 11 15 18:31 13.1

19.8

--

--

not used

not used

-2.3

-2.3

--

13.3

--

--

--

24 11 15 17:01

-2.7

-2.9

18.9

19.2

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

60.0

20.0

0.0

106.5

84.8

40.0

2

3

1 0.0

0.0

100.0

80.0

68.0

47.6

26.6


SRM

Corrected

Value

y is

mg/m3

CEM Dry

and

corrected

for, 11%

Oxygen


0.0

Carbon Monoxide - Standardised Monitoring Data

0.0

0.0

Linearity Data

4

5

6

7

8


vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

Carbon Monoxide - Plot 1 - Time series of data

-9

-8

-7

-6

-5

-4

-3

-2

-1

0

0 1 2 3 4 5 6 7 8 9 10 11

Co

nc

en

tra

tio

n (

mg

/m3)

Data Point


SRM CEM

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05


No

106.5 100.0

Data Source

Surrogate Zero's

Linearity Data

00

00

0.000.00

AMS at

measured

conditions

SRM at CEMs

Measuring

conditions

Difference

Upper limit at 2 SD

2

40.0No

Outlier test data

47.6 -7.57 No26.6 20.0 -6.60

Lower limit at 2 SD

3.46

-8.07

Carbon Monoxide - Application of the Calibration Function & Outlier Test






0 0 0.00


-2.30

2.88

-6.47 No84.8 80.0 -4.77 No68.0 60.0 -7.97 No

NoNo



Sample

123

45678

Outlier (Yes or

No)

Number of standard deviations used for outlier test


-10

-8

-6

-4

-2

0

2

4

6

0 1 2 3 4 5 6 7 8 9

Co

nc

en

tra

tio

n (

mg

/m3)

Data Point



vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

2

3

4

5

6

Carbon Monoxide - Data used to calculate calibrated values

105.81

Linearity Data

46.5

25.4

7

8

1

83.96

67.04

46.50

25.38--

106.5

84.8

--

Date and Time

67.0

Sample

CEM

Measured

Value

xi

mg/m3

CEM

Oxygen

%

0.0

--

--

--

--

--

--

--

--

--


SRM

Corrected

Value*

y is

mg/m3

-- -1.4

26.6

--

CEM Water

%

CEM

calibrated,

Dry and

corrected

for, 11%

Oxygen

-1.4

-1.4

105.8

84.0 80.0

60.0

40.0


CEM

calibrated

at CEMs

measuring

conditions

-1.40

0.0

0.0

100.0

20.0

--

--

0.0 --

0.0

0.0

-1.40

-1.40

68.0

47.6

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05





a is the intercept

b is the slope


Calibrated Value CO (mg/m3) = 1.007 X (CEM reading) -1.402 mg/m3

Carbon Monoxide - The Calibration Function

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

4.5

-2.7

-0.9

-4.0

-3.4

0.0

0.0

100.0

80.0

20.025.4

3

4

5

7.6

4.5 19.9

-1.4

105.8

84.0

67.0

46.5

0.8

15.8

11.8

5.4

CEM Dry

and

corrected

for 11%

Oxygen

SRM

Corrected

Value*

y is

mg/m3

Sample

1.4

-4.0

19.9

19.9

Square of

Difference

(D - Dmean)2

Difference

of

measured

from

calibrated

Difference

(D - Dmean)

0.0 1.4

6

7

8

-1.4

-7.0

-6.5

-5.4

4.5-1.4


1

2

-2.3

60.0

40.0

1.4

-5.8

Carbon Monoxide - Data Used for the variability test

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05


Where






3.8 < 7.29

Carbon Monoxide - Variability Test



Conditions.




3.06 < 7.65

1.96

vD ks 0*5.1

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05



0 to 5.2 mg/m3

Carbon Monoxide - Plot 2 - Plot of calibrated CEM data versus SRM data

0

20

40

60

80

100

120

-20 0 20 40 60 80 100 120

SR

M,

mg

/m3

(D

ry a

nd

Co

rre

cte

d f

or

Ox

yg

en

)




vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05







0 to 5.2 mg/m3








0 to 50 mg/m3

Carbon Monoxide - Valid range & range extension

0.0

20.0

40.0

60.0

80.0

100.0

120.0

-20.0 0.0 20.0 40.0 60.0 80.0 100.0 120.0

SR

M, m

g/m

3




vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:05

to

to

to

to

to

to

to

to

to

to




-0.8

not used 25 11 15 01:01 25 11 15 01:31 -0.3 13.2 19.0 -1.5 15.3 18.9

15.2

not used

not used 25 11 15 02:01 25 11 15 02:31 -0.3 13.4 18.8

not used 24 11 15 21:01 24 11 15 21:31

-0.4 13.2 18.8

--

25 11 15 00:01

24 11 15 22:01 24 11 15 22:31 -0.3 12.6 18.2

18.8

not used -0.3 13.3

2 0.0 -- -- 0.0 --

8 24.4 -- -- 20.0 --

19.0 -0.1 15.4 19.8

--

7

Zero Values (<5% ELV) --

3 0.0 -- -- 0.0 -- --

0.0 --0.0 ----


CEM

Measured

Value

xi

mg/m3

46.4 -- -- 40.0 -- --

Linearity Data

(shown in mg/m3)6 62.4 -- -- 60.0

Sulphur Dioxide - Raw Monitoring Data

18.8

-0.2 13.1 18.9 -0.3

not used 24 11 15 18:01 24 11 15 18:31 -0.2 13.1 19.1

-1.7 15.4 18.7

1

18.6 -1.6 15.3 18.7

80.0 -- --

4 98.1 -- -- 100.0 --

24 11 15 17:3124 11 15 17:01

15.1

19.2

not used 24 11 15 19:01 24 11 15 19:31

CEM

Oxygen

%

CEM Water

%

SRM

Measured

Value

yi

mg/m3

SRM

Oxygen

%


--

--

5 85.3 -- --

-0.3 13.3 18.7 -0.5 15.4

-0.7 15.5 18.7

not used 24 11 15 20:01 24 11 15 20:31 -0.2 13.2 18.8 -0.6 15.3

-1.1 15.1

SRM Water

%

not used 24 11 15 23:01 24 11 15 23:31

not used

-0.3 13.2

18.9

19.1

--

25 11 15 00:31

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

2 0.0 0.0

CEM Dry

and

corrected

for, 11%

Oxygen

7 40.0 46.4

8 20.0


0.0


SRM

Corrected

Value

y is

mg/m3

24.4

Linearity Data

5

3 0.0

0.0

4 100.0 98.1


1

Sulphur Dioxide - Standardised Monitoring Data

0.0

80.0 85.3

6 60.0 62.4

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Sulphur Dioxide - Plot 1 - Time series of data

-4.5

-4.0

-3.5

-3.0

-2.5

-2.0

-1.5

-1.0

-0.5

0.0

0 1 2 3 4 5 6 7 8 9 10 11

Co

nc

en

tra

tio

n (

mg

/m3)

Data Point


SRM CEM

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06







46.4 40.0 -6.43

Upper limit at 2 SD

Outlier test data

Outlier (Yes or

No)

2

0.00 No

98.1

Surrogate Zero's

Linearity Data

00

00

0.000.00

5

Sample

1

678

85.3 80.0 -5.30

NoNo

0 0

Lower limit at 2 SD

2.97

-5.49

No24.4 20.0 -4.37 No

Number of standard deviations used for outlier test

100.0 1.93 No

Sulphur Dioxide - Application of the Calibration Function & Outlier Test

Data Source



AMS at

measured

conditions

SRM at CEMs

Measuring

conditions

Difference


-1.26

2.12

23

4

60.0 -2.40 No


No62.4

-8

-6

-4

-2

0

2

4

0 1 2 3 4 5 6 7 8 9

Co

nc

en

tra

tio

n (

mg

/m3)

Data Point



vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

--

--

SRM

Corrected

Value*

y is

mg/m3

--

0.0

0.0

Linearity Data

CEM

Oxygen

%

100.0

80.0

60.0

40.0

0.5

CEM

calibrated

at CEMs

measuring

conditions

0.45


0.45

0.45

99.50

86.605

24.4 --

0.5

0.5

--

63.5

0.0

--

99.5

CEM

Measured

Value

xi

mg/m3

2 0.0 --

3 0.0 --

CEM Water

%

CEM

calibrated,

Dry and

corrected

for, 11%

Oxygen

7 46.4

Sulphur Dioxide - Data used to calculate calibrated values

--

6

1

4 98.1 --

0.0 --

Date and Time


Sample

85.3 -- -- 86.6

--

-- 63.48

47.35

25.06

62.4 --

20.0

47.3

25.18

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06





a is the intercept

b is the slope


Calibrated Value SO2 (mg/m3) = 1.01 X (CEM reading) + 0.451 mg/m3

Sulphur Dioxide - The Calibration Function

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

9.2

Sample

CEM Dry

and

corrected

for 11%

Oxygen

SRM

Corrected

Value*

y is

mg/m3

Difference

of

measured

from

calibrated

Difference

(D - Dmean)

Square of

Difference

(D - Dmean)2

4.33 0.5 0.0 -0.5 2.1

-7.3 -4.8 23.2

80.0

0.0 -0.5 2.1 4.3

1 0.5 0.0 -0.5 2.1 4.3


Sulphur Dioxide - Data Used for the variability test

6 63.5 60.0 -3.5 -0.9 0.9

5 86.6

47.3

8

7

25.1 20.0

2 0.5

-2.5 6.4

40.0

-6.6 -4.1 16.6

4 99.5 100.0 0.5 3.0

-5.1

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06


Where






Sulphur Dioxide - Variability Test



Conditions.



2.53 < 6.02


1.96

2.23 < 7.5

vD ks 0*5.1

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06



0 to 10.7 mg/m3

Sulphur Dioxide - Plot 2 - Plot of calibrated CEM data versus SRM data

0

20

40

60

80

100

120

0 20 40 60 80 100 120

SR

M,

mg

/m3

(D

ry a

nd

Co

rre

cte

d f

or

Ox

yg

en

)




vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06





0 to 50 mg/m3






0 to 10.7 mg/m3





Sulphur Dioxide - Valid range & range extension

0.0

20.0

40.0

60.0

80.0

100.0

120.0

0.0 20.0 40.0 60.0 80.0 100.0 120.0

SR

M, m

g/m

3




vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

to

to

to

to

to

to

to

to

to

to




15.3

15.5

0.0

0.0

18.9

18.9

13.1

13.1

13.2

25 11 15 00:01

25 11 15 01:01

not used

not used

--

--

15.1

15.1

15.3

15.3

-0.4

-0.4

-0.3

4.0

--

15.4

15.2

12.0

16.0

20.0

0.0

--

19.1

19.2

3

4

5

6

7

24 11 15 18:31

24 11 15 19:31

--

--

--

--

18.8

15.4

24 11 15 20:31

24 11 15 21:31

-0.4

18.7

18.7

18.8

18.7

18.8

18.6

not used

not used 18.8

13.2

13.4

-0.3

24 11 15 23:01

18.2

18.8

18.7

19.0

13.3-1.5 19.0

24 11 15 18:01

24 11 15 19:01

24 11 15 20:01

24 11 15 21:01

24 11 15 22:01

--

--

--

24 11 15 17:31

13.2

12.6

13.2

--

19.1

18.9

-0.1

--

--

--

--

--

--

--

-- --

--

--

--

8.0-- --

--

15.4

--

--

--

24 11 15 17:01

0.0

0.1

19.8

13.3

24 11 15 22:31

24 11 15 23:31 -0.3

-1.5

-1.5

-1.5

-1.5

-1.5

-1.5

SRM

Oxygen

%

SRM Water

%

0.2

--


0.2

17.1

13.6

1


Linearity Data

(shown in mg/m3)

0.2

SRM

Measured

Value

yi

mg/m3

0.0


CEM

Measured

Value

xi

mg/m3

CEM

Oxygen

%

CEM Water

%

10.0

6.3

25 11 15 02:01

not used

8

not used

not used

not used

not used

not used

-1.5

-1.5

-1.5

3.2

25 11 15 00:31

25 11 15 01:31

25 11 15 02:31

2 --

Hydrogen Chloride - Raw Monitoring Data

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

12.0

8.0

4.0


6.3

3.2

CEM Dry

and

corrected

for, 11%

Oxygen


0.2

0.2

0.0

0.0

0.0

20.0

16.0

Linearity Data

1

2

3

4

5

6

Hydrogen Chloride - Standardised Monitoring Data

7


SRM

Corrected

Value

y is

mg/m3

8

0.2

17.1

13.6

10.0

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Hydrogen Chloride - Plot 1 - Time series of data

-3.0

-2.5

-2.0

-1.5

-1.0

-0.5

0.0

0.5

0 1 2 3 4 5 6 7 8 9 10 11

Co

nc

en

tra

tio

n (

mg

/m3)

Data Point


SRM CEM

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06


Hydrogen Chloride - Application of the Calibration Function & Outlier Test






0.21

123

0.71

6.3 8.0 1.67 No3.2 4.0 0.83 No

Sample

Outlier test data

45




No

No

17.1 20.0 2.94 No13.610.0 12.0 2.04 No

Data Source

AMS at

measured

conditions

SRM at CEMs

Measuring

conditions


No)

0.210.210

Lower limit at 2 SD

2.72

Surrogate Zero's

Linearity Data678

16.0 2.36

0.210.21

0 NoNo

0.21 0

Upper limit at 2 SD

-0.12



1.30

-0.5

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

0 1 2 3 4 5 6 7 8 9

Co

nc

en

tra

tio

n (

mg

/m3)

Data Point



vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Linearity Data

Sample

CEM

Measured

Value

xi

mg/m3

CEM

Oxygen

%

1

2

3

4

5

6

Date and Time


Hydrogen Chloride - Data used to calculate calibrated values

0.0

13.210.0

--

--

--

--

--

7

8

8.0

-1.2

-1.2

23.7 20.0

16.0

12.0

3.1

--

--

0.0

0.0

--

7.8

4.0--

--

13.6

6.3

--

--

--

0.2 --

0.2

0.2

-1.24

-1.24

-1.24

23.68

18.62

13.18

7.80

3.13

CEM

calibrated

at CEMs

measuring

conditions

17.1

3.2

CEM Water

%

CEM

calibrated,

Dry and

corrected

for, 11%

Oxygen

18.6

--

SRM

Corrected

Value*

y is

mg/m3

-- -1.2


vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06





a is the intercept

b is the slope


Calibrated Value HCl (mg/m3) = 1.479 X (CEM reading) -1.553 mg/m3

Hydrogen Chloride - The Calibration Function

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

-2.6

-1.2

0.0

7

8

13.2

7.8

3.1

-1.2 0.0 1.2 1.6 2.5

-1.2

-1.2

23.7

18.6

1.6

1.6

-3.3

-2.3

-0.8

0.5

1.24.0

0.3

1.5

0.2

0.9

Sample

CEM Dry

and

corrected

for 11%

Oxygen

SRM

Corrected

Value*

y is

mg/m3

Hydrogen Chloride - Data Used for the variability test

Difference

(D - Dmean)

Square of

Difference

(D - Dmean)2


5

6

Difference

of

measured

from

calibrated

1

2

3

4

0.0

20.0

16.0

12.0

1.2

1.2

-3.7

2.5

2.5

11.2

5.2

0.7

8.0

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06


Where







0.34 < 3.34


Hydrogen Chloride - Variability Test



Conditions.

1.96

1.94 < 2.91


vD ks 0*5.1

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06



Hydrogen Chloride - Plot 2 - Plot of calibrated CEM data versus SRM data

0 to 2.2 mg/m3

0

5

10

15

20

25

-5 0 5 10 15 20 25

SR

M,

mg

/m3

(D

ry a

nd

Co

rre

cte

d f

or

Ox

yg

en

)




vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Hydrogen Chloride - Valid range & range extension

0 to 2.2 mg/m3





0 to 8.5 mg/m3










0.0

5.0

10.0

15.0

20.0

25.0

-5.0 0.0 5.0 10.0 15.0 20.0 25.0

SR

M, m

g/m

3




vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

to

to

to

to

to

to

to

to

to

to




0.0 --

--


Linearity Data

(shown in mg/m3)

-0.1 0.0

not used 25 11 15 01:01 25 11 15 01:31 0.3 13.2

not used 18.6

not used 25 11 15 02:01 25 11 15 02:31 0.3 13.4 18.8 0.0 15.5

25 11 15 00:31 0.3

18.2 0.0 15.40.3 12.6

0.0

24 11 15 17:3124 11 15 17:01

19.0 0.0 15.3

19.1

0.0 15.2 18.8

19.2

19.0 0.0 19.8

24 11 15 18:01 24 11 15 18:31 0.2 13.1

15.3 18.8

18.7

15.4 18.9

24 11 15 23:31 0.3 13.2 18.8

13.3

not used 25 11 15 00:01

-0.1 --

4 15.6 --

--

8 3.1 -- -- 3.0 -- --

7 6.3 -- -- 6.0 --

6 9.5

--

5

--

3 -0.1 -- -- 0.0 -- --

2 --

not used

not used

0.2

-- -- 9.0 --

12.4 -- -- 12.0

not used 24 11 15 20:01 24 11 15 20:31 0.2 13.2 18.8 0.0

not used 24 11 15 23:01

not used 24 11 15 19:01 24 11 15 19:31 0.2 13.1 18.9

18.7

SRM

Oxygen

%

SRM Water

%Sample Date and Time

------

VOC - Raw Monitoring Data

--

-- --

--

15.0 --

1


CEM

Measured

Value

xi

mg/m3

CEM

Oxygen

%

CEM Water

%

SRM

Measured

Value

yi

mg/m3

0.024 11 15 21:01 24 11 15 21:31 0.3 13.2

18.7

18.9

15.3

15.4

not used 24 11 15 22:01 24 11 15 22:31

19.1 0.0 15.1

13.3 18.7 0.0

15.1

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

VOC - Standardised Monitoring Data

-0.1

-0.1

15.6

5 12.0 12.4

7 6.0 6.3

8 3.0 3.1

2 0.0 -0.1

3 0.0

15.0

Linearity Data

4

6 9.0 9.5


0.0


SRM

Corrected

Value

y is

mg/m3

CEM Dry

and

corrected

for, 11%

Oxygen


1

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

VOC - Plot 1 - Time series of data

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

0.45

0.50

0 1 2 3 4 5 6 7 8 9 10 11

Co

nc

en

tra

tio

n (

mg

/m3)

Data Point


SRM CEM

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06


VOC - Application of the Calibration Function & Outlier Test






6.3 6.0 -0.273.1 3.0 -0.13 No

No

Outlier test data

9.578

3

456 -0.50 No

Lower limit at 2 SD

0.03

Sample

12




-0.25

0.14 -0.53

-0.06NoNo

-0.06 0 -0.06 No

15.6 15.0 -0.60 No12.4 12.0 -0.40 No

9.0



AMS at

measured

conditions

SRM at CEMs

Measuring

conditions


No)Data Source

Surrogate Zero's

Linearity Data

-0.06-0.06

00

-0.06

Upper limit at 2 SD

-0.70

-0.60

-0.50

-0.40

-0.30

-0.20

-0.10

0.00

0.10

0 1 2 3 4 5 6 7 8 9

Co

nc

en

tra

tio

n (

mg

/m3)

Data Point



vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

--

6 9.5 --

7 6.3 --

8 3.1 --

Linearity Data

4 15.6

5 12.4

--

-0.1 --

Date and Time


Sample

2 -0.1 --

3 -0.1 --

CEM

Measured

Value

xi

mg/m3

CEM

Oxygen

%

1

CEM Water

%

--

12.6

9.6

6.4

3.2

--

-- 3.0

15.0

0.0

--

--

--

--

--

6.0

0.0

0.0

SRM

Corrected

Value*

y is

mg/m3

VOC - Data used to calculate calibrated values

-0.1

-0.1

12.0

-0.1

15.8

CEM

calibrated,

Dry and

corrected

for, 11%

Oxygen


CEM

calibrated

at CEMs

measuring

conditions

-0.07

-0.07

-0.07

15.83

12.58

9.64

6.35

3.17

9.0

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06





a is the intercept

b is the slope


VOC - The Calibration Function

Calibrated Value TVOC (mg/m3) = 1.015 X (CEM reading) -0.006 mg/m3

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

1 -0.1 0.0 0.1 0.4 0.1

8 3.2 3.0 -0.2 0.1 0.0

Sample

CEM Dry

and

corrected

for 11%

Oxygen

SRM

Corrected

Value*

y is

mg/m3

Difference

of

measured

from

calibrated

Difference

(D - Dmean)

Square of

Difference

(D - Dmean)2


6.0 -0.4 -0.1 0.0

3 -0.1 0.0 0.1 0.4 0.1

2 -0.1 0.0 0.1 0.4 0.1

6 9.6

15.0 -0.8 -0.5 0.3

5 12.6 12.0 -0.6 -0.3 0.1

4 15.8

VOC - Data Used for the variability test

9.0 -0.6 -0.3 0.1

7 6.4

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06


Where






VOC - Variability Test



Conditions.

1.96

0.36 < 2.19



0.3 < 1.77


vD ks 0*5.1

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06



VOC - Plot 2 - Plot of calibrated CEM data versus SRM data

0 to -2 mg/m3

0

2

4

6

8

10

12

14

16

-2 0 2 4 6 8 10 12 14 16 18

SR

M,

mg

/m3

(D

ry a

nd

Co

rre

cte

d f

or

Ox

yg

en

)




vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06








0 to -2 mg/m3





0 to 10 mg/m3



VOC - Valid range & range extension

0.0

5.0

10.0

15.0

20.0

25.0

-5.0 0.0 5.0 10.0 15.0 20.0 25.0

SR

M, m

g/m

3




vD ks 0*5.1

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

to

to

to

to

to

to

to

to

to

to



Oxygen - Raw Monitoring Data


CEM

Measured

Value

xi

%

17 25 11 15 01:01 25 11 15 01:31 13.2 19.0 15.3 18.9

18 25 11 15 02:01 25 11 15 02:31 13.4 18.8 15.5 18.7

15 24 11 15 23:01 24 11 15 23:31 13.2 18.8 15.2 18.8

16 25 11 15 00:01 25 11 15 00:31 13.3 18.7 15.4 18.9

13 24 11 15 21:01 24 11 15 21:31 13.2 18.6 15.3 18.7

14 24 11 15 22:01 24 11 15 22:31 12.6 18.2 15.4 18.7

3 0.0 -- 0.0 --

11 24 11 15 19:01 24 11 15 19:31 13.1 18.9 15.1 19.1

12 24 11 15 20:01 24 11 15 20:31 13.2 18.8 15.3 18.8

--

9 24 11 15 17:01 24 11 15 17:31 13.3 19.0 15.4 19.8

10 24 11 15 18:01 24 11 15 18:31 13.1 19.1 15.1 19.2

not used

Linearity Data

--

not used --

not used --

not used --

not used

1


0.0 -- 0.0 --

2 0.0 -- 0.0 --


CEM Water

%

SRM

Measured

Value

yi

%

SRM Water

%

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

to

to

to

to

to

to

to

to

to

to18 25 11 15 02:01 25 11 15 02:31 15.5 13.4

14 24 11 15 22:01 24 11 15 22:31 15.4 12.6

15 24 11 15 23:01 24 11 15 23:31 15.2 13.2

16 25 11 15 00:01 25 11 15 00:31 15.4 13.3

17 25 11 15 01:01 25 11 15 01:31 15.3 13.2

10 24 11 15 18:01 24 11 15 18:31 15.1 13.1

11 24 11 15 19:01 24 11 15 19:31 15.1 13.1

12 24 11 15 20:01 24 11 15 20:31 15.3 13.2

13 24 11 15 21:01 24 11 15 21:31 15.3 13.2

not used

Linearity Data

not used

not used

not used

not used

9 24 11 15 17:01 24 11 15 17:31 15.4 16.4

Oxygen - Standardised Monitoring Data



SRM

Corrected

Value

y is

%

CEM Dry

1


0.0 0.0

2 0.0 0.0

3 0.0 0.0

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Oxygen - Plot 1 - Time series of data

0

2

4

6

8

10

12

14

16

18

0 1 2 3 4 5 6 7 8 9 10 11

Co

nc

en

tra

tio

n (

%)

Data Point


SRM CEM

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06


Oxygen - Application of the Calibration Function & Outlier Test






NoNo

15.1

Upper limit at 2 SD

13.3 15.4 2.12.1 No

13.4 15.5

Outlier test data

AMS at

measured

conditions

SRM at CEMs

Measuring

conditions


No)



2.2 No

Sample

1

13.3 15.4 2.0 No13.1 15.1 2.0 No

Surrogate Zero's

Linearity Data

Parallel test data

00

00

0.000.00

NoNo

0 0 0.00 No

NoNoNo

2.1 No13.2 15.3 2.0 No12.6 15.4 2.8 No13.2 15.2 2.0 No

15.3



No13.2


1.64

0.96

23

not usednot usednot usednot usednot used

91011121314

Lower limit at 2 SD

3.56

-0.28

13.1

15.3

2.0 No13.2

Data Source

15161718

-0.5

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14

Co

nc

en

tra

tio

n (

%)

Data Point



vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

to

to

to

to

to

to

to

to

to

to18 25 11 15 02:01 25 11 15 02:31 13.4 18.8 12.9 15.5

15 24 11 15 23:01 24 11 15 23:31 13.2 18.8 12.8 15.2

16 25 11 15 00:01 25 11 15 00:31 13.3 18.7 12.9 15.4

17 25 11 15 01:01 25 11 15 01:31 13.2 19.0 12.8 15.3

12 24 11 15 20:01 24 11 15 20:31 13.2 18.8 12.8 15.3

13 24 11 15 21:01 24 11 15 21:31 13.2 18.6 12.8 15.3

14 24 11 15 22:01 24 11 15 22:31 12.6 18.2 12.3 15.4

9 24 11 15 17:01 24 11 15 17:31 13.3 19.0 15.9 15.4

10 24 11 15 18:01 24 11 15 18:31 13.1 19.1 12.7 15.1

11 24 11 15 19:01 24 11 15 19:31 13.1 18.9 12.7 15.1

not used

Linearity Data

not used

not used

not used

not used

1


0.0 -- 0.2 0.0

2 0.0 -- 0.2 0.0

3 0.0 -- 0.2 0.0

Oxygen - Data used to calculate calibrated values


CEM

Measured

Value

xi

%

CEM Water

%

CEM

calibrated,

Dry

SRM

Corrected

Value

y is

%

CEM

calibrated


0.22

0.22

0.22

12.91

12.72

12.73

12.83

12.83

12.26

12.80

12.90

12.78

12.94

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06





a is the intercept

b is the slope


Oxygen - The Calibration Function

Calibrated Value Oxygen (%) = 0.953 X (CEM reading) + 0.219 %

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

17 12.8 15.3 2.5 0.8 0.7

18 12.9 15.5 2.6 0.9 0.8

14 12.3 15.4 3.2 1.5 2.3

15 12.8 15.2 2.4 0.8 0.6

16 12.9 15.4 2.5 0.9 0.7

11 12.7 15.1 2.4 0.7 0.5

12 12.8 15.3 2.5 0.8 0.7

13 12.8 15.3 2.4 0.8 0.6

not used

9 15.9 15.4 -0.6 -2.2 5.1

10 12.7 15.1 2.4 0.7 0.5

not used

not used

not used

2 0.2 0.0 -0.2 -1.9 3.6

3 0.2 0.0 -0.2 -1.9 3.6

not used

Oxygen - Data Used for the variability test


Sample CEM Dry

SRM

Corrected

Value

y is

%

Difference

of

measured

from

calibrated

Difference

(D - Dmean)

Square of

Difference

(D - Dmean)2

1 0.2 0.0 -0.2 -1.9 3.6

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06


Where



Where Surrogate Emission Limit = 25 % Measurement Uncertainty = 10%



Oxygen - Variability Test



Conditions.

1.96

1.39 < 1.86



1.67 < 1.96


vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Plot of calibrated CEM data versus SRM data, dry


Oxygen - Plot 2 - Plot of calibrated CEM data versus SRM data

0 to 20.8 %

0

2

4

6

8

10

12

14

16

18

20

0 2 4 6 8 10 12 14 16 18

SR

M,

% (

Dry

)

CEM, % (Calibration Function Applied, Dry)



vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Oxygen - Valid range & range extension



0 to 20.8 %










0 to 20.9 %



0.0

10.0

20.0

30.0

40.0

50.0

60.0

70.0

0.0 10.0 20.0 30.0 40.0 50.0 60.0

SR

M, %

Calibrated CEM, %



vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

to

to

to

to

to

to

to

to

to

to

SRM

Measured

Value

yi

%

Moisture - Raw Monitoring Data


CEM

Measured

Value

xi

%

17 25 11 15 01:01 25 11 15 01:31 19.0 18.9

18 25 11 15 02:01 25 11 15 02:31 18.8 18.7

15 24 11 15 23:01 24 11 15 23:31 18.8 18.8

16 25 11 15 00:01 25 11 15 00:31 18.7 18.9

13 24 11 15 21:01 24 11 15 21:31 18.6 18.7

14 24 11 15 22:01 24 11 15 22:31 18.2 18.7

11 24 11 15 19:01 24 11 15 19:31 18.9 19.1

12 24 11 15 20:01 24 11 15 20:31 18.8 18.8

--

outlier 24 11 15 17:01 24 11 15 17:31 19.0 19.8

10 24 11 15 18:01 24 11 15 18:31 19.1 19.2

not used

Linearity Data

0.0 --

not used 0.0 --

not used 0.0 --

not used 0.0 --

not used 0.0


1


0.0 0.0

2 0.0 0.0

3 0.0 0.0

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

to

to

to

to

to

to

to

to

to

to18 25 11 15 02:01 25 11 15 02:31 18.7 18.8

14 24 11 15 22:01 24 11 15 22:31 18.7 18.2

15 24 11 15 23:01 24 11 15 23:31 18.8 18.8

16 25 11 15 00:01 25 11 15 00:31 18.9 18.7

17 25 11 15 01:01 25 11 15 01:31 18.9 19.0

10 24 11 15 18:01 24 11 15 18:31 19.2 19.1

11 24 11 15 19:01 24 11 15 19:31 19.1 18.9

12 24 11 15 20:01 24 11 15 20:31 18.8 18.8

13 24 11 15 21:01 24 11 15 21:31 18.7 18.6

not used

Linearity Data

--

not used --

not used --

not used --

not used --

outlier 24 11 15 17:01 24 11 15 17:31 19.8 19.0

Moisture - Standardised Monitoring Data



SRM

Corrected

Value

y is

%

CEM

corrected

1


0.0 0.0

2 0.0 0.0

3 0.0 0.0

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Moisture - Plot 1 - Time series of data

vD ks 0*5.1

0

5

10

15

20

25

0 1 2 3 4 5 6 7 8 9 10 11

Co

nc

en

tra

tio

n (

%)

Data Point


SRM CEM

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06


Moisture - Application of the Calibration Function & Outlier Test






0.0 -- No0.0 -- No

19.0 19.8 0.8 Yes19.1 19.2 0.2 No18.9 19.1 0.2 No

Outlier test data

AMS at

measured

conditions

SRM at CEMs

Measuring

conditions


No)




0.15

0.26

Data Source

not usednot usednot used

outlier101112

123

not usednot used

13141516

Lower limit at 2 SD

0.68

-0.38

Upper limit at 2 SD

18.7 18.9 0.2 No19.0 18.9 -0.1 No18.8 18.7 -0.1

Sample

No

Surrogate Zero's

Linearity Data

Parallel test data

0 00

0.000.00

NoNo

0 0 0.00 No

0.0 -- No0.0 -- No0.0 -- No

18.8 18.8 0.1 No18.6 18.7 0.1 No18.2 18.7 0.5 No18.8 18.8 0.0 No

0



1718

vD ks 0*5.1

-0.6

-0.4

-0.2

0.0

0.2

0.4

0.6

0.8

1.0

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14

Co

nc

en

tra

tio

n (

%)

Data Point



vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

to

to

to

to

to

to

to

to

to

to

14 24 11 15 22:01 24 11 15 22:31 18.2 17.7 18.7

18 25 11 15 02:01 25 11 15 02:31 18.8 18.3 18.7

18.7

Moisture - Data used to calculate calibrated values



CEM

Measured

Value

xi

%

CEM

calibrated

SRM

Corrected

Value

y is

%

18.8

1


19.1

not used

Linearity Data

0.0 --

not used 0.0 --

not used 0.0 --

not used 0.0

18.9 18.411 24 11 15 19:01 24 11 15 19:31

16 25 11 15 00:01 25 11 15 00:31

0.0

--

not used 0.0 --

15 24 11 15 23:01 24 11 15 23:31 18.8 18.3 18.8

18.2 18.9

17 25 11 15 01:01 25 11 15 01:31 19.0 18.5 18.9

12 24 11 15 20:01 24 11 15 20:31 18.8 18.2

24 11 15 21:01 24 11 15 21:31 18.6 18.1 18.7

0.0 0.2

13

0.2 0.0

outlier 24 11 15 17:01 24 11 15 17:31 19.0 19.8

10 24 11 15 18:01 24 11 15 18:31 19.1 18.5 19.2

0.0

3 0.0

2 0.0 0.2

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06





a is the intercept

b is the slope


Moisture - The Calibration Function

Calibrated Value Moisture (%) = 0.961 X (CEM reading) + 0.221 %

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

17 18.5 18.9 0.4 0.0 0.0

18 18.3 18.7 0.4 0.0 0.0

14 17.7 18.7 1.0 0.6 0.4

15 18.3 18.8 0.5 0.1 0.0

16 18.2 18.9 0.7 0.3 0.1

11 18.4 19.1 0.7 0.3 0.1

12 18.2 18.8 0.6 0.2 0.0

13 18.1 18.7 0.6 0.2 0.0

not used

outlier

10 18.5 19.2 0.7 0.3 0.1

not used

not used

not used

2 0.2 0.0 -0.2 -0.6 0.4

3 0.2 0.0 -0.2 -0.6 0.4

not used

Moisture - Data Used for the variability test


Sample CEM

SRM Value

y is

%

Difference

of

measured

from

calibrated

Difference

(D - Dmean)

Square of

Difference

(D - Dmean)2

1 0.2 0.0 -0.2 -0.6 0.4

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06


Where



Where Surrogate Emission Limit = 30 % Measurement Uncertainty = 30%



Moisture - Variability Test



Conditions.

1.96

0.41 < 6.68



0.42 < 4.81


vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Plot of calibrated CEM data versus SRM data


Moisture - Plot 2 - Plot of calibrated CEM data versus SRM data

0 to 26.7 %

vD ks 0*5.1

0

5

10

15

20

25

0 2 4 6 8 10 12 14 16 18 20

SR

M,

%

CEM, % (Calibration Function Applied)



vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Moisture - Valid range & range extension



0 to 26.7 %










0 to N/A %



vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Note - CEMS Functional testing and associated reporting do not form part of ESG's Mcerts accreditation.

Section - Functional Test Report

Internal check of the CEM Yes

Cleanliness of the optical components Not Undertaken

Flushing air supply Not Undertaken

Obstructions in the optical path Not Undertaken

After re-assembly at the measurement location at least the

following shall be checked

N/A

Not Undertaken

Contamination control (internal check of optical surfaces) Not Undertaken

2. Sampling Systems

A visual inspection of the sampling system shall be performed, noting the condition of the following components, when fitted:

Sampling probe Yes

Gas conditioning systems N/A

Pumps Yes

All connections Yes

Sample lines Yes

Power supplies Yes

Filters Yes

The sampling system shall be in good condition and free of any

visible faults, which may decrease the quality of data.

Yes

3. Leak testing

Leak testing shall be performed according to the CEMs

manuals. The test shall cover the entire sampling system.

Yes

4. Zero and Span check

Reference zero and span materials shall be used to verify the

corresponding readings of the CEM.

Yes

In case of non-extractive CEM, zero and span checks shall be

performed using a reference-path free of flue gas before and

after readjustment and after re-assembly of the CEM at the

measurement location.

N/A

EA Proforma Functional Checks

Requirement Yes / No / N/A Notes

1. Alignment and Cleanliness

A visual inspection, with reference to the CEMs manuals, shall be carried out on the following when applicable:

Alignment of the measuring system

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Yes

Reference material concentration approximately 40 % of 2 x the

ELV;

Yes


ELV;

Yes

Reference material concentration approximately 80 % of 2 x

the ELV;

Yes

Reference material with zero concentration; Yes

Section 5 - Functional Checks


Requirement Yes / No / N/A Notes

5. Linearity

During the calibration/linearity tests the applied concentrations

should be logged onto the DCS to prove the complete system

i.e. concentration applied to the instrument is represented by

the instrument output and identical to the value logged on the

DCS. DCS logged values should be included in the instrument

service report.

Data Checked

The linearity of the CEM's response shall be checked using five

different reference materials, including a zero concentration.

Yes

The reference material with zero concentration, as well as the

reference materials with four different concentrations, shall

have a verifiable quantity and quality.

Yes

After each change in concentration, the first instrument reading shall be taken after a time period equal to at least three times the

response time of the CEM. At each reference material concentration, at least three readings shall be made, six readings shall be

taken at zero. The time period between the start of each of the three readings shall be separated by at least four times the response

time.

Note

Where no other method is possible, the linearity can also be performed with the aid of reference materials such as grating filters or

gas filters.

The linearity shall be calculated and tested using the procedure as given in EN 14181 annex B. If the CEM does not pass this test,

then the problem shall be identified and rectified.

6. Interferences

A test shall be undertaken if the process gases to be monitored

contain components that are known interferences, as identified

during QAL1.

N/A

7. Zero and Span drift (Audit)

The zero point and span drift shall be obtained from and

evaluated on the basis of the records of QAL3.

Yes

8. Response Time

The response time of the CEM shall be checked. This can be

performed, if appropriate, by feeding of the reference material

at the end of the sampling probe. The response time shall not

exceed the measured value that has been identified during

QAL1.

Yes

In case of gaseous reference materials, these four reference

materials can be obtained from different gas cylinders or can be

prepared by means of a calibrated dilution system from one

single gas concentration.

Yes

The reference material concentrations shall be selected such

that the measured values are at approximately 20 %, 40 %, 60

% and 80 % of the range of two times the emission limit value.

It is necessary to know the values of the ratios of their

concentrations precisely enough so that an incorrect failure of

the linearity test does not occur. The dry test reference material

shall be applied to the inlet of the CEM.

The individual CEMs are tested using the following concentrations applied in a randomised sequence:

Reference material with zero concentration; Yes


ELV;

Yes

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Section 5 - Functional Checks


Date and time work was undertaken Yes

Certification details Yes

Compliance with MCERTS (including certificate no.) Yes

9. Service Report

As a minimum requirement the service report should include the following:

Document reference for work instruction for the type of work

being undertaken

Yes

Instrument manufacturer Yes

Instrument type Yes

Instrument model Yes

Instrument Serial No Yes

Name and signature of service engineer Yes

Instrument configuration including computer file and name if

available

Yes

Operating principle Yes

Equipment used – type, serial no’s, calibration dates Yes

Gases used – certificate numbers, expiry dates, binary / mix Yes

Calibration and linearity data as required by EN14181 Yes

Operating range Yes

Measuring condition Yes

Logged data for period of calibration and linearity Yes

Location Yes

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

Control Box DGM Horiba PG-250 Analyser Laboratory Balance

Box Thermocouples JCT JCC P-1 Cooler Tape Measure

Meter In Thermocouple MAK 10 Cooler Stopwatch

Meter Out Thermocouple FT-IR Protractor

Control Box Timer FT-IR Oven Box Barometer

Umbilical Bernath 3006 FID Digital Micromanometer

Oven Box Signal 3030 FID Digital Temperature Meter

Probe Servomex Stack Thermocouple

Probe Thermocouple JCT Heated Head Filter Mass Flow Controller

Probe Thermo FID Mass Flow Control Box

Probe Thermocouple Stackmaster 1m Heated Line (1)

Probe 1m Heated Line (2)

Probe Thermocouple 1m Heated Line (3)

S-Pitot 5m Heated Line (1)

L-Pitot 5m Heated Line (2)

Site Balance 10m Heated Line (1)

Last Impinger Arm 10m Heated Line (2)

Dioxins Cond. TC 15m Heated Line (1)

Callipers 15m Heated Line (2)

Small DGM 20m Heated Line (1)

Heater Controller 20m Heated Line (2)

- 03.CD

11.61 -

Section 6 - Calibrateable Equipment Checklist

- 5854

- -

END OF REPORT

9.29 12.2 15.21

3.02

10.61 - -

- -

16.5

- - 15.7

-

3.165

- 8.17

-

- - -

- FTIR Heater Box for - -

- - -

6.7 -

- -

23.15 -

- -

- -

15.1F -

Extractive Sampling Instrumental Analyser/s Miscellaneous

Equipment Equipment I.D. Equipment Equipment I.D. Equipment Equipment I.D.

12.8 20.2

10.2A - 17.6

10.2B 5854 -

Ecophysics Analyser

vD ks 0*5.1

vD ks 0*5.1


County Cork

- of 91

LEK 10073 AST


Permit No. P0006-03

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 04-01-2017:02:07:06

BS EN 14181:2004 - AST CEMs Calibration Report · 2-4 Langlands Place Business Manager Project...

Documents

Transcript of BS EN 14181:2004 - AST CEMs Calibration Report · 2-4 Langlands Place Business Manager Project...