1

BORONIC ACID COMPOUNDSBORONIC ACID COMPOUNDS

Ⅱ

Suzuki coupling reaction, for synthesis of biaryl compounds from aryl boronic acids and aryl halides using transition metals as catalysts, is one of the most actively researched organic synthesis reaction in recent years.

The reaction in aqueous/organic biphase system using palladium compounds with phosphine ligand as catalysts and carbonates such as sodium carbonate as bases is common method1). NaOH2), Et3N3) and K3PO44) are also applicable to the reaction except for carbonates. The reaction is accelerated by 1 equivalent of TBAB（Tetrabutylammonium Bromide） which is a

phase transfer catalyst, and progresses even if only in the aqueous phase5). Recently, organic

synthesis using microwave have been actively investigated. Studies have shown that transition

metals are unnecessary and that phase catalysts such as TBAB are sufficient for Suzuki

coupling reactions to progress if microwave is used6).

Wako provides a wide variety of chemicals used for Suzuki coupling reaction including Boronic acids, Boronic acid esters and Palladium catalysts.Please contact us if you require different package size.

Reaction Examples

References

1） Miyaura, N.; Suzuki, A.: Chem. Rev., 95, 2457（1995）.

2） Watanabe, T.; Miyaura, N.; Suzuki, A.: Synlett, 207（1992）.

3） Muller, W.; Lowe, D. A. Neijt, H. Urwyler, S.: Helv. Chim. Acta, 75, 855（1992）.

4） Coleman, R. S.; Grant, E. B.: Tetrahedron Lett., 34, 222（1993）.

5） Badone, D.; Baroni, M.; Cardamone, R.; Ielmini, A. Guzzi, U.: J. Org. Chem., 62, 7170（1997）.

6） Leadbeater, N. E.; Marco, M.: J.Org. Chem., 68, 5660（2003）.

7） Yuzuru Masuda et al.: J. Org. Chem, 62, 6458（1997）.

2

BORONIC ACIDSBORONIC ACID COMPOUNDS

［CAS No.13675-18-8］

Tetrahydroxydiboron

326-63411322-63413

1g5g

［13061-96-6］

Methylboronic Acid

320-64151326-64153

1g5g

［84110-40-7］

（2-Methylpropyl）boronic Acid

329-72171327-72172

5g25g

［4426-47-5］

n-Butylboronic Acid

327-52331323-52333

1g5g

［4737-50-2］

1-Pentylboronic Acid

322-84871328-84873

1g5g

［59239-44-0］

（E）-1-Pentenylboronic Acid

320-72961326-72963

1g5g

［16343-08-1］

n -Hexylboronic Acid

326-72201322-72203

1g5g

［13331-23-2］

2-Furanboronic Acid

320-73441326-73443

1g5g

［27329-70-0］

5-Formyl-2-furanboronic Acid

324-67351 1g

［6165-68-0］

2-Thiopheneboronic Acid

321-63461327-63463

1g5g

［6165-69-1］

3-Thiopheneboronic Acid

322-64091328-64093

1g5g

［162607-17-2］

5-Bromo-2-thiopheneboronic Acid

321-69561327-69563

1g5g

［162607-18-3］

5-Chloro-2-thiopheneboronic Acid

325-64101321-64103

1g5g

［4347-31-3］

2-Formyl-3-thiopheneboronic Acid

326-64131322-64133

1g5g

［17303-83-2］

3-Formyl-2-thiopheneboronic Acid

320-65251326-65253

1g5g

［206551-43-1］

5-Acetyl-2-thiopheneboronic Acid

325-84361323-84362

5g25g

［26076-46-0］

2,5-Thiophenediboronic Acid

328-84091326-84092

5g25g

［135884-31-0］

1-BOC-pyrrole-2-boronic Acid

327-87001323-87003

1g5g

［1692-25-7］

3-Pyridineboronic Acid

322-59841328-59843

1g5g

［1692-15-5］

4-Pyridineboronic Acid

329-59851325-59853

1g5g

2-Chloro-4-pyridineboronic Acid

326-77201 1g

［174669-73-9］

2-Fluoro-3-pyridineboronic Acid

324-83351320-83353

1g5g

［163105-89-3］

2-Methoxy-5-pyridineboronic Acid

326-57301 1g

［4433-63-0］

Ethylboronic Acid

327-84941323-84943

1g5g

3

［221006-70-8］

2,6-Dimethoxy-3-pyridineboronic Acid

329-76191325-76193

1g5g

［98-80-6］

Dihydroxyphenylborane

041-23371 10g

［4612-26-4］

p-Phenylenediboronic Acid

327-67341323-67343

1g5g

［244205-40-1］

o-Bromophenylboronic Acid

326-70501324-70502

5g25g

［89598-96-9］

m-Bromophenylboronic Acid

328-69571324-69573

1g5g

［5467-74-3］

p-Bromophenylboronic Acid

322-70461328-70463

1g5g

o-Chlorophenylboronic Acid

［3900-89-8］

321-63341327-63343

1g5g

［63503-60-6］

m-Chlorophenylboronic Acid

327-64161323-64163

1g5g

［1679-18-1］

p-Chlorophenylboronic Acid

320-63311328-63312

5g25g

［175883-63-3］

3-Chloro-4-methylphenylboronic Acid

320-84931 1g

［151169-74-3］

2,3-Dichlorophenylboronic Acid

326-70481324-70482

5g25g

［68716-47-2］

2,4-Dichlorophenylboronic Acid

325-64081321-64083

1g5g

［135145-90-3］

2,5-Dichlorophenylboronic Acid

324-69551320-69553

1g5g

［73852-17-2］

2,6-Dichlorophenylboronic Acid

328-77021324-77023

1g5g

［151169-75-4］

3,4-Dichlorophenylboronic Acid

328-70201326-70202

5g25g

［67492-50-6］

3,5-Dichlorophenylboronic Acid

328-70181326-70182

5g25g

［175883-60-0］

3-Chloro-4-methoxyphenylboronic Acid

321-88121327-88123

1g5g

［89694-48-4］

5-Chloro-2-methoxyphenylboronic Acid

320-83331328-83332

5g25g

［279261-81-3］

3-Chloro-4-ethoxyphenylboronic Acid

325-84861321-84863

1g5g

［313545-72-1］

2-Chloro-4-fluorophenylboronic Acid

329-84881 1g

［144432-85-9］

3-Chloro-4-fluorophenylboronic Acid

323-70511329-70513

1g5g

［137504-86-0］

4-Chloro-3-fluorophenylboronic Acid

320-67331 1g

［182344-18-9］

2-Chloro-5-（trifluoromethyl）phenylboronic Acid

329-84901 1g

［254993-59-4］

2-Chloro-4-trifluoromethylphenylboronic Acid

321-76151 1g

Biphenyl

4

Boronic Acids

［176976-42-4］

4-Chloro-3-（trifluoromethyl）phenylboronic Acid

326-84911 500mg

［1993-03-9］

o-Fluorophenylboronic Acid

320-57201326-57203

1g5g

［768-35-4］

m-Fluorophenylboronic Acid

326-72181324-72182

5g25g

［1765-93-1］

p-Fluorophenylboronic Acid

325-39431323-39432

5g25g

［121219-16-7］

2,3-Difluorophenylboronic Acid

322-81071328-81073

1g5g

［144025-03-6］

2,4-Difluorophenylboronic Acid

327-57071325-57072

5g25g

2,5-Difluorophenylboronic Acid

［193353-34-3］

329-80361327-80362

5g25g

［162101-25-9］

2,6-Difluorophenylboronic Acid

329-70471325-70473

1g5g

［168267-41-2］

3,4-Difluorophenylboronic Acid

329-75971327-75972

5g25g

［156545-07-2］

3,5-Difluorophenylboronic Acid

322-77041320-77042

5g25g

［170981-26-7］

2-Fluoro-4-methylphenylboronic Acid

327-83341323-83343

1g5g

［139911-29-8］

（4-Fluoro-2-methylphenyl）boronic Acid

328-69071324-69073

1g5g

［139911-27-6］

4-Fluoro-3-methylphenylboronic Acid

325-80341323-80342

5g25g

［163517-62-2］

5-Fluoro-2-methylphenylboronic Acid

321-84961327-84963

1g5g

［182344-23-6］

4-Fluoro-3-（trifluoromethyl）phenylboronic Acid

328-83371324-83373

1g5g

［214210-21-6］

3-Cyano-4-fluorophenylboronic Acid

328-76161 1g

［259209-20-6］

5-Fluoro-2-hydroxyphenylboronic Acid

321-84101327-84103

1g5g

［352534-79-3］

2-Fluoro-5-formylphenylboronic Acid

324-84951 1g

［179897-94-0］

5-Fluoro-2-methoxyphenylboronic Acid

328-79461326-79462

5g25g

［149507-26-6］

3-Fluoro-4-methoxyphenylboronic Acid

322-72161328-72163

1g5g

［279263-10-4］

4-Ethoxy-3-fluorophenylboronic Acid

326-84891322-84893

1g5g

［226396-32-3］

2,3,4-Trifluorophenylboronic Acid

324-82251320-82253

1g5g

［143418-49-9］

3,4,5-Trifluorophenylboronic Acid

328-63471324-63473

1g5g

［247564-72-3］

2,4,5-Trifluorophenylboronic Acid

329-72791325-72793

1g5g

5

［89466-08-0］

o-Hydroxyphenylboronic Acid

323-72951329-72953

1g5g

［87199-18-6］

m-Hydroxyphenylboronic Acid

323-72191329-72193

1g5g

［71597-85-8］

（p-Hydroxyphenyl）boronic Acid

325-69081321-69083

1g5g

［30418-59-8］

m-Aminophenylboronic Acid

329-52151325-52153

1g5g

［85006-23-1］

m-Aminophenylboronic AcidHydrochloride

321-69061327-69063

1g5g

［13331-27-6］

m-Nitrophenylboronic Acid

324-59801320-59803

1g5g

p-Nitrophenylboronic Acid

［24067-17-2］

321-59811327-59813

1g5g

［117342-20-8］

3-Methoxycarbonyl-5-nitrophenylboronic Acid

326-85011 1g

［85107-55-7］

4-Methoxycarbonyl-2-nitrophenylboronic Acid

329-85001 1g

［5720-06-9］

o-Methoxyphenylboronic Acid

327-63321325-63322

5g25g

［10365-98-7］

m-Methoxyphenylboronic Acid

324-41471320-41473

1g5g

［5720-07-0］

p-Methoxyphenylboronic Acid

321-69201329-69202

5g25g

［90555-66-1］

m-Ethoxyphenylboronic Acid

320-84791326-84793

1g5g

［22237-13-4］

p-Ethoxyphenylboronic Acid

322-82171320-82172

5g25g

［153624-46-5］

p-Isopropoxyphenylboronic Acid

327-72971323-72973

1g5g

［186497-67-6］

p-Propoxyphenylboronic Acid

324-88111322-88112

5g25g

［105365-51-3］

p-Butoxyphenylboronic Acid

324-88091320-88093

1g5g

［175676-65-0］

o-（Trifluoromethoxy）phenylboronic Acid

324-73461320-73463

1g5g

［179113-90-7］

m-（Trifluoromethoxy）phenylboronicAcid

321-73471327-73473

1g5g

［139301-27-2］

p-（Trifluoromethoxy）phenylboronicAcid

321-83361327-83363

1g5g

［208399-66-0］

4-Methoxy-2-methylphenylboronic Acid

326-84391322-84393

1g5g

［133730-34-4］

2,4-Dimethoxyphenylboronic Acid

327-70531323-70533

1g5g

［23112-96-1］

2,6-Dimethoxyphenylboronic Acid

325-70191323-70192

5g25g

［107099-99-0］

2,5-Dimethoxyphenylboronic Acid

328-80331326-80332

5g25g

BiphenylBoronic Acids

6

［122775-35-3］

3,4-Dimethoxyphenylboronic Acid

320-70521328-70522

5g25g

［121124-97-8］

3-Formyl-4-methoxyphenylboronic Acid

321-72991329-72992

5g25g

［301699-39-8］

3,5-Dimethyl-4-methoxyphenylboronic Acid

322-85471328-85473

1g5g

［182163-96-8］

3,4,5-Trimethoxyphenylboronic Acid

327-73451 1g

［168618-42-6］

o-（Methylthio）phenylboronic Acid

320-84431326-84433

1g5g

［128312-11-8］

m-（Methylthio）phenylboronic Acid

322-69091328-69093

1g5g

p-（Methylthio）phenylboronic Acid

［98546-51-1］

321-41481327-41483

1g5g

［16419-60-6］

o-Methylphenylboronic Acid

328-41491324-41493

1g5g

［17933-03-8］

m-Methylphenylboronic Acid

321-41501327-41503

1g5g

［5720-05-8］

p-Methylphenylboronic Acid

323-63301321-63302

5g25g

［183158-34-1］

2,3-Dimethylphenylboronic Acid

323-70491321-70492

5g25g

［55499-44-0］

2,4-Dimethylphenylboronic Acid

321-77011327-77013

1g5g

［85199-06-0］

2,5-Dimethylphenylboronic Acid

325-77031321-77033

1g5g

［100379-00-8］

2,6-Dimethylphenylboronic Acid

325-72151321-72153

1g5g

［55499-43-9］

3,4-Dimethylbenzeneboronic Acid

325-53731321-53733

1g5g

［172975-69-8］

3,5-Dimethylphenylboronic Acid

322-80351320-80352

5g25g

［90002-36-1］

o-Ethylphenylboronic Acid

327-88081323-88083

1g5g

［63139-21-9］

p-Ethylphenylboronic Acid

328-73481326-73482

5g25g

［2156-04-9］

p-Vinylphenylboronic Acid

329-84401325-84403

1g5g

［51323-43-4］

m-（Bromomethyl）phenylboronic Acid

323-84801329-84803

1g5g

［68162-47-0］

p-（Bromomethyl）phenylboronic Acid

320-84811326-84813

1g5g

［87199-14-2］

o-（Hydroxymethyl）phenylboronicAcid

328-84971324-84973

1g5g

［89787-12-2］

o-Isopropylphenylboronic Acid

322-84991328-84993

100mg500mg

［134150-01-9］

p-Propylphenylboronic Acid

323-73431329-73433

1g5g

7

［216019-28-2］

m-Isopropylphenylboronic Acid

325-84981321-84983

100mg500mg

［16152-51-5］

p-Isopropylphenylboronic Acid

321-77991327-77993

1g5g

［145240-28-4］

4-n-Butylbenzeneboronic Acid

326-54501322-54503

1g5g

［121219-12-3］

p-Pentylphenylboronic Acid

324-84831320-84833

100mg500mg

［123324-71-0］

p-t-Butylphenylboronic Acid

322-64111328-64113

1g5g

［1423-27-4］

o-Trifluoromethylphenylboronic Acid

328-76281324-76283

1g5g

m-（Trifluoromethyl）phenylboronic Acid

［1423-26-3］

328-41511324-41513

1g5g

［128796-39-4］

p-（Trifluoromethyl）phenylboronic Acid

325-41521321-41523

1g5g

［153254-09-2］

2,4-Bis（trifluoromethyl）phenylboronicAcid

327-84821323-84823

1g5g

［73852-19-4］

3,5-Bis（trifluoromethyl）phenylboronicAcid

320-63291326-63293

1g5g

［150255-96-2］

m-Cyanophenylboronic Acid

326-20931324-20932

5g25g

［126747-14-6］

p-Cyanophenylboronic Acid

320-57061326-57063

1g5g

［87199-16-4］

m-Formylphenylboronic Acid

327-57211323-57213325-57212

1g5g25g

［87199-17-5］

p-Formylphenylboronic Acid

324-57221320-57223

1g5g

［123088-59-5］

p-（Aminocarbonyl）phenylboronic Acid

320-76121326-76123

1g5g

［204841-19-0］

m-Acetylphenylboronic Acid

324-70541322-70542

5g25g

［149104-90-5］

p-Acetylphenylboronic Acid

323-64141329-64143

1g5g

［268218-94-6］

（p-Benzoylphenyl）boronic Acid

320-68311 1g

［25487-66-5］

m-Carboxyphenylboronic Acid

323-57051329-57053

1g5g

［14047-29-1］

p-Carboxyphenylboronic Acid

320-41451326-41453

1g5g

［120153-08-4］

4-Carboxy-3-fluorophenylboronic Acid

323-84921 1g

［101084-81-5］

3-Carboxy-5-nitrophenylboronic Acid

321-84841 1g

［85107-54-6］

4-Carboxy-2-nitrophenylboronic Acid

328-84851 1g

8

［374538-03-1］

o-（Methoxycarbonyl）phenylboronicAcid

329-76211325-76213

1g5g

［99769-19-4］

m-（Methoxycarbonyl）phenylboronicAcid

326-57281322-57283

1g5g

［99768-12-4］

p-（Methoxycarbonyl）phenylboronicAcid

323-57291329-57293

1g5g

［380430-53-5］

o-EthoxycarbonylphenylboronicAcid

326-73421322-73423

1g5g

［4334-87-6］

m-Ethoxycarbonylphenylboronic Acid

329-57151325-57153

1g5g

［4334-88-7］

p-Ethoxycarbonylphenylboronic Acid

326-57161322-57163

1g5g

m-（Isopropoxycarbonyl）phenylboronicAcid

［342002-80-6］

325-74091321-74093

1g5g

［342002-82-8］

p-（Isopropoxycarbonyl）phenylboronicAcid

322-72781328-72783

1g5g

［169760-16-1］

o-Acetamidophenylboronic Acid

329-56931325-56933

1g5g

［78887-39-5］

m-Acetamidophenylboronic Acid

322-52141328-52143

1g5g

［101251-09-6］

p-Acetamidophenylboronic Acid

326-56941322-56943

1g5g

［480424-95-1］

N-（4-Boronophenyl）succinamic Acid

328-59821324-59823

1g5g

［146140-95-6］

2-（Pivaloylamino）phenylboronic Acid

321-57111327-57113

1g5g

［380430-68-2］

3-（BOC-amino）phenylboronic Acid

323-52311329-52313

1g5g

［380430-49-9］

4-（BOC-amino）phenylboronic Acid

320-52321 1g

2-N-（Methanesulfonamide）-phenylboronic Acid

325-57251321-57253

1g5g

［148355-75-3］

3-N-（Methanesulfonamide）-phenylboronic Acid

322-57261328-57263

1g5g

［380430-57-9］

4-N-（Methanesulfonamide）-phenylboronic Acid

329-57271325-57273

1g5g

［178432-25-2］

o-［（Dimethylamino）sulfonyl］phenylboronic Acid

327-68321 1g

［17865-11-1］

p-（Trimethylsilyl）phenylboronic Acid

328-85331324-85333

1g5g

［94839-07-3］

3,4-（Methylenedioxy）phenylboronicAcid

322-57381328-57383

1g5g

［192182-55-1］

1-Methyl-5-indoleboronic Acid

323-77211 1g

［164014-95-3］

（1,4-Benzodioxan-6-yl）boronic Acid

323-56951329-56953

1g5g

［98437-24-2］

2-Benzofuranboronic Acid

322-84371328-84373

1g5g

BiphenylBoronic Acids

9

Boronic Acids

［98437-23-1］

Benzo［b］thiophene-2-boronic Acid

329-64121325-64123

1g5g

［191162-39-7］

3-Quinolineboronic Acid

328-74101324-74103

1g5g

［86-58-8］

8-Quinolineboronic Acid

327-77111323-77113

1g5g

［192182-56-2］

4-Isoquinolineboronic Acid

329-63381 1g

［13922-41-3］

1-Naphthaleneboronic Acid

326-63391322-63393

1g5g

3-Biphenylboronic Acid

［5122-95-2］

328-82151324-82153

1g5g

［5122-94-1］

4-Biphenylboronic Acid

328-59441326-59442

5g25g

4'-Methyl-4-biphenylboronic Acid

328-24391 1g

［178305-99-2］

2-Fluoro-4-biphenylylboronicAcid

327-88101323-88103

1g5g

［153035-62-2］

4'-Ethyl-4-biphenylboronic Acid

321-24401 1g

［190661-29-1］

o-Benzyloxyphenylboronic Acid

329-77171325-77173

1g5g

［156682-54-1］

m-Benzyloxyphenylboronic Acid

326-77181322-77183

1g5g

［146631-00-7］

p-Benzyloxyphenylboronic Acid

329-84381325-84383

1g5g

［133057-83-7］

4-Benzyloxy-3-fluorophenylboronicAcid

323-84421329-84423

1g5g

p-BenzyloxycarbonylphenylboronicAcid

［184000-11-1］

327-84441323-84443

1g5g

［100124-07-0］

4-Phenoxathiinboronic Acid

323-67321 1g

10

BORONIC ACIDS ESTERS

［5735-41-1］

2-（Hydroxymethyl）phenylboronic AcidCyclic Monoester

326-72941322-72943

1g5g

［25015-63-8］

4,4,5,5-Tetramethyl-1,3,2-dioxaborolane

325-59831323-59832

5g25g

［61676-62-8］

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

327-41461325-41462

5g25g

［69190-62-1］

2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

324-56981320-56983

1g5g

［161344-85-0］

2-Butyl-N,N,N',N'-tetramethyl-1,3,2-dioxaborolane-（4R,5R）-dicarboxamide

321-52351327-52353

1g5g

［161344-84-9］

2-Butyl-N,N,N',N'-tetramethyl-1,3,2-dioxaborolane-（4S,5S）-dicarboxamide

328-52361324-52363

1g5g

trans-4,4,5,5-Tetramethyl-2-（1-octenyl）-1,3,2-dioxaborolane

［83947-55-1］

322-60211328-60213

1g5g

［126689-01-8］

2-Cyclopropyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

322-76181 1g

［269410-08-4］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）-1H-pyrazole

324-60151320-60153

1g5g

1-Methyl-4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）-1H-pyrazole

326-57421322-57423

1g5g

1-BOC-4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）pyrazole

321-60161327-60163

1g5g

1-Benzyl-4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）-1H-pyrazole

323-77191329-77193

1g5g

3,5-Dimethyl-4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）-1H-pyrazole

322-57141328-57143

1g5g

［248924-59-6］

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）furan

326-59981322-59983

1g5g

［193978-23-3］

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）thiophene

323-63421329-63423

1g5g

［214360-70-0］

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）thiophene

320-63431326-63433

1g5g

［329214-79-1］

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）pyridine

328-60171324-60173

1g5g

［181219-01-2］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）pyridine

325-60181321-60183

1g5g

［444120-94-9］

2-Chloro-5-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）pyridine

324-76141320-76143

1g5g

［445264-61-9］

2-Methoxy-5-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）pyridine

327-57331 1g

2-Amino-5-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）pyridine

322-77161328-77163

1g5g

1-［5-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）pyridin-2-yl］piperazine

321-76271327-76273

1g5g

2-Hydroxy-5-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）pyridine

327-77231 1g

［485799-04-0］

4-［5-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）pyridin-2-yl］morpholine

324-76261320-76263

1g5g

1-Methyl-4-［4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）pyridin-2-yl］piperazine

320-76241 1g

1-［4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）pyridin-2-yl］piperazine

324-77241 1g

2-Amino-5-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）pyrimidine

321-77251 1g

［214360-73-3］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）aniline

320-59901326-59903

1g5g

［171364-78-6］

N,N-Dimethyl［4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］amine

325-82161321-82163

1g5g

［461699-81-0］

2-Methoxy-4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）aniline

329-82201325-82203

1g5g

［190788-59-1］

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）nitrobenzene

323-60001329-60003

1g5g

2,6-Dimethoxy-5-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）pyrimidine

322-76201328-76203

1g5g

［24388-23-6］

（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzene

327-59911325-59912

5g25g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）chlorobenzene

［195062-61-4］

325-59951323-59952

5g25g

［401797-02-2］

2-（3,4-Dichlorophenyl）-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

325-63361323-63362

5g25g

［214360-58-4］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）fluorobenzene

329-59971325-59973

1g5g

［288101-48-4］

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）-1,5-difluorobenzene

322-59961320-59962

5g25g

［191171-55-8］

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）aniline

320-59881326-59883

1g5g

［210907-84-9］

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）aniline

327-59891323-59893

1g5g

［68716-48-3］

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）nitrobenzene

320-60011326-60013

1g5g

［171364-83-3］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）nitrobenzene

327-60021323-60023

1g5g

［269409-97-4］

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenol

324-60031320-60033

1g5g

［214360-76-6］

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenol

321-60041327-60043

1g5g

［269409-70-3］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenol

327-57451323-57453

1g5g

［269410-22-2］

2-Methoxy-4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）phenol

323-57311329-57313

1g5g

2-（3-Benzyloxyphenyl）-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

321-82141327-82143

1g5g

［269410-25-5］

2,6-Dimethyl-4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）phenol

328-57121324-57123

1g5g

11

Boronic Acids Esters

12

2-（4-Benzyloxyphenyl）-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

［754226-40-9］

327-76131323-76133

1g5g

［253342-48-2］

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）toluene

327-82241323-82243

1g5g

［214360-46-0］

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzonitrile

321-59931327-59933

1g5g

［171364-82-2］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzonitrile

328-59941324-59943

1g5g

［128376-64-7］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzaldehyde

320-86131326-86133

1g5g

［269409-73-6］

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzoic Acid

324-59921320-59923

1g5g

［180516-87-4］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzoic Acid

320-57441326-57443

1g5g

［653589-95-8］

Methyl 2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzoate

323-82221329-82223

1g5g

Methyl 3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzoate

［480425-35-2］

322-57401328-57403

1g5g

［171364-80-0］

Methyl 4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzoate

329-57411325-57413

1g5g

［269409-99-6］

Ethyl 2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzoate

323-57171329-57173

1g5g

［269410-00-6］

Ethyl 3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzoate

320-57181326-57183

1g5g

［195062-62-5］

Ethyl 4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzoate

327-57191323-57193

1g5g

［190788-60-4］

2-（2-Methoxyphenyl）-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

326-82191322-82193

1g5g

［480424-68-8］

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl Acetate

328-60051324-60053

1g5g

［480424-69-9］

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl Acetate

325-60061321-60063

1g5g

［480424-70-2］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl Acetate

322-60071328-60073

1g5g

2-Methoxy-4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl Acetate

320-57321326-57323

1g5g

［480424-71-3］

t-Butyl 2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl Carbonate

322-57021328-57023

1g5g

［480438-74-2］

t-Butyl 3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl Carbonate

329-57031325-57033

1g5g

［480438-75-3］

t-Butyl 4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl Carbonate

326-57041322-57043

1g5g

［144432-80-4］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）biphenyl

326-87451322-87453

1g5g

［195062-57-8］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）toluene

325-60201321-60203

1g5g

［214360-48-2］

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）benzonitrile

320-82231326-82233

1g5g

13

［480424-94-0］

N-［4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］formamide

329-60101325-60103

1g5g

［380430-61-5］

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）acetanilide

326-59861322-59863

1g5g

［480424-93-9］

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）acetanilide

323-59871 329-59873

1g5g

［214360-60-8］

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）acetanilide

323-57431329-57433

1g5g

［480424-98-4］

N-［4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］succinamic Acid

327-60141323-60143

1g5g

2,2-Dimethyl-N-［2-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］-propionamide

325-57131321-57133

1g5g

t-Butyl N-［2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl）phenyl］carbamate

［159624-15-4］

321-56991327-56993

1g5g

［330793-09-4］

t-Butyl N-［3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl）phenyl］carbamate

328-57001324-57003

1g5g

［330793-01-6］

t-Butyl N-［4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl）phenyl］carbamate

325-57011321-57013

1g5g

N-BOC-N-methyl-4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）-aniline

322-52381328-52383

1g5g

［380430-60-4］

N-［2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］-methanesulfonamide

326-60111322-60113

1g5g

［305448-92-4］

N-［3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］-methanesulfonamide

323-60121329-60123

1g5g

N-［4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］-methanesulfonamide

320-60131326-60133

1g5g

2-（2-Methylthiophenyl）-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

326-82211322-82213

1g5g

［603143-27-7］

2-（4-Methylsulfonylphenyl）-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

329-82181325-82183

1g5g

［269410-24-4］

5-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）-1H-indole

323-59991329-59993

1g5g

1-Methyl-5-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）-1H-indole

326-76221322-76223

1g5g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）isoquinoline

327-63441 1g

［87100-28-5］

2-Benzyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

326-52161322-52163

1g5g

［83947-56-2］

trans-2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）styrene

322-60191328-60193

1g5g

［747413-21-4］

1-Methyl-4-［4-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］piperazine

323-76231329-76233

1g5g

4-［4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］morpholine

320-77221 1g

［480425-36-3］

N-［2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］formamide

329-60081325-60083

1g5g

［480425-37-4］

N-［3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］formamide

326-60091322-60093

1g5g

14

Boronic Acids Esters

1-cis-1,2-Bis（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）pentene

［307531-75-5］

322-52261328-52263

1g5g

［312693-52-0］

1-cis-1,2-Bis（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）hexene

325-52251321-52253

1g5g

［151416-94-3］

cis-1,2-Bis（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）stilbene

329-52271325-52273

1g5g

［160068-88-2］

p-（1,3,2-Dioxaborinan-2-yl）benzaldehyde

320-68291326-68293

1g5g

3-（5,5-Dimethyl-1,3,2-dioxaborinan-2-yl）pyridine

322-63371328-63373

1g5g

［5123-13-7］

5,5-Dimethyl-2-phenyl-1,3,2-dioxaborinane

321-57091327-57093

1g5g

［225916-39-2］

2-（4-Fluorophenyl）-5,5-dimethyl-1,3,2-dioxaborinane

324-57081320-57083

1g5g

［137297-49-5］

Diisopropyl （Bromomethyl）boronate

323-68301329-68303

1g5g

Triisopropyl Borate

［5419-55-6］

320-41532324-41535

25g500g

［3262-89-3］

Triphenylboroxin

322-26491320-26492

5g25g

［7519-91-7］

Tris（p-chlorophenyl）boroxin

326-26531324-26532

5g25g

［307531-74-4］

1-cis-1,2-Bis（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）heptene

328-52241324-52243

1g5g

cis-1,2-Bis（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）styrene

326-52281322-52283

1g5g

15

DIBORON ESTERS

［ 73183-34-3 ］

Bis（pinacolato）diboron

327-56971323-56973

1g5g

Bis（N,N,N',N'-tetramethyl-D-tartaramideglycolato）diboron

323-52291329-52293

1g5g

［ 230299-42-0 ］

Bis（N,N,N',N'-tetramethyl-L-tartaramideglycolato）diboron

326-52301322-52303

1g5g

Bis（diisopropyl-D-tartrateglycolato）diboron

327-52191323-52193

1g5g

［ 230299-10-2 ］

Bis（diisopropyl-L-tartrateglycolato）diboron

320-52201326-52203

1g5g

［ 230299-17-9 ］

Bis［（-）-pinanediolato］diboron

324-52221320-52223

1g5g

Bis［（+）-pinanediolato］diboron

［ 230299-05-5 ］

321-52231327-52233

1g5g

［ 201733-56-4 ］

Bis（neopentylglycolato）diboron

324-63331320-63333

1g5g

［ 230299-21-5 ］

Bis（hexyleneglycolato）diboron

327-52211323-52213

1g5g

PHASE TRANSFER CATALYST205-04331203-04332207-04335

[ 1643-19-2 ]5g25g500g

Tetrabutylammonium Bromide

Wako Cat. No. Package SizeDescription

16

Chemical Subject Index （Boronic Acids）2,5-Dimethoxyphenylboronic Acid2,6-Dimethoxyphenylboronic Acid3,4-Dimethoxyphenylboronic Acid2,6-Dimethoxy-3-pyridineboronic Acido-[(Dimethylamino)sulfonyl]phenylboronic Acid3,4-Dimethylbenzeneboronic Acid3,5-Dimethyl-4-methoxyphenylboronic Acid2,3-Dimethylphenylboronic Acid2,4-Dimethylphenylboronic Acid2,5-Dimethylphenylboronic Acid2,6-Dimethylphenylboronic Acid3,5-Dimethylphenylboronic Acido-Ethoxycarbonylphenylboronic Acidm-Ethoxycarbonylphenylboronic Acidp-Ethoxycarbonylphenylboronic Acid4-Ethoxy-3-fluorophenylboronic Acidm-Ethoxyphenylboronic Acidp-Ethoxyphenylboronic Acid4'-Ethyl-4-biphenylboronic AcidEthylboronic Acido-Ethylphenylboronic Acidp-Ethylphenylboronic Acid2-Fluoro-4-biphenylylboronic Acid2-Fluoro-5-formylphenylboronic Acid5-Fluoro-2-hydroxyphenylboronic Acid3-Fluoro-4-methoxyphenylboronic Acid5-Fluoro-2-methoxyphenylboronic Acid2-Fluoro-4-methylphenylboronic Acid(4-Fluoro-2-methylphenyl)boronic Acid4-Fluoro-3-methylphenylboronic Acid5-Fluoro-2-methylphenylboronic Acido-Fluorophenylboronic Acidm-Fluorophenylboronic Acidp-Fluorophenylboronic Acid2-Fluoro-3-pyridineboronic Acid4-Fluoro-3-(trifluoromethyl)phenylboronic Acid5-Formyl-2-furanboronic Acid3-Formyl-4-methoxyphenylboronic Acidm-Formylphenylboronic Acidp-Formylphenylboronic Acid2-Formyl-3-thiopheneboronic Acid3-Formyl-2-thiopheneboronic Acid2-Furanboronic Acidn-Hexylboronic Acido-(Hydroxymethyl)phenylboronic Acido-Hydroxyphenylboronic Acidm-Hydroxyphenylboronic Acid(p-Hydroxyphenyl)boronic Acidm-(Isopropoxycarbonyl)phenylboronic Acidp-(Isopropoxycarbonyl)phenylboronic Acidp-Isopropoxyphenylboronic Acido-Isopropylphenylboronic Acidm-Isopropylphenylboronic Acidp-Isopropylphenylboronic Acid4-Isoquinolineboronic Acid2-N-(Methanesulfonamide)-phenylboronic Acid3-N-(Methanesulfonamide)-phenylboronic Acid4-N-(Methanesulfonamide)-phenylboronic Acid3-Methoxycarbonyl-5-nitrophenylboronic Acid4-Methoxycarbonyl-2-nitrophenylboronic Acido-(Methoxycarbonyl)phenylboronic Acidm-(Methoxycarbonyl)phenylboronic Acidp-(Methoxycarbonyl)phenylboronic Acid4-Methoxy-2-methylphenylboronic Acido-Methoxyphenylboronic Acidm-Methoxyphenylboronic Acidp-Methoxyphenylboronic Acid2-Methoxy-5-pyridineboronic Acid4'-Methyl-4-biphenylboronic AcidMethylboronic Acid3,4-(Methylenedioxy)phenylboronic Acid1-Methyl-5-indoleboronic Acido-Methylphenylboronic Acidm-Methylphenylboronic Acid

Page 5-65-66-13-18-56-46-16-36-36-46-46-48-18-28-24-65-45-49-32-16-56-59-34-54-54-54-54-34-34-44-44-14-14-12-64-42-36-17-47-42-42-42-32-26-65-15-15-18-28-25-46-67-17-19-18-48-58-55-25-38-18-18-15-65-35-35-32-69-32-18-68-66-26-3

o-Acetamidophenylboronic Acidm-Acetamidophenylboronic Acidp-Acetamidophenylboronic Acidm-Acetylphenylboronic Acidp-Acetylphenylboronic Acid5-Acetyl-2-thiopheneboronic Acidp-(Aminocarbonyl)phenylboronic Acidm-Aminophenylboronic Acidm-Aminophenylboronic Acid Hydrochloride(1,4-Benzodioxan-6-yl)boronic Acid2-Benzofuranboronic AcidBenzo[b]thiophene-2-boronic Acid(p-Benzoylphenyl)boronic Acidp-Benzyloxycarbonylphenylboronic Acid4-Benzyloxy-3-fluorophenylboronic Acido-Benzyloxyphenylboronic Acidm-Benzyloxyphenylboronic Acidp-Benzyloxyphenylboronic Acid3-Biphenylboronic Acid4-Biphenylboronic Acid2,4-Bis(trifluoromethyl)phenylboronic Acid3,5-Bis(trifluoromethyl)phenylboronic Acid3-(BOC-amino)phenylboronic Acid4-(BOC-amino)phenylboronic Acid1-BOC-pyrrole-2-boronic AcidN-(4-Boronophenyl)succinamic Acidm-(Bromomethyl)phenylboronic Acidp-(Bromomethyl)phenylboronic Acido-Bromophenylboronic Acidm-Bromophenylboronic Acidp-Bromophenylboronic Acid5-Bromo-2-thiopheneboronic Acidp-Butoxyphenylboronic Acid4-n-Butylbenzeneboronic Acidn-Butylboronic Acidp-t-Butylphenylboronic Acid4-Carboxy-3-fluorophenylboronic Acid3-Carboxy-5-nitrophenylboronic Acid4-Carboxy-2-nitrophenylboronic Acidm-Carboxyphenylboronic Acidp-Carboxyphenylboronic Acid3-Chloro-4-ethoxyphenylboronic Acid2-Chloro-4-fluorophenylboronic Acid3-Chloro-4-fluorophenylboronic Acid4-Chloro-3-fluorophenylboronic Acid3-Chloro-4-methoxyphenylboronic Acid5-Chloro-2-methoxyphenylboronic Acid3-Chloro-4-methylphenylboronic Acido-Chlorophenylboronic Acidm-Chlorophenylboronic Acidp-Chlorophenylboronic Acid2-Chloro-4-pyridineboronic Acid5-Chloro-2-thiopheneboronic Acid2-Chloro-4-trifluoromethylphenylboronic Acid2-Chloro-5-(trifluoromethyl)phenylboronic Acid4-Chloro-3-(trifluoromethyl)phenylboronic Acid3-Cyano-4-fluorophenylboronic Acidm-Cyanophenylboronic Acidp-Cyanophenylboronic Acid2,3-Dichlorophenylboronic Acid2,4-Dichlorophenylboronic Acid2,5-Dichlorophenylboronic Acid2,6-Dichlorophenylboronic Acid3,4-Dichlorophenylboronic Acid3,5-Dichlorophenylboronic Acid2,3-Difluorophenylboronic Acid2,4-Difluorophenylboronic Acid2,5-Difluorophenylboronic Acid2,6-Difluorophenylboronic Acid3,4-Difluorophenylboronic Acid3,5-Difluorophenylboronic AcidDihydroxyphenylborane2,4-Dimethoxyphenylboronic Acid

Page 8-38-38-37-47-52-57-45-15-28-68-69-17-59-59-49-49-49-49-29-27-37-38-48-42-58-36-56-63-13-23-22-45-57-12-27-27-67-67-67-57-63-53-53-63-63-53-53-33-23-23-32-62-43-63-64-14-47-37-33-33-33-43-43-43-44-24-24-24-24-34-33-15-6

17

Chemical Subject Index (Boronic Acids)

3-Quinolineboronic Acid8-Quinolineboronic AcidTetrahydroxydiboron2-Thiopheneboronic Acid3-Thiopheneboronic Acid2,5-Thiophenediboronic Acido-(Trifluoromethoxy)phenylboronic Acidm-(Trifluoromethoxy)phenylboronic Acidp-(Trifluoromethoxy)phenylboronic Acido-Trifluoromethylphenylboronic Acidm-(Trifluoromethyl)phenylboronic Acidp-(Trifluoromethyl)phenylboronic Acid2,3,4-Trifluorophenylboronic Acid2,4,5-Trifluorophenylboronic Acid3,4,5-Trifluorophenylboronic Acid3,4,5-Trimethoxyphenylboronic Acidp-(Trimethylsilyl)phenylboronic Acidp-Vinylphenylboronic Acid

Page 9-19-12-12-32-32-55-55-55-57-27-27-24-64-64-66-18-56-5

p-Methylphenylboronic Acid(2-Methylpropyl)boronic Acido-(Methylthio)phenylboronic Acidm-(Methylthio)phenylboronic Acidp-(Methylthio)phenylboronic Acid1-Naphthaleneboronic Acidm-Nitrophenylboronic Acidp-Nitrophenylboronic Acid(E)-1-Pentenylboronic Acid1-Pentylboronic Acidp-Pentylphenylboronic Acid4-Phenoxathiinboronic Acidp-Phenylenediboronic Acid2-(Pivaloylamino)phenylboronic Acidp-Propoxyphenylboronic Acidp-Propylphenylboronic Acid3-Pyridineboronic Acid4-Pyridineboronic Acid

Page 6-32-16-26-26-29-25-25-22-22-27-19-53-18-45-46-62-52-6

Chemical Subject Index (Esters)

2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrimidine2-(3-Benzyloxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane2-(4-Benzyloxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane2-Benzyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane1-Benzyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazoleBis(diisopropyl-D-tartrate glycolato)diboronBis(diisopropyl-L-tartrate glycolato)diboronBis(hexylene glycolato)diboronBis(neopentyl glycolato)diboronBis(pinacolato)diboronBis[(-)-pinanediolato]diboronBis[(+)-pinanediolato]diboron1-cis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)heptene1-cis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hexene1-cis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pentenecis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)stilbenecis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)styreneBis(N,N,N',N'-tetramethyl-D-tartaramide glycolato)diboronBis(N,N,N',N'-tetramethyl-L-tartaramide glycolato)diboronN-BOC-N-methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-aniline1-BOC-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane2-Butyl-N,N,N',N'-tetramethyl-1,3,2-dioxaborolane-(4R,5R)-dicarboxamide2-Butyl-N,N,N',N'-tetramethyl-1,3,2-dioxaborolane-(4S,5S)-dicarboxamidet-Butyl N-[2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)phenyl]carbamatet-Butyl N-[3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)phenyl]carbamatet-Butyl N-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)phenyl]carbamatet-Butyl 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Carbonatet-Butyl 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Carbonatet-Butyl 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Carbonate2-Chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine2-Cyclopropyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane2-(3,4-Dichlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneDiisopropyl (Bromomethyl)boronate2,6-Dimethoxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrimidine3-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)pyridine5,5-Dimethyl-2-phenyl-1,3,2-dioxaborinane2,6-Dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenolN,N-Dimethyl[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]amine2,2-Dimethyl-N-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-propionamide3,5-Dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazolep-(1,3,2-Dioxaborinan-2-yl)benzaldehyde

Page 10-611-111-612-113-610-315-115-215-315-215-115-215-214-114-114-114-214-115-115-113-410-310-110-210-213-313-313-412-612-612-610-510-211-214-311-214-214-211-611-413-310-414-2

18

Chemical Subject Index (Esters)Ethyl 2-(4,4,5,5-TetramEthyl -1,3,2-dioxaborolan-2-yl)benzoateEthyl 3-(4,4,5,5-TetramEthyl -1,3,2-dioxaborolan-2-yl)benzoateEthyl 4-(4,4,5,5-TetramEthyl -1,3,2-dioxaborolan-2-yl)benzoate2-(4-Fluorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane2-(Hydroxymethyl)phenylboronic Acid Cyclic Monoester2-Hydroxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane2-(2-Methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Acetate2-Methoxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine2-(4-Methylsulfonylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneMethyl 2-(4,4,5,5-Tetramethyl -1,3,2-dioxaborolan-2-yl)benzoateMethyl 3-(4,4,5,5-Tetramethyl -1,3,2-dioxaborolan-2-yl)benzoateMethyl 4-(4,4,5,5-Tetramethyl -1,3,2-dioxaborolan-2-yl)benzoate1-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole1-Methyl-4-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]piperazine1-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole1-Methyl-4-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl]piperazine2-(2-Methylthiophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane4,4,5,5-Tetramethyl-1,3,2-dioxaborolane2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)acetanilide3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)acetanilide4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)acetanilide2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic Acid4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic Acid2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)chlorobenzene2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5-difluorobenzene4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)fluorobenzene3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)furan5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)isoquinoline2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Acetate3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Acetate4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl AcetateN-[2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]formamideN-[3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]formamideN-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]formamideN-[2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-methanesulfonamideN-[3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-methanesulfonamideN-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-methanesulfonamide4-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]morpholineN-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]succinamicAcid4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine4-[5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl]morpholine1-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl]piperazine1-[5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl]piperazinetrans-2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)styrene2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)toluene4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)toluenetrans-4,4,5,5-Tetramethyl-2-(1-octenyl)-1,3,2-dioxaborolaneTriisopropyl BorateTriphenylboroxinTris(p-chlorophenyl)boroxin

Page 12-412-412-414-310-110-610-112-411-411-612-510-613-512-312-312-313-613-110-311-113-510-113-213-213-211-311-311-412-211-212-212-312-112-212-212-611-211-311-310-413-513-611-411-511-511-511-511-612-512-512-513-113-113-213-413-413-513-113-310-310-510-511-111-110-613-610-410-412-112-110-214-314-314-4

PALLADIUM CATALYSTSDescriptionWako Cat. No. Package Size

024-12151

026-10891

027-12141

329-42021

321-27821

327-27823

329-37751

323-40961

040-24061

040-22481

046-22483

048-24241

324-56621

320-56623

321-56631

327-56633

328-56641

324-56643

163-07141

169-07143

161-07142

163-13871

160-13881

167-13891

169-00041

322-37741

160-13901

163-07543

165-07542

167-07541

166-00051

162-00053

164-00052

168-20553

161-20543

160-20471

162-15281

168-15283

168-21991

164-21993

160-22811

325-37731

320-40971

201-14701

203-14641

205-14721

Bis（acetonitrile）dichloropalladium （Ⅱ）

Bis（acetylacetonato）palladium（Ⅱ）

Bis（benzonitrile）dichloropalladium （Ⅱ）

Bis（dibenzylideneacetone）palladium（0）

［1,1'-Bis（diphenylphosphino）ferrocene］dichloropalladium（Ⅱ）,

Dichloromethane Adduct　［PdCl2（dppf）］

Bis（ethylenediamine）palladium（Ⅱ） Chloride

Diamminedichloropalladium（Ⅱ）

Dichloro（η-cycloocta-1,5-diene）palladium （Ⅱ）

trans-Dichlorobis（triphenylphosphine）palladium（Ⅱ）

Di-μ-chlorobis［（η-allyl）palladium （Ⅱ）］

FibreCat®1001※

［Palladium（Ⅱ） Acetate-Triphenylphosphine PE fibres］

FibreCat®1007※

［Palladium（Ⅱ） Acetate-Dicyclohexylphenylphosphine PE fibres］

FibreCat®1026※

［Acetonitrile Dichloropalladium（Ⅱ）-Triphenylphosphine PE fibres］

Palladium（Ⅱ） Acetate

Palladium-Alumina （Pd:5%）

Palladium-Barium Carbonate （Pd:5%）

Pallladium-Barium Sulfate （Pd:5%）

Palladium Black

Palladium（Ⅱ） Bromide

Palladium-Calcium Carbonate, Lindlar Catalyst （Pd:5%）

Palladium-Carbon

Palladium（Ⅱ） Chloride

Palladium （Ⅱ）-Hydrotalcite（m） （Pd:0.8%）

Palladium （Ⅱ）-Hydrotalcite （Pd:1.5%）

Palladium-Nanocage

Palladium（Ⅱ） Oxide

PI Palladium （Pd abt. 3%）

PMI Palladium

Tetraamminepalladium（Ⅱ） Chloride

Tetraamminepalladium（Ⅱ） Nitrate Solution（abt.13%）

Tetrakis（acetonitrile）palladium（Ⅱ） Bis（tetrafluoroborate）

Tetrakis（triphenylphosphine）palladium（0）

Tris（dibenzylideneacetone）dipalladium（0）

［14592-56-4］

［14024-61-4］

［14220-64-5］

［32005-36-0］

［72287-26-4］

［13963-53-6］

［14323-43-4］

［12107-56-1］

［13965-03-2］

［12012-95-2］

Pd content：2.7 ～ 4%

Pdcontent：3 ～ 4%

Pdcontent：3.5 ～ 4.5%

［3375-31-3］

［7440-05-3］

［7440-05-3］

［13444-94-5］

［7647-10-1］

［1314-08-5］

［13815-17-3］

［13601-08-6］

［21797-13-7］

［14221-01-3］

［52409-22-0］

1g

1g

1g

1g

1g

5g

500mg

500mg

1g

1g

5g

1g

1g

5g

1g

5g

1g

5g

1g

5g

25g

10g

10g

10g

1g

1g

10g

5g

25g

100g

1g

5g

25g

10g

5g

1g

1g

5g

1g

5g

1g

100mg

5g

1g

5g

1g

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FUJIFILM Wako Chemicals U.S.A. Corporation

Head Offlce

FUJIFILM Wako Pure Chemical Corporation

FUJIFILM Wako Chemicals Europe GmbHEuropean Offlce:

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