Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A)...

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Biochemistry Seventh Edition CHAPTER 9 Catalytic Strategies Copyright © 2012 by W. H. Freeman and Company Berg • Tymoczko • Stryer

Transcript of Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A)...

Page 1: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh

Biochemistry Seventh Edition

CHAPTER 9 Catalytic Strategies

Copyright © 2012 by W. H. Freeman and Company

Berg • Tymoczko • Stryer

Page 2: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 3: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 4: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 5: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 6: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 7: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 8: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 9: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 10: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 11: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 12: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 13: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 14: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 15: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 16: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 17: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 18: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 19: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 20: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 21: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 22: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 23: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 24: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 25: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 26: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 27: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 28: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 29: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 30: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 31: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 32: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 33: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 34: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 35: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 36: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 37: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 38: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 39: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 40: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 41: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 42: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 43: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 44: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 45: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 46: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 47: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 48: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 49: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 50: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 51: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 52: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 53: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 54: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 55: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 56: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 57: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 58: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 59: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 60: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 61: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 62: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 63: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 64: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 65: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 66: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 67: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 68: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 69: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 70: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 71: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 72: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 73: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 74: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 75: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 76: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 77: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 78: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 79: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 80: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 81: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 82: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 83: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 84: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh
Page 85: Biochemistry - Oregon State Universityoregonstate.edu/instruct/bb450/spring13/stryer7/9/ch09.pdf(A) —c —c OH + H = ROH (ester), RNH2 (amide) Enzyme Figure 9.5 Biochemistry, Seventh

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