Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a...

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Automated Soluble Salt Meter ISO 8502-6 & 8502-9 Equivalent Annual International Marine Coatings Summit October 31, 2008 1 Presented by: Mr. Herbert Jansen electronic developments

Transcript of Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a...

Page 1: Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a patented design that provides a hand held, ... Laboratory Test Methodevents.nace.org/conferences/IMCS2008/papers/20.pdf ·

Automated Soluble Salt Meter

ISO 8502-6 & 8502-9 Equivalent

Annual International Marine Coatings Summit

October 31, 2008

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Presented by: Mr. Herbert Jansen

electronic developments

Page 2: Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a patented design that provides a hand held, ... Laboratory Test Methodevents.nace.org/conferences/IMCS2008/papers/20.pdf ·

Brief Summary Introduction

About the SSM Equipment

Design

Key Features

Measurement Procedure

Comparison of the Bresle method and the SSM

Independent Testing

Approvals2

Page 3: Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a patented design that provides a hand held, ... Laboratory Test Methodevents.nace.org/conferences/IMCS2008/papers/20.pdf ·

Introduction The SSM is a patented design that provides a hand

held, automated method for detection of soluble salts.

The Model RPCT-07-001 was performance tested and approved as an alternative method of taking conductivity measurements by the United States Navy. Listed in Standard Item 009-32 FY-10

The US Department of Transportation is in the process of approving the SSM for use.

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Measurement Equipment

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SSM Design1. MENU button

2. ENTER button

3. LCD screen

4. Green/Red LED status indicator

5. Piston

6. Magnets

7. Silicone seal

8. Plunger

9. Power/USB port with protective plug

10. Tube connector

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Key Features Only fully automated tool available worldwide Exactly replicates the Bresle method No consumables, sticky residue, syringes

Proven to reduce cycle time for new ship construction (lean manufacturing)

Measures conductivity and fluid temperature Displays both conductivity and concentration Data extraction into any Coatings Technical

File (CTF)

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Measurement Procedure

6 Simple Steps

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Process Steps1. Attach meter to surface2. Inject deionized water into measurement chamber

with one press of the dose bottle3. Meter automatically agitates solution (~ 45 seconds)4. Meter automatically takes reading

Displays reading on LCD screen Stores values electronically

5. Wipe remaining water from surface after removing SSM

6. Flush meter by turning over and injecting water from dose bottle.

6 Total Process Steps ≈ 1 minute

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Page 9: Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a patented design that provides a hand held, ... Laboratory Test Methodevents.nace.org/conferences/IMCS2008/papers/20.pdf ·

Attach Meter to Surface

Magnets allow

the meter to

adhere to any

ferrous surface

Removal is

easy with no

sticky

adhesive

residue as

with the

Bresle patch 9

Page 10: Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a patented design that provides a hand held, ... Laboratory Test Methodevents.nace.org/conferences/IMCS2008/papers/20.pdf ·

Inject 3 mL Deionized WaterThe included

dispenser

automatically

doses exactly

3ml of deionized

water every time.

No syringes

required

Reduces the risk

for human error

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Meter Agitates Solution and Extracts Salts

Reading

takes less

than a minute

4 conductivity

sensors and 1

temperature

sensor

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Reading Displayed and Stored

Stores 10

batches of 100

readings

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Data Transfer via USB with SSMlink software

Page 14: Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a patented design that provides a hand held, ... Laboratory Test Methodevents.nace.org/conferences/IMCS2008/papers/20.pdf ·

Clear display and storage of batches

Page 15: Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a patented design that provides a hand held, ... Laboratory Test Methodevents.nace.org/conferences/IMCS2008/papers/20.pdf ·

Data export in .xls format for direct use in any Coating Technical File

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Comparison of methods

Bresle Method

1250 mm2 (footprint variable due to stretching)

SSM

1250 mm2

(circular fixed footprint)

Bresle Method

Manual syringe injection (prone to errors)

SAMPLING AREA

SSM

Automated, with simple press of 3 mL fixed volume dispenser

WATER INJECTION METHOD

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Comparison of Methods

Bresle Method

Patch with adhesive • Prone to leaving adhesive residue on surface

SSM

Magnetic with silicone seal• No effect on surface quality• Proven to seal over deep pits

Bresle Method

Manual • Measurements must be recorded by hand

ATTACHMENT METHOD

SSM

Automatic • Up to 1000 measurements

stored electronically.• Computer upload for QA reporting

In Coating Technical File

RECORD KEEPING

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Comparison of MethodsBresle Method SSM

Dosing Accuracy Variable with user ± 0.05 mL

Air Evacuation Manual syringe removalAutomated (measurement chamber relaxes automatically – no time delays)

Solution Agitation Method

Manual – rub patch with finger Automated – plunger agitation

Measurement Process Steps

17 6

Total Process Time (Reading to Reading)

10 minutes 1 minute

CalculationConductivity measurement converted to equivalent NaCl concentration manually using equation.

Conductivity measurement converted to equivalent NaCl concentration automatically by meter.

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Page 19: Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a patented design that provides a hand held, ... Laboratory Test Methodevents.nace.org/conferences/IMCS2008/papers/20.pdf ·

SSM Technical SpecificationsTemperature Sensors 1 probe (stainless steel)

Working Temperature Range 5 – 50 °C (41 – 122 °F)

Temperature Accuracy ± 0.3 °C

Conductivity Sensors 4 probes (stainless steel)

Measurement Range 0-300 µS/cm (0-360 mg/m2)

Measurement Accuracy ± 1% full scale

Indicators Red/Green LED

MemoryHolds up to 1000 measurements (10 batches of up to 100 measurements each)

Power Supply Lithium-ion rechargeable battery

CalibrationNot required; meter is calibrated by manufacturer. Daily validation method provided.

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Independent Testing

Verification of Accuracy and Efficacy

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Field Testing

Patch leaves adhesive and

foam residue on surface

following removal

SSM can attach to any

orientation (vertical,

overhead, etc.)

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Page 22: Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a patented design that provides a hand held, ... Laboratory Test Methodevents.nace.org/conferences/IMCS2008/papers/20.pdf ·

Summary of Testing Tested by the US Navy in field studies Reduced labor by over 50%

Ease of use-immediate results recorded electronically

Tested by two independent laboratories against the Bresle method and benchmark laboratory grade conductivity meter Concurrent Technologies Corporation (CTC)- February

2008

Corrosion Control Consultants & Labs, Inc. (CCC&L)-April/May 2008

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Laboratory Test Method 50 test areas were evaluated for 3 different doping

concentrations. 10 doped tests were run on each panel.

A total of 5 panels were used for each concentration.

The center of each identified patch area was doped with 50 µL of solution.

The doped panels were allowed to dry in the laboratory at ambient conditions overnight (~15 hours).

After drying the panels were tested according to the Bresle Test Method.

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SSM

Mean Solution 1: 41.76 µS/cm

Solution 2: 57.02 µS/cm

Solution 3: 89.26 µS/cm

Standard Deviation Solution 1: 2.39 µS/cm

Solution 2: 1.71 µS/cm

Solution 3: 2.46 µS/cm

Mean Solution 1: 41.44 µS/cm

Solution 2: 56.64 µS/cm

Solution 3: 88.5 µS/cm

Standard Deviation Solution 1: 3.48 µS/cm

Solution 2: 4.26 µS/cm

Solution 3: 3.33 µS/cm

Comparison

Bresle

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10/31/2008 25SSM Bresle

40

50

60

70

80

90

Doping Solution 1

Co

nd

ucti

vit

y (

S

/cm

)

SSM Bresle

40

50

60

70

80

90

Doping Solution 2

Co

nd

ucti

vit

y (

S

/cm

)

SSM Bresle

40

50

60

70

80

90

Doping Solution 3

Co

nd

ucti

vit

y (

S

/cm

)

Box Plots of SSM and Bresle Data

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10/31/2008 26

Doping Solution 1

Conductivity ( S/cm)

Den

sit

y

35 40 45 50 55

0.0

00.1

00.2

00.3

0 SSM

Doping Solution 2

Conductivity ( S/cm)

Den

sit

y

45 55 65 75

0.0

00.1

00.2

00.3

0 SSM

Doping Solution 3

Conductivity ( S/cm)

Den

sit

y

75 85 95 105

0.0

00.1

00.2

00.3

0 SSM

Doping Solution 1

Conductivity ( S/cm)

Den

sit

y

35 40 45 50 55

0.0

00.1

00.2

00.3

0 Bresle

Doping Solution 2

Conductivity ( S/cm)

Den

sit

y

45 55 65 75

0.0

00.1

00.2

00.3

0 Bresle

Doping Solution 3

Conductivity ( S/cm)

Den

sit

y

75 85 95 1050.0

00.1

00.2

00.3

0 Bresle

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Conclusion Independent testing demonstrates that both methods

return equivalent results . The mean measured values are almost identical.

The only discernable difference between the two methods is that the SSM has much lower variability in measurements. The variance in SSM measured values is significantly

less than those measured with the Bresle patch.

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SummaryUnited States Patent No. 6,946,844 was issued on

20 September 2005. International patents have been filed. Approved and implemented by US Navy for

soluble salt determination in accordance with NAVSEA Standard Item 009-32 (FY-10)Equivalent to ISO Standard 8502-6 Extraction of

soluble contaminants for analysis -- The Bresle methodAutomatically calculates equivalent soluble salt

concentration in accordance with ISO Standard 8502-9 Field method for the conductometric determination of water-soluble salts

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Page 29: Automated Soluble Salt Meter - NACE InternationalAutomated Soluble Salt Meter ... The SSM is a patented design that provides a hand held, ... Laboratory Test Methodevents.nace.org/conferences/IMCS2008/papers/20.pdf ·

Questions?

International Sales:

Hedon Electronics Development B.V.

www.solublesaltmeter.com

Phone: +31 (0) 15 2755555

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US Sales:

ARP Instruments, Inc.

www.rpct.net

Phone: (540) 752-7651

electronic developments