ATOMIC SPECTROMETRY 1. Flames 2. Electrothermal Atomizers 3. Plasmas.

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ATOMIC SPECTROMETRY 1. Flames 2. Electrothermal Atomizers 3. Plasmas

Transcript of ATOMIC SPECTROMETRY 1. Flames 2. Electrothermal Atomizers 3. Plasmas.

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ATOMIC SPECTROMETRY

1. Flames

2. Electrothermal Atomizers

3. Plasmas

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Inductively Coupled Plasma

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ICP Torch

Coolant (plasma) flow

Optional auxiliary flow

Sample aerosol

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Induction Coil

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RF Load Coil

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Plasma “Donut”

RF Frequency: 5 MHz 27 MHz

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Sample Directed Through Donut

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Temperature Profile

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Plasma viewed through a glass darkly…

Load Coil

Radial Viewing Zone

Tail Plume

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Axial View

Load Coil

Shear Gas

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Dual View

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Continuum Source Background Correction(continuum source passes through furnace)

Background Only

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Sample Introduction

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Sample Introduction

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Sample Introduction

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Traditional Nebulizers

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Pneumatic Nebulizers

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Fritted Glass Nebulizer

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Hildebrand Grid Nebulizer

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Ultrasonic Nebulizer

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Water Removal from Sample Aerosol

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Ultrasonic Nebulizer

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Ultrasonic Nebulizer

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Spray Chambers

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Echelle Optics

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Echelle Optics

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Echelle Optics: 2-D CCD Camera on Focal Plane

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Elements Detected by ICP Emission Spectrometry

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ICP Emission Spectrometry

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ICP Emission Spectrometry Detection Limits

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ICP Emission Spectrometry Detection Limits

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ICP Emission Spectrometry Linearity

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