Low Moisture, Encapsulation Carpet Cleaning Brush Pro ENCAPSULATION CLEANING USING Cimex.
ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived...
Transcript of ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived...
![Page 1: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/1.jpg)
Appendix A.
Supplementary Information
Metal-Organic Frameworks Derived Reverse-
Encapsulation Co-NC@Mo2C Complex for
Efficient Overall Water Splitting
Qirui Lianga, Huihui Jina, Zhe Wangb, Yuli Xiong*c, Shuai Yuana, Xianci Zengb, Daping He*a,b
and Shichun Mu*a
a State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,
Wuhan University of Technology, Wuhan 430070, China.
b Hubei Engineering Research Center of RF-Microwave Technology and Application, Wuhan
University of Technology, Wuhan 430070, China.
c School of Electronic and Electrical Engineering, Wuhan Textile University, Wuhan 430200,
China.
*Address corresponding to: [email protected], [email protected], [email protected]
![Page 2: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/2.jpg)
Figure S1 SEM images of ZIF-67.
![Page 3: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/3.jpg)
Figure S2 TEM images of ZIF-67.
![Page 4: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/4.jpg)
Figure S3 SEM images of ZIF-67 after grinding with ammonium molybdate tetrahydrate.
![Page 5: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/5.jpg)
Figure S4 SEM images of Co-NC@Mo2C.
![Page 6: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/6.jpg)
Figure S5 (a) TEM and (b) HAADF-STEM images of Co-NC@Mo2C.
![Page 7: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/7.jpg)
Figure S6 HRTEM image of Co-NC@Mo2C
![Page 8: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/8.jpg)
Figure S7 EDX spectrum of Co-NC@Mo2C.
![Page 9: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/9.jpg)
Figure S8 SEM images of Co-NC.
![Page 10: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/10.jpg)
Figure S9 TEM images of ZIF-8.
![Page 11: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/11.jpg)
Figure S10 TEM images of NC@Mo2C.
![Page 12: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/12.jpg)
Figure S11 XRD patterns of Co-NC@Mo2C and some contrast samples.
![Page 13: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/13.jpg)
Figure S12 Raman spectrum of Co-NC@Mo2C.
![Page 14: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/14.jpg)
Figure S13 XPS spectra of Co-NC@Mo2C: (a) survey, (b) C 1s, (c) N 1s, (d) O 1s.
![Page 15: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/15.jpg)
Figure S14 HER polarization curves of Co-NC@Mo2C at different temperatures in 1.0 M
KOH aqueous solution.
![Page 16: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/16.jpg)
Figure S15 Time-dependent current density curves for Pt/C at constant potentials for 25 h
and corresponding polarization curves before and after 1000 CV cycles in (a) 1.0 M KOH
and (b) 0.5 M H2SO4 aqueous solution.
![Page 17: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/17.jpg)
Figure S16 XPS spectra of Co-NC@Mo2C after HER stability test.
![Page 18: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/18.jpg)
Figure S17 XRD patterns of Co-NC@Mo2C before and after HER stability test.
![Page 19: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/19.jpg)
Figure S18 SEM image of the Co-NC@Mo2C after HER stability test.
![Page 20: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/20.jpg)
Figure S19 (a, b, c) CVs with different rates from 20 to 120 mV s−1 in the region of -0.5 ~ -
0.6 V for Co-NC@Mo2C, Co-NC, NC@Mo2C in 1.0 M KOH aqueous solution respectively.
(d) The capacitive currents at -0.55 V with different scan rates.
![Page 21: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/21.jpg)
Figure S20 Time-dependent current density curves for (a) IrO2 and (b) IrO2-Pt/C at constant
potentials for 20 h and corresponding polarization curves before and after 1000 CV cycles.
![Page 22: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/22.jpg)
Figure S21 Comparison with selected state-of-the-art (a, b) HER and (c) OER electrocatalysts.
![Page 23: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/23.jpg)
Figure S22 Gas collection device of water splitting.
![Page 24: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/24.jpg)
Table S1 Inductively coupled plasma results for Co and Mo contents in Co-NC@Mo2C.
Element W(B)%Co 27.43Mo 62.95
![Page 25: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/25.jpg)
Table S2 The surface element content of Co-NC@Mo2C measured by XPS measurements.
Element Content (at.%)C 19.64N 28.57O 31.45Co 6.94Mo 13.41
![Page 26: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/26.jpg)
Table S3 Tafel slope (mV dec-1) of several catalysts in this experiment.
HER in 1.0 M KOH HER in 0.5 M H2SO4 OER in 1.0 M KOHCo-NC@Mo2C 65 60 61
Co-NC 172 267 121
NC@Mo2C 68 65 176
NC 277 319 228
Commercial Mo2C
122 180 96
Commercial Pt/C 69 34 /
Commercial Ir2O / / 88
![Page 27: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/27.jpg)
Table S4 Comparison of HER performance in acid/alkaline media for Co-NC@Mo2C with
other reported electrocatalysts.
Catalysts Electrolytes η@10mA cm-2(mV)
Catalyst loading (mg cm-2)
Ref.
Co-NC@Mo2C 0.5 M H2SO4
1.0 M KOH14399
0.83 This work
MoCN-3D 0.5 M H2SO4
1.0 M KOH89122
0.26 Asia. Mater. 2016, 8, e293-e293.
Co-C-N 0.5 M H2SO4
1.0 M KOH138178
- J. Am. Chem. Soc. 2015, 137, 15070-15073.
CoP/CC 0.5 M H2SO4
1.0 M KOH67209
0.92 J. Am. Chem. Soc.2014, 136, 7587-7590.
Co, N/3DG-2 0.5 M H2SO4 141 0.28 J. Power Sources 2017, 363, 260-268.
CoP/CNT 0.5 M H2SO4 122 0.285 Angew. Chem. Int. Ed. 2014, 53, 6710-6714.
Co-NCNT/CC 0.5 M H2SO4
1.0 M KOH78180
3.4 ChemSusChem2015, 8, 1850-1855.
CoNC/GD 0.5 M H2SO4
1.0 M KOH340284
- ACS. Appl. Mater. Inter.2016, 8, 31083-31091.
Zn0.30Co2.70S4 0.5 M H2SO4
1.0 M KOH8085
0.285 J. Am. Chem. Soc. 2016, 138, 1359-1365.
MoCx/C 0.5 M H2SO4
1.0 M KOH135150
0.45 Small Methods2018, 2, 1700353.
Mo2C/GCSs 0.5 M H2SO4 200 0.36 ACS. Catal.2014, 4, 2658-2661.
![Page 28: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/28.jpg)
Mo2CTx 0.5 M H2SO4 283 0.1 ACS. Energy. Lett.2016, 1, 589-594.
Mo2C@2D-NPCs
0.5 M H2SO4
1.0 M KOH8645
- ACS. Nano2017, 11, 3933-3942.
Mo2C@NC 0.5 M H2SO4
1.0 M KOH12460
0.28 Angew. Chem. Int. Ed. 2015, 54, 10752-10757.
uf-Mo2C/CF 0.5 M H2SO4
1.0 M KOH184185
0.25 Small Methods 2018, 2, 1700396.
Mo2C QD/NGCL
0.5 M H2SO4
1.0 M KOH136111
2.0 Chem. Commun.2016, 52, 12753-12756.
Co-P/NC 1.0 M KOH 154 0.283 Chem. Mater.2015, 27, 7636-7642.
Co-P 1.0 M KOH 94 - Angew. Chem. Int. Ed.2015, 54, 6251-6254.
![Page 29: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/29.jpg)
Table S5 The surface elemental content of Co-NC@Mo2C after HER stability test measured
by XPS measurements.
Element Content (at.%)C 18.16N 10.76O 55.72Co 5.29Mo 10.07
![Page 30: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/30.jpg)
Table S6 Comparison of OER performance in alkaline media for Co-NC@Mo2C with other
reported electrocatalysts.
Catalysts Electrolytes η@10mA cm-2(mV)
Catalyst loading(mg cm-2)
Ref.
Co-NC@Mo2C 1.0 M KOH 347 0.83 This work
Co-P/NC 1.0 M KOH 319 0.283 Chem. Mater. 2015, 27, 7636-7642.
Co-P 1.0 M KOH 345 - Angew. Chem. Int. Ed. 2015, 54, 6251-6254.
NiCoP/C 1.0 M KOH 330 0.25 Angew. Chem. Int. Ed. 2017, 56, 3897-3900.
Co NPs 0.1 M KOH 390 0.2 J. Am. Chem. Soc. 2015, 137, 7071-7074.
ZnCo2O4 1.0 M KOH 390 - J. Phys. Chem. Lett. 2014, 5, 2370-2374.
Co3O4 0.1 M KOH 300 - Angew. Chem. Int. Ed. 2016, 55, 5277-5281.
NCO–HNSs 1.0 M NaOH 340 - Adv. Energy. Mater. 2015, 5, 1500091.
Co3O4_EC_0.50 1.0 M NaOH 377 - ACS. Appl. Mater. Inter.
2015, 7, 24550-24555.
HFC Co3O4 2.0 M KOH 409 0.14 ACS. Appl. Mater. Inter. 2015, 7, 20322-
20331.
Ni-Co2-O HNSs 0.1 M KOH 362 0.2 Chem. Commun. 2015, 51, 7851-7854.
Co-S/Ti mesh 1.0 M KOH 361 - Electrochem.Commun. 2015, 60, 92-96.
![Page 31: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/31.jpg)
CFO/rGO 1.0 M KOH 340 - ChemSusChem 2015, 8, 659-664.
CeO2/Co3O4-2 0.3 M KOH 386 - J. Mater. Sci-Mater. El. 2016, 27, 5294-
5302.
Fe1Co1-ONS 0.1 M KOH 308 0.36 Adv. Mater. 2017, 29. 1703614.
NiCo2O4 0.1 M KOH 340 0.25 Dalton Trans. 2015, 44, 4148-4154.
Ni-Fe-Co 0.1 M KOH 310 0.25 ACS. Catal. 2015, 6, 155-161.
BCFSn-721 0.1 M KOH 450 - Adv. Sci. 2016, 3, 1500187.
![Page 32: ars.els-cdn.com · Web viewAppendix A. Supplementary Information Metal-Organic Frameworks Derived Reverse-Encapsulation Co-NC@Mo 2 C Complex for Efficient Overall Water Splitting](https://reader033.fdocuments.net/reader033/viewer/2022050323/5f7d791147ed13234033f242/html5/thumbnails/32.jpg)
Table S7 Comparison of catalytic performance (mV) at the current density of 10 mA cm–2 in
1.0 M KOH aqueous solution for Co-NC@Mo2C with other relevant bifunctional
electrocatalysts reported in recent years.
Catalysts HER(mV)
OER(mV)
Water Splitting(V)
Ref.
Co-NC@Mo2C
Cu@CoFe LDH
Fe-Co
PO-Ni/Ni-N-CNFs
Co/NBC
N-NiMoO4/NiS2
Ni–Co–P HNBs
99
171
163
262
117
99
107
347
240
283
420
302
283
270
1.685
1.681
1.68
1.69
1.68
1.60
1.62
This work
Nano Energy 2017, 41, 327–336
Nano Energy 2017, 38, 576–584
Nano Energy 2018, 51, 286–293
Adv. Funct. Mater. 2018, 28, 1801136.
Adv. Funct. Mater. 2018, 1805298.
Energy Environ. Sci.2018, 11, 872