Application of Oleochemicals in Soap, Detergents and

Cosmetic Industries

Fathy Hassan, PhD

COO, Oleo Misr

drfh71@oleomisr.com

www.oleomisr.com

Focus Points

What is Oleochemicals

Vegetable Oil in Oleochemicals

Oleochemicals = Happy Life

Application of Oleochemicals in Soap Industry

Application of Oleochemicals in Cosmetic Industry

Conclusion

Non-Food Uses of Oleo Chemicals

OLEO CHEMICALS USED IN MANY INDUSTRIES

OLEO CHEMICALS USED IN MANY INDUSTRIES

OLEO CHEMICALS USED IN MANY INDUSTRIES

Oleochemicals are chemicals derived from Oils &

Fats (plant or animal). They are analogous to

petrochemicals derived from petroleum

Important processes in oleochemical

manufacturing include hydrolysis, splitting,

hydrogenation, methylation and transesterification,

among others.

OLEO CHEMICALS USED IN MANY INDUSTRIES

The formation of basic oleochemical substances like fatty

acids, glycerol, fatty acid methyl esters (FAME), fatty

alcohols, fatty amines and glycerols are by various chemical

and enzymatic reactions. Intermediate chemical substances

produced from these basic oleochemical substances include

alcohol ethoxylates, alcohol sulfates, alcohol ether glucose,

quaternary ammonium salts, monoacylglycerols (MAG),

diacylglycerols (DAG), structured triacylglycerols (TAG),

sugar esters, and other oleochemical products

OLEO CHEMICALS USED IN MANY INDUSTRIES

Adhesives & Sealants Metal Working

Agricultural Chemicals Oilfield Chemicals

Chemical Derivatives Paints, Coatings & Inks

Coatings and Inks Paper Chemicals

Construction Chemicals Personal Care

Electrodes Pharmaceutical

Emulsion Polymerization Polymers & Plastics

Flavors & Fragrance Rubber & Tires

Food Processing Textile Chemicals

Household Care Tobacco

Industrial & Institutional Cleaners Wax & Candles

Lubricants and Greases

OLEO CHEMICALS USED IN MANY INDUSTRIES

The expected total oleo chemical consumption

of Egypt, Africa and Middle east is about 1.5 :

1.7 million tons 2017.

Non-Food Uses of Oleo Chemicals

SUBJECT CONTENTSOLEO CHEMICALS = HAPPY LIFE VEGETABLE OIL IN OLEO CHEMICALS OLEO CHEMICALS IN SOME INDUSTRIAL PROCESS

IN SOAPIN COSMETICSIN IN LEATHERIN TEXTIALIN SURFACTANT, EMULSIFIERS & OTHERSIN PHARMACEUTICALS, PAINTING & OTHERS

Non-Food Uses of Oleo Chemicals

OLEO CHEMICALS = HAPPY LIFE

WE CAN MAKE A DIFFERENCE TO THE FUTURE OF

OUR LIFE BY THE RIGHT CHOICE :

ALL OUR LIFE IS BOLUTED BY HYDROCARBON

IN FOOD / INKS / TEXTILE / COSMETICS

AGRICULTURE PESTICIDES / IN MANY

WHAT WE CAN DO?

Non-Food Uses of Oleo Chemicals

OLEO CHEMICALS = HAPPY LIFE

WRITE ANSWER BACK TO THE NATURE(RIGHT CHOICE FOR GREEN LIFE)

OLEO CHEMICALS ARE USED IN ALL

SPECIALTIES IN OUR EVERY DAY LIFE

THANKS OLEO CHEMICALS WITH

RESPICT TO THE TRIGLYCERIDES

Non-Food Uses of Oleo Chemicals

Vegetable oil & FAT are being processed to produce a wide

variety of Fatty Acid based derivatives and end products

including oleo chemicals.

Non-Food Uses of Oleo Chemicals

What oleo chemicals are derived from Fat & Oil?In addition to the Fat & Oil derivatives used for food

applications, there are also a number of Oil-based oleo

chemicals, including:

Fatty acids / Fatty alcohols / Fatty methyl ester

Fatty nitrogen compounds / Glycerine

These substances are used in cosmetics , painting ,

surfactants , emulsifiers , and among other products.

Non-Food Uses of Oleo Chemicals

Non-Food Uses of Oleo Chemicals

Non-Food Uses of Oleo Chemicals

The most important of non-food

application of fatty acids in OLEO MISR

COMPANY. / Egypt now is for the

production of BASIC OLEO

CHEMICALS i.e. All fatty acids and

special oleo chemicals i.e. palmetic,

stearic, oleic fatty acids and their

derivatives with respect to the tri

glycerides .

Non-Food Uses of Oleo Chemicals

OLEO CHEMICALS IN SOME INDUSTRIAL PROCESS

IN SOAP

Non-Food Uses of Oleo Chemicals

.

ITS SOO EASY TO MAKE A SOAP BUT ITS

VERY DIFFICULT TO MAKE A GOOD SOAP

OLEO CHEMICALS IN SOAP PROCESS

Non-Food Uses of Oleo Chemicals

OLEO CHEMICALS IN SOAP PROCESS

Non-Food Uses of Oleo Chemicals

SOAP ( salt of fatty acid ) is not use only as soap

bar for cleaning but its use in many field

We have the calcium, potassium, lithium salt of

fatty acid , soap amine , natural hand soap, and

Soap of carboxylic acids and amines which is

useful in removal and prevention of scale.

OLEO CHEMICALS IN SOAP PROCESS

Non-Food Uses of Oleo Chemicals

Fatty amine : in chemistry, is any amine attached to a C

12 or more . These are classified as oleochemicals. More

commonly are derived from C12-C18 , coco amine,

oleylamine, tallow amine, and soya amine. Some

applications of these compounds are in Soap Bar fabric

softeners, and corrosion inhibitors. They are the basis for

a variety of soap & cosmetic formulations.

OLEO CHEMICALS IN SOAP PROCESS

Non-Food Uses of Oleo Chemicals

OLEO MISR COMPANY. / Egypt has a facility to produce

snow white soap noodles via a continuous neutralization process.

Snow White soap cannot be prepared directly from continuous

Saponification process because of their high Saponification color

values. When palm fatty acids are distilled, however, some of the

impurities are removed and good quality soaps can therefore be made

from them. In addition to ease of production, the fatty acid route

allows soap formulators to determine the ratio of fatty acids to be

used, by blending, thus offering greater flexibility.

Non-Food Uses of Oleo Chemicals

OLEO MISR WILL PRODUCE DIFFERENT FORMULATION FOR

TOILET SOAP, NOODLES , COMBAR, TRANSLUCENT AND

TRANSPARANT SOAP NOODLES

ALSO WE HAVE A FACILITIES TO PRODUCE SWING SOAP

NOODLES DIRECT FROM OIL WITHOUT SEPARATING THE

GLYCEROL

Non-Food Uses of Oleo Chemicals

QUALITY DIFFERENCE BETWEEN SOAP

NOODLES FROM OILS AND FATTY ACIDS

SOAP NOODLES FROM FATTY ACID SOAP NOODLES FROM OILS

Color Top white fancy color Yellowish

Dust Little High

Salt 0.1 : as req. 0.4 min.

Alk. 0.0 : as req. Difficult to adjust.

Glycerol 0.1 : as req. 1.0 min.

Un-sap 0.15 max. 0.25 min.

Irritation - +

Non-Food Uses of Oleo Chemicals

QUALITY DIFFERENCE BETWEEN SOAP

NOODLES FROM OILS AND FATTY ACIDS

•Less qty. Of TiO2 and bighting agent

•Less qty. Of Caustic soda

•Less qty. Of sodium salt

•Less qty. Of fragrance

•Less qty. Of preservative

•High quality with different formulations

Non-Food Uses of Oleo Chemicals

OUR TARGET IN SOAP MANUFACTURE WILL BE NEW

FORMULATION WITH HIGH QUALITY TO EXCEED THE

CUSTOMER EXPECTATIONS :

OLEO MISR WILL PRODUCE DIFFERENT BLEND

OF SOAP NOODLES TO ACHIEVE THE STANDARD

No. OF INS, HR, & S.R.

USE NEW TECHNOLOGY TO

PRODUSE SNOW WHITE SOAP

NOODLES FROM METHYL ESTER

Non-Food Uses of Oleo Chemicals

OIL DREVATIVES AS OLEO SOAP

ON THE OTHER HAND GLYCEROL COMES

FROM SPLITING OF VEGETABLE OIL IS MORE

HIGH QUALITY THAN THIS ONE COMES

FROM SAPONIFICATION i.e. Odder, Colour and

free of chloride ion and triglycerides

Non-Food Uses of Oleo Chemicals

OLEO CHEMICALS IN SOME INDUSTRIAL PROCESS

IN COSMETICS & BODY CARE / HOME CARE & DRILLING DETERGENTS

IN COSMETICS

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

MOST OF THE R.M IN COSMETICS ARE OLEO

CHEMICALS, WHICH USED IN BODY CARE,

PERSONAL CARE , HOME CARE , HAIR CARE ,

BABY CARE, & ALL KINDS OF DETERGENTS

WHICH USED IN HOUSE, HOTELS, PAPER,

TANNING, TEXTILE , AGRICULTURE, PESTICIDES,

DRILLING, OTHERS

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

MOST OF OLEO CHEMICALS IN THE ABOVE

WORKS AS ACTIVE MATTER, SURFACTANTS,

EMULSIFIER, WETING AGENTS, PLASTICIZER,

LUBRICANTS, EMOLLIENTS, THICKENER,

MOISTURIZERS ---------------------

Non-Food Uses of Oleo Chemicals

.Hypoallergenic

Biodegradable

Septic System Safe

EcoLogo compliant

Vegan

Leaping Bunny approved

WELCOME OLEO CHEMICALS IN COSMETICS

Non-Food Uses of Oleo Chemicals

WELCOME OLEO CHEMICALS IN COSMETICS

Good bye to these ingredients in Cosmetics and detergents products:

Sodium Lauryl Sulphate free

Chlorine Free

Phosphates Free

Synthetic fragrances Free

Ethylenediaminetetraacetic acid (EDTA) Free

Alkylphenol ethoxylates (APEs) Free

Petrochemical R.M Free

Non-Food Uses of Oleo Chemicals

WELCOME OLEO CHEMICALS IN COSMETICS

Do you know the main ingredient in shampoo & hand Soap?

Sodium Lauryl Sulphate / ether sulphate 10 : 20 %

We need all cosmetics products sulphate free

Its better to use Lauryl glucoside / succinate or

Use fatty Acid & fatty acid derivatives in hand soap & shampoo

Non-Food Uses of Oleo Chemicals

STABLE SOAP BASED CLEANSING SYSTEM

( More particularly )

The liquid skin cleansing relates to phase stable liquid

skin cleansing compositions comprising a fatty acid soap,

and acrylate based copolymer and an acidifying agent.

OLEO CHEMICALS IN HAND SOAP .

Non-Food Uses of Oleo Chemicals

OLEO CHEMICALS IN HAND SOAP .A liquid soap composition is prepared by the back-acid formulation

technique utilizing the following recipe.

Non-Food Uses of Oleo Chemicals

OLEO CHEMICALS IN HAND SOAP .The pH is sequentially lowered by back-acid treating with citric acid. The

viscosity and yield values following the sequential reduction of the pH values

of the liquid soap composition are reported in the table below.

Non-Food Uses of Oleo Chemicals

OLEO CHEMICALS IN HAND SOAP .The back-acid technique with citric acid (25% solution) to a pH of 8.6

Different formula with low % of fatty acid blend

OLEOCHEMICAL IN COSMETICS

Oleo chemical in disinfectant :

We know that the custor Soap used in disinfectant with

PCMX / IRGAZAN / OTHERS AS anti-bacterial agent

and ( Isopropyl + D.I water ), caramel as color .

OUR COMPANY PRODUSED NEW FORMULA FROM

OLEO CHEMICAL 100 %

Non-Food Uses of Oleo Chemicals

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

Caprylyl / Myristyl Glucoside Caprylyl /Myristyl

Glucoside are cleaning agent, an Amine Oxide surfactant

that can also be found in a variety of products including

shampoos and dishwashing detergents. It removes dirt

and deposits by surrounding dirt particles to loosen them

from the surface they're attached to, so they can be rinsed

away. Function: Plant based cleaning agent (Surfactant),

Liquid Laundry .

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

Cocamidopropyl Hydroxysultaine used in (Hand soap,

soaps, shampoos, lotions etc.) It has uses as a foam booster,

viscosity builder, and an antistatic agent. : Made by blending raw

coconut oil with a naturally-derived chemical. This ingredient usually

provides the mild and gentle "sudsing" base for body washes, facial

cleansers, shampoos, bubble bath, and other liquid cleansing

formulations. It is also has properties that can be used to adjust the

thickness (viscosity) of formulations. Function: Viscosity adjuster

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

Lauramine Oxide : Function: Plant based cleaning agent

(Surfactant) . Produced by the reaction of glucose from

corn starch with the fatty alcohol from P. kernel oil or

coconut. It is a cleaning agent that can also be found in a

variety of products including shampoos and dishwashing

detergents

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

Glyceryl Oleate is the ester of glycerin and oleic

acid. It is produced from oils that contain high

concentrations of oleic acid, such as olive oil,

peanut oil, teaseed oil or pecan oil. It is used as

an emulsifier in Hand soap & others (mixes oil

and water). Function: Lipid enhancer

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

Glycerine is derived from Vegetable Oil, and is a by-

product of soap making process. Glycerine is a

moisturizer that can also be found in personal care

products such as skin lotion. It helps prevent a product

from drying out and breaking apart. It works by drawing

water in and forming a barrier on a surface to help retain

moisture. Function: Solvent / Foam stabilizer

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

Methyl Bis (soya amidoethyl) -2-Hydroxyethyl

Quaternary Ammonium Methyl Sulphate: A soy based

ingredient and an alkaline based compound that is used to

soften garments and also acts an anti-static agent to

reduce static cling. Used in Fabric Softener .Function:

Plant based softening agent

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

Sodium Methyl 2-Sulfolaurate/Disodium 2-

Sulfolaurate Is derived from Vegetable oil as a

renewable natural resources. It is Produced by

the reaction of between an acidic and alkaline

compounds. A cleaning agent that can also be

found in a variety of laundry products. Function:

Plant based cleaning agent (Surfactant)

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

Alkyl polyglycosides (APGs)

Illustrative of green cleaning agents are APGs, a class of non-

ionic surfactants widely used in a variety of household and industrial

applications. APG are derived from sugars, usually glucose

derivatives, and fatty alcohols. They are used to enhance the

formation of foams in detergents for dishwashing and for delicate

fabrics. In addition to their favourable foaming properties, they are

attractive because they readily biodegrade. The raw materials for

industrial manufacture are typically starch and fat.

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

Stearyl alcohol with the formula

CH3 (CH2)16CH2OH. It is classified as a fatty alcohol. which are insoluble

in water. It has a wide range of uses as an ingredient

in lubricants, resins, perfumes and cosmetics. It is used as

an emollient, emulsifier, and thickener in ointments of various sorts, and is

widely used as a hair coating in shampoos and hair conditioners. It has also

found application as an evaporation suppressing monolayer when applied

to the surface of water. Stearyl alcohol is prepared from stearic acid by the

process of catalytic hydrogenation. It has low toxicity.

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

Cetyl alcohol

also known as hexadecan-1-ol and palmityl alcohol, is a fatty alcohol with

the formula CH3(CH2)15OH. At room temperature, cetyl alcohol takes the form of

a waxy white solid or flakes.

Preparation

Cetyl alcohol Modern production is based on the reduction of palmitic acid, which

is obtained from vegetable oil.

Uses

Cetyl alcohol is used in the cosmetic industry as an opacifier in shampoos, or as

an emollient, emulsifier or thickening agent in the manufacture of skin creams and

lotions It is also employed as a lubricant for nuts and bolts, and is the active

ingredient in some "liquid pool covers" (forming a surface layer to reduce

evaporation and retain heat).

Non-Food Uses of Oleo Chemicals

EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS

Sorbitanne Stearate or Oleates used as Emulsifying agent in many

Cosmetics i.e. Cream , Lotions, Shaving Foams

Glycerol monostearate used as an Emulsifier & Pacifier in

Cosmetics , also as Lubricant, Anti-static agent . Fabric Softener in

Textile , Drilling & Cutting Oil

Lauryl Glucoside is a surfactant used in cosmetics. It is produced

from glucose and lauryl alcohol. Also as a Foaming agent

Non-Food Uses of Oleo Chemicals

Some Oleo chemical products in Personal care Formula

Peel off Face Mask & ScrubCeraphyl 791 Isocetyl Stearoyl Stearate

Cetyl Alcohol Ceraphyl 368 Octyl Palmitate

Application of Oleochemicals in Soap, Detergents and

Cosmetic Industries

Fathy Hassan, PhD

COO, Oleo Misr

drfh71@oleomisr.com

www.oleomisr.com