Appendix F – Site Water Balance (Foresight Engineering ......smaller dam to the west of the site...
Transcript of Appendix F – Site Water Balance (Foresight Engineering ......smaller dam to the west of the site...
Camperdown Compost Works Approval Application July 2020
91 | P a g e
Appendix F – Site Water Balance (Foresight Engineering, June 2020)
9/2 Star Road Bright VIC 3741
Design Report
Project Name: Fertiliser Production Site Storm Analysis Date: 28/05/20
Report No. SPR-01 Rev E By: A Robinson
Client: Sustainable Project Management Page: 1
Introduction
Sustainable Project Management recently engaged Foresight Engineering to perform a rainwater detention analysis for a
proposed compost production facility to be located in south-west Victoria. The facility design submission is required to show
that the site can accommodate a 1 in 100 year design storm without discharging any untreated water offsite. Due to the
nature of the facility, the majority of the rainfall runoff cannot be discharged directly offsite is it can become contaminated
by the composting medium. Instead it is proposed that the rainfall runoff (excluding covered areas such as buildings) be
contained within the site and be consumed later as part of the production process.
This report outlines the approach used to determine the minimum required size of the catchments dam to ensure the site
can tolerate a 1 in 100 year storm event (1% AEP).
This analysis demonstrates that minimum volume of the detention dam should have a volume of at least 6289 m³.
Site Information
The proposed facility is to be located near Camperdown, Victoria. The site layout used in the analysis is based on the provided
drawing no. GP-01 (drawn 26.05.20) (refer appendix 1). The site is comprised of two areas. One main catchment area where
the composting windrows are located and the detention dam makes up the second area.
Inputs and Assumptions
Client Supplied Data
• Dam water can be evaporated at a minimum rate of 4 m³/hour by the manufacturing process and can still occur
during a rainfall event.
Assumptions
• All information provided to Foresight is true and correct. For example drawings and process data.
• The following areas are plumbed so that they do not contribute to the stormwater catchment area; Pumphouse/ Maintenance Shed, PIW Storage Bunker, PIW Receival Pit, Sump for contact area, Rollover Bund.
• All rainwater that falls in the Contact Dam Catchment area (shaded orange in the layout drawing) is transported into the Contact Water Dam with minimal time delay.
Methodology
The analysis consists of two stages. Stage 1 is a simple calculation to determine the amount of rainwater volume the site
collects during a single 1% AEP storm event. This shows the absolute minimum detention requirement of the site. Stage 2
uses a statistical approach to allow for the possibility that the detention dam is already partially filled due to prior storms.
Hence, the stage 2 analysis sets a more rigorous criteria for the detention capability of the site. The key steps for stage 1 and
2 methods are described below. As a worst case, both analysis only consider storm durations of 168 hours (7 days) as this is
the longest duration provided in the BOM data and the longest storms always result in the highest total volume for a given
AEP.
Stage 1
Based on the provided site drawing (refer appendix 1), the site has a total catchment area of 34902m². The BOM IFD data for
Camperdown, Victoria states that a 1 % AEP, 168 hour duration storm has a total depth of 153mm. This means that the site
will collect a total of 5340m³ of rainwater. Hence, the stage 1 analysis suggests that the site should have a detention dam
volume of 5340m³ or greater.
9/2 Star Road Bright VIC 3741
Design Report
Project Name: Fertiliser Production Site Storm Analysis Date: 28/05/20
Report No. SPR-01 Rev E By: A Robinson
Client: Sustainable Project Management Page: 2
Stage 2
Due to the relatively slow rate that the site/ process can consume stormwater, it cannot be assumed that the detention dam
will be empty when a 1% AEP storm event occurs. This analysis instead determines the maximum volume of two events that
combined, result in an AEP of 1% or greater. Doing this takes into account the possibility that a smaller storm event can occur
before a larger event, effectively removing some of the dams capacity, or, after a larger event when there could be insufficient
capacity remaining in the dam.
Stage 2 consists of several key steps;
1. Determining the design probability of a storm event or combination of storm events during a 100 year design period.
2. If the event or event combination has a probability greater than 1% AEP the total rain volume is computed.
3. The largest total rain volume out of all the event combinations corresponds to the required detention volume.
The steps are described in more detail below. The full calculations can be seen in appendix 2.
Determining the event probability
For a 100 year design period there is an expected number of times that a certain storm will occur (e.g for a 10% AEP storm it
is expected to get 10 storms in the 100 year period). After one of these events has occurred (event 1) there is a drawdown
period before the dam is empty again, given by the rain volume and the process evaporation rate. There is a certain probability
that a second storm event (event 2) occurs during this period, based on the second event’s AEP. The probability that one or
more event 2’s occur during the drawdown period of any one of the event 1’s during the 100 year design period can be
described by a binomial distribution. The analysis takes into account any event 1 and event 2 combinations that have a
probability greater than 50% of occurring in the 100 year design period. If the combined probability of the two events is less
than 50% over 100 years then the site only has to detain the volume of the first storm, assuming the first storm has an AEP of
1% or greater, this is described by the ‘valid inflow’ calculation in appendix 2. This is considerably more conservative than the
nominal single 1 in 100 year storm event.
Computing the Total Event Rain Volume
IFD data from BOM (appendix 3) and the overall catchment area is used to compute a total volume for storms of various
Annual Exceedance Probabilities (AEP). For an event consisting of two combined storms, a conservative total volume is simply
the individual event volumes added together.
Results
A single 1% AEP, 168 hour storm gives a storm volume of 5340 m³ based on the catchment of the site.
The stage 2 analysis showed that a combined event of a 10% AEP, 168 hour storm followed by a 50%, 168 hour storm resulted
in the highest total storm volume of 6289 m³, 949 m³ larger than the stage 1 analysis. This was the maximum volume
calculated under all the scenarios that had a probability of greater than 50% over the 100 year period.
Hence, the facility requires a total detention dam volume of at least 6289 m³ to meet the required 1 in 100 year storm
capability whilst also allowing for the low water consumption rate of the process.
LunchRoom11.20m2
W1
W1
D1
SB
W1
D1
ChangeRoom4.76m2
Office24m2
W1
W1
D1
SB
W1
Coms
W1
W1
HWS
Toilet/Shower16.24m2
SB
W1
W1 W1 W1
Shr
Bsn
Wc Wc
1 2 3 4 5 6 7 8 9 10 11 12
3690008000
500038000
50006000 20000 12000 32000 12000 100000 15000 60000 10000
600027000
6000
7000
2190
025
100
1650
026
500
5000
7000
5000
80005000
B L I N D C R E E K R O A D
WEIGH BRIDGE
SITE AMENITIESSIPHONTANKS
LIQUIDSEPARATION
PIT
PUMPSHED
LIQUIDSPIT
MACHINERYSHED
DAM
100m X 68.1mPASTEURISATION
AREA(12 ROWS)
60m X 68.1mMATURATION
AREA(12 ROWS)
CO
MPO
STST
ORA
GE
ENTRYEXIT
CAR PARKING
SOLIDSEPARATION
BUNKER
2 NO. OF PUMPS FORSEPARATION SYSTEM
2 BAYS OF SHEDENCLOSEDFOR WORKSHOP
8 NO. OF STANDARD CAR SPACES+ 1 CAR SPACE AS PER AS1428
RESTRICTED ENTRY
2.4m HIGHREINFORCED
CONCRETE WALL
2.0m WIDE BUND& CHAINWIRE MESH FENCINGAROUND PERIMETER
CONCRETE PAVING FORTURNER TURNOUT
ROLLOVER KERB
VEHICLE EXIT
275,000LT RWTFOR SUPPLY TO
PASTEURISATION
275,000LT RWTWITH DEDICATED SUPPLYFOR FIRE FIGHTING
CONCRETESPOON DRAIN
(EAST) SOLIDSEPARATION
PIT
(WEST) SOLIDSEPARATIONPIT
UNDERGROUND PIPE NETWORKFOR PASTEURISATION SYSTEM
4 BAYS OF SHEDOPEN FOR HOUSINGMACHINERY & EQUIPMENT
BAMBOO TREE PLANTATIONTO PROVIDE PRIVACY SCREENAROUND PERIMETER
3690008000
500038000
50006000 20000 12000 32000 12000 100000 15000 60000 10000
600027000
6000
7000
2190
025
100
1650
026
500
5000
7000
5000
80005000
Site Layoutscale 1:1000 @ A3
Drawing no.
Drawn: Date:Checked: Revision:
Drawing name:
Ammendments: Date:RevB. ENG. CCB-U-57908Registered Building Practitioner
Ph: (03) 5595 1078 Fax: (03) 5595 1644 Web: www.greencon.com.au Australia Pty. Ltd.GreenCon
CCOMPOST FACILITY UPGRADEfor Camperdown Compost Company
located at 445 Blind Creek Rd, BOOKARDD
- -- GP-01
--------
GENERAL PLAN PROPOSED
26.05.2020
N
Catchment Inputs
Contact Catchment Units Values Comments
Catchment Length (East) m 350 dimensions updated from client supplied drawing no. GP-01 (26.05.2020)
Catchment Width (North) m 107
Contact Dam Length (East) m 38
Contact Dam Width (north) m 95
Contact Dam Area m² 3610
Contact Catchment Area m² 37450
non catchment areas m² 2548
Total Catchment Area m² 34902
Process Inputs
Nominal/ Initial Dam Volume m³ 0 NOT USED
Outflow from Catchment Dam due to evaporation m³/day 96 from client data
Maximum inflow into catchment dam due to process m³/day 24 from client data
Minimum evaporation from catchment dam due to natural
processmm/day
0.68
lowest monthly average from client supplied data, assumes trans-evap = lake-evap (conservative
assumuption)
Minimum evaporation from catchment dam due to natural
processm³/day
2.4548
Total Dam Outflow (Minimum) m³/day 74.4548
Storm Inputs (from BOM IFD data page)
STORM EVENT %AEPChance per day
Daily Probability of
Exceedance (one in…) 168 hour Storm Deph (mm) from Bom dataStorm Volume (m³)
1 2.73973E-05 36500 153 5340.0
2 5.47945E-05 18250 139 4851.4
5 0.000136986 7300 121 4223.1
10 0.000273973 3650 107 3734.5
20 0.000547945 1825 93.2 3252.9
50 0.001369863 730 73.2 2554.8
63.2 0.001731507 577.5 66.9 2334.9
Outputs
Contact Dam Required Storm Volume m³ 6289.34
Calculations
DESIGN OVERALL AEP (percentage) 1%
DESIGN AEP (factor) 0.01
PERIOD for probability of 1 100.00
DESIGN PERIOD (years) 100
Design period probability 1.00
SCENARIOS
EVENT 1 AEP% EVENT 2 AEP%
EVENT #1 Daily Probability
(1 in x) Number of Expected Event 1 Storms over Design Period (Also number of event 2 trials) Event #1 Volume Event # 1draw down time EVENT #2 Daily Probability
EVENT #2 probability over
DRAWDOWN period (1 in x)
EVENT #2 probability over
DRAWDOWN period (decimal
probability) Event #2 Volume
Probability that event 2
happens AT least once
during event 1
drawdown periods
Allowable probability
over DESIGN period Total Volume Valid Inflow
1 1 36500 1 5340.006 71.72144711 36500 508.91 0.00196 5340.01 0.00 0.50 10680.01 5340.006
1 2 36500 1 5340.006 71.72144711 18250 254.46 0.00393 4851.38 0.00 0.50 10191.38 5340.006
1 5 36500 1 5340.006 71.72144711 7300 101.78 0.00982 4223.14 0.01 0.50 9563.15 5340.006
1 10 36500 1 5340.006 71.72144711 3650 50.89 0.01965 3734.51 0.02 0.50 9074.52 5340.006
1 20 36500 1 5340.006 71.72144711 1825 25.45 0.03930 3252.87 0.04 0.50 8592.87 5340.006
1 50 36500 1 5340.006 71.72144711 730 10.18 0.09825 2554.83 0.10 0.50 7894.83 5340.006
1 63.2 36500 1 5340.006 71.72144711 577.5316456 8.05 0.12419 2334.9438 0.12 0.50 7674.95 5340.006
2 1 18250 2 4851.378 65.15870031 36500 560.17 0.00179 5340.01 0.00 0.50 10191.38 4851.378
2 2 18250 2 4851.378 65.15870031 18250 280.09 0.00357 4851.38 0.01 0.50 9702.76 4851.378
2 5 18250 2 4851.378 65.15870031 7300 112.03 0.00893 4223.14 0.02 0.50 9074.52 4851.378
2 10 18250 2 4851.378 65.15870031 3650 56.02 0.01785 3734.51 0.04 0.50 8585.89 4851.378
2 20 18250 2 4851.378 65.15870031 1825 28.01 0.03570 3252.87 0.07 0.50 8104.24 4851.378
2 50 18250 2 4851.378 65.15870031 730 11.20 0.08926 2554.83 0.17 0.50 7406.20 4851.378
2 63.2 18250 2 4851.378 65.15870031 577.5316456 8.86 0.11282 2334.94 0.21 0.50 7186.32 4851.378
5 1 7300 5 4223.142 56.72088301 36500 643.50 0.00155 5340.01 0.01 0.50 9563.15 4223.142
5 2 7300 5 4223.142 56.72088301 18250 321.75 0.00311 4851.38 0.02 0.50 9074.52 4223.142
5 5 7300 5 4223.142 56.72088301 7300 128.70 0.00777 4223.14 0.04 0.50 8446.28 4223.142
5 10 7300 5 4223.142 56.72088301 3650 64.35 0.01554 3734.51 0.08 0.50 7957.66 4223.142
5 20 7300 5 4223.142 56.72088301 1825 32.18 0.03108 3252.87 0.15 0.50 7476.01 4223.142
5 50 7300 5 4223.142 56.72088301 730 12.87 0.07770 2554.83 0.33 0.50 6777.97 4223.142
5 63.2 7300 5 4223.142 56.72088301 577.5316456 10.18 0.09821 2334.94 0.40 0.50 6558.09 4223.142
10 1 3650 10 3734.514 50.15813621 36500 727.70 0.00137 5340.01 0.01 0.50 9074.52 3734.514
10 2 3650 10 3734.514 50.15813621 18250 363.85 0.00275 4851.38 0.03 0.50 8585.89 3734.514
10 5 3650 10 3734.514 50.15813621 7300 145.54 0.00687 4223.14 0.07 0.50 7957.66 3734.514
10 10 3650 10 3734.514 50.15813621 3650 72.77 0.01374 3734.51 0.13 0.50 7469.03 3734.514
10 20 3650 10 3734.514 50.15813621 1825 36.38 0.02748 3252.87 0.24 0.50 6987.38 3734.514
10 50 3650 10 3734.514 50.15813621 730 14.55 0.06871 2554.83 0.51 0.50 6289.34 6289.3404
10 63.2 3650 10 3734.514 50.15813621 577.5316456 11.51 0.08685 2334.94 0.60 0.50 6069.46 6069.4578
20 1 1825 20 3252.8664 43.68914294 36500 835.45 0.00120 5340.01 0.02 0.50 8592.87 3252.8664
20 2 1825 20 3252.8664 43.68914294 18250 417.72 0.00239 4851.38 0.05 0.50 8104.24 3252.8664
20 5 1825 20 3252.8664 43.68914294 7300 167.09 0.00598 4223.14 0.11 0.50 7476.01 3252.8664
20 10 1825 20 3252.8664 43.68914294 3650 83.54 0.01197 3734.51 0.21 0.50 6987.38 3252.8664
20 20 1825 20 3252.8664 43.68914294 1825 41.77 0.02394 3252.87 0.38 0.50 6505.73 3252.8664
20 50 1825 20 3252.8664 43.68914294 730 16.71 0.05985 2554.83 0.71 0.50 5807.69 5807.6928
20 63.2 1825 20 3252.8664 43.68914294 577.5316456 13.22 0.07565 2334.94 0.79 0.50 5587.81 5587.8102
50 1 730 50 2554.8264 34.31379038 36500 1063.71 0.00094 5340.01 0.05 0.50 7894.83 2554.8264
50 2 730 50 2554.8264 34.31379038 18250 531.86 0.00188 4851.38 0.09 0.50 7406.20 2554.8264
50 5 730 50 2554.8264 34.31379038 7300 212.74 0.00470 4223.14 0.21 0.50 6777.97 2554.8264
50 10 730 50 2554.8264 34.31379038 3650 106.37 0.00940 3734.51 0.38 0.50 6289.34 2554.8264
50 20 730 50 2554.8264 34.31379038 1825 53.19 0.01880 3252.87 0.61 0.50 5807.69 5807.6928
50 50 730 50 2554.8264 34.31379038 730 21.27 0.04701 2554.83 0.91 0.50 5109.65 5109.6528
50 63.2 730 50 2554.8264 34.31379038 577.5316456 16.83 0.05941 2334.94 0.95 0.50 4889.77 4889.7702
63.2 1 577.5316456 63.2 2334.9438 31.36055432 36500 1163.88 0.00086 5340.01 0.05 0.50 7674.95 2334.9438
63.2 2 577.5316456 63.2 2334.9438 31.36055432 18250 581.94 0.00172 4851.38 0.10 0.50 7186.32 2334.9438
63.2 5 577.5316456 63.2 2334.9438 31.36055432 7300 232.78 0.00430 4223.14 0.24 0.50 6558.09 2334.9438
63.2 10 577.5316456 63.2 2334.9438 31.36055432 3650 116.39 0.00859 3734.51 0.42 0.50 6069.46 2334.9438
63.2 20 577.5316456 63.2 2334.9438 31.36055432 1825 58.19 0.01718 3252.87 0.66 0.50 5587.81 5587.8102
63.2 50 577.5316456 63.2 2334.9438 31.36055432 730 23.28 0.04296 2554.83 0.94 0.50 4889.77 4889.7702
63.2 63.2 577.5316456 63.2 2334.9438 31.36055432 577.5316456 18.42 0.05430 2334.94 0.97 0.50 4669.89 4669.8876
6289.3404max inflow (above 1% AEP)
Flowrates for design storms based on the site catchment area given in m³/hour
Duration 63.20% 50%# 20%* 10% 5% 2% 1%1 min 2669.5 3029.3 4245.3 5108.8 6008.2 7303.4 8382.82 min 2284.6 2579.6 3543.8 4209.4 4928.9 5792.4 6440.03 min 2036.3 2306.2 3180.4 3813.6 4425.2 5252.7 5900.34 min 1849.2 2097.5 2907.0 3486.2 4065.5 4892.9 5504.65 min 1701.7 1928.4 2683.9 3227.2 3777.6 4569.1 5180.810 min 1241.2 1410.3 1975.2 2392.5 2824.2 3450.2 3957.515 min 1000.2 1133.3 1590.2 1924.8 2281.0 2788.3 3212.820 min 845.5 960.6 1345.6 1629.8 1924.8 2352.9 2709.125 min 741.1 841.9 1172.9 1421.1 1680.1 2047.1 2352.930 min 662.0 751.9 1046.9 1266.4 1496.7 1820.5 2086.745 min 514.5 582.8 809.5 975.0 1147.7 1388.7 1583.01 hour 428.1 485.7 672.8 805.9 946.2 1144.1 1298.81.5 hour 331.4 374.2 518.1 618.8 726.7 870.7 985.82 hour 275.9 311.9 431.7 514.5 600.8 719.6 816.73 hour 213.7 241.4 332.8 399.4 464.1 557.7 629.64.5 hour 165.5 187.4 258.7 309.4 363.4 435.3 492.96 hour 138.2 156.5 216.2 259.4 303.7 367.0 417.39 hour 106.9 120.9 168.0 202.2 237.5 288.2 330.312 hour 88.9 100.7 140.0 168.7 199.0 242.1 278.518 hour 68.4 77.0 107.2 129.5 153.6 187.8 216.624 hour 56.1 63.3 87.8 106.5 126.6 154.7 178.830 hour 48.2 54.3 75.2 91.0 108.3 132.0 152.236 hour 42.5 47.9 65.8 79.5 94.6 115.5 132.848 hour 34.7 38.9 52.9 64.0 75.9 91.7 105.172 hour 25.9 28.7 38.5 46.1 54.3 65.1 73.496 hour 21.0 23.2 30.6 36.3 42.5 50.0 56.1120 hour 18.0 19.7 25.7 30.1 34.8 40.7 45.3144 hour 15.9 17.4 22.3 25.9 29.6 34.3 37.8168 hour 14.3 15.7 20.0 22.9 25.8 29.8 32.8
Annual Exceedance Probability (AEP)
Duration 63.20% 50%# 20%* 10% 5% 2% 1%
1 min 1.24 1.4 1.96 2.37 2.79 3.39 3.882 min 2.12 2.39 3.28 3.91 4.55 5.37 5.983 min 2.83 3.21 4.42 5.28 6.16 7.32 8.24 min 3.43 3.89 5.39 6.46 7.56 9.05 10.25 min 3.94 4.47 6.22 7.48 8.78 10.6 1210 min 5.75 6.53 9.15 11.1 13.1 16 18.415 min 6.94 7.88 11 13.4 15.8 19.4 22.320 min 7.85 8.9 12.5 15.1 17.8 21.8 25.125 min 8.59 9.74 13.6 16.5 19.4 23.7 27.230 min 9.22 10.4 14.6 17.6 20.8 25.3 2945 min 10.7 12.2 16.9 20.3 23.9 28.9 331 hour 11.9 13.5 18.7 22.4 26.3 31.8 36.1
1.5 hour 13.8 15.6 21.6 25.8 30.2 36.3 41.1
2 hour 15.3 17.3 23.9 28.6 33.4 40.1 45.43 hour 17.8 20.1 27.8 33.2 38.7 46.5 52.6
4.5 hour 20.7 23.4 32.3 38.7 45.2 54.4 61.8
6 hour 23 26.1 36.1 43.3 50.6 61.1 69.69 hour 26.7 30.3 42 50.6 59.4 72.1 82.612 hour 29.6 33.6 46.7 56.3 66.3 80.8 92.918 hour 34.1 38.6 53.6 64.9 76.9 93.9 10824 hour 37.5 42.3 58.7 71.1 84.5 103 11930 hour 40.3 45.3 62.6 75.9 90.3 110 12736 hour 42.5 47.7 65.7 79.6 94.8 115 13348 hour 46.3 51.6 70.5 85.2 101 123 14072 hour 51.8 57.4 77 92.3 109 130 14796 hour 56.2 61.9 81.7 96.9 113 133 149
120 hour 60 65.8 85.7 100 116 136 151
144 hour 63.5 69.5 89.4 104 118 137 152
168 hour 66.9 73.2 93.2 107 121 139 153
Annual Exceedance Probability (AEP)
BOM IFD data for Camperdown, Victoria
Camperdown Compost Works Approval Application July 2020
92 | P a g e
Appendix G – Groundwater Monitoring Reports – March, 2017, May 2018 and March/May 2020 (SESL)
!
Groundwater Monitoring Event Camperdown Compost Company Pty Ltd 445 Sandy’s Lane, Bookaar VIC 3260
Prepared for:
Nick Rouston
June 2017
(Report: C8080.B42507.Q6406. CC GME)
!
Groundwater Monitoring Report Camperdown Compost Company Pty Ltd
445 Sandy Lane, Bookaar, VIC 3260 C8080.B42507.Q6406.CC GME
Our Ref:
Camperdown Compost Company Pty Ltd 445 Sandys Lane, Bookaar, VIC 3260
Dear Nick,
Re: Camperdown Compost Company, March 2017 GME. 445 Sandy’s Lane, Bookaar
SESL Australia (SESL) was commissioned to conduct a groundwater monitoring event (GME) for the Camperdown Compost Company at their composting facility accessed via 445 Sandy’s Lane, Bookaar (the site). Records and evaluation of the monitoring for the March 2017 GME are provided below in this report.
Groundwater from all site monitoring wells was sampled on 15th March 2017. The report provides initial characterisation of groundwater quality of the site. SESL is of the opinion that there is no obvious groundwater impact from the composting facility. Recommended action includes:
• continue the groundwater monitoring program on a bi-annual basis (for at least the next 2 years and annually thereafter) and undertake trend analysis of contaminant concentrations to understand any potential impact;
• include analysis of phenols and volatile organic compounds including volatile halogenated compounds as the site receives wastewater from industrial facilities;
• monthly monitoring of the water level in the dams and groundwater level in well MW1 and MW2 to understand the relationship between the dam and groundwater;
• undertake slug testing to determine hydraulic conductivity of the site; and • develop a conceptual site model for a more detailed understanding of the interaction of groundwater
with dam water and future risk assessment.
Please do not hesitate in contacting our office if you have any questions.
SESL AUSTRALIA PTY LIMITED
Samantha Grant-Vest Subhas Nandy
Environmental Scientist Senior Hydrogeologist
Groundwater Monitoring Report Camperdown Compost Company Pty Ltd
445 Sandy Lane, Bookaar, VIC 3260 C8080.B42507.Q6406.CC GME
1 INTRODUCTION
SESL Australia (SESL) was commissioned, in February 2017, to conduct groundwater monitoring event (GME) for the Camperdown Compost Company (the Client) at their composting facility located at 445 Sandy’s Lane, Bookaar Victoria (the Site).
The Client operates under the Victorian Environmental Protection Authority (EPA) issued license 13415. This license addresses odour discharges and allows for green waste and certain prescribed industrial wastes to be composted onsite. The composting capacity of the premises is 24,000 tonnes of waste per year. Detail of the license conditions is provided in Appendix A. This report outlines the works involved in undertaking the first GME at the Site. Groundwater from three wells identified in this report as MW1, MW2 and MW3 were sampled and the results of the groundwater characterisation are discussed in this report.
2 OBJECTIVES AND SCOPE OF WORK
The primary objectives of the monitoring at the site is to:
• Initial characterisation of groundwater underlying the site; • Determine the contamination status of groundwater from the site related activities; • Compare groundwater results with relevant assessment criteria based on beneficial use of
groundwater; and • Determine ongoing associated trends in future.
2.1 SCOPE OF WORK The scope of works performed by SESL environmental scientists is as follows:
• Develop a Health and Safety Plan and Job Safety Analysis; • Gauge existing site groundwater monitoring wells to obtain depths to groundwater and record any
observation (hydrocarbon odours, sheen or other physical evidence of contamination); • Sample the three monitoring wells by low-flow method involving a micropurge pump, as per
methods described in the February 2017 Groundwater Monitoring Plan (GMP) and Groundwater Sampling Guidelines (EPA, Vic 2000) and collection of field water quality parameters;
• Conduct laboratory analysis of groundwater samples for Potential Contaminants of Concern (PCoC) discussed in Section 2.2.1;
• Collect trip blanks and quality control blind duplicate samples for quality assurance purposes as per the requirements in the February 2017 GMP;
• Engage a surveyor to survey the installed groundwater monitoring well heads; and • Prepare a short summary report.
Groundwater Monitoring Report Camperdown Compost Company Pty Ltd
445 Sandy Lane, Bookaar, VIC 3260 C8080.B42507.Q6406.CC GME
2.2 SITE INFORMATION The Camperdown Compost Company receives liquid and solid waste from regional industries and turns the waste materials into compost for agricultural and horticultural application. The Site is located within a Victorian district (Table 1) dominated by agricultural and horticultural land use (Figure 1 and Figure 2).
A pair of solar powered boom gates allow vehicular access to the site. Waste is accepted at a receiving area where a concrete pad and wash-down pump are located. Waste materials are taken to the centre of the site, from which numerous windrows extend. The compost is turned systematically and matures in windrows until such time the materials are fully composted and are ready for dispatch. A clay bund forms the perimeter of the site, enclosing the composting field and two leachate storage dams. Additional infrastructure at the site includes:
• 2 x 37,000 Litre water tanks which are used for washing trucks; and • 3 m x 4 m tool shed
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Table 1. Site Information
2.1.1 Site activities
COMPOSTING PROCESS
Windrow Layout
The materials to be composted are received at the centre of the site. The site has a number of large windrows, approximately four to five metres high, that start in the central drop off point and move out at either end of the site. The windrows are immature at the central point, and mature as they reach the end, resulting in a continuous composting process, rather than a batch system.
Liquids
Liquids are dropped off in the middle of the site and are moved by gravity down between the windrows as detailed above. On a weekly, or less frequent basis, the liquid is covered by pushing the top off one of the adjoining windrows. The windrow is then turned backwards and stood back up. This adds the moisture to the windrow as it is turned back.
Compost Monitoring
Weekly production meetings provide the forum for planning and monitoring in which production processes such as moisture levels and windrow turning are discussed. Odour monitoring occurs both onsite and offsite.
Site Address 445 Sandy’s Lane, Bookaar Victoria, 3260
Approximate Investigation Area
3.7 ha
Title Identification Lot 3 TP 430209
Current VIC EPA Licence 13415 (Amended 20th August 2014)
Local Governmnet Area Corangamite Shire Council
Current Zoning FZ1 – Farming Zone, Schedule 1
Current Site Use Composting facility
Surrounding Land Use FZ1 – Farming Zone, Schedule 1 (in all directions)
Surface Water Bodies Blind Creek – 450 m west Mount Emu Creek – 11 km west Lake Bookaar – 9 km north-east Lake Gnotuk – 11.5 km east
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Fate of waste materials
The materials that are received on site enter into the composting process. Materials are not stored prior to processing, and little pre-treatment or screening of materials occur. Some of the green organics entering the site may have obvious foreign materials removed if there is evidence of contamination with plastic or glass. In most cases, this is screened before being delivered.
Materials Received
A summary of the materials received and the potential contaminants of concern (PCoC) are summarized below:
Table 2. Summary of Materials Received at the Camperdown Compost Company Site and relevant PCoC
WASTE CODE DESCRIPTION PCoC K100 Animal effluent and residues Pathogens, nutrients, metals, total organic
carbon, animal oil (TRH). K120 Grease interceptor trap effluent Hydrocarbons (TRH, BTEX and PAH) and
metals. K200 Food and beverage processing wastes, including animal and vegetable oils
and derivatives Hydrocarbons (TRH, BTEX, PAH), metals, pathogens and nutrients.
L100 Car and truck wash waters Hydrocarbons (TRH, BTEX, PAH), metals; phenols, surfactants (nutrients).
L150 Industrial wash waters from cleaning, rinsing or washing operations, e.g. textile cleaning processing effluent, industrial plant and machinery washers, cooling tower wash waters.
Volatile Organic Compounds (VOC) including halogenated compounds, solvents, TRH, BTEX, PAH, Phenols, PCBs, pesticides, and metals.
N150 Fly ash Heavy metals(including, boron molybdenum, iron and aluminium) and PAH;
N190 Filter cake Metals; nutrients, hydrocarbons; pathogens
T130 Inert sludges or slurries such as clay or ceramic suspensions, drilling mud and pit water with negligible hydrocarbon contamination
Metals (including cadmium); TRH, BTEX, PAH and volatile halogenated compounds
TRH = total recoverable hydrocarbons, PAH = polyaromatic hydrocarbon, BTEX = benzene, toluene, ethylbenzene and xylene
Dams
There are two dams on the site; the larger dam closest to the facility has a capacity of approximately 3 ML. The smaller dam to the west of the site holds approximately 1 ML and is used as the reserve dam when the larger dam is reaching capacity.
When the site was established, the client was advised that approximately 21.4 m of heavy clay underlay the site. After testing the elutriability of the clay, the client decided lining was not necessary and as such, both dams are un-lined. The client has observed high nutrient loads in the dam water at times.
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Leachate Management
The dams are used to run rainwater off the site during the winter months. During the wetter months of the year, some windrows can also become saturated as liquid that is received is added into the windrows. In these circumstances, there is a drop out of high nutrient water that runs to the dam. There have been two cases in the last five years where untreated wastewater has been put straight into the dam. Each year, the dams are emptied back onto the site.
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3 GEOLOGY AND HYDROGEOLGY
Review of the regional geology maps of Victoria (Geoscience Australia) indicates the site is located within the Brighton Group, which is characterised by non-marine sands, sandy clay, silt and gravel; locally altered to quartzite (“grey billy”) and precellanite. The Corangamite Region soils also exhibit clay-rich gradational to strongly duplex profile, particularly south on the marls and limestones where soils have developed on Pliocene sand plains (Dahlhaus, 2010).
A review of the registered groundwater bores within a 10 Km radius of the Site (Bureau of Meteorology, Australian Groundwater Explorer) indicated that bores are primarily used for stock and domestic purposes; however other data is limited (Table 3). A map of the groundwater bores can be seen in Appendix C.
Table 3. Summary of Data for Groundwater Bores Within a 10 Km Radius of the Site.
BORE ID BORE DEPTH
(m) CONSTRUCTION
DATE PURPOSE SALINITY (µS/cm)
134663 12 11/10/1997 Exploration nd
70418 12.9 30/10/1973 Stock and domestic 1099
70436 12.8 01/01/1988 Stock and domestic nd
70429 13.4 06/10/1982 Stock and domestic 2700
133393 16.76 13/02/1996 Stock and domestic nd
70434 13.75 30/01/1986 Stock and domestic 5000
70424 14.0 06/02/1980 Stock and domestic 7700
70435 14.0 17/10/1985 Stock and domestic 4900
70419 15.24 08/03/1974 Stock and Domestic 1570
* nd = no data
The Site falls within the Hopkins-Corangamite Groundwater Catchment area located in the Otway Basin in south-western Victoria (Southern Rural Water, 2016). Groundwater in this catchment in jointly managed by Southern Rural Water (SRW) and the Department of Environment, Land, Water and Planning (DELWP) .The area falls outside of the groundwater management units (GMU) of Hopkins-Corangamite Groundwater Catchment. The Site groundwater is derived from the upper aquifer in the catchment at less than 5 m below ground surface (Appendix C: Depth to Water Table map (Colac Otway Shire Map)) with salinity in the range of 1001 – 3500 mg/L (Appendix C: Groundwater Salinity Map (Colac Otway Shire Map).
3.1 SITE GEOLOGY Based on the EarthEon Pty Ltd bore installation reports (2015, re-issued 2017) (Appendix F), three groundwater monitoring wells (MW1, MW2 and MW3) were installed at locations which were: most likely to intercept the estimated ‘southwest’ direction of groundwater flow; close to the leachate ponds and accessibility. The report describes as follows:
• ~0 – 3 m below ground surface (mbgs) stiff CLAY; and • ~3 – 9 (mbgs) pale grey SANDY CLAY
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4 REGULATORY FRAMEWORK FOR GROUNDWATER ASSESSMENT
In accordance with Section 16 (1) of the Environmental Protection Act 1970, groundwater is protected under the State Environment Protection Policy, Groundwater’s of Victoria (Groundwater SEPP), Gazette no. S160, Dec 1997 and varied Gazette no. G12, March 2002. This policy aims to maintain and where necessary improve groundwater quality in order that the existing and potential beneficial uses of groundwater are preserved.
The Groundwater Resource Report (Vic, DELWP) indicates the groundwater in the Hopkins – Corangamite surface aquifer has salinity/TDS of 1001 – 3,500 mg/L, which would be classed under Segment B of the Groundwater SEPP, 1997. Groundwater analysis on site revealed TDS in the range of 4730 – 9360 mg/L (Appendix E); exceeding the acceptable criteria for TDS in Segment B under the Groundwater SEPP (potable water). As such, the most appropriate category for the site groundwater is Segment C under Groundwater SEPP. Under this classification, the protected beneficial uses include:
• stock watering; • maintenance of aquatic ecosystem (freshwater); • industrial water use; • primary contact recreation; and • buildings and structures.
In accordance with SEPP, and based on the beneficial use of groundwater, associated guideline adopted for the assessment of groundwater quality is presented in Table 4.
Table 4. Groundwater Beneficial Uses
BENEFICIAL USE ADOPTED GUIDELINE
Maintenance of ecosystems
ANZECC 2000 “Aquatic systems” guidelines for marine and freshwater species. Trigger values for 95%Freshwater Aquatic Ecosystem. Also Hickey (2002) for nitrate criteria.
Agriculture, Parks and Gardens
ANZECC, 2000 “Primary Industries” guidelines for irrigation water quality.
Stock Watering ANZECC, 2000 “Primary Industries” guidelines for livestock drinking water quality.
Industrial Water Use No specific guidelines as stated in ANZECC 2000.
Primary Contact Recreation
NHMRC Guidelines for Managing Risks in Recreational Waters, 2008 (Australian Drinking Water Guideline (2011 updated in 2016) value multiplied by a factor of 10)
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4.1 ADOPTED GUIDELINE DOCUMENTATION This groundwater investigation was conducted in accordance with:
• Australian and New Zealand Environment Conservation Council, Australian and New Zealand Guidelines for Fresh and Marine Water Quality, October 2000;
• Victorian Government State Environment Protection Policy, Waters of Victoria; • Victorian Government State Environment Protection Policy, Groundwaters of Victoria 1972, as
varied 19/3/2002; and • Victorian EPA Publication 669, Groundwater Sampling Guidelines, April 2000.
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5 FIELD WORK
5.1 PERSONNEL This GME was undertaken in accordance with guidelines listed in Section 4.1. Andrew Jacovides, SESL Environmental Scientist and Declan McDonald, SESL Senior Soil Scientist conducted the GME on 15th March 2017.
5.2 GROUNDWATER SAMPLING METHODOLOGY SESL consultants undertook a groundwater-monitoring event (GME) at the Camperdown Compost Company facility in accordance with the Victorian EPA Groundwater Sampling Guidelines (2000).
Prior to sampling, the three wells (MW1, MW2 and MW3) were gauged and purged using a low-flow, micro-purge pump and low density polyethylene (LDPE) tubing. The pump was set to intersect groundwater within the screened section of the monitoring well. A calibrated water quality meter was used to measure field groundwater quality parameters during purging, and when field parameters were stabilized, the groundwater samples were collected. Purging log sheets are presented in Appendix D. Calibration certificates associated with sampling equipment including the water quality meter are provided at Appendix D.
Three wells were sampled using disposable nitrile gloves at each well. Re-useable sampling equipment was decontaminated between wells using deionized water and Decon 90. LDPE tubing, bladders and filters dedicated to each well were used.
Samples were collected in laboratory supplied containers with appropriate preservatives, stored in a chilled esky and transported to a NATA accredited laboratory for analysis with a signed chain of custody form (Appendix E).
* It should be noted that at the time of sampling, no well identification was observed on the wells. The identification system adopted by SESL’s environmental consultant was changed, post sampling upon correct identification of the wells to match the drillers logs (see correspondence Appendix F).
Groundwater samples were collected from three groundwater monitoring wells (MW1 to MW3) at the site and analysed for the following PCoCs:
• pH; • Total dissolved solids (TDS); • Total organic carbon (TOC); • Major cations and anions; • Heavy metals (8); • Total petroleum hydrocarbons (TPH) (+ silica gel clean-up) • Benzene, ethylbenzene, toluene, xylene; • Polycyclic aromatic hydrocarbons; • Organochlorines and organophosphate pesticides (OCPs and OPPs); • Polychlorinated biphenyls;
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• Nutrients; and • bacteria (E.coli, faecal coliforms, Salmonella spp., and Legionella);
5.2.1 Groundwater Elevations and Inferred Groundwater Flow
Standing water levels (SWL) were measured from the top of the well casing and gauged. The elevations of the top of the well casings were surveyed by a licensed surveyor (Alan H. Simpson Land Surveyor Pty Ltd) to the Map Grid of Australian (MGA) and Australian Height Datum (AHD) (Appendix B). Based on the groundwater levels the inferred direction of groundwater flow is towards west (Table 5) (Figure 2).
Table 5. Groundwater Levels
AHD = Australian Height Datum BTOC = Below top of casing
Groundwater levels and gauging results are recorded in sampling sheets provided in Appendix D and the groundwater potentiometric contour map based on gauging data from the March 2017 GME is provided in Figure 2.
BORE ID EASTING NORTHING
BORE DEPTH
(m BTOC)
NATURAL SURFACE (m AHD)
TOP OF CASING (m AHD)
STANDING WATER LEVEL
(m BTOC)
REDUCED LEVEL
(m AHD)
SCREEN INTERVAL (m BTOC)
MW3 682288.591 5772785.549 7.793 138.381 139.178 3.013 136.165 3-7
MW1 682027.116 5772772.089 9.71 137.901 138.657 2.985 135.672 3-9
MW2 681979.086 5772821.750 7.830 137.768 138.560 3.115 135.445 3-7
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Figure 1. Groundwater Flow Direction at Camperdown Compost Company site, Bookaar, Victoria, Australia.
5.2.2 Field Water Quality Parameters Extracted groundwater was observed to be almost neutral and saline. Some variation was observed between wells. Negative redox potential observed in groundwater indicates a slightly reducing environment. A summary of the water quality parameters observed in the field is given in Table 6.
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Table 6. Summary of Water Quality Parameters for Groundwater
Water Quality Parameter
MW1 MW2 MW3
Temperature range (C) 17.2 18.1 23.3
Electrical conductivity (µS/cm)
5161 6881 11295
pH 6.95 7.34 6.7
ORP/Eh2 (mv) -110 -139.2 nd
DO (mg/L) 1.92 1.14 2.31
Turbidity First 9 litres extracted were muddy brown, clearing to
clear/brown with subsequent extraction.
First 2 litres extracted were pinky brown, clearing to clear/brown with
subsequent extractions.
First 9 litres extracted were milky and subsequent volumes
extracted were clear.
Other No odour No odour No odour
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6 QUALITY ASSURANCE AND QUALITY CONTROL (QA/QC) RESULTS
As part of the SAQP in the February GMP report, data quality objectives (DQOs) and data quality indicators (DQIs) have been stated with targets for quality assurance and controls in accordance with the NEPM (NEPC 2013). The sections below outline the performance of fieldwork, sampling and analysis against DQI’s as a qualitative and quantitative assessment of the validity and usability of data collected at the site during this assessment.
6.1 FIELD QA/QC A summary of the quality control sampling program is provided in Table 7 below and discussed within other subsections below.
The analytical results and RPD calculations for groundwater analyses are provided in Table A1 – Replicate Quality Samples (RPDS); Appendix E. The analytical results of Rinsate Blank samples are provided in Table A2 – Blanks Quality Samples; Appendix E. Laboratory certificates are provided in Appendix E – Laboratory Analytical Results.
The following comments are made as a summary regarding the quality of the field and analytical components of this project:
• Water quality meter used during the fieldwork was hired from Air-Met Scientific Pty Ltd in Nunawading Victoria. The calibration certificates for the equipment are included in Appendix D;
• Sample integrity and container requirements were documented as acceptable (refer to sample receipt notifications at Appendix E);
• Holding time compliances were documented as acceptable. All samples were received by the laboratory within the relevant holding times (refer to sample receipt notifications at Appendix E); and
• The primary (ALS) laboratory was NATA registered at the time of analysis and NATA accredited for all analyses performed.
Table 7. Summary of Quality Control Sampling Program
Summary of Quality Sample Results from Analytical Table 3 and Analytical Table 4.
Total RPD Comparisons 124
Total RPD > 30% 3.2% min. target
Achieved Quality Targets?
% RPD <= 30% 96.8% =>95% Y
Total GW Primary 3
Total Primary 3 min. target actual
Total Duplicates QAQC 1 5.0% 11.1% Y
Count min. target >LOR
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Summary of Quality Sample Results from Analytical Table 3 and Analytical Table 4.
QAQC 1 1 0 Y
Total Rinsate Blanks 1 1 0 Y
All quality control including blanks and replicate samples met the quality control targets.
6.2 LABORATORY QA/QC Laboratory QA/QC for groundwater analysis comprised of chain-of-custody documentation, sample integrity and holding times, sample temperatures on receipt, use of acceptable NATA-registered laboratory methods and laboratory QA/QC results. A summary is provided in Table 8 below.
ALS has provided a QA/QC report of laboratory control samples performance and other quality performance records provided with laboratory certificates in Appendix E. A performance summary is provided below in Section 6.3.
Table 8. Summary of Laboratory Quality Control Programme
6.3 PERFORMANCE AGAINST DATA QUALITY INDICATORS Quality control qualitative and quantitative results from fieldwork and laboratory analyses have been compared in Table 9 below against the DQIs.
Lab Report # Quality Control Samples Holding Times Frequency of Quality Control Samples
ALS EM1702381_1_QC1 (groundwater)
Laboratory control spikes for Organophosphorus pesticides (OP) Monocrotophos and Parathion-methyl were outside of the control limit. Matrix spikes for Sulfate (as SO4-) and total Kjeldahl Nitrogen (as N) could not be determined as background concentrations exceeded spike levels.
pH holding times were exceeded by five days on all samples. pH was recorded in the field however. Total carbon and total inorganic carbon exceeded holding time by 5 days on all samples. In all samples, the concentrations returned did not exceed guideline criteria (Appendix E). Samples were submitted to ALS just before the close of business on Friday afternoon and could not be extracted until after the weekend.
Laboratory duplicates and matrix spikes for Polycyclic Aromatic Hydrocarbons (PAH)/phenols, Pesticides, Polychlorinated Biphenyls, Total Recoverable Hydrocarbons were not analysed at the required rate. These analytes were not present in in groundwater samples submitted for analysis.
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Table 9. Data Quality Evaluation Summary
Data Quality Objectives
Sampling Frequency Required
Frequency Achieved?
DQI
95% DQI Met?
Precision
Field duplicates 1/20 (>=5%) Yes – 33.3% <=30% RPD Yes.
Laboratory duplicates (ALS) 1/20 Yes - <16% RPD
<=30% RPD
Yes exceptions are listed in Table 8. above.
Laboratory method blanks 1 per batch Yes <LOR Yes.
Accuracy
Laboratory matrix spikes 1/20 Yes 70 to 130%
Yes
Laboratory control samples 1/20 Yes Yes.
Representativeness
Sampling handling storage and transport appropriate for media and analyses - - Yes Samples chilled and transported in accordance
with COC requirements.
Rinsate blank
1 per day Yes – 1 samples <LOR Yes
Samples extracted and analysed within holding times.
24 hrs - Bacteria, 14 days - organics 6 months– inorganics, Iron – 7 days
Holding time not met for pH, Total Carbon and Total Inorganic Carbon as listed in Table 8. above.
Comparability
Standard operating procedures used for sample collection and handling (including decontamination)
All Samples - Yes
All sampling completed in accordance with SESL standard operating procedures. New sampling equipment and sampling gloves used for each sample.
Standard operating procedures used for sample collection and handling (including decontamination) Standard analytical methods used for all analyses
1 Rinsate blank during programme
Yes <LOR Yes, collected off the pump after decontamination toward the end of each sampling day.
All Samples -
Yes NATA accredited methods used for all analyses.
Consistent field conditions, sampling staff and laboratory analysis All Samples - Yes
All field work completed by Andrew Jacovides, SESL Environmental Scientist and Declan McDonald, Senior Soil Scientist. All laboratory analysis completed by NATA accredited laboratories (ALS).
Limits of reporting appropriate and consistent All Samples - Yes Yes – all LORs below investigation levels.
Completeness
COC completed and appropriate All Samples - Yes Refer to Appendix E for laboratory certifications and signed COCs.
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Appropriate documentation All Samples - Yes Refer to Appendix D for groundwater sampling logs. Refer to Appendix D for sampling instrument calibration records.
Notes: DQI – Data Quality Indicator LOR – laboratory’s limit of reporting RPD – relative percentage difference COC – Chain of custody documentation
6.4 STATEMENT ON DATA QUALITY Overall, the data quality objectives were met during the investigation, as demonstrated throughout this report. Documentation was maintained and complete, sufficient data was collected to characterise the site in accordance with statutory requirements. The data have been shown to be comparable and representative of the site, and precision and accuracy has been demonstrated in the field and laboratory QA/QC programs.
The overall data quality performance against DQIs indicates that the analytical data is representative of site conditions at the time of the investigation as well as suitable to enable valid assessment of the site.
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7 ANALYTICAL RESULTS SUMMARY
Discrete groundwater samples collected at the site in March 2017 were analysed for selected PCoCs described below. Analytical results are summarised below and in Table 10, and laboratory analytical certificates are provided at Appendix E – Laboratory Analytical Results.
All samples were submitted to ALS Environmental (ALS) in Springvale, Victoria. ALS is NATA accredited for the analyses performed, and an associated statement of NATA accreditation is supplied in the laboratory certificates provided at Appendix E.
Based on the location of the wells and groundwater flow direction, MW3 is hydraulically up-gradient of the direction of groundwater flow (discussed in Section 5.3.1), and MW2 and MW 1 is hydraulically down gradient and cross gradient of the site. MW3 could be considered a background well.
7.1 GROUNDWATER RESULTS The concentrations in groundwater samples were compared with the guidelines outlined in Section 4, Table 4 of this report. The results are summarized in Appendix E (Table A3) and discussed below.
7.1.1 Dissolved Hydrocarbons All groundwater samples were analysed for hydrocarbon (BTEX, TRH and PAHs) with results presented in Analytical Table 3.
• MW1, MW2 and MW3 did not contain any detectable concentrations of hydrocarbons.
7.1.2 Dissolved Heavy Metals All groundwater samples were analysed for heavy metals (arsenic, cadmium, chromium, copper, lead, nickel, zinc, mercury). A summary of metal exceedance is provided Table 10. Metal exceedances are noted to be marginal.
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Table 10. Summary of Metals of Concern in Sampled Groundwater
Contaminant
(mg/L)
Well identification Guideline Criteria (mg/L)
MW1 MW2 MW3
AN
ZEC
C 2
000
Fres
hwat
er A
quat
ic
Ecos
yste
ms
AN
ZEC
C 2
000
Rec
reat
iona
l Wat
er
Qua
lity
AD
WG
201
5 R
ecre
atio
nal W
ater
Q
ualit
y (D
WG
x 1
0)
AN
ZEC
C 2
000
Live
stoc
k D
rinki
ng
Wat
er –
low
risk
Nickel 0.008 0.014 0.009 0.011 0.1 - 1.0
Zinc 0.011 0.011 0.009 0.008 5.0 5.0 20
Copper <0.001 0.002 <0.001 0.0014 1.0 2.0 0.4
* Bold text denotes exceedance of adopted guideline criteria
7.1.3 PCBs, OCPs, OPPs Concentrations of PCB’s, OCP’s and OPP’s remained below the laboratory Limit of Reporting (LOR).
7.1.4 Pathogens Legionella sp., Escherichia coli, or faecal coliforms remained below the LOR. Salmonella spp. was not detected in any samples.
7.1.5 Nutrients Ammonia as N in MW2 (0.02 mg/L) exceeded ANZECC Freshwater aquatic ecosystem criteria (0.01 mg/L). Nitrate as N in MW2 (44.5 mg/L) and MW1 (24.1 mg/L) exceeded ANZECC Freshwater aquatic ecosystem criteria (2.4 mg/L) as per Hickey (2015).
7.1.6 Major Cations and Anions Exceedances in all three wells in the range of (1770 – 3970 mg/L) were observed for chloride and exceedances in all three wells in the range of (861 – 1900 mg/L) were observed in sodium when compared against the ANZECC 2000 Recreational Water Quality and Aesthetics: Primary Contact, acceptance criteria.
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8 ASSESSMENT SUMMARY
On behalf of Camperdown Compost Company, SESL conducted this GME in March 2017, which included the following:
• Survey and level gauging of groundwater monitoring wells; • Preparation and interpretation of groundwater contour map and suitability of installed wells; • Groundwater monitoring event including low-flow sampling methodology of all three groundwater
monitoring wells at the site; • Laboratory analysis for PCoCs; • Reporting the results of fieldwork and laboratory analysis of groundwater samples; and • The assessment data was compared with data quality indicators, which indicated that the data
quality has met the objectives and regulatory requirements, and the data discussed is therefore likely to be indicative of site conditions.
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9 CONCLUSION AND RECOMMENDATIONS
Groundwater level measurements indicate that the groundwater flows towards west (Figure 2). Based on the groundwater flow direction, MW3 is located hydraulically up gradient and MW2 and MW1 is hydraulically down-gradient and cross-gradient. The current GME provides initial characterisation of groundwater in the site.
Groundwater in MW2 exhibited generally higher concentrations of metals (copper, zinc and nickel) and nutrients than groundwater in wells MW3 and MW1. TDS, chloride and bicarbonate concentrations were also higher in M2, than MW3 and MW1. Chloride, nitrogen (as ammonia, total Kjeldahl nitrogen and nitrate) and sodium concentrations were greater in MW1 groundwater than MW3 groundwater (located up gradient of the groundwater flow).
No baseline groundwater quality data is available for the site to confirm if the higher concentrations of metals, nutrients, TDS, chloride and bicarbonate is related to impact from migration of contaminants via through-flow from the composting field, or represents background groundwater quality. However, the downstream positions of MW2 and MW1, and chemical characterisation of the groundwater indicate that site activities may be impacting on groundwater quality.
Two dams are located on the western side (Figure 1) of the Camperdown Compost Facility. E-mail communication with Nick Rouston on 21 April 2017 revealed the following:
• “The dams were not lined. During the site establishment, Camperdown Compost Company was advised that the site was located on around 70 feet of heavy clay underneath and the elutriability of the clay indicated lining was not necessary.
• The dams received runoff of the site during the winter months. During the wetter months of the year, some compost windrows can be saturated as wastewater received from different industrial facilities is added into the windrows. In these circumstances, there is a drop out of high nutrient water that runs to the dam. Rarely, untreated wastewater has been put straight in the dam. Each year, the dams are emptied”
The groundwater level is above the base of the dam and hence, the dam may work as a groundwater sink when the dam water level is below the groundwater level. However, when the dam is at full capacity, there is potential for recharge to groundwater from the dam (especially during winter months). The amount of recharge to the groundwater table surrounding the dam will depend on the hydraulic conductivity of the material. There is no hydraulic conductivity measurement undertaken for the site.
SESL recommends the following:
• Continue the groundwater monitoring program on a bi-annual basis (for at least the next 2 years and annually thereafter) and undertake trend analysis of contaminant concentrations to understand any potential impact;
• Include analysis of phenols and volatile organic compounds including volatile halogenated compounds as the site receives wastewater from industrial facilities;
• Monthly monitoring of the water level in the dams and groundwater level in well MW1 and MW2 to understand the relationship between the dam and groundwater;
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• Undertake slug testing to determine hydraulic conductivity of the site; and • Develop a conceptual site model for a more detailed understanding of the interaction of groundwater with
dam water and future risk assessment.
ATTACHMENTS:
ANALYTICAL TABLES
A1 – REPLICATE QUALITY SAMPLES (RPDS)
A2 – BLANKS QUALITY SAMPLES
A3 – WATER QUALITY RESULTS
APPENDICES
APPENDIX A - EPA LICENSE APPENDIX B - SURVEY INFORMATION APPENDIX C - DEPTH TO WATER TABLE MAP
GROUNDWATER SALINITY MAP APPENDIX D - FIELD INSTRUMENT CALIBRATION CERTIFICATES GROUNDWATER SAMPLING FIELD SHEETS APPENDIX E - CHAIN OF CUSTODY FORM LABORATORY CERTIFICATES LABORATORY ANALYTICAL RESULTS APPENDIX F - EARTHEON BORE INSTALLATION REPORT
Groundwater Monitoring Report Camperdown Compost Company Pty Ltd
445 Sandy Lane, Bookaar, VIC 3260 C8080.B42507.Q6406.CC GME
10 REFERENCES
1) ANZECC and ARMCANZ (2000). Australian and New Zealand Guidelines for Fresh and Marine Water Quality (October 2000);
2) Bureau of Meteorology (2017) Australian Groundwater Explorer http://www.bom.gov.au/water/groundwater/explorer/map.shtml
3) Centre for eResearch and Digital Innovation, Federation University Australia 2017 Visualising Victoria’s Groundwater.
4) Colac Otway Shire Maps, 2017, (http://cos.cerdi.com.au/cos_map.php).
5) Dahlhaus P.G. (2010) Salinity risk in the Corangamite Region, Australia [thesis] Federation University Australia; (http://theses.flinders.edu.au/public/adt-SFU20100928.150627/index.html).
6) Geoscience Australia. Australian Stratigraphic Units Database: Brighton Group. Stratno:2556; http://dbforms.ga.gov.au/pls/www/geodx.strat_units.sch_full?wher=stratno=2556
7) National Environmental Protection Council (NEPC) (2013). National Environment Protection (Assessment of Site Contamination) Measure 1999 (as amended April 2013);
8) NHMRC & NRMMC (2011). Australian Drinking Water Guidelines (ADWG) - National Health and Medical Research Council & Natural Resource Management Ministerial Council.
9) USEPA (2000). Guidance for the Data Quality Objectives Process, EPAC QA/G-4 DEC/600/r-96/055, United States Environmental Protection Agency Office of Environmental Information, Washington DC.
10) VIC. Department of Environment, Land, Water & Planning (2015), Groundwater Resource Report.
11) VIC EPA (2000) Groundwater Sampling Guidelines No.669.
12) VIC EPA (2006) Hydrogeological Assessment (groundwater quality) Guidelines; publication no. 668.
13) VIC EPA (2015) Designing, Constructing and Operating Composting Facilities; publication no.1588.
14) Southern Rural Water, 2016. The Hopkins-Corangamite Groundwater Catchment Statement. (http://www.srw.com.au/wp-content/uploads/2016/06/Hopkins-Corangamite-GCS_Final-April-2016.pdf. SRW).
Groundwater Monitoring Report Camperdown Compost Company Pty Ltd
445 Sandy Lane, Bookaar, VIC 3260 C8080.B42507.Q6406.CC GME
11 DISCLAIMER AND LIMITATIONS
The conclusions presented in this report are relevant to the conditions of the site and the state of legislation currently enacted at the date of this report. We do not make any representation or warranty that the conclusions in this report will be applicable in the future as there may be changes in the condition of the site, applicable legislation or other factors that would affect the conclusions contained in this report.
SESL Australia Pty Ltd has used a degree of skill and care ordinarily exercised by reputable members of our profession practicing in the same or similar locality. Conclusions are based on representative samples or locations at the site, the intensity of those samples being in accordance with the usual levels of testing carried out for this type of investigation. Due to the inherent variability soils and groundwater and the general environment, we cannot warrant that the overall condition of the site is identical or substantially similar to the representative samples.
This report has been prepared for Camperdown Compost Company Pty Ltd for the specific purpose to which it refers. No responsibility is accepted to any third party. Neither the whole of the report or any part or reference thereto may be published in any document, statement or circular nor in any communication with third parties without our prior written approval of the form and context in which it will appear.
This report and the information contained in it is the intellectual property of SESL. Camperdown Compost Company Pty Ltd is granted an exclusive license for the use of the report for the purpose described in the report.
Groundwater Monitoring Report Camperdown Compost Company Pty Ltd
445 Sandy Lane, Bookaar, VIC 3260 C8080.B42507.Q6406.CC GME
Appendix A
ENVIRONMENT PROTECTION ACT 1970 SECTION 20
LICENCE
THE CAMPERDOWN COMPOST COMPANY PTY LTDHolder ofLicence: 13415
Issued: 11/04/2008Last Amended: 20/08/2014ACN: 108 839 363Registered Address: 4915 PRINCES HWY
CAMPERDOWN VIC 3260Premises Address: BLIND CREEK RD
BOOKAAR VIC 3260Scheduled Categories: A01 Prescribed Industrial Waste Management
A07 CompostingDescription: The licence holder operates a composting facility. This licence addresses odour
discharges and allows for green waste and certain prescribed industrial wastes to be composted onsite. The composting capacity of the premises is 24,000 tonnes of waste per year.
HELEN CORRY Team Leader Development Assessments Delegate of the Environment Protection Authority Issued under the Environment Protection Act 1970, Section 20
SECTION 20 LICENCE
Licence: 13415 Last Amended: 20/08/2014 Page 2 of 7
PREAMBLE
Licences
Who we are: The Environment Protection Authority (“EPA”) is an independent statutory authority established under the Environment Protection Act 1970 (“the Act”). Our purpose is to protect and improve our environment by preventing harm to the environment and human health.
Why we issue licences: EPA is responsible for preventing or controlling pollution (including noise) and improving the quality of the environment. This responsibility includes regulating activities that may present a danger to the environment. One of the tools available to EPA is the licensing of certain scheduled premises that may present a risk to the environment.
Section 20 of the Act requires the occupier of a “scheduled premises” to obtain an EPA licence to discharge, handle, treat or dispose of waste to the environment. These premises are defined in the Environment Protection (Scheduled Premises and Exemptions) Regulations 2007 (“the Regulations”).
When we issue licences: EPA will issue a licence when satisfied that an applicant has put in place measures to protect the environment. Licences allow activities to occur and set performance outcomes based on a site’s environmental risk. EPA can amend, suspend or revoke a licence in response to changes in standards, site activities or licence holder performance. Licence holders must submit an annual performance statement and pay an annual fee to EPA. All licences and performance statements are publicly available.
Licence information and obligations
For the purposes of this licence “You” means the licence holder identified on the first page of this licence at the “premises” identified on the first page and represented in Schedule 1.
If you object to any of the licence conditions, you may have the decision reviewed by applying in writing to the Registrar, Planning and Environment Division, Victorian Civil and Administrative Tribunal (“VCAT”), 7th Floor, 55 King Street, Melbourne within 21 days of the date of issue. An application fee may be applicable when lodging an appeal with VCAT. Contact VCAT on (03) 9628 9777 for further details on fees associated with an appeal. A copy of the appeal should also be forwarded to the Manager, Development Assessments Unit, Environment Protection Authority, GPO Box 4395, Melbourne, 3001, within 7 days of lodgement of the appeal.
Interested (third) parties may also appeal against the licence within 21 days of the date of issue. The Tribunal will notify you if such appeals are received. If an appeal is lodged, this licence will not come into effect.
Compliance: You must comply at all times with the Act and all policies and regulations administered by EPA. Strict penalties apply for non-compliance with any part of your licence or making a false claim on your annual performance statement.
Licence structure
Structure: Your licence has multiple parts: • Environmental performance conditions - setting out the performance outcomes you must meet; • Schedule 1A - locality plan of your premises; • Schedule 1B - plan of premises (provided by you).
Some types of licences also contain Schedule 1C - final landfill contour plans and/or Schedule 2 - tables specifying wastes that may be accepted at the premises and the associated treatment applied to them.
SECTION 20 LICENCE
Licence: 13415 Last Amended: 20/08/2014 Page 3 of 7
CONDITIONS
General Conditions
LI_G1 Waste from the premises must not be discharged to the environment except in accordance with this licence.
LI_G2 You must immediately notify EPA of non-compliance with any condition of this licence.LI_G3 By 30 September each year you must submit an annual performance statement to EPA for
the previous financial year in accordance with the Annual Performance Statement Guidelines (EPA Publication 1320).
LI_G4 Documents and monitoring records used for preparation of the annual performance statement must be retained at the premises for seven years from the date of each statement.
LI_G5 You must implement a monitoring program that enables you and EPA to determine compliance with this licence.
LI_G6 You must maintain a financial assurance calculated in accordance with the EPA method.
Amenity Conditions
LI_A1 Offensive odours must not be discharged beyond the boundaries of the premises.LI_A2 Unacceptable noise (including vibration) must not be emitted beyond the boundaries of the
premises.LI_A3 Nuisance dust must not be discharged beyond the boundaries of the premises.
Waste Acceptance Conditions
LI_WA1 Only wastes listed in Schedule 2 may be accepted at the premises.LI_WA1.5 You must not accept Drilling Mud (Waste Code T130 as specified in schedule 2) for the
purpose of treatment code (R16-Composting), if the drilling mud has free flowing liquid in it.LI_WA2 Wastes accepted at the premises may only be treated or disposed of in accordance with
Schedule 2.
Waste Management Conditions
LI_WM1.3 You must not treat more than 24000 tonnes of waste on the premises per year.LI_WM3 You must ensure that litter is not deposited beyond the boundaries of the premises.LI_WM4 You must ensure that waste does not burn at the premises.
Landfill Conditions
Licence does not have any landfill conditions.
Air Conditions
SECTION 20 LICENCE
Licence: 13415 Last Amended: 20/08/2014 Page 4 of 7
Licence does not have any discharge to air conditions.
Water Conditions
LI_DW1 Stormwater discharged from the premises must not be contaminated with waste.
Land Conditions
LI_DL1 You must not contaminate land or groundwater.
SECTION 20 LICENCE
Licence: 13415 Last Amended: 20/08/2014 Page 5 of 7
Licence: 13415Company Name: THE CAMPERDOWN COMPOST COMPANY PTY LTD
ACN: 108 839 363Premises Address: Blind Creek RD, BOOKAAR VIC 3260
Issued: 11/04/2008Last Amended: 20/08/2014
Before relying on the information in this map, users should carefully evaluate its accuracy, currency, completeness and relevance for their purposes, and should obtain any appropriate professional advice relevant to their particular circumstances.
SCHEDULE 1A - LOCALITY PLAN
SECTION 20 LICENCE
Licence: 13415 Last Amended: 20/08/2014 Page 6 of 7
Licence: 13415Company Name: THE CAMPERDOWN COMPOST COMPANY PTY LTD
ACN: 108 839 363Premises Address: Blind Creek RD, BOOKAAR VIC 3260
Issued: 11/04/2008Last Amended: 20/08/2014
Before relying on the information in this map, users should carefully evaluate its accuracy, currency, completeness and relevance for their purposes, and should obtain any appropriate professional advice relevant to their particular circumstances.
SCHEDULE 1B - PREMISES PLAN
SECTION 20 LICENCE
Licence: 13415 Last Amended: 20/08/2014 Page 7 of 7
SCHEDULE 2 - WASTE ACCEPTANCE TABLES
Prescribed Waste Acceptance and Treatment Types
Waste Code Waste Description Treatment Code
Treatment Description
K100 Animal effluent and residues. Examples: abattoir wastes, poultry wastes, fish and shellfish wastes
R16 Composting
K120 Grease interceptor trap effluent R16 CompostingK200 Food and beverage processing wastes,
including animal and vegetable oils and derivatives
R16 Composting
L100 Car and truck washwaters R16 CompostingL150 Industrial washwaters from cleaning,
rinsing or washing operations, NOS. Examples: textile cleaning/processing effluent NOS, industrial plant and machinery washwaters, cooling tower washwaters
R16 Composting
N150 Fly ash R16 CompostingN190 Filter cake R16 CompostingT130 Inert sludges or slurries, such as clay or
ceramic suspensions, drilling mud, and pit water with negligible hydrocarbon contamination
R16 Composting
Compost Waste Acceptance Types
Waste DescriptionHard green wastesMunicipal green waste
Appendix B
Appendix C
Appendix D
SESL$AUSTRALIA$PTY$LTD CAMPERDOWN$COMPOST$PURGING$FIELD$SHEET [15TH$MARCH$2017]
Copyright$iEnvironmental$Australia.$$$$iEnvironmental$Field$Data$Groundwater$Quality$Sheets$v1.0.$$$$$$$ $$$$MW3$$$$$$Page$1$of$3$
PURGING'FIELD,WATER,QUALITY,MEASUREMENTS,FORM Sampled,By: Andrew$JacovidesRepair,Actions,and,
notes:
WELL,ID: DATE: Photo,of,Well,Head Photo,of,First,Bail
Depth,of,Well: 7.793 mBTOC Sample,Depth: 6.5 mBTOCSample,
Method:
Quality,Samples:
Location: Camperdown$Compost Ref:Well,
Condition:
Well,
radius(m):0.025
QAQC1
Clock,TimeWater,
DepthPurge,Rate
Volume,
PurgedSpec.,Cond.1 ORP/Eh2 DO Turbidity
24,HR m L/min litres µS/cm mv mg/L NTU,/,Desriptive
01:06 3.013
13:30 3.628 7 23.9 6.69
13:35 3.623 5 2 23.3 6.70 2.23
13:45 3.632 10 4 22.8 11360 2.37
13:56 3.634 11 4 23.3 11346 2.31
14:01 3.634 5 2 23.3 11295 2.31
1$x$well$volume= 9.4 litres TOTAL,PURGED 19 0.5 0.6% 0.00 0.0 0.06 Stable
±$0.5$o$Celsius ±$3% ±$0.1$standard$
units*
±$10$millivolts ±$0.3$
milligrams$per$
litre
1.$µSiemens$per$cm(same$as$µmhos/cm)at$25$$$C.2.$Oxidation$reduction$potential$(stand$in$for$Eh).*$The$±$0.1$may$not$always$be$obtainable,$especially$if$purging$and$sampling$with$bailers.$Therefore,$professional$judgement$may$be$needed.
**Visual$inspection$may$be$used$to$validate$turbidity,$and$professional$judgement$may$be$needed$to$indicate$if$turbidity$is$clear$or$stable
milky$colour
MW3 1'Mar'17
Micropurge
good
MinutesTemp.
CpH Comments,[H,odour,=,hydrocarbon,
odour;,sl,=,slight(ly)]
Guaging
Stabilisation$Criteria$for$3$consecutive$readings:$$(Yeskis$and$Zavala,$2002) ±$10%$(when$>$10$NTUs)
maintained$at$<$10$NTUs,$consider$stabilised**
Milky$colour
Clear
Clear
Clear
`
<lll$3$Readings$Variance
SESL$AUSTRALIA$PTY$LTD Camperdown$Compost$Purging$Field$Sheet$(1)$0.2.xlsx [15TH$MARCH$2017]
Copyright$iEnvironmental$Australia.$$$$iEnvironmental$Field$Data$Groundwater$Quality$Sheets$v1.0.$$$$$$$ $$$$MW1$$$$$$Page$2$of$3$
PURGING'FIELD,WATER,QUALITY,MEASUREMENTS,FORM Sampled,By: Andrew$JacovidesRepair,Actions,and,
notes:
WELL,ID: DATE: Photo,of,Well,Head Photo,of,First,Bail
Depth,of,Well: 9.710 mBTOC Sample,Depth: 8.5 mBTOC Sample,
Method:
Quality,Samples:
Location: Camperdown$Compost Ref:Well,
Condition:
Well,
radius(m):0.025
l
Clock,TimeWater,
DepthPurge,Rate
Volume,
PurgedSpec.,Cond.1 ORP/Eh2 DO Turbidity
24,HR m L/min litres µS/cm mv mg/L NTU,/,Desriptive
2.985
14:50 3.095 1 17.9 5319 7.48 l87.9 2.79
15:05 3.094 15 8 17.3 5168 6.99 l78.4 2.00
13:10 3.094 5 3 17.2 5154 6.88 l89.9 2.57
13:20 3.095 10 6 17.7 5214 6.90 l98.8 2.01
13:25 3.095 5 3 17.3 5165 6.94 l103.6 1.99
13:30 3.095 5 3 17.3 5166 6.93 l107.2 1.96
13:35 3.095 5 3 17.2 5161 6.95 l110.0 1.92
17:02
1$x$well$volume= 13.2 litres TOTAL,PURGED 27 0.1 0.1% 0.02 6.4 0.07 Stable
±$0.5$o$Celsius ±$3% ±$0.1$standard$units*
±$10$millivolts ±$0.3$milligrams$per$
litre
1.$µSiemens$per$cm(same$as$µmhos/cm)at$25$$$C.2.$Oxidation$reduction$potential$(stand$in$for$Eh).*$The$±$0.1$may$not$always$be$obtainable,$especially$if$purging$and$sampling$with$bailers.$Therefore,$professional$judgement$may$be$needed.
**Visual$inspection$may$be$used$to$validate$turbidity,$and$professional$judgement$may$be$needed$to$indicate$if$turbidity$is$clear$or$stable
Muddy$brown
MW1 1'Mar'17
Micropurge
Good
MinutesTemp.
CpH Comments,[H,odour,=,hydrocarbon,
odour;,sl,=,slight(ly)]
Guaging
Stabilisation$Criteria$for$3$consecutive$readings:$$(Yeskis$and$Zavala,$2002) ±$10%$(when$>$10$NTUs)maintained$at$<$10$NTUs,$consider$stabilised**
Muddy$brown,$clearer$than$above
Slight$brown,$clearer$than$above
Clear/Brown
Clear/brown
Clear/brown
Clear/Brown.$Sample$Collected
<lll$3$Readings$Variance
SESL$AUSTRALIA$PTY$LTD Camperdown$Compost$Purging$Field$Sheet$(1)$0.2.xlsx [15TH$MARCH$2017]
Copyright$iEnvironmental$Australia.$$$$iEnvironmental$Field$Data$Groundwater$Quality$Sheets$v1.0.$$$$$$$ $$$$MW2$$$$$$Page$3$of$3$
PURGING'FIELD,WATER,QUALITY,MEASUREMENTS,FORM Sampled,By: Andrew$JacovidesRepair,Actions,and,
notes:
WELL,ID: DATE: Photo,of,Well,Head Photo,of,First,Bail
Depth,of,Well: 7.830 mBTOC Sample,Depth: 6.5 mBTOC Sample,
Method:
Quality,Samples:
Location: Camperdown$Compost Ref:Well,
Condition:
Well,
radius(m):0.025
l
Clock,TimeWater,
DepthPurge,Rate
Volume,
PurgedSpec.,Cond.1 ORP/Eh2 DO Turbidity
24,HR m L/min litres µS/cm mv mg/L NTU,/,Desriptive
15:57 3.115
16:05 0 18.5 6853 7.49 l84.4 2.70
16:17 3.680 17 5 18.4 6910 7.28 l117.4 0.16
16:22 3.675 1.5 18.5 6916 7.26 l117.2 0.12
16:27 3.685 1.5 18.8 6989 7.25 l121.9 0.53
16:32 3.680 1.5 18.6 7069 7.26 l130.8 0.95
16:37 3.685 1.5 18.3 6865 7.32 l140.1 1.09
16:42 18.1 6881 7.34 l139.2 1.14
1$x$well$volume= 9.3 litres TOTAL,PURGED 11 0.5 3.0% 0.07 18.2 0.56 Not$Stable
±$0.5$o$Celsius ±$3% ±$0.1$standard$units*
±$10$millivolts ±$0.3$milligrams$per$
litre
1.$µSiemens$per$cm(same$as$µmhos/cm)at$25$$$C.2.$Oxidation$reduction$potential$(stand$in$for$Eh).*$The$±$0.1$may$not$always$be$obtainable,$especially$if$purging$and$sampling$with$bailers.$Therefore,$professional$judgement$may$be$needed.
**Visual$inspection$may$be$used$to$validate$turbidity,$and$professional$judgement$may$be$needed$to$indicate$if$turbidity$is$clear$or$stable
Initial$Reading
MW2 1'Mar'17
Micropurge
Good
MinutesTemp.
CpH Comments,[H,odour,=,hydrocarbon,
odour;,sl,=,slight(ly)]
Guaging
Stabilisation$Criteria$for$3$consecutive$readings:$$(Yeskis$and$Zavala,$2002) ±$10%$(when$>$10$NTUs)maintained$at$<$10$NTUs,$consider$stabilised**
Brown/Pinky$(see$photo)
Brown/Pinky$(see$photo)
Brown,$clearing
Brown/Clear
`
Brown/Clear
<lll$3$Readings$Variance
Appendix E
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 9EM1702381
:Amendment 1:: LaboratoryClient SESL Australia Pty Ltd Environmental Division Melbourne
: :ContactContact MR RYAN JACKA:: AddressAddress PO BOX 357
PENNANT HILLS NSW, AUSTRALIA 17154 Westall Rd Springvale VIC Australia 3171
:Telephone +61 02 9980 6554 :Telephone +61-3-8549 9600:Project Camperdown Groundwater Date Samples Received : 03-Mar-2017 09:25:Order number ---- Date Analysis Commenced : 03-Mar-2017:C-O-C number ---- Issue Date : 16-May-2017 14:05
Sampler : ANDREW JACOVIDESSite : ----Quote number : SYBQ/259/16
5:No. of samples received
5:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:l General Commentsl Analytical Resultsl Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.Signatories Accreditation CategoryPosition
Chris Lemaitre Non-Metals Team Leader Melbourne Inorganics, Springvale, VICDilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VICNancy Wang Senior Semivolatile Instrument Chemist Melbourne Organics, Springvale, VICSamantha Smith Senior Project Manager WRG Subcontracting, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
2 of 9:Page
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:Client
EM1702381 Amendment 1
Camperdown Groundwater:Project
SESL Australia Pty Ltd
General CommentsThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
Amendment (16/05/2017): This report has been amended as a result of a request to change sample identification numbers (IDs) received by ALS from S.Grant-Vest on 16/05/2017. All analysis results are as per
the previous report.
l
Ionic balances were calculated using: major anions - chloride, alkalinity and sulfate; and major cations - calcium, magnesium, potassium and sodium.l
ED045G: The presence of thiocyanate can positively contribute to the chloride result, thereby may bias results higher than expected. Results should be scrutinised accordingly.l
EA016: Calculated TDS is determined from Electrical conductivity using a conversion factor of 0.65.l
Salmonella - VIDAS (MM625) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989.l
Benzo(a)pyrene Toxicity Equivalent Quotient (TEQ) is the sum total of the concentration of the eight carcinogenic PAHs multiplied by their Toxicity Equivalence Factor (TEF) relative to Benzo(a)pyrene. TEF values
are provided in brackets as follows: Benz(a)anthracene (0.1), Chrysene (0.01), Benzo(b+j) & Benzo(k)fluoranthene (0.1), Benzo(a)pyrene (1.0), Indeno(1.2.3.cd)pyrene (0.1), Dibenz(a.h)anthracene (1.0),
Benzo(g.h.i)perylene (0.01). Less than LOR results for 'TEQ Zero' are treated as zero.
l
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Analytical ResultsRB1QAQC1MW1MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702381-005EM1702381-004EM1702381-003EM1702381-002EM1702381-001UnitLORCAS NumberCompoundResult Result Result Result Result
EA005P: pH by PC Titrator7.81 7.80 7.96 7.86 ----pH Unit0.01----pH Value
EA006: Sodium Adsorption Ratio (SAR)19.0 11.6 21.9 19.0 -----0.01----Sodium Adsorption Ratio
EA010P: Conductivity by PC Titrator14400 7280 9420 14400 ----µS/cm1----Electrical Conductivity @ 25°C
EA016: Calculated TDS (from Electrical Conductivity)9360 4730 6120 9360 ----mg/L1----Total Dissolved Solids (Calc.)
EA065: Total Hardness as CaCO31900 1040 752 1860 ----mg/L1----Total Hardness as CaCO3
ED037P: Alkalinity by PC Titrator<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 ----mg/L1DMO-210-001<1Carbonate Alkalinity as CaCO3 <1 <1 <1 ----mg/L13812-32-6698Bicarbonate Alkalinity as CaCO3 532 559 705 ----mg/L171-52-3698 532 559 705 ----mg/L1----Total Alkalinity as CaCO3
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA191Sulfate as SO4 - Turbidimetric 73 166 192 ----mg/L114808-79-8
ED045G: Chloride by Discrete Analyser3970Chloride 1770 2450 4040 ----mg/L116887-00-6
ED093F: Dissolved Major Cations150Calcium 111 54 146 ----mg/L17440-70-2370Magnesium 185 150 362 ----mg/L17439-95-41900Sodium 861 1380 1880 ----mg/L17440-23-5
9Potassium 8 5 9 ----mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS<0.001Arsenic <0.001 <0.001 <0.001 ----mg/L0.0017440-38-2
<0.0001Cadmium 0.0001 <0.0001 <0.0001 ----mg/L0.00017440-43-9<0.001Chromium <0.001 <0.001 <0.001 ----mg/L0.0017440-47-30.002Copper <0.001 <0.001 0.002 ----mg/L0.0017440-50-8
<0.001Lead <0.001 <0.001 <0.001 ----mg/L0.0017439-92-10.014Nickel 0.009 0.008 0.014 ----mg/L0.0017440-02-00.011Zinc 0.009 0.011 0.009 ----mg/L0.0057440-66-6
EG020T: Total Metals by ICP-MS----Arsenic ---- ---- ---- <0.001mg/L0.0017440-38-2
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Analytical ResultsRB1QAQC1MW1MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702381-005EM1702381-004EM1702381-003EM1702381-002EM1702381-001UnitLORCAS NumberCompoundResult Result Result Result Result
EG020T: Total Metals by ICP-MS - Continued----Cadmium ---- ---- ---- <0.0001mg/L0.00017440-43-9----Chromium ---- ---- ---- <0.001mg/L0.0017440-47-3----Copper ---- ---- ---- <0.001mg/L0.0017440-50-8----Nickel ---- ---- ---- <0.001mg/L0.0017440-02-0----Lead ---- ---- ---- <0.001mg/L0.0017439-92-1----Zinc ---- ---- ---- <0.005mg/L0.0057440-66-6
EG035F: Dissolved Mercury by FIMS<0.0001Mercury <0.0001 <0.0001 <0.0001 ----mg/L0.00017439-97-6
EG035T: Total Recoverable Mercury by FIMS----Mercury ---- ---- ---- <0.0001mg/L0.00017439-97-6
EK040P: Fluoride by PC Titrator1.1Fluoride 0.9 1.2 1.1 ----mg/L0.116984-48-8
EK055G: Ammonia as N by Discrete Analyser0.02Ammonia as N <0.01 0.01 0.03 ----mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser0.02Nitrite as N <0.01 0.58 0.02 ----mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser44.5Nitrate as N 0.08 24.1 44.8 ----mg/L0.0114797-55-8
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser44.5 0.08 24.7 44.8 ----mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser2.1 <0.1 1.0 1.9 ----mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser46.6^ <0.1 25.7 46.7 ----mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser0.02 0.10 0.05 0.02 ----mg/L0.01----Total Phosphorus as P
EK071G: Reactive Phosphorus as P by discrete analyser0.02Reactive Phosphorus as P 0.04 0.01 0.01 ----mg/L0.0114265-44-2
EN055: Ionic Balance130 62.1 83.7 132 ----meq/L0.01----Total Anions121 58.4 75.2 119 ----meq/L0.01----Total Cations3.63 3.04 5.37 5.16 ----%0.01----Ionic Balance
EP005: Total Organic Carbon (TOC)
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Analytical ResultsRB1QAQC1MW1MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702381-005EM1702381-004EM1702381-003EM1702381-002EM1702381-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP005: Total Organic Carbon (TOC) - Continued
6 <1 8 7 ----mg/L1----Total Organic Carbon
EP006 Total Inorganic Carbon150 112 118 150 ----mg/L1----Total Inorganic Carbon
EP007 Total Carbon156Total Carbon 112 127 156 ----mg/L1TC
EP066: Polychlorinated Biphenyls (PCB)<1 <1 <1 <1 ----µg/L1----Total Polychlorinated biphenyls
EP068A: Organochlorine Pesticides (OC)<0.5alpha-BHC <0.5 <0.5 <0.5 ----µg/L0.5319-84-6<0.5Hexachlorobenzene (HCB) <0.5 <0.5 <0.5 ----µg/L0.5118-74-1<0.5beta-BHC <0.5 <0.5 <0.5 ----µg/L0.5319-85-7<0.5gamma-BHC <0.5 <0.5 <0.5 ----µg/L0.558-89-9<0.5delta-BHC <0.5 <0.5 <0.5 ----µg/L0.5319-86-8<0.5Heptachlor <0.5 <0.5 <0.5 ----µg/L0.576-44-8<0.5Aldrin <0.5 <0.5 <0.5 ----µg/L0.5309-00-2<0.5Heptachlor epoxide <0.5 <0.5 <0.5 ----µg/L0.51024-57-3<0.5trans-Chlordane <0.5 <0.5 <0.5 ----µg/L0.55103-74-2<0.5alpha-Endosulfan <0.5 <0.5 <0.5 ----µg/L0.5959-98-8<0.5cis-Chlordane <0.5 <0.5 <0.5 ----µg/L0.55103-71-9<0.5Dieldrin <0.5 <0.5 <0.5 ----µg/L0.560-57-1<0.54.4`-DDE <0.5 <0.5 <0.5 ----µg/L0.572-55-9<0.5Endrin <0.5 <0.5 <0.5 ----µg/L0.572-20-8<0.5beta-Endosulfan <0.5 <0.5 <0.5 ----µg/L0.533213-65-9<0.54.4`-DDD <0.5 <0.5 <0.5 ----µg/L0.572-54-8<0.5Endrin aldehyde <0.5 <0.5 <0.5 ----µg/L0.57421-93-4<0.5Endosulfan sulfate <0.5 <0.5 <0.5 ----µg/L0.51031-07-8<2.04.4`-DDT <2.0 <2.0 <2.0 ----µg/L250-29-3<0.5Endrin ketone <0.5 <0.5 <0.5 ----µg/L0.553494-70-5<2.0Methoxychlor <2.0 <2.0 <2.0 ----µg/L272-43-5<0.5^ <0.5 <0.5 <0.5 ----µg/L0.5----Total Chlordane (sum)
<0.5^ Sum of DDD + DDE + DDT <0.5 <0.5 <0.5 ----µg/L0.572-54-8/72-55-9/50-2
<0.5^ Sum of Aldrin + Dieldrin <0.5 <0.5 <0.5 ----µg/L0.5309-00-2/60-57-1
EP068B: Organophosphorus Pesticides (OP)
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Analytical ResultsRB1QAQC1MW1MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702381-005EM1702381-004EM1702381-003EM1702381-002EM1702381-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP068B: Organophosphorus Pesticides (OP) - Continued<0.5Dichlorvos <0.5 <0.5 <0.5 ----µg/L0.562-73-7<0.5Demeton-S-methyl <0.5 <0.5 <0.5 ----µg/L0.5919-86-8<2.0Monocrotophos <2.0 <2.0 <2.0 ----µg/L26923-22-4<0.5Dimethoate <0.5 <0.5 <0.5 ----µg/L0.560-51-5<0.5Diazinon <0.5 <0.5 <0.5 ----µg/L0.5333-41-5<0.5Chlorpyrifos-methyl <0.5 <0.5 <0.5 ----µg/L0.55598-13-0<2.0Parathion-methyl <2.0 <2.0 <2.0 ----µg/L2298-00-0<0.5Malathion <0.5 <0.5 <0.5 ----µg/L0.5121-75-5<0.5Fenthion <0.5 <0.5 <0.5 ----µg/L0.555-38-9<0.5Chlorpyrifos <0.5 <0.5 <0.5 ----µg/L0.52921-88-2<2.0Parathion <2.0 <2.0 <2.0 ----µg/L256-38-2<0.5Pirimphos-ethyl <0.5 <0.5 <0.5 ----µg/L0.523505-41-1<0.5Chlorfenvinphos <0.5 <0.5 <0.5 ----µg/L0.5470-90-6<0.5Bromophos-ethyl <0.5 <0.5 <0.5 ----µg/L0.54824-78-6<0.5Fenamiphos <0.5 <0.5 <0.5 ----µg/L0.522224-92-6<0.5Prothiofos <0.5 <0.5 <0.5 ----µg/L0.534643-46-4<0.5Ethion <0.5 <0.5 <0.5 ----µg/L0.5563-12-2<0.5Carbophenothion <0.5 <0.5 <0.5 ----µg/L0.5786-19-6<0.5Azinphos Methyl <0.5 <0.5 <0.5 ----µg/L0.586-50-0
EP071 SG: Total Petroleum Hydrocarbons - Silica gel cleanup<50 <50 <50 <50 ----µg/L50----C10 - C14 Fraction
<100 <100 <100 <100 ----µg/L100----C15 - C28 Fraction<50 <50 <50 <50 ----µg/L50----C29 - C36 Fraction<50^ <50 <50 <50 ----µg/L50----C10 - C36 Fraction (sum)
EP071 SG: Total Recoverable Hydrocarbons - NEPM 2013 Fractions - Silica gel cleanup<100 <100 <100 <100 ----µg/L100---->C10 - C16 Fraction<100 <100 <100 <100 ----µg/L100---->C16 - C34 Fraction<100 <100 <100 <100 ----µg/L100---->C34 - C40 Fraction<100^ <100 <100 <100 ----µg/L100---->C10 - C40 Fraction (sum)<100 <100 <100 <100 ----µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons<1.0Naphthalene <1.0 <1.0 <1.0 ----µg/L191-20-3<1.0Acenaphthylene <1.0 <1.0 <1.0 ----µg/L1208-96-8
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Analytical ResultsRB1QAQC1MW1MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702381-005EM1702381-004EM1702381-003EM1702381-002EM1702381-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued<1.0Acenaphthene <1.0 <1.0 <1.0 ----µg/L183-32-9<1.0Fluorene <1.0 <1.0 <1.0 ----µg/L186-73-7<1.0Phenanthrene <1.0 <1.0 <1.0 ----µg/L185-01-8<1.0Anthracene <1.0 <1.0 <1.0 ----µg/L1120-12-7<1.0Fluoranthene <1.0 <1.0 <1.0 ----µg/L1206-44-0<1.0Pyrene <1.0 <1.0 <1.0 ----µg/L1129-00-0<1.0Benz(a)anthracene <1.0 <1.0 <1.0 ----µg/L156-55-3<1.0Chrysene <1.0 <1.0 <1.0 ----µg/L1218-01-9<1.0Benzo(b+j)fluoranthene <1.0 <1.0 <1.0 ----µg/L1205-99-2 205-82-3<1.0Benzo(k)fluoranthene <1.0 <1.0 <1.0 ----µg/L1207-08-9<0.5Benzo(a)pyrene <0.5 <0.5 <0.5 ----µg/L0.550-32-8<1.0Indeno(1.2.3.cd)pyrene <1.0 <1.0 <1.0 ----µg/L1193-39-5<1.0Dibenz(a.h)anthracene <1.0 <1.0 <1.0 ----µg/L153-70-3<1.0Benzo(g.h.i)perylene <1.0 <1.0 <1.0 ----µg/L1191-24-2<0.5^ <0.5 <0.5 <0.5 ----µg/L0.5----Sum of polycyclic aromatic hydrocarbons<0.5^ <0.5 <0.5 <0.5 ----µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons<20 <20 <20 <20 <20µg/L20----C6 - C9 Fraction
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions<20C6 - C10 Fraction <20 <20 <20 <20µg/L20C6_C10<20^ C6 - C10 Fraction minus BTEX
(F1)<20 <20 <20 <20µg/L20C6_C10-BTEX
EP080: BTEXN<1Benzene <1 <1 <1 <1µg/L171-43-2<2Toluene <2 <2 <2 <2µg/L2108-88-3<2Ethylbenzene <2 <2 <2 <2µg/L2100-41-4<2meta- & para-Xylene <2 <2 <2 <2µg/L2108-38-3 106-42-3<2ortho-Xylene <2 <2 <2 <2µg/L295-47-6<2^ Total Xylenes <2 <2 <2 <2µg/L21330-20-7<1^ <1 <1 <1 <1µg/L1----Sum of BTEX<5Naphthalene <5 <5 <5 <5µg/L591-20-3
MM527: Legionella in Water<10Legionella Pneumophila
Serogroup 1<10 <10 <10 ----CFU/mL10LEGIONELLA_SG1
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Analytical ResultsRB1QAQC1MW1MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702381-005EM1702381-004EM1702381-003EM1702381-002EM1702381-001UnitLORCAS NumberCompoundResult Result Result Result Result
MM527: Legionella in Water - Continued
<10Legionella Pneumophila
Serogroup 2-14
<10 <10 <10 ----CFU/mL10LEGIONELLA_SG2
<10 <10 <10 <10 ----CFU/mL10----Legionella Species
MM540: E.coli & Faecal Coliforms by MF<10 <10 <10 <10 ----orgs/100mL1----Faecal Coliforms
MM540: E.coli & Faecal Coliforms by MF (clean water)<10 <10 <10 <10 ----orgs/100mL1----Escherichia coli
MM625: Salmonella - VIDAS (absence / presence)Not Detected Not Detected Not Detected Not Detected ----------Salmonella spp.
EP066S: PCB Surrogate70.4Decachlorobiphenyl 72.8 71.2 54.9 ----%12051-24-3
EP068S: Organochlorine Pesticide Surrogate70.3Dibromo-DDE 70.4 68.8 53.0 ----%0.521655-73-2
EP068T: Organophosphorus Pesticide Surrogate52.6DEF 52.4 55.0 63.4 ----%0.578-48-8
EP075(SIM)S: Phenolic Compound Surrogates10.1Phenol-d6 24.6 25.8 23.7 ----%113127-88-332.62-Chlorophenol-D4 59.1 64.6 51.2 ----%193951-73-661.12.4.6-Tribromophenol 64.8 60.0 51.4 ----%1118-79-6
EP075(SIM)T: PAH Surrogates80.12-Fluorobiphenyl 78.4 82.0 64.0 ----%1321-60-882.1Anthracene-d10 84.9 84.8 68.3 ----%11719-06-878.24-Terphenyl-d14 81.1 80.0 62.4 ----%11718-51-0
EP080S: TPH(V)/BTEX Surrogates87.81.2-Dichloroethane-D4 89.0 94.2 92.2 89.5%217060-07-091.0Toluene-D8 92.6 96.9 94.6 95.5%22037-26-51044-Bromofluorobenzene 103 108 104 107%2460-00-4
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Surrogate Control LimitsRecovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP066S: PCB SurrogateDecachlorobiphenyl 2051-24-3 41 125
EP068S: Organochlorine Pesticide SurrogateDibromo-DDE 21655-73-2 49 117
EP068T: Organophosphorus Pesticide SurrogateDEF 78-48-8 51 127
EP075(SIM)S: Phenolic Compound SurrogatesPhenol-d6 13127-88-3 10 462-Chlorophenol-D4 93951-73-6 23 1042.4.6-Tribromophenol 118-79-6 28 130
EP075(SIM)T: PAH Surrogates2-Fluorobiphenyl 321-60-8 36 114Anthracene-d10 1719-06-8 51 1194-Terphenyl-d14 1718-51-0 49 127
EP080S: TPH(V)/BTEX Surrogates1.2-Dichloroethane-D4 17060-07-0 73 129Toluene-D8 2037-26-5 70 1254-Bromofluorobenzene 460-00-4 71 129
False
4 4.00True
Environmental
QUALITY CONTROL REPORTWork Order : EM1702381 Page : 1 of 11
:Amendment 1
:: LaboratoryClient Environmental Division MelbourneSESL Australia Pty Ltd:Contact MR RYAN JACKA :Contact:Address PO BOX 357
PENNANT HILLS NSW, AUSTRALIA 1715Address : 4 Westall Rd Springvale VIC Australia 3171
::Telephone +61 02 9980 6554 +61-3-8549 9600:Telephone
:Project Camperdown Groundwater Date Samples Received : 03-Mar-2017:Order number ---- Date Analysis Commenced : 03-Mar-2017
:C-O-C number ---- Issue Date : 16-May-2017Sampler : ANDREW JACOVIDESSite : ----Quote number : SYBQ/259/16No. of samples received 5:No. of samples analysed 5:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limitsl Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limitsl Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.Signatories Accreditation CategoryPosition
Chris Lemaitre Non-Metals Team Leader Melbourne Inorganics, Springvale, VICDilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VICNancy Wang Senior Semivolatile Instrument Chemist Melbourne Organics, Springvale, VICSamantha Smith Senior Project Manager WRG Subcontracting, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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General CommentsThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lotCAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society. LOR = Limit of reporting RPD = Relative Percentage Difference# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) ReportThe quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR: No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA005P: pH by PC Titrator (QC Lot: 779010)EA005-P: pH Value ---- 0.01 pH Unit 6.73 6.60 1.95 0% - 20%Anonymous EM1702345-005
EA005-P: pH Value ---- 0.01 pH Unit 7.80 7.77 0.385 0% - 20%MW3 EM1702381-002
EA010P: Conductivity by PC Titrator (QC Lot: 779011)EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm 7280 7350 0.920 0% - 20%MW3 EM1702381-002
ED037P: Alkalinity by PC Titrator (QC Lot: 779009)ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM1702342-011
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 971 971 0.00 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 971 971 0.00 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM1702345-005
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 214 216 0.962 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 214 216 0.962 0% - 20%
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QC Lot: 777208)ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 92 91 0.00 0% - 20%Anonymous EM1702344-008
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 11 12 0.00 0% - 50%Anonymous EM1702335-003
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QC Lot: 777211)ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 166 164 1.31 0% - 20%MW1 EM1702381-003
ED045G: Chloride by Discrete Analyser (QC Lot: 777207)ED045G: Chloride 16887-00-6 1 mg/L 3970 4040 1.81 0% - 20%MW2 EM1702381-001
ED045G: Chloride 16887-00-6 1 mg/L 35 37 3.42 0% - 20%Anonymous EM1702335-003
ED093F: Dissolved Major Cations (QC Lot: 777824)ED093F: Calcium 7440-70-2 1 mg/L 97 95 1.75 0% - 20%Anonymous EM1702335-003
ED093F: Magnesium 7439-95-4 1 mg/L 4 4 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
ED093F: Dissolved Major Cations (QC Lot: 777824) - continued
ED093F: Sodium 7440-23-5 1 mg/L 18 18 0.00 0% - 50%Anonymous EM1702335-003
ED093F: Potassium 7440-09-7 1 mg/L <1 <1 0.00 No Limit
ED093F: Calcium 7440-70-2 1 mg/L 1 <1 0.00 No LimitAnonymous EM1702352-001
ED093F: Magnesium 7439-95-4 1 mg/L 11 11 0.00 0% - 50%
ED093F: Sodium 7440-23-5 1 mg/L 111 113 1.43 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 1 1 0.00 No Limit
EG020F: Dissolved Metals by ICP-MS (QC Lot: 777823)
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L 0.0002 <0.0001 0.00 No LimitAnonymous EM1702335-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.010 0.010 0.00 0% - 50%
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.028 0.028 0.00 No Limit
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702342-011
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.010 0.010 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.024 0.025 5.10 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 778578)
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L 0.0005 0.0004 35.0 No LimitAnonymous EM1702297-002
EG020A-T: Arsenic 7440-38-2 0.001 mg/L 0.005 0.005 0.00 No Limit
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-T: Lead 7439-92-1 0.001 mg/L 0.011 0.011 0.00 0% - 50%
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.006 0.006 0.00 No Limit
EG020A-T: Zinc 7440-66-6 0.005 mg/L 0.102 0.106 3.27 0% - 20%
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702411-076
EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG035F: Dissolved Mercury by FIMS (QC Lot: 777825)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitQAQC1 EM1702381-004
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702352-001
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG035T: Total Recoverable Mercury by FIMS (QC Lot: 778485)
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702313-012
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702389-004
EK040P: Fluoride by PC Titrator (QC Lot: 779007)
EK040P: Fluoride 16984-48-8 0.1 mg/L 0.1 0.1 0.00 No LimitAnonymous EM1702345-005
EK040P: Fluoride 16984-48-8 0.1 mg/L 0.9 0.9 0.00 No LimitMW3 EM1702381-002
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 777445)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 58.5 65.8 11.8 0% - 20%Anonymous EM1702313-012
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.03 0.03 0.00 No LimitQAQC1 EM1702381-004
EK057G: Nitrite as N by Discrete Analyser (QC Lot: 777209)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EM1702352-001
EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.02 0.02 0.00 No LimitMW2 EM1702381-001
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 777446)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.01 0.01 0.00 No LimitAnonymous EM1702375-003
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 44.8 49.4 9.85 0% - 20%QAQC1 EM1702381-004
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 777269)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.4 0.6 27.8 No LimitAnonymous EM1702352-005
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 0.3 91.0 No LimitAnonymous EM1702352-001
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 777271)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 1.9 1.8 6.29 0% - 50%QAQC1 EM1702381-004
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 777270)
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.02 0.04 54.1 No LimitAnonymous EM1702352-005
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.03 0.03 0.00 No LimitAnonymous EM1702352-001
EK071G: Reactive Phosphorus as P by discrete analyser (QC Lot: 777210)
EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L 0.02 0.02 0.00 No LimitMW2 EM1702381-001
EP005: Total Organic Carbon (TOC) (QC Lot: 779015)
EP005: Total Organic Carbon ---- 1 mg/L 28 30 8.24 0% - 20%Anonymous EM1702342-006
EP005: Total Organic Carbon ---- 1 mg/L 7 7 0.00 No LimitQAQC1 EM1702381-004
EP006 Total Inorganic Carbon (QC Lot: 780788)
EP006: Total Inorganic Carbon ---- 1 mg/L 150 151 0.864 0% - 20%MW2 EM1702381-001
EP007 Total Carbon (QC Lot: 780787)
EP007: Total Carbon TC 1 mg/L 156 154 0.967 0% - 20%MW2 EM1702381-001
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 778477)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitMW2 EM1702381-001
EP080: C6 - C9 Fraction ---- 20 µg/L 4660 4830 3.57 0% - 20%Anonymous EM1702435-006
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 778477)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitMW2 EM1702381-001
EP080: C6 - C10 Fraction C6_C10 20 µg/L 4470 4620 3.40 0% - 20%Anonymous EM1702435-006
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP080: BTEXN (QC Lot: 778477)EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitMW2 EM1702381-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3 106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L 2950 2980 1.31 0% - 20%Anonymous EM1702435-006
EP080: Toluene 108-88-3 2 µg/L 49 50 2.26 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L 353 362 2.45 0% - 20%
EP080: meta- & para-Xylene 108-38-3 106-42-3
2 µg/L 642 649 1.12 0% - 20%
EP080: ortho-Xylene 95-47-6 2 µg/L 356 363 1.72 0% - 20%
EP080: Naphthalene 91-20-3 5 µg/L 36 38 5.16 No Limit
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Method Blank (MB) and Laboratory Control Spike (LCS) ReportThe quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA010P: Conductivity by PC Titrator (QCLot: 779011)EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm <1 1192000 µS/cm 12080
ED037P: Alkalinity by PC Titrator (QCLot: 779009)ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 101200 mg/L 11090
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 777208)ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 10425 mg/L 11592
<1 99.3100 mg/L 11592
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 777211)ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 10425 mg/L 11592
<1 100100 mg/L 11592
ED045G: Chloride by Discrete Analyser (QCLot: 777207)ED045G: Chloride 16887-00-6 1 mg/L <1 99.510 mg/L 11789
<1 1011000 mg/L 11292
ED093F: Dissolved Major Cations (QCLot: 777824)ED093F: Calcium 7440-70-2 1 mg/L <1 96.85 mg/L 10892
ED093F: Magnesium 7439-95-4 1 mg/L <1 97.25 mg/L 10892
ED093F: Sodium 7440-23-5 1 mg/L <1 98.250 mg/L 10789
ED093F: Potassium 7440-09-7 1 mg/L <1 98.850 mg/L 10789
EG020F: Dissolved Metals by ICP-MS (QCLot: 777823)EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 97.00.1 mg/L 10894
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 92.80.1 mg/L 10886
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 93.50.1 mg/L 11086
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 95.90.1 mg/L 10787
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 94.50.1 mg/L 10987
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 92.10.1 mg/L 10987
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 99.00.1 mg/L 10787
EG020T: Total Metals by ICP-MS (QCLot: 778578)EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 1030.1 mg/L 11394
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 98.40.1 mg/L 11088
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 94.60.1 mg/L 11287
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 94.60.1 mg/L 11287
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 98.30.1 mg/L 11388
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 1020.1 mg/L 11191
EG020A-T: Zinc 7440-66-6 0.005 mg/L <0.005 1050.1 mg/L 11288
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EG035F: Dissolved Mercury by FIMS (QCLot: 777825)EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 1020.01 mg/L 11788
EG035T: Total Recoverable Mercury by FIMS (QCLot: 778485)EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 92.90.01 mg/L 11387
EK040P: Fluoride by PC Titrator (QCLot: 779007)EK040P: Fluoride 16984-48-8 0.1 mg/L <0.1 92.45 mg/L 11285
EK055G: Ammonia as N by Discrete Analyser (QCLot: 777445)EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 98.01 mg/L 11580
EK057G: Nitrite as N by Discrete Analyser (QCLot: 777209)EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 1000.5 mg/L 10794
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 777446)EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1010.5 mg/L 11489
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 777269)EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 87.65 mg/L 11770
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 777271)EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 87.75 mg/L 11770
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 777270)EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 1012.21 mg/L 12070
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 777210)EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 1050.5 mg/L 10894
EP005: Total Organic Carbon (TOC) (QCLot: 779015)EP005: Total Organic Carbon ---- 1 mg/L <1 95.4100 mg/L 10981
EP006 Total Inorganic Carbon (QCLot: 780788)EP006: Total Inorganic Carbon ---- 1 mg/L <1 93.3100 mg/L 12080
EP007 Total Carbon (QCLot: 780787)EP007: Total Carbon TC 1 mg/L <1 91.9100 mg/L 11581
EP066: Polychlorinated Biphenyls (PCB) (QCLot: 778703)EP066: Total Polychlorinated biphenyls ---- 1 µg/L <1 84.610 µg/L 13254
EP068A: Organochlorine Pesticides (OC) (QCLot: 778700)EP068: alpha-BHC 319-84-6 0.5 µg/L <0.5 72.65 µg/L 12353
EP068: Hexachlorobenzene (HCB) 118-74-1 0.5 µg/L <0.5 69.75 µg/L 12047
EP068: beta-BHC 319-85-7 0.5 µg/L <0.5 72.65 µg/L 12752
EP068: gamma-BHC 58-89-9 0.5 µg/L <0.5 69.45 µg/L 12052
EP068: delta-BHC 319-86-8 0.5 µg/L <0.5 69.45 µg/L 12453
EP068: Heptachlor 76-44-8 0.5 µg/L <0.5 66.55 µg/L 12045
EP068: Aldrin 309-00-2 0.5 µg/L <0.5 70.15 µg/L 12246
EP068: Heptachlor epoxide 1024-57-3 0.5 µg/L <0.5 70.55 µg/L 12251
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP068A: Organochlorine Pesticides (OC) (QCLot: 778700) - continuedEP068: trans-Chlordane 5103-74-2 0.5 µg/L <0.5 57.35 µg/L 12548
EP068: alpha-Endosulfan 959-98-8 0.5 µg/L <0.5 70.05 µg/L 12648
EP068: cis-Chlordane 5103-71-9 0.5 µg/L <0.5 70.25 µg/L 12549
EP068: Dieldrin 60-57-1 0.5 µg/L <0.5 90.75 µg/L 12749
EP068: 4.4`-DDE 72-55-9 0.5 µg/L <0.5 69.05 µg/L 12449
EP068: Endrin 72-20-8 0.5 µg/L <0.5 67.25 µg/L 12545
EP068: beta-Endosulfan 33213-65-9 0.5 µg/L <0.5 69.45 µg/L 12950
EP068: 4.4`-DDD 72-54-8 0.5 µg/L <0.5 70.85 µg/L 12650
EP068: Endrin aldehyde 7421-93-4 0.5 µg/L <0.5 98.25 µg/L 12446
EP068: Endosulfan sulfate 1031-07-8 0.5 µg/L <0.5 87.75 µg/L 12549
EP068: 4.4`-DDT 50-29-3 2 µg/L <2.0 87.05 µg/L 12939
EP068: Endrin ketone 53494-70-5 0.5 µg/L <0.5 91.55 µg/L 11553
EP068: Methoxychlor 72-43-5 2 µg/L <2.0 87.05 µg/L 12336
EP068B: Organophosphorus Pesticides (OP) (QCLot: 778700)EP068: Dichlorvos 62-73-7 0.5 µg/L <0.5 1035 µg/L 11444
EP068: Demeton-S-methyl 919-86-8 0.5 µg/L <0.5 1075 µg/L 12444
EP068: Monocrotophos 6923-22-4 2 µg/L <2.0 # 71.85 µg/L 4110
EP068: Dimethoate 60-51-5 0.5 µg/L <0.5 60.95 µg/L 11443
EP068: Diazinon 333-41-5 0.5 µg/L <0.5 72.85 µg/L 12151
EP068: Chlorpyrifos-methyl 5598-13-0 0.5 µg/L <0.5 70.05 µg/L 12151
EP068: Parathion-methyl 298-00-0 ---- µg/L ---- # 57.85 µg/L 13070
EP068: Malathion 121-75-5 0.5 µg/L <0.5 74.05 µg/L 12951
EP068: Fenthion 55-38-9 0.5 µg/L <0.5 69.25 µg/L 12153
EP068: Chlorpyrifos 2921-88-2 0.5 µg/L <0.5 59.95 µg/L 12650
EP068: Parathion 56-38-2 2 µg/L <2.0 58.05 µg/L 13155
EP068: Pirimphos-ethyl 23505-41-1 0.5 µg/L <0.5 66.95 µg/L 12559
EP068: Chlorfenvinphos 470-90-6 0.5 µg/L <0.5 93.05 µg/L 12650
EP068: Bromophos-ethyl 4824-78-6 0.5 µg/L <0.5 66.25 µg/L 11948
EP068: Fenamiphos 22224-92-6 0.5 µg/L <0.5 55.15 µg/L 12745
EP068: Prothiofos 34643-46-4 0.5 µg/L <0.5 65.55 µg/L 12252
EP068: Ethion 563-12-2 0.5 µg/L <0.5 66.85 µg/L 12549
EP068: Carbophenothion 786-19-6 0.5 µg/L <0.5 87.75 µg/L 12650
EP068: Azinphos Methyl 86-50-0 0.5 µg/L <0.5 87.05 µg/L 13410
EP071 SG: Total Petroleum Hydrocarbons - Silica gel cleanup (QCLot: 778702)EP071SG: C10 - C14 Fraction ---- 50 µg/L <50 10352700 µg/L 14468
EP071SG: C15 - C28 Fraction ---- 100 µg/L <100 109101500 µg/L 13367
EP071SG: C29 - C36 Fraction ---- 50 µg/L <50 -------- --------
EP071SG: C10 - C36 Fraction (sum) ---- 50 µg/L <50 -------- --------
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP071 SG: Total Recoverable Hydrocarbons - NEPM 2013 Fractions - Silica gel cleanup (QCLot: 778702)EP071SG: >C10 - C16 Fraction ---- 100 µg/L <100 -------- --------
EP071SG: >C16 - C34 Fraction ---- 100 µg/L <100 -------- --------
EP071SG: >C34 - C40 Fraction ---- 100 µg/L <100 -------- --------
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 778701)EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 70.25 µg/L 11039
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 72.15 µg/L 12440
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 73.35 µg/L 11747
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 73.45 µg/L 11851
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 77.65 µg/L 11953
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 73.25 µg/L 11351
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 74.75 µg/L 12359
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 78.65 µg/L 12358
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 72.05 µg/L 12652
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 82.35 µg/L 12355
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2 205-82-3
1 µg/L <1.0 72.45 µg/L 13152
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 79.55 µg/L 12657
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 67.65 µg/L 12656
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 73.55 µg/L 12353
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 73.65 µg/L 12553
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 75.45 µg/L 12553
EP080/071: Total Petroleum Hydrocarbons (QCLot: 778477)EP080: C6 - C9 Fraction ---- 20 µg/L <20 97.8360 µg/L 12767
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 778477)EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 97.3450 µg/L 12565
EP080: BTEXN (QCLot: 778477)EP080: Benzene 71-43-2 1 µg/L <1 10520 µg/L 12076
EP080: Toluene 108-88-3 2 µg/L <2 10320 µg/L 12476
EP080: Ethylbenzene 100-41-4 2 µg/L <2 10620 µg/L 12472
EP080: meta- & para-Xylene 108-38-3 106-42-3
2 µg/L <2 10540 µg/L 13072
EP080: ortho-Xylene 95-47-6 2 µg/L <2 10320 µg/L 12878
EP080: Naphthalene 91-20-3 5 µg/L <5 94.15 µg/L 12971
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 777208)Anonymous EM1702339-006 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric # Not
Determined
10 mg/L 13070
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 777211)QAQC1 EM1702381-004 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric # Not
Determined
10 mg/L 13070
ED045G: Chloride by Discrete Analyser (QCLot: 777207)Anonymous EM1702352-001 16887-00-6ED045G: Chloride 107400 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 777823)Anonymous EM1702335-001 7440-38-2EG020A-F: Arsenic 92.10.2 mg/L 13185
7440-43-9EG020A-F: Cadmium 98.10.05 mg/L 13381
7440-47-3EG020A-F: Chromium 94.30.2 mg/L 13571
7440-50-8EG020A-F: Copper 91.80.2 mg/L 13076
7439-92-1EG020A-F: Lead 93.50.2 mg/L 13375
7440-02-0EG020A-F: Nickel 98.40.2 mg/L 13173
7440-66-6EG020A-F: Zinc 96.90.2 mg/L 13175
EG020T: Total Metals by ICP-MS (QCLot: 778578)Anonymous EM1702297-002 7440-38-2EG020A-T: Arsenic 1101 mg/L 11882
7440-43-9EG020A-T: Cadmium 1030.25 mg/L 12975
7440-47-3EG020A-T: Chromium 98.41 mg/L 11880
7440-50-8EG020A-T: Copper 1021 mg/L 11581
7439-92-1EG020A-T: Lead 1021 mg/L 12183
7440-02-0EG020A-T: Nickel 1061 mg/L 11880
7440-66-6EG020A-T: Zinc 1041 mg/L 11674
EG035F: Dissolved Mercury by FIMS (QCLot: 777825)Anonymous EM1702352-002 7439-97-6EG035F: Mercury 1010.01 mg/L 12070
EG035T: Total Recoverable Mercury by FIMS (QCLot: 778485)Anonymous EM1702313-013 7439-97-6EG035T: Mercury 89.70.01 mg/L 13070
EK040P: Fluoride by PC Titrator (QCLot: 779007)Anonymous EM1702345-002 16984-48-8EK040P: Fluoride 92.45 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 777445)Anonymous EM1702313-013 7664-41-7EK055G: Ammonia as N 98.51 mg/L 13070
EK057G: Nitrite as N by Discrete Analyser (QCLot: 777209)Anonymous EM1702352-002 14797-65-0EK057G: Nitrite as N 88.80.5 mg/L 11480
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 777446)Anonymous EM1702375-004 ----EK059G: Nitrite + Nitrate as N 71.80.5 mg/L 13070
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 777269)
Anonymous EM1702352-002 ----EK061G: Total Kjeldahl Nitrogen as N 88.25 mg/L 13070
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 777271)
Anonymous EM1702382-001 ----EK061G: Total Kjeldahl Nitrogen as N # Not
Determined
5 mg/L 13070
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 777270)
Anonymous EM1702352-002 ----EK067G: Total Phosphorus as P 1131 mg/L 13070
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 777210)
MW3 EM1702381-002 14265-44-2EK071G: Reactive Phosphorus as P 85.90.5 mg/L 12379
EP005: Total Organic Carbon (TOC) (QCLot: 779015)
Anonymous EM1702342-007 ----EP005: Total Organic Carbon 100100 mg/L 11480
EP006 Total Inorganic Carbon (QCLot: 780788)
MW3 EM1702381-002 ----EP006: Total Inorganic Carbon 75.650 mg/L 13070
EP007 Total Carbon (QCLot: 780787)
MW3 EM1702381-002 TCEP007: Total Carbon 74.8100 mg/L 13070
EP080/071: Total Petroleum Hydrocarbons (QCLot: 778477)
MW3 EM1702381-002 ----EP080: C6 - C9 Fraction 82.7280 µg/L 12543
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 778477)
MW3 EM1702381-002 C6_C10EP080: C6 - C10 Fraction 77.8330 µg/L 12244
EP080: BTEXN (QCLot: 778477)
MW3 EM1702381-002 71-43-2EP080: Benzene 10420 µg/L 13068
108-88-3EP080: Toluene 10420 µg/L 13272
True
Environmental
QA/QC Compliance Assessment to assist with Quality Review
Work Order : EM1702381 Page : 1 of 12
:Amendment 1
:: LaboratoryClient Environmental Division MelbourneSESL Australia Pty Ltd
:Contact MR RYAN JACKA Telephone : +61-3-8549 9600:Project Camperdown Groundwater Date Samples Received : 03-Mar-2017
Site : ---- Issue Date : 16-May-2017ANDREW JACOVIDES:Sampler No. of samples received : 5
:Order number ---- No. of samples analysed : 5
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of OutliersOutliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l Laboratory Control outliers exist - please see following pages for full details.
l Matrix Spike outliers exist - please see following pages for full details.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliancel Analysis Holding Time Outliers exist - please see following pages for full details.
Outliers : Frequency of Quality Control Samplesl Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Quality Control SamplesDuplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATERCompound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number
Laboratory Control Spike (LCS) Recoveries QC-778700-001 6923-22-4Monocrotophos---- Recovery greater than upper control
limit10-41%71.8 %EP068B: Organophosphorus Pesticides (OP)
QC-778700-001 298-00-0Parathion-methyl---- Recovery less than lower control limit70-130%57.8 %EP068B: Organophosphorus Pesticides (OP)
Matrix Spike (MS) Recoveries EM1702339--006 14808-79-8Sulfate as SO4 -
TurbidimetricAnonymous MS recovery not determined,
background level greater than or equal to 4x spike level.
----Not Determined
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
EM1702381--004 14808-79-8Sulfate as SO4 - Turbidimetric
QAQC1 MS recovery not determined, background level greater than or equal to 4x spike level.
----Not Determined
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
EM1702382--001 ----Total Kjeldahl Nitrogen as N
Anonymous MS recovery not determined, background level greater than or equal to 4x spike level.
----Not Determined
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
Outliers : Analysis Holding Time ComplianceMatrix: WATER
AnalysisExtraction / PreparationDate analysedDate extractedContainer / Client Sample ID(s) Days
overdueDays
overdueDue for extraction Due for analysis
Method
EA005P: pH by PC TitratorClear Plastic Bottle - Natural
01-Mar-2017----MW2, MW3,MW1, QAQC1
06-Mar-2017---- ---- 5
EP006 Total Inorganic CarbonClear Plastic Bottle - Natural
02-Mar-2017----MW2, MW3,MW1, QAQC1
07-Mar-2017---- ---- 5
EP007 Total CarbonClear Plastic Bottle - Natural
02-Mar-2017----MW2, MW3,MW1, QAQC1
07-Mar-2017---- ---- 5
Outliers : Frequency of Quality Control SamplesMatrix: WATER
Quality Control SpecificationQuality Control Sample TypeMethod ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP)NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 10.000 13NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 10.000 5NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 10.000 5
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Matrix: WATERQuality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP) - ContinuedNEPM 2013 B3 & ALS QC StandardTRH - Total Recoverable Hydrocarbons - Silica Gel C 0.00 10.000 4
Matrix Spikes (MS)NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 5.000 13NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 5.000 5NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 5.000 5NEPM 2013 B3 & ALS QC StandardTRH - Total Recoverable Hydrocarbons - Silica Gel C 0.00 5.000 4
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics 14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA005P: pH by PC TitratorClear Plastic Bottle - Natural (EA005-P)
MW2, MW3,MW1, QAQC1
01-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- û
EA006: Sodium Adsorption Ratio (SAR)Clear Plastic Bottle - Nitric Acid; Filtered (ED093F)
MW2, MW3,MW1, QAQC1
29-Mar-2017---- 07-Mar-2017----01-Mar-2017 ---- ü
EA010P: Conductivity by PC TitratorClear Plastic Bottle - Natural (EA010-P)
MW2, MW3,MW1, QAQC1
29-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EA065: Total Hardness as CaCO3Clear Plastic Bottle - Nitric Acid; Filtered (ED093F)
MW2, MW3,MW1, QAQC1
29-Mar-2017---- 07-Mar-2017----01-Mar-2017 ---- ü
ED037P: Alkalinity by PC TitratorClear Plastic Bottle - Natural (ED037-P)
MW2, MW3,MW1, QAQC1
15-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
ED041G: Sulfate (Turbidimetric) as SO4 2- by DAClear Plastic Bottle - Natural (ED041G)
MW2, MW3,
MW1, QAQC1
29-Mar-2017---- 03-Mar-2017----01-Mar-2017 ---- ü
ED045G: Chloride by Discrete AnalyserClear Plastic Bottle - Natural (ED045G)
MW2, MW3,
MW1, QAQC1
29-Mar-2017---- 03-Mar-2017----01-Mar-2017 ---- ü
ED093F: Dissolved Major CationsClear Plastic Bottle - Nitric Acid; Filtered (ED093F)
MW2, MW3,
MW1, QAQC1
29-Mar-2017---- 07-Mar-2017----01-Mar-2017 ---- ü
EG020F: Dissolved Metals by ICP-MSClear Plastic Bottle - Nitric Acid; Filtered (EG020A-F)
MW2, MW3,
MW1, QAQC1
28-Aug-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EG020T: Total Metals by ICP-MSClear Plastic Bottle - Nitric Acid; Unfiltered (EG020A-T)
RB1 28-Aug-201728-Aug-2017 06-Mar-201706-Mar-201701-Mar-2017 ü üEG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Nitric Acid; Filtered (EG035F)MW2, MW3,
MW1, QAQC1
29-Mar-2017---- 07-Mar-2017----01-Mar-2017 ---- ü
EG035T: Total Recoverable Mercury by FIMSClear Plastic Bottle - Nitric Acid; Unfiltered (EG035T)
RB1 29-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- üEK040P: Fluoride by PC Titrator
Clear Plastic Bottle - Natural (EK040P)MW2, MW3,
MW1, QAQC1
29-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EK055G: Ammonia as N by Discrete AnalyserClear Plastic Bottle - Sulfuric Acid (EK055G)
MW2, MW3,
MW1, QAQC1
29-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EK057G: Nitrite as N by Discrete AnalyserClear Plastic Bottle - Natural (EK057G)
MW2, MW3,
MW1, QAQC1
03-Mar-2017---- 03-Mar-2017----01-Mar-2017 ---- ü
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete AnalyserClear Plastic Bottle - Sulfuric Acid (EK059G)
MW2, MW3,
MW1, QAQC1
29-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EK061G: Total Kjeldahl Nitrogen By Discrete AnalyserClear Plastic Bottle - Sulfuric Acid (EK061G)
MW2, MW3,
MW1, QAQC1
29-Mar-201729-Mar-2017 06-Mar-201706-Mar-201701-Mar-2017 ü ü
EK067G: Total Phosphorus as P by Discrete AnalyserClear Plastic Bottle - Sulfuric Acid (EK067G)
MW2, MW3,
MW1, QAQC1
29-Mar-201729-Mar-2017 06-Mar-201706-Mar-201701-Mar-2017 ü ü
EK071G: Reactive Phosphorus as P by discrete analyserClear Plastic Bottle - Natural (EK071G)
MW2, MW3,
MW1, QAQC1
03-Mar-2017---- 03-Mar-2017----01-Mar-2017 ---- ü
EP005: Total Organic Carbon (TOC)Amber VOC Vial - Sulfuric Acid (EP005)
MW2, MW3,
MW1, QAQC1
29-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EP006 Total Inorganic CarbonClear Plastic Bottle - Natural (EP006)
MW2, MW3,
MW1, QAQC1
02-Mar-2017---- 07-Mar-2017----01-Mar-2017 ---- û
EP007 Total CarbonClear Plastic Bottle - Natural (EP007)
MW2, MW3,
MW1, QAQC1
02-Mar-2017---- 07-Mar-2017----01-Mar-2017 ---- û
EP066: Polychlorinated Biphenyls (PCB)Clear Plastic Bottle - Natural (EP066)
MW2, MW3,
MW1, QAQC1
16-Apr-201708-Mar-2017 08-Mar-201707-Mar-201701-Mar-2017 ü ü
EP068A: Organochlorine Pesticides (OC)Clear Plastic Bottle - Natural (EP068)
MW2, MW3,
MW1, QAQC1
16-Apr-201708-Mar-2017 08-Mar-201707-Mar-201701-Mar-2017 ü ü
EP068B: Organophosphorus Pesticides (OP)Clear Plastic Bottle - Natural (EP068)
MW2, MW3,
MW1, QAQC1
16-Apr-201708-Mar-2017 08-Mar-201707-Mar-201701-Mar-2017 ü ü
EP071 SG: Total Petroleum Hydrocarbons - Silica gel cleanupClear Plastic Bottle - Natural (EP071SG)
MW2, MW3,
MW1, QAQC1
16-Apr-201708-Mar-2017 08-Mar-201707-Mar-201701-Mar-2017 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP071 SG: Total Recoverable Hydrocarbons - NEPM 2013 Fractions - Silica gel cleanupClear Plastic Bottle - Natural (EP071SG)
MW2, MW3,
MW1, QAQC1
16-Apr-201708-Mar-2017 08-Mar-201707-Mar-201701-Mar-2017 ü ü
EP075(SIM)B: Polynuclear Aromatic HydrocarbonsClear Plastic Bottle - Natural (EP075(SIM))
MW2, MW3,
MW1, QAQC1
16-Apr-201708-Mar-2017 08-Mar-201707-Mar-201701-Mar-2017 ü ü
EP080/071: Total Petroleum HydrocarbonsAmber VOC Vial - Sulfuric Acid (EP080)
MW2, MW3,
MW1, QAQC1,
RB1
15-Mar-201715-Mar-2017 06-Mar-201706-Mar-201701-Mar-2017 ü ü
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 FractionsAmber VOC Vial - Sulfuric Acid (EP080)
MW2, MW3,
MW1, QAQC1,
RB1
15-Mar-201715-Mar-2017 06-Mar-201706-Mar-201701-Mar-2017 ü ü
EP080: BTEXNAmber VOC Vial - Sulfuric Acid (EP080)
MW2, MW3,
MW1, QAQC1,
RB1
15-Mar-201715-Mar-2017 06-Mar-201706-Mar-201701-Mar-2017 ü ü
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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
EvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-PNEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üAmmonia as N by Discrete analyser EK055GNEPM 2013 B3 & ALS QC Standard 15.38 10.002 13 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 25.00 10.001 4 üConductivity by PC Titrator EA010-PNEPM 2013 B3 & ALS QC Standard 20.00 10.002 10 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üFluoride by PC Titrator EK040PNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üMajor Cations - Dissolved ED093FNEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059GNEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üNitrite as N by Discrete Analyser EK057GNEPM 2013 B3 & ALS QC Standard 0.00 10.000 13 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)NEPM 2013 B3 & ALS QC Standard 0.00 10.000 5 ûPesticides by GCMS EP068NEPM 2013 B3 & ALS QC Standard 11.11 10.002 18 üpH by PC Titrator EA005-PNEPM 2013 B3 & ALS QC Standard 0.00 10.000 5 ûPolychlorinated Biphenyls (PCB) EP066NEPM 2013 B3 & ALS QC Standard 25.00 10.001 4 üReactive Phosphorus as P-By Discrete Analyser EK071GNEPM 2013 B3 & ALS QC Standard 13.04 10.003 23 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 25.00 10.001 4 üTotal Carbon EP007NEPM 2013 B3 & ALS QC Standard 25.00 10.001 4 üTotal Inorganic Carbon EP006NEPM 2013 B3 & ALS QC Standard 13.04 10.003 23 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061GNEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üTotal Mercury by FIMS EG035TNEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üTotal Metals by ICP-MS - Suite A EG020A-TNEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 11.11 10.002 18 üTotal Phosphorus as P By Discrete Analyser EK067GNEPM 2013 B3 & ALS QC Standard 0.00 10.000 4 ûTRH - Total Recoverable Hydrocarbons - Silica Gel C EP071SGNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTRH Volatiles/BTEX EP080
Laboratory Control Samples (LCS)NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAlkalinity by PC Titrator ED037-PNEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üAmmonia as N by Discrete analyser EK055GNEPM 2013 B3 & ALS QC Standard 15.38 10.002 13 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üConductivity by PC Titrator EA010-PNEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üFluoride by PC Titrator EK040PNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093FNEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059GNEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üNitrite as N by Discrete Analyser EK057G
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
EvaluationAnalytical Methods Method
Laboratory Control Samples (LCS) - ContinuedNEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üPAH/Phenols (GC/MS - SIM) EP075(SIM)NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üPesticides by GCMS EP068NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üPolychlorinated Biphenyls (PCB) EP066NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üReactive Phosphorus as P-By Discrete Analyser EK071GNEPM 2013 B3 & ALS QC Standard 17.39 10.004 23 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Carbon EP007NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Inorganic Carbon EP006NEPM 2013 B3 & ALS QC Standard 8.70 5.002 23 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061GNEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üTotal Mercury by FIMS EG035TNEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTotal Metals by ICP-MS - Suite A EG020A-TNEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üTotal Phosphorus as P By Discrete Analyser EK067GNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTRH - Total Recoverable Hydrocarbons - Silica Gel C EP071SGNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
Method Blanks (MB)NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üAmmonia as N by Discrete analyser EK055GNEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üConductivity by PC Titrator EA010-PNEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üFluoride by PC Titrator EK040PNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093FNEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059GNEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üNitrite as N by Discrete Analyser EK057GNEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üPAH/Phenols (GC/MS - SIM) EP075(SIM)NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üPesticides by GCMS EP068NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üPolychlorinated Biphenyls (PCB) EP066NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üReactive Phosphorus as P-By Discrete Analyser EK071GNEPM 2013 B3 & ALS QC Standard 8.70 5.002 23 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Carbon EP007NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Inorganic Carbon EP006NEPM 2013 B3 & ALS QC Standard 8.70 5.002 23 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061GNEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üTotal Mercury by FIMS EG035TNEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTotal Metals by ICP-MS - Suite A EG020A-TNEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üTotal Phosphorus as P By Discrete Analyser EK067GNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTRH - Total Recoverable Hydrocarbons - Silica Gel C EP071SGNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
Matrix Spikes (MS)NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üAmmonia as N by Discrete analyser EK055G
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
EvaluationAnalytical Methods Method
Matrix Spikes (MS) - Continued
NEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 13 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 5 ûPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 5 ûPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 8.70 5.002 23 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Carbon EP007
NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Inorganic Carbon EP006
NEPM 2013 B3 & ALS QC Standard 8.70 5.002 23 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 4 ûTRH - Total Recoverable Hydrocarbons - Silica Gel C EP071SG
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
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Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 H+ B. This procedure determines pH of water samples by automated ISE. This method is compliant with NEPM (2013) Schedule B(3)
pH by PC Titrator EA005-P WATER
In house: Referenced to APHA 2510 B. This procedure determines conductivity by automated ISE. This method is compliant with NEPM (2013) Schedule B(3)
Conductivity by PC Titrator EA010-P WATER
In house: Calculation from Electrical Conductivity (APHA 2510 B) using a conversion factor specified in the analytical report. This method is compliant with NEPM (2013) Schedule B(3)
Calculated TDS (from Electrical Conductivity)
EA016 WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013) Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500-SO4. Dissolved sulfate is determined in a 0.45um filtered sample. Sulfate ions are converted to a barium sulfate suspension in an acetic acid medium with barium chloride. Light absorbance of the BaSO4 suspension is measured by a photometer and the SO4-2 concentration is determined by comparison of the reading with a standard curve. This method is compliant with NEPM (2013) Schedule B(3)
Sulfate (Turbidimetric) as SO4 2- by Discrete Analyser
ED041G WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013) Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
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:ClientEM1702381 Amendment 1SESL Australia Pty LtdCamperdown Groundwater:Project
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS) Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique. A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell. Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS) FIM-AAS is an automated flameless atomic absorption technique. A bromate/bromide reagent is used to oxidise any organic mercury compounds in the unfiltered sample. The ionic mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell. Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Total Mercury by FIMS EG035T WATER
In house: Referenced to APHA 4500-F C: CDTA is added to the sample to provide a uniform ionic strength background, adjust pH, and break up complexes. Fluoride concentration is determined by either manual or automatic ISE measurement. This method is compliant with NEPM (2013) Schedule B(3)
Fluoride by PC Titrator EK040P WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Nitrite as N by Discrete Analyser EK057G WATER
In house: Referenced to APHA 4500-NO3- F. Nitrate is reduced to nitrite by way of a chemical reduction followed by quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate calculated as the difference between the two results. This method is compliant with NEPM (2013) Schedule B(3)
Nitrate as N by Discrete Analyser EK058G WATER
In house: Referenced to APHA 4500-NO3- F. Combined oxidised Nitrogen (NO2+NO3) is determined by Chemical Reduction and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Nitrite and Nitrate as N (NOx) by Discrete Analyser
EK059G WATER
In house: Referenced to APHA 4500-Norg D (In house). An aliquot of sample is digested using a high temperature Kjeldahl digestion to convert nitrogenous compounds to ammonia. Ammonia is determined colorimetrically by discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Kjeldahl Nitrogen as N By Discrete Analyser
EK061G WATER
In house: Referenced to APHA 4500-Norg / 4500-NO3-. This method is compliant with NEPM (2013) Schedule B(3)
Total Nitrogen as N (TKN + Nox) By Discrete Analyser
EK062G WATER
In house: Referenced to APHA 4500-P H, Jirka et al (1976), Zhang et al (2006). This procedure involves sulphuric acid digestion of a sample aliquot to break phosphorus down to orthophosphate. The orthophosphate reacts with ammonium molybdate and antimony potassium tartrate to form a complex which is then reduced and its concentration measured at 880nm using discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Phosphorus as P By Discrete Analyser
EK067G WATER
In house: Referenced to APHA 4500-P F Ammonium molybdate and potassium antimonyl tartrate reacts in acid medium with othophosphate to form a heteropoly acid -phosphomolybdic acid - which is reduced to intensely coloured molybdenum blue by ascorbic acid. Quantification is by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Reactive Phosphorus as P-By Discrete Analyser
EK071G WATER
In house: Referenced to APHA 1030F. This method is compliant with NEPM (2013) Schedule B(3)Ionic Balance by PCT DA and Turbi SO4 DA
EN055 - PG WATER
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:ClientEM1702381 Amendment 1SESL Australia Pty LtdCamperdown Groundwater:Project
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to APHA 5310 B The automated carbon analyzer removes Inorganic carbon as CO2, which is swept into an IR detector. This method is compliant with NEPM (2013) Schedule B(3)
Total Inorganic Carbon EP006 WATER
In house: Referenced to APHA 5310 B The automated Carbon analyzer converts all Carbon to CO2, which is swept into an IR detector. This method is compliant with NEPM (2013) Schedule B(3)
Total Carbon EP007 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Polychlorinated Biphenyls (PCB) EP066 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Pesticides by GCMS EP068 WATER
In house: Referenced to USEPA SW 846 - 8015A Sample extracts are analysed by Capillary GC/FID and quantified against alkane standards over the range C10 - C36. This method is compliant with NEPM (2013) Schedule B(3) (Method 506.1)
TRH - Total Recoverable Hydrocarbons - Silica Gel C
EP071SG WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS in SIM Mode and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
PAH/Phenols (GC/MS - SIM) EP075(SIM) WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. Alternatively, a sample is equilibrated in a headspace vial and a portion of the headspace determined by GCMS analysis. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH Volatiles/BTEX EP080 WATER
Specialist microbiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).Legionella in Water MM527 WATERMicrobiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).E.coli and Faecal Coliforms by MF MM540 WATERMicrobiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).Salmonella - VIDAS (absence /
presence)MM625 WATER
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 Norg - D; APHA 4500 P - H. This method is compliant with NEPM (2013) Schedule B(3)
TKN/TP Digestion EK061/EK067 WATER
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
In house: Referenced to USEPA SW 846 - 3510B 100 mL to 1L of sample is transferred to a separatory funnel and serially extracted three times using 60mL DCM for each extract. The resultant extracts are combined, dehydrated and concentrated for analysis. This method is compliant with NEPM (2013) Schedule B(3) . ALS default excludes sediment which may be resident in the container.
Separatory Funnel Extraction of Liquids ORG14 WATER
A 5 mL aliquot or 5 mL of a diluted sample is added to a 40 mL VOC vial for sparging.Volatiles Water Preparation ORG16-W WATER
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)
Work Order : EM1702381
:Amendment 1
:: LaboratoryClient Environmental Division MelbourneSESL Australia Pty Ltd
: :ContactContact MR RYAN JACKA:: AddressAddress PO BOX 357
PENNANT HILLS NSW, AUSTRALIA 1715
4 Westall Rd Springvale VIC Australia 3171
:: E-mailE-mail [email protected]:: TelephoneTelephone +61 02 9980 6554 +61-3-8549 9600:: FacsimileFacsimile +61 02 9484 2427 +61-3-8549 9601
::Project Camperdown Groundwater Page 1 of 3:Order number ---- :Quote number ES2016SESLAB0002 (SYBQ/259/16):C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----Sampler : ANDREW JACOVIDES
DatesDate Samples Received : Issue Date : 16-May-201703-Mar-2017 09:25
Scheduled Reporting Date: 20-Mar-2017:Client Requested Due Date
10-Mar-2017
Delivery DetailsMode of Delivery : :Undefined Not AvailableSecurity Seal
No. of coolers/boxes : :1 Temperature 10.6°C - Ice present: : 5 / 5Receipt Detail No. of samples received / analysed
General CommentsThis report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverablesl Please direct any queries related to sample condition / numbering / breakages to Client Services.
l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of work order.l Analytical work for this work order will be conducted at ALS Springvale and ALS Scoresby.
l Please refer to the Proactive Holding Time Report table below which summarises breaches of
recommended holding times that have occurred prior to samples/instructions being received at
the laboratory. The absence of this summary table indicates that all samples have been received
within the recommended holding times for the analysis requested.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client SESL Australia Pty LtdWork Order : EM1702381 Amendment 1
2 of 3:Page16-May-2017:Issue Date
Sample Container(s)/Preservation Non-CompliancesAll comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
MethodSample Container Received Preferred Sample Container for AnalysisClient sample ID
PAH/Phenols (GC/MS - SIM) : EP075(SIM)MW2 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedMW3 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedMW1 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedQAQC1 - Clear Plastic Bottle - Natural - Amber Glass Bottle - Unpreserved
Pesticides by GCMS : EP068MW2 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedMW3 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedMW1 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedQAQC1 - Clear Plastic Bottle - Natural - Amber Glass Bottle - Unpreserved
Polychlorinated Biphenyls (PCB) : EP066MW2 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedMW3 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedMW1 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedQAQC1 - Clear Plastic Bottle - Natural - Amber Glass Bottle - Unpreserved
TRH - Total Recoverable Hydrocarbons - Silica Gel C : EP071SGMW2 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedMW3 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedMW1 - Clear Plastic Bottle - Natural - Amber Glass Bottle - UnpreservedQAQC1 - Clear Plastic Bottle - Natural - Amber Glass Bottle - Unpreserved
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory process necessary for the execution of client requested tasks. Packages may contain additional analyses, such as the determination of moisture content and preparation tasks, that are included in the package.If no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a time component
WA
TER
- IN
-3TO
C/T
IC/T
C C
ombi
ned
Sui
te
WA
TER
- M
3 - E
M (S
ubco
ntra
cted
)FC
& E
.col
i by
MF
WA
TER
- M
M52
7 (S
ubco
ntra
cted
)Le
gion
ella
in W
ater
WA
TER
- M
M62
5 (S
ubco
ntra
cted
)S
alm
onel
la -
VID
AS
(abs
ence
/ pr
esen
ce)
WA
TER
- N
T-14
Ext
ende
d W
ater
Sui
te B
WA
TER
- W
-13
OC
/OP
/PC
B
WA
TER
- W
-26
SG
TRH
/BTE
XN
/PA
H/8
Met
als
inc
Sili
ca G
el C
lean
EM1702381-001 01-Mar-2017 00:00 MW2 ü ü ü ü ü ü ü
EM1702381-002 01-Mar-2017 00:00 MW3 ü ü ü ü ü ü ü
EM1702381-003 01-Mar-2017 00:00 MW1 ü ü ü ü ü ü ü
EM1702381-004 01-Mar-2017 00:00 QAQC1 ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample ID
Client sampling date / time
WA
TER
- W
-02T
8 m
etal
s (T
otal
)
WA
TER
- W
-18
TRH
(C6
- C9)
/BTE
XN
EM1702381-005 01-Mar-2017 00:00 RB1 ü ü
Matrix: WATER
Client sample IDLaboratory sample ID
Client sampling date / time
:Client SESL Australia Pty Ltd
Work Order : EM1702381 Amendment 13 of 3:Page
16-May-2017:Issue Date
Proactive Holding Time ReportThe following table summarises breaches of recommended holding times that have occurred prior to samples/instructions being
received at the laboratory.
Evaluation: û = Holding time breach ; ü = Within holding time. Matrix: WATER
EvaluationClient Sample ID(s)
Due for extraction
Due for analysis Evaluation
Samples Received Instructions ReceivedDate Date
Method
ContainerEA005-P: pH by PC Titrator
MW1 û --------03-Mar-201701-Mar-2017----Clear Plastic Bottle - Natural
MW2 û --------03-Mar-201701-Mar-2017----Clear Plastic Bottle - Natural
MW3 û --------03-Mar-201701-Mar-2017----Clear Plastic Bottle - Natural
QAQC1 û --------03-Mar-201701-Mar-2017----Clear Plastic Bottle - Natural
EP006: Total Inorganic CarbonMW1 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
MW2 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
MW3 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
QAQC1 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
EP007: Total CarbonMW1 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
MW2 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
MW3 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
QAQC1 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
Requested DeliverablesACCOUNTS PAYABLE
- A4 - AU Tax Invoice (INV) Email [email protected]
ANDREW JACOVIDES- *AU Certificate of Analysis - NATA (COA) Email [email protected]
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email [email protected]
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email [email protected]
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email [email protected]
- Chain of Custody (CoC) (COC) Email [email protected]
- EDI Format - ENMRG (ENMRG) Email [email protected]
- EDI Format - ESDAT (ESDAT) Email [email protected]
ESdat&Export&Information:Project(s):Filter:Export2Date/Time:Exported2By:Settings:Chem2Profile:Env2Standards:Include2Result2Prefix: YDetects2Only: NExceedances2Only: NQualifiers:Comments:Chem2Grouping:Hidden2Groups:Hidden2ChemNames:
Error&Settings:RDP2(%)
1 2M2 10 8110 2M2 30 50
2>2 30 30
Terms2&2Conditions
Concentration2x2EQL
RPD2=2Relative2Percent2DifferenceEQL2=2Estimated2Quantitation2Limit2(also2called2LOR)
Disclaimer:All2care2has2been2exercised2in2the2compilation2of2these2guidelines2(or2Environmental2Standards),2however2no2liability2is2taken2for2any2error.It2is2the2responsibility2of2the2user2to2review2the2contained2data2and2ensure2their2data2is2compliant2with2the2relevant2guidelines,2and2that2this2compilation2of2guidelines2meets2their2requirements.
Sys2Default
LabChem2Group
Benzo(a)pyrene2TEQ2calc2(Zero)
42507Lab2Reports EM170238131/05/201729:44fiona
Table A1 - Replicate Quality Samples
>C10%&%C16%Fraction%
minus%Naphthalene%
(F2)%(SG)
>C10%&%C40%Fraction%
(sum)%(SG)
Legionella%
Pneumophila%
Serogroup%1
Legionella%
Pneumophila%
Serogroup%2&14
Legionella%Species
Salm
onella%sp
Sulfate%as%SO4%&%
Turbidim
etric%(filtered)
Total%Carbon
Total%Dissolved%Solids%
(Calc.)
Total%Inorganic%Carbon
Benzene
Toluene
Ethylbenzene
Xylene%(m%&%p)
Xylene%(o)
mg/L mg/L CFU/mL CFU/mL CFU/mL & mg/L mg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L
EQL 0.1 0.1 10 10 10 1 1 1 1 1 2 2 2 2
Lab%Report%Number Sample%Code Field%ID Date
EM1702381 EM1702381001 MW1 1/03/2017 <0.1 <0.1 <10 <10 <10 0#1 191 156 9,360 150 <1 <2 <2 <2 <2EM1702381 EM1702381004 QAQC1 1/03/2017 <0.1 <0.1 <10 <10 <10 0#1 192 156 9,360 150 <1 <2 <2 <2 <2RPD 0 0 0 0 0 /2,147,483,648 1 0 0 0 0 0 0 0 0
Comments
#13Not3Detected
NA BTEX
EQL
Lab%Report%Number Sample%Code Field%ID Date
EM1702381 EM1702381001 MW1 1/03/2017
EM1702381 EM1702381004 QAQC1 1/03/2017
RPD
Comments
#13Not3Detected
Table A1 - Replicate Quality Samples (Continued)
Biological Biological
Halogenated%
Benzenes
Xylene%Total
Total%BTEX
Faecal%Coliforms
E.%Coli
Hexachlorobenzene
Nitrite%+%Nitrate%as%N
Alkalinity%(Bicarbonate%
as%CaCO3)
Alkalinity%(Carbonate%
as%CaCO3)
Alkalinity%(Hydroxide)%
as%CaCO3
Alkalinity%(total)%as%
CaCO3
Ammonia%as%N
Anions%Total
Cations%Total
Chloride
µg/L mg/L CFU/100mL cfu/100%ml µg/L mg/L mg/L mg/L mg/L mg/L mg/L meq/L meq/L mg/L
2 0.001 1 1 0.5 0.01 1 1 1 1 0.01 0.01 0.01 1
<2 <0.001 <10 <10 <0.5 44.5 698 <1 <1 698 0.02 130 121 3,970<2 <0.001 <10 <10 <0.5 44.8 705 <1 <1 705 0.03 132 119 4,0400 0 0 0 0 1 1 0 0 1 40 2 2 2
BTEX Inorganics
EQL
Lab%Report%Number Sample%Code Field%ID Date
EM1702381 EM1702381001 MW1 1/03/2017
EM1702381 EM1702381004 QAQC1 1/03/2017RPD
Comments#13Not3Detected
Table A1 - Replicate Quality Samples (Continued)
Lead Metals
Electrical%con
ductivity%
*(lab)
Fluo
ride
Ionic%Ba
lance
Kjelda
hl%Nitrogen%
Total
Nitrate%(a
s%N)
Nitrite%(a
s%N)
Nitrogen%(Total)
pH%(Lab
)
Reactive%Pho
spho
rus%
as%P
Sodium
%(filtered
)
Sodium
%Absorption%
Ratio%(filtered
)
TOC
Hardn
ess%as%CaC
O3%
(filtered
)
Lead
%(filtered
)
Arsen
ic%(filtered
)
uS/cm mg/L % mg/L mg/L mg/L µg/L & mg/L mg/L & mg/L mg/L mg/L mg/L
1 0.1 0.01 0.1 0.01 0.01 100 0.01 0.01 1 1 1 0.001 0.001
14,400 1.1 3.63 2.1 44.5 0.02 46,600 7.81 0.02 1,900 19 6 1,900 <0.001 <0.00114,400 1.1 5.16 1.9 44.8 0.02 46,700 7.86 0.01 1,880 19 7 1,860 <0.001 <0.001
0 0 35 10 1 0 0 1 67 1 0 15 2 0 0
Inorganics
EQL
Lab%Report%Number Sample%Code Field%ID Date
EM1702381 EM1702381001 MW1 1/03/2017EM1702381 EM1702381004 QAQC1 1/03/2017RPD
Comments#13Not3Detected
Table A1 - Replicate Quality Samples (Continued)
Cadm
ium%(filtered
)
Calcium
%(filtered
)
Chromium%(III+
VI)%
(filte
red)
Copp
er%(filtered
)
Magne
sium%(filtered
)
Mercury%(filtered
)
Nickel%(filtered
)
Phosph
orus
Potassium%(filtered
)
Zinc%(filtered
)
4,4&DD
E
a&BH
C
Aldrin
Aldrin%+%Dieldrin
b&BH
C
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L0.0001 1 0.001 0.001 1 0.0001 0.001 0.01 1 0.005 0.5 0.5 0.5 0.5 0.5
<0.0001 150 <0.001 0.002 370 <0.0001 0.014 0.02 9 0.011 <0.5 <0.5 <0.5 <0.5 <0.5<0.0001 146 <0.001 0.002 362 <0.0001 0.014 0.02 9 0.009 <0.5 <0.5 <0.5 <0.5 <0.5
0 3 0 0 2 0 0 0 0 20 0 0 0 0 0
Organochlorine%PesticidesMetals
EQL
Lab%Report%Number Sample%Code Field%ID Date
EM1702381 EM1702381001 MW1 1/03/2017EM1702381 EM1702381004 QAQC1 1/03/2017RPD
Comments#13Not3Detected
Table A1 - Replicate Quality Samples (Continued)
chlordan
e
Chlordan
e%(cis)
Chlordan
e%(tran
s)
d&BH
C
DDD
DDT
DDT+DD
E+DD
D
Dieldrin
Endo
sulfa
n%I
Endo
sulfa
n%II
Endo
sulfa
n%sulpha
te
Endrin
Endrin%aldeh
yde
Endrin%keton
e
g&BH
C%(Linda
ne)
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L0.5 0.5 0.5 0.5 0.5 2 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Organochlorine%Pesticides
EQL
Lab%Report%Number Sample%Code Field%ID Date
EM1702381 EM1702381001 MW1 1/03/2017
EM1702381 EM1702381004 QAQC1 1/03/2017RPD
Comments#13Not3Detected
Table A1 - Replicate Quality Samples (Continued)
Hep
tachlor
Hep
tachlor%ep
oxide
Metho
xychlor
Azino
phos%m
ethyl
Brom
opho
sðyl
Carbop
heno
thion
Chlorfen
vinp
hos
Chlorpyrifo
s
Chlorpyrifo
s&methyl
Diazino
n
Dichlorvos
Dim
etho
ate
Ethion
Fenthion
Malathion
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L
0.5 0.5 2 0.5 0.5 0.5 0.5 0.5 0.0005 0.5 0.5 0.5 0.5 0.5 0.5
<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.0005 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.0005 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Organochlorine%Pesticides Organophosphorous%Pesticides
EQL
Lab%Report%Number Sample%Code Field%ID Date
EM1702381 EM1702381001 MW1 1/03/2017
EM1702381 EM1702381004 QAQC1 1/03/2017RPD
Comments#13Not3Detected
Table A1 - Replicate Quality Samples (Continued)
Methyl%parathion
Mon
ocrotoph
os
Prothiofos
Acena
phthen
e
Acena
phthylen
e
Anthracen
e
Benz(a)anthracen
e
Benzo(a)%pyren
e
Benzo(b+
j)fluoran
then
e Benzo(g,h,i)p
erylen
e
Benzo(k)flu
oran
then
e
Chrysene
Diben
z(a,h)an
thracene
Fluo
ranthe
ne
Fluo
rene
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L
2 2 0.5 1 1 1 1 0.5 0.001 1 1 1 1 1 1
<2 <2 <0.5 <1 <1 <1 <1 <0.5 <0.001 <1 <1 <1 <1 <1 <1<2 <2 <0.5 <1 <1 <1 <1 <0.5 <0.001 <1 <1 <1 <1 <1 <10 0 0 0 0 0 0 0 0 0 0 0 0 0 0
PAHOrganophosphorous%Pesticides
EQL
Lab%Report%Number Sample%Code Field%ID Date
EM1702381 EM1702381001 MW1 1/03/2017EM1702381 EM1702381004 QAQC1 1/03/2017RPD
Comments#13Not3Detected
Table A1 - Replicate Quality Samples (Continued)Polychlorinated%
Biphenyls
Inde
no(1,2,3&
c,d)pyrene
Nap
htha
lene
Phen
anthrene
Pyrene
PAHs
%(Vic%EPA
%List)
Demeton
&S&m
ethyl
Fena
mipho
s
Parathion
Pirim
phosðyl
PCBs%(Sum
%of%total)
C6&C9
C6&C10
TPH%C1
0&C1
4%%Fraction%
after%S
ilica%Clean
up
TPH%C1
5&C2
8%%Fraction%
after%S
ilica%Clean
up
µg/L µg/L µg/L µg/L ug/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L mg/L mg/L1 1 1 1 0.5 0.5 0.5 2 0.5 1 20 0.02 0.05 0.1
<1 <1 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <0.02 <0.05 <0.1<1 <1 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <0.02 <0.05 <0.10 0 0 0 0 0 0 0 0 0 0 0 0 0
PesticidesPAH TPH
EQL
Lab%Report%Number Sample%Code Field%ID Date
EM1702381 EM1702381001 MW1 1/03/2017
EM1702381 EM1702381004 QAQC1 1/03/2017RPD
Comments#13Not3Detected
Table A1 - Replicate Quality Samples (Continued)
TPH%C29
&C36
%%Fraction%
after%Silica%Cleanu
p
TRH%>C1
0&C1
6%(after%
silica%gel%clean
&up)
TRH%>C1
6&C3
4%(after%
silica%gel%clean
&up)
TRH%>C3
4&C4
0%(after%
silica%gel%clean
&up)
TRH%C10
&C36
%(Total)%
(after%silica%gel%clean
&up
)
F1%m
inus%BTEX
mg/L mg/L mg/L mg/L mg/L mg/L
0.05 0.1 0.1 0.1 0.05 0.02
<0.05 <0.1 <0.1 <0.1 <0.05 <0.02<0.05 <0.1 <0.1 <0.1 <0.05 <0.020 0 0 0 0 0
TPH
Lead PAH
Ben
zene
Toluen
e
Ethylben
zene
Xylen
e5(m
5&5p)
Xylen
e5(o)
Xylen
e5To
tal
Total5B
TEX
Lead
Arsen
ic
Cad
mium
Chromium5(III+VI)
Copper
Mercury
Nickel
Zinc
Nap
hthalen
e
C6HC9
C6HC10
F15m
inus5BTEX
µg/L µg/L µg/L µg/L µg/L µg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L µg/L µg/L mg/L mg/L
Lab5Report5NumberSample5Code Field5ID Date Depth
EM1702381 EM1702381005RB1 1/03/2017 <1 <2 <2 <2 <2 <2 <0.001 <0.001 <0.001 <0.0001 <0.001 <0.001 <0.0001 <0.001 <0.005 <5 <20 <0.02 <0.02
BTEX Metals TPH
Table5A2_BLANKS5QUALITY5SAMPLES
>C
10
- C
16
Fra
cti
on
min
us
Na
ph
tha
len
e
(F2
) (S
G)
>C
10
- C
40
Fra
cti
on
(su
m)
(SG
)
Le
gio
ne
lla
Pn
eu
mo
ph
ila
Se
rog
rou
p 1
Le
gio
ne
lla
Pn
eu
mo
ph
ila
Se
rog
rou
p 2
-14
Le
gio
ne
lla
Sp
ec
ies
Sa
lmo
ne
lla
sp
Su
lfa
te a
s S
O4
-
Tu
rbid
ime
tric
(fil
tere
d)
To
tal
Ca
rbo
n
To
tal
Dis
solv
ed
So
lid
s (C
alc
.)
To
tal
Ino
rga
nic
Ca
rbo
n
mg/L mg/L CFU/mL CFU/mL CFU/mL - mg/L mg/L mg/L mg/L
EQL 0.1 0.1 10 10 10 1 1 1 1ADWG 2015 Aesthetic 250 600ADWG Recreation (ADWG Health x10)ANZECC 2000 FW 95%ANZECC 2000 Livestock DW Low Risk Trigger ValuesANZECC 2000 Rec Water Quality and Aesthetics: Primary contact 400 1000ANZECC 2000 Recreational water quality and aestheticsNEPM 2013 Table 1C GILs, Fresh WatersNEPM 2013 Table 1A(4) Comm/Ind HSL D GW for Vapour Intrusion, Clay 2-4m 4-8m
Site ID Sample Code Field ID Date
EM1702381002 MW2 1/3/17 <0.1 <0.1 <10 <10 <10 0#1 191 156 9,360 150EM1702381003 MW3 1/3/17 <0.1 <0.1 <10 <10 <10 0#1 73 112 4,730 112EM1702381001 MW1 1/3/17 <0.1 <0.1 <10 <10 <10 0#1 166 127 6,120 118
Statistics
Number of Results 3 3 3 3 3 3 3 3 3 3
Number of Detects 0 0 0 0 0 3 3 3 3 3
Minimum Concentration <0.1 <0.1 <10 <10 <10 0 73 112 4,730 112
Minimum Detect ND ND ND ND ND ND 73 112 4,730 112
Maximum Concentration <0.1 <0.1 <10 <10 <10 0 191 156 9,360 150
Maximum Detect ND ND ND ND ND 0 191 156 9,360 150
Average Concentration * 0.05 0.05 5 5 5 0 143 132 6,737 127
Median Concentration * 0.05 0.05 5 5 5 0 166 127 6,120 118
Standard Deviation * 0 0 0 0 0 0 62 22 2,376 20
95% UCL (Student's-t) * 0.05 0.05 5 5 5 0 248.2 169.4 10,742 161.1
* A Non Detect Multiplier of 0.5 has been applied.
Comments
#1 Not Detected
Environmental Standards
DoE, 2000, ANZECC 2000 slightly-moderately disturbed systemsNHMRC, 2015, ADWG 2015 AestheticNHMRC, 2015, ADWG 2015 HealthDoE, 2000, ANZECC 2000 FW 95%DoE, 2000, ANZECC 2000 Livestock DW Low Risk Trigger ValuesDoE, 2000, ANZECC 2000 Rec Water Quality and Aesthetics: Primary contactDoE, 2000, ANZECC 2000 Recreational water quality and aesthetics* for recreational purposes, the ADWG health criteria was multiplied by a factor of 10 considering ingestion during recreational activity would be less than 10 times of standard drinking water consumption
Hickey (2002), Nitrate Criteria
NA
Halogenated
Benzenes
Be
nze
ne
To
lue
ne
Eth
ylb
en
zen
e
Xy
len
e (
m &
p)
Xy
len
e (
o)
Xy
len
e T
ota
l
To
tal
BT
EX
Fa
ec
al
Co
lifo
rms
E.
Co
li
He
xa
ch
loro
be
nze
ne
Nit
rite
+ N
itra
te a
s N
Alk
ali
nit
y
(Bic
arb
on
ate
as
Ca
CO
3)
Alk
ali
nit
y
(Ca
rbo
na
te a
s
Ca
CO
3)
Alk
ali
nit
y
(Hy
dro
xid
e)
as
Ca
CO
3
Alk
ali
nit
y (
tota
l) a
s
Ca
CO
3
Am
mo
nia
as
N
µg/L µg/L µg/L µg/L µg/L µg/L mg/L CFU/100mL cfu/100 ml µg/L mg/L mg/L mg/L mg/L mg/L mg/L
1 2 2 2 2 2 0.001 1 1 0.5 0.01 1 1 1 1 0.0125 3 20 0.5
10 8000 3000 6000950 350 0.9
10 600 500,000 0.0110 0.01
950 350 550
30,00030,000
<1 <2 <2 <2 <2 <2 <0.001 <10 <10 <0.5 44.5 698 <1 <1 698 0.02<1 <2 <2 <2 <2 <2 <0.001 <10 <10 <0.5 0.08 532 <1 <1 532 <0.01<1 <2 <2 <2 <2 <2 <0.001 <10 <10 <0.5 24.7 559 <1 <1 559 0.01
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3
0 0 0 0 0 0 0 0 0 0 3 3 0 0 3 2
<1 <2 <2 <2 <2 <2 <0.001 <10 <10 <0.5 0.08 532 <1 <1 532 0.01
ND ND ND ND ND ND ND ND ND ND 0.08 532 ND ND 532 0.01
<1 <2 <2 <2 <2 <2 <0.001 <10 <10 <0.5 44.5 698 <1 <1 698 0.02
ND ND ND ND ND ND ND ND ND ND 44.5 698 ND ND 698 0.02
0.5 1 1 1 1 1 0.0005 5 5 0.25 23 596 0.5 0.5 596 0.012
0.5 1 1 1 1 1 0.0005 5 5 0.25 24.7 559 0.5 0.5 559 0.01
0 0 0 0 0 0 0 0 0 0 22 89 0 0 89 0.0076
0.5 1 1 1 1 1 0.0005 5 5 0.25 60.61 746.5 0.5 0.5 746.5 0.0245
BTEX Biological Inorganics
An
ion
s T
ota
l
Ca
tio
ns
To
tal
Ch
lori
de
Ele
ctr
ica
l
co
nd
uc
tiv
ity
*(l
ab
)
Flu
ori
de
Ion
ic B
ala
nc
e
Kje
lda
hl
Nit
rog
en
To
tal
Nit
rate
(a
s N
)
Nit
rite
(a
s N
)
Nit
rog
en
(T
ota
l)
pH
(L
ab
)
Re
ac
tiv
e P
ho
sph
oru
s
as
P
So
diu
m (
filt
ere
d)
So
diu
m A
bso
rpti
on
Ra
tio
(fi
lte
red
)
TO
C
Ha
rdn
ess
as
Ca
CO
3
(fil
tere
d)
meq/L meq/L mg/L uS/cm mg/L % mg/L mg/L mg/L µg/L - mg/L mg/L - mg/L mg/L
0.01 0.01 1 1 0.1 0.01 0.1 0.01 0.01 100 0.01 0.01 1 1 1250 6.5-8.5 180 200
15 307.2^
210 1 6.5 - 8.5 300 500
400 10 1 6.5-8.5 300 500
130 121 3,970 14,400 1.1 3.63 2.1 44.5 0.02 46,600 7.81 0.02 1,900 19 6 1,90062.1 58.4 1,770 7,280 0.9 3.04 <0.1 0.08 <0.01 <100 7.8 0.04 861 11.6 <1 1,04083.7 75.2 2,450 9,420 1.2 5.37 1 24.1 0.58 25,700 7.96 0.01 1,380 21.9 8 752
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3
3 3 3 3 3 3 2 3 2 2 3 3 3 3 2 3
62.1 58.4 1,770 7,280 0.9 3.04 <0.1 0.08 <0.01 <100 7.8 0.01 861 11.6 <1 752
62.1 58.4 1,770 7,280 0.9 3.04 1 0.08 0.02 25,700 7.8 0.01 861 11.6 6 752
130 121 3,970 14,400 1.2 5.37 2.1 44.5 0.58 46,600 7.96 0.04 1,900 21.9 8 1,900
130 121 3,970 14,400 1.2 5.37 2.1 44.5 0.58 46,600 7.96 0.04 1,900 21.9 8 1,900
92 85 2,730 10,367 1.1 4 1 23 0.2 24,117 7.9 0.023 1,380 18 4.8 1,231
83.7 75.2 2,450 9,420 1.1 3.63 1 24.1 0.02 25,700 7.81 0.02 1,380 19 6 1,040
35 32 1,126 3,653 0.15 1.2 1 22 0.33 23,315 0.09 0.015 520 5.3 3.9 597
150.4 139.5 4,629 16,525 1.324 6.056 2.78 60.38 0.754 63,423 8.008 0.0491 2,256 26.45 11.38 2,238
Inorganics
Lead
Le
ad
(fi
lte
red
)
Ars
en
ic (
filt
ere
d)
Ca
dm
ium
(fi
lte
red
)
Ca
lciu
m (
filt
ere
d)
Ch
rom
ium
(II
I+V
I)
(fil
tere
d)
Co
pp
er
(fil
tere
d)
Ma
gn
esi
um
(fil
tere
d)
Me
rcu
ry (
filt
ere
d)
Nic
ke
l (f
ilte
red
)
Ph
osp
ho
rus
Po
tass
ium
(fi
lte
red
)
Zin
c (
filt
ere
d)
4,4
-DD
E
a-B
HC
Ald
rin
Ald
rin
+ D
ield
rin
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L µg/L µg/L µg/L µg/L
0.001 0.001 0.0001 1 0.001 0.001 1 0.0001 0.001 0.01 1 0.005 0.5 0.5 0.5 0.51 3
0.1 0.1 0.02 20 0.01 30.0034 0.0002 0.0014 0.0006 0.011 0.008
0.1 0.5 0.01 1 0.4 0.002 1 200.05 0.05 0.005 0.05 1 0.001 0.1 50.05 0.05 0.005 0.05 1 0.001 0.1 5 1
0.0034 0.0002 0.0014 6E-05 0.011 0.008
<0.001 <0.001 <0.0001 150 <0.001 0.002 370 <0.0001 0.014 0.02 9 0.011 <0.5 <0.5 <0.5 <0.5<0.001 <0.001 0.0001 111 <0.001 <0.001 185 <0.0001 0.009 0.1 8 0.009 <0.5 <0.5 <0.5 <0.5<0.001 <0.001 <0.0001 54 <0.001 <0.001 150 <0.0001 0.008 0.05 5 0.011 <0.5 <0.5 <0.5 <0.5
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3
0 0 1 3 0 1 3 0 3 3 3 3 0 0 0 0
<0.001 <0.001 0.0001 54 <0.001 <0.001 150 <0.0001 0.008 0.02 5 0.009 <0.5 <0.5 <0.5 <0.5
ND ND 0.0001 54 ND 0.002 150 ND 0.008 0.02 5 0.009 ND ND ND ND
<0.001 <0.001 0.0001 150 <0.001 0.002 370 <0.0001 0.014 0.1 9 0.011 <0.5 <0.5 <0.5 <0.5
ND ND 0.0001 150 ND 0.002 370 ND 0.014 0.1 9 0.011 ND ND ND ND
0.0005 0.0005 0.000067 105 0.0005 0.001 235 0.00005 0.01 0.057 7.3 0.01 0.25 0.25 0.25 0.25
0.0005 0.0005 0.00005 111 0.0005 0.0005 185 0.00005 0.009 0.05 8 0.011 0.25 0.25 0.25 0.25
0 0 0.000029 48 0 0.00087 118 0 0.0032 0.04 2.1 0.0012 0 0 0 0
0.0005 0.0005 0.00011533 186.4 0.0005 0.00246 434.3 0.00005 0.0158 0.125 10.84 0.0123 0.25 0.25 0.25 0.25
Organochlorine PesticidesMetals
b-B
HC
ch
lord
an
e
Ch
lord
an
e (
cis
)
Ch
lord
an
e (
tra
ns)
d-B
HC
DD
D
DD
T
DD
T+
DD
E+
DD
D
Die
ldri
n
En
do
sulf
an
I
En
do
sulf
an
II
En
do
sulf
an
su
lph
ate
En
dri
n
En
dri
n a
lde
hy
de
En
dri
n k
eto
ne
g-B
HC
(L
ind
an
e)
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
0.5 0.5 0.5 0.5 0.5 0.5 2 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
20 90 1000.08 0.01 0.02 0.2
6 3 1 1 100.03 0.006 0.01 0.2
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
0.25 0.25 0.25 0.25 0.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25
0.25 0.25 0.25 0.25 0.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0.25 0.25 0.25 0.25 0.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25
Organochlorine Pesticides
He
pta
ch
lor
He
pta
ch
lor
ep
ox
ide
Me
tho
xy
ch
lor
Azi
no
ph
os
me
thy
l
Bro
mo
ph
os-
eth
yl
Ca
rbo
ph
en
oth
ion
Ch
lorf
en
vin
ph
os
Ch
lorp
yri
fos
Ch
lorp
yri
fos-
me
thy
l
Dia
zin
on
Dic
hlo
rvo
s
Dim
eth
oa
te
Eth
ion
Fe
nth
ion
Ma
lath
ion
Me
thy
l p
ara
thio
n
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
0.5 0.5 2 0.5 0.5 0.5 0.5 0.5 0.0005 0.5 0.5 0.5 0.5 0.5 0.5 2
3 300 100 5 20 100 40 50 70 40 70 700 70.09 0.02 0.01 0.01 0.15 0.05
3 10 20 1 10 2 10 20 100 6 100 60.01 0.01 0.01 0.15 0.05
<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.0005 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.0005 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.0005 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.0005 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.0005 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
0.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.00025 0.25 0.25 0.25 0.25 0.25 0.25 1
0.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.00025 0.25 0.25 0.25 0.25 0.25 0.25 1
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.00025 0.25 0.25 0.25 0.25 0.25 0.25 1
Organochlorine Pesticides Organophosphorous Pesticides
Mo
no
cro
top
ho
s
Pro
thio
fos
Ac
en
ap
hth
en
e
Ac
en
ap
hth
yle
ne
An
thra
ce
ne
Be
nz(
a)a
nth
rac
en
e
Be
nzo
(a)
py
ren
e
Be
nzo
(b+
j)fl
uo
ran
th
en
e
Be
nzo
(g,h
,i)p
ery
len
e
Be
nzo
(k)f
luo
ran
the
n
e Ch
ryse
ne
Dib
en
z(a
,h)a
nth
rac
e
ne
Flu
ora
nth
en
e
Flu
ore
ne
Ind
en
o(1
,2,3
-
c,d
)py
ren
e
Na
ph
tha
len
e
µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
2 0.5 1 1 1 1 0.5 0.001 1 1 1 1 1 1 1 1
20 0.116
2 0.0116
<2 <0.5 <1 <1 <1 <1 <0.5 <0.001 <1 <1 <1 <1 <1 <1 <1 <1<2 <0.5 <1 <1 <1 <1 <0.5 <0.001 <1 <1 <1 <1 <1 <1 <1 <1<2 <0.5 <1 <1 <1 <1 <0.5 <0.001 <1 <1 <1 <1 <1 <1 <1 <1
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 6
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
<2 <0.5 <1 <1 <1 <1 <0.5 <0.001 <1 <1 <1 <1 <1 <1 <1 <1
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
<2 <0.5 <1 <1 <1 <1 <0.5 <0.001 <1 <1 <1 <1 <1 <1 <1 <5
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
1 0.25 0.5 0.5 0.5 0.5 0.25 0.0005 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5
1 0.25 0.5 0.5 0.5 0.5 0.25 0.0005 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1 0.25 0.5 0.5 0.5 0.5 0.25 0.0005 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2.401
Organophosphorous Pesticides PAH
Polychlorinated
Biphenyls
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(Su
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4
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8
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µg/L µg/L ug/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
1 1 0.5 0.5 0.5 2 0.5 1 20 0.02 0.05 0.1 0.05 0.1 0.1 0.1
5 200 50.004
30 10.004
<1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <0.02 <0.05 <0.1 <0.05 <0.1 <0.1 <0.1<1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <0.02 <0.05 <0.1 <0.05 <0.1 <0.1 <0.1<1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <0.02 <0.05 <0.1 <0.05 <0.1 <0.1 <0.1
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
<1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <0.02 <0.05 <0.1 <0.05 <0.1 <0.1 <0.1
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
<1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <0.02 <0.05 <0.1 <0.05 <0.1 <0.1 <0.1
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
0.5 0.5 0.25 0.25 0.25 1 0.25 0.5 10 0.01 0.025 0.05 0.025 0.05 0.05 0.05
0.5 0.5 0.25 0.25 0.25 1 0.25 0.5 10 0.01 0.025 0.05 0.025 0.05 0.05 0.05
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0.5 0.5 0.25 0.25 0.25 1 0.25 0.5 10 0.01 0.025 0.05 0.025 0.05 0.05 0.05
PAH Pesticides TPH
TR
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(aft
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mg/L mg/L
0.05 0.02
<0.05 <0.02<0.05 <0.02<0.05 <0.02
3 3
0 0
<0.05 <0.02
ND ND
<0.05 <0.02
ND ND
0.025 0.01
0.025 0.01
0 0
0.025 0.01
TPH
Appendix F
EarthEon Pty Ltd
Proposal: Drilling Supervision for Camperdown Compost Company
ACN 120 654 677
ABN 28 120 654 677
12 Thomas Street, Williamstown VIC 3016
May 16, 2017 Nick Routson Camperdown Compost Company 4915 Princes Highway Camperdown VIC 3260
Dear Nick,
Ref: CC001
MONITORING BORE INSTALLATION AT CAMPERDOWN COMPOST COMPANY.
EarthEon Pty Ltd (EarthEon) was engaged to select locations for groundwater monitoring bores and supervising bore installation at Camperdown Compost Company. This letter summarises the results from the groundwater monitoring bore installation works.
Background Camperdown Compost Company operates a composting facility located on Blind Creek Road, approximately 8 km northwest of Camperdown. The facility operates under an EPA licence and it has become necessary to install groundwater monitoring bores at the site to ensure the protection of beneficial uses of groundwater.
Results Three monitoring bores were installed at the site under Southern Rural Water Works Licence WLE062257 (see Attachment A). The siting of monitoring bores was based on site access, estimated direction of groundwater flow (southwest) and location of leachate ponds at the western end of the site (see Figure 1).
EarthEon Pty Ltd
Proposal: Drilling Supervision for Camperdown Compost Company
Figure 1: Approximate monitoring bore locations (source image Google)
The bores were installed by a Class 1 licenced driller from South Western Drilling Pty Ltd on the 11 June 2015. Bores were installed to depths of 7 to 10 m and constructed with cl 18 uPVC 50 mm diameter bore casing with machine slotted screens. Bores were gravel packed with 8/16 washed sand to 0.5 m above the screen and sealed with bentonite and cement grout. Bores were completed with above ground steel bore covers. Bore installation was completed in line with Minimum Construction Requirement for Water Bores in Australia 3rd Edition and the conditions of the Works Licence. A summary of bore construction details is provided in Table 1. Table 1: Summary bore construction information
Name MGA E (approx.)
MGA N (approx.)
Stickup (m agl)
Depth (m) Screen (m)
Electrical conductivity (mS/cm)
MW1 682030 5772770 +0.80 9 3-9 6.10
MW2 681976 5772821 +0.80 7 3-7 7.01
MW3 682289 5772786 +0.75 7 3-7 7.92
Drill holes typically penetrated stiff clay from ground surface to 3 m below ground level, which was underlain by a pale grey sandy clay unit. One bore, MW1, penetrated the sandy clay to a stiff clay at 9 m. Bore construction logs are included in Attachment B. Monitoring bores were developed using a bailer to remove at least 5 bore volumes. Developed water had moderately salinity (electrical conductivity from 6.1 to 7.9 mS/cm indicating a salinity of 3,600 to 4,800 mg/L total dissolved solids). Developed water appeared to be alkaline (pH of up to 9.5) but the pH meter was not considered reliable during bore development and groundwater pH should be confirmed during groundwater sampling. No odour or sheens were noticed in the development. Development records are included in Attachment C. The depth to water recovered to approximately 3 m below ground level in the three bores. The rate of recovery in the monitoring bores was reasonable after development suggesting that the clay sand aquifer at the site has low to moderate hydraulic conductivity.
• MW2
• MW1
• MW3
60 m (approx.)
EarthEon Pty Ltd
Proposal: Drilling Supervision for Camperdown Compost Company
Recommendations The following steps are recommended to assess groundwater quality at the site and establish a groundwater sampling plan to comply with Corangamite Compost Company’s EPA licence:
! Conduct a survey of monitoring bores (steel cover, ground and PVC) including location and elevation to Australian Height Datum. This is critical to determine groundwater flow direction.
! Determine groundwater elevations to estimate groundwater flow direction. ! Sample the three newly installed monitoring bores in line with EPA sampling
guidelines and analysis by NATA accredited laboratory. ! Analytes to be included but not limited to: total dissolved solids, pH, major ions,
metals, total petroleum hydrocarbons, nutrients, BTEX, OCPs, OPPs and polyromantic hydrocarbons. It may be necessary to conduct a broader screen than this in the initial sampling round or if further information is forthcoming about the wastes received at the site.
! Conduct analysis of groundwater sampling results to confirm the relevant beneficial uses of groundwater at the site are protected.
! Develop a groundwater management plan outlining the ongoing monitoring requirements for the site to comply with Corangamite Compost Company’s EPA licence. The groundwater management plan should include sampling frequency, technique, analyte list, trigger levels and contingency measures.
Closure Please contact the undersigned if you wish to discuss any aspect of this letter. Regards
Ben Hall Principal Hydrogeologist M 0499 006 625 E [email protected]
EarthEon Pty Ltd
Proposal: Drilling Supervision for Camperdown Compost Company
Attachment A : Works Licence
Copy of RecordPrinted on: 03 Jun 2015 4:00:10 pm
Works Licence ID:WLE062257
Page 1 of 5
Works Licence ID:
WLE062257Printed on: 03 Jun 2015 4:00:10 pm
COPY OF RECORD IN THE VICTORIAN WATER REGISTER
LICENCE TO CONSTRUCT WORKSunder Section 67 of the Water Act 1989
The information in this copy of record is as recorded at the time of printing. Current information should be obtained bya search of the register. The State of Victoria does not warrant the accuracy or completeness of this information andaccepts no responsibility for any subsequent release, publication or reproduction of this information.
This licence does not remove the need to apply for any authorisation or permission necessary under any other Act ofParliament with respect to anything authorised by the works licence.
Water used under this licence is not fit for any use that may involve human consumption, directly or indirectly, withoutfirst being properly treated.
This licence is not to be interpreted as an endorsement of the design and/or construction of any works (including dams).The Authority does not accept any responsibility or liability for any suits or actions arising from injury, loss, damage ordeath to person or property which may arise from the maintenance, existence or use of the works.
Each person named as a licence holder is responsible for ensuring all the conditions of this licence are complied with.
This licence authorises its holders to construct the described works, subject to the conditions.
Licence Holder(s)CAMPERDOWN COMPOST CO of 4915 PRINCES HIGHWAY CAMPERDOWN VIC 3260
Licence Contact DetailsCAMPERDOWN COMPOST CO 4915 PRINCES HIGHWAY
CAMPERDOWN VIC 3260
Licence DetailsExpiry date 03 Jun 2016Status ActiveAuthority Southern Rural Water
Name of waterway or aquifer UNC-UnincorporatedWater system Unincorporated (GMU)
Summary of Licensed Works
The details in this section are a summary only. They are subject to the conditions specified in this licence.
Works ID Works type Use of waterWRK086854 Bore Observation or investigationWRK086855 Bore Observation or investigationWRK086856 Bore Observation or investigation
Description of Licensed Works
WORKS ID WRK086854
Copy of RecordPrinted on: 03 Jun 2015 4:00:10 pm
Works Licence ID:WLE062257
Page 2 of 5
Works type Bore
Works subtype Drilled bore
Proposed maximum depth 25.000 metres
Extraction DetailsUse of water Observation or investigation
Works locationEasting Northing Zone MGA682113 5772785 Zone 54
Land descriptionVolume 8924 Folio 119Lot 3 of Plan TP430209L
Property addressBLIND CREEK ROAD, BOOKAAR, VIC 3260
Description of Licensed Works
WORKS ID WRK086855
Works type Bore
Works subtype Drilled bore
Proposed maximum depth 25.000 metres
Extraction DetailsUse of water Observation or investigation
Works locationEasting Northing Zone MGANil
Land descriptionVolume 8924 Folio 119Lot 3 of Plan TP430209L
Property addressBLIND CREEK ROAD, BOOKAAR, VIC 3260
Description of Licensed Works
WORKS ID WRK086856
Works type Bore
Works subtype Drilled bore
Proposed maximum depth 25.000 metres
Extraction DetailsUse of water Observation or investigation
Copy of RecordPrinted on: 03 Jun 2015 4:00:10 pm
Works Licence ID:WLE062257
Page 3 of 5
Works locationEasting Northing Zone MGANil
Land descriptionVolume 8924 Folio 119Lot 3 of Plan TP430209L
Property addressBLIND CREEK ROAD, BOOKAAR, VIC 3260
Related InstrumentsRelated entitlements Nil
Related water-use entities Nil
Application HistoryReference Type Status Lodged date Approved date Recorded dateWLI018495 Issue Approved 03 Jun 2015 03 Jun 2015
Copy of RecordPrinted on: 03 Jun 2015 4:00:10 pm
Works Licence ID:WLE062257
Page 4 of 5
ConditionsLicence WLE062257 is subject to the following conditions:Siting and construction1 The bore must be constructed on the land described in the licence, at coordinates E: 682113.0,
N: 5772785.0, Zone: 54.2 The bore(s) must be drilled at the location specified in the application approved by the
Authority, but if after drilling a bore is considered unsatisfactory, a replacement bore may bedrilled at an alternative site no greater than 20 metres from the authorised site and no closer toneighbouring bores or nearby waterways, or as authorised by the Authority before thecommencement of drilling.
Preventing pollution3 $OO�HDUWKZRUNV�PXVW�EH�FDUULHG�RXW��DQG�DOO�GULOOLQJ�IOXLGV�DQG�ZDWHUV�SURGXFHG�GXULQJ
FRQVWUXFWLRQ�DQG�GHYHORSPHQW�PXVW�EH�GLVSRVHG�RI��LQ�ZD\V�WKDW�DYRLG�FRQWDPLQDWLQJ�QDWLYHYHJHWDWLRQ��ZDWHUZD\V��DTXLIHUV��WKH�ULSDULDQ�HQYLURQPHQW��WKH�ULYHULQH�HQYLURQPHQW�RU�RWKHUSHRSOH¶V�SURSHUW\�
4 &RQVWUXFWLRQ�PXVW�VWRS�LPPHGLDWHO\�LI�WKH�$XWKRULW\�UHDVRQDEO\�EHOLHYHV�WKDW�IXHO��OXEULFDQW�GULOOLQJ�IOXLG��VRLO�RU�ZDWHU�SURGXFHG�GXULQJ�FRQVWUXFWLRQ�DQG�GHYHORSPHQW�LV�DW�ULVN�RI�EHLQJVSLOOHG�LQWR�QDWLYH�YHJHWDWLRQ��ZDWHUZD\V��DTXLIHUV��WKH�ULSDULDQ�HQYLURQPHQW��WKH�ULYHULQHHQYLURQPHQW�RU�RWKHU�SHRSOH¶V�SURSHUW\�
5 7KH�OLFHQFH�KROGHU�PXVW�FRQVWUXFW�DQG�PDLQWDLQ�EXQG�ZDOOV��LQ�DFFRUGDQFH�ZLWK�WKH�WLPHIUDPH�VSHFLILFDWLRQV��JXLGHOLQHV�RU�VWDQGDUGV�SUHVFULEHG�E\�WKH�$XWKRULW\��WR�SUHYHQW�IXHO��OXEULFDQW�GULOOLQJ�IOXLG��VRLO�RU�ZDWHU�SURGXFHG�GXULQJ�FRQVWUXFWLRQ�DQG�GHYHORSPHQW�IURP�EHLQJ�VSLOOHGLQWR�QDWLYH�YHJHWDWLRQ��ZDWHUZD\V��DTXLIHUV��WKH�ULSDULDQ�HQYLURQPHQW��WKH�ULYHULQH�HQYLURQPHQWRU�RWKHU�SHRSOH¶V�SURSHUW\�
Construction standards6 The bore(s) must be constructed, and where relevant decommissioned, in accordance with the
Minimum Construction Requirements for Water Bores in Australia, Edition 3.
Drilling licence and supervision requirements7 The bore(s) must be constructed by, or under the direct supervision of, a driller licensed under
the Water Act 1989 and endorsed as a Class 1, 2, or 3 driller, with appropriate endorsements.8 The licence holder must ensure that the licensed driller notifies the Authority's Drilling
Inspector at least one day prior to work commencing on any grouting operations and must notproceed with the work unless authorised by the Drilling Inspector.
Bore completion report9 The licence holder must ensure that the licensed driller sends a Bore Completion Report to the
Authority within twenty-eight working days of the bore(s) being completed.10 The works referred to in the licence must not be made operational until the Authority
acknowledges receipt of an acceptable Bore Completion Report.11 The works referred to in the licence must not be made operational until the licence holder sends
a water sample to the laboratory nominated by the Authority.
Protecting water resources12 No more than 3 bore(s) may be brought to final development under this licence.13 At the completion of drilling, and before the drilling rig leaves the site, all but 3 bore(s) must
be decommissioned so as to eliminate physical hazards, conserve aquifer yield, preventgroundwater contamination and prevent the intermingling of desirable and undesirable waters.
Protecting water quality14 The bore(s) must be constructed so as to prevent aquifer contamination caused by vertical flow
outside the casing.15 If two or more aquifers are encountered, the bore(s) must be constructed to ensure that an
Copy of Record
Printed on: 03 Jun 2015 4:00:10 pm
Works Licence ID:WLE062257
Page 5 of 5
impervious seal is made and maintained between each aquifer to prevent aquifer connection
through vertical flow outside the casing; under no circumstances are two or more aquifers to be
screened within the one bore or in any other manner to allow connection between them.
16 Boreheads must be constructed, to ensure that no flood water, surface runoff or potential
subsurface contaminated soakage can enter the bore or bore annulus.
17 Drilling must not exceed the maximum depth unless the Authority approves, in advance,
drilling beyond this depth.
Protecting other water users18 7KH�OLFHQFH�KROGHU�PXVW��DW�WKH�OLFHQFH�KROGHU¶V�H[SHQVH��LI�UHTXLUHG�E\�WKH�$XWKRULW\��FRQGXFW�D
SXPSLQJ�WHVW�DQG�REWDLQ�D�K\GURJHRORJLFDO�UHSRUW��WR�WKH�$XWKRULW\V�VSHFLILFDWLRQ��RQ�WKHSRWHQWLDO�IRU�ERUH�RSHUDWLRQ�WR�LQWHUIHUH�ZLWK�DQ\�ERUH��DTXLIHU��JURXQGZDWHU�GHSHQGHQWHFRV\VWHP�RU�ZDWHUZD\�
Fees and charges19 The licence holder must, when requested by the Authority, pay all fees, costs and other charges
under the Water Act 1989 in respect of this licence.
END OF COPY OF RECORD
EarthEon Pty Ltd
Proposal: Drilling Supervision for Camperdown Compost Company
Attachment B : Bore Construction Logs
Bore Construction Log
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EarthEon Pty Ltd
Proposal: Drilling Supervision for Camperdown Compost Company
Attachment C : Bore Development Records
On Tue, May 16, 2017 at 2:06 PM, Graeme Jablonskas <[email protected]> wrote: Hi#Sam # IDs#have#been#amended#and#work#order#rereleased.#Reports#have#gone#to#Andrew#Jacovids#as#per#original#reports.#Did#you#need#a#copy? # Kind#Regards Graeme&Jablonskas&Senior#Project#Manager#–#Springvale�Environmental
T#+61#3#8549#9600##D#+61#3#8549#9609##F#+61#3#8549#9626# [email protected] 2Q4#Westall#Rd Springvale#Vic#3171 Australia
We are keen for your feedback! Please click here for your 1 question survey EnviroMail™#109#–#PFOS#Trace#Analysis#to#Meet#Trace#Guideline#Requirements EnviroMail™ 110 – Identifying Hidden PFAS Chemicals in Environmental Samples and Firefighting Foams EnviroMailTM 00 – Summary of all EnviroMailsTM by Category Subscribe to EnviroMailTM Follow us on LinkedIn
Right#Solutions#•#Right#Partner�www.alsglobal.com # From:#Samantha#GrantQVest#[mailto:[email protected]]##Sent:#Tuesday,#16#May#2017#1:43#PM#To:#Graeme#Jablonskas#<[email protected]>#Subject:#Request#for#ReQissue#of#report Hi Graeme, as per our conversation this afternoon, I would like you to re-issue an existing report with different sample ID's. The work order number is EM1702381 Client: SESL Australia Project: Camperdown Groundwater Could you please make the following changes: MW1 (EM1702381-001) should be re-named MW2 MW2 (EM1702381-002) should be re-named MW3 MW3 (EM1702381-003) should be re-named MW1
Please let me know if you need any further clarification on this. Thank you Graeme. Kind Regards, Samantha Grant-Vest Environmental Scientist B Env, B Hort T 1300 30 40 80 F 1300 64 46 89 E [email protected] M 0437 311 567
PLEASE CONSIDER THE ENVIRONMENT BEFORE YOU PRINT THIS E-MAIL The information in this email is confidential, privileged or otherwise protected by law from disclosure. If you are not the intended recipient, you must not read, use, copy, disclose or disseminate this email, any attachments or information contained in this email, and must delete it. The responsibility for virus detection is the recipients and we do not accept any responsibility for any loss or damage arising in any way from the use of this email or any attachments. Unless specifically stated; information in this email should not be treated as advice or relied upon. http://sesl.com.au/terms-and-conditions/ ABN 70 106 810 708 #
Groundwater Monitoring – May 2018 445 Sandy’s Lane Bookaar VIC 3260
Prepared for:
Camperdown Compost Company
July 2018
(Ref: J000990)
Camperdown Compost Company
Groundwater Monitoring – May 2018 445 Sandy’s Lane, Bookaar VIC
J000990 CamperdownCompostGME 2.0.docx
SESL Australia – July 2018
Page 1 of 25
Document Record
Revision No.
Reviewed By Action Issued To Date Release Authorisation Signature
0.1 Ryan Jacka Technical and peer review
SESL Internal 25/07/2018
1.0 Ryan Jacka Final review and minor corrections
Client 30/07/2018
2.0 A. Grigaliunas Final review and
minor corrections Client 12/05/2020
File Name: J000990 CamperdownCompostGME 2.0
Main Author: Stephen Cox
Qualifications: B Sc (Hons)
Role: Graduate Soil Scientist
Reviewer: Ryan Jacka
Qualifications: B Env Sc, M Env Sc, ASSSI, MEIANZ, CEnvP
Role: Senior Environmental Consultant
Final Reviewer Andres Grigaliunas
Qualifications: BSc (Mar Biol), GradDip Env Mgmt, Prin Env Aud
Role: Principal Environmental Scientist, National Environmental Manager
Client: Camperdown Compost Company
Document Title: Camperdown Compost Groundwater Monitoring – May 2018
Document Version: Final 2.0
Reference Number: J000990
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Our Ref: J000990 CamperdownCompostGME 1.0.docx
Camperdown Compost Company 4915 Princes Hwy Camperdown VIC 3260
Re: Camperdown Compost Groundwater Monitoring – May 2018
Attn: Nick Rouston
1. INTRODUCTION
SESL Australia was commissioned to conduct groundwater monitoring for the Camperdown Compost Company (the client) at their composting facility located at 445 Sandy’s Lane, Bookaar (the site). These works are the second groundwater monitoring event conducted at the site by SESL. The groundwater monitoring program requires and are part of the ongoing groundwater monitoring program that SESL initiated on behalf of the client in 2017.
2. OBJECTIVES AND SCOPE OF WORK
The primary objectives of the monitoring at this site are to:
• Determine the contamination status of groundwater from site related activities;
• Compare groundwater results with relevant assessment criteria based on beneficial use of
groundwater; • Compare groundwater results with previous benchmark testing to determine trends in
groundwater analytes; and
• Determine ongoing associated trends in future.
The scope of works performed by SESL environmental scientists is as follows:
• Gauge the three existing site groundwater monitoring wells to obtain depths to groundwater and
record any observation (hydrocarbon odours, sheen or other physical evidence of contamination);
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• Sample monitoring wells by low-flow method involving a micropurge pump, as per methods
described in the February 2017 Groundwater Monitoring Plan (GMP) and Groundwater Sampling Guidelines (EPA Vic 2000) and collection of field water quality parameters;
• Conduct laboratory analysis of groundwater samples for potential contaminants of concern
(PCoC); • Collect trip and rinsate blanks, along with quality control blind duplicate samples for quality
assurance purposes as per the requirements in the February 2017 GMP; and • Prepare a short summary report.
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3. SITE INFORMATION
The Camperdown Compost Company (Figure 1) receives liquid and solid waste from regional industries and turns waste materials into compost for agricultural and horticultural application. The site is located within a Victorian district (Table 1) dominated by agricultural and horticultural use.
Figure1-SiteLocation
A pair of solar powered boom gates allow vehicular access to the site. Waste is accepted at a receiving area where a concrete pad and wash-down pump are located. Waste materials are taken to the centre of the site, from which numerous windrows extend. The compost is turned systematically and matures in windrows until such time as the materials are fully composted and are ready for dispatch. A clay bund forms the perimeter of the site, enclosing the composting field and two leachate storage dams. Additional infrastructure at the site includes:
• 2 x 37,000 Litre water tanks which are used for washing trucks; and
• 3m x 4m tool shed.
Table 1 – Site Information
Site Address 445 Sandy’s Lane, Bookaar Victoria, 3260
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Approximate Investigation Area 3.7ha
Title Identification Lot 3 TP 430209
Current VIC EPA Licence 13415 (Amended 20th August 2014)
Local Government Area Corangamite Shire Council
Current Zoning FZ1- Farming Zone, Schedule 1
Current Site Use Composting facility
Surrounding Land Use FZ1- Farming Zone, Schedule 1 (in all directions)
Surface Water Bodies Blind Creek – 450m west
Mount Emu Creek – 11km west
Lake Bookaar – 9km north-east
Lake Gnotuk – 11.5km east
3.1.1 Site Activities
Windrow Layout
The materials to be composted are received at the centre of the site. The site has a number of large windrows, approximately four to five metres high, that start in the central drop off point and move out at either end of the site. The windrows are immature at the central point, and mature as they reach the end, resulting in a continuous composting process, rather than a batch system.
Liquids
Liquids are dropped off in the middle of the site and are moved by gravity down between the windrows as detailed above. On a weekly, or less frequent basis, the liquid is covered by pushing the top off one of the adjoining windrows. The windrow is then turned backwards and stood back up. This adds the moisture to the windrow as it is turned back.
Compost Monitoring
Weekly production meetings provide the forum for planning and monitoring; in which production processes such as moisture levels and windrow turning are discussed. Odour monitoring occurs both onsite and offsite.
Fate of waste materials
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All materials that are received on site enter into the composting process. Materials are not stored prior to processing, and little pre-treatment or screening of materials occur. Some of the green organics entering the site may have obvious foreign materials removed if there is evidence of contamination with plastic or glass. In most cases, this is screened before being delivered.
Materials Received
A summary of the materials received and the potential contaminants of concern (PCoC) are summarised below:
Table 2 – Summary of Materials Received at the Camperdown Compost Company Site and PCOCs
WASTE CODE DESCRIPTION PCoC
K100 Animal effluent and residues. Pathogens, nutrients, metals, total
organic carbon, animal oil (TRH).
K120 Grease interceptor trap effluent. Hydrocarbons (TRH, BTEX and PAH)
and metals.
K200 Food and beverage processing wastes, including animal and
vegetable oils and derivatives.
Hydrocarbons (TRH, BTEX and PAH),
metals, pathogens and nutrients.
L100 Car and truck wash waters. Hydrocarbons (TRH, BTEX, PAH),
metals; phenols, surfactants (nutrients).
L150 Industrial wash waters from cleaning, rinsing or washing
operations, e.g. textile cleaning processing effluent,
industrial plant and machinery washers, cooling tower wash
waters.
Volatile Organic Compounds (VOC)
including halogenated compounds,
solvents, TRH, BTEX, PAH, phenols,
PCB’s, pesticides and metals.
N150 Fly ash. Heavy metals (including boron,
molybdenum, iron and aluminium) and
PAH.
N190 Filter cake. Metals; nutrients, hydrocarbons;
pathogens.
T130 Inert sludges or slurries such as clay or ceramic
suspensions, drilling mud and pit water with negligible
hydrocarbon contamination.
Metals (including cadmium); TRH, BTEX,
PAH and volatile halogenated
compounds.
TRH = total recoverable hydrocarbons, PAH= polyaromatic hydrocarbon, BTEX= benzene, toluene, ethylbenzene and xylene.
Dams
There are two dams on the site; the larger dam closest to the facility has a capacity of approximately 3 ML. The smaller dam to the west of the site holds approximately 1 ML and is used as the reserve dam when the larger dam is reaching capacity.
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When the site was established, the client was advised that approximately 21.4 m of heavy clay underlay the site. After testing the elutriability of the clay, the client decided lining was not necessary and as such, both dams are un-lined. The client has observed high nutrient loads in the dam water at times.
Leachate Management
The dams are used to run rainwater off the site during the winter months. During the wetter months of the year, some windrows can also become saturated as liquid that is received is added into the windrows. In these circumstances, there is a drop out of high nutrient water that runs to the dam. There have been two cases in the last five years where untreated wastewater has been put straight into the dam. Each year, the dams are emptied back onto the site.
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4. GEOLOGY AND HYDROGEOLOGY
A detailed review of the regional geology and hydrogeology was prepared and reported with the initial groundwater monitoring event (SESL Australia 2017). Please refer to the previous report (C8080.B42507.Q6406.CC GME) for a summary of the regional geologic and hydrogeologic information for this site.
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5. REGULATORY FRAMEWORK FOR GROUNDWATER ASSESSMENT
In accordance with Section 16 (1) of the Environmental Protection Act 1970, groundwater is protected under the State Environment Protection Policy, Groundwater’s of Victoria (Groundwater SEPP), Gazette no. S160, Dec 1997 and varied Gazette no. G12, March 2002. This policy aims to maintain and where necessary improve groundwater quality in order that the existing and potential beneficial uses of groundwater are preserved.
5.1 Adopted Guideline Documentation
This groundwater investigation was conducted in accordance with:
• Australian and New Zealand Environment Conservation Council, Australian and New Zealand Guidelines for Fresh and Marine Water Quality, October 2000;
• Victorian Government State Environment Protection Policy, Waters of Victoria; • Victorian Government State Environment Protection Policy, Groundwaters of Victoria 1972, as
varied 19/3/2002; and • Victorian EPA Publication 669, Groundwater Sampling Guidelines, April 2000.
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6. FIELD WORK
6.1 Personnel
This GME was undertaken in accordance with guidelines listed in Section 4.1. Stephen Cox, SESL Graduate Soil Scientist and Declan McDonald, SESL Senior Soil Scientist conducted the GME on the 23rd of May 2018.
6.2 Groundwater Sampling Methodology
SESL consultants undertook a groundwater-monitoring event (GME) at the Camperdown Compost Company facility in accordance with the Victorian EPA Groundwater Sampling Guidelines (2000).
Prior to sampling, the wells were gauged and purged using a low-flow, micro- purge pump and low-density poly ethylene (LDPE) tubing. The pump was set to intersect groundwater within the screened section of the monitoring well. A calibrated water quality meter was used to measure field groundwater quality parameters during purging, and when field parameters were stabilised, the groundwater samples were collected. Purging log sheets are presented in Appendix A.
Only two wells (MW1 and MW2) were sampled as MW3 had been damaged by the weight of an encroaching compost windrow, which had filled with sand. Sampling was carried out using disposable nitrile gloves at each well. Re-useable sampling equipment was decontaminated between wells using deionized water and Decon 90. LPDE tubing, bladders and filters dedicated to each well were used. A field duplicate was sampled from MW1. A rinsate blank sample was collected off the interface probe after decontamination at the end of the sampling day.
Samples were collected in laboratory supplied containers with appropriate preservatives, stored in a chilled esky and transported to a NATA accredited laboratory for analysis with a signed chain of custody form (Appendix A).
Groundwater samples were collected from two groundwater monitoring wells (MW1 & MW2) at the site and were analysed for the following PCoCs:
• Total recoverable hydrocarbons (TRH);
• Polycyclic aromatic hydrocarbons;
• Heavy metals (As, Cd, Cr, Cu, Ni, Pb, Zn, Hg);
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• Organochlorine and organophosphate pesticides (OCPs and OPPs);
• Polychlorinated biphenyls (PCB);
• Benzene, ethylbenzene, toluene and xylenes (BTEX);
• Total organic carbon (TOC);
• Major cations (calcium, magnesium, sodium and potassium) and anions (chloride);
• Volatile organic compounds (VOC’s); and
• Bacteria (E.coli, faecal coliforms, Salmonella spp. And Legionella).
6.2.1 Groundwater Elevations and Inferred Groundwater Flow
Standing water levels (SWL) were measured from the top of the well casing and recorded. The elevations of the top of the well casings were surveyed by a licensed surveyor (Alan H. Simpson Land Surveyor Pty Ltd) to the Map Grid of Australia (MGA) and Australian Height Datum (AHD) (See Appendix B from 2017 GME report). As groundwater flow can’t be determined from two points (Table
3), it is not possible to determine flow direction from this monitoring event. The groundwater flow direction from previous monitoring was determined to be towards the west of the site (Figure 2), this is assumed to be correct for this current monitoring event although it cannot be confirmed until MW3 is reinstalled.
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Figure 2 – Groundwater flow direction at Camperdown Compost Company site from March 2017 GME, Bookaar, Victoria, Australia
Table 3 – Groundwater Levels
Bore ID
Easting Northing Bore Depth (MBTOC)
Natural Surface (M AHD)
Top of Casing (M AHD)
Standing Water Level (MBTOC)
Reduced Level (M AHD)
Screen Interval (MBTOC)
MW2 681979.086 5772821.750 7.785 137.768 138.560 3.130 135.430 3-7 MW1 682027.116 5772822.089 9.700 137.901 138.657 3.182 135.475 3-9
Groundwater levels and gauging results are recorded in the purging log sheets provided in Appendix A and the groundwater flow direction map based on gauging data from the May 2018 GME is provided in Figure 2.
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6.2.2 Field Water Quality Parameters
A summary of the water quality parameters observed in the field is given in Table 4.
Table 4 - Summary of Water Quality Parameters for Groundwater
Water Quality Parameter MW1 MW2 Temperature range (C) 15.1 15.0 Electrical conductivity (µS/cm) 5004 6569 pH 7.11 7.27 ORP/Eh2 (mv) -109 -82.3 DO (mg/L) 1.48 1.43 Turbidity First 4 litres extracted were muddy
brown, clearing to clear/brown with subsequent extraction.
First 7 litres extracted were muddy brown, clearing to clear/brown with subsequent extraction.
Other No odour detected. No oil sheen in bailer.
No odour detected. No oil sheen in bailer.
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7 QUALITY ASSURANCE AND QUALITY CONTROL (QA/QC) RESULTS
As part of the SAQP in the February 2017 GMP report, data quality objectives (DQOs) and data quality indicators have been stated with targets for quality assurance and controls in accordance with the NEPM (NEPC 2013). The sections below outline the performance of fieldwork, sampling and analysis against DQI’s as a qualitative and quantitative assessment of the validity and usability of data collected at the site during this assessment.
7.1 Field QA/QC
A summary of the quality control sampling program is provided in Table 5 below and discussed within other subsections below.
The analytical results and RPD calculations for groundwater analyses are provided in Table A1 -Replicate Quality Samples (RPDS); Appendix A. The analytical results of the rinsate and travel blank samples are provided in Table A2- Black Quality Samples; Appendix A. Laboratory certificates are provided in Appendix A- Laboratory Analytical Results.
The following comments are made as a summary regarding the quality of the field and analytical components of this project:
• Water quality meter used during the fieldwork was hired from Air-Met Scientific Pty Ltd in
Nunawading Victoria. • Sample integrity and container requirements were documented as acceptable (refer to sample
receipt notifications at Appendix A).
• Holding time compliances were documented as acceptable. All samples were received by the laboratory within the relevant holding times (refer to sample receipt notifications in Appendix A).
• The primary (ALS) laboratory was NATA registered at the time of analysis and NATA accredited for all analyses performed.
Table 5 - Summary of Quality Control Program
Summary of Quality Sample Results from Analytical Table 1 and Analytical Table 2 Total RPD Comparisons 143 Total RPD >30% 2.8% min. target Achieved Quality Targets % RPD <= 30% 97.2% =>95% Y
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Total GW Primary 2 Total Primary 2 min. target actual Total Duplicates QAQC 1 5.0% 33.3% Y Count min. target >LOR QAQC 1 1 0 Y Total Rinsate Blanks 1 1 0 Y Total Trip Blanks 1 1 0 Y
7.2 Laboratory QA/QC
Laboratory QA/QC for groundwater analysis comprised of chain-of-custody documentation, sample integrity and holding times, sample temperatures on receipt, use of acceptable NATA-registered laboratory methods and laboratory QA/QC results. A summary is provided in Table 6 below.
ALS has provided a QA/QC report of laboratory control samples performance and other quality performance records provided with laboratory certificates in Appendix A. A performance summary is provided below in Section 6.3.
Table 6 – Summary of Laboratory Quality Control Programme
Lab Report # Quality Control Samples Holding times Frequency of Quality Control Samples
ALS EM1808482_0_QCl Laboratory control spikes for Organophosphorus pesticides (OP) Parathion and Azinphos-methyl were outside the upper control limit.
Matrix spikes for chloride could not be determined as background concentrations exceeded spike levels.
Laboratory recovery for Mercury was less than the lower data quality objective.
No sample analysis holding times were exceeded.
Laboratory duplicates and matrix spikes for Polycyclic Aromatic Hydrocarbons (PAH)/phenols, Pesticides, Polychlorinated Biphenyls (PCB) and Total Recoverable Hydrocarbons were not analysed at the required rate.
These analytes were not present in the groundwater samples submitted for analysis.
7.3 Performance Against Data Quality Indicators
Quality control qualitative and quantitative results from fieldwork and laboratory analyses have been compared in Table 7 below against the DQIs.
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Table 7 – Data Quality Evaluation Summary
Data Quality Objectives Sampling Frequency Required
Frequency Achieved?
DQI 95% DQI Met?
Precision Field duplicates 1/20 (>=5%) Yes- 33.3% <=30% Yes Laboratory duplicates (ALS)
1/20 Yes <=30% Yes exceptions are listed in Table 6 above.
Laboratory method blanks 1 per batch Yes <LOR Yes Accuracy Laboratory matrix spikes 1/20 Yes 70 to 130 % Yes Laboratory control samples
1/20 Yes Yes
Representativeness Sampling handling storage and transport appropriate for media and analyses
- - Yes Samples chilled and transported in accordance with COC requirements.
Rinsate blank 1 per day Yes- 1 sample
<LOR Yes
Trip blank 1 per trip Yes- 1 sample
<LOR Yes
Samples extracted and analysed within holding times
- - 24hrs- Bacteria, 14 days- organics, 6 months-inorganics, Iron- 7 days.
Yes
Comparability Standard operating procedures used for sample collection and handling (including decontamination)
All samples - Yes All samples completed in accordance with SESL standard operating procedures.
Standard operating procedures used for sample collection and handling (including decontamination)
1 Rinsate blank during programme
Yes <LOR Yes, collected off the interface probe after decontamination at the end of the sampling day.
Standard analytical methods used for all analyses
All samples - Yes NATA accredited methods used for all analyses.
Consistent field conditions, sampling staff and laboratory analysis
All samples - Yes All field work completed by Stephen Cox, Graduate Soil Scientist and Declan McDonald, Senior Soil Scientist.
All laboratory analysis completed by NATA accredited laboratories (ALS).
Limits of reporting appropriate and consistent
All samples - Yes Yes-all LORs below investigation levels.
Completeness
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COC completed and appropriate
All samples - Yes Refer to Appendix B for laboratory certifications and signed COCs
Appropriate documentation
All samples - Refer to Appendix A for groundwater sampling logs.
Notes: DQI= Data Quality Indicator LOR= laboratory’s limit of reporting RPD= relative percentage difference COC= Chain of custody documentation
7.4 Statement on Data Quality
Overall, the data quality objectives were met during the investigation, as demonstrated throughout this report. Documentation was maintained, and complete, sufficient data was collected to characterise the site in accordance with statutory requirements. The data has been shown to be comparable and representative of the site, and precision and accuracy has been demonstrated in the field and laboratory QA/QC programs.
The overall data quality performance against DQIs indicates that the analytical data is representative of site conditions at the time of the investigation as well as suitable to enable valid assessment of the site.
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8 ANALYTICAL RESULTS SUMMARY
Discrete groundwater samples collected at the site in May 2018 were analysed for selected PCoCs described below. Analytical results are summarised below and in Table 8.
8.1 Groundwater Results
The concentrations in groundwater samples were compared with the guidelines outlined in Section 5 of this report and benchmark groundwater testing conducted at this site in 2017. The results are summarized in Appendix A and discussed below. The results are summarised in Appendix A (Table A3) and discussed below.
Groundwater samples were not collected from MW3 due to the destruction of the monitoring well.
8.1.1 Dissolved Hydrocarbons
All groundwater samples were analysed for hydrocarbons (BTEX, TRH, PAH’s) with results presented in Analytical Table 3 (Appendix A).
• MW1 and MW2 did not contain any detectable traces of hydrocarbons. This is consistent with previous testing done on site.
8.1.2 Dissolved Heavy Metals
All groundwater samples were analysed for heavy metals (As, Cd, Cr, Cu, Ni, Pb, Zn, Hg). A summary of metal exceedance is provided Table 8. Metal exceedances are noted to be marginal.
Metal exceedances were recorded for MW1 for zinc, copper and nickel, in previous benchmark testing it had exceedances for zinc only. Lead was also detected above the laboratory limit of reporting (LOR) but below guideline criteria. MW2 has no metal exceedances; however copper was detected above the laboratory limit of reporting (LOR). These results differ slightly to previous benchmark testing conducted in 2017, with MW1 only having exceedances in zinc and MW2 having exceedances in nickel, zinc and copper. These exceedances while marginal will need to monitored to confirm if the impacts are from site activity. Arsenic, chromium, cadmium, and mercury levels were below the LOR for both wells.
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Table 8. Summary of Metals of Concern in Sampled Groundwater
Contaminant(mg/L)
WellIdentification GuidelineCriteria(mg/L)
MW1 MW2 MW3
ANZECC2000
Freshw
aterAquatic
Ecosystems
ANZECC2000
RecreationalWater
Quality
ADWG2015
RecreationalWater
Quality(DWGx10)
ANZECC2000Livestock
DrinkingWater–low
risk
Nickel 0.016 <0.001 NotTested 0.011 0.1 - 1.0
Zinc 0.036 0.006 NotTested 0.008 5.0 5.0 20
Copper 0.022 <0.001 NotTested 0.0014 1.0 2.0 0.4
Lead 0.002 <0.001 NotTested 0.0034 0.05 0.1 0.1
* Bold text denotes exceedance of adopted guideline criteria
8.1.3 PCBs, OCPs, OPPs
Concentrations of PCB’s, OCP’s and OPP’s remained below the laboratory Limit of Reporting (LOR). This is consistent with previous testing done on site.
8.1.4 Pathogens Legionella sp. remained below the LOR in all sampled wells. Escherichia coli and faecal coliforms remained below the LOR for MW2 but were above the LOR in MW1, but these were still below guideline criteria. Salmonella spp. was not detected in any samples.
The levels of Escherichia coli and faecal coliforms in MW1 have increased since benchmark testing was completed. These levels are still below guideline criteria, however these will need to monitored to determine if they are being caused by on-site activity.
8.1.5 Major Cations and Anions
Exceedances in all wells in the range of (1730-2480 mg/L) were detected for chloride and exceedances in all wells in the range of (787-1260 mg/L) were observed in sodium when compared against the ANZECC (2000) criteria for Recreational water quality and aesthetics. These exceedances are similar or lower than previous benchmark testing. It was determined from this benchmark testing that the exceedances were unlikely to be related to site activities based on comparison of concentration of the up-gradient well MW3, while this is still likely to be the case it cannot be demonstrated in this round of testing as sampling was not possible from MW3 due to well damage.
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8.1.6 Volatile Organic Compounds (VOCs)
Concentrations of VOC’s were below the laboratory Limit of Reporting (LOR). VOC’s were included in this round of testing to determine if there was any potential contamination from industrial waste water received on site. No contamination was detected, this data will form an important baseline for future testing.
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9 ASSESSMENT SUMMARY
On behalf of Camperdown Compost Company, SESL conducted this GME in May 2018, which included the following:
• Gauging of groundwater monitoring wells; • Preparation and interpretation of groundwater flow map and suitability of installed wells; • Groundwater monitoring event including low-flow sampling methodology of two groundwater
monitoring wells at the site, sampling was unable to be conducted for MW3 due to well damage; • Laboratory analysis for PCoCs; • Reporting the results of fieldwork and laboratory analysis of groundwater samples; and • The assessment data was compared with data quality indicators, which indicated that the data
quality has met the objectives and regulatory requirements, and the data discussed is therefore likely to be indicative of site conditions.
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10 CONCLUSIONS AND RECOMMENDATIONS
Due to the destruction of MW3, it is not possible to determine groundwater flow direction. Based on the calculated groundwater flow direction from the 2017 monitoring event MW3 was located hydraulically up-gradient, MW1 and MW2 are hydraulically cross-gradient and down-gradient. While it is likely that groundwater flow direction remains the same this will need to be confirmed once MW3 is repaired.
Metal (copper, zinc and nickel) concentrations exceeded assessment criteria in MW1 which in previous testing only had exceedances for zinc, the zinc concentrations have also increased slightly. Lead levels have also increased but are still below assessment criteria. MW2 had no exceedances for metals despite having elevated nickel, copper and zinc levels during benchmark testing. While these exceedances are marginal the increases in zinc, lead, copper and nickel concentrations in MW1 will have to be monitored to determine if this increase in concentrations is a result of the migration of contaminants through the composting field or represent background groundwater quality fluctuations. However, the potential downstream positions of MW1 and MW2 and chemical characterisation of the groundwater indicate that site activities may be impacting on groundwater quality. This cannot be confirmed until MW3 is repaired.
E. coli and faecal coliforms were detected in MW1, these are still below assessment criteria but represent an increase in levels since benchmark tested was conducted. As MW1 is likely hydraulically down gradient for this site, it could represent potentially contamination from composting practices on site; however this will need to confirmed through future assessment.
Sodium and chloride levels in both wells exceeded ANZECC (2000) criteria for Recreational water quality and aesthetics, despite this both sodium and chloride levels are largely in-line or lower than previous testing done on-site. While previous testing indicated that the elevated levels of sodium and chloride may represent background groundwater quality for this area, due to the destruction of MW3 this cannot be confirmed until that well is repaired.
SESL recommends the following:
• MW3 must be decommissioned by an appropriate licensed driller. Decommission will likely
involve the drilling out of the well using mechanical auger to the depth of screen installation, and slurry filing the entire well void with a combined concrete/bentonite mix to hydraulically seal the well from the surface;
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• MW3 will require reinstallation in an approximate position prior to the next monitoring event.
Installation will also require well establishment to ensure water quality in MW3 is representative of the aquifer prior to sampling;
• Continue the groundwater monitoring program on a bi-annual basis (for at least the next 2 years
and annually thereafter), with further trend analysis of contaminant concentrations to understand any potential impact;
• Monthly monitoring of the water level in the dams and groundwater level in well MW1 and MW2 to understand the relationship between the dam and groundwater. This has not been done to date, and therefore the hydraulic connectivity cannot be determined;
• Undertake slug testing to determine hydraulic conductivity of the site; and
• Develop a conceptual site model for a more detailed understanding of the interaction of groundwater with dam water and future risk assessment.
ATTACHMENTS:
ANALYTICAL TABLES
A1- REPLICATE QUALITY SAMPLES
A2- BLANK QUALITY SAMPLES
A3- WATER QUALITY RESULTS
APPENDICES
APPENDIX A- GROUNDWATER SAMPLING FIELD SHEETS
CHAIN OF CUSTODY FORM
LABORATORY CERTIFICATES
LABORATORY ANALYTICAL RESULTS
Camperdown Compost Company
Groundwater Monitoring – May 2018 445 Sandy’s Lane, Bookaar VIC
J000990 CamperdownCompostGME 2.0.docx
SESL Australia – July 2018
Page 24 of 25
11 DISCLAIMER AND LIMITATIONS
The conclusions presented in this report are relevant to the conditions of the site and the state of legislation currently enacted at the date of this report. We do not make any representation or warranty that the conclusions in this report will be applicable in the future as there may be changes in the condition of the site, applicable legislation or other factors that would affect the conclusions contained in this report.
SESL Australia Pty Ltd has used a degree of skill and care ordinarily exercised by reputable members of our profession practicing in the same or similar locality. Conclusions are based on representative samples or locations at the site, the intensity of those samples being in accordance with the usual levels of testing carried out for this type of investigation. Due to the inherent variability soils and groundwater and the general environment, we cannot warrant that the overall condition of the site is identical or substantially similar to the representative samples.
This report has been prepared for Camperdown Compost Company Pty Ltd for the specific purpose to which it refers. No responsibility is accepted to any third party. Neither the whole of the report or any part or reference thereto may be published in any document, statement or circular nor in any communication with third parties without our prior written approval of the form and context in which it will appear.
This report and the information contained in it is the intellectual property of SESL. Camperdown Compost Company Pty Ltd is granted an exclusive license for the use of the report for the purpose described in the report.
COPYRIGHT: The concepts, information and design ideas contained in this document are the property of SESL Australia Pty Ltd (ABN 70106 810 708). Use or copying of this document in whole or in part without the written permission of SESL Australia constitutes an infringement of copyright.
Camperdown Compost Company
Groundwater Monitoring – May 2018 445 Sandy’s Lane, Bookaar VIC
J000990 CamperdownCompostGME 2.0.docx
SESL Australia – July 2018
Page 25 of 25
12 REFERENCES
• ANZECC and ARMCANZ (2000). Australian and New Zealand Guidelines for Fresh and Marine
Water Quality (October 2000);
• National Environmental Protection Council (NEPC) (2013). National Environment Protection (Assessment of Site Contamination) Measure 1999 (as amended April 2013);
• NHMRC & NRMMC (2011). Australian Drinking Water Guidelines (ADWG) - National Health and Medical Research Council & Natural Resource Management Ministerial Council.
• USEPA (2000). Guidance for the Data Quality Objectives Process, EPAC QA/G-4 DEC/600/r-96/055, United States Environmental Protection Agency Office of Environmental Information, Washington DC;
• VIC. Department of Environment, Land, Water & Planning (2015), Groundwater Resource Report;
• VIC EPA (2000) Groundwater Sampling Guidelines No.669;
• VIC EPA (2006) Hydrogeological Assessment (groundwater quality) Guidelines; publication no. 668;
• SESL Groundwater Monitoring Event 2017 Report C8080.B42507.Q6406. CC GME; and
• SESL Groundwater Monitoring Plan 2017 C8080Q6406B.
Appendix A
PURGING'FIELD,WATER,QUALITY,MEASUREMENTS,FORM Sampled,By: Stephen'Cox/Declan'McDonaldRepair,Actions,
and,notes:
WELL,ID: DATE: Photo,of,Well,HeadPhoto,of,First,Bail
Depth,of,Well: 9.700 mBTOCSample,
Depth:8.1 mBTOC
Sample,
Method:
Quality,
Samples:
Location: Camperdown'Compost Ref:Well,
Condition:
Well,
radius(m):0.025
H
Clock,TimeWater,
DepthPurge,Rate
Volume,
PurgedSpec.,Cond.1 ORP/Eh2 DO Turbidity
24,HR m L/min litres µS/cm mv mg/LNTU,/,
Desriptive
3.182
16:04 3.037 0.3 14.6 5031 7.19 H126.5 3.52
16:12 3.083 2 15.1 5073 7.14 H124.0 2.69
16:18 3.085 2 15.1 5014 7.12 H118.0 2.03
16:25 3.078 2 15.1 5009 7.11 H114.2 1.51
16:31 3.092 2 15.1 5013 7.11 H111.2 1.72
16:37 3.092 2 15.1 5004 7.11 H109.0 1.48
1'x'well'volume= 12.8 litresTOTAL,
PURGED
10.3 0.0 #DIV/0! 0.00 0.0 0.00 #DIV/0!
±'0.5'o'
Celsius
±'3% ±'0.1'standard'
units*
±'10'millivolts ±'0.3'
milligrams'per'
litre1.'µSiemens'per'cm(same'as'µmhos/cm)at'25'''C.2.'Oxidation'reduction'potential'(stand'in'for'Eh).*'The'±'0.1'may'not'always'be'obtainable,'especially'if'purging'and'sampling'with'bailers.'Therefore,'professional'judgement'may'be'needed.
**Visual'inspection'may'be'used'to'validate'turbidity,'and'professional'judgement'may'be'needed'to'indicate'if'turbidity'is'clear'or'stable
<HHH'3'Readings'Variance
Stabilisation'Criteria'for'3'consecutive'readings:''(Yeskis'and'Zavala,'2002) ±'10%'(when'>'10'NTUs)
maintained'at'<'10'NTUs,'consider'
stabilised**
muddy'Brown
muddy'Brown
Slightly'brown
slightly'brown
very'pale'brown'(sample'taken)
MinutesTemp.
CpH
Comments,[H,odour,=,
hydrocarbon,odour;,sl,=,
slight(ly)]
Guage
Muddy'Brown
MW1 23'May'18
Micropurge
Good
PURGING'FIELD,WATER,QUALITY,MEASUREMENTS,FORM Sampled,By: Stephen'Cox/Declan'McDonaldRepair,Actions,
and,notes:
WELL,ID: DATE: Photo,of,Well,HeadPhoto,of,First,Bail
Depth,of,Well: 7.785 mBTOCSample,
Depth:6.5 mBTOC
Sample,
Method:
Quality,
Samples:
Location: Camperdown'Compost Ref: MW1Well,
Condition:
Well,
radius(m):0.025
QAQC1
Clock,TimeWater,
DepthPurge,Rate
Volume,
PurgedSpec.,Cond.1 ORP/Eh2 DO Turbidity
24,HR m L/min litres µS/cm mv mg/LNTU,/,
Desriptive
3.130
12:50 3.487 5 2.5 15.2 6691 7.30 H86.9 8.83
13:00 3.515 5 2 15.2 6671 7.28 H90.6 8.32
13:15 3.675 5 2.5 15.2 6654 7.28 H96.0 7.73
13:20 3.885 5 2.2 15.2 6643 7.27 H90.7 2.95
13:42 3.645 5 2 15.2 6628 7.27 H90.2 1.62
14:06 3.426 5 1.5 15.1 6606 7.28 H92.0 1.55
14:22 3.297 3 0.5 15.0 6570 7.27 H89.0 1.45
14:35 3.296 0.5 15.0 6569 7.27 H82.3 1.43
1'x'well'volume= 9.1 litresTOTAL,
PURGED13.7 0.0 #DIV/0! 0.00 0.0 0.00 #DIV/0!
±'0.5'o'
Celsius
±'3% ±'0.1'standard'
units*
±'10'millivolts ±'0.3'
milligrams'per'
litre1.'µSiemens'per'cm(same'as'µmhos/cm)at'25'''C.2.'Oxidation'reduction'potential'(stand'in'for'Eh).*'The'±'0.1'may'not'always'be'obtainable,'especially'if'purging'and'sampling'with'bailers.'Therefore,'professional'judgement'may'be'needed.
**Visual'inspection'may'be'used'to'validate'turbidity,'and'professional'judgement'may'be'needed'to'indicate'if'turbidity'is'clear'or'stable
clear'(sample'taken)
<HHH'3'Readings'Variance
Stabilisation'Criteria'for'3'consecutive'readings:''(Yeskis'and'Zavala,'2002) ±'10%'(when'>'10'NTUs)
maintained'at'<'10'NTUs,'consider'stabilised**
muddy'brown
muddy'brown
slight'brown'(had'to'recharge)
clear/brown'(had'to'recharge)
clear/brown'(had'to'recharge)
clear/brown'(had'to'recharge)
MinutesTemp.
CpH
Comments,[H,odour,=,hydrocarbon,
odour;,sl,=,slight(ly)]
Guaging
muddy'brown
MW2 23'May'18
Micropurge
good
PURGING'FIELD,WATER,QUALITY,MEASUREMENTS,FORM Sampled,By: Stephen'Cox/Declan'McDonaldRepair,Actions,
and,notes:
WELL,ID: DATE: Photo,of,Well,HeadPhoto,of,First,Bail
Depth,of,Well: mBTOCSample,
Depth:mBTOC
Sample,
Method:
Quality,
Samples:
Location: Camperdown'Compost Ref:Well,
Condition:
Well,
radius(m):0.025
H
Clock,TimeWater,
DepthPurge,Rate
Volume,
PurgedSpec.,Cond.1 ORP/Eh2 DO Turbidity
24,HR m L/min litres µS/cm mv mg/LNTU,/,
Desriptive
1'x'well'volume= 0.0 litresTOTAL,
PURGED
0 0.0 #DIV/0! 0.00 0.0 0.00 #DIV/0!
±'0.5'o'
Celsius
±'3% ±'0.1'standard'
units*
±'10'millivolts ±'0.3'
milligrams'per'
litre1.'µSiemens'per'cm(same'as'µmhos/cm)at'25'''C.2.'Oxidation'reduction'potential'(stand'in'for'Eh).*'The'±'0.1'may'not'always'be'obtainable,'especially'if'purging'and'sampling'with'bailers.'Therefore,'professional'judgement'may'be'needed.
**Visual'inspection'may'be'used'to'validate'turbidity,'and'professional'judgement'may'be'needed'to'indicate'if'turbidity'is'clear'or'stable
<HHH'3'Readings'Variance
Stabilisation'Criteria'for'3'consecutive'readings:''(Yeskis'and'Zavala,'2002) ±'10%'(when'>'10'NTUs)
maintained'at'<'10'NTUs,'consider'
stabilised**
`
MinutesTemp.
CpH
Comments,[H,odour,=,hydrocarbon,
odour;,sl,=,slight(ly)]
MW3 24'May'18
Micropurge
Well'Damaged,'Samples'
unable'to'be'taken.
Table A1 - Replicate Quality Samples Table A1 - Replicate Quality Samples (Continued)
Biological BiologicalHalogenated
Benzenes
>C10
- C16
Frac
tion
min
us N
apht
hale
ne
(F2)
(SG)
>C10
- C40
Frac
tion
(sum
) (SG
)
Legi
onel
la
Pneu
mop
hila
Se
rogr
oup
1
Legi
onel
la
Pneu
mop
hila
Se
rogr
oup
2-14
Legi
onel
la Sp
ecie
s
Salm
onel
la sp
Sulfa
te as
SO4
- Tu
rbid
imet
ric
(filte
red)
Benz
ene
Tolu
ene
Ethy
lben
zene
Xyle
ne (m
& p
)
Xyle
ne (o
)
Xyle
ne To
tal
Tota
l BTE
X
Faec
al C
olifo
rms
E. C
oli
Hexa
chlo
robe
nzen
e
Alka
linity
(B
icar
bona
te as
Ca
CO3)
mg/L mg/L CFU/mL CFU/mL CFU/mL - mg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L CFU/100mL cfu/100 ml µg/L mg/LEQL 0.1 0.1 10 10 10 1 1 2 2 2 2 2 0.001 1 1 0.5 1
Lab Report Number Sample Code Field ID DateEM1808482 EM1808482002 MW2 23/5/18 <0.1 <0.1 <10 <10 <10 0#1 71 <1 <2 <2 <2 <2 <2 <0.001 <10 <10 <0.5 446EM1808482 EM1808482002 QAQC1 23/5/18 <0.1 <0.1 <10 <10 <10 0#1 70 <1 <2 <2 <2 <2 <2 <0.001 <10 <10 <0.5 456RPD 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 2
Comments#1 Not Detected
NA BTEX BTEX
EQL
Lab Report Number Sample Code Field ID DateEM1808482 EM1808482002 MW2 23/5/18EM1808482 EM1808482002 QAQC1 23/5/18RPD
Comments#1 Not Detected
Table A1 - Replicate Quality Samples (Continued) Table A1 - Replicate Quality Samples (Continued)
Lead Metals
Alka
linity
(C
arbo
nate
as
CaCO
3)
Alka
linity
(H
ydro
xide
) as
CaCO
3
Alka
linity
(tot
al) a
s Ca
CO3
Anio
ns To
tal
Catio
ns To
tal
Chlo
ride
Ioni
c Bal
ance
Sodi
um (f
ilter
ed)
Sodi
um A
bsor
ptio
n Ra
tio (f
ilter
ed)
TOC
Lead
(filt
ered
)
Arse
nic (
filte
red)
Cadm
ium
(filt
ered
)
Calc
ium
(filt
ered
)
Chro
miu
m (I
II+VI
) (fi
ltere
d)
Copp
er (f
ilter
ed)
Mag
nesiu
m
(filte
red)
Mer
cury
(filt
ered
)
Nick
el (f
ilter
ed)
mg/L mg/L mg/L meq/L meq/L mg/L % mg/L - mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L1 1 1 0.01 0.01 1 0.01 1 1 0.001 0.001 0.001 1 0.001 0.001 1 0.0001 0.001
32 <1 478 59.8 54.3 1730 4.82 787 10.8 2 <0.001 <0.001 <0.001 110 <0.001 <0.001 175 <0.0001 <0.00136 <1 492 60.6 55.3 1750 4.59 802 11 2 <0.001 <0.001 <0.001 112 <0.001 0.0034 178 <0.0001 0.00512 0 3 1 2 1 5 2 2 0 0 0 0 2 0 109 2 0 133
Metals
EQL
Lab Report Number Sample Code Field ID DateEM1808482 EM1808482002 MW2 23/5/18EM1808482 EM1808482002 QAQC1 23/5/18RPD
Comments#1 Not Detected
Table A1 - Replicate Quality Samples (Continued)
Pota
ssiu
m (f
ilter
ed)
Zinc
(filt
ered
)
4,4-
DDE
a-BH
C
Aldr
in
Aldr
in +
Diel
drin
b-BH
C
chlo
rdan
e
Chlo
rdan
e (c
is)
Chlo
rdan
e (tr
ans)
d-BH
C
DDD
DDT
DDT+
DDE+
DDD
Diel
drin
Endo
sulfa
n I
Endo
sulfa
n II
Endo
sulfa
n su
lpha
te
Endr
in
mg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L1 0.005 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2 0.5 0.5 0.5 0.5 0.5 0.5
8 0.006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.58 0.037 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 144 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Metals Organochlorine Pesticides Organochlorine Pesticides
EQL
Lab Report Number Sample Code Field ID DateEM1808482 EM1808482002 MW2 23/5/18EM1808482 EM1808482002 QAQC1 23/5/18RPD
Comments#1 Not Detected
Table A1 - Replicate Quality Samples (Continued) Table A1 - Replicate Quality Samples (Continued)
Endr
in al
dehy
de
Endr
in ke
tone
g-BH
C (L
inda
ne)
Hept
achl
or
Hept
achl
or e
poxi
de
Met
hoxy
chlo
r
Azin
opho
s met
hyl
Brom
opho
s-eth
yl
Carb
ophe
noth
ion
Chlo
rfenv
inph
os
Chlo
rpyr
ifos
Chlo
rpyr
ifos-m
ethy
l
Diaz
inon
Dich
lorv
os
Dim
etho
ate
Ethi
on
Fent
hion
Mal
athi
on
Met
hyl p
arat
hion
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L0.5 0.5 0.5 0.5 0.5 2 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2
<0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2<0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Organochlorine Pesticides Organochlorine Pesticides Organophosphorous Pesticides Organophosphorous Pesticides
EQL
Lab Report Number Sample Code Field ID DateEM1808482 EM1808482002 MW2 23/5/18EM1808482 EM1808482002 QAQC1 23/5/18RPD
Comments#1 Not Detected
Table A1 - Replicate Quality Samples (Continued) Table A1 - Replicate Quality Samples (Continued)
Mon
ocro
toph
os
Prot
hiof
os
Acen
apht
hene
Acen
apht
hyle
ne
Anth
race
ne
Benz
(a)a
nthr
acen
e
Benz
o(a)
pyr
ene
Benz
o(b+
j)flu
oran
then
e
Benz
o(g,
h,i)p
eryl
ene
Benz
o(k)
fluor
anth
ene Ch
ryse
ne
Dibe
nz(a
,h)a
nthr
ace
ne Fluo
rant
hene
Fluo
rene
Inde
no(1
,2,3
-c,
d)py
rene
Naph
thal
ene
Phen
anth
rene
Pyre
ne
PAHs
(Vic
EPA
List
)
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L ug/L2 0.5 1 1 1 1 0.5 1 1 1 1 1 1 1 1 1 1 1 0.5
<2 <0.5 <1 <1 <1 <1 <0.5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <0.5<2 <0.5 <1 <1 <1 <1 <0.5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <0.50 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
PAHPAHOrganophosphorous Pesticides
EQL
Lab Report Number Sample Code Field ID DateEM1808482 EM1808482002 MW2 23/5/18EM1808482 EM1808482002 QAQC1 23/5/18RPD
Comments#1 Not Detected
Table A1 - Replicate Quality Samples (Continued) Table A1 - Replicate Quality Samples (Continued)Polychlorinated
Biphenyls
Dem
eton
-S-m
ethy
l
Fena
mip
hos
Para
thio
n
Pirim
phos
-eth
yl
PCBs
(Sum
of t
otal
)
C6-C
9
C6-C
10
TPH
C10-
C14
Fr
actio
n
TPH
C15-
C28
Fr
actio
n
TPH
C29-
C36
Fr
actio
n
TRH
>C10
-C16
(afte
r sil
ica g
el cl
ean-
up)
TRH
>C16
-C34
TRH
>C34
-C40
TRH
C10-
C36
(Tot
al)
F1 m
inus
BTE
X
Styr
ene
Isop
ropy
lben
zene
n-Pr
opyl
benz
ene
1.3.
5-Tr
imet
hylb
enze
ne
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L0.5 0.5 2 0.5 1 20 20 50 100 50 0.1 100 100 50 20 <5 <5 <5 <5
<0.5 <0.5 <2 <0.5 <1 <20 <20 <50 <100 <50 <0.1 <100 <100 <50 <20 <5 <5 <5 <5<0.5 <0.5 <2 <0.5 <1 <20 <20 <50 <100 <50 <0.1 <100 <100 <50 <20 <5 <5 <5 <5
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
VOCTPHPesticides TPH
EQL
Lab Report Number Sample Code Field ID DateEM1808482 EM1808482002 MW2 23/5/18EM1808482 EM1808482002 QAQC1 23/5/18RPD
Comments#1 Not Detected
Table A1 - Replicate Quality Samples (Continued)
sec-
Buty
lben
zene
1.2.
4-Tr
imet
hylb
enze
ne
tert
-But
ylbe
nzen
e
p-Is
opro
pylto
ulen
e
n-Bu
tylb
enze
ne
Viny
l Ace
tate
2-Bu
tano
ne (M
EK)
4-M
ethy
l-2-
pent
anon
e (M
IBK)
2-H
exan
one
(MBK
)
Carb
on d
isul
fide
2.2-
Dic
hlor
opro
pane
1.2
Dic
hlor
opro
pane
cis-
1.3
-D
ichl
orop
ropa
ne
tran
s-1.
3-D
ichl
orop
ropa
ne
1.2-
Dib
rom
oeth
ane
(ED
B)
Dic
hlor
odifl
urom
etha
ne
Chlo
rom
etha
ne
Viny
l Chl
orid
e
Brom
omet
hane
Chlo
roet
hane
Tric
hlor
oflu
orom
etha
ne
1.1-
Dic
hlor
oeth
ene
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L<5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <50 <50 <5
<5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <50 <50 <5<5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <50 <50 <50 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
VOC VOC
EQL
Lab Report Number Sample Code Field ID DateEM1808482 EM1808482002 MW2 23/5/18EM1808482 EM1808482002 QAQC1 23/5/18RPD
Comments#1 Not Detected
Table A1 - Replicate Quality Samples (Continued)
Iodo
met
hane
tran
s-1.
2-D
ichl
oroe
then
e
1.1-
Dic
hlor
oeth
ane
cis-
1.2-
Dic
hlor
oeth
ene
1.1.
1-Tr
ichl
oroe
than
e
1.1-
Dic
hlor
opro
pyle
ne
Carb
on
Tetr
achl
orid
e
1.2-
Dic
hlor
oeth
ane
Tric
hlor
oeth
ene
Dib
rom
omet
hane
1.1.
2-Tr
ichl
oroe
than
e
1.3-
Dic
hlor
opro
pane
Tetr
achl
oroe
then
e
1.1.
1.2-
Tetr
achl
oroe
than
e
tran
s-1.
4-D
ichl
oro-
2-bu
tene
cis-
1.4-
Dic
hlor
o-2-
bute
ne
1.1.
2.2-
Tetr
achl
oroe
than
e
1.2.
3-Tr
ichl
orop
ropa
ne
Pent
achl
oroe
than
e
1.2-
Dib
rom
o-3-
chlo
ropr
opan
e
Hex
achl
orob
utad
iene Ch
loro
benz
ene
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
VOC VOC
EQL
Lab Report Number Sample Code Field ID DateEM1808482 EM1808482002 MW2 23/5/18EM1808482 EM1808482002 QAQC1 23/5/18RPD
Comments#1 Not Detected
Table A1 - Replicate Quality Samples (Continued)
Brom
oben
zene
2-Ch
loro
tolu
ene
4-Ch
loro
tolu
ene
1.3-
Dic
hlor
oben
zene
1.4-
Dic
hlor
oben
zene
1.2-
Dic
hlor
oben
zene
1.2.
4-Tr
ichl
orob
enze
ne
1.2.
3-Tr
ichl
orob
enze
ne
Chlo
rofo
rm
Brom
odic
hlor
omet
hane
Dib
rom
ochl
orom
etha
ne
Brom
ofor
m
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 0 0 0 0 0 0 0 0 0 0 0
VOC
Lead
Benzene
Toluene
Ethylbenzene
Xylene2(m
2&2p)
Xylene2(o
)
Xylene2Total
Total2B
TEX
Naphthalene
Lead
Arsenic
Cadm
ium
Chromium2(III+VI)
Copper
Mercury
Nickel
Zinc
C6FC9
C10FC14
C15FC28
C29FC36
C10FC362Sum
C6FC10
F12m
inus2BTEX
Styrene
Isopropylbenzene
nFPropylbenzene
1.3.5F
Trim
ethylbenzene
secFBu
tylbenzene
1.2.4F
Trim
ethylbenzene
tertFButylbenzene
pFIsopropylto
ulene
nFBu
tylbenzene
Vinyl2A
cetate
2FBu
tanone2(M
EK)
4FMethylF2
Fpentanone2(M
IBK)
2FHexanone2(M
BK)
Carbon2disulfid
e
2.2F
Dichloropropane
1.22
Dichloropropane
cisF21.3F
Dichloropropane
transF1.3F
Dichloropropane
1.2FDibromoethane2
(EDB)
Dichlorodiflurom
ethane
Chloromethane
Vinyl2Chloride
Brom
omethane
Chloroethane
Trichlorofluorom
ethane
1.1FDichloroethene
Iodomethane
transF1.2F
Dichloroethene
1.1FDichloroethane
cisF1.2F
Dichloroethene
1.1.1F
Trichloroethane
1.1F
Dichloropropylene
Carbon2
Tetrachloride
1.2FDichloroethane
Trichloroethene
Dibromom
ethane
1.1.2F
Trichloroethane
1.3F
Dichloropropane
Tetrachloroethene
1.1.1.2F
Tetrachloroethane
transF1.4FDichloroF
2Fbutene
cisF1.4FDichloroF2F
butene
1.1.2.2F
Tetrachloroethane
1.2.3F
Trichloropropane
Pentachloroethane
1.2FDibromoF3F
chloropropane
Hexachlorobutadie
ne Chlorobenzene
Brom
obenzene
2FChlorotoluene
4FChlorotoluene
1.3F
Dichlorobenzene
1.4F
Dichlorobenzene
1.2F
Dichlorobenzene
1.2.4F
Trichlorobenzene
1.2.3F
Trichlorobenzene
Chloroform
Brom
odichlorom
ethane
Dibromochlorom
ethane
Brom
oform
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
Lab2Report2NumberSample2Code Field2ID Date DepthEM1808482 EM1808482004 RB1 23/05/2018 <1 <2 <2 <2 <2 <2 <0.001 <5 <0.001 <0.001 <0.0001 <0.001 <0.001 <0.0001 <0.001 <0.005 <20 ' ' ' ' <20 <20EM1808482 EM1808482005 TB1 24/05/2018 <1 <2 <2 <2 <2 <2 <0.001 <5 <20 <50 <100 <50 <50 <20 <20 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Metals TPH VOCTable2A2_BLANKS2QUALITY2SAMPLES
BTEX
>C10
- C16
Frac
tion
min
us N
apht
hale
ne
(F2)
(SG)
>C10
- C40
Frac
tion
(sum
) (SG
)
Legi
onel
la
Pneu
mop
hila
Se
rogr
oup
1
Legi
onel
la
Pneu
mop
hila
Se
rogr
oup
2-14
Legi
onel
la Sp
ecie
s
Salm
onel
la sp
Sulfa
te as
SO4
- Tu
rbid
imet
ric
(filte
red)
Benz
ene
Tolu
ene
mg/L mg/L CFU/mL CFU/mL CFU/mL - mg/L µg/L µg/LEQL 0.1 0.1 10 10 10 1 1 2ANZECC 2000 slightly-moderately disturbed systems 950ADWG 2015 Aesthetic 25ADWG 2015 Health 1 800ANZECC 2000 FW 95% 950ANZECC 2000 Livestock DW Low Risk Trigger ValuesANZECC 2000 Rec Water Quality and Aesthetics: Primary contactANZECC 2000 Recreational water quality and aesthetics 10NEPM 2013 Table 1C GILs, Drinking Water 1 800NEPM 2013 Table 1C GILs, Fresh Waters 950NEPM 2013 Table 1A(4) Comm/Ind HSL D GW for Vapour Intrusion, Clay 2-4m 30,000 4-8m 30,000 >8m 35,000
Site IDLab Report Number Sample CodeField ID Date DepthEM1808482 EM1808482001MW1 23/5/18 <0.1 <0.1 <10 <10 <10 0#1 169 <1 <2EM1808482 EM1808482002MW2 23/5/18 <0.1 <0.1 <10 <10 <10 0#1 71 <1 <2
StatisticsNumber of Results 2 2 2 2 2 2 2 2 2Number of Detects 0 0 0 0 0 0 2 0 0Minimum Concentration <0.1 <0.1 <10 <10 <10 0 71 <1 <2Minimum Detect ND ND ND ND ND ND 71 ND NDMaximum Concentration <0.1 <0.1 <10 <10 <10 0 169 <1 <2Maximum Detect ND ND ND ND ND 0 169 ND NDAverage Concentration * 0.05 0.05 5 5 5 0 120 0.5 1Median Concentration * 0.05 0.05 5 5 5 0 120 0.5 1Standard Deviation * 0 0 0 0 0 0 69 0 095% UCL (Student's-t) * 0.05 0.05 5 5 5 0 429 0.5 1* A Non Detect Multiplier of 0.5 has been applied.0.5
Comments#1 Not Detected
Environmental StandardsDoE, 2000, ANZECC 2000 slightly-moderately disturbed systemsNHMRC, 2015, ADWG 2015 AestheticNHMRC, 2015, ADWG 2015 HealthDoE, 2000, ANZECC 2000 FW 95%DoE, 2000, ANZECC 2000 Livestock DW Low Risk Trigger ValuesDoE, 2000, ANZECC 2000 Rec Water Quality and Aesthetics: Primary contactDoE, 2000, ANZECC 2000 Recreational water quality and aesthetics
NA BTEX
Analytical Table A3- Results Analytical Table A3- ResultsAnalytical Table A3- Results
Halogenated Benzenes
Ethy
lben
zene
Xyle
ne (m
& p
)
Xyle
ne (o
)
Xyle
ne To
tal
Tota
l BTE
X
Faec
al C
olifo
rms
E. C
oli
Hexa
chlo
robe
nzen
e
Alka
linity
(B
icar
bona
te as
Ca
CO3)
Alka
linity
(C
arbo
nate
as
CaCO
3)
Alka
linity
(H
ydro
xide
) as
CaCO
3
Alka
linity
(tot
al) a
s Ca
CO3
Anio
ns To
tal
Catio
ns To
tal
µg/L µg/L µg/L µg/L mg/L CFU/100mL cfu/100 ml µg/L mg/L mg/L mg/L mg/L meq/L meq/L2 2 2 2 0.001 1 1 0.5 1 1 1 1 0.01 0.01
3503 20
300 600350
600
300 600350 550
<2 <2 <2 <2 <0.001 36 5 <0.5 458 87 <1 546 84.4 71.4<2 <2 <2 <2 <0.001 <10 <10 <0.5 446 32 <1 478 59.8 54.3
2 2 2 2 2 2 2 2 2 2 2 2 2 20 0 0 0 0 1 1 0 2 2 0 2 2 2
<2 <2 <2 <2 <0.001 <10 <10 <0.5 446 32 <1 478 59.8 54.3ND ND ND ND ND ND ND ND 446 32 ND 478 59.8 54.3<2 <2 <2 <2 <0.001 36 5 <0.5 458 87 <1 546 84.4 71.4ND ND ND ND ND 36 5 ND 458 87 ND 546 84.4 71.41 1 1 1 0.0005 18.25 2.75 0.25 452 59.5 0.5 512 72.1 62.851 1 1 1 0.0005 18.25 2.75 0.25 452 59.5 0.5 512 72.1 62.850 0 0 0 0 25 3.18 0 8.49 39 0 48 17 12.091 1 1 1 0.0005 130 16.96 0.25 489.88 233.1 0.5 726.7 149.76 116.83
BTEX Biological Inorganics
Analytical Table A3- Results Analytical Table A3- Results Analytical Table A3- Results
Lead
Chlo
ride
Ioni
c Bal
ance
Sodi
um (f
ilter
ed)
Sodi
um A
bsor
ptio
n Ra
tio (f
ilter
ed)
TOC
Lead
(filt
ered
)
Arse
nic (
filte
red)
Cadm
ium
(filt
ered
)
Calc
ium
(filt
ered
)
Chro
miu
m (I
II+VI
) (fi
ltere
d)
Copp
er (f
ilter
ed)
Mag
nesiu
m
(filte
red)
Mer
cury
(filt
ered
)
Nick
el (f
ilter
ed)
mg/L % mg/L - mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L1 0.01 1 1 0.001 0.001 0.0001 1 0.001 0.001 1 0.0001 0.001
0.0034 0.0002 0.0014 6E-05 0.011250 180 1
0.01 0.01 0.002 2 0.001 0.020.0034 0.0002 0.0014 0.0006 0.011
0.1 0.5 0.01 1 0.4 0.002 1
400 300 0.05 0.05 0.005 0.05 1 0.001 0.10.01 0.01 0.002 2 0.001 0.02
0.0034 0.0002 0.0014 6E-05 0.011
2480 8.32 1260 19.1 12 0.002 <0.001 <0.0001 62 <0.001 0.022 163 <0.0001 0.0161730 4.82 787 10.8 2 <0.001 <0.001 <0.0001 110 <0.001 <0.001 175 <0.0001 <0.001
2 2 2 2 2 2 2 2 2 2 2 2 2 22 2 2 2 2 1 0 0 2 0 1 2 0 1
1,730 4.82 787 10.8 2 <0.001 <0.001 <0.0001 62 <0.001 <0.001 163 <0.0001 <0.0011,730 4.82 787 10.8 2 ND ND ND 62 ND ND 163 ND <0.0012,480 8.32 1,260 19.1 12 0.002 <0.001 <0.0001 110 <0.001 0.022 175 <0.0001 0.0162,480 8.32 1,260 19.1 12 0.002 ND ND 110 ND 0.022 175 ND 0.0162,105 6.57 1,023.5 14.95 7.0 0.25 0.0005 0.00005 86 0.0005 0.26 169 0.00005 0.262,105 6.57 1,023.5 14.95 7.0 0.25 0.0005 0.00005 86 0.0005 0.26 169 0.00005 0.26
530.33 2.47 334.46 5.87 7.07 0.35 0 0 33.94 0 0.34 8.49 0 0.344,472.75 17.62 2,516.76 41.15 38.57 1.82 0.0005 0.00005 237.54 0.0005 1.77 206.88 0.00005 1.79
Inorganics Metals
Analytical Table A3- Results Analytical Table A3- Results Analytical Table A3- Results
Pota
ssiu
m (f
ilter
ed)
Zinc
(filt
ered
)
4,4-
DDE
a-BH
C
Aldr
in
Aldr
in +
Diel
drin
b-BH
C
chlo
rdan
e
Chlo
rdan
e (c
is)
Chlo
rdan
e (tr
ans)
d-BH
C
DDD
DDT
DDT+
DDE+
DDD
Diel
drin
Endo
sulfa
n I
Endo
sulfa
n II
Endo
sulfa
n su
lpha
te
Endr
in
Endr
in al
dehy
de
Endr
in ke
tone
g-BH
C (L
inda
ne)
mg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L1 0.005 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
0.008 0.03 0.006 0.01 0.23
0.3 2 9 100.008 0.08 0.01 0.02 0.2
20
5 1 6 3 1 1 100.3 2 9 10
0.008 0.03 0.006 0.01 0.2
4 0.036 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.58 0.006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 22 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 04 0.006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.54 0.006 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND8 0.036 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.58 0.036 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND6 0.02 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.256 0.02 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25
2.83 0.02 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 018.63 0.12 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25
Metals Organochlorine Pesticides
Analytical Table A3- Results Analytical Table A3- Results Analytical Table A3- ResultsAnalytical Table A3- Results
Hept
achl
or
Hept
achl
or e
poxi
de
Met
hoxy
chlo
r
Azin
opho
s met
hyl
Brom
opho
s-eth
yl
Carb
ophe
noth
ion
Chlo
rfenv
inph
os
Chlo
rpyr
ifos
Chlo
rpyr
ifos-m
ethy
l
Diaz
inon
Dich
lorv
os
Dim
etho
ate
Ethi
on
Fent
hion
Mal
athi
on
Met
hyl p
arat
hion
Mon
ocro
toph
os
Prot
hiof
os
Acen
apht
hene
Acen
apht
hyle
ne
Anth
race
ne
Benz
(a)a
nthr
acen
e
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L0.5 0.5 2 0.5 0.5 0.5 0.5 0.5 0.0005 0.5 0.5 0.5 0.5 0.5 0.5 2 2 0.5 1 1 1 1
0.01 0.01 0.01 0.01 0.15 0.05
0.3 30 10 0.5 2 10 4 5 7 4 7 70 0.7 20.09 0.02 0.01 0.01 0.15 0.05
3 10 20 1 10 2 10 20 100 6 100 6 20.3 30 2 10 4 5 7 4 7 70 0.7
0.01 0.01 0.01 0.15 0.05
<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.005 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <2 <0.5 <1 <1 <1 <1<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.005 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <2 <0.5 <1 <1 <1 <1
2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 20 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.0005 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <2 <0.5 <1 <1 <1 <1ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.0005 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <2 <0.5 <1 <1 <1 <1ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
0.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.00025 0.25 0.25 0.25 0.25 0.25 0.25 1 1 0.25 0.5 0.5 0.5 0.50.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.00025 0.25 0.25 0.25 0.25 0.25 0.25 1 1 0.25 0.5 0.5 0.5 0.5
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.00025 0.25 0.25 0.25 0.25 0.25 0.25 1 1 0.25 0.5 0.5 0.5 0.5
Organochlorine Pesticides Organophosphorous Pesticides PAH
Analytical Table A3- Results Analytical Table A3- Results Analytical Table A3- Results Analytical Table A3- Results
Polychlorinated Biphenyls
Benz
o(a)
pyr
ene
Benz
o(b+
j)flu
oran
then
e
Benz
o(g,
h,i)p
eryl
ene
Benz
o(k)
fluor
anth
ene Ch
ryse
ne
Dibe
nz(a
,h)a
nthr
ace
ne Fluo
rant
hene
Fluo
rene
Inde
no(1
,2,3
-c,
d)py
rene
Naph
thal
ene
Phen
anth
rene
Pyre
ne
PAHs
(Vic
EPA
List
)
Dem
eton
-S-m
ethy
l
Fena
mip
hos
Para
thio
n
Pirim
phos
-eth
yl
PCBs
(Sum
of t
otal
)
C6-C
9
C6-C
10
TPH
C10-
C14
Fr
actio
n af
ter S
ilica
Cl
eanu
p
TPH
C15-
C28
Fr
actio
n af
ter S
ilica
Cl
eanu
p
µg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L ug/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L mg/L mg/L0.5 0.001 1 1 1 1 1 1 1 1 1 1 0.5 0.5 0.5 2 0.5 1 20 0.02 0.05 0.1
16 0.004
0.01 0.5 20 0.516 0.004
0.01 30 10.01 0.5 20
16 0.004
<0.5 <0.001 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <0.02 <0.05 <0.1<0.5 <0.001 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <0.02 <0.05 <0.1
2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 20 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
<0.5 <0.001 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <0.02 <0.05 <0.1ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
<0.5 <0.001 <1 <1 <1 <1 <1 <1 <1 <5 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <0.02 <0.05 <0.1ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
0.25 0.0005 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.25 0.25 0.25 1 0.25 0.5 10 0.01 0.025 0.050.25 0.0005 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.25 0.25 0.25 1 0.25 0.5 10 0.01 0.025 0.05
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00.25 0.0005 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2.401 0.5 0.5 0.25 0.25 0.25 1 0.25 0.5 10 0.01 0.025 0.05
PAH Pesticides TPH
Analytical Table A3- Results Analytical Table A3- Results Analytical Table A3- Results Analytical Table A3- Results
TPH
C29-
C36
Fr
actio
n af
ter S
ilica
Cl
eanu
p
TRH
>C10
-C16
(afte
r sil
ica g
el cl
ean-
up)
TRH
>C16
-C34
(afte
r sil
ica g
el cl
ean-
up)
TRH
>C34
-C40
(afte
r sil
ica g
el cl
ean-
up)
TRH
C10-
C36
(Tot
al)
(afte
r sili
ca ge
l cle
an-
up)
F1 m
inus
BTE
X
Styr
ene
Isopr
opyl
benz
ene
n-Pr
opyl
benz
ene
1.3.
5-Tr
imet
hylb
enze
ne
sec-
Buty
lben
zene
1.2.
4-Tr
imet
hylb
enze
ne
tert-
Buty
lben
zene
p-Iso
prop
ylto
ulen
e
n-Bu
tylb
enze
ne
Viny
l Ace
tate
2-Bu
tano
ne (M
EK)
4-M
ethy
l-2-
pent
anon
e (M
IBK)
2-He
xano
ne (M
BK)
Carb
on d
isulfi
de
2.2-
Dich
loro
prop
ane
1.2
Dich
loro
prop
ane
cis- 1
.3-
Dich
loro
prop
ane
trans
-1.3
-Di
chlo
ropr
opan
e
1.2-
Dibr
omoe
than
e (E
DB)
Dich
loro
diflu
rom
etha
ne
mg/L mg/L mg/L mg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L0.05 0.1 0.1 0.1 0.05 0.02 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <50
430
30
<0.05 <0.1 <0.1 <0.1 <0.05 <0.02 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <50<0.05 <0.1 <0.1 <0.1 <0.05 <0.02 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <50
2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 20 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
<0.05 <0.1 <0.1 <0.1 <0.05 <0.02 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <50ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
<0.05 <0.1 <0.1 <0.1 <0.05 <0.02 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <50ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
0.025 0.05 0.05 0.05 0.025 0.01 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 25 25 25 25 2.5 2.5 2.5 2.5 2.5 2.5 250.025 0.05 0.05 0.05 0.025 0.01 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 25 25 25 25 2.5 2.5 2.5 2.5 2.5 2.5 25
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00.025 0.05 0.05 0.05 0.025 0.01 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 25 25 25 25 2.5 2.5 2.5 2.5 2.5 2.5 25
TPH
Analytical Table A3- Results Analytical Table A3- Results Analytical Table A3- Results Analytical Table A3- ResultsAnalytical Table A3- Results
Chlo
rom
etha
ne
Viny
l Chl
orid
e
Brom
omet
hane
Chlo
roet
hane
Trich
loro
fluor
omet
hane
1.1-
Dich
loro
ethe
ne
Iodo
met
hane
trans
-1.2
-Di
chlo
roet
hene
1.1-
Dich
loro
etha
ne
cis-1
.2-
Dich
loro
ethe
ne
1.1.
1-Tr
ichlo
roet
hane
1.1-
Dich
loro
prop
ylen
e
Carb
on
Tetra
chlo
ride
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L<50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5
3
0.3 30 60 3
<50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5<50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5
2 2 2 2 2 2 2 2 2 2 2 2 20 0 0 0 0 0 0 0 0 0 0 0 0
<50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5ND ND ND ND ND ND ND ND ND ND ND ND ND<50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5ND ND ND ND ND ND ND ND ND ND ND ND ND25 25 25 25 25 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.525 25 25 25 25 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.50 0 0 0 0 0 0 0 0 0 0 0 0
25 25 25 25 25 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5
Analytical Table A3- ResultsAnalytical Table A3- Results Analytical Table A3- Results
1.2-
Dich
loro
etha
ne
Trich
loro
ethe
ne
Dibr
omom
etha
ne
1.1.
2-Tr
ichlo
roet
hane
1.3-
Dich
loro
prop
ane
Tetra
chlo
roet
hene
1.1.
1.2-
Tetra
chlo
roet
hane
trans
-1.4
-Dich
loro
-2-
bute
ne
cis-1
.4-D
ichlo
ro-2
-bu
tene
1.1.
2.2-
Tetra
chlo
roet
hane
1.2.
3-Tr
ichlo
ropr
opan
e
Pent
achl
oroe
than
e
1.2-
Dibr
omo-
3-ch
loro
prop
ane
Hexa
chlo
robu
tadi
ene Ch
loro
benz
ene
Brom
oben
zene
2-Ch
loro
tolu
ene
4-Ch
loro
tolu
ene
1.3-
Dich
loro
benz
ene
1.4-
Dich
loro
benz
ene
1.2-
Dich
loro
benz
ene
1.2.
4-Tr
ichlo
robe
nzen
e
1.2.
3-Tr
ichlo
robe
nzen
e
Chlo
rofo
rm
Brom
odich
loro
met
hane
Dibr
omoc
hlor
omet
hane
Brom
ofor
m
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
10 20 0.3 1 5 53 50 0.7 300 40 1500 30 30 50 50 50 50
3 0.7 40 1500 50 50 50 506500 260 60 160 170 10
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 20 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.52.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.50 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5
Analytical Table A3- Results Analytical Table A3- Results Analytical Table A3- Results Analytical Table A3- Results
False
6 6.00False
Environmental
QUALITY CONTROL REPORTWork Order : EM1808482 Page : 1 of 13
:: LaboratoryClient Environmental Division MelbourneSESL Australia Pty Ltd:Contact DECLAN MCDONALD :Contact Customer Services EM:Address LEVEL 1, 21 SHIELDS ST
FLEMINGTON VIC 3031
Address : 4 Westall Rd Springvale VIC Australia 3171
::Telephone +61 02 9980 6554 +61-3-8549 9600:Telephone
:Project Camperdown Groundwater Date Samples Received : 24-May-2018:Order number J000990 Date Analysis Commenced : 24-May-2018
:C-O-C number ---- Issue Date : 07-Jun-2018Sampler : StephenSite : ----Quote number : SYBQ/259/16No. of samples received 5:No. of samples analysed 5:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSWDilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VICNancy Wang 2IC Organic Chemist Melbourne Organics, Springvale, VICNikki Stepniewski Senior Inorganic Instrument Chemist Melbourne Inorganics, Springvale, VICXing Lin Senior Organic Chemist Melbourne Organics, Springvale, VICZachary Chataway Laboratory Manager WRG Subcontracting, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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:ClientEM1808482SESL Australia Pty LtdCamperdown Groundwater:Project
General CommentsThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lotCAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society. LOR = Limit of reporting RPD = Relative Percentage Difference# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) ReportThe quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR: No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
ED037P: Alkalinity by PC Titrator (QC Lot: 1675384)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM1808489-001
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 252 255 1.08 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 252 255 1.08 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM1808470-003
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 91 92 0.00 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 91 92 0.00 0% - 20%
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QC Lot: 1675631)
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 371 371 0.00 0% - 20%Anonymous EM1808473-002
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 12 11 0.00 0% - 50%Anonymous EM1808467-001
ED045G: Chloride by Discrete Analyser (QC Lot: 1675630)
ED045G: Chloride 16887-00-6 1 mg/L 1180 1170 0.788 0% - 20%Anonymous EM1808473-001
ED045G: Chloride 16887-00-6 1 mg/L 203 203 0.00 0% - 20%Anonymous EM1808467-001
ED045G: Chloride by Discrete Analyser (QC Lot: 1675632)
ED045G: Chloride 16887-00-6 1 mg/L 1730 1760 1.56 0% - 20%MW2 EM1808482-002
ED045G: Chloride 16887-00-6 1 mg/L 62 61 1.81 0% - 20%Anonymous EM1808493-001
ED093F: Dissolved Major Cations (QC Lot: 1680281)
ED093F: Calcium 7440-70-2 1 mg/L 157 167 6.04 0% - 20%Anonymous EM1808471-002
ED093F: Magnesium 7439-95-4 1 mg/L 589 618 4.92 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 3770 3910 3.66 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 40 42 5.71 No Limit
ED093F: Calcium 7440-70-2 1 mg/L 53 54 1.94 0% - 20%Anonymous EM1808526-001
ED093F: Magnesium 7439-95-4 1 mg/L 37 38 0.00 0% - 20%
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:Client
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SESL Australia Pty Ltd
Camperdown Groundwater:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
ED093F: Dissolved Major Cations (QC Lot: 1680281) - continuedED093F: Sodium 7440-23-5 1 mg/L 498 506 1.55 0% - 20%Anonymous EM1808526-001
ED093F: Potassium 7440-09-7 1 mg/L 24 25 0.00 0% - 20%
EG020F: Dissolved Metals by ICP-MS (QC Lot: 1680278)
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1808498-002
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.233 0.204 13.6 0% - 20%
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.002 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.004 0.003 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.012 0.010 16.9 No Limit
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1808460-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.005 0.006 19.4 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.005 0.005 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.070 0.072 2.03 0% - 50%
EG020T: Total Metals by ICP-MS (QC Lot: 1683414)
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitRB1 EM1808482-004
EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1808537-001
EG020A-T: Arsenic 7440-38-2 0.001 mg/L 0.001 0.001 0.00 No Limit
EG020A-T: Chromium 7440-47-3 0.001 mg/L 0.013 0.014 0.00 0% - 50%
EG020A-T: Copper 7440-50-8 0.001 mg/L 0.007 0.006 0.00 No Limit
EG020A-T: Lead 7439-92-1 0.001 mg/L 0.004 0.004 0.00 No Limit
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.003 0.004 0.00 No Limit
EG020A-T: Zinc 7440-66-6 0.005 mg/L 0.018 0.017 0.00 No Limit
EG035F: Dissolved Mercury by FIMS (QC Lot: 1680279)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1808505-003
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1808460-001
EG035T: Total Recoverable Mercury by FIMS (QC Lot: 1687034)
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1808318-019
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1808541-002
EP005: Total Organic Carbon (TOC) (QC Lot: 1681201)
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SESL Australia Pty Ltd
Camperdown Groundwater:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP005: Total Organic Carbon (TOC) (QC Lot: 1681201) - continuedEP005: Total Organic Carbon ---- 1 mg/L 1280 1340 4.65 0% - 20%Anonymous EM1808469-010
EP005: Total Organic Carbon ---- 1 mg/L 46 46 0.00 0% - 20%Anonymous ES1815199-005
EP074A: Monocyclic Aromatic Hydrocarbons (QC Lot: 1675218)EP074: Styrene 100-42-5 5 µg/L <5 <5 0.00 No LimitMW1 EM1808482-001
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 <5 0.00 No Limit
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 <5 0.00 No Limit
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 <5 0.00 No Limit
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 <5 0.00 No Limit
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 <5 0.00 No Limit
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 <5 0.00 No Limit
EP074B: Oxygenated Compounds (QC Lot: 1675218)EP074: Vinyl Acetate 108-05-4 50 µg/L <50 <50 0.00 No LimitMW1 EM1808482-001
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 <50 0.00 No Limit
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 <50 0.00 No Limit
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 <50 0.00 No Limit
EP074C: Sulfonated Compounds (QC Lot: 1675218)EP074: Carbon disulfide 75-15-0 5 µg/L <5 <5 0.00 No LimitMW1 EM1808482-001
EP074D: Fumigants (QC Lot: 1675218)EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 <5 0.00 No LimitMW1 EM1808482-001
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 <5 0.00 No Limit
EP074E: Halogenated Aliphatic Compounds (QC Lot: 1675218)EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 <5 0.00 No LimitMW1 EM1808482-001
EP074: Iodomethane 74-88-4 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 <5 0.00 No Limit
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 <5 0.00 No Limit
EP074: Trichloroethene 79-01-6 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromomethane 74-95-3 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 <5 0.00 No Limit
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:ClientEM1808482SESL Australia Pty LtdCamperdown Groundwater:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074E: Halogenated Aliphatic Compounds (QC Lot: 1675218) - continuedEP074: Tetrachloroethene 127-18-4 5 µg/L <5 <5 0.00 No LimitMW1 EM1808482-001
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: Pentachloroethane 76-01-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 <5 0.00 No Limit
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 <5 0.00 No Limit
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 <50 0.00 No Limit
EP074: Chloromethane 74-87-3 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl chloride 75-01-4 50 µg/L <50 <50 0.00 No Limit
EP074: Bromomethane 74-83-9 50 µg/L <50 <50 0.00 No Limit
EP074: Chloroethane 75-00-3 50 µg/L <50 <50 0.00 No Limit
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 <50 0.00 No Limit
EP074F: Halogenated Aromatic Compounds (QC Lot: 1675218)
EP074: Chlorobenzene 108-90-7 5 µg/L <5 <5 0.00 No LimitMW1 EM1808482-001
EP074: Bromobenzene 108-86-1 5 µg/L <5 <5 0.00 No Limit
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 <5 0.00 No Limit
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 <5 0.00 No Limit
EP074G: Trihalomethanes (QC Lot: 1675218)
EP074: Chloroform 67-66-3 5 µg/L <5 <5 0.00 No LimitMW1 EM1808482-001
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 <5 0.00 No Limit
EP074: Bromoform 75-25-2 5 µg/L <5 <5 0.00 No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1675217)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EM1808505-004
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitMW1 EM1808482-001
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 1675217)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EM1808505-004
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitMW1 EM1808482-001
EP080: BTEXN (QC Lot: 1675217)
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EM1808505-004
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP080: BTEXN (QC Lot: 1675217) - continuedEP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No LimitAnonymous EM1808505-004
EP080: meta- & para-Xylene 108-38-3 106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitMW1 EM1808482-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3 106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
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Method Blank (MB) and Laboratory Control Spike (LCS) ReportThe quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
ED037P: Alkalinity by PC Titrator (QCLot: 1675384)ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 104200 mg/L 10988
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 1675631)ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 10225 mg/L 11592
<1 98.7100 mg/L 11592
ED045G: Chloride by Discrete Analyser (QCLot: 1675630)ED045G: Chloride 16887-00-6 1 mg/L <1 94.810 mg/L 11888
<1 1071000 mg/L 11888
ED045G: Chloride by Discrete Analyser (QCLot: 1675632)ED045G: Chloride 16887-00-6 1 mg/L <1 98.710 mg/L 11888
<1 1061000 mg/L 11888
ED093F: Dissolved Major Cations (QCLot: 1680281)ED093F: Calcium 7440-70-2 1 mg/L <1 93.25 mg/L 11093
ED093F: Magnesium 7439-95-4 1 mg/L <1 91.65 mg/L 11091
ED093F: Sodium 7440-23-5 1 mg/L <1 10250 mg/L 10990
ED093F: Potassium 7440-09-7 1 mg/L <1 97.950 mg/L 10989
EG020F: Dissolved Metals by ICP-MS (QCLot: 1680278)EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 95.70.1 mg/L 10791
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 89.50.1 mg/L 10484
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 94.20.1 mg/L 10383
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 91.90.1 mg/L 10382
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 97.90.1 mg/L 10583
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 92.80.1 mg/L 10682
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 1040.1 mg/L 10985
EG020T: Total Metals by ICP-MS (QCLot: 1683414)EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 99.60.1 mg/L 11090
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 93.60.1 mg/L 11186
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 96.60.1 mg/L 10987
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 95.10.1 mg/L 10887
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 95.20.1 mg/L 10988
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 97.60.1 mg/L 11187
EG020A-T: Zinc 7440-66-6 0.005 mg/L <0.005 96.50.1 mg/L 11387
EG035F: Dissolved Mercury by FIMS (QCLot: 1680279)EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 93.60.01 mg/L 11481
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EG035T: Total Recoverable Mercury by FIMS (QCLot: 1687034)
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 1010.01 mg/L 11481
EP005: Total Organic Carbon (TOC) (QCLot: 1681201)
EP005: Total Organic Carbon ---- 1 mg/L <1 98.510 mg/L 12072
EP066: Polychlorinated Biphenyls (PCB) (QCLot: 1675453)
EP066: Total Polychlorinated biphenyls ---- 1 µg/L <1.0 10310 µg/L 13254
EP068A: Organochlorine Pesticides (OC) (QCLot: 1675454)
EP068: alpha-BHC 319-84-6 0.5 µg/L <0.5 98.45 µg/L 12251
EP068: Hexachlorobenzene (HCB) 118-74-1 0.5 µg/L <0.5 85.05 µg/L 11851
EP068: beta-BHC 319-85-7 0.5 µg/L <0.5 95.55 µg/L 11957
EP068: gamma-BHC 58-89-9 0.5 µg/L <0.5 93.15 µg/L 12151
EP068: delta-BHC 319-86-8 0.5 µg/L <0.5 90.05 µg/L 11458
EP068: Heptachlor 76-44-8 0.5 µg/L <0.5 1065 µg/L 11347
EP068: Aldrin 309-00-2 0.5 µg/L <0.5 94.45 µg/L 11853
EP068: Heptachlor epoxide 1024-57-3 0.5 µg/L <0.5 94.15 µg/L 11753
EP068: trans-Chlordane 5103-74-2 0.5 µg/L <0.5 87.05 µg/L 12650
EP068: alpha-Endosulfan 959-98-8 0.5 µg/L <0.5 85.15 µg/L 12155
EP068: cis-Chlordane 5103-71-9 0.5 µg/L <0.5 88.35 µg/L 12054
EP068: Dieldrin 60-57-1 0.5 µg/L <0.5 1055 µg/L 12150
EP068: 4.4`-DDE 72-55-9 0.5 µg/L <0.5 98.55 µg/L 12054
EP068: Endrin 72-20-8 0.5 µg/L <0.5 1105 µg/L 12245
EP068: beta-Endosulfan 33213-65-9 0.5 µg/L <0.5 92.45 µg/L 12055
EP068: 4.4`-DDD 72-54-8 0.5 µg/L <0.5 1105 µg/L 12653
EP068: Endrin aldehyde 7421-93-4 0.5 µg/L <0.5 1035 µg/L 12352
EP068: Endosulfan sulfate 1031-07-8 0.5 µg/L <0.5 84.55 µg/L 12148
EP068: 4.4`-DDT 50-29-3 2 µg/L <2.0 1065 µg/L 12046
EP068: Endrin ketone 53494-70-5 0.5 µg/L <0.5 1045 µg/L 11856
EP068: Methoxychlor 72-43-5 2 µg/L <2.0 1065 µg/L 12342
EP068B: Organophosphorus Pesticides (OP) (QCLot: 1675454)
EP068: Dichlorvos 62-73-7 0.5 µg/L <0.5 1105 µg/L 12345
EP068: Demeton-S-methyl 919-86-8 0.5 µg/L <0.5 1235 µg/L 12942
EP068: Monocrotophos 6923-22-4 2 µg/L <2.0 13.75 µg/L 4310
EP068: Dimethoate 60-51-5 0.5 µg/L <0.5 92.85 µg/L 11538
EP068: Diazinon 333-41-5 0.5 µg/L <0.5 89.65 µg/L 12154
EP068: Chlorpyrifos-methyl 5598-13-0 0.5 µg/L <0.5 99.25 µg/L 11856
EP068: Parathion-methyl 298-00-0 2 µg/L <2.0 1085 µg/L 11543
EP068: Malathion 121-75-5 0.5 µg/L <0.5 1145 µg/L 12050
EP068: Fenthion 55-38-9 0.5 µg/L <0.5 1115 µg/L 11955
EP068: Chlorpyrifos 2921-88-2 0.5 µg/L <0.5 1055 µg/L 12250
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP068B: Organophosphorus Pesticides (OP) (QCLot: 1675454) - continuedEP068: Parathion 56-38-2 2 µg/L <2.0 # 1215 µg/L 11444
EP068: Pirimphos-ethyl 23505-41-1 0.5 µg/L <0.5 96.45 µg/L 11752
EP068: Chlorfenvinphos 470-90-6 0.5 µg/L <0.5 1195 µg/L 12642
EP068: Bromophos-ethyl 4824-78-6 0.5 µg/L <0.5 98.55 µg/L 11750
EP068: Fenamiphos 22224-92-6 0.5 µg/L <0.5 1145 µg/L 12745
EP068: Prothiofos 34643-46-4 0.5 µg/L <0.5 1035 µg/L 12052
EP068: Ethion 563-12-2 0.5 µg/L <0.5 1165 µg/L 11849
EP068: Carbophenothion 786-19-6 0.5 µg/L <0.5 94.45 µg/L 11952
EP068: Azinphos Methyl 86-50-0 0.5 µg/L <0.5 # 1555 µg/L 12021
EP074A: Monocyclic Aromatic Hydrocarbons (QCLot: 1675218)EP074: Styrene 100-42-5 5 µg/L <5 99.920 µg/L 11479
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 97.620 µg/L 11672
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 95.520 µg/L 11571
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 96.420 µg/L 11472
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 94.820 µg/L 11472
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 96.320 µg/L 11274
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 95.520 µg/L 11473
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 95.820 µg/L 11570
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 94.120 µg/L 11662
EP074B: Oxygenated Compounds (QCLot: 1675218)EP074: Vinyl Acetate 108-05-4 50 µg/L <50 98.4200 µg/L 12673
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 103200 µg/L 13668
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 101200 µg/L 12776
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 103200 µg/L 13171
EP074C: Sulfonated Compounds (QCLot: 1675218)EP074: Carbon disulfide 75-15-0 5 µg/L <5 93.320 µg/L 12355
EP074D: Fumigants (QCLot: 1675218)EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 96.520 µg/L 12267
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 10020 µg/L 12078
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 97.520 µg/L 11870
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 95.820 µg/L 11568
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 10320 µg/L 12078
EP074E: Halogenated Aliphatic Compounds (QCLot: 1675218)EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 87.8200 µg/L 14062
EP074: Chloromethane 74-87-3 50 µg/L <50 96.7200 µg/L 13868
EP074: Vinyl chloride 75-01-4 50 µg/L <50 95.4200 µg/L 13964
EP074: Bromomethane 74-83-9 50 µg/L <50 83.0200 µg/L 13048
EP074: Chloroethane 75-00-3 50 µg/L <50 86.8200 µg/L 13071
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP074E: Halogenated Aliphatic Compounds (QCLot: 1675218) - continuedEP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 94.4200 µg/L 12671
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 94.620 µg/L 12465
EP074: Iodomethane 74-88-4 5 µg/L <5 72.520 µg/L 12027
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 97.020 µg/L 12173
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 99.220 µg/L 12077
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 99.320 µg/L 12078
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 95.020 µg/L 11668
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 94.820 µg/L 11966
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 91.220 µg/L 11966
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 10120 µg/L 11879
EP074: Trichloroethene 79-01-6 5 µg/L <5 98.120 µg/L 12070
EP074: Dibromomethane 74-95-3 5 µg/L <5 10320 µg/L 11575
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 10420 µg/L 11487
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 10320 µg/L 11684
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 96.520 µg/L 11975
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 98.020 µg/L 11275
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 10420 µg/L 11963
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 97.920 µg/L 11954
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 10320 µg/L 12581
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 10420 µg/L 12581
EP074: Pentachloroethane 76-01-7 5 µg/L <5 93.620 µg/L 11062
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 97.720 µg/L 10663
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 98.220 µg/L 12663
EP074F: Halogenated Aromatic Compounds (QCLot: 1675218)EP074: Chlorobenzene 108-90-7 5 µg/L <5 99.820 µg/L 11482
EP074: Bromobenzene 108-86-1 5 µg/L <5 99.220 µg/L 11774
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 98.720 µg/L 11471
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 96.420 µg/L 11271
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 95.120 µg/L 11673
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 97.020 µg/L 11876
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 99.120 µg/L 11282
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 97.420 µg/L 11962
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 100.020 µg/L 11874
EP074G: Trihalomethanes (QCLot: 1675218)EP074: Chloroform 67-66-3 5 µg/L <5 10020 µg/L 11979
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 98.020 µg/L 11270
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 98.820 µg/L 10768
EP074: Bromoform 75-25-2 5 µg/L <5 97.120 µg/L 10862
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1675451)EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 85.05 µg/L 11048
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 86.95 µg/L 12449
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 88.15 µg/L 11753
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 89.85 µg/L 11854
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 88.95 µg/L 11957
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 1085 µg/L 11351
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 91.95 µg/L 12359
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 89.75 µg/L 12358
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 91.75 µg/L 12652
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 88.25 µg/L 12355
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 92.45 µg/L 13152
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 91.45 µg/L 12657
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 93.35 µg/L 12656
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 91.35 µg/L 12353
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 90.75 µg/L 12553
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 91.35 µg/L 12553
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1675217)EP080: C6 - C9 Fraction ---- 20 µg/L <20 117360 µg/L 12568
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1675452)EP071: C10 - C14 Fraction ---- 50 µg/L <50 1184331 µg/L 13458
EP071: C15 - C28 Fraction ---- 100 µg/L <100 12116952 µg/L 13360
EP071: C29 - C36 Fraction ---- 50 µg/L <50 1198695 µg/L 13754
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1675217)EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 122450 µg/L 12366
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1675452)EP071: >C10 - C16 Fraction ---- 100 µg/L <100 1176292 µg/L 12258
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 12022143 µg/L 13256
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 1221677 µg/L 13758
EP080: BTEXN (QCLot: 1675217)EP080: Benzene 71-43-2 1 µg/L <1 11520 µg/L 12374
EP080: Toluene 108-88-3 2 µg/L <2 11820 µg/L 12877
EP080: Ethylbenzene 100-41-4 2 µg/L <2 11620 µg/L 12673
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 11840 µg/L 13172
EP080: ortho-Xylene 95-47-6 2 µg/L <2 12020 µg/L 13174
EP080: Naphthalene 91-20-3 5 µg/L <5 1215 µg/L 12474
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Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 1675631)Anonymous EM1808467-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric 91.5100 mg/L 13070
ED045G: Chloride by Discrete Analyser (QCLot: 1675630)Anonymous EM1808467-002 16887-00-6ED045G: Chloride 98.3400 mg/L 13070
ED045G: Chloride by Discrete Analyser (QCLot: 1675632)QAQC1 EM1808482-003 16887-00-6ED045G: Chloride # Not
Determined
400 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 1680278)Anonymous EM1808460-001 7440-38-2EG020A-F: Arsenic 91.90.2 mg/L 13185
7440-43-9EG020A-F: Cadmium 88.50.05 mg/L 13381
7440-47-3EG020A-F: Chromium 94.40.2 mg/L 13571
7440-50-8EG020A-F: Copper 89.70.2 mg/L 13076
7439-92-1EG020A-F: Lead 92.60.2 mg/L 13375
7440-02-0EG020A-F: Nickel 89.50.2 mg/L 13173
7440-66-6EG020A-F: Zinc 91.00.2 mg/L 13175
EG020T: Total Metals by ICP-MS (QCLot: 1683414)RB1 EM1808482-004 7440-38-2EG020A-T: Arsenic 95.81 mg/L 11882
7440-43-9EG020A-T: Cadmium 93.40.25 mg/L 12975
7440-47-3EG020A-T: Chromium 89.31 mg/L 11880
7440-50-8EG020A-T: Copper 88.51 mg/L 11581
7439-92-1EG020A-T: Lead 86.31 mg/L 12183
7440-02-0EG020A-T: Nickel 93.41 mg/L 11880
7440-66-6EG020A-T: Zinc 95.21 mg/L 11674
EG035F: Dissolved Mercury by FIMS (QCLot: 1680279)Anonymous EM1808460-002 7439-97-6EG035F: Mercury # 43.70.01 mg/L 12070
EG035T: Total Recoverable Mercury by FIMS (QCLot: 1687034)RB1 EM1808482-004 7439-97-6EG035T: Mercury 97.40.01 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 1681201)MW1 EM1808482-001 ----EP005: Total Organic Carbon 84.1100 mg/L 13070
EP074E: Halogenated Aliphatic Compounds (QCLot: 1675218)MW2 EM1808482-002 75-35-4EP074: 1.1-Dichloroethene 76.620 µg/L 12440
79-01-6EP074: Trichloroethene 82.520 µg/L 12654
EP074F: Halogenated Aromatic Compounds (QCLot: 1675218)
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EP074F: Halogenated Aromatic Compounds (QCLot: 1675218) - continuedMW2 EM1808482-002 108-90-7EP074: Chlorobenzene 89.120 µg/L 13268
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1675217)MW2 EM1808482-002 ----EP080: C6 - C9 Fraction 72.4280 µg/L 12543
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1675217)MW2 EM1808482-002 C6_C10EP080: C6 - C10 Fraction 75.8330 µg/L 12244
EP080: BTEXN (QCLot: 1675217)MW2 EM1808482-002 71-43-2EP080: Benzene 90.020 µg/L 13068
108-88-3EP080: Toluene 89.520 µg/L 13272
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EM1808482 Page : 1 of 11
:: LaboratoryClient Environmental Division MelbourneSESL Australia Pty Ltd
:Contact DECLAN MCDONALD Telephone : +61-3-8549 9600:Project Camperdown Groundwater Date Samples Received : 24-May-2018
Site : ---- Issue Date : 07-Jun-2018Stephen:Sampler No. of samples received : 5
:Order number J000990 No. of samples analysed : 5
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of OutliersOutliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l Laboratory Control outliers exist - please see following pages for full details.
l Matrix Spike outliers exist - please see following pages for full details.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliancel NO Analysis Holding Time Outliers exist.
Outliers : Frequency of Quality Control Samplesl Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Quality Control SamplesDuplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATER
Compound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number
Laboratory Control Spike (LCS) Recoveries
QC-1675454-001 56-38-2Parathion---- Recovery greater than upper control
limit
44-114%121 %EP068B: Organophosphorus Pesticides (OP)
QC-1675454-001 86-50-0Azinphos Methyl---- Recovery greater than upper control
limit
21-120%155 %EP068B: Organophosphorus Pesticides (OP)
Matrix Spike (MS) Recoveries
EM1808482--003 16887-00-6ChlorideQAQC1 MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not Determined
ED045G: Chloride by Discrete Analyser
EM1808460--002 7439-97-6MercuryAnonymous Recovery less than lower data quality
objective
70-120%43.7 %EG035F: Dissolved Mercury by FIMS
Outliers : Frequency of Quality Control SamplesMatrix: WATER
Quality Control SpecificationQuality Control Sample TypeMethod ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP)NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 10.000 7NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 10.000 3NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 10.000 8NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 10.000 14
Matrix Spikes (MS)NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 5.000 7NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 5.000 3NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 5.000 8NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 5.000 14
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics 14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
ED037P: Alkalinity by PC TitratorClear Plastic Bottle - Natural (ED037-P)
MW1, MW2,
QAQC1
06-Jun-2018---- 25-May-2018----23-May-2018 ---- ü
ED041G: Sulfate (Turbidimetric) as SO4 2- by DAClear Plastic Bottle - Natural (ED041G)
MW1 20-Jun-2018---- 28-May-2018----23-May-2018 ---- üClear Plastic Bottle - Natural (ED041G)
MW2, QAQC1 20-Jun-2018---- 29-May-2018----23-May-2018 ---- üED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)MW1 20-Jun-2018---- 28-May-2018----23-May-2018 ---- ü
Clear Plastic Bottle - Natural (ED045G)MW2, QAQC1 20-Jun-2018---- 29-May-2018----23-May-2018 ---- ü
ED093F: Dissolved Major CationsClear Plastic Bottle - Nitric Acid; Unspecified (ED093F)
MW1, MW2,
QAQC1
30-May-2018---- 28-May-2018----23-May-2018 ---- ü
ED093F: SAR and Hardness CalculationsClear Plastic Bottle - Nitric Acid; Unspecified (ED093F)
MW1, MW2,
QAQC1
30-May-2018---- 28-May-2018----23-May-2018 ---- ü
EG020F: Dissolved Metals by ICP-MSClear Plastic Bottle - Nitric Acid; Unspecified (EG020A-F)
MW1, MW2,
QAQC1
19-Nov-2018---- 29-May-2018----23-May-2018 ---- ü
EG020T: Total Metals by ICP-MSClear Plastic Bottle - Nitric Acid; Unspecified (EG020A-T)
RB1 19-Nov-201819-Nov-2018 29-May-201829-May-201823-May-2018 ü üEG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Nitric Acid; Unspecified (EG035F)MW1, MW2,
QAQC1
06-Jun-2018---- 30-May-2018----23-May-2018 ---- ü
EG035T: Total Recoverable Mercury by FIMSClear Plastic Bottle - Nitric Acid; Unspecified (EG035T)
RB1 20-Jun-2018---- 30-May-2018----23-May-2018 ---- üEP005: Total Organic Carbon (TOC)
Amber TOC Vial - Sulfuric Acid (EP005)MW1, MW2,
QAQC1
20-Jun-2018---- 28-May-2018----23-May-2018 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP066: Polychlorinated Biphenyls (PCB)Amber Glass Bottle - Unpreserved (EP066)
MW1, MW2,QAQC1
04-Jul-201830-May-2018 28-May-201825-May-201823-May-2018 ü ü
EP068A: Organochlorine Pesticides (OC)Amber Glass Bottle - Unpreserved (EP068)
MW1, MW2,QAQC1
04-Jul-201830-May-2018 28-May-201825-May-201823-May-2018 ü ü
EP068B: Organophosphorus Pesticides (OP)Amber Glass Bottle - Unpreserved (EP068)
MW1, MW2,QAQC1
04-Jul-201830-May-2018 28-May-201825-May-201823-May-2018 ü ü
EP074A: Monocyclic Aromatic HydrocarbonsAmber VOC Vial - Sulfuric Acid (EP074)
TB1 31-May-201831-May-2018 25-May-201825-May-201817-May-2018 ü üAmber VOC Vial - Sulfuric Acid (EP074)
MW1, MW2,QAQC1
06-Jun-201806-Jun-2018 25-May-201825-May-201823-May-2018 ü ü
EP074B: Oxygenated CompoundsAmber VOC Vial - Sulfuric Acid (EP074)
TB1 31-May-201831-May-2018 25-May-201825-May-201817-May-2018 ü üAmber VOC Vial - Sulfuric Acid (EP074)
MW1, MW2,QAQC1
06-Jun-201806-Jun-2018 25-May-201825-May-201823-May-2018 ü ü
EP074C: Sulfonated CompoundsAmber VOC Vial - Sulfuric Acid (EP074)
TB1 31-May-201831-May-2018 25-May-201825-May-201817-May-2018 ü üAmber VOC Vial - Sulfuric Acid (EP074)
MW1, MW2,QAQC1
06-Jun-201806-Jun-2018 25-May-201825-May-201823-May-2018 ü ü
EP074D: FumigantsAmber VOC Vial - Sulfuric Acid (EP074)
TB1 31-May-201831-May-2018 25-May-201825-May-201817-May-2018 ü üAmber VOC Vial - Sulfuric Acid (EP074)
MW1, MW2,QAQC1
06-Jun-201806-Jun-2018 25-May-201825-May-201823-May-2018 ü ü
EP074E: Halogenated Aliphatic CompoundsAmber VOC Vial - Sulfuric Acid (EP074)
TB1 31-May-201831-May-2018 25-May-201825-May-201817-May-2018 ü üAmber VOC Vial - Sulfuric Acid (EP074)
MW1, MW2,QAQC1
06-Jun-201806-Jun-2018 25-May-201825-May-201823-May-2018 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP074F: Halogenated Aromatic CompoundsAmber VOC Vial - Sulfuric Acid (EP074)
TB1 31-May-201831-May-2018 25-May-201825-May-201817-May-2018 ü üAmber VOC Vial - Sulfuric Acid (EP074)
MW1, MW2,QAQC1
06-Jun-201806-Jun-2018 25-May-201825-May-201823-May-2018 ü ü
EP074G: TrihalomethanesAmber VOC Vial - Sulfuric Acid (EP074)
TB1 31-May-201831-May-2018 25-May-201825-May-201817-May-2018 ü üAmber VOC Vial - Sulfuric Acid (EP074)
MW1, MW2,QAQC1
06-Jun-201806-Jun-2018 25-May-201825-May-201823-May-2018 ü ü
EP075(SIM)B: Polynuclear Aromatic HydrocarbonsAmber Glass Bottle - Unpreserved (EP075(SIM))
MW1, MW2,QAQC1
04-Jul-201830-May-2018 28-May-201825-May-201823-May-2018 ü ü
EP080/071: Total Petroleum HydrocarbonsAmber Glass Bottle - Unpreserved (EP071)
TB1 03-Jul-201824-May-2018 28-May-201824-May-201817-May-2018 ü üAmber Glass Bottle - Unpreserved (EP071)
MW1, MW2,QAQC1
04-Jul-201830-May-2018 28-May-201825-May-201823-May-2018 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)TB1 31-May-201831-May-2018 25-May-201825-May-201817-May-2018 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)MW1, MW2,QAQC1, RB1
06-Jun-201806-Jun-2018 25-May-201825-May-201823-May-2018 ü ü
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 FractionsAmber Glass Bottle - Unpreserved (EP071)
TB1 03-Jul-201824-May-2018 28-May-201824-May-201817-May-2018 ü üAmber Glass Bottle - Unpreserved (EP071)
MW1, MW2,QAQC1
04-Jul-201830-May-2018 28-May-201825-May-201823-May-2018 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)TB1 31-May-201831-May-2018 25-May-201825-May-201817-May-2018 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)MW1, MW2,QAQC1, RB1
06-Jun-201806-Jun-2018 25-May-201825-May-201823-May-2018 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP080: BTEXNAmber VOC Vial - Sulfuric Acid (EP080)
TB1 31-May-201831-May-2018 25-May-201825-May-201817-May-2018 ü üAmber VOC Vial - Sulfuric Acid (EP080)
MW1, MW2,QAQC1, RB1
06-Jun-201806-Jun-2018 25-May-201825-May-201823-May-2018 ü ü
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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
EvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-PNEPM 2013 B3 & ALS QC Standard 10.00 10.004 40 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üMajor Cations - Dissolved ED093FNEPM 2013 B3 & ALS QC Standard 0.00 10.000 7 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)NEPM 2013 B3 & ALS QC Standard 0.00 10.000 3 ûPesticides by GCMS EP068NEPM 2013 B3 & ALS QC Standard 0.00 10.000 8 ûPolychlorinated Biphenyls (PCB) EP066NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üTotal Mercury by FIMS EG035TNEPM 2013 B3 & ALS QC Standard 22.22 10.002 9 üTotal Metals by ICP-MS - Suite A EG020A-TNEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 0.00 10.000 14 ûTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 11.11 10.001 9 üVolatile Organic Compounds EP074
Laboratory Control Samples (LCS)NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAlkalinity by PC Titrator ED037-PNEPM 2013 B3 & ALS QC Standard 10.00 10.004 40 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093FNEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPAH/Phenols (GC/MS - SIM) EP075(SIM)NEPM 2013 B3 & ALS QC Standard 33.33 5.001 3 üPesticides by GCMS EP068NEPM 2013 B3 & ALS QC Standard 12.50 5.001 8 üPolychlorinated Biphenyls (PCB) EP066NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üTotal Mercury by FIMS EG035TNEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üTotal Metals by ICP-MS - Suite A EG020A-TNEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üVolatile Organic Compounds EP074
Method Blanks (MB)NEPM 2013 B3 & ALS QC Standard 5.00 5.002 40 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093F
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
EvaluationAnalytical Methods Method
Method Blanks (MB) - ContinuedNEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPAH/Phenols (GC/MS - SIM) EP075(SIM)NEPM 2013 B3 & ALS QC Standard 33.33 5.001 3 üPesticides by GCMS EP068NEPM 2013 B3 & ALS QC Standard 12.50 5.001 8 üPolychlorinated Biphenyls (PCB) EP066NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üTotal Mercury by FIMS EG035TNEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üTotal Metals by ICP-MS - Suite A EG020A-TNEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üVolatile Organic Compounds EP074
Matrix Spikes (MS)NEPM 2013 B3 & ALS QC Standard 5.00 5.002 40 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 0.00 5.000 7 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)NEPM 2013 B3 & ALS QC Standard 0.00 5.000 3 ûPesticides by GCMS EP068NEPM 2013 B3 & ALS QC Standard 0.00 5.000 8 ûPolychlorinated Biphenyls (PCB) EP066NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üTotal Mercury by FIMS EG035TNEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üTotal Metals by ICP-MS - Suite A EG020A-TNEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 0.00 5.000 14 ûTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üVolatile Organic Compounds EP074
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Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013) Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500-SO4. Dissolved sulfate is determined in a 0.45um filtered sample. Sulfate ions are converted to a barium sulfate suspension in an acetic acid medium with barium chloride. Light absorbance of the BaSO4 suspension is measured by a photometer and the SO4-2 concentration is determined by comparison of the reading with a standard curve. This method is compliant with NEPM (2013) Schedule B(3)
Sulfate (Turbidimetric) as SO4 2- by Discrete Analyser
ED041G WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013) Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS) Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique. A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell. Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
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Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS) FIM-AAS is an automated flameless atomic absorption technique. A bromate/bromide reagent is used to oxidise any organic mercury compounds in the unfiltered sample. The ionic mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell. Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Total Mercury by FIMS EG035T WATER
In house: Referenced to APHA 1030F. This method is compliant with NEPM (2013) Schedule B(3)Ionic Balance by PCT DA and Turbi SO4 DA
EN055 - PG WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Polychlorinated Biphenyls (PCB) EP066 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Pesticides by GCMS EP068 WATER
In house: Referenced to USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and quantification is by comparison against an established 5 point calibration curve of n-Alkane standards. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH - Semivolatile Fraction EP071 WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Volatile Organic Compounds EP074 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS in SIM Mode and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
PAH/Phenols (GC/MS - SIM) EP075(SIM) WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. Alternatively, a sample is equilibrated in a headspace vial and a portion of the headspace determined by GCMS analysis. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH Volatiles/BTEX EP080 WATER
Specialist microbiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).Legionella in Water MM527 WATERMicrobiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).Salmonella (absence / presence) MM532 WATERMicrobiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).E. coli and Faecal Coliforms by MF
(Chromogenic Media)MM696 WATER
Microbiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).Total Coliforms and E. coli by MF (Chromogenic Media)
MM698 WATER
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
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Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to USEPA SW 846 - 3510B 100 mL to 1L of sample is transferred to a separatory funnel and serially extracted three times using 60mL DCM for each extract. The resultant extracts are combined, dehydrated and concentrated for analysis. This method is compliant with NEPM (2013) Schedule B(3) . ALS default excludes sediment which may be resident in the container.
Separatory Funnel Extraction of Liquids ORG14 WATER
A 5 mL aliquot or 5 mL of a diluted sample is added to a 40 mL VOC vial for sparging.Volatiles Water Preparation ORG16-W WATER
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 10EM1808482
:: LaboratoryClient SESL Australia Pty Ltd Environmental Division Melbourne: :ContactContact DECLAN MCDONALD Customer Services EM
:: AddressAddress LEVEL 1, 21 SHIELDS STFLEMINGTON VIC 3031
4 Westall Rd Springvale VIC Australia 3171
:Telephone +61 02 9980 6554 :Telephone +61-3-8549 9600:Project Camperdown Groundwater Date Samples Received : 24-May-2018 15:25:Order number J000990 Date Analysis Commenced : 24-May-2018:C-O-C number ---- Issue Date : 07-Jun-2018 15:12
Sampler : StephenSite : ----Quote number : SYBQ/259/16
5:No. of samples received
5:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:l General Commentsl Analytical Resultsl Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSWDilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VICNancy Wang 2IC Organic Chemist Melbourne Organics, Springvale, VICNikki Stepniewski Senior Inorganic Instrument Chemist Melbourne Inorganics, Springvale, VICXing Lin Senior Organic Chemist Melbourne Organics, Springvale, VICZachary Chataway Laboratory Manager WRG Subcontracting, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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General CommentsThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When sampling time information is not provided by the client, sampling dates are shown without a time component. In these instances, the time component has been assumed by the laboratory for processing purposes.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.LOR = Limit of reporting^ = This result is computed from individual analyte detections at or above the level of reportingø = ALS is not NATA accredited for these tests.~ = Indicates an estimated value.
Key :
EG020F: EM1808482-001-003 dissolved metal results have been confirmed by re-preparation and re-analysisl
E.Coli & FC (MM696) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989. NATA accreditation does not cover performance of this method.l
TC & E.Coli (MM698) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989. NATA accreditation does not cover performance of this method.l
EG035F:EM1808460 #2 Poor matrix spike recovery for dissolved mercury due to sample matrix. Confirmed by re-extraction and re-analysis.l
Ionic balances were calculated using: major anions - chloride, alkalinity and sulfate; and major cations - calcium, magnesium, potassium and sodium.l
ED045G: The presence of thiocyanate can positively contribute to the chloride result, thereby may bias results higher than expected. Results should be scrutinised accordingly.l
Legionella (MM527) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989.l
Salmonella (MM532) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989.l
Benzo(a)pyrene Toxicity Equivalent Quotient (TEQ) is the sum total of the concentration of the eight carcinogenic PAHs multiplied by their Toxicity Equivalence Factor (TEF) relative to Benzo(a)pyrene. TEF values are provided in brackets as follows: Benz(a)anthracene (0.1), Chrysene (0.01), Benzo(b+j) & Benzo(k)fluoranthene (0.1), Benzo(a)pyrene (1.0), Indeno(1.2.3.cd)pyrene (0.1), Dibenz(a.h)anthracene (1.0), Benzo(g.h.i)perylene (0.01). Less than LOR results for 'TEQ Zero' are treated as zero.
l
Sodium Adsorption Ratio (where reported): Where results for Na, Ca or Mg are <LOR, a concentration at half the reported LOR is incorporated into the SAR calculation. This represents a conservative approach for Na relative to the assumption that <LOR = zero concentration and a conservative approach for Ca & Mg relative to the assumption that <LOR is equivalent to the LOR concentration.
l
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Analytical ResultsTB1RB1QAQC1MW2MW1Client sample IDSub-Matrix: WATER
(Matrix: WATER)17-May-2018 00:0023-May-2018 15:3023-May-2018 15:3023-May-2018 15:3023-May-2018 15:30Client sampling date / time
EM1808482-005EM1808482-004EM1808482-003EM1808482-002EM1808482-001UnitLORCAS NumberCompoundResult Result Result Result Result
ED037P: Alkalinity by PC Titrator<1Hydroxide Alkalinity as CaCO3 <1 <1 ---- ----mg/L1DMO-210-001
87Carbonate Alkalinity as CaCO3 32 36 ---- ----mg/L13812-32-6
458Bicarbonate Alkalinity as CaCO3 446 456 ---- ----mg/L171-52-3
546 478 492 ---- ----mg/L1----Total Alkalinity as CaCO3
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA169Sulfate as SO4 - Turbidimetric 71 70 ---- ----mg/L114808-79-8
ED045G: Chloride by Discrete Analyser2480Chloride 1730 1750 ---- ----mg/L116887-00-6
ED093F: Dissolved Major Cations62Calcium 110 112 ---- ----mg/L17440-70-2
163Magnesium 175 178 ---- ----mg/L17439-95-4
1260Sodium 787 802 ---- ----mg/L17440-23-5
4Potassium 8 8 ---- ----mg/L17440-09-7
ED093F: SAR and Hardness Calculations19.1^ 10.8 11.0 ---- -----0.01----Sodium Adsorption Ratio
EG020F: Dissolved Metals by ICP-MS<0.001Arsenic <0.001 <0.001 ---- ----mg/L0.0017440-38-2
<0.0001Cadmium <0.0001 <0.0001 ---- ----mg/L0.00017440-43-9
<0.001Chromium <0.001 <0.001 ---- ----mg/L0.0017440-47-3
0.022Copper <0.001 0.034 ---- ----mg/L0.0017440-50-8
0.016Nickel <0.001 0.005 ---- ----mg/L0.0017440-02-0
0.002Lead <0.001 0.003 ---- ----mg/L0.0017439-92-1
0.036Zinc 0.006 0.037 ---- ----mg/L0.0057440-66-6
EG020T: Total Metals by ICP-MS----Arsenic ---- ---- <0.001 ----mg/L0.0017440-38-2
----Cadmium ---- ---- <0.0001 ----mg/L0.00017440-43-9
----Chromium ---- ---- <0.001 ----mg/L0.0017440-47-3
----Copper ---- ---- <0.001 ----mg/L0.0017440-50-8
----Nickel ---- ---- <0.001 ----mg/L0.0017440-02-0
----Lead ---- ---- <0.001 ----mg/L0.0017439-92-1
----Zinc ---- ---- <0.005 ----mg/L0.0057440-66-6
EG035F: Dissolved Mercury by FIMS<0.0001Mercury <0.0001 <0.0001 ---- ----mg/L0.00017439-97-6
EG035T: Total Recoverable Mercury by FIMS
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Analytical ResultsTB1RB1QAQC1MW2MW1Client sample IDSub-Matrix: WATER
(Matrix: WATER)17-May-2018 00:0023-May-2018 15:3023-May-2018 15:3023-May-2018 15:3023-May-2018 15:30Client sampling date / time
EM1808482-005EM1808482-004EM1808482-003EM1808482-002EM1808482-001UnitLORCAS NumberCompoundResult Result Result Result Result
EG035T: Total Recoverable Mercury by FIMS - Continued----Mercury ---- ---- <0.0001 ----mg/L0.00017439-97-6
EN055: Ionic Balance84.4 59.8 60.6 ---- ----meq/L0.01----Total Anions71.4 54.3 55.3 ---- ----meq/L0.01----Total Cations8.32 4.82 4.59 ---- ----%0.01----Ionic Balance
EP005: Total Organic Carbon (TOC)12 2 2 ---- ----mg/L1----Total Organic Carbon
EP066: Polychlorinated Biphenyls (PCB)<1 <1 <1 ---- ----µg/L1----Total Polychlorinated biphenyls
EP068A: Organochlorine Pesticides (OC)<0.5alpha-BHC <0.5 <0.5 ---- ----µg/L0.5319-84-6<0.5Hexachlorobenzene (HCB) <0.5 <0.5 ---- ----µg/L0.5118-74-1<0.5beta-BHC <0.5 <0.5 ---- ----µg/L0.5319-85-7<0.5gamma-BHC <0.5 <0.5 ---- ----µg/L0.558-89-9<0.5delta-BHC <0.5 <0.5 ---- ----µg/L0.5319-86-8<0.5Heptachlor <0.5 <0.5 ---- ----µg/L0.576-44-8<0.5Aldrin <0.5 <0.5 ---- ----µg/L0.5309-00-2<0.5Heptachlor epoxide <0.5 <0.5 ---- ----µg/L0.51024-57-3<0.5trans-Chlordane <0.5 <0.5 ---- ----µg/L0.55103-74-2<0.5alpha-Endosulfan <0.5 <0.5 ---- ----µg/L0.5959-98-8<0.5cis-Chlordane <0.5 <0.5 ---- ----µg/L0.55103-71-9<0.5Dieldrin <0.5 <0.5 ---- ----µg/L0.560-57-1<0.54.4`-DDE <0.5 <0.5 ---- ----µg/L0.572-55-9<0.5Endrin <0.5 <0.5 ---- ----µg/L0.572-20-8<0.5beta-Endosulfan <0.5 <0.5 ---- ----µg/L0.533213-65-9<0.54.4`-DDD <0.5 <0.5 ---- ----µg/L0.572-54-8<0.5Endrin aldehyde <0.5 <0.5 ---- ----µg/L0.57421-93-4<0.5Endosulfan sulfate <0.5 <0.5 ---- ----µg/L0.51031-07-8<2.04.4`-DDT <2.0 <2.0 ---- ----µg/L2.050-29-3<0.5Endrin ketone <0.5 <0.5 ---- ----µg/L0.553494-70-5<2.0Methoxychlor <2.0 <2.0 ---- ----µg/L2.072-43-5<0.5^ <0.5 <0.5 ---- ----µg/L0.5----Total Chlordane (sum)<0.5^ Sum of DDD + DDE + DDT <0.5 <0.5 ---- ----µg/L0.572-54-8/72-55-9/5
0-2
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(Matrix: WATER)
17-May-2018 00:0023-May-2018 15:3023-May-2018 15:3023-May-2018 15:3023-May-2018 15:30Client sampling date / time
EM1808482-005EM1808482-004EM1808482-003EM1808482-002EM1808482-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP068A: Organochlorine Pesticides (OC) - Continued
<0.5^ Sum of Aldrin + Dieldrin <0.5 <0.5 ---- ----µg/L0.5309-00-2/60-57-1
EP068B: Organophosphorus Pesticides (OP)<0.5Dichlorvos <0.5 <0.5 ---- ----µg/L0.562-73-7
<0.5Demeton-S-methyl <0.5 <0.5 ---- ----µg/L0.5919-86-8
<2.0Monocrotophos <2.0 <2.0 ---- ----µg/L2.06923-22-4
<0.5Dimethoate <0.5 <0.5 ---- ----µg/L0.560-51-5
<0.5Diazinon <0.5 <0.5 ---- ----µg/L0.5333-41-5
<0.5Chlorpyrifos-methyl <0.5 <0.5 ---- ----µg/L0.55598-13-0
<2.0Parathion-methyl <2.0 <2.0 ---- ----µg/L2.0298-00-0
<0.5Malathion <0.5 <0.5 ---- ----µg/L0.5121-75-5
<0.5Fenthion <0.5 <0.5 ---- ----µg/L0.555-38-9
<0.5Chlorpyrifos <0.5 <0.5 ---- ----µg/L0.52921-88-2
<2.0Parathion <2.0 <2.0 ---- ----µg/L2.056-38-2
<0.5Pirimphos-ethyl <0.5 <0.5 ---- ----µg/L0.523505-41-1
<0.5Chlorfenvinphos <0.5 <0.5 ---- ----µg/L0.5470-90-6
<0.5Bromophos-ethyl <0.5 <0.5 ---- ----µg/L0.54824-78-6
<0.5Fenamiphos <0.5 <0.5 ---- ----µg/L0.522224-92-6
<0.5Prothiofos <0.5 <0.5 ---- ----µg/L0.534643-46-4
<0.5Ethion <0.5 <0.5 ---- ----µg/L0.5563-12-2
<0.5Carbophenothion <0.5 <0.5 ---- ----µg/L0.5786-19-6
<0.5Azinphos Methyl <0.5 <0.5 ---- ----µg/L0.586-50-0
EP074A: Monocyclic Aromatic Hydrocarbons<5Styrene <5 <5 ---- <5µg/L5100-42-5
<5Isopropylbenzene <5 <5 ---- <5µg/L598-82-8
<5n-Propylbenzene <5 <5 ---- <5µg/L5103-65-1
<51.3.5-Trimethylbenzene <5 <5 ---- <5µg/L5108-67-8
<5sec-Butylbenzene <5 <5 ---- <5µg/L5135-98-8
<51.2.4-Trimethylbenzene <5 <5 ---- <5µg/L595-63-6
<5tert-Butylbenzene <5 <5 ---- <5µg/L598-06-6
<5p-Isopropyltoluene <5 <5 ---- <5µg/L599-87-6
<5n-Butylbenzene <5 <5 ---- <5µg/L5104-51-8
EP074B: Oxygenated Compounds<50Vinyl Acetate <50 <50 ---- <50µg/L50108-05-4
<502-Butanone (MEK) <50 <50 ---- <50µg/L5078-93-3
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(Matrix: WATER)17-May-2018 00:0023-May-2018 15:3023-May-2018 15:3023-May-2018 15:3023-May-2018 15:30Client sampling date / time
EM1808482-005EM1808482-004EM1808482-003EM1808482-002EM1808482-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP074B: Oxygenated Compounds - Continued<504-Methyl-2-pentanone (MIBK) <50 <50 ---- <50µg/L50108-10-1
<502-Hexanone (MBK) <50 <50 ---- <50µg/L50591-78-6
EP074C: Sulfonated Compounds<5Carbon disulfide <5 <5 ---- <5µg/L575-15-0
EP074D: Fumigants<52.2-Dichloropropane <5 <5 ---- <5µg/L5594-20-7
<51.2-Dichloropropane <5 <5 ---- <5µg/L578-87-5
<5cis-1.3-Dichloropropylene <5 <5 ---- <5µg/L510061-01-5
<5trans-1.3-Dichloropropylene <5 <5 ---- <5µg/L510061-02-6
<51.2-Dibromoethane (EDB) <5 <5 ---- <5µg/L5106-93-4
EP074E: Halogenated Aliphatic Compounds<50Dichlorodifluoromethane <50 <50 ---- <50µg/L5075-71-8
<50Chloromethane <50 <50 ---- <50µg/L5074-87-3
<50Vinyl chloride <50 <50 ---- <50µg/L5075-01-4
<50Bromomethane <50 <50 ---- <50µg/L5074-83-9
<50Chloroethane <50 <50 ---- <50µg/L5075-00-3
<50Trichlorofluoromethane <50 <50 ---- <50µg/L5075-69-4
<51.1-Dichloroethene <5 <5 ---- <5µg/L575-35-4
<5Iodomethane <5 <5 ---- <5µg/L574-88-4
<5trans-1.2-Dichloroethene <5 <5 ---- <5µg/L5156-60-5
<51.1-Dichloroethane <5 <5 ---- <5µg/L575-34-3
<5cis-1.2-Dichloroethene <5 <5 ---- <5µg/L5156-59-2
<51.1.1-Trichloroethane <5 <5 ---- <5µg/L571-55-6
<51.1-Dichloropropylene <5 <5 ---- <5µg/L5563-58-6
<5Carbon Tetrachloride <5 <5 ---- <5µg/L556-23-5
<51.2-Dichloroethane <5 <5 ---- <5µg/L5107-06-2
<5Trichloroethene <5 <5 ---- <5µg/L579-01-6
<5Dibromomethane <5 <5 ---- <5µg/L574-95-3
<51.1.2-Trichloroethane <5 <5 ---- <5µg/L579-00-5
<51.3-Dichloropropane <5 <5 ---- <5µg/L5142-28-9
<5Tetrachloroethene <5 <5 ---- <5µg/L5127-18-4
<51.1.1.2-Tetrachloroethane <5 <5 ---- <5µg/L5630-20-6
<5trans-1.4-Dichloro-2-butene <5 <5 ---- <5µg/L5110-57-6
<5cis-1.4-Dichloro-2-butene <5 <5 ---- <5µg/L51476-11-5
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(Matrix: WATER)
17-May-2018 00:0023-May-2018 15:3023-May-2018 15:3023-May-2018 15:3023-May-2018 15:30Client sampling date / time
EM1808482-005EM1808482-004EM1808482-003EM1808482-002EM1808482-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP074E: Halogenated Aliphatic Compounds - Continued
<51.1.2.2-Tetrachloroethane <5 <5 ---- <5µg/L579-34-5
<51.2.3-Trichloropropane <5 <5 ---- <5µg/L596-18-4
<5Pentachloroethane <5 <5 ---- <5µg/L576-01-7
<51.2-Dibromo-3-chloropropane <5 <5 ---- <5µg/L596-12-8
<5Hexachlorobutadiene <5 <5 ---- <5µg/L587-68-3
EP074F: Halogenated Aromatic Compounds
<5Chlorobenzene <5 <5 ---- <5µg/L5108-90-7
<5Bromobenzene <5 <5 ---- <5µg/L5108-86-1
<52-Chlorotoluene <5 <5 ---- <5µg/L595-49-8
<54-Chlorotoluene <5 <5 ---- <5µg/L5106-43-4
<51.3-Dichlorobenzene <5 <5 ---- <5µg/L5541-73-1
<51.4-Dichlorobenzene <5 <5 ---- <5µg/L5106-46-7
<51.2-Dichlorobenzene <5 <5 ---- <5µg/L595-50-1
<51.2.4-Trichlorobenzene <5 <5 ---- <5µg/L5120-82-1
<51.2.3-Trichlorobenzene <5 <5 ---- <5µg/L587-61-6
EP074G: Trihalomethanes
<5Chloroform <5 <5 ---- <5µg/L567-66-3
<5Bromodichloromethane <5 <5 ---- <5µg/L575-27-4
<5Dibromochloromethane <5 <5 ---- <5µg/L5124-48-1
<5Bromoform <5 <5 ---- <5µg/L575-25-2
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
<1.0Naphthalene <1.0 <1.0 ---- ----µg/L1.091-20-3
<1.0Acenaphthylene <1.0 <1.0 ---- ----µg/L1.0208-96-8
<1.0Acenaphthene <1.0 <1.0 ---- ----µg/L1.083-32-9
<1.0Fluorene <1.0 <1.0 ---- ----µg/L1.086-73-7
<1.0Phenanthrene <1.0 <1.0 ---- ----µg/L1.085-01-8
<1.0Anthracene <1.0 <1.0 ---- ----µg/L1.0120-12-7
<1.0Fluoranthene <1.0 <1.0 ---- ----µg/L1.0206-44-0
<1.0Pyrene <1.0 <1.0 ---- ----µg/L1.0129-00-0
<1.0Benz(a)anthracene <1.0 <1.0 ---- ----µg/L1.056-55-3
<1.0Chrysene <1.0 <1.0 ---- ----µg/L1.0218-01-9
<1.0Benzo(b+j)fluoranthene <1.0 <1.0 ---- ----µg/L1.0205-99-2 205-82-3
<1.0Benzo(k)fluoranthene <1.0 <1.0 ---- ----µg/L1.0207-08-9
<0.5Benzo(a)pyrene <0.5 <0.5 ---- ----µg/L0.550-32-8
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(Matrix: WATER)17-May-2018 00:0023-May-2018 15:3023-May-2018 15:3023-May-2018 15:3023-May-2018 15:30Client sampling date / time
EM1808482-005EM1808482-004EM1808482-003EM1808482-002EM1808482-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued<1.0Indeno(1.2.3.cd)pyrene <1.0 <1.0 ---- ----µg/L1.0193-39-5
<1.0Dibenz(a.h)anthracene <1.0 <1.0 ---- ----µg/L1.053-70-3
<1.0Benzo(g.h.i)perylene <1.0 <1.0 ---- ----µg/L1.0191-24-2
<0.5^ <0.5 <0.5 ---- ----µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ <0.5 <0.5 ---- ----µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons<20 <20 <20 <20 <20µg/L20----C6 - C9 Fraction
<50 <50 <50 ---- <50µg/L50----C10 - C14 Fraction
<100 <100 <100 ---- <100µg/L100----C15 - C28 Fraction
<50 <50 <50 ---- <50µg/L50----C29 - C36 Fraction
<50^ <50 <50 ---- <50µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions<20C6 - C10 Fraction <20 <20 <20 <20µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX (F1)
<20 <20 <20 <20µg/L20C6_C10-BTEX
<100 <100 <100 ---- <100µg/L100---->C10 - C16 Fraction
<100 <100 <100 ---- <100µg/L100---->C16 - C34 Fraction
<100 <100 <100 ---- <100µg/L100---->C34 - C40 Fraction
<100^ <100 <100 ---- <100µg/L100---->C10 - C40 Fraction (sum)
<100^ <100 <100 ---- <100µg/L100---->C10 - C16 Fraction minus Naphthalene (F2)
EP080: BTEXN<1Benzene <1 <1 <1 <1µg/L171-43-2
<2Toluene <2 <2 <2 <2µg/L2108-88-3
<2Ethylbenzene <2 <2 <2 <2µg/L2100-41-4
<2meta- & para-Xylene <2 <2 <2 <2µg/L2108-38-3 106-42-3
<2ortho-Xylene <2 <2 <2 <2µg/L295-47-6
<2^ <2 <2 <2 <2µg/L2----Total Xylenes
<1^ <1 <1 <1 <1µg/L1----Sum of BTEX
<5Naphthalene <5 <5 <5 <5µg/L591-20-3
MM527: Legionella in Water<10Legionella Total <10 <10 ---- ----cfu/ml10LEGIONELLA_TOT
<10 <10 <10 ---- ----cfu/ml10----Legionella pneumophila <10 <10 <10 ---- ----cfu/ml10----Legionella Species
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Analytical ResultsTB1RB1QAQC1MW2MW1Client sample IDSub-Matrix: WATER
(Matrix: WATER)17-May-2018 00:0023-May-2018 15:3023-May-2018 15:3023-May-2018 15:3023-May-2018 15:30Client sampling date / time
EM1808482-005EM1808482-004EM1808482-003EM1808482-002EM1808482-001UnitLORCAS NumberCompoundResult Result Result Result Result
MM532: Salmonella (absence / presence)Not Detected Not Detected Not Detected ---- ----------Salmonella spp.
MM696: E. coli & Faecal Coliforms by MF (Chromogenic)5 <10 <10 ---- ----CFU/100mL1----Escherichia coli 36 <10 <10 ---- ----CFU/100mL1----Faecal Coliforms
MM698: Total Coliforms and E. coli by MF (Chromogenic)200 350 250 ---- ----CFU/100mL1----Total Coliforms by MF
EP066S: PCB Surrogate107Decachlorobiphenyl 120 124 ---- ----%12051-24-3
EP068S: Organochlorine Pesticide Surrogate63.3Dibromo-DDE 69.8 81.7 ---- ----%0.521655-73-2
EP068T: Organophosphorus Pesticide Surrogate91.6DEF 97.2 106 ---- ----%0.578-48-8
EP074S: VOC Surrogates94.31.2-Dichloroethane-D4 96.4 94.4 ---- 95.1%517060-07-0
98.4Toluene-D8 95.9 97.2 ---- 97.8%52037-26-5
95.64-Bromofluorobenzene 94.2 95.2 ---- 96.8%5460-00-4
EP075(SIM)S: Phenolic Compound Surrogates28.2Phenol-d6 31.5 35.1 ---- ----%1.013127-88-3
71.32-Chlorophenol-D4 79.0 85.3 ---- ----%1.093951-73-6
77.92.4.6-Tribromophenol 74.5 87.2 ---- ----%1.0118-79-6
EP075(SIM)T: PAH Surrogates79.32-Fluorobiphenyl 91.1 97.5 ---- ----%1.0321-60-8
86.4Anthracene-d10 91.1 102 ---- ----%1.01719-06-8
94.34-Terphenyl-d14 102 112 ---- ----%1.01718-51-0
EP080S: TPH(V)/BTEX Surrogates1021.2-Dichloroethane-D4 104 102 103 102%217060-07-0
96.2Toluene-D8 93.7 94.8 95.6 95.5%22037-26-5
1054-Bromofluorobenzene 103 102 103 104%2460-00-4
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Surrogate Control LimitsRecovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP066S: PCB SurrogateDecachlorobiphenyl 2051-24-3 41 125
EP068S: Organochlorine Pesticide SurrogateDibromo-DDE 21655-73-2 49 117
EP068T: Organophosphorus Pesticide SurrogateDEF 78-48-8 51 127
EP074S: VOC Surrogates1.2-Dichloroethane-D4 17060-07-0 72 132
Toluene-D8 2037-26-5 77 132
4-Bromofluorobenzene 460-00-4 67 131
EP075(SIM)S: Phenolic Compound SurrogatesPhenol-d6 13127-88-3 10 46
2-Chlorophenol-D4 93951-73-6 23 104
2.4.6-Tribromophenol 118-79-6 28 130
EP075(SIM)T: PAH Surrogates2-Fluorobiphenyl 321-60-8 36 114
Anthracene-d10 1719-06-8 51 119
4-Terphenyl-d14 1718-51-0 49 127
EP080S: TPH(V)/BTEX Surrogates1.2-Dichloroethane-D4 17060-07-0 73 129
Toluene-D8 2037-26-5 70 125
4-Bromofluorobenzene 460-00-4 71 129
Camperdown Compost Groundwater Monitoring Event March-May 2020
Prepared for:
Camperdown Compost
June 2020
Camperdown Compost Company
Groundwater Monitoring – March-May 2020 445 Sandy’s Lane, Bookaar VIC
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Document Record
Revision No.
Date Reviewed By Action Issued To Date Release Authorisation Signature
0.1 23/04/2020 L. Jacovides Initial technical review.
Internal 23/04/2020
1.0 4/05/2020 A. Grigaliunas Sent to client. Client 04/05/2020
2.0 18/05/2020 A. Grigaliunas Minor
corrections. Client 18/05/2020
3.0 5/06/2020 A. Grigaliunas Include results of
duplicate sampling event.
Client 5/06/2020
Last Saved: 5 June 2020 10:41 am
File Name: J002435 Camperdown Compost Groundwater Monitoring March-May 3.0.docx
Main Author: Stephen Cox
Qualifications: B Sc (Hons)
Role: Soil Scientist
Final Reviewer: Andres Grigaliunas
Qualifications: BSc (Mar Biol), GradDip Env Mgmt, Prin Env Aud
Role: Principal Environmental Scientist, National Environmental Manager
Client: Camperdown Compost Company
Document Title: Camperdown Compost Groundwater Monitoring – March-May 2020
Document Version: Final 3.0
Reference Number: J002435
Camperdown Compost Company
Groundwater Monitoring – March-May 2020 445 Sandy’s Lane, Bookaar VIC
J002435 Camperdown Compost Groundwater Monitoring March-May 3.0.docx
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Our Ref: J002435 Camperdown Compost Groundwater Monitoring March-May 3.0.docx
Camperdown Compost Company 4915 Princes Hwy Camperdown VIC 3260
Re: Camperdown Compost Groundwater Monitoring – March 2020
Attn: Nick Rouston
1. INTRODUCTION
SESL Australia Pty Ltd (SESL) was commissioned to conduct groundwater monitoring for the Camperdown Compost Company (the client) at their composting facility located at 445 Sandy’s Lane, Bookaar,Victoria 3260 (the site). These works are part of the ongoing groundwater monitoring program that SESL initiated on behalf of the client in 2017.
Initial sampling was conducted in March 2020 with duplicate sampling event conducted in May 2020.
2. OBJECTIVES AND SCOPE OF WORK
The primary objectives of the monitoring at this site are to:
• Determine the contamination status of groundwater from site related activities;
• Compare groundwater results with relevant assessment criteria based on beneficial use of groundwater;
• Compare groundwater results with previous benchmark testing to determine trends in groundwater analytes; and
• Determine ongoing associated trends in future.
The scope of works performed by SESL environmental scientists for each round of sampling is as follows:
• Gauge three site groundwater monitoring wells to obtain depths to groundwater and record any observations (hydrocarbon odours, non-aqueous phase liquids or other physical evidence of contamination);
Camperdown Compost Company
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• Sample monitoring wells by low-flow method involving a micropurge pump, as per methods
described in the February 2020 Groundwater Monitoring Plan (GMP) and Groundwater Sampling Guidelines (EPA Vic 2000) and collection of field water quality parameters including pH, electrical conductivity, temperature, dissolved oxygen and oxidation-reduction potential;
• Conduct laboratory analysis of 3 groundwater samples for potential contaminants of concern (PCoC);
• Collect trip and rinsate blanks, along with quality control blind duplicate samples for quality assurance purposes as per the requirements in the February 2020 GMP; and
• Prepare a report summarising the findings of the monitoring event.
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3. SITE INFORMATION
The Camperdown Compost Company (Figure 1) receives liquid and solid waste from regional industries and turns waste materials into compost for agricultural and horticultural application. The site is located within a Victorian district (Table 1) dominated by agricultural and horticultural use.
Figure 1 - Site Location
A pair of solar powered boom gates allow vehicular access to the site. Waste is accepted at a receiving area where a concrete pad and wash-down pump are located. Waste materials are taken to the centre of the site, from which numerous windrows extend. The compost is turned systematically and matures in windrows until such time as the materials are fully composted and are ready for dispatch. A summary of the site information is outlined in Table 1. Additional infrastructure at the site includes:
• 2 x 37,000 Litre water tanks which are used for washing trucks; and
• 3m x 4m tool shed.
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Table 1 – Site Information
3.1 GEOLOGY AND HYDROGEOLOGY
The Site is located in Bookaar, an area of rural properties located approximately 7km north west of Camperdown, Victoria. A review of aerial photography indicates that the surrounding land uses are predominantly agricultural; the properties within a 1 km radius appearing to be rural in nature.
The Site is located approximately 450 metres north east of Blind Creek, which is the closest surface water body. Blind Creek is a tributary of Mt Emu Creek which spans approximately 250 km in length. Mt Emu Creek is known to contain breeding populations of platypus, and is home to native fish species, as well as introduced recreational species such as Redfin.
The site and its surrounds are predominantly flat, with a very slight slope (<1%) towards Blind Creek to the south west. It does not lie within any water protection areas.
A search of registered groundwater bores within 1 km of the site indicates that there is a single bore present (#133393) north and upgradient of the site. This 16.76 m deep bore is functional and has a registered use of Stock and Domestic; however, it is not being monitored.
Review of the regional geology maps of Victoria (Seamless Geology Victoria, Geoscience Victoria 2014) indicates that the site is located within the Brighton Group, which is characterised by gravel, sand and silt: variably calcareous to ferruginous sandstones and coquinas; marine to non-marine.
3.2 Groundwater Flow
A previous groundwater monitoring conducted by SESL in 2017 determined that the groundwater flowed in a westerly direction across the site. Groundwater flow direction was unable to be determined in a subsequent groundwater monitoring event conducted by SESL in 2018 due to the destruction of MW3.
Site Address 445 Sandy’s Lane, Bookaar Victoria, 3260 Lot and DP Number Portion of Lot 3, TP 430209 Approximate Investigation Area 2.4 ha Current VIC EPA Licence 13415 (Amended 24/11/2017) Local Government Area Corangamite Shire Council Geographical Coordinates 38°10.45”S, 143°04’.85”E Current Site Use A01- Prescribed Industrial Waste Management
A07- Composting Surrounding Land Use FZ1- Farming Zone, Schedule 1 (in all directions) Locality Map Figure 1 Site Layout Figure 2
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SESL oversaw the installation of three new wells (MW4, MW5 and MW6) at the site in March 2020. This groundwater monitoring event has determined that groundwater is flowing in a westerly direction across the site which is shown in Figure 3 below. This indicates that MW4 is located hydraulically up-gradient with MW5 and MW6 being hydraulically cross-gradient and down-gradient respectively.
3.3 Site Activities
The site is currently used for the processing and storage of up to 24,000 tonnes of compost materials. It is licensed to receive the following waste streams for the manufacture of compost:
• K100: Animal effluent and residues. Examples: abattoir wastes, poultry wastes, fish and shellfish wastes;
• K120: Grease interceptor trap effluent;
• K200: Food and beverage processing wastes, including animal and vegetable oils and derivatives;
• L100: Car and truck wastewaters;
• L150: Industrial washwaters from cleaning, rinsing or washing operations, NOS. Examples:
textile cleaning/processing effluent NOS, industrial plant and machinery washwaters, cooling tower washwaters;
• N150: Fly ash;
• N190: Filter cake;
• T130: Inert sludges or slurries, such as clay or ceramic suspensions, drilling mud, and pit water with negligible hydrocarbon contamination; and
• Compost: hard green wastes and municipal green wastes.
NOTE: NOS means Not Otherwise Specified
See the site layout in Figure 2 below.
Figure 2. Site Layout
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The Site is licensed to treat the waste by composting (treatment code: R16).
The site operations take place on a clay hardstand. The integrity of the dam lining was assessed in June 2019 through geotechnical testing of the clay liner. The results indicate permeability of the dam floor and walls are 6 x 10-10 and 7 x 10 -11, and well below the 1,10 x 10-9 requirement.
Upon receipt, the wastes to be composted are delivered to the centre of the site. Solid waste products are added to the existing windrows, with the newest material placed on the end of the windrow that is closest to the centre of the site. Liquid waste is deposited onto a bunded area, which directs the flow of all liquids between the existing windrows at the site. Liquids are incorporated into the windrows via manual, mechanical mixing. Each windrow is ‘pushed’ atop the liquid that is present on the ground surface between the windrows. The material is then restructured into a windrow, approximately 4 metres in height. Windrows increase in maturity towards the outermost points of the site. Using this methodology, the windrows work as a continuous process, rather than a batch-styled approach.
The surface water and leachate from the windrows are directed to the onsite storage dams. The client has reported that during construction, the dams were lined with 500 mm of clay. No groundwater was intercepted during construction to a depth of approximately 4.0 m to 4.5 m.
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The client identified groundwater at 3.0 m bgl when the first groundwater monitoring bores were installed in 2015.
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4. REGULATORY FRAMEWORK FOR GROUNDWATER ASSESSMENT
In accordance with Section 16 (1) of the Environmental Protection Act 1970, groundwater is protected under the State Environment Protection Policy, Waters 2018 (SEPP Waters), Gazette no. S493 dated 19 October 2018. This policy aims to maintain and, where necessary, improve groundwater quality in order that the existing and potential beneficial uses of groundwater are preserved.
The Groundwater Resource Report (VIC, DELWP) indicates the groundwater in the Hopkins – Corangamite surface aquifer has salinity/TDS of 1001-3500 m/L, which would be classed under Segment B of the SEPP Waters, 2018. Groundwater analysis on site revealed TDS in the range of 4710-5150 mg/L (Appendix D); exceeding the acceptable criteria for TDS in Segment B under the SEPP Waters 2018 (potable water). As such, the most appropriate category for the site groundwater is Segment C under SEPP Waters 2018. Under this classification, the protected beneficial uses include:
• Water dependant ecosystems and species;
• Potable mineral water supply;
• Agricultural and irrigation (stock watering);
• Industrial and commercial;
• Water-based recreation (primary contact recreation);
• Traditional owner cultural values;
• Cultural and spiritual values;
• Buildings and structures; and
• Geothermal properties.
In accordance with SEPP, and based on the beneficial use of groundwater, associated guidelines adopted for assessment of the groundwater quality is presented in Table 2.
Table 2. Groundwater Beneficial Uses
BENEFICIAL USE ADOPTED GUIDELINE
Maintenance of ecosystems ANZG 2018 Australian and New Zealand Guidelines for Fresh and Marine Water Quality.
Agriculture, Parks and Gardens ANZG 2018 “Primary Industries” guidelines for irrigation water quality.
Stock Watering ANZG 2018 “Primary Industries” guidelines for livestock drinking water quality.
Industrial Water Use No specific guidelines as stated in ANZG 2018.
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Primary Contact Recreation NHMRC Guidelines for Managing Risks in Recreational Waters, 2008 (Australian Drinking
Water Guideline (2011 updated in 2017) value multiplied by a factor of 10).
4.1 Adopted Guideline Documentation
This groundwater investigation was conducted in accordance with:
• Australian and New Zealand Environment Guidelines for Fresh and Marine Water Quality, 2018; • State Environment Protection Policy S493 (Waters), State Government of Victoria, 2018; and • Victorian EPA Publication 669, Groundwater Sampling Guidelines, April 2000.
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5. FIELD WORK
5.1 Personnel
Both GME (March and May 2020) were undertaken in accordance with guidelines listed in Section 4.1. Stephen Cox, SESL Soil Scientist conducted the first GME on the 17th of March 2020 (March GME) and a duplicate GME on the 13th of May 2020 (May GME) to confirm results from the March GME.
5.2 Groundwater Sampling Methodology
SESL consultants undertook a groundwater-monitoring events (GME) at the Camperdown Compost Company facility in accordance with the Victorian EPA Groundwater Sampling Guidelines (2000).
Prior to both sampling events, the wells were gauged and purged using a low-flow, micro- purge pump and low-density poly ethylene (LDPE) tubing. The pump was set to intersect groundwater within the screened section of the monitoring well. A calibrated water quality meter was used to measure field groundwater quality parameters during purging, and when field parameters were stabilised, the groundwater samples were collected. Purging log sheets are presented in Appendix A. Calibration certificates for field equipment are provided in Appendix B.
Sampling was carried out using disposable nitrile gloves at each well. Re-useable sampling equipment was decontaminated between wells using deionized water and Decon 90. LPDE tubing, bladders and filters dedicated to each well were used.
Samples were collected in laboratory supplied containers with appropriate preservatives, stored in a chilled esky and transported to a NATA accredited laboratory for analysis with a signed chain of custody form (Appendix C).
Groundwater samples were collected from three groundwater monitoring wells (MW4, MW5 & MW6) at the site and were analysed for the following PCoCs during the March GME:
• Total Recoverable Hydrocarbons; • BTEXN; • Hexachlorobenzene; • Polynuclear Aromatic Hydrocarbons (PAH); • Heavy Metals (As, Cd, Cr, Cu, Ni, Pb, Zn, Hg);
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• Organochlorine and Organophosphate Pesticides (OC/OP); • Polychlorinated biphenyls (PCB); • Volatile organic compounds (VOCs) including volatile halogenated compounds (VHCs); • Legionella; • Salmonella; • E. coli; • Faecal coliforms; • Total potassium; • Total sodium; • Sodium adsorption ratio (SAR); • Hardness; • Nitrate; • Nitrite; • Ammonia; • Total Kjeldahl Nitrogen (TKN) • Total Nitrogen; • Total Phosphorus; • Filterable Reactive Phosphate; • Total organic carbon; • Total carbon; and • Major cations and anions.
Groundwater samples were collected from three groundwater monitoring wells (MW4, MW5 & MW6) at the site and were analysed for the following PCoCs during the duplicate GME in May:
• Heavy Metals (As, Cd, Cr, Cu, Ni, Pb, Zn, Hg); • Legionella; • Salmonella; • E. coli; • Faecal coliforms; • Total potassium; • Total sodium; • Sodium adsorption ratio (SAR); • Hardness; • Nitrate; • Nitrite; • Ammonia; • Total Kjeldahl Nitrogen (TKN) • Total Nitrogen; • Total Phosphorus;
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• Filterable Reactive Phosphate; • Total organic carbon; • Total carbon; and • Major cations and anions.
5.2.1 Groundwater Elevations and Inferred Groundwater Flow
Standing water levels (SWL) were measured from the top of the well casing and recorded. The elevations of the top of the well casings were surveyed by a licensed surveyor (David Simpson Pty Ltd) to the Map Grid of Australia (MGA) and Australian Height Datum (AHD) (See Appendix E). Based on the groundwater levels the inferred direction of groundwater flow is towards the west (Table 3) (Figure
3). The 2017 groundwater monitoring event and May 2020 resampling event also found the groundwater flowed towards the west. A groundwater flow direction was not determined during the 2018 groundwater monitoring event due to the destruction of one of the monitoring wells.
Figure 3. Groundwater flow map showing western flow direction. Groundwater levels are shown in m AHD.
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Table 3 – Groundwater Levels Date Sampled
Bore ID
Easting Northing Bore Depth (MBTOC)
Natural Surface (M AHD)
Top of Casing (M AHD)
Standing Water Level (MBTOC)
Reduced Level (M AHD)
Screen Interval (MBTOC)
17/03/20 MW4 682326.558 5772764.349 7.706 138.265 138.989 3.109 135.880 2.5-3.5 17/03/20 MW5 682023.547 5772738.790 7.613 137.734 138.520 3.243 135.277 2.5-3.5 17/03/20 MW6 681962.298 5772826.487 6.960 137.518 138.518 3.265 135.253 2.5-3.5 13/05/20 MW4 682326.558 5772764.349 7.706 138.265 138.989 3.021 135.968 2.5-3.5 13/05/20 MW5 682023.547 5772738.790 7.613 137.734 138.520 2.632 135.888 2.5-3.5 13/05/20 MW6 681962.298 5772826.487 6.960 137.518 138.518 2.643 135.875 2.5-3.5
Groundwater levels and gauging results are recorded in the purging log sheets provided in Appendix A and the groundwater flow direction map based on gauging data from the March GME is provided in Figure 3.
5.2.2 Field Water Quality Parameters
A summary of the water quality parameters observed in the field is given in Table 4 (March GME) and Table 5 (May GME).
Table 4 - Summary of Water Quality Parameters for Groundwater during March GME Water Quality Parameter MW4 MW5 MW6 Temperature (oC) 20.3 22.9 19.8 Electrical conductivity (µS/cm) 6880 7311 6335 pH 6.76 6.19 6.53 ORP/Eh2 (mv) 63.2 106.9 65.7 DO (mg/L) 2.30 4.24 2.24 Turbidity First 1 litre extracted was
muddy brown, clearing to slightly brown with subsequent extraction.
First 2.5 litres extracted were muddy brown, clearing to slightly brown with subsequent extraction.
First 2 litres extracted were muddy brown, clearing to clear/brown with subsequent extraction.
Other No odour detected. No oil sheen in bailer.
No odour detected. No oil sheen in bailer.
No odour detected. No oil sheen in bailer.
Table 5 - Summary of Water Quality Parameters for Groundwater during May GME
Water Quality Parameter MW4 MW5 MW6 Temperature (oC) 14.6 15.0 13.3 Electrical conductivity (µS/cm) 6157 5869 5402 pH 7.19 7.34 7.45 ORP/Eh2 (mv) 84.8 83.7 96.5 DO (mg/L) 2.84 4.56 4.67 Turbidity First 1 litre extracted was
slightly brown, clearing to clear brown with subsequent extraction.
First 1.5 litres extracted were slightly brown, clearing to clear brown with subsequent extraction.
First 1.2 litres extracted were slightly brown, clearing to clear/brown with subsequent extraction.
Other No odour detected. No oil sheen in bailer.
No odour detected. No oil sheen in bailer.
No odour detected. No oil sheen in bailer.
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6 QUALITY ASSURANCE AND QUALITY CONTROL (QA/QC) RESULTS
As part of the SAQP in the February 2020 GMP report, data quality objectives (DQOs) and data quality indicators have been stated with targets for quality assurance and controls in accordance with the NEPM (NEPC 2013). The sections below outline the performance of fieldwork, sampling and analysis against DQI’s as a qualitative and quantitative assessment of the validity and usability of data collected at the site during this assessment.
6.1 Field QA/QC
A summary of the quality control sampling program is provided in Tables 6 (March GME) & 7 (May GME) below and discussed within other subsections below.
The analytical results and RPD calculations for groundwater analyses are provided in Table A1 -Replicate Quality Samples (RPDS); Appendix D. The analytical results of the rinsate and travel blank samples are provided in Table A2- Black Quality Samples; Appendix D. Laboratory certificates are provided in Appendix C- Laboratory Analytical Results.
The following comments are made as a summary regarding the quality of the field and analytical components of this project:
• Water quality meter used during the fieldwork was hired from Air-Met Scientific Pty Ltd in Nunawading Victoria. Calibration certificates are provided in Appendix B;
• Sample integrity and container requirements were documented as acceptable (refer to sample
receipt notifications in Appendix C); • Holding time compliances were documented as acceptable. All samples were received by the
laboratory within the relevant holding times (refer to sample receipt notifications in Appendix C); and
• The primary (ALS) laboratory was NATA registered at the time of analysis and NATA accredited for all analyses performed.
Table 6 - Summary of Quality Control Program (March GME) Summary of Quality Sample Results from Analytical Table 1 and Analytical Table 2 Total RPD Comparisons 183 Total RPD >30% 3.3% min. target Achieved Quality Targets
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% RPD <= 30% 96.7% =>95% Y Total GW Primary 3 Total Primary 3 min. target actual Total Duplicates QAQC 1 5% 25% Y Count min. target >LOR QAQC 1 1 0 Y Total Rinsate Blanks 1 1 0 Y Total Trip Blanks 1 1 0 Y
Table 7 - Summary of Quality Control Program (May GME)
Summary of Quality Sample Results from Analytical Table 1 and Analytical Table 2 Total RPD Comparisons 44 Total RPD >30% 6.8% min. target Achieved Quality Targets % RPD <= 30% 92.2% =>95% N Total GW Primary 3 Total Primary 3 min. target actual Total Duplicates QAQC 1 5% 25% Y Count min. target > LOR QAQC 1 1 0 Y Total Rinsate Blanks 1 1 0 Y Total Trip Blanks 1 1 0 Y
6.2 Laboratory QA/QC
Laboratory QA/QC for groundwater analysis comprised of chain-of-custody documentation, sample integrity and holding times, sample temperatures on receipt, use of acceptable NATA-registered laboratory methods and laboratory QA/QC results. A summary is provided in Table 8 below.
ALS has provided a QA/QC report of laboratory control samples performance and other quality performance records provided with laboratory certificates in Appendix C. A performance summary is provided below in Section 7.3.
Table 8. Summary of Laboratory Quality Control Programme for March GME and May duplicate GME Lab Report # Quality Control Samples Holding times Frequency of Quality
Control Samples ALS EM2004399_0_QCl Matrix spikes for chloride could not
be determined on MW5 sample as background concentrations exceeded spike levels.
pH holding times were exceeded by 3 days on all samples. However pH was measured in the field.
Total carbon and total inorganic carbon exceeded holding time by 2 days on all samples. In all samples, the concentrations returned did not exceed guideline criteria (Appendix D).
Samples were submitted to ALS
Laboratory duplicates and matrix spikes for Polycyclic Aromatic Hydrocarbons (PAH)/phenols, Pesticides and Polychlorinated Biphenyls (PCB) were not analysed at the required rate.
These analytes were not present in the groundwater samples submitted for analysis.
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within the holding times of total carbon and total inorganic carbon, however extraction didn’t commence until 2 days later despite instructions provided to the laboratory.
ALS EM2008003_0_QCl Matrix spikes for nitrite + nitrate as N could not be determined on MW4 sample as background concentrations were greater than or equal to 4x spike level.
pH holding times were exceeded by 3 days on all samples. However pH was measured in the field.
Total carbon and total inorganic carbon exceeded holding time by 2 days on all samples. In all samples, the concentrations returned did not exceed guideline criteria (Appendix D).
Samples were submitted to ALS within the holding times of total carbon and total inorganic carbon, however extraction didn’t commence until 2 days later despite instructions provided to the laboratory.
Laboratory duplicates and matrix spikes for fluoride were not analysed at the required rate.
6.3 Performance Against Data Quality Indicators
Quality control qualitative and quantitative results from fieldwork and laboratory analyses have been compared in Table 9 &10 below against the DQIs.
Table 9. Data Quality Evaluation Summary for March GME Data Quality Objectives Sampling
Frequency Required
Frequency Achieved?
DQI 95% DQI Met?
Precision Field duplicates 1/20 (>=5%) Yes- 25% <=30% Yes Laboratory duplicates (ALS) 1/20 Yes <=30% Yes exceptions are listed in Table 8
above. Laboratory method blanks 1 per batch Yes <LOR Yes Accuracy Laboratory matrix spikes 1/20 Yes 70 to 130 % Yes Laboratory control samples 1/20 Yes Yes Representativeness Sampling handling storage and transport appropriate for media and analyses
- - Yes Samples chilled and transported in accordance with COC requirements.
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Rinsate blank 1 per day Yes- 1 sample <LOR Yes Trip blank 1 per esky Yes- 1 sample <LOR Yes Samples extracted and analysed within holding times
- - 24hrs- Bacteria, 14 days- organics, 6 months-inorganics, Iron- 7 days.
Holding time not met for pH, Total Carbon and Total Inorganic Carbon as listed in Table 8 above.
Comparability Standard operating procedures used for sample collection and handling (including decontamination)
All samples - Yes All samples completed in accordance with SESL standard operating procedures. New sampling equipment and sampling gloves used for each sample.
Standard operating procedures used for sample collection and handling (including decontamination)
1 Rinsate blank during programme
Yes <LOR Yes, collected off the interface probe after decontamination at the end of the sampling day.
Standard analytical methods used for all analyses
All samples - Yes NATA accredited methods used for all analyses.
Consistent field conditions, sampling staff and laboratory analysis
All samples - Yes All field work completed by Stephen Cox, Soil Scientist.
All laboratory analysis completed by NATA accredited laboratories (ALS).
Limits of reporting appropriate and consistent
All samples - Yes Yes-all LORs below investigation levels.
Completeness COC completed and appropriate
All samples - Yes Refer to Appendix C for laboratory certifications and signed COCs
Appropriate documentation All samples - Refer to Appendix A for groundwater sampling logs.
Notes: DQI= Data Quality Indicator LOR= laboratory’s limit of reporting RPD= relative percentage difference COC= Chain of custody documentation
Table 10. Data Quality Evaluation Summary for May GME Data Quality Objectives Sampling
Frequency Required
Frequency Achieved?
DQI 95% DQI Met?
Precision Field duplicates 1/20 (>=5%) Yes- 25% <=30% Yes Laboratory duplicates (ALS) 1/20 Yes <=30% Yes exceptions are listed in Table 8
above. Laboratory method blanks 1 per batch Yes <LOR Yes Accuracy Laboratory matrix spikes 1/20 Yes 70 to 130 % Yes Laboratory control samples 1/20 Yes Yes Representativeness Sampling handling storage and transport appropriate for media and analyses
- - Yes Samples chilled and transported in accordance with COC requirements.
Rinsate blank 1 per day Yes- 1 sample <LOR Yes Trip blank 1 per esky Yes- 1 sample <LOR Yes
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Samples extracted and analysed within holding times
- - 24hrs- Bacteria, 14 days- organics, 6 months-inorganics, Iron- 7 days.
Holding time not met for pH, Total Carbon and Total Inorganic Carbon as listed in Table 8 above.
Comparability Standard operating procedures used for sample collection and handling (including decontamination)
All samples - Yes All samples completed in accordance with SESL standard operating procedures. New sampling equipment and sampling gloves used for each sample.
Standard operating procedures used for sample collection and handling (including decontamination)
1 Rinsate blank during programme
Yes <LOR Yes, collected off the interface probe after decontamination at the end of the sampling day.
Standard analytical methods used for all analyses
All samples - Yes NATA accredited methods used for all analyses.
Consistent field conditions, sampling staff and laboratory analysis
All samples - Yes All field work completed by Stephen Cox, Soil Scientist.
All laboratory analysis completed by NATA accredited laboratories (ALS).
Limits of reporting appropriate and consistent
All samples - Yes Yes-all LORs below investigation levels.
Completeness COC completed and appropriate
All samples - Yes Refer to Appendix C for laboratory certifications and signed COCs
Appropriate documentation All samples - Refer to Appendix A for groundwater sampling logs.
Notes: DQI= Data Quality Indicator LOR= laboratory’s limit of reporting RPD= relative percentage difference COC= Chain of custody documentation
6.4 Statement on Data Quality
Overall, the data quality objectives were met during the investigation, as demonstrated throughout this report. Documentation was maintained, and complete, sufficient data was collected to characterise the site in accordance with statutory requirements. The data has been shown to be comparable and representative of the site, and precision and accuracy has been demonstrated in the field and laboratory QA/QC programs.
The overall data quality performance against DQIs indicates that the analytical data is representative of site conditions at the time of the investigation as well as suitable to enable valid assessment of the site.
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7 ANALYTICAL RESULTS SUMMARY
Discrete groundwater samples collected at the site in March 2020 and May 2020 were analysed for selected PCoCs described below. Analytical results are summarised below. Laboratory analytical certificates are provided in Appendix C.
All samples were submitted to ALS Environmental (ALS) in Springvale, Victoria. ALS is NATA accredited for the analyses performed, and an associated stated of NATA accreditation is supplied in the laboratory certificates provided in Appendix C.
Based on the location of the wells and groundwater flow direction, MW4 is hydraulically up-gradient of the direction of groundwater flow (discussed in Section 5.2.1). MW6 and MW5 are hydraulically down gradient and cross gradient of the site. MW4 could be considered a background well.
7.1 Groundwater Results
The concentrations in groundwater samples were compared with the guidelines outlined in Section 4.1 of this report and groundwater testing conducted at this site in 2017 and 2018. The results are summarised in Appendix D and discussed below.
7.1.1 Dissolved Hydrocarbons
All groundwater samples during the March GME were analysed for hydrocarbon (BTEX, TRH, PAH’s, MAH’s) with results presented in Analytical Table 3 (Appendix D).
• MW4, MW5 and MW6 did not contain any detectable traces of hydrocarbons. This is consistent
with previous testing done on site at the decommissioned bores MW1, MW2 & MW3; and • Groundwater samples were not analysed for dissolved hydrocarbons during the May GME as
all previous testing has failed to detect traces of hydrocarbons.
7.1.2 Pathogens The groundwater samples were analysed for Legionella sp., Salmonella spp., Escherichia coli and faecal coliforms during both the March GME and May GME. A summary of pathogen exceedances during the March GME is provided in Table 11.
7.1.2.1 March GME Pathogen Results
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• Legionella sp. remained below the LOR in all sampled wells. Salmonella spp. was not detected
in any samples; • E. coli and faecal coliforms were above the LOR in all wells, but these were still below ANZG
(2018) Primary Industry Guidelines for Livestock Water Quality for MW5 and MW6. E. coli levels exceeded guideline criteria in the up gradient well MW4. It is possible for contaminants to spread against the groundwater flow direction;
• E.coli and faecal coliforms are not native to groundwater aquifers. Primarily this is a result of aquifer conditions being unsuitable for their survival (e.g. no food, wrong temperature etc). Because of this E.coli and faecal coliforms presence within an aquifer generally indicate recent contamination of the groundwater; and
• As E.coli and faecal coliforms are prevalent at the surface and given that the monitoring wells were recently installed, it is possible that cross-contamination of the groundwater has occurred during monitoring well construction which is unrelated to composting activities on-site. To determine whether these results represented actual contamination of groundwater or whether they are an anomalous result a duplicate, sampling event was conducted in May. The groundwater monitoring wells were purged one week prior to resampling to further reduce the risk of cross contamination. Results for the duplicate sampling event are summarised in Section 7.1.2.2 below.
Table 11. Summary of Pathogens Exceeding Guideline Criteria in Sampled Groundwater Well ID ANALYTE CONCENTRATION
(CFU/100mL) ANZG (2018) Primary Industries Guidelines for Livestock Water Quality
MW4 E.coli 2000 <100
7.1.2.1 May GME Pathogen Results
Legionella sp., Salmonella spp., Escherichia coli and faecal coliforms were not detected in any of monitoring wells.
This result confirms that the E.coli and faecal coliforms results from the initial March sampling event are anomalous and likely represent cross-contamination of groundwater during well construction rather than from on-site composting activities.
7.1.3 Dissolved Heavy Metals
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The groundwater samples were analysed for heavy metals (arsenic, cadmium, chromium, copper, lead, nickel, zinc, mercury) during the March GME and the May GME. A summary of metal exceedance is provided in Table 12. Metal exceedances are noted to be marginal. Levels of arsenic, cadmium, chromium, lead and mercury were below the laboratory LOR for both sampling events.
Previous testing conducted in 2017 and 2018 also noted marginal exceedances for copper, nickel and zinc.
Table 12. Summary of Metals Exceeding Guideline Criteria in Sampled Groundwater
Contaminant(mg/L)
WellIdentification GuidelineCriteria(mg/L)
MW4 MW5 MW6
ANZG2018Freshwater
AquaticEcosystem
s(95%)
ANZG2018Recreational
WaterQuality
ADWG2015
RecreationalWater
Quality(DWGx10)
ANZG2018Livestock
DrinkingWater–low
risk
MarchGMEResults
Nickel 0.064 0.015 0.006 0.011 0.1 - 1.0
Zinc 0.062 0.059 0.03 0.008 5.0 5.0 20
Copper 0.02 0.014 0.007 0.0014 1.0 2.0 0.4
MayGMEResults
Nickel 0.010 0.006 0.004 0.011 0.1 - 1.0
Zinc 0.039 0.048 0.018 0.008 5.0 5.0 20
Copper 0.006 0.009 0.003 0.0014 1.0 2.0 0.4
* Bold text denotes exceedance of adopted guideline criteria
Metal exceedances were recorded for all monitoring wells during both sampling events for zinc and copper. Nickel exceedances were recorded in all wells during the March GME. No exceedances were recorded during May GME for nickel; however, levels are still above the laboratory LOR. Nickel, zinc and copper levels within the groundwater have fallen between the March and May sampling events.
Nickel levels are highest within the upgradient monitoring well (MW4) during both sampling events. As such, these exceedances are likely to represent natural background fluctuations rather than contamination from on-site composting activities.
Zinc and copper levels were highest within the cross-gradient monitoring well (MW5) during the May sampling event, but were highest in the up-gradient monitoring well (MW4) during the initial March
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GME. The downstream position of MW5 indicates that site activities may be impacting on groundwater quality, however given the consistently high concentrations in the upgradient well (MW4) the concentrations of zinc and copper may also represent natural background fluctuations.
7.1.4 PCBs, OCPs, OPPs
Concentrations of PCB’s, OCP’s and OPP’s remained below the laboratory Limit of Reporting (LOR) for all wells during the March GME. This is consistent with previous testing carried out on site.
Groundwater samples were not analysed for PCB’s, OCP’s and OPP’s during the May duplicate GME as all previous testing has failed to detect traces of pesticides.
7.1.5 Major Cations and Anions
Exceedances in MW4 and MW5 were detected for chloride during the March GME when compared against the NHMRC (2008) Guidelines for Managing Risks in Recreational Water. No exceedances were detected in the subsequent May GME. These results are consistent with previous testing conducted in 2017 and 2018. A summary of chloride exceedances is provided in Table 13.
Table 13. Summary of Metals Exceeding Guideline Criteria in Sampled Groundwater
Contaminant(mg/L)
WellIdentification GuidelineCriteria(mg/L)
MW4 MW5 MW6ADWG2015RecreationalWaterQuality(DWGx10)
MarchGMEResults
Chloride 2570 2610 2040 2500
MayresamplingGMEResultsChloride 2490 2080 1890 2500
* Bold text denotes exceedance of adopted guideline criteria
Concentrations of chloride in all wells in the range of 2040-2610 mg/L were observed in the March GME and concentrations in all wells in the range of 1890-2490 mg/L in May GME.
The cross gradient well (MW5) marginally recorded the highest chloride level during the March GME. Chloride levels were highest in the up gradient well (MW4) during the May GME.
Due to the high levels of chlorides present within the up-gradient well (MW4) it is likely that these elevated chloride levels represent natural background fluctuations rather than contamination from on-site activities.
7.1.6 Volatile Organic Compounds (VOCs)
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Concentrations of VOC’s remained below the laboratory Limit of Reporting (LOR) for all monitoring wells. This is consistent with previous testing done on site in 2018.
Groundwater samples were not analysed for VOC’s during the May GME as all previous testing has failed to detect any traces of VOC’s.
7.1.7 Nutrients
7.1.7.1 Ammonia
Ammonia as N was detected above the LOR in all wells during the March GME. Levels were below ANZG (2018) Freshwater and Marine Quality criteria for 99% level of species protection (0.32 mg/L) in all wells.
Ammonia as N was detected above the LOR in the upgradient (MW4) and downgradient well (MW6) during the duplicate GME in May. Levels were below ANZG (2018) Freshwater and Marine Quality criteria for 99% level of species protection (0.32 mg/L) in all wells. Levels are marginally higher in the downgradient well.
Ammonia is often an indicator of groundwater contamination as it is not naturally present within groundwater aquifers and breaks down rapidly in the environment
7.1.7.2 Nitrate as N
Nitrate as N marginally exceeded ANZG Freshwater and Marine Quality criteria (2.4mg/L) as per Hickey (2013) in the cross-gradient well (MW5) during the March GME. This level is higher than the levels in the upgradient well (0.57mg/L) and down gradient well (2.19mg/L). These nitrate levels are lower than previous benchmark testing conducted in 2017 which had exceedances in two wells MW1(cross-gradient) and MW2 (down-gradient) of 24.1 mg/L and 44.5 mg/L respectively. .
Nitrate as N levels have increased since March GME in MW5 and MW6. A summary of these results are provided in Table 14 below.
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Table 14. Summary of Nitrate as N Exceeding Guideline Criteria in Sampled Groundwater
Contaminant(mg/L)
WellIdentification GuidelineCriteria(mg/L)
MW4 MW5 MW6ANZG2018FreshwaterAquaticEcosystems95%Grading
ValueasperHickey2013
MarchGMEResults
NitrateasN 0.57 3.92 2.20 2.4
MayduplicateGMEResultsNitrateasN 0.42 9.48 6.89 2.4
* Bold text denotes exceedance of adopted guideline criteria
Nitrate as N levels in the downstream wells (MW5 and MW6) indicate that site activities may be impacting on groundwater quality.
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8 ASSESSMENT SUMMARY
On behalf of Camperdown Compost Company, SESL conducted an initial GME in March 2020 and a duplicate GME in May 2020, which included the following:
• Gauging of groundwater monitoring wells; • Preparation and interpretation of groundwater flow map; • Groundwater monitoring event including low-flow sampling methodology of three groundwater
monitoring wells (MW4, MW5 & MW6) at the site; • Laboratory analysis for PCoCs; • Reporting the results of fieldwork and laboratory analysis of groundwater samples; and • The assessment data was compared with data quality indicators, which indicated that the data
quality has met the objectives and regulatory requirements, and the data discussed is therefore likely to be indicative of site conditions.
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9 CONCLUSIONS AND RECOMMENDATIONS
Groundwater level measurements during both monitoring events indicate that the groundwater flows towards the west (Figure 2). Based on the groundwater flow direction, MW4 is located hydraulically up gradient, MW6 is hydraulically down gradient and MW5 is hydraulically cross gradient.
Initial sampling in March detected elevated levels of E.coli and faecal coliforms in the upgradient well (MW4). As it is possible for contamination plumes to spread against the groundwater flow direction in slow moving aquifers this would have serious implications as to whether MW4 could be relied upon to represent background groundwater conditions if the results. As these groundwater monitoring wells had only been recently installed (two weeks prior) it was possible that the drilling process had introduced the contamination to the groundwater instead of on-site composting activities. To rule out potential cross contamination of the groundwater a duplicate sampling event was conducted in May for all contaminants which had levels above the laboratory LOR in the initial March monitoring event. All three groundwater monitoring wells on-site were completely purged one week prior to the duplicate sampling event to ensure that sampling subsequent sampling was representative of groundwater conditions within the aquifer.
The duplicate GME conducted in May did not detect E.coli or faecal coliforms above the laboratory LOR. Therefore it is likely that the detections of E.coli and faecal coliforms during the initial March GME represent cross contamination of the groundwater and do not indicate contamination from on-site composting activities. This means that the upgradient well (MW4) can be reliably used as a background well as there is no evidence of a contamination plume travelling upgradient.
Nickel concentrations were above the laboratory LOR for all wells on both sampling events, but only exceeded assessment criteria on MW4 and MW5 during the March sampling event. Nickel concentrations were highest within the upgradient well (MW4) during each sampling event which indicates that detected nickel concentrations represent natural background fluctuations. Chloride concentrations exceeded assessment criteria in MW4 and MW5 during initial sampling in March. There were no chloride exceedances detected during the May duplicate sampling event with the highest concentrations being recorded in the upgradient well (MW4). These fluctuations likely represent natural background fluctuations and are unlikely to be as a result of on-site composting activities.
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Copper and zinc concentrations were highest in the upgradient well (MW4) during the initial GME in March and highest in the cross-gradient well (MW5) during the duplicate sampling event in May. It is unclear whether these exceedances represent natural background fluctuations or contamination from on-site activities however the downstream position of MW5 indicates that site activities may be impacting on groundwater quality.
Groundwater in the downgradient (MW6) and cross-gradient well (MW5) exhibited generally higher concentrations of nitrate as N then the upgradient well (MW4) during both sampling events. The downstream positions of MW5 and MW6 likely indicate that on-site activities are impacting on groundwater quality.
SESL recommends the following:
• Continue the groundwater monitoring program on a bi-annual basis and undertake further trend analysis of contaminant concentrations to understand any potential impact.
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ATTACHMENTS:
APPENDIX A- GROUNDWATER SAMPLING FIELD SHEETS
APPENDIX B- FIELD INSTRUMENT CALIBRATION CERTIFICATES
APPENDIX C- CHAIN OF CUSTODY FORM
LABORATORY CERTIFICATES
LABORATORY ANALYTICAL RESULTS
APPENDIX D- ANALYTICAL TABLES
A1- REPLICATE QUALITY SAMPLES
A2- BLANKS QUALITY SAMPLES
A3- WATER QUALITY RESULTS
APPENDIX E- SURVEY INFORMATION
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10 DISCLAIMER AND LIMITATIONS
The conclusions presented in this report are relevant to the conditions of the site and the state of legislation currently enacted at the date of this report. We do not make any representation or warranty that the conclusions in this report will be applicable in the future as there may be changes in the condition of the site, applicable legislation or other factors that would affect the conclusions contained in this report.
SESL Australia Pty Ltd has used a degree of skill and care ordinarily exercised by reputable members of our profession practicing in the same or similar locality. Conclusions are based on representative samples or locations at the site, the intensity of those samples being in accordance with the usual levels of testing carried out for this type of investigation. Due to the inherent variability soils and groundwater and the general environment, we cannot warrant that the overall condition of the site is identical or substantially similar to the representative samples.
This report has been prepared for Camperdown Compost Company Pty Ltd for the specific purpose to which it refers. No responsibility is accepted to any third party. Neither the whole of the report or any part or reference thereto may be published in any document, statement or circular nor in any communication with third parties without our prior written approval of the form and context in which it will appear.
This report and the information contained in it is the intellectual property of SESL. Camperdown Compost Company Pty Ltd is granted an exclusive license for the use of the report for the purpose described in the report.
COPYRIGHT: The concepts, information and design ideas contained in this document are the property of SESL Australia Pty Ltd (ABN 70106 810 708). Use or copying of this document in whole or in part without the written permission of SESL Australia constitutes an infringement of copyright.
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11 REFERENCES
• Australian and New Zealand Guidelines (ANZG) (2018) for Fresh and Marine Water Quality;
• National Environmental Protection Council (NEPC) (2013). National Environment Protection (Assessment of Site Contamination) Measure 1999 (as amended April 2013);
• NHMRC & NRMMC (2011). Australian Drinking Water Guidelines (ADWG) - National Health and Medical Research Council & Natural Resource Management Ministerial Council.
• USEPA (2000). Guidance for the Data Quality Objectives Process, EPAC QA/G-4 DEC/600/r-96/055, United States Environmental Protection Agency Office of Environmental Information, Washington DC.
• State Environment Protection Policy S493 (Waters), State Government of Victoria, 2018
• SESL Groundwater Monitoring Event Report C8080.B42507.Q6406. CC GME.
• SESL Groundwater Monitoring Event Report J000990 1.0.
• SESL Groundwater Monitoring Plan C8080Q6406B (Updated February 2020).
• VIC EPA (2000) Groundwater Sampling Guidelines No.669.
• VIC EPA (2006) Hydrogeological Assessment (groundwater quality) Guidelines; publication no. 668.
Appendix A Groundwater Sampling Sheets
Appendix B Field Instrument Calibration Certificates
Appendix C Chain of Custody Form
Laboratory Certificates
Laboratory Results
March GME
False
5 5.00True
Environmental
QUALITY CONTROL REPORTWork Order : EM2004399 Page : 1 of 15
:: LaboratoryClient Environmental Division MelbourneSESL Australia Pty Ltd:Contact STEPHEN COX :Contact Customer Services EM
:Address LEVEL 1, 21 SHIELDS ST
FLEMINGTON VIC 3031
Address : 4 Westall Rd Springvale VIC Australia 3171
::Telephone ---- +61-3-8549 9600:Telephone
:Project GWM EVENT J002435 Date Samples Received : 18-Mar-2020
:Order number J002435 Date Analysis Commenced : 18-Mar-2020
:C-O-C number ---- Issue Date : 31-Mar-2020
Sampler : STEPHEN
Site : ----
Quote number : SYBQ/404/18
No. of samples received 6:
No. of samples analysed 6:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Dilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VIC
Nancy Wang 2IC Organic Chemist Melbourne Organics, Springvale, VIC
Nikki Stepniewski Senior Inorganic Instrument Chemist Melbourne Inorganics, Springvale, VIC
Samantha Smith Laboratory Coordinator WRG Subcontracting, Springvale, VIC
Xing Lin Senior Organic Chemist Melbourne Organics, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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General CommentsThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) ReportThe quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA005P: pH by PC Titrator (QC Lot: 2924971)EA005-P: pH Value ---- 0.01 pH Unit 6.69 6.69 0.00 0% - 20%Anonymous EM2004388-003
EA005-P: pH Value ---- 0.01 pH Unit 6.62 6.51 1.68 0% - 20%Anonymous EM2004425-001
EA010P: Conductivity by PC Titrator (QC Lot: 2924970)EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm 400 398 0.501 0% - 20%Anonymous EM2004388-003
EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm 1860 1880 1.12 0% - 20%Anonymous EM2004425-001
ED037P: Alkalinity by PC Titrator (QC Lot: 2924969)ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM2004382-002
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 1600 1600 0.113 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 1600 1600 0.113 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM2004388-003
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 144 145 1.01 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 144 145 1.01 0% - 20%
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QC Lot: 2924218)ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 27 27 0.00 0% - 20%Anonymous EM2004412-006
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 105 104 0.00 0% - 20%MW4 EM2004399-001
ED045G: Chloride by Discrete Analyser (QC Lot: 2924221)ED045G: Chloride 16887-00-6 1 mg/L 57 58 1.82 0% - 20%Anonymous EM2004412-006
ED045G: Chloride 16887-00-6 1 mg/L 2570 2490 3.24 0% - 20%MW4 EM2004399-001
ED093F: Dissolved Major Cations (QC Lot: 2927424)ED093F: Calcium 7440-70-2 1 mg/L 116 116 0.00 0% - 20%MW5 EM2004399-002
ED093F: Magnesium 7439-95-4 1 mg/L 202 204 0.681 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 1300 1310 1.01 0% - 20%
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
ED093F: Dissolved Major Cations (QC Lot: 2927424) - continuedED093F: Potassium 7440-09-7 1 mg/L 14 14 0.00 0% - 50%MW5 EM2004399-002
EG020F: Dissolved Metals by ICP-MS (QC Lot: 2927422)EG020A-F: Cadmium 7440-43-9 0.0001 mg/L 0.0002 0.0002 0.00 No LimitAnonymous EM2004429-010
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.171 0.172 0.851 0% - 20%
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.004 0.004 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.010 0.010 0.00 0% - 50%
EG020A-F: Zinc 7440-66-6 0.005 mg/L 1.40 1.43 2.32 0% - 20%
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM2004103-002
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG020F: Dissolved Metals by ICP-MS (QC Lot: 2930167)EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM2004443-009
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.072 0.068 4.89 0% - 50%
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitRB1 EM2004399-005
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG035F: Dissolved Mercury by FIMS (QC Lot: 2927423)EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM2004430-003
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM2004103-002
EG035F: Dissolved Mercury by FIMS (QC Lot: 2930168)EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM2004443-010
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitRB1 EM2004399-005
EK040P: Fluoride by PC Titrator (QC Lot: 2924966)EK040P: Fluoride 16984-48-8 0.1 mg/L 0.6 0.6 0.00 No LimitAnonymous EM2004368-015
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EK040P: Fluoride by PC Titrator (QC Lot: 2924966) - continuedEK040P: Fluoride 16984-48-8 0.1 mg/L 0.9 0.9 0.00 No LimitAnonymous EM2004368-012
EK040P: Fluoride by PC Titrator (QC Lot: 2924972)EK040P: Fluoride 16984-48-8 0.1 mg/L 0.3 0.4 0.00 No LimitAnonymous EM2004429-003
EK040P: Fluoride 16984-48-8 0.1 mg/L 0.5 0.5 0.00 No LimitAnonymous EM2004452-002
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 2923366)EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.04 0.04 0.00 No LimitAnonymous EM2004365-001
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.04 0.07 61.9 No LimitAnonymous EM2004365-010
EK057G: Nitrite as N by Discrete Analyser (QC Lot: 2924220)EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.04 0.04 0.00 No LimitAnonymous EM2004429-004
EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.01 0.01 0.00 No LimitMW4 EM2004399-001
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 2923367)EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 2.96 3.00 1.48 0% - 20%Anonymous EM2004365-001
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EM2004365-010
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 2923115)EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 2.0 1.9 5.12 0% - 20%Anonymous EM2004207-024
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 89.0 89.5 0.559 0% - 20%Anonymous EM2004335-003
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 2923117)EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.6 0.5 0.00 No LimitMW5 EM2004399-002
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 1.0 1.0 0.00 0% - 50%Anonymous EM2004429-004
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 2923116)EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.11 0.11 0.00 0% - 50%MW5 EM2004399-002
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.05 0.06 19.5 No LimitAnonymous EM2004429-004
EK071G: Reactive Phosphorus as P by discrete analyser (QC Lot: 2924219)EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 <0.01 0.00 No LimitMW4 EM2004399-001
EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L 0.49 0.52 6.77 0% - 20%Anonymous EM2004452-003
EP005: Total Organic Carbon (TOC) (QC Lot: 2932166)EP005: Total Organic Carbon ---- 1 mg/L 2 <1 78.3 No LimitMW4 EM2004399-001
EP005: Total Organic Carbon ---- 1 mg/L <1 <1 0.00 No LimitAnonymous EM2004534-004
EP006 Total Inorganic Carbon (QC Lot: 2927330)EP006: Total Inorganic Carbon ---- 1 mg/L 21 24 12.8 0% - 20%Anonymous EM2004269-001
EP007 Total Carbon (QC Lot: 2927331)EP007: Total Carbon TC 1 mg/L 139 132 5.01 0% - 20%MW4 EM2004399-001
EP074A: Monocyclic Aromatic Hydrocarbons (QC Lot: 2926342)EP074: Styrene 100-42-5 5 µg/L <5 <5 0.00 No LimitAnonymous EM2004334-008
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 <5 0.00 No Limit
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 <5 0.00 No Limit
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 <5 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074A: Monocyclic Aromatic Hydrocarbons (QC Lot: 2926342) - continuedEP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 <5 0.00 No LimitAnonymous EM2004334-008
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 <5 0.00 No Limit
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 <5 0.00 No Limit
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 <5 0.00 No Limit
EP074B: Oxygenated Compounds (QC Lot: 2926342)EP074: Vinyl Acetate 108-05-4 50 µg/L <50 <50 0.00 No LimitAnonymous EM2004334-008
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 <50 0.00 No Limit
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 <50 0.00 No Limit
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 <50 0.00 No Limit
EP074C: Sulfonated Compounds (QC Lot: 2926342)EP074: Carbon disulfide 75-15-0 5 µg/L <5 <5 0.00 No LimitAnonymous EM2004334-008
EP074D: Fumigants (QC Lot: 2926342)EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM2004334-008
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 <5 0.00 No Limit
EP074E: Halogenated Aliphatic Compounds (QC Lot: 2926342)EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 <5 0.00 No LimitAnonymous EM2004334-008
EP074: Iodomethane 74-88-4 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 <5 0.00 No Limit
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 <5 0.00 No Limit
EP074: Trichloroethene 79-01-6 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromomethane 74-95-3 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 <5 0.00 No Limit
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: Pentachloroethane 76-01-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 <5 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074E: Halogenated Aliphatic Compounds (QC Lot: 2926342) - continuedEP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 <5 0.00 No LimitAnonymous EM2004334-008
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 <50 0.00 No Limit
EP074: Chloromethane 74-87-3 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl chloride 75-01-4 50 µg/L <50 <50 0.00 No Limit
EP074: Bromomethane 74-83-9 50 µg/L <50 <50 0.00 No Limit
EP074: Chloroethane 75-00-3 50 µg/L <50 <50 0.00 No Limit
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 <50 0.00 No Limit
EP074F: Halogenated Aromatic Compounds (QC Lot: 2926342)EP074: Chlorobenzene 108-90-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM2004334-008
EP074: Bromobenzene 108-86-1 5 µg/L <5 <5 0.00 No Limit
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 <5 0.00 No Limit
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 <5 0.00 No Limit
EP074G: Trihalomethanes (QC Lot: 2926342)EP074: Chloroform 67-66-3 5 µg/L <5 <5 0.00 No LimitAnonymous EM2004334-008
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 <5 0.00 No Limit
EP074: Bromoform 75-25-2 5 µg/L <5 <5 0.00 No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 2923848)EP071: C15 - C28 Fraction ---- 100 µg/L <100 <100 0.00 No LimitAnonymous EM2004448-012
EP071: C10 - C14 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
EP071: C29 - C36 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
EP071: C15 - C28 Fraction ---- 100 µg/L <100 <100 0.00 No LimitAnonymous EM2004448-005
EP071: C10 - C14 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
EP071: C29 - C36 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 2926343)EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EM2004542-002
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EM2004334-008
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 2923848)EP071: >C10 - C16 Fraction ---- 100 µg/L <100 <100 0.00 No LimitAnonymous EM2004448-012
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 <100 0.00 No LimitAnonymous EM2004448-005
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 2926343)EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EM2004542-002
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EM2004334-008
EP080: BTEXN (QC Lot: 2926343)EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EM2004542-002
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EM2004334-008
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
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Method Blank (MB) and Laboratory Control Spike (LCS) ReportThe quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA010P: Conductivity by PC Titrator (QCLot: 2924970)EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm <1 98.61412 µS/cm 11985.0
ED037P: Alkalinity by PC Titrator (QCLot: 2924969)ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 106200 mg/L 11288.0
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 2924218)ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 98.725 mg/L 11785.8
<1 99.3100 mg/L 11785.8
ED045G: Chloride by Discrete Analyser (QCLot: 2924221)ED045G: Chloride 16887-00-6 1 mg/L <1 94.510 mg/L 12285.0
<1 1041000 mg/L 12285.0
ED093F: Dissolved Major Cations (QCLot: 2927424)ED093F: Calcium 7440-70-2 1 mg/L <1 1065 mg/L 11788.2
ED093F: Magnesium 7439-95-4 1 mg/L <1 1065 mg/L 11485.6
ED093F: Sodium 7440-23-5 1 mg/L <1 10450 mg/L 11490.0
ED093F: Potassium 7440-09-7 1 mg/L <1 98.650 mg/L 11186.7
EG020F: Dissolved Metals by ICP-MS (QCLot: 2927422)EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 1010.1 mg/L 10888.5
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 1000.1 mg/L 10883.5
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 95.90.1 mg/L 10583.2
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 1020.1 mg/L 10683.1
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 1000.1 mg/L 10784.6
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 1040.1 mg/L 10884.3
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 1060.1 mg/L 11186.3
EG020F: Dissolved Metals by ICP-MS (QCLot: 2930167)EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 92.20.1 mg/L 10888.5
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 94.40.1 mg/L 10883.5
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 89.80.1 mg/L 10583.2
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 86.20.1 mg/L 10683.1
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 87.40.1 mg/L 10784.6
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 91.70.1 mg/L 10884.3
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 96.50.1 mg/L 11186.3
EG035F: Dissolved Mercury by FIMS (QCLot: 2927423)EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 89.40.01 mg/L 11271.1
EG035F: Dissolved Mercury by FIMS (QCLot: 2930168)
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EG035F: Dissolved Mercury by FIMS (QCLot: 2930168) - continuedEG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 92.90.01 mg/L 11271.1
EK040P: Fluoride by PC Titrator (QCLot: 2924966)EK040P: Fluoride 16984-48-8 0.1 mg/L <0.1 99.05 mg/L 12284.3
EK040P: Fluoride by PC Titrator (QCLot: 2924972)EK040P: Fluoride 16984-48-8 0.1 mg/L <0.1 1005 mg/L 12284.3
EK055G: Ammonia as N by Discrete Analyser (QCLot: 2923366)EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 90.61 mg/L 11688.0
EK057G: Nitrite as N by Discrete Analyser (QCLot: 2924220)EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 1060.5 mg/L 11290.9
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 2923367)EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1050.5 mg/L 11790.0
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 2923115)EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 1105 mg/L 11770.0
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 2923117)EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 1065 mg/L 11770.0
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 2923116)EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 1022.21 mg/L 11471.9
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 2924219)EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 1080.5 mg/L 11992.7
EP005: Total Organic Carbon (TOC) (QCLot: 2932166)EP005: Total Organic Carbon ---- 1 mg/L <1 91.8100 mg/L 10981.2
EP006 Total Inorganic Carbon (QCLot: 2927330)EP006: Total Inorganic Carbon ---- 1 mg/L <1 92.2100 mg/L 12080.0
EP007 Total Carbon (QCLot: 2927331)EP007: Total Carbon TC 1 mg/L <1 89.7100 mg/L 11581.0
EP066: Polychlorinated Biphenyls (PCB) (QCLot: 2923846)EP066: Total Polychlorinated biphenyls ---- 1 µg/L <1 95.210 µg/L 12447.7
EP068A: Organochlorine Pesticides (OC) (QCLot: 2923847)EP068: alpha-BHC 319-84-6 0.5 µg/L <0.5 76.02.5 µg/L 11950.6
EP068: Hexachlorobenzene (HCB) 118-74-1 0.5 µg/L <0.5 59.22.5 µg/L 11744.2
EP068: beta-BHC 319-85-7 0.5 µg/L <0.5 79.22.5 µg/L 11953.7
EP068: gamma-BHC 58-89-9 0.5 µg/L <0.5 76.92.5 µg/L 11747.7
EP068: delta-BHC 319-86-8 0.5 µg/L <0.5 77.62.5 µg/L 11750.1
EP068: Heptachlor 76-44-8 0.5 µg/L <0.5 71.92.5 µg/L 11846.5
EP068: Aldrin 309-00-2 0.5 µg/L <0.5 74.42.5 µg/L 11548.0
EP068: Heptachlor epoxide 1024-57-3 0.5 µg/L <0.5 77.82.5 µg/L 11951.1
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP068A: Organochlorine Pesticides (OC) (QCLot: 2923847) - continuedEP068: trans-Chlordane 5103-74-2 0.5 µg/L <0.5 77.42.5 µg/L 12046.1
EP068: alpha-Endosulfan 959-98-8 0.5 µg/L <0.5 75.52.5 µg/L 11849.9
EP068: cis-Chlordane 5103-71-9 0.5 µg/L <0.5 76.62.5 µg/L 11850.0
EP068: Dieldrin 60-57-1 0.5 µg/L <0.5 63.92.5 µg/L 11648.0
EP068: 4.4`-DDE 72-55-9 0.5 µg/L <0.5 75.02.5 µg/L 11647.8
EP068: Endrin 72-20-8 0.5 µg/L <0.5 94.62.5 µg/L 12847.1
EP068: beta-Endosulfan 33213-65-9 0.5 µg/L <0.5 78.62.5 µg/L 11851.4
EP068: 4.4`-DDD 72-54-8 0.5 µg/L <0.5 74.62.5 µg/L 12248.6
EP068: Endrin aldehyde 7421-93-4 0.5 µg/L <0.5 73.42.5 µg/L 12849.4
EP068: Endosulfan sulfate 1031-07-8 0.5 µg/L <0.5 64.12.5 µg/L 12349.1
EP068: 4.4`-DDT 50-29-3 2 µg/L <2.0 75.42.5 µg/L 12645.6
EP068: Endrin ketone 53494-70-5 0.5 µg/L <0.5 75.92.5 µg/L 11752.8
EP068: Methoxychlor 72-43-5 2 µg/L <2.0 75.62.5 µg/L 12647.1
EP068B: Organophosphorus Pesticides (OP) (QCLot: 2923847)EP068: Dichlorvos 62-73-7 0.5 µg/L <0.5 77.52.5 µg/L 13343.6
EP068: Demeton-S-methyl 919-86-8 0.5 µg/L <0.5 80.42.5 µg/L 12946.4
EP068: Monocrotophos 6923-22-4 2 µg/L <2.0 14.02.5 µg/L 42.910.0
EP068: Dimethoate 60-51-5 0.5 µg/L <0.5 74.32.5 µg/L 13136.2
EP068: Diazinon 333-41-5 0.5 µg/L <0.5 76.62.5 µg/L 12249.4
EP068: Chlorpyrifos-methyl 5598-13-0 0.5 µg/L <0.5 75.62.5 µg/L 12350.9
EP068: Parathion-methyl 298-00-0 2 µg/L <2.0 74.72.5 µg/L 13252.0
EP068: Malathion 121-75-5 0.5 µg/L <0.5 78.62.5 µg/L 13351.8
EP068: Fenthion 55-38-9 0.5 µg/L <0.5 78.62.5 µg/L 12351.8
EP068: Chlorpyrifos 2921-88-2 0.5 µg/L <0.5 89.82.5 µg/L 12248.7
EP068: Parathion 56-38-2 2 µg/L <2.0 73.02.5 µg/L 13649.5
EP068: Pirimphos-ethyl 23505-41-1 0.5 µg/L <0.5 76.92.5 µg/L 12349.1
EP068: Chlorfenvinphos 470-90-6 0.5 µg/L <0.5 73.72.5 µg/L 13150.9
EP068: Bromophos-ethyl 4824-78-6 0.5 µg/L <0.5 74.72.5 µg/L 12647.5
EP068: Fenamiphos 22224-92-6 0.5 µg/L <0.5 77.42.5 µg/L 13846.5
EP068: Prothiofos 34643-46-4 0.5 µg/L <0.5 76.32.5 µg/L 11949.2
EP068: Ethion 563-12-2 0.5 µg/L <0.5 73.42.5 µg/L 12650.0
EP068: Carbophenothion 786-19-6 0.5 µg/L <0.5 80.02.5 µg/L 13150.0
EP068: Azinphos Methyl 86-50-0 0.5 µg/L <0.5 99.22.5 µg/L 15041.7
EP074A: Monocyclic Aromatic Hydrocarbons (QCLot: 2926342)EP074: Styrene 100-42-5 5 µg/L <5 10020 µg/L 11780.4
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 10220 µg/L 11875.0
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 10620 µg/L 11468.7
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 10320 µg/L 11472.1
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 10820 µg/L 11569.6
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP074A: Monocyclic Aromatic Hydrocarbons (QCLot: 2926342) - continuedEP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 10820 µg/L 11372.4
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 11120 µg/L 11672.6
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 10820 µg/L 11569.2
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 10620 µg/L 11561.4
EP074B: Oxygenated Compounds (QCLot: 2926342)EP074: Vinyl Acetate 108-05-4 50 µg/L <50 87.3200 µg/L 12571.3
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 78.0200 µg/L 13266.4
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 78.8200 µg/L 13275.2
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 80.4200 µg/L 13173.9
EP074C: Sulfonated Compounds (QCLot: 2926342)EP074: Carbon disulfide 75-15-0 5 µg/L <5 86.620 µg/L 12458.2
EP074D: Fumigants (QCLot: 2926342)EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 10320 µg/L 12068.7
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 96.820 µg/L 11679.6
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 91.220 µg/L 11476.2
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 84.420 µg/L 11477.0
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 89.920 µg/L 11880.1
EP074E: Halogenated Aliphatic Compounds (QCLot: 2926342)EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 101200 µg/L 14053.4
EP074: Chloromethane 74-87-3 50 µg/L <50 98.4200 µg/L 13463.8
EP074: Vinyl chloride 75-01-4 50 µg/L <50 103200 µg/L 13557.1
EP074: Bromomethane 74-83-9 50 µg/L <50 95.9200 µg/L 12651.1
EP074: Chloroethane 75-00-3 50 µg/L <50 104200 µg/L 12964.9
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 96.0200 µg/L 12765.7
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 89.920 µg/L 12367.4
EP074: Iodomethane 74-88-4 5 µg/L <5 80.220 µg/L 12630.9
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 10120 µg/L 11969.2
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 10220 µg/L 12076.7
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 10020 µg/L 11878.9
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 96.820 µg/L 12069.2
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 99.420 µg/L 12067.0
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 10520 µg/L 12063.7
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 88.920 µg/L 11682.0
EP074: Trichloroethene 79-01-6 5 µg/L <5 99.020 µg/L 11872.9
EP074: Dibromomethane 74-95-3 5 µg/L <5 87.820 µg/L 11681.0
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 89.520 µg/L 11884.9
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 94.920 µg/L 11983.4
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 10720 µg/L 11870.4
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP074E: Halogenated Aliphatic Compounds (QCLot: 2926342) - continuedEP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 91.320 µg/L 11377.9
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 80.720 µg/L 12272.6
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 80.320 µg/L 11967.8
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 86.420 µg/L 12583.0
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 85.220 µg/L 12382.4
EP074: Pentachloroethane 76-01-7 5 µg/L <5 92.820 µg/L 11172.7
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 80.520 µg/L 11475.4
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 11120 µg/L 12862.6
EP074F: Halogenated Aromatic Compounds (QCLot: 2926342)EP074: Chlorobenzene 108-90-7 5 µg/L <5 99.920 µg/L 11681.7
EP074: Bromobenzene 108-86-1 5 µg/L <5 10320 µg/L 11875.2
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 10920 µg/L 11475.0
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 10620 µg/L 11372.8
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 10420 µg/L 11674.7
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 10320 µg/L 11975.5
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 99.620 µg/L 11382.0
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 10620 µg/L 12364.0
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 11120 µg/L 11975.5
EP074G: Trihalomethanes (QCLot: 2926342)EP074: Chloroform 67-66-3 5 µg/L <5 91.520 µg/L 11880.4
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 88.320 µg/L 11578.6
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 87.820 µg/L 11377.7
EP074: Bromoform 75-25-2 5 µg/L <5 83.420 µg/L 11374.2
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 2923845)EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 84.35 µg/L 11641.1
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 99.05 µg/L 12147.2
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 91.75 µg/L 11847.3
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 95.45 µg/L 12149.4
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 97.45 µg/L 12452.5
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 91.85 µg/L 12552.3
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 98.65 µg/L 12752.4
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 99.15 µg/L 13051.3
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 1005 µg/L 13050.0
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 95.75 µg/L 13149.6
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 1105 µg/L 13251.5
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 1015 µg/L 13154.0
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 1075 µg/L 13352.3
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GWM EVENT J002435:Project
Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 2923845) - continuedEP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 1005 µg/L 12750.4
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 1005 µg/L 12750.0
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 1005 µg/L 12850.8
EP080/071: Total Petroleum Hydrocarbons (QCLot: 2923848)EP071: C10 - C14 Fraction ---- 50 µg/L <50 98.73330 µg/L 12544.8
EP071: C15 - C28 Fraction ---- 100 µg/L <100 97.316500 µg/L 13551.3
EP071: C29 - C36 Fraction ---- 50 µg/L <50 98.07800 µg/L 13449.4
EP080/071: Total Petroleum Hydrocarbons (QCLot: 2926343)EP080: C6 - C9 Fraction ---- 20 µg/L <20 104360 µg/L 12965.5
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 2923848)EP071: >C10 - C16 Fraction ---- 100 µg/L <100 87.85690 µg/L 12947.3
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 10020700 µg/L 13350.4
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 1071510 µg/L 13645.2
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 2926343)EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 104450 µg/L 12664.3
EP080: BTEXN (QCLot: 2926343)EP080: Benzene 71-43-2 1 µg/L <1 98.420 µg/L 12469.8
EP080: Toluene 108-88-3 2 µg/L <2 10120 µg/L 12673.6
EP080: Ethylbenzene 100-41-4 2 µg/L <2 10320 µg/L 12672.0
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 11040 µg/L 13271.5
EP080: ortho-Xylene 95-47-6 2 µg/L <2 11020 µg/L 13276.5
EP080: Naphthalene 91-20-3 5 µg/L <5 1025 µg/L 12770.5
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 2924218)MW5 EM2004399-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric 78.6100 mg/L 13070.0
ED045G: Chloride by Discrete Analyser (QCLot: 2924221)MW5 EM2004399-002 16887-00-6ED045G: Chloride # Not
Determined
400 mg/L 13070.0
EG020F: Dissolved Metals by ICP-MS (QCLot: 2927422)
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EG020F: Dissolved Metals by ICP-MS (QCLot: 2927422) - continuedAnonymous EM2004103-002 7440-38-2EG020A-F: Arsenic 1050.2 mg/L 13185.0
7440-43-9EG020A-F: Cadmium 91.90.05 mg/L 13381.0
7440-47-3EG020A-F: Chromium 89.00.2 mg/L 13571.0
7440-50-8EG020A-F: Copper 94.50.2 mg/L 13076.0
7439-92-1EG020A-F: Lead 91.20.2 mg/L 13375.0
7440-02-0EG020A-F: Nickel 97.60.2 mg/L 13173.0
7440-66-6EG020A-F: Zinc 1010.2 mg/L 13175.0
EG020F: Dissolved Metals by ICP-MS (QCLot: 2930167)RB1 EM2004399-005 7440-38-2EG020A-F: Arsenic 89.10.2 mg/L 13185.0
7440-43-9EG020A-F: Cadmium 84.60.05 mg/L 13381.0
7440-47-3EG020A-F: Chromium 84.50.2 mg/L 13571.0
7440-50-8EG020A-F: Copper 80.00.2 mg/L 13076.0
7439-92-1EG020A-F: Lead 81.00.2 mg/L 13375.0
7440-02-0EG020A-F: Nickel 82.30.2 mg/L 13173.0
7440-66-6EG020A-F: Zinc 83.20.2 mg/L 13175.0
EG035F: Dissolved Mercury by FIMS (QCLot: 2927423)Anonymous EM2004103-005 7439-97-6EG035F: Mercury 89.60.01 mg/L 12070.0
EG035F: Dissolved Mercury by FIMS (QCLot: 2930168)Anonymous EM2004430-004 7439-97-6EG035F: Mercury 89.80.01 mg/L 12070.0
EK040P: Fluoride by PC Titrator (QCLot: 2924966)Anonymous EM2004368-006 16984-48-8EK040P: Fluoride 1075 mg/L 13070.0
EK040P: Fluoride by PC Titrator (QCLot: 2924972)Anonymous EM2004429-004 16984-48-8EK040P: Fluoride 1035 mg/L 13070.0
EK055G: Ammonia as N by Discrete Analyser (QCLot: 2923366)Anonymous EM2004365-002 7664-41-7EK055G: Ammonia as N 98.81 mg/L 13070.0
EK057G: Nitrite as N by Discrete Analyser (QCLot: 2924220)MW5 EM2004399-002 14797-65-0EK057G: Nitrite as N 96.60.5 mg/L 11480.0
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 2923367)Anonymous EM2004365-002 ----EK059G: Nitrite + Nitrate as N 93.50.5 mg/L 13070.0
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 2923115)Anonymous EM2004269-001 ----EK061G: Total Kjeldahl Nitrogen as N 1085 mg/L 13070.0
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 2923117)MW6 EM2004399-003 ----EK061G: Total Kjeldahl Nitrogen as N 1115 mg/L 13070.0
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 2923116)MW6 EM2004399-003 ----EK067G: Total Phosphorus as P 1071 mg/L 13070.0
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 2924219)MW5 EM2004399-002 14265-44-2EK071G: Reactive Phosphorus as P 1010.5 mg/L 12379.0
EP005: Total Organic Carbon (TOC) (QCLot: 2932166)MW5 EM2004399-002 ----EP005: Total Organic Carbon 110100 mg/L 11480.0
EP006 Total Inorganic Carbon (QCLot: 2927330)MW4 EM2004399-001 ----EP006: Total Inorganic Carbon 11650 mg/L 13070.0
EP007 Total Carbon (QCLot: 2927331)MW5 EM2004399-002 TCEP007: Total Carbon 94.1500 mg/L 13070.0
EP074E: Halogenated Aliphatic Compounds (QCLot: 2926342)MW4 EM2004399-001 75-35-4EP074: 1.1-Dichloroethene 10220 µg/L 12440.0
79-01-6EP074: Trichloroethene 94.820 µg/L 12654.0
EP074F: Halogenated Aromatic Compounds (QCLot: 2926342)MW4 EM2004399-001 108-90-7EP074: Chlorobenzene 98.920 µg/L 13268.0
EP080/071: Total Petroleum Hydrocarbons (QCLot: 2923848)Anonymous EM2004448-005 ----EP071: C10 - C14 Fraction 1133330 µg/L 13050.0
----EP071: C15 - C28 Fraction 10016500 µg/L 13654.0
----EP071: C29 - C36 Fraction 1007800 µg/L 14250.0
EP080/071: Total Petroleum Hydrocarbons (QCLot: 2926343)MW4 EM2004399-001 ----EP080: C6 - C9 Fraction 89.9280 µg/L 12543.0
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 2923848)Anonymous EM2004448-005 ----EP071: >C10 - C16 Fraction 95.65690 µg/L 12850.0
----EP071: >C16 - C34 Fraction 10320700 µg/L 15050.0
----EP071: >C34 - C40 Fraction 1101510 µg/L 15951.0
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 2926343)MW4 EM2004399-001 C6_C10EP080: C6 - C10 Fraction 83.8330 µg/L 12244.0
EP080: BTEXN (QCLot: 2926343)MW4 EM2004399-001 71-43-2EP080: Benzene 97.420 µg/L 13068.0
108-88-3EP080: Toluene 10220 µg/L 13272.0
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EM2004399 Page : 1 of 13
:: LaboratoryClient Environmental Division MelbourneSESL Australia Pty Ltd
:Contact STEPHEN COX Telephone : +61-3-8549 9600:Project GWM EVENT J002435 Date Samples Received : 18-Mar-2020
Site : ---- Issue Date : 31-Mar-2020STEPHEN:Sampler No. of samples received : 6
:Order number J002435 No. of samples analysed : 6
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of OutliersOutliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l Matrix Spike outliers exist - please see following pages for full details.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliancel Analysis Holding Time Outliers exist - please see following pages for full details.
Outliers : Frequency of Quality Control Samplesl Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Quality Control SamplesDuplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATER
Compound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number
Matrix Spike (MS) Recoveries
EM2004399--002 16887-00-6ChlorideMW5 MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not Determined
ED045G: Chloride by Discrete Analyser
Outliers : Analysis Holding Time ComplianceMatrix: WATER
AnalysisExtraction / PreparationDate analysedDate extractedContainer / Client Sample ID(s) Days
overdueDays
overdueDue for extraction Due for analysis
Method
EA005P: pH by PC Titrator
Clear Plastic Bottle - Natural
17-Mar-2020----MW4, MW5,MW6, QAQC1
20-Mar-2020---- ---- 3
EP006 Total Inorganic Carbon
Clear Plastic Bottle - Natural
18-Mar-2020----MW4, MW5,MW6, QAQC1
20-Mar-2020---- ---- 2
EP007 Total Carbon
Clear Plastic Bottle - Natural
18-Mar-2020----MW4, MW5,MW6, QAQC1
20-Mar-2020---- ---- 2
Outliers : Frequency of Quality Control SamplesMatrix: WATER
Quality Control SpecificationQuality Control Sample TypeMethod ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP)NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 10.000 6NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 10.000 4NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 10.000 4
Matrix Spikes (MS)NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 5.000 6NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 5.000 4NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 5.000 4
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Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics 14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA005P: pH by PC Titrator
Clear Plastic Bottle - Natural (EA005-P)MW4, MW5,MW6, QAQC1
17-Mar-2020---- 20-Mar-2020----17-Mar-2020 ---- û
EA006: Sodium Adsorption Ratio (SAR)
Clear Plastic Bottle - Nitric Acid; Filtered (ED093F)MW4, MW5,MW6, QAQC1
14-Apr-2020---- 21-Mar-2020----17-Mar-2020 ---- ü
EA010P: Conductivity by PC Titrator
Clear Plastic Bottle - Natural (EA010-P)MW4, MW5,MW6, QAQC1
14-Apr-2020---- 20-Mar-2020----17-Mar-2020 ---- ü
EA065: Total Hardness as CaCO3
Clear Plastic Bottle - Nitric Acid; Filtered (ED093F)MW4, MW5,MW6, QAQC1
14-Apr-2020---- 21-Mar-2020----17-Mar-2020 ---- ü
ED037P: Alkalinity by PC Titrator
Clear Plastic Bottle - Natural (ED037-P)MW4, MW5,MW6, QAQC1
31-Mar-2020---- 20-Mar-2020----17-Mar-2020 ---- ü
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
Clear Plastic Bottle - Natural (ED041G)MW4, MW5,MW6, QAQC1
14-Apr-2020---- 19-Mar-2020----17-Mar-2020 ---- ü
ED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)MW4, MW5,MW6, QAQC1
14-Apr-2020---- 19-Mar-2020----17-Mar-2020 ---- ü
ED093F: Dissolved Major Cations
Clear Plastic Bottle - Nitric Acid; Filtered (ED093F)MW4, MW5,MW6, QAQC1
14-Apr-2020---- 21-Mar-2020----17-Mar-2020 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EG020F: Dissolved Metals by ICP-MS
Clear Plastic Bottle - Nitric Acid; Filtered (EG020A-F)MW4, MW5,MW6, QAQC1
13-Sep-2020---- 20-Mar-2020----17-Mar-2020 ---- ü
Clear Plastic Bottle - Nitric Acid; Filtered (EG020A-F)RB1 13-Sep-2020---- 23-Mar-2020----17-Mar-2020 ---- ü
EG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Nitric Acid; Filtered (EG035F)MW4, MW5,MW6, QAQC1
14-Apr-2020---- 20-Mar-2020----17-Mar-2020 ---- ü
Clear Plastic Bottle - Nitric Acid; Filtered (EG035F)RB1 14-Apr-2020---- 23-Mar-2020----17-Mar-2020 ---- ü
EK040P: Fluoride by PC Titrator
Clear Plastic Bottle - Natural (EK040P)MW4, MW5,MW6, QAQC1
14-Apr-2020---- 20-Mar-2020----17-Mar-2020 ---- ü
EK055G: Ammonia as N by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK055G)MW4, MW5,MW6, QAQC1
14-Apr-2020---- 19-Mar-2020----17-Mar-2020 ---- ü
EK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural (EK057G)MW4, MW5,MW6, QAQC1
19-Mar-2020---- 19-Mar-2020----17-Mar-2020 ---- ü
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK059G)MW4, MW5,MW6, QAQC1
14-Apr-2020---- 19-Mar-2020----17-Mar-2020 ---- ü
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK061G)MW4, MW5,MW6, QAQC1
14-Apr-202014-Apr-2020 19-Mar-202019-Mar-202017-Mar-2020 ü ü
EK067G: Total Phosphorus as P by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK067G)MW4, MW5,MW6, QAQC1
14-Apr-202014-Apr-2020 19-Mar-202019-Mar-202017-Mar-2020 ü ü
EK071G: Reactive Phosphorus as P by discrete analyser
Clear Plastic Bottle - Natural (EK071G)MW4, MW5,MW6, QAQC1
19-Mar-2020---- 19-Mar-2020----17-Mar-2020 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP005: Total Organic Carbon (TOC)
Amber TOC Vial - Sulfuric Acid (EP005)MW4, MW5,MW6, QAQC1
14-Apr-2020---- 24-Mar-2020----17-Mar-2020 ---- ü
EP006 Total Inorganic Carbon
Clear Plastic Bottle - Natural (EP006)MW4, MW5,MW6, QAQC1
18-Mar-2020---- 20-Mar-2020----17-Mar-2020 ---- û
EP007 Total Carbon
Clear Plastic Bottle - Natural (EP007)MW4, MW5,MW6, QAQC1
18-Mar-2020---- 20-Mar-2020----17-Mar-2020 ---- û
EP066: Polychlorinated Biphenyls (PCB)
Amber Glass Bottle - Unpreserved (EP066)MW4, MW5,MW6, QAQC1
28-Apr-202024-Mar-2020 21-Mar-202019-Mar-202017-Mar-2020 ü ü
EP068A: Organochlorine Pesticides (OC)
Amber Glass Bottle - Unpreserved (EP068)MW4, MW5,MW6, QAQC1
28-Apr-202024-Mar-2020 21-Mar-202019-Mar-202017-Mar-2020 ü ü
EP068B: Organophosphorus Pesticides (OP)
Amber Glass Bottle - Unpreserved (EP068)MW4, MW5,MW6, QAQC1
28-Apr-202024-Mar-2020 21-Mar-202019-Mar-202017-Mar-2020 ü ü
EP074A: Monocyclic Aromatic Hydrocarbons
Amber VOC Vial - Sulfuric Acid (EP074)MW4, MW5,MW6, QAQC1,TB1
31-Mar-202031-Mar-2020 20-Mar-202020-Mar-202017-Mar-2020 ü ü
EP074B: Oxygenated Compounds
Amber VOC Vial - Sulfuric Acid (EP074)MW4, MW5,MW6, QAQC1,TB1
31-Mar-202031-Mar-2020 20-Mar-202020-Mar-202017-Mar-2020 ü ü
EP074C: Sulfonated Compounds
Amber VOC Vial - Sulfuric Acid (EP074)MW4, MW5,MW6, QAQC1,TB1
31-Mar-202031-Mar-2020 20-Mar-202020-Mar-202017-Mar-2020 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP074D: Fumigants
Amber VOC Vial - Sulfuric Acid (EP074)MW4, MW5,MW6, QAQC1,TB1
31-Mar-202031-Mar-2020 20-Mar-202020-Mar-202017-Mar-2020 ü ü
EP074E: Halogenated Aliphatic Compounds
Amber VOC Vial - Sulfuric Acid (EP074)MW4, MW5,MW6, QAQC1,TB1
31-Mar-202031-Mar-2020 20-Mar-202020-Mar-202017-Mar-2020 ü ü
EP074F: Halogenated Aromatic Compounds
Amber VOC Vial - Sulfuric Acid (EP074)MW4, MW5,MW6, QAQC1,TB1
31-Mar-202031-Mar-2020 20-Mar-202020-Mar-202017-Mar-2020 ü ü
EP074G: Trihalomethanes
Amber VOC Vial - Sulfuric Acid (EP074)MW4, MW5,MW6, QAQC1,TB1
31-Mar-202031-Mar-2020 20-Mar-202020-Mar-202017-Mar-2020 ü ü
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
Amber Glass Bottle - Unpreserved (EP075(SIM))MW4, MW5,MW6, QAQC1
28-Apr-202024-Mar-2020 21-Mar-202019-Mar-202017-Mar-2020 ü ü
EP080/071: Total Petroleum Hydrocarbons
Amber Glass Bottle - Unpreserved (EP071)MW4, MW5,MW6, QAQC1,RB1
28-Apr-202024-Mar-2020 21-Mar-202019-Mar-202017-Mar-2020 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)MW4, MW5,MW6, QAQC1,RB1, TB1
31-Mar-202031-Mar-2020 20-Mar-202020-Mar-202017-Mar-2020 ü ü
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
Amber Glass Bottle - Unpreserved (EP071)MW4, MW5,MW6, QAQC1,RB1
28-Apr-202024-Mar-2020 21-Mar-202019-Mar-202017-Mar-2020 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)MW4, MW5,MW6, QAQC1,RB1, TB1
31-Mar-202031-Mar-2020 20-Mar-202020-Mar-202017-Mar-2020 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP080: BTEXN
Amber VOC Vial - Sulfuric Acid (EP080)MW4, MW5,MW6, QAQC1,RB1, TB1
31-Mar-202031-Mar-2020 20-Mar-202020-Mar-202017-Mar-2020 ü ü
MM527: Legionella in Water
Sterile Plastic Bottle - Sodium Thiosulfate (MM527)MW4, MW5,MW6, QAQC1
19-Mar-2020---- 18-Mar-2020----17-Mar-2020 ---- ü
MM625: Salmonella - VIDAS (absence / presence)
Sterile Plastic Bottle - Sodium Thiosulfate (MM625)MW4, MW5,MW6, QAQC1
18-Mar-2020---- 18-Mar-2020----17-Mar-2020 ---- ü
MM696: E. coli & Faecal Coliforms by MF (Chromogenic)
Sterile Plastic Bottle - Sodium Thiosulfate (MM696)MW4, MW5,MW6, QAQC1
18-Mar-2020---- 18-Mar-2020----17-Mar-2020 ---- ü
MM698: Total Coliforms and E. coli by MF (Chromogenic)
Sterile Plastic Bottle - Sodium Thiosulfate (MM698)MW4, MW5,MW6, QAQC1
18-Mar-2020---- 18-Mar-2020----17-Mar-2020 ---- ü
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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification. Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
EvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-PNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAmmonia as N by Discrete analyser EK055GNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üConductivity by PC Titrator EA010-PNEPM 2013 B3 & ALS QC Standard 10.53 10.004 38 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 10.00 10.004 40 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 11.11 10.004 36 üFluoride by PC Titrator EK040PNEPM 2013 B3 & ALS QC Standard 14.29 10.001 7 üMajor Cations - Dissolved ED093FNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059GNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite as N by Discrete Analyser EK057GNEPM 2013 B3 & ALS QC Standard 0.00 10.000 6 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)NEPM 2013 B3 & ALS QC Standard 0.00 10.000 4 ûPesticides by GCMS EP068NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üpH by PC Titrator EA005-PNEPM 2013 B3 & ALS QC Standard 0.00 10.000 4 ûPolychlorinated Biphenyls (PCB) EP066NEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üReactive Phosphorus as P-By Discrete Analyser EK071GNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 12.50 10.001 8 üTotal Carbon EP007NEPM 2013 B3 & ALS QC Standard 11.11 10.001 9 üTotal Inorganic Carbon EP006NEPM 2013 B3 & ALS QC Standard 10.26 10.004 39 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061GNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üTotal Phosphorus as P By Discrete Analyser EK067GNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 10.00 10.001 10 üVolatile Organic Compounds EP074
Laboratory Control Samples (LCS)NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAlkalinity by PC Titrator ED037-PNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055GNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üConductivity by PC Titrator EA010-PNEPM 2013 B3 & ALS QC Standard 5.26 5.002 38 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 5.00 5.002 40 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 5.56 5.002 36 üFluoride by PC Titrator EK040PNEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üMajor Cations - Dissolved ED093FNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057GNEPM 2013 B3 & ALS QC Standard 16.67 5.001 6 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification. Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
EvaluationAnalytical Methods Method
Laboratory Control Samples (LCS) - ContinuedNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üPesticides by GCMS EP068NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üPolychlorinated Biphenyls (PCB) EP066NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üReactive Phosphorus as P-By Discrete Analyser EK071GNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 12.50 5.001 8 üTotal Carbon EP007NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üTotal Inorganic Carbon EP006NEPM 2013 B3 & ALS QC Standard 5.13 5.002 39 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üTotal Phosphorus as P By Discrete Analyser EK067GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üVolatile Organic Compounds EP074
Method Blanks (MB)NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üConductivity by PC Titrator EA010-PNEPM 2013 B3 & ALS QC Standard 5.26 5.002 38 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 5.00 5.002 40 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 5.56 5.002 36 üFluoride by PC Titrator EK040PNEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üMajor Cations - Dissolved ED093FNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057GNEPM 2013 B3 & ALS QC Standard 16.67 5.001 6 üPAH/Phenols (GC/MS - SIM) EP075(SIM)NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üPesticides by GCMS EP068NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üPolychlorinated Biphenyls (PCB) EP066NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üReactive Phosphorus as P-By Discrete Analyser EK071GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 12.50 5.001 8 üTotal Carbon EP007NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üTotal Inorganic Carbon EP006NEPM 2013 B3 & ALS QC Standard 5.13 5.002 39 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üTotal Phosphorus as P By Discrete Analyser EK067GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üVolatile Organic Compounds EP074
Matrix Spikes (MS)NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 5.26 5.002 38 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 5.00 5.002 40 üDissolved Metals by ICP-MS - Suite A EG020A-F
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification. Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
EvaluationAnalytical Methods Method
Matrix Spikes (MS) - ContinuedNEPM 2013 B3 & ALS QC Standard 5.56 5.002 36 üFluoride by PC Titrator EK040PNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057GNEPM 2013 B3 & ALS QC Standard 0.00 5.000 6 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)NEPM 2013 B3 & ALS QC Standard 0.00 5.000 4 ûPesticides by GCMS EP068NEPM 2013 B3 & ALS QC Standard 0.00 5.000 4 ûPolychlorinated Biphenyls (PCB) EP066NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üReactive Phosphorus as P-By Discrete Analyser EK071GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 12.50 5.001 8 üTotal Carbon EP007NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üTotal Inorganic Carbon EP006NEPM 2013 B3 & ALS QC Standard 5.13 5.002 39 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üTotal Phosphorus as P By Discrete Analyser EK067GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üVolatile Organic Compounds EP074
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Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 H+ B. This procedure determines pH of water samples by automated ISE. This method is compliant with NEPM (2013) Schedule B(3)
pH by PC Titrator EA005-P WATER
In house: Referenced to APHA 2510 B. This procedure determines conductivity by automated ISE. This method is compliant with NEPM (2013) Schedule B(3)
Conductivity by PC Titrator EA010-P WATER
In house: Calculation from Electrical Conductivity (APHA 2510 B) using a conversion factor specified in the analytical report. This method is compliant with NEPM (2013) Schedule B(3)
Calculated TDS (from Electrical Conductivity)
EA016 WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013) Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500-SO4. Dissolved sulfate is determined in a 0.45um filtered sample. Sulfate ions are converted to a barium sulfate suspension in an acetic acid medium with barium chloride. Light absorbance of the BaSO4 suspension is measured by a photometer and the SO4-2 concentration is determined by comparison of the reading with a standard curve. This method is compliant with NEPM (2013) Schedule B(3)
Sulfate (Turbidimetric) as SO4 2- by Discrete Analyser
ED041G WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013) Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS) Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique. A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell. Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
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Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500-F C: CDTA is added to the sample to provide a uniform ionic strength background, adjust pH, and break up complexes. Fluoride concentration is determined by either manual or automatic ISE measurement. This method is compliant with NEPM (2013) Schedule B(3)
Fluoride by PC Titrator EK040P WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Nitrite as N by Discrete Analyser EK057G WATER
In house: Referenced to APHA 4500-NO3- F. Nitrate is reduced to nitrite by way of a chemical reduction followed by quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate calculated as the difference between the two results. This method is compliant with NEPM (2013) Schedule B(3)
Nitrate as N by Discrete Analyser EK058G WATER
In house: Referenced to APHA 4500-NO3- F. Combined oxidised Nitrogen (NO2+NO3) is determined by Chemical Reduction and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Nitrite and Nitrate as N (NOx) by Discrete Analyser
EK059G WATER
In house: Referenced to APHA 4500-Norg D (In house). An aliquot of sample is digested using a high temperature Kjeldahl digestion to convert nitrogenous compounds to ammonia. Ammonia is determined colorimetrically by discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Kjeldahl Nitrogen as N By Discrete Analyser
EK061G WATER
In house: Referenced to APHA 4500-Norg / 4500-NO3-. This method is compliant with NEPM (2013) Schedule B(3)
Total Nitrogen as N (TKN + Nox) By Discrete Analyser
EK062G WATER
In house: Referenced to APHA 4500-P H, Jirka et al (1976), Zhang et al (2006). This procedure involves sulphuric acid digestion of a sample aliquot to break phosphorus down to orthophosphate. The orthophosphate reacts with ammonium molybdate and antimony potassium tartrate to form a complex which is then reduced and its concentration measured at 880nm using discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Phosphorus as P By Discrete Analyser
EK067G WATER
In house: Referenced to APHA 4500-P F Ammonium molybdate and potassium antimonyl tartrate reacts in acid medium with othophosphate to form a heteropoly acid -phosphomolybdic acid - which is reduced to intensely coloured molybdenum blue by ascorbic acid. Quantification is by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Reactive Phosphorus as P-By Discrete Analyser
EK071G WATER
In house: Referenced to APHA 1030F. This method is compliant with NEPM (2013) Schedule B(3)Ionic Balance by PCT DA and Turbi SO4 DA
* EN055 - PG WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to APHA 5310 B The automated carbon analyzer removes Inorganic carbon as CO2, which is swept into an IR detector. This method is compliant with NEPM (2013) Schedule B(3)
Total Inorganic Carbon EP006 WATER
In house: Referenced to APHA 5310 B The automated Carbon analyzer converts all Carbon to CO2, which is swept into an IR detector. This method is compliant with NEPM (2013) Schedule B(3)
Total Carbon EP007 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Polychlorinated Biphenyls (PCB) EP066 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Pesticides by GCMS EP068 WATER
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Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and quantification is by comparison against an established 5 point calibration curve of n-Alkane standards. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH - Semivolatile Fraction EP071 WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Volatile Organic Compounds EP074 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS in SIM Mode and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
PAH/Phenols (GC/MS - SIM) EP075(SIM) WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. Alternatively, a sample is equilibrated in a headspace vial and a portion of the headspace determined by GCMS analysis. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH Volatiles/BTEX EP080 WATER
Specialist microbiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).Legionella in Water MM527 WATERMicrobiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).Salmonella - VIDAS (absence /
presence)MM625 WATER
Microbiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).E. coli and Faecal Coliforms by MF (Chromogenic Media)
MM696 WATER
Microbiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).Total Coliforms and E. coli by MF (Chromogenic Media)
MM698 WATER
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 Norg - D; APHA 4500 P - H. This method is compliant with NEPM (2013) Schedule B(3)
TKN/TP Digestion EK061/EK067 WATER
In house: Referenced to USEPA SW 846 - 3510B 100 mL to 1L of sample is transferred to a separatory funnel and serially extracted three times using DCM for each extract. The resultant extracts are combined, dehydrated and concentrated for analysis. This method is compliant with NEPM (2013) Schedule B(3) . ALS default excludes sediment which may be resident in the container.
Separatory Funnel Extraction of Liquids ORG14 WATER
A 5 mL aliquot or 5 mL of a diluted sample is added to a 40 mL VOC vial for sparging.Volatiles Water Preparation ORG16-W WATER
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 14EM2004399
:: LaboratoryClient SESL Australia Pty Ltd Environmental Division Melbourne: :ContactContact STEPHEN COX Customer Services EM
:: AddressAddress LEVEL 1, 21 SHIELDS STFLEMINGTON VIC 3031
4 Westall Rd Springvale VIC Australia 3171
:Telephone ---- :Telephone +61-3-8549 9600:Project GWM EVENT J002435 Date Samples Received : 18-Mar-2020 09:20:Order number J002435 Date Analysis Commenced : 18-Mar-2020:C-O-C number ---- Issue Date : 31-Mar-2020 16:40
Sampler : STEPHENSite : ----Quote number : SYBQ/404/18
6:No. of samples received
6:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:l General Commentsl Analytical Resultsl Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Dilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VICNancy Wang 2IC Organic Chemist Melbourne Organics, Springvale, VICNikki Stepniewski Senior Inorganic Instrument Chemist Melbourne Inorganics, Springvale, VICSamantha Smith Laboratory Coordinator WRG Subcontracting, Springvale, VICXing Lin Senior Organic Chemist Melbourne Organics, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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General CommentsThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When sampling time information is not provided by the client, sampling dates are shown without a time component. In these instances, the time component has been assumed by the laboratory for processing purposes.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.LOR = Limit of reporting^ = This result is computed from individual analyte detections at or above the level of reportingø = ALS is not NATA accredited for these tests.~ = Indicates an estimated value.
Key :
E.Coli & FC (MM696) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989. NATA accreditation does not cover performance of this method.l
TC & E.Coli (MM698) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989. NATA accreditation does not cover performance of this method.l
Benzo(a)pyrene Toxicity Equivalent Quotient (TEQ) per the NEPM (2013) is the sum total of the concentration of the eight carcinogenic PAHs multiplied by their Toxicity Equivalence Factor (TEF) relative to Benzo(a)pyrene. TEF values are provided in brackets as follows: Benz(a)anthracene (0.1), Chrysene (0.01), Benzo(b+j) & Benzo(k)fluoranthene (0.1), Benzo(a)pyrene (1.0), Indeno(1.2.3.cd)pyrene (0.1), Dibenz(a.h)anthracene (1.0), Benzo(g.h.i)perylene (0.01). Less than LOR results for 'TEQ Zero' are treated as zero.
l
It is recognised that total carbon is less than total inorganic carbon for samples #1, #3 and #4. However, the difference is within experimental variation of the methods.l
Ionic balances were calculated using: major anions - chloride, alkalinity and sulfate; and major cations - calcium, magnesium, potassium and sodium.l
ED045G: The presence of thiocyanate can positively contribute to the chloride result, thereby may bias results higher than expected. Results should be scrutinised accordingly.l
EA010-P: Electrical Conductivity @ 25°C was analysed by manual method (EA010).l
EA016: Calculated TDS is determined from Electrical conductivity using a conversion factor of 0.65.l
Salmonella - VIDAS (MM625) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989.l
Legionella (MM527) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989.l
Sodium Adsorption Ratio (where reported): Where results for Na, Ca or Mg are <LOR, a concentration at half the reported LOR is incorporated into the SAR calculation. This represents a conservative approach for Na relative to the assumption that <LOR = zero concentration and a conservative approach for Ca & Mg relative to the assumption that <LOR is equivalent to the LOR concentration.
l
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Analytical ResultsRB1QAQC1MW6MW5MW4Client sample IDSub-Matrix: WATER
(Matrix: WATER)
17-Mar-2020 11:0017-Mar-2020 11:0017-Mar-2020 10:3017-Mar-2020 13:0017-Mar-2020 15:30Client sampling date / time
EM2004399-005EM2004399-004EM2004399-003EM2004399-002EM2004399-001UnitLORCAS NumberCompoundResult Result Result Result Result
EA005P: pH by PC Titrator
7.14 6.44 7.10 6.97 ----pH Unit0.01----pH Value
EA006: Sodium Adsorption Ratio (SAR)
13.0^ 16.9 17.1 17.2 -----0.01----Sodium Adsorption Ratio
EA010P: Conductivity by PC Titrator
7700 7920 7240 7260 ----µS/cm1----Electrical Conductivity @ 25°C
EA016: Calculated TDS (from Electrical Conductivity)
5000 5150 4710 4720 ----mg/L1----Total Dissolved Solids (Calc.)
EA065: Total Hardness as CaCO3
1380 1120 928 954 ----mg/L1----Total Hardness as CaCO3
ED037P: Alkalinity by PC Titrator<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 ----mg/L1DMO-210-001<1Carbonate Alkalinity as CaCO3 <1 <1 <1 ----mg/L13812-32-6516Bicarbonate Alkalinity as CaCO3 597 612 605 ----mg/L171-52-3516 597 612 605 ----mg/L1----Total Alkalinity as CaCO3
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
105Sulfate as SO4 - Turbidimetric 147 120 123 ----mg/L114808-79-8
ED045G: Chloride by Discrete Analyser
2570Chloride 2610 2040 2050 ----mg/L116887-00-6
ED093F: Dissolved Major Cations
138Calcium 116 88 90 ----mg/L17440-70-2251Magnesium 202 172 177 ----mg/L17439-95-41110Sodium 1300 1200 1220 ----mg/L17440-23-514Potassium 14 12 12 ----mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS<0.001Arsenic <0.001 <0.001 <0.001 <0.001mg/L0.0017440-38-2
<0.0001Cadmium <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9<0.001Chromium <0.001 <0.001 <0.001 <0.001mg/L0.0017440-47-30.020Copper 0.014 0.007 0.004 <0.001mg/L0.0017440-50-80.064Nickel 0.015 0.006 0.006 <0.001mg/L0.0017440-02-0
<0.001Lead <0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-10.062Zinc 0.059 0.030 0.024 <0.005mg/L0.0057440-66-6
EG035F: Dissolved Mercury by FIMS<0.0001Mercury <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6
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Analytical ResultsRB1QAQC1MW6MW5MW4Client sample IDSub-Matrix: WATER
(Matrix: WATER)
17-Mar-2020 11:0017-Mar-2020 11:0017-Mar-2020 10:3017-Mar-2020 13:0017-Mar-2020 15:30Client sampling date / time
EM2004399-005EM2004399-004EM2004399-003EM2004399-002EM2004399-001UnitLORCAS NumberCompoundResult Result Result Result Result
EK040P: Fluoride by PC Titrator
1.0Fluoride 1.0 1.3 1.3 ----mg/L0.116984-48-8
EK055G: Ammonia as N by Discrete Analyser
0.02Ammonia as N 0.06 0.02 <0.01 ----mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
0.01Nitrite as N <0.01 0.01 0.01 ----mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser
0.57Nitrate as N 3.92 2.19 2.24 ----mg/L0.0114797-55-8
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.58 3.92 2.20 2.25 ----mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
0.1 0.6 0.3 0.5 ----mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
0.7^ 4.5 2.5 2.8 ----mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
0.01 0.11 0.03 0.03 ----mg/L0.01----Total Phosphorus as P
EK071G: Reactive Phosphorus as P by discrete analyser<0.01Reactive Phosphorus as P <0.01 <0.01 <0.01 ----mg/L0.0114265-44-2
EN055: Ionic Balance
85.0ø 88.6 72.3 72.5 ----meq/L0.01----Total Anions
76.2ø 79.3 71.0 72.4 ----meq/L0.01----Total Cations
5.46ø 5.54 0.85 0.03 ----%0.01----Ionic Balance
EP005: Total Organic Carbon (TOC)
2 <1 <1 <1 ----mg/L1----Total Organic Carbon
EP006 Total Inorganic Carbon
142 184 165 168 ----mg/L1----Total Inorganic Carbon
EP007 Total Carbon
139Total Carbon 184 163 165 ----mg/L1TC
EP066: Polychlorinated Biphenyls (PCB)<1^ <1 <1 <1 ----µg/L1----Total Polychlorinated biphenyls
EP068A: Organochlorine Pesticides (OC)<0.5alpha-BHC <0.5 <0.5 <0.5 ----µg/L0.5319-84-6<0.5Hexachlorobenzene (HCB) <0.5 <0.5 <0.5 ----µg/L0.5118-74-1<0.5beta-BHC <0.5 <0.5 <0.5 ----µg/L0.5319-85-7
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Analytical ResultsRB1QAQC1MW6MW5MW4Client sample IDSub-Matrix: WATER
(Matrix: WATER)
17-Mar-2020 11:0017-Mar-2020 11:0017-Mar-2020 10:3017-Mar-2020 13:0017-Mar-2020 15:30Client sampling date / time
EM2004399-005EM2004399-004EM2004399-003EM2004399-002EM2004399-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP068A: Organochlorine Pesticides (OC) - Continued
<0.5gamma-BHC <0.5 <0.5 <0.5 ----µg/L0.558-89-9<0.5delta-BHC <0.5 <0.5 <0.5 ----µg/L0.5319-86-8<0.5Heptachlor <0.5 <0.5 <0.5 ----µg/L0.576-44-8<0.5Aldrin <0.5 <0.5 <0.5 ----µg/L0.5309-00-2<0.5Heptachlor epoxide <0.5 <0.5 <0.5 ----µg/L0.51024-57-3<0.5trans-Chlordane <0.5 <0.5 <0.5 ----µg/L0.55103-74-2<0.5alpha-Endosulfan <0.5 <0.5 <0.5 ----µg/L0.5959-98-8<0.5cis-Chlordane <0.5 <0.5 <0.5 ----µg/L0.55103-71-9<0.5Dieldrin <0.5 <0.5 <0.5 ----µg/L0.560-57-1<0.54.4`-DDE <0.5 <0.5 <0.5 ----µg/L0.572-55-9<0.5Endrin <0.5 <0.5 <0.5 ----µg/L0.572-20-8<0.5beta-Endosulfan <0.5 <0.5 <0.5 ----µg/L0.533213-65-9<0.54.4`-DDD <0.5 <0.5 <0.5 ----µg/L0.572-54-8<0.5Endrin aldehyde <0.5 <0.5 <0.5 ----µg/L0.57421-93-4<0.5Endosulfan sulfate <0.5 <0.5 <0.5 ----µg/L0.51031-07-8<2.04.4`-DDT <2.0 <2.0 <2.0 ----µg/L2.050-29-3<0.5Endrin ketone <0.5 <0.5 <0.5 ----µg/L0.553494-70-5<2.0Methoxychlor <2.0 <2.0 <2.0 ----µg/L2.072-43-5<0.5^ <0.5 <0.5 <0.5 ----µg/L0.5----Total Chlordane (sum)
<0.5^ Sum of DDD + DDE + DDT <0.5 <0.5 <0.5 ----µg/L0.572-54-8/72-55-9/50-2
<0.5^ Sum of Aldrin + Dieldrin <0.5 <0.5 <0.5 ----µg/L0.5309-00-2/60-57-1
EP068B: Organophosphorus Pesticides (OP)<0.5Dichlorvos <0.5 <0.5 <0.5 ----µg/L0.562-73-7<0.5Demeton-S-methyl <0.5 <0.5 <0.5 ----µg/L0.5919-86-8<2.0Monocrotophos <2.0 <2.0 <2.0 ----µg/L2.06923-22-4<0.5Dimethoate <0.5 <0.5 <0.5 ----µg/L0.560-51-5<0.5Diazinon <0.5 <0.5 <0.5 ----µg/L0.5333-41-5<0.5Chlorpyrifos-methyl <0.5 <0.5 <0.5 ----µg/L0.55598-13-0<2.0Parathion-methyl <2.0 <2.0 <2.0 ----µg/L2.0298-00-0<0.5Malathion <0.5 <0.5 <0.5 ----µg/L0.5121-75-5<0.5Fenthion <0.5 <0.5 <0.5 ----µg/L0.555-38-9<0.5Chlorpyrifos <0.5 <0.5 <0.5 ----µg/L0.52921-88-2<2.0Parathion <2.0 <2.0 <2.0 ----µg/L2.056-38-2<0.5Pirimphos-ethyl <0.5 <0.5 <0.5 ----µg/L0.523505-41-1
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(Matrix: WATER)
17-Mar-2020 11:0017-Mar-2020 11:0017-Mar-2020 10:3017-Mar-2020 13:0017-Mar-2020 15:30Client sampling date / time
EM2004399-005EM2004399-004EM2004399-003EM2004399-002EM2004399-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP068B: Organophosphorus Pesticides (OP) - Continued
<0.5Chlorfenvinphos <0.5 <0.5 <0.5 ----µg/L0.5470-90-6<0.5Bromophos-ethyl <0.5 <0.5 <0.5 ----µg/L0.54824-78-6<0.5Fenamiphos <0.5 <0.5 <0.5 ----µg/L0.522224-92-6<0.5Prothiofos <0.5 <0.5 <0.5 ----µg/L0.534643-46-4<0.5Ethion <0.5 <0.5 <0.5 ----µg/L0.5563-12-2<0.5Carbophenothion <0.5 <0.5 <0.5 ----µg/L0.5786-19-6<0.5Azinphos Methyl <0.5 <0.5 <0.5 ----µg/L0.586-50-0
EP074A: Monocyclic Aromatic Hydrocarbons<5Styrene <5 <5 <5 ----µg/L5100-42-5<5Isopropylbenzene <5 <5 <5 ----µg/L598-82-8<5n-Propylbenzene <5 <5 <5 ----µg/L5103-65-1<51.3.5-Trimethylbenzene <5 <5 <5 ----µg/L5108-67-8<5sec-Butylbenzene <5 <5 <5 ----µg/L5135-98-8<51.2.4-Trimethylbenzene <5 <5 <5 ----µg/L595-63-6<5tert-Butylbenzene <5 <5 <5 ----µg/L598-06-6<5p-Isopropyltoluene <5 <5 <5 ----µg/L599-87-6<5n-Butylbenzene <5 <5 <5 ----µg/L5104-51-8
EP074B: Oxygenated Compounds<50Vinyl Acetate <50 <50 <50 ----µg/L50108-05-4<502-Butanone (MEK) <50 <50 <50 ----µg/L5078-93-3<504-Methyl-2-pentanone (MIBK) <50 <50 <50 ----µg/L50108-10-1<502-Hexanone (MBK) <50 <50 <50 ----µg/L50591-78-6
EP074C: Sulfonated Compounds<5Carbon disulfide <5 <5 <5 ----µg/L575-15-0
EP074D: Fumigants<52.2-Dichloropropane <5 <5 <5 ----µg/L5594-20-7<51.2-Dichloropropane <5 <5 <5 ----µg/L578-87-5<5cis-1.3-Dichloropropylene <5 <5 <5 ----µg/L510061-01-5<5trans-1.3-Dichloropropylene <5 <5 <5 ----µg/L510061-02-6<51.2-Dibromoethane (EDB) <5 <5 <5 ----µg/L5106-93-4
EP074E: Halogenated Aliphatic Compounds<50Dichlorodifluoromethane <50 <50 <50 ----µg/L5075-71-8<50Chloromethane <50 <50 <50 ----µg/L5074-87-3<50Vinyl chloride <50 <50 <50 ----µg/L5075-01-4
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(Matrix: WATER)
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EM2004399-005EM2004399-004EM2004399-003EM2004399-002EM2004399-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP074E: Halogenated Aliphatic Compounds - Continued
<50Bromomethane <50 <50 <50 ----µg/L5074-83-9<50Chloroethane <50 <50 <50 ----µg/L5075-00-3<50Trichlorofluoromethane <50 <50 <50 ----µg/L5075-69-4<51.1-Dichloroethene <5 <5 <5 ----µg/L575-35-4<5Iodomethane <5 <5 <5 ----µg/L574-88-4<5trans-1.2-Dichloroethene <5 <5 <5 ----µg/L5156-60-5<51.1-Dichloroethane <5 <5 <5 ----µg/L575-34-3<5cis-1.2-Dichloroethene <5 <5 <5 ----µg/L5156-59-2<51.1.1-Trichloroethane <5 <5 <5 ----µg/L571-55-6<51.1-Dichloropropylene <5 <5 <5 ----µg/L5563-58-6<5Carbon Tetrachloride <5 <5 <5 ----µg/L556-23-5<51.2-Dichloroethane <5 <5 <5 ----µg/L5107-06-2<5Trichloroethene <5 <5 <5 ----µg/L579-01-6<5Dibromomethane <5 <5 <5 ----µg/L574-95-3<51.1.2-Trichloroethane <5 <5 <5 ----µg/L579-00-5<51.3-Dichloropropane <5 <5 <5 ----µg/L5142-28-9<5Tetrachloroethene <5 <5 <5 ----µg/L5127-18-4<51.1.1.2-Tetrachloroethane <5 <5 <5 ----µg/L5630-20-6<5trans-1.4-Dichloro-2-butene <5 <5 <5 ----µg/L5110-57-6<5cis-1.4-Dichloro-2-butene <5 <5 <5 ----µg/L51476-11-5<51.1.2.2-Tetrachloroethane <5 <5 <5 ----µg/L579-34-5<51.2.3-Trichloropropane <5 <5 <5 ----µg/L596-18-4<5Pentachloroethane <5 <5 <5 ----µg/L576-01-7<51.2-Dibromo-3-chloropropane <5 <5 <5 ----µg/L596-12-8<5Hexachlorobutadiene <5 <5 <5 ----µg/L587-68-3
EP074F: Halogenated Aromatic Compounds<5Chlorobenzene <5 <5 <5 ----µg/L5108-90-7<5Bromobenzene <5 <5 <5 ----µg/L5108-86-1<52-Chlorotoluene <5 <5 <5 ----µg/L595-49-8<54-Chlorotoluene <5 <5 <5 ----µg/L5106-43-4<51.3-Dichlorobenzene <5 <5 <5 ----µg/L5541-73-1<51.4-Dichlorobenzene <5 <5 <5 ----µg/L5106-46-7<51.2-Dichlorobenzene <5 <5 <5 ----µg/L595-50-1<51.2.4-Trichlorobenzene <5 <5 <5 ----µg/L5120-82-1<51.2.3-Trichlorobenzene <5 <5 <5 ----µg/L587-61-6
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Analytical ResultsRB1QAQC1MW6MW5MW4Client sample IDSub-Matrix: WATER
(Matrix: WATER)
17-Mar-2020 11:0017-Mar-2020 11:0017-Mar-2020 10:3017-Mar-2020 13:0017-Mar-2020 15:30Client sampling date / time
EM2004399-005EM2004399-004EM2004399-003EM2004399-002EM2004399-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP074G: Trihalomethanes<5Chloroform <5 <5 <5 ----µg/L567-66-3<5Bromodichloromethane <5 <5 <5 ----µg/L575-27-4<5Dibromochloromethane <5 <5 <5 ----µg/L5124-48-1<5Bromoform <5 <5 <5 ----µg/L575-25-2
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons<1.0Naphthalene <1.0 <1.0 <1.0 ----µg/L1.091-20-3<1.0Acenaphthylene <1.0 <1.0 <1.0 ----µg/L1.0208-96-8<1.0Acenaphthene <1.0 <1.0 <1.0 ----µg/L1.083-32-9<1.0Fluorene <1.0 <1.0 <1.0 ----µg/L1.086-73-7<1.0Phenanthrene <1.0 <1.0 <1.0 ----µg/L1.085-01-8<1.0Anthracene <1.0 <1.0 <1.0 ----µg/L1.0120-12-7<1.0Fluoranthene <1.0 <1.0 <1.0 ----µg/L1.0206-44-0<1.0Pyrene <1.0 <1.0 <1.0 ----µg/L1.0129-00-0<1.0Benz(a)anthracene <1.0 <1.0 <1.0 ----µg/L1.056-55-3<1.0Chrysene <1.0 <1.0 <1.0 ----µg/L1.0218-01-9<1.0Benzo(b+j)fluoranthene <1.0 <1.0 <1.0 ----µg/L1.0205-99-2 205-82-3<1.0Benzo(k)fluoranthene <1.0 <1.0 <1.0 ----µg/L1.0207-08-9<0.5Benzo(a)pyrene <0.5 <0.5 <0.5 ----µg/L0.550-32-8<1.0Indeno(1.2.3.cd)pyrene <1.0 <1.0 <1.0 ----µg/L1.0193-39-5<1.0Dibenz(a.h)anthracene <1.0 <1.0 <1.0 ----µg/L1.053-70-3<1.0Benzo(g.h.i)perylene <1.0 <1.0 <1.0 ----µg/L1.0191-24-2<0.5^ <0.5 <0.5 <0.5 ----µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ <0.5 <0.5 <0.5 ----µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons<20 <20 <20 <20 <20µg/L20----C6 - C9 Fraction
<50 <50 <50 <50 <50µg/L50----C10 - C14 Fraction
<100 <100 <100 <100 <100µg/L100----C15 - C28 Fraction
<50 <50 <50 <50 <50µg/L50----C29 - C36 Fraction
<50^ <50 <50 <50 <50µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions<20C6 - C10 Fraction <20 <20 <20 <20µg/L20C6_C10<20^ C6 - C10 Fraction minus BTEX
(F1)
<20 <20 <20 <20µg/L20C6_C10-BTEX
<100 <100 <100 <100 <100µg/L100---->C10 - C16 Fraction
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Analytical ResultsRB1QAQC1MW6MW5MW4Client sample IDSub-Matrix: WATER
(Matrix: WATER)
17-Mar-2020 11:0017-Mar-2020 11:0017-Mar-2020 10:3017-Mar-2020 13:0017-Mar-2020 15:30Client sampling date / time
EM2004399-005EM2004399-004EM2004399-003EM2004399-002EM2004399-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions - Continued
<100 <100 <100 <100 <100µg/L100---->C16 - C34 Fraction
<100 <100 <100 <100 <100µg/L100---->C34 - C40 Fraction
<100^ <100 <100 <100 <100µg/L100---->C10 - C40 Fraction (sum)
<100^ <100 <100 <100 <100µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN<1Benzene <1 <1 <1 <1µg/L171-43-2<2Toluene <2 <2 <2 <2µg/L2108-88-3<2Ethylbenzene <2 <2 <2 <2µg/L2100-41-4<2meta- & para-Xylene <2 <2 <2 <2µg/L2108-38-3 106-42-3<2ortho-Xylene <2 <2 <2 <2µg/L295-47-6<2^ <2 <2 <2 <2µg/L2----Total Xylenes
<1^ <1 <1 <1 <1µg/L1----Sum of BTEX
<5Naphthalene <5 <5 <5 <5µg/L591-20-3
MM527: Legionella in Water<10Legionella Total <10 <10 <10 ----cfu/ml10LEGIONELLA_TOT<10 <10 <10 <10 ----cfu/ml10----Legionella pneumophila <10 <10 <10 <10 ----cfu/ml10----Legionella Species
MM625: Salmonella - VIDAS (absence / presence)
Not Detected Not Detected Not Detected Not Detected -----1----Salmonella spp.
MM696: E. coli & Faecal Coliforms by MF (Chromogenic)
2000 60 10 <10 ----CFU/100mL1----Escherichia coli 2000 60 10 <10 ----CFU/100mL1----Faecal Coliforms
MM698: Total Coliforms and E. coli by MF (Chromogenic)
2700 6500 60 30 ----CFU/100mL1----Total Coliforms by MF
EP066S: PCB Surrogate
80.8Decachlorobiphenyl 75.4 73.1 74.4 ----%12051-24-3
EP068S: Organochlorine Pesticide Surrogate
94.1Dibromo-DDE 86.8 89.0 89.1 ----%0.521655-73-2
EP068T: Organophosphorus Pesticide Surrogate
102DEF 99.1 99.8 101 ----%0.578-48-8
EP074S: VOC Surrogates
97.61.2-Dichloroethane-D4 99.2 96.9 98.1 ----%517060-07-0
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Analytical ResultsRB1QAQC1MW6MW5MW4Client sample IDSub-Matrix: WATER
(Matrix: WATER)
17-Mar-2020 11:0017-Mar-2020 11:0017-Mar-2020 10:3017-Mar-2020 13:0017-Mar-2020 15:30Client sampling date / time
EM2004399-005EM2004399-004EM2004399-003EM2004399-002EM2004399-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP074S: VOC Surrogates - Continued
97.0Toluene-D8 98.3 100 94.4 ----%52037-26-598.24-Bromofluorobenzene 99.7 98.7 98.1 ----%5460-00-4
EP075(SIM)S: Phenolic Compound Surrogates
34.2Phenol-d6 31.6 32.1 34.5 ----%1.013127-88-394.42-Chlorophenol-D4 93.1 89.0 95.5 ----%1.093951-73-61062.4.6-Tribromophenol 105 100 102 ----%1.0118-79-6
EP075(SIM)T: PAH Surrogates
94.42-Fluorobiphenyl 92.2 90.2 93.9 ----%1.0321-60-893.1Anthracene-d10 88.0 88.3 89.4 ----%1.01719-06-898.54-Terphenyl-d14 91.5 93.3 93.5 ----%1.01718-51-0
EP080S: TPH(V)/BTEX Surrogates
1011.2-Dichloroethane-D4 104 101 103 100%217060-07-098.0Toluene-D8 99.9 102 95.8 98.4%22037-26-51094-Bromofluorobenzene 113 111 107 108%2460-00-4
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Analytical Results----------------TB1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------17-Mar-2020 11:00Client sampling date / time
--------------------------------EM2004399-006UnitLORCAS NumberCompoundResult ---- ---- ---- ----
EP074A: Monocyclic Aromatic Hydrocarbons<5Styrene ---- ---- ---- ----µg/L5100-42-5<5Isopropylbenzene ---- ---- ---- ----µg/L598-82-8<5n-Propylbenzene ---- ---- ---- ----µg/L5103-65-1<51.3.5-Trimethylbenzene ---- ---- ---- ----µg/L5108-67-8<5sec-Butylbenzene ---- ---- ---- ----µg/L5135-98-8<51.2.4-Trimethylbenzene ---- ---- ---- ----µg/L595-63-6<5tert-Butylbenzene ---- ---- ---- ----µg/L598-06-6<5p-Isopropyltoluene ---- ---- ---- ----µg/L599-87-6<5n-Butylbenzene ---- ---- ---- ----µg/L5104-51-8
EP074B: Oxygenated Compounds<50Vinyl Acetate ---- ---- ---- ----µg/L50108-05-4<502-Butanone (MEK) ---- ---- ---- ----µg/L5078-93-3<504-Methyl-2-pentanone (MIBK) ---- ---- ---- ----µg/L50108-10-1<502-Hexanone (MBK) ---- ---- ---- ----µg/L50591-78-6
EP074C: Sulfonated Compounds<5Carbon disulfide ---- ---- ---- ----µg/L575-15-0
EP074D: Fumigants<52.2-Dichloropropane ---- ---- ---- ----µg/L5594-20-7<51.2-Dichloropropane ---- ---- ---- ----µg/L578-87-5<5cis-1.3-Dichloropropylene ---- ---- ---- ----µg/L510061-01-5<5trans-1.3-Dichloropropylene ---- ---- ---- ----µg/L510061-02-6<51.2-Dibromoethane (EDB) ---- ---- ---- ----µg/L5106-93-4
EP074E: Halogenated Aliphatic Compounds<50Dichlorodifluoromethane ---- ---- ---- ----µg/L5075-71-8<50Chloromethane ---- ---- ---- ----µg/L5074-87-3<50Vinyl chloride ---- ---- ---- ----µg/L5075-01-4<50Bromomethane ---- ---- ---- ----µg/L5074-83-9<50Chloroethane ---- ---- ---- ----µg/L5075-00-3<50Trichlorofluoromethane ---- ---- ---- ----µg/L5075-69-4<51.1-Dichloroethene ---- ---- ---- ----µg/L575-35-4<5Iodomethane ---- ---- ---- ----µg/L574-88-4<5trans-1.2-Dichloroethene ---- ---- ---- ----µg/L5156-60-5<51.1-Dichloroethane ---- ---- ---- ----µg/L575-34-3<5cis-1.2-Dichloroethene ---- ---- ---- ----µg/L5156-59-2
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Analytical Results----------------TB1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------17-Mar-2020 11:00Client sampling date / time
--------------------------------EM2004399-006UnitLORCAS NumberCompoundResult ---- ---- ---- ----
EP074E: Halogenated Aliphatic Compounds - Continued
<51.1.1-Trichloroethane ---- ---- ---- ----µg/L571-55-6<51.1-Dichloropropylene ---- ---- ---- ----µg/L5563-58-6<5Carbon Tetrachloride ---- ---- ---- ----µg/L556-23-5<51.2-Dichloroethane ---- ---- ---- ----µg/L5107-06-2<5Trichloroethene ---- ---- ---- ----µg/L579-01-6<5Dibromomethane ---- ---- ---- ----µg/L574-95-3<51.1.2-Trichloroethane ---- ---- ---- ----µg/L579-00-5<51.3-Dichloropropane ---- ---- ---- ----µg/L5142-28-9<5Tetrachloroethene ---- ---- ---- ----µg/L5127-18-4<51.1.1.2-Tetrachloroethane ---- ---- ---- ----µg/L5630-20-6<5trans-1.4-Dichloro-2-butene ---- ---- ---- ----µg/L5110-57-6<5cis-1.4-Dichloro-2-butene ---- ---- ---- ----µg/L51476-11-5<51.1.2.2-Tetrachloroethane ---- ---- ---- ----µg/L579-34-5<51.2.3-Trichloropropane ---- ---- ---- ----µg/L596-18-4<5Pentachloroethane ---- ---- ---- ----µg/L576-01-7<51.2-Dibromo-3-chloropropane ---- ---- ---- ----µg/L596-12-8<5Hexachlorobutadiene ---- ---- ---- ----µg/L587-68-3
EP074F: Halogenated Aromatic Compounds<5Chlorobenzene ---- ---- ---- ----µg/L5108-90-7<5Bromobenzene ---- ---- ---- ----µg/L5108-86-1<52-Chlorotoluene ---- ---- ---- ----µg/L595-49-8<54-Chlorotoluene ---- ---- ---- ----µg/L5106-43-4<51.3-Dichlorobenzene ---- ---- ---- ----µg/L5541-73-1<51.4-Dichlorobenzene ---- ---- ---- ----µg/L5106-46-7<51.2-Dichlorobenzene ---- ---- ---- ----µg/L595-50-1<51.2.4-Trichlorobenzene ---- ---- ---- ----µg/L5120-82-1<51.2.3-Trichlorobenzene ---- ---- ---- ----µg/L587-61-6
EP074G: Trihalomethanes<5Chloroform ---- ---- ---- ----µg/L567-66-3<5Bromodichloromethane ---- ---- ---- ----µg/L575-27-4<5Dibromochloromethane ---- ---- ---- ----µg/L5124-48-1<5Bromoform ---- ---- ---- ----µg/L575-25-2
EP080/071: Total Petroleum Hydrocarbons<20 ---- ---- ---- ----µg/L20----C6 - C9 Fraction
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Analytical Results----------------TB1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------17-Mar-2020 11:00Client sampling date / time
--------------------------------EM2004399-006UnitLORCAS NumberCompoundResult ---- ---- ---- ----
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions<20C6 - C10 Fraction ---- ---- ---- ----µg/L20C6_C10<20^ C6 - C10 Fraction minus BTEX
(F1)
---- ---- ---- ----µg/L20C6_C10-BTEX
EP080: BTEXN<1Benzene ---- ---- ---- ----µg/L171-43-2<2Toluene ---- ---- ---- ----µg/L2108-88-3<2Ethylbenzene ---- ---- ---- ----µg/L2100-41-4<2meta- & para-Xylene ---- ---- ---- ----µg/L2108-38-3 106-42-3<2ortho-Xylene ---- ---- ---- ----µg/L295-47-6<2^ ---- ---- ---- ----µg/L2----Total Xylenes
<1^ ---- ---- ---- ----µg/L1----Sum of BTEX
<5Naphthalene ---- ---- ---- ----µg/L591-20-3
EP074S: VOC Surrogates
97.21.2-Dichloroethane-D4 ---- ---- ---- ----%517060-07-094.3Toluene-D8 ---- ---- ---- ----%52037-26-594.44-Bromofluorobenzene ---- ---- ---- ----%5460-00-4
EP080S: TPH(V)/BTEX Surrogates
1011.2-Dichloroethane-D4 ---- ---- ---- ----%217060-07-095.8Toluene-D8 ---- ---- ---- ----%22037-26-51074-Bromofluorobenzene ---- ---- ---- ----%2460-00-4
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Surrogate Control LimitsRecovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP066S: PCB Surrogate
Decachlorobiphenyl 2051-24-3 41 125
EP068S: Organochlorine Pesticide Surrogate
Dibromo-DDE 21655-73-2 49 117
EP068T: Organophosphorus Pesticide Surrogate
DEF 78-48-8 51 127
EP074S: VOC Surrogates
1.2-Dichloroethane-D4 17060-07-0 72 132Toluene-D8 2037-26-5 77 1324-Bromofluorobenzene 460-00-4 67 131
EP075(SIM)S: Phenolic Compound Surrogates
Phenol-d6 13127-88-3 10 462-Chlorophenol-D4 93951-73-6 23 1042.4.6-Tribromophenol 118-79-6 28 130
EP075(SIM)T: PAH Surrogates
2-Fluorobiphenyl 321-60-8 36 114Anthracene-d10 1719-06-8 51 1194-Terphenyl-d14 1718-51-0 49 127
EP080S: TPH(V)/BTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 73 129Toluene-D8 2037-26-5 70 1254-Bromofluorobenzene 460-00-4 71 129
May GME
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 10EM2008003
:: LaboratoryClient SESL Australia Pty Ltd Environmental Division Melbourne: :ContactContact STEPHEN COX Customer Services EM
:: AddressAddress LEVEL 1, 21 SHIELDS STFLEMINGTON VIC 3031
4 Westall Rd Springvale VIC Australia 3171
:Telephone ---- :Telephone +61-3-8549 9600:Project GWME J002546 Date Samples Received : 14-May-2020 09:15:Order number J002546 Date Analysis Commenced : 14-May-2020:C-O-C number ---- Issue Date : 22-May-2020 16:01
Sampler : STEPHEN COXSite : ----Quote number : SYBQ/404/18
6:No. of samples received
6:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:l General Commentsl Analytical Resultsl Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Arenie Vijayaratnam Non-Metals Team Leader Melbourne Inorganics, Springvale, VICDilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VICNancy Wang 2IC Organic Chemist Melbourne Organics, Springvale, VICSamantha Smith Laboratory Coordinator WRG Subcontracting, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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General CommentsThe analytical procedures used by ALS have been developed from established internationally recognised procedures such as those published by the USEPA, APHA, AS and NEPM. In house developed procedures are fully validated and are often at the client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When sampling time information is not provided by the client, sampling dates are shown without a time component. In these instances, the time component has been assumed by the laboratory for processing purposes.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.LOR = Limit of reporting^ = This result is computed from individual analyte detections at or above the level of reportingø = ALS is not NATA accredited for these tests.~ = Indicates an estimated value.
Key :
EK040-P: EM2007941 #3. Insufficient sample provided to analyse fluoride duplicate.l
EP005, EP006 & EP007: EM2008003 #1-#4 has been diluted prior to analysis due to sample matrix. LORs have been raised accordingly.l
Prelim sent to client, as per request by Stephen Cox 22/05/2020l
It is recognised that total carbon is less than dissolved inorganic carbon for samples #1 and #4. However, the difference is within experimental variation of the methods.l
Total Coliforms by MF (Chromogenic Media) (MM698) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989.l
E.coli and Faecal Coliforms by MF (Chromogenic Media) (MM696) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989.l
Ionic balances were calculated using: major anions - chloride, alkalinity and sulfate; and major cations - calcium, magnesium, potassium and sodium.l
ED045G: The presence of thiocyanate can positively contribute to the chloride result, thereby may bias results higher than expected. Results should be scrutinised accordingly.l
EG020F: EM2007935 #1 Poor matrix spike recovery for dissolved Lead and Vanadium due to sample matrix. Confirmed by re-preparation and re-analysis.l
EA016: Calculated TDS is determined from Electrical conductivity using a conversion factor of 0.65.l
Salmonella - VIDAS (MM625) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989.l
Legionella (MM527) is conducted by ALS Scoresby NATA accreditation no. 992, site no. 989.l
Sodium Adsorption Ratio (where reported): Where results for Na, Ca or Mg are <LOR, a concentration at half the reported LOR is incorporated into the SAR calculation. This represents a conservative approach for Na relative to the assumption that <LOR = zero concentration and a conservative approach for Ca & Mg relative to the assumption that <LOR is equivalent to the LOR concentration.
l
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Analytical ResultsRB1 - 56716 : 5QAQC1 - 56716 : 4MW6 - 56716 : 3MW5 - 56716 : 2MW4 - 56716 :1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
13-May-2020 15:3013-May-2020 10:3013-May-2020 15:2013-May-2020 13:3013-May-2020 10:30Client sampling date / time
EM2008003-005EM2008003-004EM2008003-003EM2008003-002EM2008003-001UnitLORCAS NumberCompoundResult Result Result Result Result
EA005P: pH by PC Titrator
7.87 8.06 8.24 7.90 ----pH Unit0.01----pH Value
EA006: Sodium Adsorption Ratio (SAR)
12.4^ 18.6 18.4 12.4 -----0.01----Sodium Adsorption Ratio
EA010P: Conductivity by PC Titrator
7340 7150 6900 7360 ----µS/cm1----Electrical Conductivity @ 25°C
EA016: Calculated TDS (from Electrical Conductivity)
4770 4650 4480 4780 ----mg/L1----Total Dissolved Solids (Calc.)
EA065: Total Hardness as CaCO3
1350 773 728 1360 ----mg/L1----Total Hardness as CaCO3
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 ----mg/L1DMO-210-001<1Carbonate Alkalinity as CaCO3 <1 <1 <1 ----mg/L13812-32-6497Bicarbonate Alkalinity as CaCO3 527 537 500 ----mg/L171-52-3497 527 537 500 ----mg/L1----Total Alkalinity as CaCO3
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
97Sulfate as SO4 - Turbidimetric 126 148 99 ----mg/L114808-79-8
ED045G: Chloride by Discrete Analyser
2490Chloride 2080 1890 2580 ----mg/L116887-00-6
ED093F: Dissolved Major Cations
143Calcium 72 69 143 ----mg/L17440-70-2242Magnesium 144 135 243 ----mg/L17439-95-41050Sodium 1190 1140 1050 ----mg/L17440-23-514Potassium 9 18 13 ----mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
<0.001Arsenic <0.001 <0.001 <0.001 ----mg/L0.0017440-38-2<0.0001Cadmium <0.0001 <0.0001 <0.0001 ----mg/L0.00017440-43-9<0.001Chromium <0.001 <0.001 <0.001 ----mg/L0.0017440-47-30.006Copper 0.009 0.003 0.003 ----mg/L0.0017440-50-80.010Nickel 0.006 0.004 0.007 ----mg/L0.0017440-02-0
<0.001Lead <0.001 <0.001 <0.001 ----mg/L0.0017439-92-10.039Zinc 0.048 0.018 0.030 ----mg/L0.0057440-66-6
EG020T: Total Metals by ICP-MS
----Arsenic ---- ---- ---- <0.001mg/L0.0017440-38-2
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Analytical ResultsRB1 - 56716 : 5QAQC1 - 56716 : 4MW6 - 56716 : 3MW5 - 56716 : 2MW4 - 56716 :1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
13-May-2020 15:3013-May-2020 10:3013-May-2020 15:2013-May-2020 13:3013-May-2020 10:30Client sampling date / time
EM2008003-005EM2008003-004EM2008003-003EM2008003-002EM2008003-001UnitLORCAS NumberCompoundResult Result Result Result Result
EG020T: Total Metals by ICP-MS - Continued
----Cadmium ---- ---- ---- <0.0001mg/L0.00017440-43-9----Chromium ---- ---- ---- <0.001mg/L0.0017440-47-3----Copper ---- ---- ---- <0.001mg/L0.0017440-50-8----Nickel ---- ---- ---- <0.001mg/L0.0017440-02-0----Lead ---- ---- ---- <0.001mg/L0.0017439-92-1----Zinc ---- ---- ---- <0.005mg/L0.0057440-66-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 ----mg/L0.00017439-97-6
EG035T: Total Recoverable Mercury by FIMS
----Mercury ---- ---- ---- <0.0001mg/L0.00017439-97-6
EK040P: Fluoride by PC Titrator
1.2Fluoride 1.8 1.6 1.1 ----mg/L0.116984-48-8
EK055G: Ammonia as N by Discrete Analyser
0.05Ammonia as N <0.01 0.08 0.01 ----mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
<0.01Nitrite as N <0.01 0.03 <0.01 ----mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser
0.42Nitrate as N 9.48 6.89 0.42 ----mg/L0.0114797-55-8
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.42 9.48 6.92 0.42 ----mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
0.2 0.4 0.4 0.2 ----mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
0.6^ 9.9 7.3 0.6 ----mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
<0.01 <0.01 <0.01 <0.01 ----mg/L0.01----Total Phosphorus as P
EK071G: Reactive Phosphorus as P by discrete analyser
<0.01Reactive Phosphorus as P <0.01 <0.01 <0.01 ----mg/L0.0114265-44-2
EN055: Ionic Balance
82.2ø 71.8 67.1 84.8 ----meq/L0.01----Total Anions
73.1ø 67.4 64.6 73.1 ----meq/L0.01----Total Cations
5.86ø 3.15 1.92 7.40 ----%0.01----Ionic Balance
EP005: Total Organic Carbon (TOC)
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Analytical ResultsRB1 - 56716 : 5QAQC1 - 56716 : 4MW6 - 56716 : 3MW5 - 56716 : 2MW4 - 56716 :1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
13-May-2020 15:3013-May-2020 10:3013-May-2020 15:2013-May-2020 13:3013-May-2020 10:30Client sampling date / time
EM2008003-005EM2008003-004EM2008003-003EM2008003-002EM2008003-001UnitLORCAS NumberCompoundResult Result Result Result Result
EP005: Total Organic Carbon (TOC) - Continued
<5 <5 <5 <5 ----mg/L1----Total Organic Carbon
EP006 Total Inorganic Carbon
125 129 130 127 ----mg/L1----Total Inorganic Carbon
EP007 Total Carbon
122Total Carbon 133 133 125 ----mg/L1TC
EP080/071: Total Petroleum Hydrocarbons
---- ---- ---- ---- <20µg/L20----C6 - C9 Fraction
---- ---- ---- ---- <50µg/L50----C10 - C14 Fraction
---- ---- ---- ---- <100µg/L100----C15 - C28 Fraction
---- ---- ---- ---- <50µg/L50----C29 - C36 Fraction
----^ ---- ---- ---- <50µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
----C6 - C10 Fraction ---- ---- ---- <20µg/L20C6_C10----^ C6 - C10 Fraction minus BTEX
(F1)
---- ---- ---- <20µg/L20C6_C10-BTEX
---- ---- ---- ---- <100µg/L100---->C10 - C16 Fraction
---- ---- ---- ---- <100µg/L100---->C16 - C34 Fraction
---- ---- ---- ---- <100µg/L100---->C34 - C40 Fraction
----^ ---- ---- ---- <100µg/L100---->C10 - C40 Fraction (sum)
----^ ---- ---- ---- <100µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN
----Benzene ---- ---- ---- <1µg/L171-43-2----Toluene ---- ---- ---- <2µg/L2108-88-3----Ethylbenzene ---- ---- ---- <2µg/L2100-41-4----meta- & para-Xylene ---- ---- ---- <2µg/L2108-38-3 106-42-3----ortho-Xylene ---- ---- ---- <2µg/L295-47-6----^ ---- ---- ---- <2µg/L2----Total Xylenes
----^ ---- ---- ---- <1µg/L1----Sum of BTEX
----Naphthalene ---- ---- ---- <5µg/L591-20-3
MM527: Legionella in Water
<10Legionella Total <10 <10 <10 ----cfu/ml10LEGIONELLA_TOT<10 <10 <10 <10 ----cfu/ml10----Legionella pneumophila <10 <10 <10 <10 ----cfu/ml10----Legionella Species
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Analytical ResultsRB1 - 56716 : 5QAQC1 - 56716 : 4MW6 - 56716 : 3MW5 - 56716 : 2MW4 - 56716 :1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
13-May-2020 15:3013-May-2020 10:3013-May-2020 15:2013-May-2020 13:3013-May-2020 10:30Client sampling date / time
EM2008003-005EM2008003-004EM2008003-003EM2008003-002EM2008003-001UnitLORCAS NumberCompoundResult Result Result Result Result
MM625: Salmonella - VIDAS (absence / presence)
Not Detected Not Detected Not Detected Not Detected -----1----Salmonella spp.
MM696: E. coli & Faecal Coliforms by MF (Chromogenic)
<10 <10 <10 <10 ----CFU/100mL1----Escherichia coli <10 <10 <10 <10 ----CFU/100mL1----Faecal Coliforms
MM698: Total Coliforms and E. coli by MF (Chromogenic)
1300 48 18 1400 ----CFU/100mL1----Total Coliforms by MF
EP080S: TPH(V)/BTEX Surrogates
----1.2-Dichloroethane-D4 ---- ---- ---- 98.6%217060-07-0----Toluene-D8 ---- ---- ---- 101%22037-26-5----4-Bromofluorobenzene ---- ---- ---- 104%2460-00-4
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Analytical Results----------------TB1 - 56716 : 6Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------13-May-2020 00:00Client sampling date / time
--------------------------------EM2008003-006UnitLORCAS NumberCompoundResult ---- ---- ---- ----
EP074A: Monocyclic Aromatic Hydrocarbons
<5Styrene ---- ---- ---- ----µg/L5100-42-5<5Isopropylbenzene ---- ---- ---- ----µg/L598-82-8<5n-Propylbenzene ---- ---- ---- ----µg/L5103-65-1<51.3.5-Trimethylbenzene ---- ---- ---- ----µg/L5108-67-8<5sec-Butylbenzene ---- ---- ---- ----µg/L5135-98-8<51.2.4-Trimethylbenzene ---- ---- ---- ----µg/L595-63-6<5tert-Butylbenzene ---- ---- ---- ----µg/L598-06-6<5p-Isopropyltoluene ---- ---- ---- ----µg/L599-87-6<5n-Butylbenzene ---- ---- ---- ----µg/L5104-51-8
EP074B: Oxygenated Compounds
<50Vinyl Acetate ---- ---- ---- ----µg/L50108-05-4<502-Butanone (MEK) ---- ---- ---- ----µg/L5078-93-3<504-Methyl-2-pentanone (MIBK) ---- ---- ---- ----µg/L50108-10-1<502-Hexanone (MBK) ---- ---- ---- ----µg/L50591-78-6
EP074C: Sulfonated Compounds
<5Carbon disulfide ---- ---- ---- ----µg/L575-15-0
EP074D: Fumigants
<52.2-Dichloropropane ---- ---- ---- ----µg/L5594-20-7<51.2-Dichloropropane ---- ---- ---- ----µg/L578-87-5<5cis-1.3-Dichloropropylene ---- ---- ---- ----µg/L510061-01-5<5trans-1.3-Dichloropropylene ---- ---- ---- ----µg/L510061-02-6<51.2-Dibromoethane (EDB) ---- ---- ---- ----µg/L5106-93-4
EP074E: Halogenated Aliphatic Compounds
<50Dichlorodifluoromethane ---- ---- ---- ----µg/L5075-71-8<50Chloromethane ---- ---- ---- ----µg/L5074-87-3<50Vinyl chloride ---- ---- ---- ----µg/L5075-01-4<50Bromomethane ---- ---- ---- ----µg/L5074-83-9<50Chloroethane ---- ---- ---- ----µg/L5075-00-3<50Trichlorofluoromethane ---- ---- ---- ----µg/L5075-69-4<51.1-Dichloroethene ---- ---- ---- ----µg/L575-35-4<5Iodomethane ---- ---- ---- ----µg/L574-88-4<5trans-1.2-Dichloroethene ---- ---- ---- ----µg/L5156-60-5<51.1-Dichloroethane ---- ---- ---- ----µg/L575-34-3<5cis-1.2-Dichloroethene ---- ---- ---- ----µg/L5156-59-2
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Analytical Results----------------TB1 - 56716 : 6Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------13-May-2020 00:00Client sampling date / time
--------------------------------EM2008003-006UnitLORCAS NumberCompoundResult ---- ---- ---- ----
EP074E: Halogenated Aliphatic Compounds - Continued
<51.1.1-Trichloroethane ---- ---- ---- ----µg/L571-55-6<51.1-Dichloropropylene ---- ---- ---- ----µg/L5563-58-6<5Carbon Tetrachloride ---- ---- ---- ----µg/L556-23-5<51.2-Dichloroethane ---- ---- ---- ----µg/L5107-06-2<5Trichloroethene ---- ---- ---- ----µg/L579-01-6<5Dibromomethane ---- ---- ---- ----µg/L574-95-3<51.1.2-Trichloroethane ---- ---- ---- ----µg/L579-00-5<51.3-Dichloropropane ---- ---- ---- ----µg/L5142-28-9<5Tetrachloroethene ---- ---- ---- ----µg/L5127-18-4<51.1.1.2-Tetrachloroethane ---- ---- ---- ----µg/L5630-20-6<5trans-1.4-Dichloro-2-butene ---- ---- ---- ----µg/L5110-57-6<5cis-1.4-Dichloro-2-butene ---- ---- ---- ----µg/L51476-11-5<51.1.2.2-Tetrachloroethane ---- ---- ---- ----µg/L579-34-5<51.2.3-Trichloropropane ---- ---- ---- ----µg/L596-18-4<5Pentachloroethane ---- ---- ---- ----µg/L576-01-7<51.2-Dibromo-3-chloropropane ---- ---- ---- ----µg/L596-12-8<5Hexachlorobutadiene ---- ---- ---- ----µg/L587-68-3
EP074F: Halogenated Aromatic Compounds
<5Chlorobenzene ---- ---- ---- ----µg/L5108-90-7<5Bromobenzene ---- ---- ---- ----µg/L5108-86-1<52-Chlorotoluene ---- ---- ---- ----µg/L595-49-8<54-Chlorotoluene ---- ---- ---- ----µg/L5106-43-4<51.3-Dichlorobenzene ---- ---- ---- ----µg/L5541-73-1<51.4-Dichlorobenzene ---- ---- ---- ----µg/L5106-46-7<51.2-Dichlorobenzene ---- ---- ---- ----µg/L595-50-1<51.2.4-Trichlorobenzene ---- ---- ---- ----µg/L5120-82-1<51.2.3-Trichlorobenzene ---- ---- ---- ----µg/L587-61-6
EP074G: Trihalomethanes
<5Chloroform ---- ---- ---- ----µg/L567-66-3<5Bromodichloromethane ---- ---- ---- ----µg/L575-27-4<5Dibromochloromethane ---- ---- ---- ----µg/L5124-48-1<5Bromoform ---- ---- ---- ----µg/L575-25-2
EP080/071: Total Petroleum Hydrocarbons
<20 ---- ---- ---- ----µg/L20----C6 - C9 Fraction
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Analytical Results----------------TB1 - 56716 : 6Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------13-May-2020 00:00Client sampling date / time
--------------------------------EM2008003-006UnitLORCAS NumberCompoundResult ---- ---- ---- ----
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction ---- ---- ---- ----µg/L20C6_C10<20^ C6 - C10 Fraction minus BTEX
(F1)
---- ---- ---- ----µg/L20C6_C10-BTEX
EP080: BTEXN
<1Benzene ---- ---- ---- ----µg/L171-43-2<2Toluene ---- ---- ---- ----µg/L2108-88-3<2Ethylbenzene ---- ---- ---- ----µg/L2100-41-4<2meta- & para-Xylene ---- ---- ---- ----µg/L2108-38-3 106-42-3<2ortho-Xylene ---- ---- ---- ----µg/L295-47-6<2^ ---- ---- ---- ----µg/L2----Total Xylenes
<1^ ---- ---- ---- ----µg/L1----Sum of BTEX
<5Naphthalene ---- ---- ---- ----µg/L591-20-3
EP074S: VOC Surrogates
97.71.2-Dichloroethane-D4 ---- ---- ---- ----%517060-07-0102Toluene-D8 ---- ---- ---- ----%52037-26-51054-Bromofluorobenzene ---- ---- ---- ----%5460-00-4
EP080S: TPH(V)/BTEX Surrogates
97.71.2-Dichloroethane-D4 ---- ---- ---- ----%217060-07-0102Toluene-D8 ---- ---- ---- ----%22037-26-51054-Bromofluorobenzene ---- ---- ---- ----%2460-00-4
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Surrogate Control LimitsRecovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP074S: VOC Surrogates
1.2-Dichloroethane-D4 17060-07-0 72 132Toluene-D8 2037-26-5 77 1324-Bromofluorobenzene 460-00-4 67 131
EP080S: TPH(V)/BTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 73 129Toluene-D8 2037-26-5 70 1254-Bromofluorobenzene 460-00-4 71 129
False
4 4.00True
Environmental
QUALITY CONTROL REPORTWork Order : EM2008003 Page : 1 of 15
:: LaboratoryClient Environmental Division MelbourneSESL Australia Pty Ltd:Contact STEPHEN COX :Contact Customer Services EM:Address LEVEL 1, 21 SHIELDS ST
FLEMINGTON VIC 3031Address : 4 Westall Rd Springvale VIC Australia 3171
::Telephone ---- +61-3-8549 9600:Telephone
:Project GWME J002546 Date Samples Received : 14-May-2020:Order number J002546 Date Analysis Commenced : 14-May-2020
:C-O-C number ---- Issue Date : 22-May-2020Sampler : STEPHEN COXSite : ----Quote number : SYBQ/404/18No. of samples received 6:No. of samples analysed 6:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limitsl Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limitsl Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.Signatories Accreditation CategoryPosition
Arenie Vijayaratnam Non-Metals Team Leader Melbourne Inorganics, Springvale, VICDilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VICNancy Wang 2IC Organic Chemist Melbourne Organics, Springvale, VICSamantha Smith Laboratory Coordinator WRG Subcontracting, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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General CommentsThe analytical procedures used by ALS have been developed from established internationally recognised procedures such as those published by the USEPA, APHA, AS and NEPM. In house developed procedures are fully validated and are often at the client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lotCAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society. LOR = Limit of reporting RPD = Relative Percentage Difference# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) ReportThe quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR: No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA005P: pH by PC Titrator (QC Lot: 3020838)EA005-P: pH Value ---- 0.01 pH Unit 6.20 5.86 5.62 0% - 20%Anonymous EM2007967-004
EA005-P: pH Value ---- 0.01 pH Unit 7.98 8.07 1.12 0% - 20%Anonymous EM2008006-007
EA010P: Conductivity by PC Titrator (QC Lot: 3020837)EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm 2220 2220 0.00 0% - 20%Anonymous EM2007946-008
EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm 548 548 0.00 0% - 20%Anonymous EM2007967-004
ED037P: Alkalinity by PC Titrator (QC Lot: 3020839)ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM2007967-004
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 1 <1 0.00 No Limit
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 1 <1 0.00 No Limit
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM2008006-007
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 244 246 0.441 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 244 246 0.441 0% - 20%
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QC Lot: 3019430)ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 130 131 0.00 0% - 20%Anonymous EM2007949-002
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 268 268 0.00 0% - 20%Anonymous EM2007920-001
ED045G: Chloride by Discrete Analyser (QC Lot: 3019431)ED045G: Chloride 16887-00-6 1 mg/L 465 464 0.396 0% - 20%Anonymous EM2007920-001
ED045G: Chloride 16887-00-6 1 mg/L 162 161 0.00 0% - 20%Anonymous EM2007931-001
ED093F: Dissolved Major Cations (QC Lot: 3019602)ED093F: Calcium 7440-70-2 1 mg/L 547 566 3.26 0% - 20%Anonymous EM2007941-002
ED093F: Magnesium 7439-95-4 1 mg/L 2470 2550 3.13 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 22700 23500 3.39 0% - 20%
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
ED093F: Dissolved Major Cations (QC Lot: 3019602) - continuedED093F: Potassium 7440-09-7 1 mg/L 178 180 1.12 0% - 50%Anonymous EM2007941-002
ED093F: Calcium 7440-70-2 1 mg/L 72 71 2.03 0% - 20%MW5 - 56716 : 2 EM2008003-002
ED093F: Magnesium 7439-95-4 1 mg/L 144 142 1.72 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 1190 1170 1.64 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 9 9 0.00 No Limit
EG020F: Dissolved Metals by ICP-MS (QC Lot: 3019600)EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM2007949-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.003 0.003 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.011 0.011 0.00 0% - 50%
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.009 0.008 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.062 0.057 8.44 0% - 50%
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.004 0.004 0.00 No LimitAnonymous EM2007931-001
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.010 0.010 0.00 0% - 50%
EG020T: Total Metals by ICP-MS (QC Lot: 3021041)EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM2007845-001
EG020A-T: Arsenic 7440-38-2 0.001 mg/L 0.003 0.003 0.00 No Limit
EG020A-T: Chromium 7440-47-3 0.001 mg/L 0.004 0.004 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-T: Zinc 7440-66-6 0.005 mg/L 0.032 0.033 3.96 No Limit
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0010 0.0012 18.1 No LimitAnonymous EM2008025-003
EG020A-T: Arsenic 7440-38-2 0.001 mg/L 63.2 64.2 1.53 0% - 20%
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.010 <0.010 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L 6.98 7.55 7.84 0% - 20%
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.010 <0.010 0.00 No Limit
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.294 0.324 9.75 0% - 20%
EG020A-T: Zinc 7440-66-6 0.005 mg/L 1.81 1.92 5.94 0% - 20%
EG035F: Dissolved Mercury by FIMS (QC Lot: 3019599)EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM2007949-001
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM2007931-001
EG035T: Total Recoverable Mercury by FIMS (QC Lot: 3020431)EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM2007845-001
EK040P: Fluoride by PC Titrator (QC Lot: 3020834)EK040P: Fluoride 16984-48-8 0.1 mg/L 0.8 0.8 0.00 No LimitAnonymous EM2007931-001
EK040P: Fluoride by PC Titrator (QC Lot: 3020840)
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EK040P: Fluoride by PC Titrator (QC Lot: 3020840) - continuedEK040P: Fluoride 16984-48-8 0.1 mg/L 0.2 0.2 0.00 No LimitAnonymous EM2008008-001
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 3022004)EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.02 0.02 0.00 No LimitAnonymous EM2007946-001
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.17 0.19 11.8 0% - 50%Anonymous EM2007946-010
EK057G: Nitrite as N by Discrete Analyser (QC Lot: 3019432)EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.03 0.03 0.00 No LimitMW6 - 56716 : 3 EM2008003-003
EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.07 0.07 0.00 No LimitAnonymous EM2007931-001
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 3022003)EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 16.9 17.0 0.665 0% - 20%Anonymous EM2007913-002
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EM2007946-003
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 3022005)EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.42 0.42 0.00 0% - 20%QAQC1 - 56716 : 4 EM2008003-004
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EM2008010-005
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 3022903)EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.2 0.2 0.00 No LimitMW4 - 56716 :1 EM2008003-001
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.1 0.2 0.00 No LimitAnonymous EM2008012-003
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 3022904)EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 <0.01 0.00 No LimitMW4 - 56716 :1 EM2008003-001
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.02 0.02 0.00 No LimitAnonymous EM2008012-003
EK071G: Reactive Phosphorus as P by discrete analyser (QC Lot: 3019434)EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 <0.01 0.00 No LimitMW4 - 56716 :1 EM2008003-001
EP005: Total Organic Carbon (TOC) (QC Lot: 3029914)EP005: Total Organic Carbon ---- 1 mg/L <5 <5 0.00 No LimitMW4 - 56716 :1 EM2008003-001
EP006 Total Inorganic Carbon (QC Lot: 3029073)EP006: Total Inorganic Carbon ---- 1 mg/L 125 126 0.874 0% - 20%MW4 - 56716 :1 EM2008003-001
EP007 Total Carbon (QC Lot: 3029072)EP007: Total Carbon TC 1 mg/L 122 124 1.42 0% - 20%MW4 - 56716 :1 EM2008003-001
EP074A: Monocyclic Aromatic Hydrocarbons (QC Lot: 3020494)EP074: Styrene 100-42-5 5 µg/L <5 <5 0.00 No LimitAnonymous EM2008012-003
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 <5 0.00 No Limit
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 <5 0.00 No Limit
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 <5 0.00 No Limit
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 <5 0.00 No Limit
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 <5 0.00 No Limit
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 <5 0.00 No Limit
EP074: Styrene 100-42-5 5 µg/L <5 <5 0.00 No LimitAnonymous EM2007931-001
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074A: Monocyclic Aromatic Hydrocarbons (QC Lot: 3020494) - continuedEP074: Isopropylbenzene 98-82-8 5 µg/L <5 <5 0.00 No LimitAnonymous EM2007931-001
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 <5 0.00 No Limit
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 <5 0.00 No Limit
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 <5 0.00 No Limit
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 <5 0.00 No Limit
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 <5 0.00 No Limit
EP074B: Oxygenated Compounds (QC Lot: 3020494)EP074: Vinyl Acetate 108-05-4 50 µg/L <50 <50 0.00 No LimitAnonymous EM2008012-003
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 <50 0.00 No Limit
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 <50 0.00 No Limit
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl Acetate 108-05-4 50 µg/L <50 <50 0.00 No LimitAnonymous EM2007931-001
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 <50 0.00 No Limit
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 <50 0.00 No Limit
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 <50 0.00 No Limit
EP074C: Sulfonated Compounds (QC Lot: 3020494)EP074: Carbon disulfide 75-15-0 5 µg/L <5 <5 0.00 No LimitAnonymous EM2008012-003
EP074: Carbon disulfide 75-15-0 5 µg/L <5 <5 0.00 No LimitAnonymous EM2007931-001
EP074D: Fumigants (QC Lot: 3020494)EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM2008012-003
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 <5 0.00 No Limit
EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM2007931-001
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 <5 0.00 No Limit
EP074E: Halogenated Aliphatic Compounds (QC Lot: 3020494)EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 <5 0.00 No LimitAnonymous EM2008012-003
EP074: Iodomethane 74-88-4 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 <5 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074E: Halogenated Aliphatic Compounds (QC Lot: 3020494) - continuedEP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 <5 0.00 No LimitAnonymous EM2008012-003
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 <5 0.00 No Limit
EP074: Trichloroethene 79-01-6 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromomethane 74-95-3 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 <5 0.00 No Limit
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: Pentachloroethane 76-01-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 <5 0.00 No Limit
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 <5 0.00 No Limit
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 <50 0.00 No Limit
EP074: Chloromethane 74-87-3 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl chloride 75-01-4 50 µg/L <50 <50 0.00 No Limit
EP074: Bromomethane 74-83-9 50 µg/L <50 <50 0.00 No Limit
EP074: Chloroethane 75-00-3 50 µg/L <50 <50 0.00 No Limit
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 <50 0.00 No Limit
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 <5 0.00 No LimitAnonymous EM2007931-001
EP074: Iodomethane 74-88-4 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 <5 0.00 No Limit
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 <5 0.00 No Limit
EP074: Trichloroethene 79-01-6 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromomethane 74-95-3 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 <5 0.00 No Limit
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 <5 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074E: Halogenated Aliphatic Compounds (QC Lot: 3020494) - continuedEP074: Pentachloroethane 76-01-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM2007931-001
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 <5 0.00 No Limit
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 <5 0.00 No Limit
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 <50 0.00 No Limit
EP074: Chloromethane 74-87-3 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl chloride 75-01-4 50 µg/L <50 <50 0.00 No Limit
EP074: Bromomethane 74-83-9 50 µg/L <50 <50 0.00 No Limit
EP074: Chloroethane 75-00-3 50 µg/L <50 <50 0.00 No Limit
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 <50 0.00 No Limit
EP074F: Halogenated Aromatic Compounds (QC Lot: 3020494)EP074: Chlorobenzene 108-90-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM2008012-003
EP074: Bromobenzene 108-86-1 5 µg/L <5 <5 0.00 No Limit
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 <5 0.00 No Limit
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 <5 0.00 No Limit
EP074: Chlorobenzene 108-90-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM2007931-001
EP074: Bromobenzene 108-86-1 5 µg/L <5 <5 0.00 No Limit
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 <5 0.00 No Limit
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 <5 0.00 No Limit
EP074G: Trihalomethanes (QC Lot: 3020494)EP074: Chloroform 67-66-3 5 µg/L <5 <5 0.00 No LimitAnonymous EM2008012-003
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 <5 0.00 No Limit
EP074: Bromoform 75-25-2 5 µg/L <5 <5 0.00 No Limit
EP074: Chloroform 67-66-3 5 µg/L <5 <5 0.00 No LimitAnonymous EM2007931-001
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 <5 0.00 No Limit
EP074: Bromoform 75-25-2 5 µg/L <5 <5 0.00 No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 3019779)EP071: C15 - C28 Fraction ---- 100 µg/L <100 <100 0.00 No LimitAnonymous EM2007949-001
EP071: C10 - C14 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 3019779) - continuedEP071: C29 - C36 Fraction ---- 50 µg/L <50 <50 0.00 No LimitAnonymous EM2007949-001
EP071: C15 - C28 Fraction ---- 100 µg/L <100 <100 0.00 No LimitAnonymous EM2007949-002
EP071: C10 - C14 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
EP071: C29 - C36 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 3020493)EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EM2008012-003
EP080: C6 - C9 Fraction ---- 20 µg/L 30 30 0.00 No LimitAnonymous EM2007931-001
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 3019779)EP071: >C10 - C16 Fraction ---- 100 µg/L <100 <100 0.00 No LimitAnonymous EM2007949-001
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 <100 0.00 No LimitAnonymous EM2007949-002
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 3020493)EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EM2008012-003
EP080: C6 - C10 Fraction C6_C10 20 µg/L 30 40 0.00 No LimitAnonymous EM2007931-001
EP080: BTEXN (QC Lot: 3020493)EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EM2008012-003
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3 106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EM2007931-001
EP080: Toluene 108-88-3 2 µg/L 11 11 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3 106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
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Method Blank (MB) and Laboratory Control Spike (LCS) ReportThe quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA010P: Conductivity by PC Titrator (QCLot: 3020837)EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm <1 1001412 µS/cm 11985.0
ED037P: Alkalinity by PC Titrator (QCLot: 3020839)ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 91.1200 mg/L 11288.0
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 3019430)ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 10425 mg/L 11785.8
<1 98.6100 mg/L 11785.8
ED045G: Chloride by Discrete Analyser (QCLot: 3019431)ED045G: Chloride 16887-00-6 1 mg/L <1 10010 mg/L 12285.0
<1 1021000 mg/L 12285.0
ED093F: Dissolved Major Cations (QCLot: 3019602)ED093F: Calcium 7440-70-2 1 mg/L <1 1125 mg/L 11788.2
ED093F: Magnesium 7439-95-4 1 mg/L <1 1075 mg/L 11485.6
ED093F: Sodium 7440-23-5 1 mg/L <1 11050 mg/L 11490.0
ED093F: Potassium 7440-09-7 1 mg/L <1 10850 mg/L 11186.7
EG020F: Dissolved Metals by ICP-MS (QCLot: 3019600)EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 1000.1 mg/L 10888.5
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 98.80.1 mg/L 10883.5
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 95.80.1 mg/L 10583.2
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 96.60.1 mg/L 10683.1
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 99.60.1 mg/L 10784.6
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 98.50.1 mg/L 10884.3
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 97.30.1 mg/L 11186.3
EG020T: Total Metals by ICP-MS (QCLot: 3021041)EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 1050.1 mg/L 11389.2
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 1010.1 mg/L 11286.4
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 1020.1 mg/L 11086.9
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 98.60.1 mg/L 10986.9
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 1020.1 mg/L 11088.3
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 98.60.1 mg/L 11187.9
EG020A-T: Zinc 7440-66-6 0.005 mg/L <0.005 1070.1 mg/L 11486.7
EG035F: Dissolved Mercury by FIMS (QCLot: 3019599)EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 89.30.01 mg/L 11271.1
EG035T: Total Recoverable Mercury by FIMS (QCLot: 3020431)
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EG035T: Total Recoverable Mercury by FIMS (QCLot: 3020431) - continuedEG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 83.30.01 mg/L 11572.6
EK040P: Fluoride by PC Titrator (QCLot: 3020834)EK040P: Fluoride 16984-48-8 0.1 mg/L <0.1 95.05 mg/L 12284.3
EK040P: Fluoride by PC Titrator (QCLot: 3020840)EK040P: Fluoride 16984-48-8 0.1 mg/L <0.1 1015 mg/L 12284.3
EK055G: Ammonia as N by Discrete Analyser (QCLot: 3022004)EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 92.41 mg/L 11688.0
EK057G: Nitrite as N by Discrete Analyser (QCLot: 3019432)EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 1080.5 mg/L 11290.9
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 3022003)EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1100.5 mg/L 11790.0
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 3022005)EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1100.5 mg/L 11790.0
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 3022903)EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 88.65 mg/L 11770.0
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 3022904)EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 81.82.21 mg/L 11471.9
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 3019434)EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 1120.5 mg/L 11992.7
EP005: Total Organic Carbon (TOC) (QCLot: 3029914)EP005: Total Organic Carbon ---- 1 mg/L <1 90.2100 mg/L 10981.2
EP006 Total Inorganic Carbon (QCLot: 3029073)EP006: Total Inorganic Carbon ---- 1 mg/L <1 91.2100 mg/L 12080.0
EP007 Total Carbon (QCLot: 3029072)EP007: Total Carbon TC 1 mg/L <1 89.9100 mg/L 11581.0
EP074A: Monocyclic Aromatic Hydrocarbons (QCLot: 3020494)EP074: Styrene 100-42-5 5 µg/L <5 10520 µg/L 11780.4
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 11020 µg/L 11875.0
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 97.920 µg/L 11468.7
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 96.620 µg/L 11472.1
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 10120 µg/L 11569.6
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 96.120 µg/L 11372.4
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 10120 µg/L 11672.6
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 98.320 µg/L 11569.2
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 95.820 µg/L 11561.4
EP074B: Oxygenated Compounds (QCLot: 3020494)
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP074B: Oxygenated Compounds (QCLot: 3020494) - continuedEP074: Vinyl Acetate 108-05-4 50 µg/L <50 107200 µg/L 12571.3
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 113200 µg/L 13266.4
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 114200 µg/L 13275.2
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 121200 µg/L 13173.9
EP074C: Sulfonated Compounds (QCLot: 3020494)EP074: Carbon disulfide 75-15-0 5 µg/L <5 95.020 µg/L 12458.2
EP074D: Fumigants (QCLot: 3020494)EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 10920 µg/L 12068.7
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 99.620 µg/L 11679.6
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 98.520 µg/L 11476.2
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 10120 µg/L 11477.0
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 10620 µg/L 11880.1
EP074E: Halogenated Aliphatic Compounds (QCLot: 3020494)EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 116200 µg/L 14053.4
EP074: Chloromethane 74-87-3 50 µg/L <50 104200 µg/L 13463.8
EP074: Vinyl chloride 75-01-4 50 µg/L <50 102200 µg/L 13557.1
EP074: Bromomethane 74-83-9 50 µg/L <50 88.2200 µg/L 12651.1
EP074: Chloroethane 75-00-3 50 µg/L <50 110200 µg/L 12964.9
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 115200 µg/L 12765.7
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 10920 µg/L 12367.4
EP074: Iodomethane 74-88-4 5 µg/L <5 62.820 µg/L 12630.9
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 10120 µg/L 11969.2
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 10420 µg/L 12076.7
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 10120 µg/L 11878.9
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 10620 µg/L 12069.2
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 10320 µg/L 12067.0
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 10520 µg/L 12063.7
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 10420 µg/L 11682.0
EP074: Trichloroethene 79-01-6 5 µg/L <5 10220 µg/L 11872.9
EP074: Dibromomethane 74-95-3 5 µg/L <5 10220 µg/L 11681.0
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 10820 µg/L 11884.9
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 10320 µg/L 11983.4
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 10920 µg/L 11870.4
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 10320 µg/L 11377.9
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 11620 µg/L 12272.6
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 11020 µg/L 11967.8
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 11620 µg/L 12583.0
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 11420 µg/L 12382.4
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Sub-Matrix: WATER Method Blank (MB) Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP074E: Halogenated Aliphatic Compounds (QCLot: 3020494) - continuedEP074: Pentachloroethane 76-01-7 5 µg/L <5 93.020 µg/L 11172.7
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 11120 µg/L 11475.4
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 10120 µg/L 12862.6
EP074F: Halogenated Aromatic Compounds (QCLot: 3020494)EP074: Chlorobenzene 108-90-7 5 µg/L <5 10520 µg/L 11681.7
EP074: Bromobenzene 108-86-1 5 µg/L <5 99.620 µg/L 11875.2
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 10120 µg/L 11475.0
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 95.520 µg/L 11372.8
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 96.420 µg/L 11674.7
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 10220 µg/L 11975.5
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 10020 µg/L 11382.0
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 96.820 µg/L 12364.0
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 99.520 µg/L 11975.5
EP074G: Trihalomethanes (QCLot: 3020494)EP074: Chloroform 67-66-3 5 µg/L <5 10320 µg/L 11880.4
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 10020 µg/L 11578.6
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 10320 µg/L 11377.7
EP074: Bromoform 75-25-2 5 µg/L <5 10620 µg/L 11374.2
EP080/071: Total Petroleum Hydrocarbons (QCLot: 3019779)EP071: C10 - C14 Fraction ---- 50 µg/L <50 99.93330 µg/L 12544.8
EP071: C15 - C28 Fraction ---- 100 µg/L <100 88.916500 µg/L 13551.3
EP071: C29 - C36 Fraction ---- 50 µg/L <50 89.97800 µg/L 13449.4
EP080/071: Total Petroleum Hydrocarbons (QCLot: 3020493)EP080: C6 - C9 Fraction ---- 20 µg/L <20 104360 µg/L 12965.5
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 3019779)EP071: >C10 - C16 Fraction ---- 100 µg/L <100 90.65690 µg/L 12947.3
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 91.020700 µg/L 13350.4
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 97.01510 µg/L 13645.2
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 3020493)EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 101450 µg/L 12664.3
EP080: BTEXN (QCLot: 3020493)EP080: Benzene 71-43-2 1 µg/L <1 97.820 µg/L 12469.8
EP080: Toluene 108-88-3 2 µg/L <2 10420 µg/L 12673.6
EP080: Ethylbenzene 100-41-4 2 µg/L <2 10320 µg/L 12672.0
EP080: meta- & para-Xylene 108-38-3 106-42-3
2 µg/L <2 10440 µg/L 13271.5
EP080: ortho-Xylene 95-47-6 2 µg/L <2 10420 µg/L 13276.5
EP080: Naphthalene 91-20-3 5 µg/L <5 1145 µg/L 12770.5
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Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 3019430)Anonymous EM2007920-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric 75.7100 mg/L 13070.0
ED045G: Chloride by Discrete Analyser (QCLot: 3019431)Anonymous EM2007920-002 16887-00-6ED045G: Chloride 87.7400 mg/L 13070.0
EG020F: Dissolved Metals by ICP-MS (QCLot: 3019600)Anonymous EM2007931-001 7440-38-2EG020A-F: Arsenic 1000.2 mg/L 13185.0
7440-43-9EG020A-F: Cadmium 1050.05 mg/L 13381.07440-47-3EG020A-F: Chromium 83.90.2 mg/L 13571.07440-50-8EG020A-F: Copper 84.40.2 mg/L 13076.07439-92-1EG020A-F: Lead # 62.30.2 mg/L 13375.07440-02-0EG020A-F: Nickel 90.90.2 mg/L 13173.07440-66-6EG020A-F: Zinc 99.30.2 mg/L 13175.0
EG020T: Total Metals by ICP-MS (QCLot: 3021041)Anonymous EM2007845-001 7440-38-2EG020A-T: Arsenic 1121 mg/L 11882.0
7440-43-9EG020A-T: Cadmium 1080.25 mg/L 12975.07440-47-3EG020A-T: Chromium 1011 mg/L 11880.07440-50-8EG020A-T: Copper 1031 mg/L 11581.07439-92-1EG020A-T: Lead 1021 mg/L 12183.07440-02-0EG020A-T: Nickel 1081 mg/L 11880.07440-66-6EG020A-T: Zinc 1101 mg/L 11674.0
EG035F: Dissolved Mercury by FIMS (QCLot: 3019599)Anonymous EM2007935-001 7439-97-6EG035F: Mercury 83.30.01 mg/L 12070.0
EG035T: Total Recoverable Mercury by FIMS (QCLot: 3020431)Anonymous EM2007940-010 7439-97-6EG035T: Mercury 85.10.01 mg/L 13070.0
EK040P: Fluoride by PC Titrator (QCLot: 3020834)Anonymous EM2007925-004 16984-48-8EK040P: Fluoride 99.05 mg/L 13070.0
EK040P: Fluoride by PC Titrator (QCLot: 3020840)Anonymous EM2008061-001 16984-48-8EK040P: Fluoride 1055 mg/L 13070.0
EK055G: Ammonia as N by Discrete Analyser (QCLot: 3022004)Anonymous EM2007946-002 7664-41-7EK055G: Ammonia as N 75.71 mg/L 13070.0
EK057G: Nitrite as N by Discrete Analyser (QCLot: 3019432)Anonymous EM2007949-001 14797-65-0EK057G: Nitrite as N 97.60.5 mg/L 11480.0
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 3022003)Anonymous EM2007926-003 ----EK059G: Nitrite + Nitrate as N 97.30.5 mg/L 13070.0
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 3022005)Anonymous EM2008004-001 ----EK059G: Nitrite + Nitrate as N # Not
Determined0.5 mg/L 13070.0
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 3022903)MW5 - 56716 : 2 EM2008003-002 ----EK061G: Total Kjeldahl Nitrogen as N 85.25 mg/L 13070.0
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 3022904)MW5 - 56716 : 2 EM2008003-002 ----EK067G: Total Phosphorus as P 82.51 mg/L 13070.0
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 3019434)MW5 - 56716 : 2 EM2008003-002 14265-44-2EK071G: Reactive Phosphorus as P 1040.5 mg/L 12379.0
EP005: Total Organic Carbon (TOC) (QCLot: 3029914)MW5 - 56716 : 2 EM2008003-002 ----EP005: Total Organic Carbon 86.4500 mg/L 11480.0
EP006 Total Inorganic Carbon (QCLot: 3029073)MW5 - 56716 : 2 EM2008003-002 ----EP006: Total Inorganic Carbon 121250 mg/L 13070.0
EP007 Total Carbon (QCLot: 3029072)MW5 - 56716 : 2 EM2008003-002 TCEP007: Total Carbon 81.7500 mg/L 13070.0
EP074E: Halogenated Aliphatic Compounds (QCLot: 3020494)TB1 - 56716 : 6 EM2008003-006 75-35-4EP074: 1.1-Dichloroethene 10520 µg/L 12440.0
79-01-6EP074: Trichloroethene 94.820 µg/L 12654.0
EP074F: Halogenated Aromatic Compounds (QCLot: 3020494)TB1 - 56716 : 6 EM2008003-006 108-90-7EP074: Chlorobenzene 10220 µg/L 13268.0
EP080/071: Total Petroleum Hydrocarbons (QCLot: 3019779)Anonymous EM2007949-001 ----EP071: C10 - C14 Fraction 1043330 µg/L 13050.0
----EP071: C15 - C28 Fraction 95.416500 µg/L 13654.0----EP071: C29 - C36 Fraction 96.27800 µg/L 14250.0
EP080/071: Total Petroleum Hydrocarbons (QCLot: 3020493)TB1 - 56716 : 6 EM2008003-006 ----EP080: C6 - C9 Fraction 75.0280 µg/L 12543.0
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 3019779)Anonymous EM2007949-001 ----EP071: >C10 - C16 Fraction 95.25690 µg/L 12850.0
----EP071: >C16 - C34 Fraction 97.720700 µg/L 15050.0----EP071: >C34 - C40 Fraction 1001510 µg/L 15951.0
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 3020493)TB1 - 56716 : 6 EM2008003-006 C6_C10EP080: C6 - C10 Fraction 69.9330 µg/L 12244.0
EP080: BTEXN (QCLot: 3020493)
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EP080: BTEXN (QCLot: 3020493) - continuedTB1 - 56716 : 6 EM2008003-006 71-43-2EP080: Benzene 95.420 µg/L 13068.0
108-88-3EP080: Toluene 96.420 µg/L 13272.0
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EM2008003 Page : 1 of 12
:: LaboratoryClient Environmental Division MelbourneSESL Australia Pty Ltd:Contact STEPHEN COX Telephone : +61-3-8549 9600:Project GWME J002546 Date Samples Received : 14-May-2020
Site : ---- Issue Date : 22-May-2020STEPHEN COX:Sampler No. of samples received : 6
:Order number J002546 No. of samples analysed : 6
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this report contribute to the overall DQO assessment and reporting for guideline compliance. Brief method summaries and references are also provided to assist in traceability.
Summary of OutliersOutliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.l NO Duplicate outliers occur.l NO Laboratory Control outliers occur.l Matrix Spike outliers exist - please see following pages for full details.l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliancel Analysis Holding Time Outliers exist - please see following pages for full details.
Outliers : Frequency of Quality Control Samplesl Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Quality Control SamplesDuplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATERCompound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number
Matrix Spike (MS) Recoveries EM2007931--001 7439-92-1LeadAnonymous Recovery less than lower data quality
objective75.0-133%62.3 %EG020F: Dissolved Metals by ICP-MS
EM2008004--001 ----Nitrite + Nitrate as NAnonymous MS recovery not determined, background level greater than or equal to 4x spike level.
----Not Determined
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
Outliers : Analysis Holding Time ComplianceMatrix: WATER
AnalysisExtraction / PreparationDate analysedDate extractedContainer / Client Sample ID(s) Days
overdueDays
overdueDue for extraction Due for analysis
Method
EA005P: pH by PC TitratorClear Plastic Bottle - Natural
13-May-2020----MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
15-May-2020---- ---- 2
EP005: Total Organic Carbon (TOC)Clear Plastic Bottle - Natural
14-May-2020----MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
20-May-2020---- ---- 6
EP006 Total Inorganic CarbonClear Plastic Bottle - Natural
14-May-2020----MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
19-May-2020---- ---- 5
EP007 Total CarbonClear Plastic Bottle - Natural
14-May-2020----MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
19-May-2020---- ---- 5
Outliers : Frequency of Quality Control SamplesMatrix: WATER
Quality Control SpecificationQuality Control Sample TypeMethod ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP)NEPM 2013 B3 & ALS QC StandardFluoride by PC Titrator 8.70 10.002 23
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Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics 14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA005P: pH by PC TitratorClear Plastic Bottle - Natural (EA005-P)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
13-May-2020---- 15-May-2020----13-May-2020 ---- û
EA006: Sodium Adsorption Ratio (SAR)Clear Plastic Bottle - Nitric Acid; Filtered (ED093F)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-2020---- 19-May-2020----13-May-2020 ---- ü
EA010P: Conductivity by PC TitratorClear Plastic Bottle - Natural (EA010-P)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-2020---- 15-May-2020----13-May-2020 ---- ü
EA065: Total Hardness as CaCO3Clear Plastic Bottle - Nitric Acid; Filtered (ED093F)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-2020---- 19-May-2020----13-May-2020 ---- ü
ED037P: Alkalinity by PC TitratorClear Plastic Bottle - Natural (ED037-P)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
27-May-2020---- 15-May-2020----13-May-2020 ---- ü
ED041G: Sulfate (Turbidimetric) as SO4 2- by DAClear Plastic Bottle - Natural (ED041G)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-2020---- 15-May-2020----13-May-2020 ---- ü
ED045G: Chloride by Discrete AnalyserClear Plastic Bottle - Natural (ED045G)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-2020---- 15-May-2020----13-May-2020 ---- ü
ED093F: Dissolved Major CationsClear Plastic Bottle - Nitric Acid; Filtered (ED093F)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-2020---- 19-May-2020----13-May-2020 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EG020F: Dissolved Metals by ICP-MSClear Plastic Bottle - Nitric Acid; Filtered (EG020A-F)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
09-Nov-2020---- 14-May-2020----13-May-2020 ---- ü
EG020T: Total Metals by ICP-MSClear Plastic Bottle - Nitric Acid; Unfiltered (EG020A-T)
RB1 - 56716 : 5 09-Nov-202009-Nov-2020 15-May-202015-May-202013-May-2020 ü üEG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Nitric Acid; Filtered (EG035F)MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-2020---- 14-May-2020----13-May-2020 ---- ü
EG035T: Total Recoverable Mercury by FIMSClear Plastic Bottle - Nitric Acid; Unfiltered (EG035T)
RB1 - 56716 : 5 10-Jun-2020---- 14-May-2020----13-May-2020 ---- üEK040P: Fluoride by PC Titrator
Clear Plastic Bottle - Natural (EK040P)MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-2020---- 15-May-2020----13-May-2020 ---- ü
EK055G: Ammonia as N by Discrete AnalyserClear Plastic Bottle - Sulfuric Acid (EK055G)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-2020---- 18-May-2020----13-May-2020 ---- ü
EK057G: Nitrite as N by Discrete AnalyserClear Plastic Bottle - Natural (EK057G)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
15-May-2020---- 14-May-2020----13-May-2020 ---- ü
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete AnalyserClear Plastic Bottle - Sulfuric Acid (EK059G)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-2020---- 15-May-2020----13-May-2020 ---- ü
EK061G: Total Kjeldahl Nitrogen By Discrete AnalyserClear Plastic Bottle - Sulfuric Acid (EK061G)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-202010-Jun-2020 18-May-202018-May-202013-May-2020 ü ü
EK067G: Total Phosphorus as P by Discrete AnalyserClear Plastic Bottle - Sulfuric Acid (EK067G)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
10-Jun-202010-Jun-2020 18-May-202018-May-202013-May-2020 ü ü
EK071G: Reactive Phosphorus as P by discrete analyserClear Plastic Bottle - Natural (EK071G)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
15-May-2020---- 14-May-2020----13-May-2020 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP005: Total Organic Carbon (TOC)Clear Plastic Bottle - Natural (EP005)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
14-May-2020---- 20-May-2020----13-May-2020 ---- û
EP006 Total Inorganic CarbonClear Plastic Bottle - Natural (EP006)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
14-May-2020---- 19-May-2020----13-May-2020 ---- û
EP007 Total CarbonClear Plastic Bottle - Natural (EP007)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
14-May-2020---- 19-May-2020----13-May-2020 ---- û
EP074A: Monocyclic Aromatic HydrocarbonsAmber VOC Vial - Sulfuric Acid (EP074)
TB1 - 56716 : 6 27-May-202027-May-2020 15-May-202015-May-202013-May-2020 ü üEP074B: Oxygenated Compounds
Amber VOC Vial - Sulfuric Acid (EP074)TB1 - 56716 : 6 27-May-202027-May-2020 15-May-202015-May-202013-May-2020 ü ü
EP074C: Sulfonated CompoundsAmber VOC Vial - Sulfuric Acid (EP074)
TB1 - 56716 : 6 27-May-202027-May-2020 15-May-202015-May-202013-May-2020 ü üEP074D: Fumigants
Amber VOC Vial - Sulfuric Acid (EP074)TB1 - 56716 : 6 27-May-202027-May-2020 15-May-202015-May-202013-May-2020 ü ü
EP074E: Halogenated Aliphatic CompoundsAmber VOC Vial - Sulfuric Acid (EP074)
TB1 - 56716 : 6 27-May-202027-May-2020 15-May-202015-May-202013-May-2020 ü üEP074F: Halogenated Aromatic Compounds
Amber VOC Vial - Sulfuric Acid (EP074)TB1 - 56716 : 6 27-May-202027-May-2020 15-May-202015-May-202013-May-2020 ü ü
EP074G: TrihalomethanesAmber VOC Vial - Sulfuric Acid (EP074)
TB1 - 56716 : 6 27-May-202027-May-2020 15-May-202015-May-202013-May-2020 ü üEP080/071: Total Petroleum Hydrocarbons
Amber Glass Bottle - Unpreserved (EP071)RB1 - 56716 : 5 23-Jun-202020-May-2020 15-May-202014-May-202013-May-2020 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)RB1 - 56716 : 5, TB1 - 56716 : 6 27-May-202027-May-2020 15-May-202015-May-202013-May-2020 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time. AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 FractionsAmber Glass Bottle - Unpreserved (EP071)
RB1 - 56716 : 5 23-Jun-202020-May-2020 15-May-202014-May-202013-May-2020 ü üAmber VOC Vial - Sulfuric Acid (EP080)
RB1 - 56716 : 5, TB1 - 56716 : 6 27-May-202027-May-2020 15-May-202015-May-202013-May-2020 ü üEP080: BTEXN
Amber VOC Vial - Sulfuric Acid (EP080)RB1 - 56716 : 5, TB1 - 56716 : 6 27-May-202027-May-2020 15-May-202015-May-202013-May-2020 ü ü
MM527: Legionella in WaterSterile Plastic Bottle - Sodium Thiosulfate (MM527)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
15-May-2020---- 14-May-2020----13-May-2020 ---- ü
MM625: Salmonella - VIDAS (absence / presence)Sterile Plastic Bottle - Sodium Thiosulfate (MM625)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
14-May-2020---- 14-May-2020----13-May-2020 ---- ü
MM696: E. coli & Faecal Coliforms by MF (Chromogenic)Sterile Plastic Bottle - Sodium Thiosulfate (MM696)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
14-May-2020---- 14-May-2020----13-May-2020 ---- ü
MM698: Total Coliforms and E. coli by MF (Chromogenic)Sterile Plastic Bottle - Sodium Thiosulfate (MM698)
MW4 - 56716 :1, MW5 - 56716 : 2,MW6 - 56716 : 3, QAQC1 - 56716 : 4
14-May-2020---- 14-May-2020----13-May-2020 ---- ü
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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification. Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
EvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-PNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAmmonia as N by Discrete analyser EK055GNEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üConductivity by PC Titrator EA010-PNEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 8.70 10.002 23 ûFluoride by PC Titrator EK040PNEPM 2013 B3 & ALS QC Standard 15.38 10.002 13 üMajor Cations - Dissolved ED093FNEPM 2013 B3 & ALS QC Standard 11.43 10.004 35 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059GNEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üNitrite as N by Discrete Analyser EK057GNEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üpH by PC Titrator EA005-PNEPM 2013 B3 & ALS QC Standard 25.00 10.001 4 üReactive Phosphorus as P-By Discrete Analyser EK071GNEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 25.00 10.001 4 üTotal Carbon EP007NEPM 2013 B3 & ALS QC Standard 25.00 10.001 4 üTotal Inorganic Carbon EP006NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061GNEPM 2013 B3 & ALS QC Standard 14.29 10.001 7 üTotal Mercury by FIMS EG035TNEPM 2013 B3 & ALS QC Standard 11.11 10.002 18 üTotal Metals by ICP-MS - Suite A EG020A-TNEPM 2013 B3 & ALS QC Standard 20.00 10.001 5 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Phosphorus as P By Discrete Analyser EK067GNEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üVolatile Organic Compounds EP074
Laboratory Control Samples (LCS)NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAlkalinity by PC Titrator ED037-PNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055GNEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üConductivity by PC Titrator EA010-PNEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 8.70 5.002 23 üFluoride by PC Titrator EK040PNEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üMajor Cations - Dissolved ED093FNEPM 2013 B3 & ALS QC Standard 5.71 5.002 35 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059GNEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üNitrite as N by Discrete Analyser EK057GNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üReactive Phosphorus as P-By Discrete Analyser EK071GNEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification. Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
EvaluationAnalytical Methods Method
Laboratory Control Samples (LCS) - ContinuedNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Carbon EP007NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Inorganic Carbon EP006NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061GNEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üTotal Mercury by FIMS EG035TNEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üTotal Metals by ICP-MS - Suite A EG020A-TNEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067GNEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üVolatile Organic Compounds EP074
Method Blanks (MB)NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055GNEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üConductivity by PC Titrator EA010-PNEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 8.70 5.002 23 üFluoride by PC Titrator EK040PNEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üMajor Cations - Dissolved ED093FNEPM 2013 B3 & ALS QC Standard 5.71 5.002 35 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059GNEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üNitrite as N by Discrete Analyser EK057GNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üReactive Phosphorus as P-By Discrete Analyser EK071GNEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Carbon EP007NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Inorganic Carbon EP006NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061GNEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üTotal Mercury by FIMS EG035TNEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üTotal Metals by ICP-MS - Suite A EG020A-TNEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067GNEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üVolatile Organic Compounds EP074
Matrix Spikes (MS)NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055GNEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üChloride by Discrete Analyser ED045GNEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üDissolved Mercury by FIMS EG035FNEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üDissolved Metals by ICP-MS - Suite A EG020A-FNEPM 2013 B3 & ALS QC Standard 8.70 5.002 23 üFluoride by PC Titrator EK040PNEPM 2013 B3 & ALS QC Standard 5.71 5.002 35 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059GNEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üNitrite as N by Discrete Analyser EK057G
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification. Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular ActualRate (%)Quality Control Sample Type Count
EvaluationAnalytical Methods Method
Matrix Spikes (MS) - ContinuedNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üReactive Phosphorus as P-By Discrete Analyser EK071GNEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041GNEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Carbon EP007NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Inorganic Carbon EP006NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061GNEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üTotal Mercury by FIMS EG035TNEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üTotal Metals by ICP-MS - Suite A EG020A-TNEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üTotal Organic Carbon EP005NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067GNEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üTRH - Semivolatile Fraction EP071NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üTRH Volatiles/BTEX EP080NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üVolatile Organic Compounds EP074
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Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 H+ B. This procedure determines pH of water samples by automated ISE. This method is compliant with NEPM (2013) Schedule B(3)
pH by PC Titrator EA005-P WATER
In house: Referenced to APHA 2510 B. This procedure determines conductivity by automated ISE. This method is compliant with NEPM (2013) Schedule B(3)
Conductivity by PC Titrator EA010-P WATER
In house: Calculation from Electrical Conductivity (APHA 2510 B) using a conversion factor specified in the analytical report. This method is compliant with NEPM (2013) Schedule B(3)
Calculated TDS (from Electrical Conductivity)
EA016 WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013) Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500-SO4. Dissolved sulfate is determined in a 0.45um filtered sample. Sulfate ions are converted to a barium sulfate suspension in an acetic acid medium with barium chloride. Light absorbance of the BaSO4 suspension is measured by a photometer and the SO4-2 concentration is determined by comparison of the reading with a standard curve. This method is compliant with NEPM (2013) Schedule B(3)
Sulfate (Turbidimetric) as SO4 2- by Discrete Analyser
ED041G WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013) Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
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Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS) Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique. A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell. Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS) FIM-AAS is an automated flameless atomic absorption technique. A bromate/bromide reagent is used to oxidise any organic mercury compounds in the unfiltered sample. The ionic mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell. Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Total Mercury by FIMS EG035T WATER
In house: Referenced to APHA 4500-F C: CDTA is added to the sample to provide a uniform ionic strength background, adjust pH, and break up complexes. Fluoride concentration is determined by either manual or automatic ISE measurement. This method is compliant with NEPM (2013) Schedule B(3)
Fluoride by PC Titrator EK040P WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Nitrite as N by Discrete Analyser EK057G WATER
In house: Referenced to APHA 4500-NO3- F. Nitrate is reduced to nitrite by way of a chemical reduction followed by quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate calculated as the difference between the two results. This method is compliant with NEPM (2013) Schedule B(3)
Nitrate as N by Discrete Analyser EK058G WATER
In house: Referenced to APHA 4500-NO3- F. Combined oxidised Nitrogen (NO2+NO3) is determined by Chemical Reduction and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Nitrite and Nitrate as N (NOx) by Discrete Analyser
EK059G WATER
In house: Referenced to APHA 4500-Norg D (In house). An aliquot of sample is digested using a high temperature Kjeldahl digestion to convert nitrogenous compounds to ammonia. Ammonia is determined colorimetrically by discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Kjeldahl Nitrogen as N By Discrete Analyser
EK061G WATER
In house: Referenced to APHA 4500-Norg / 4500-NO3-. This method is compliant with NEPM (2013) Schedule B(3)
Total Nitrogen as N (TKN + Nox) By Discrete Analyser
EK062G WATER
In house: Referenced to APHA 4500-P H, Jirka et al (1976), Zhang et al (2006). This procedure involves sulphuric acid digestion of a sample aliquot to break phosphorus down to orthophosphate. The orthophosphate reacts with ammonium molybdate and antimony potassium tartrate to form a complex which is then reduced and its concentration measured at 880nm using discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Phosphorus as P By Discrete Analyser
EK067G WATER
In house: Referenced to APHA 4500-P F Ammonium molybdate and potassium antimonyl tartrate reacts in acid medium with othophosphate to form a heteropoly acid -phosphomolybdic acid - which is reduced to intensely coloured molybdenum blue by ascorbic acid. Quantification is by Discrete Analyser. This method is compliant with NEPM (2013) Schedule B(3)
Reactive Phosphorus as P-By Discrete Analyser
EK071G WATER
In house: Referenced to APHA 1030F. This method is compliant with NEPM (2013) Schedule B(3)Ionic Balance by PCT DA and Turbi SO4 DA
* EN055 - PG WATER
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Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to APHA 5310 B The automated carbon analyzer removes Inorganic carbon as CO2, which is swept into an IR detector. This method is compliant with NEPM (2013) Schedule B(3)
Total Inorganic Carbon EP006 WATER
In house: Referenced to APHA 5310 B The automated Carbon analyzer converts all Carbon to CO2, which is swept into an IR detector. This method is compliant with NEPM (2013) Schedule B(3)
Total Carbon EP007 WATER
In house: Referenced to USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and quantification is by comparison against an established 5 point calibration curve of n-Alkane standards. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH - Semivolatile Fraction EP071 WATER
In house: Referenced to USEPA SW 846 - 8260D Water samples are directly purged prior to analysis by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Volatile Organic Compounds EP074 WATER
In house: Referenced to USEPA SW 846 - 8260D Water samples are directly purged prior to analysis by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. Alternatively, a sample is equilibrated in a headspace vial and a portion of the headspace determined by GCMS analysis. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH Volatiles/BTEX EP080 WATER
Specialist microbiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).Legionella in Water MM527 WATERMicrobiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).Salmonella - VIDAS (absence /
presence)MM625 WATER
Microbiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).E. coli and Faecal Coliforms by MF (Chromogenic Media)
MM696 WATER
Microbiological analysis subcontracted to ALS Scoresby (NATA Accredited Laboratory No. 992).Total Coliforms and E. coli by MF (Chromogenic Media)
MM698 WATER
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 Norg - D; APHA 4500 P - H. This method is compliant with NEPM (2013) Schedule B(3)
TKN/TP Digestion EK061/EK067 WATER
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
In house: Referenced to USEPA SW 846 - 3510B 100 mL to 1L of sample is transferred to a separatory funnel and serially extracted three times using DCM for each extract. The resultant extracts are combined, dehydrated and concentrated for analysis. This method is compliant with NEPM (2013) Schedule B(3) . ALS default excludes sediment which may be resident in the container.
Separatory Funnel Extraction of Liquids ORG14 WATER
A 5 mL aliquot or 5 mL of a diluted sample is added to a 40 mL VOC vial for sparging.Volatiles Water Preparation ORG16-W WATER
Appendix D Analytical Tables
A1- Replicate Quality Samples
A2- Blanks Quality Samples
A3- Water Quality Results
March GME
Table A1 - Replicate Quality Samples Table A1 - Replicate Quality Samples (Continued)Halogenated
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Alk
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(Car
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Alk
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(Hyd
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CaC
O3
µg/L µg/L µg/L µg/L µg/L µg/L µg/L CFU/mL CFU/mL CFU/mL - CFU/100mL cfu/100 ml µg/L mg/L mg/L mg/L mg/L
EQL 1 2 2 2 2 2 1 10 10 10 1 1 0.5 0.01 1 1 1
Site ID Lab Report NumberSample Code Field ID Date
Camperdown CompostEM2004399 EM2004399-003 MW6 17/3/20 <1 <2 <2 <2 <2 <2 <1 <10 <10 <10 0#1 10 10 <0.5 2.2 612 <1 <1Camperdown CompostEM2004399 EM2004399-004 QAQC1 17/3/20 <1 <2 <2 <2 <2 <2 <1 <10 <10 <10 0#1 <10 <10 <0.5 2.25 605 <1 <1
0 0 0 0 0 0 0 0 0 0 0 181 181 0 2.2 1.15 0 0
Comments
#1 Not Detected
RPD
BTEX Biological Inorganics
EQL
Site ID Lab Report NumberSample Code Field ID
Camperdown CompostEM2004399 EM2004399-003 MW6
Camperdown CompostEM2004399 EM2004399-004 QAQC1
Comments
#1 Not Detected
RPD
Table A1 - Replicate Quality Samples (Continued) Table A1 - Replicate Quality Samples (Continued)
Alk
alin
ity
(to
tal)
as
CaC
O3
Am
mo
nia
as
N
An
ion
s To
tal
Cat
ion
s To
tal
Ch
lori
de
Ele
ctri
cal c
on
du
ctiv
ity
*(la
b)
Flu
ori
de
Ion
ic B
alan
ce
Kje
ldah
l Nit
roge
n T
ota
l
Nit
rate
(as
N)
Nit
rite
(as
N)
Nit
roge
n (T
ota
l)
pH
(Lab
)
Re
acti
ve P
ho
sph
oru
s as
P
Sod
ium
(fil
tere
d)
Sod
ium
Ab
sorp
tio
n R
atio
(fil
tere
d)
Sulf
ate
as
SO4
-
Turb
idim
etr
ic (f
ilte
red
)
Tota
l Car
bo
n
Tota
l Dis
solv
ed
So
lid
s
(Cal
c.)
Tota
l In
org
anic
Car
bo
n
mg/L mg/L meq/L meq/L mg/L uS/cm mg/L % mg/L mg/L mg/L mg/L - mg/L mg/L - mg/L mg/L mg/L mg/L
1 0.01 0.01 0.01 1 1 0.1 0.01 0.1 0.01 0.01 100 0.01 0.01 1 1 1 1 1
612 0.02 72.3 71 2040 7240 1.2 0.85 0.3 2.19 0.01 2.5 7.1 <0.01 1200 17.1 120 163 4710 163605 <0.01 72.5 72.4 2050 7260 1.3 0.03 0.5 2.24 0.01 2.8 6.97 <0.01 1220 17.2 123 165 4720 1681.15 66.7 0.3 2 0.5 0.3 8 186 50 2.3 0 11 1.9 0 1.7 0.6 2.5 1.3 0.2 3
Inorganics
EQL
Site ID Lab Report NumberSample Code Field ID
Camperdown CompostEM2004399 EM2004399-003 MW6
Camperdown CompostEM2004399 EM2004399-004 QAQC1
Comments
#1 Not Detected
RPD
Table A1 - Replicate Quality Samples (Continued) Table A1 - Replicate Quality Samples (Continued)
Lead
TOC
Har
dn
ess
as
CaC
O3
(fil
tere
d)
Lead
(fil
tere
d)
Ars
en
ic (f
ilte
red
)
Cad
miu
m (f
ilte
red
)
Cal
ciu
m (f
ilte
red
)
Ch
rom
ium
(III
+VI)
(fil
tere
d)
Co
pp
er
(fil
tere
d)
Mag
ne
siu
m (f
ilte
red
)
Me
rcu
ry (f
ilte
red
)
Nic
kel (
filt
ere
d)
Ph
osp
ho
rus
Po
tass
ium
(fil
tere
d)
Zin
c (f
ilte
red
)
4,4
-DD
E
a-B
HC
Ald
rin
Ald
rin
+ D
ield
rin
b-B
HC
chlo
rdan
e
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L
1 1 0.001 0.001 0.0001 1 0.001 0.001 1 0.0001 0.001 0.01 1 0.005 0.5 0.5 0.5 0.5 0.5 0.5
<1 928 <0.001 <0.001 <0.0001 88 <0.001 0.007 172 <0.0001 0.006 0.03 12 0.03 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<1 954 <0.001 <0.001 <0.0001 90 <0.001 0.004 177 <0.0001 0.006 0.03 12 0.024 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50 2.8 0 0 0 2.3 0 55 2.9 0 0 0 0 22 0 0 0 0 0 0
Inorganics Metals Organochlorine Pesticides
EQL
Site ID Lab Report NumberSample Code Field ID
Camperdown CompostEM2004399 EM2004399-003 MW6
Camperdown CompostEM2004399 EM2004399-004 QAQC1
Comments
#1 Not Detected
RPD
Table A1 - Replicate Quality Samples (Continued) Table A1 - Replicate Quality Samples (Continued)
Ch
lord
ane
(cis
)
Ch
lord
ane
(tra
ns)
d-B
HC
DD
D
DD
T
DD
T+D
DE+
DD
D
Die
ldri
n
End
osu
lfan
I
End
osu
lfan
II
End
osu
lfan
su
lph
ate
End
rin
End
rin
ald
eh
yde
End
rin
ke
ton
e
g-B
HC
(Lin
dan
e)
He
pta
chlo
r
He
pta
chlo
r e
po
xid
e
Me
tho
xych
lor
Azi
no
ph
os
me
thyl
Bro
mo
ph
os-
eth
yl
Car
bo
ph
en
oth
ion
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
0.5 0.5 0.5 0.5 2 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2 0.5 0.5 0.5
<0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Organophosphorous PesticidesOrganochlorine Pesticides
EQL
Site ID Lab Report NumberSample Code Field ID
Camperdown CompostEM2004399 EM2004399-003 MW6
Camperdown CompostEM2004399 EM2004399-004 QAQC1
Comments
#1 Not Detected
RPD
Table A1 - Replicate Quality Samples (Continued)
Ch
lorf
en
vin
ph
os
Ch
lorp
yrif
os
Ch
lorp
yrif
os-
me
thyl
Dia
zin
on
Dic
hlo
rvo
s
Dim
eth
oat
e
Eth
ion
Fen
thio
n
Mal
ath
ion
Me
thyl
par
ath
ion
Mo
no
cro
top
ho
s
Pro
thio
fos
Ace
nap
hth
en
e
Ace
nap
hth
yle
ne
An
thra
cen
e
Be
nz(
a)an
thra
cen
e
Be
nzo
(a) p
yre
ne
Be
nzo
(b+j
)flu
ora
nth
en
e
Be
nzo
(g,h
,i)p
ery
len
e
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2 2 0.5 1 1 1 1 0.5 1 1
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <2 <0.5 <1 <1 <1 <1 <0.5 <1 <1<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <2 <0.5 <1 <1 <1 <1 <0.5 <1 <1
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Organophosphorous Pesticides PAH
EQL
Site ID Lab Report NumberSample Code Field ID
Camperdown CompostEM2004399 EM2004399-003 MW6
Camperdown CompostEM2004399 EM2004399-004 QAQC1
Comments
#1 Not Detected
RPD
Table A1 - Replicate Quality Samples (Continued)Polychlorinated
Biphenyls
Be
nzo
(k)f
luo
ran
the
ne
Ch
ryse
ne
Dib
en
z(a,
h)a
nth
race
ne
Flu
ora
nth
en
e
Flu
ore
ne
Ind
en
o(1
,2,3
-c,d
)pyr
en
e
Nap
hth
ale
ne
Ph
en
anth
ren
e
Pyr
en
e
PA
Hs
(Vic
EP
A L
ist)
De
me
ton
-S-m
eth
yl
Fen
amip
ho
s
Par
ath
ion
Pir
imp
ho
s-e
thyl
PC
Bs
(Su
m o
f to
tal)
C6
-C9
C6
-C1
0
TPH
C1
0-C
14
Fra
ctio
n
TPH
C1
5-C
28
Fra
ctio
n
TPH
C2
9-C
36
Fra
ctio
n
TRH
>C
10
-C1
6
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L ug/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
1 1 1 1 1 1 1 1 1 0.5 0.5 0.5 2 0.5 1 20 20 50 100 50 100
<1 <1 <1 <1 <1 <1 <1 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <20 <50 <100 <50 <100<1 <1 <1 <1 <1 <1 <1 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <20 <50 <100 <50 <1000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
PAH Pesticides TPH
EQL
Site ID Lab Report NumberSample Code Field ID
Camperdown CompostEM2004399 EM2004399-003 MW6
Camperdown CompostEM2004399 EM2004399-004 QAQC1
Comments
#1 Not Detected
RPD
Table A1 - Replicate Quality Samples (Continued) Table A1 - Replicate Quality Samples (Continued)
TRH
>C
16
-C3
4
TRH
>C
34
-C4
0
>C1
0 -
C1
6 F
ract
ion
min
us
Nap
hth
ale
ne
(F2
) (SG
)
>C1
0 -
C4
0 F
ract
ion
(su
m)
(SG
)
F1 m
inu
s B
TEX
Sty
ren
e
Iso
pro
py
lbe
nze
ne
n-P
rop
ylb
en
zen
e
1.3
.5-T
rim
eth
ylb
en
zen
e
sec-
Bu
tylb
en
zen
e
1.2
.4-T
rim
eth
ylb
en
zen
e
tert
-Bu
tylb
en
zen
e
p-I
sop
rop
ylt
ou
len
e
n-B
uty
lbe
nze
ne
Vin
yl
Ace
tate
2-B
uta
no
ne
(M
EK
)
4-M
eth
yl-
2-p
en
tan
on
e
(MIB
K)
2-H
ex
an
on
e (
MB
K)
Ca
rbo
n d
isu
lfid
e
2.2
-Dic
hlo
rop
rop
an
e
1.2
Dic
hlo
rop
rop
an
e
cis-
1.3
-Dic
hlo
rop
rop
an
e
tra
ns-
1.3
-
Dic
hlo
rop
rop
an
e
1.2
-Dib
rom
oe
tha
ne
(ED
B)
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
100 100 100 100 20 5 5 5 5 5 5 5 5 5 50 50 50 50 5 5 5 5 5 5
<100 <100 <100 <100 <20 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5<100 <100 <100 <100 <20 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
VOC'sTPH MAH's
EQL
Site ID Lab Report NumberSample Code Field ID
Camperdown CompostEM2004399 EM2004399-003 MW6
Camperdown CompostEM2004399 EM2004399-004 QAQC1
Comments
#1 Not Detected
RPD
Table A1 - Replicate Quality Samples (Continued) Table A1 - Replicate Quality Samples (Continued)
Dic
hlo
rod
iflu
rom
eth
an
e
Ch
loro
me
tha
ne
Vin
yl
Ch
lori
de
Bro
mo
me
tha
ne
Ch
loro
eth
an
e
Tri
chlo
rofl
uo
rom
eth
an
e
1.1
-Dic
hlo
roe
the
ne
Iod
om
eth
an
e
tra
ns-
1.2
-
Dic
hlo
roe
the
ne
1.1
-Dic
hlo
roe
tha
ne
cis-
1.2
-Dic
hlo
roe
the
ne
1.1
.1-T
rich
loro
eth
an
e
1.1
-Dic
hlo
rop
rop
yle
ne
Ca
rbo
n T
etr
ach
lori
de
1.2
-Dic
hlo
roe
tha
ne
Tri
chlo
roe
the
ne
Dib
rom
om
eth
an
e
1.1
.2-T
rich
loro
eth
an
e
1.3
-Dic
hlo
rop
rop
an
e
Te
tra
chlo
roe
the
ne
1.1
.1.2
-
Te
tra
chlo
roe
tha
ne
tra
ns-
1.4
-Dic
hlo
ro-2
-
bu
ten
e
cis-
1.4
-Dic
hlo
ro-2
-
bu
ten
e
1.1
.2.2
-
Te
tra
chlo
roe
tha
ne
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
50 50 50 50 50 50 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5
<50 <50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<50 <50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
VOC's
EQL
Site ID Lab Report NumberSample Code Field ID
Camperdown CompostEM2004399 EM2004399-003 MW6
Camperdown CompostEM2004399 EM2004399-004 QAQC1
Comments
#1 Not Detected
RPD1
.2.3
-Tri
chlo
rop
rop
an
e
Pe
nta
chlo
roe
tha
ne
1.2
-Dib
rom
o-3
-
chlo
rop
rop
an
e
He
xa
chlo
rob
uta
die
ne
Ch
loro
be
nze
ne
Bro
mo
be
nze
ne
2-C
hlo
roto
lue
ne
4-C
hlo
roto
lue
ne
1.3
-Dic
hlo
rob
en
zen
e
1.4
-Dic
hlo
rob
en
zen
e
1.2
-Dic
hlo
rob
en
zen
e
1.2
.4-T
rich
loro
be
nze
ne
1.2
.3-T
rich
loro
be
nze
ne
Ch
loro
form
Bro
mo
dic
hlo
rom
eth
an
e
Dib
rom
och
loro
me
tha
ne
Bro
mo
form
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
VOC's
Benz
ene
Tolu
ene
Ethy
lben
zene
Xyle
ne (m
& p
)
Xyle
ne (o
)
µg/L µg/L µg/L µg/L µg/L
Lab Report NumberSample Code Field ID Date DepthEM2004399 EM2004399-005 RB1 17/3/20 <1 <2 <2 <2 <2EM2004399 EM2004399-006 TB1 17/3/20 <1 <2 <2 <2 <2
Table A2_BLANKS QUALITY SAMPLESBTEX
LeadXy
lene
Tot
al
Tota
l BTE
X
Nap
htha
lene
Lead
Arse
nic
Cadm
ium
Chro
miu
m (I
II+VI
)
Copp
er
Mer
cury
Nic
kel
Zinc
µg/L µg/L µg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
<2 <0.1 <5 <0.001 <0.001 <0.0001 <0.001 <0.001 <0.0001 <0.001 <0.005<2 <0.1 <5
MetalsTable A2_BLANKS QUALITY SAMPLES
BTEX
C6-C
9
C10-
C14
C15-
C28
C29-
C36
C10-
C36
Sum
C6-C
10
F1 m
inus
BTE
X
µg/L µg/L µg/L µg/L µg/L µg/L µg/L
<20 <50 <100 <50 <50 <20 <20<20 - - - - <20 -
TPHTable A2_BLANKS QUALITY SAMPLES
Styr
ene
Isop
ropy
lben
zene
n-Pr
opyl
benz
ene
1.3.
5-Tr
imet
hylb
enze
ne
sec-
Buty
lben
zene
1.2.
4-Tr
imet
hylb
enze
ne
tert
-But
ylbe
nzen
e
p-Is
opro
pylto
ulen
e
n-Bu
tylb
enze
ne
Viny
l Ace
tate
2-Bu
tano
ne (M
EK)
4-M
ethy
l-2-
pent
anon
e (M
IBK)
2-H
exan
one
(MBK
)
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
<5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50
VOCTable A2_BLANKS QUALITY SAMPLES
Carb
on d
isul
fide
2.2-
Dic
hlor
opro
pane
1.2
Dic
hlor
opro
pane
cis-
1.3
-D
ichl
orop
ropa
ne
tran
s-1.
3-D
ichl
orop
ropa
ne
1.2-
Dib
rom
oeth
ane
(ED
B)
Dic
hlor
odifl
urom
etha
ne
Chlo
rom
etha
ne
Viny
l Chl
orid
e
Brom
omet
hane
Chlo
roet
hane
Tric
hlor
oflu
orom
etha
ne
1.1-
Dic
hlor
oeth
ene
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
<5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <50 <50 <5
VOCTable A2_BLANKS QUALITY SAMPLES
Iodo
met
hane
tran
s-1.
2-D
ichl
oroe
then
e
1.1-
Dic
hlor
oeth
ane
cis-
1.2-
Dic
hlor
oeth
ene
1.1.
1-Tr
ichl
oroe
than
e
1.1-
Dic
hlor
opro
pyle
ne
Carb
on
Tetr
achl
orid
e
1.2-
Dic
hlor
oeth
ane
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
<5 <5 <5 <5 <5 <5 <5 <5
VOCTable A2_BLANKS QUALITY SAMPLES
Tric
hlor
oeth
ene
Dib
rom
omet
hane
1.1.
2-Tr
ichl
oroe
than
e
1.3-
Dic
hlor
opro
pane
Tetr
achl
oroe
then
e
1.1.
1.2-
Tetr
achl
oroe
than
e
tran
s-1.
4-D
ichl
oro-
2-bu
tene
cis-
1.4-
Dic
hlor
o-2-
bute
ne
1.1.
2.2-
Tetr
achl
oroe
than
e
1.2.
3-Tr
ichl
orop
ropa
ne
Pent
achl
oroe
than
e
1.2-
Dib
rom
o-3-
chlo
ropr
opan
e
Hex
achl
orob
utad
iene
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
VOCTable A2_BLANKS QUALITY SAMPLES
Chlo
robe
nzen
e
Brom
oben
zene
2-Ch
loro
tolu
ene
4-Ch
loro
tolu
ene
1.3-
Dic
hlor
oben
zene
1.4-
Dic
hlor
oben
zene
1.2-
Dic
hlor
oben
zene
1.2.
4-Tr
ichl
orob
enze
ne
1.2.
3-Tr
ichl
orob
enze
ne
Chlo
rofo
rm
Brom
odic
hlor
omet
hane
Dib
rom
ochl
orom
etha
ne
Brom
ofor
m
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
VOCTable A2_BLANKS QUALITY SAMPLES
Benz
ene
Tolu
ene
Ethy
lben
zene
Xyle
ne (m
& p
)
µg/L µg/L µg/L µg/LEQL 1 2 2 2ANZECC 2000 slightly-moderately disturbed systems 950ADWG 2015 Aesthetic 25 3ADWG 2015 Health 1 800 300ANZECC 2000 FW 95% 950ANZECC 2000 Livestock DW Low Risk Trigger ValuesANZECC 2000 Rec Water Quality and Aesthetics: Primary contactANZECC 2000 Recreational water quality and aesthetics 10NEPM 2013 Table 1C GILs, Drinking Water 1 800 300NEPM 2013 Table 1C GILs, Fresh Waters 950NEPM 2013 Table 1A(4) Comm/Ind HSL D GW for Vapour Intrusion, Clay 2-4m 30,000 4-8m 30,000 >8m 35,000
Site ID Lab Report Number Sample Code Field ID DateCamperdown Compost EM2004399 EM2004399-001 MW4 17/3/20 <1 <2 <2 <2Camperdown Compost EM2004399 EM2004399-002 MW5 17/3/20 <1 <2 <2 <2Camperdown Compost EM2004399 EM2004399-003 MW6 17/3/20 <1 <2 <2 <2
StatisticsNumber of Results 3 3 3 3Number of Detects 0 0 0 0Minimum Concentration <1 <2 <2 <2Minimum Detect ND ND ND NDMaximum Concentration <1 <2 <2 <2Maximum Detect ND ND ND NDAverage Concentration * 0.5 1 1 1Median Concentration * 0.5 1 1 1Standard Deviation * 0 0 0 095% UCL (Student's-t) * 0.5 1 1 1* A Non Detect Multiplier of 0.5 has been applied.
Comments#1 Not Detected
Environmental StandardsDoE, 2000, ANZECC 2000 slightly-moderately disturbed systemsNHMRC, 2015, ADWG 2015 AestheticNHMRC, 2015, ADWG 2015 HealthDoE, 2000, ANZECC 2000 FW 95%DoE, 2000, ANZECC 2000 Livestock DW Low Risk Trigger ValuesDoE, 2000, ANZECC 2000 Rec Water Quality and Aesthetics: Primary contactDoE, 2000, ANZECC 2000 Recreational water quality and aesthetics
BTEX
Halogenated Benzenes
Xyle
ne (o
)
Xyle
ne To
tal
Tota
l BTE
X
Legi
onel
la
Pneu
mop
hila
Se
rogr
oup
1
Legi
onel
la
Pneu
mop
hila
Se
rogr
oup
2-14
Legi
onel
la Sp
ecie
s
Salm
onel
la sp
Faec
al C
olifo
rms
E. C
oli
Hexa
chlo
robe
nzen
e
Nitr
ite +
Nitr
ate
as N
Alka
linity
(B
icar
bona
te as
Ca
CO3)
Alka
linity
(C
arbo
nate
as
CaCO
3)
Alka
linity
(H
ydro
xide
) as
CaCO
3
Alka
linity
(tot
al) a
s Ca
CO3
Amm
onia
as N
Anio
ns To
tal
Catio
ns To
tal
µg/L µg/L µg/L CFU/mL CFU/mL CFU/mL - CFU/100mL cfu/100 ml µg/L mg/L mg/L mg/L mg/L mg/L mg/L meq/L meq/L2 2 1 10 10 10 1 1 0.5 0.01 1 1 1 1 0.01 0.01 0.01
350 0.69920
600350 0.9
6000.01
600350 550
<2 <2 <1 <10 <10 <10 0#1 2000 2000 <0.5 0.58 516 <1 <1 1380 0.02 85 76.2<2 <2 <1 <10 <10 <10 0#1 60 60 <0.5 3.92 597 <1 <1 1120 0.06 88.6 79.3<2 <2 <1 <10 <10 <10 0#1 10 10 <0.5 2.2 612 <1 <1 928 0.02 72.3 71
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 30 0 0 0 0 0 0 3 3 0 3 3 0 0 3 3 3 3
<2 <2 <1 <10 <10 <10 0 10 10 <0.5 0.58 516 <1 <1 928 0.02 72.3 71.0ND ND ND ND ND ND ND ND ND ND 0.58 516 ND ND 928 0.02 72.3 71.0<2 <2 <1 <10 <10 <10 0 2000 2000 <0.5 3.9 612 <1 <1 1,380 0.06 88.6 79.3ND ND ND ND ND ND 0 ND ND ND 3.9 612 ND ND 1,380 0.06 88.6 79.31 1 0.5 5 5 5 0 690 690 0.25 2.2 575 0.5 0.5 1,143 0.03 82 75.51 1 0.5 5 5 5 0 60 60 0.25 2.2 597 0.5 0.5 1,120 0.02 85 76.20 0 0.0 0 0 0 0 1,135 1,135 0 1.7 52 0 0 227 0.02 9 4.21 1 0.5 5 5 5 0 2,000 2,000 0.25 4.2 634.6 0.5 0.5 1,404.6 0.06 91.9 80.3
BTEX Biological Inorganics
Lead
Chlo
ride
Elec
tric
al
cond
uctiv
ity *(
lab)
Fluo
ride
Ioni
c Bal
ance
Kjel
dahl
Nitr
ogen
To
tal
Nitr
ate
(as N
)
Nitr
ite (a
s N)
Nitr
ogen
(Tot
al)
pH (L
ab)
Reac
tive
Phos
phor
us
as P
Sodi
um (f
ilter
ed)
Sodi
um A
bsor
ptio
n Ra
tio (f
ilter
ed)
Sulfa
te as
SO4
- Tu
rbid
imet
ric
(filte
red)
Tota
l Car
bon
Tota
l Diss
olve
d So
lids (
Calc
.)
Tota
l Ino
rgan
ic
Carb
on
TOC
Hard
ness
as C
aCO3
(fi
ltere
d)
Lead
(filt
ered
)
mg/L uS/cm mg/L % mg/L mg/L mg/L µg/L - mg/L mg/L - mg/L mg/L mg/L mg/L mg/L mg/L mg/L1 1 0.1 0.01 0.1 0.01 0.01 100 0.01 0.01 1 1 1 1 1 1 1 0.001
0.0034250 6.5-8.5 180 200
1.5 0.012.4 0.0034
2 0.1
400 10 1 6.5-8.5 300 500 0.051.5 0.01
0.0034
2570 7700 1 5.46 0.1 0.57 0.01 700 7.14 <0.01 1110 13 105 139 5000 142 2 1380 <0.0012610 7920 1 5.54 0.6 3.92 <0.01 4500 6.44 <0.01 1300 16.9 147 184 5150 184 <1 1120 <0.0012040 7240 1.2 0.85 0.3 2.19 0.01 2500 7.1 <0.01 1200 17.1 120 163 4710 163 <1 928 <0.001
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 33 3 3 3 3 3 2 3 3 0 3 3 3 3 3 3 1 3 0
2,040 7,240 1.0 0.85 0.10 0.57 <0.01 700 6.4 <0.01 1,110 13.0 105 139 4,710 142 <1 928 <0.0012,040 7,240 1.0 0.85 0.10 0.57 0.01 700 6.4 ND 1,110 13.0 105 139 4,710 142 2.0 928 ND2,610 7,920 1.2 5.54 0.60 3.92 0.01 4,500 7.14 <0.01 1,300 17.1 147 184 5,150 184 2.0 1,380 <0.0012,610 7,920 1.2 5.54 0.60 3.92 0.01 4,500 7.14 ND 1,300 17.1 147 184 5,150 184 2.0 1,380 ND2,407 7,620 1.1 3.95 0.33 2.23 0.01 2,567 6.89 0.005 1,203 15.7 124 162 4,953 163 1.0 1,143 0.00052,570 7,700 1.0 5.46 0.30 2.19 0.01 2,500 7.10 0.005 1,200 16.9 120 163 5,000 163 0.5 1,120 0.0005
318 347 0.1 2.68 0.25 1.68 0.00 1,901 0.39 0 95 2.3 21 23 224 21 0.9 91 02,774 8,021 1.2 7.05 0.62 4.16 0.01 4,762 7.35 0.005 1,313 18.3 149 188 5,212 187 2.0 1,405 0.0005
Inorganics
Arse
nic (
filte
red)
Cadm
ium
(filt
ered
)
Calc
ium
(filt
ered
)
Chro
miu
m (I
II+VI
) (fi
ltere
d)
Copp
er (f
ilter
ed)
Mag
nesiu
m
(filte
red)
Mer
cury
(filt
ered
)
Nick
el (f
ilter
ed)
Phos
phor
us
Pota
ssiu
m (f
ilter
ed)
Zinc
(filt
ered
)
4,4-
DDE
a-BH
C
Aldr
in
Aldr
in +
Diel
drin
b-BH
C
chlo
rdan
e
Chlo
rdan
e (c
is)
Chlo
rdan
e (tr
ans)
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L0.001 0.0001 1 0.001 0.001 1 0.0001 0.001 0.01 1 0.005 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
0.0002 0.0014 6E-05 0.011 0.008 0.031 3
0.01 0.002 2 0.001 0.02 0.3 20.0002 0.0014 0.0006 0.011 0.008 0.08
0.5 0.01 1 0.4 0.002 1 20
0.05 0.005 0.05 1 0.001 0.1 5 1 60.01 0.002 2 0.001 0.02 0.3 2
0.0002 0.0014 6E-05 0.011 0.008 0.03
<0.001 <0.0001 138 <0.001 0.02 251 <0.0001 0.064 0.01 14 0.062 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.001 <0.0001 116 <0.001 0.014 202 <0.0001 0.015 0.11 14 0.059 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.001 <0.0001 88 <0.001 0.007 172 <0.0001 0.006 0.03 12 0.03 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 30 0 3 0 3 3 0 3 3 3 3 0 0 0 0 0 0 0 0
<0.001 <0.0001 88 <0.001 0.007 172 <0.0001 0.006 0.01 12.0 0.030 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5ND ND 88 ND 0.007 172 ND 0.006 0.01 12.0 0.030 ND ND ND ND ND ND ND ND
<0.001 <0.0001 138 <0.001 0.020 251 <0.0001 0.064 0.11 14.0 0.062 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5ND ND 138 ND 0.020 251 ND 0.064 0.11 14.0 0.062 ND ND ND ND ND ND ND ND
0.0005 0.00005 114 0.0005 0.001 208 0.00005 0.030 0.05 13.3 0.05 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.250.0005 0.00005 116 0.0005 0.014 202 0.00005 0.015 0.03 14.0 0.059 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25
0 0 25 0 0.01 40 0 0.030 0.05 1.2 0.02 0 0 0 0 0 0 0 00.0005 0.00005 143 0.0005 0.02 254 0.00005 0.060 0.11 14.7 0.07 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25
Metals Organochlorine Pesticides
d-BH
C
DDD
DDT
DDT+
DDE+
DDD
Diel
drin
Endo
sulfa
n I
Endo
sulfa
n II
Endo
sulfa
n su
lpha
te
Endr
in
Endr
in al
dehy
de
Endr
in ke
tone
g-BH
C (L
inda
ne)
Hept
achl
or
Hept
achl
or e
poxi
de
Met
hoxy
chlo
r
Azin
opho
s met
hyl
Brom
opho
s-eth
yl
Carb
ophe
noth
ion
Chlo
rfenv
inph
os
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L0.5 0.5 2 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2 0.5 0.5 0.5 0.5
0.006 0.01 0.2 0.01 0.01
9 10 0.3 30 10 0.5 20.01 0.02 0.2 0.09 0.02
3 1 1 10 3 10 20 1 109 10 0.3 30 2
0.006 0.01 0.2 0.01
<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
<0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <0.5 <0.5 <0.5 <0.5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
0.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 1 0.25 0.25 0.25 0.250.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 1 0.25 0.25 0.25 0.25
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00.25 0.25 1 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 1 0.25 0.25 0.25 0.25
Organochlorine Pesticides Organophosphorous Pesticides
Chlo
rpyr
ifos
Chlo
rpyr
ifos-m
ethy
l
Diaz
inon
Dich
lorv
os
Dim
etho
ate
Ethi
on
Fent
hion
Mal
athi
on
Met
hyl p
arat
hion
Mon
ocro
toph
os
Prot
hiof
os
Acen
apht
hene
Acen
apht
hyle
ne
Anth
race
ne
Benz
(a)a
nthr
acen
e
Benz
o(a)
pyr
ene
Benz
o(b+
j)flu
oran
then
e
Benz
o(g,
h,i)p
eryl
ene
Benz
o(k)
fluor
anth
ene
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 2 2 0.5 1 1 1 1 0.5 1 1 1
0.01 0.01 0.15 0.05
10 4 5 7 4 7 70 0.7 2 0.010.01 0.01 0.15 0.05
2 10 20 100 6 100 6 2 0.0110 4 5 7 4 7 70 0.7 0.01
0.01 0.01 0.15 0.05
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <2 <0.5 <1 <1 <1 <1 <0.5 <1 <1 <1<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <2 <0.5 <1 <1 <1 <1 <0.5 <1 <1 <1<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <2 <0.5 <1 <1 <1 <1 <0.5 <1 <1 <1
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <2 <0.5 <1 <1 <1 <1 <0.5 <1 <1 <1ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2 <2 <0.5 <1 <1 <1 <1 <0.5 <1 <1 <1ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 1 1 0.25 0.5 0.5 0.5 0.5 0.25 0.5 0.5 0.50.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 1 1 0.25 0.5 0.5 0.5 0.5 0.25 0.5 0.5 0.5
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 1 1 0.25 0.5 0.5 0.5 0.5 0.25 0.5 0.5 0.5
Organophosphorous Pesticides PAH
Polychlorinated Biphenyls
Chry
sene
Dibe
nz(a
,h)a
nthr
ace
ne Fluo
rant
hene
Fluo
rene
Inde
no(1
,2,3
-c,
d)py
rene
Naph
thal
ene
Phen
anth
rene
Pyre
ne
PAHs
(Vic
EPA
List
)
Dem
eton
-S-m
ethy
l
Fena
mip
hos
Para
thio
n
Pirim
phos
-eth
yl
PCBs
(Sum
of t
otal
)
C6-C
9
C6-C
10
TPH
C10-
C14
Fr
actio
n
TPH
C15-
C28
Fr
actio
n
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L ug/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L1 1 1 1 1 1 1 1 0.5 0.5 0.5 2 0.5 1 20 20 50 100
16 0.004
0.5 20 0.516 0.004
30 10.5 20
16 0.004
<1 <1 <1 <1 <1 <1 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <20 <50 <100<1 <1 <1 <1 <1 <1 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <20 <50 <100<1 <1 <1 <1 <1 <1 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <20 <50 <100
3 3 3 3 3 6 3 3 3 3 3 3 3 3 3 3 3 30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
<1 <1 <1 <1 <1 <1 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <20 <50 <100ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND<1 <1 <1 <1 <1 <5 <1 <1 <0.5 <0.5 <0.5 <2 <0.5 <1 <20 <20 <50 <100ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND0.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.25 0.25 0.25 1 0.25 0.5 10 10 25 500.5 0.5 0.5 0.5 0.5 1.5 0.5 0.5 0.25 0.25 0.25 1 0.25 0.5 10 10 25 50
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00.5 0.5 0.5 0.5 0.5 2.401 0.5 0.5 0.25 0.25 0.25 1 0.25 0.5 10 10 25 50
PAH Pesticides TPH
TPH
C29-
C36
Fr
actio
n
TRH
>C10
-C16
TRH
>C16
-C34
TRH
>C34
-C40
>C10
- C16
Frac
tion
min
us N
apht
hale
ne
(F2)
(SG)
>C10
- C40
Frac
tion
(sum
) (SG
)
F1 m
inus
BTE
X
Styr
ene
Isop
ropy
lben
zene
n-Pr
opyl
benz
ene
1.3.
5-Tr
imet
hylb
enze
ne
sec-
Buty
lben
zene
1.2.
4-Tr
imet
hylb
enze
ne
tert
-But
ylbe
nzen
e
p-Is
opro
pylto
ulen
e
n-Bu
tylb
enze
ne
Viny
l Ace
tate
2-Bu
tano
ne (M
EK)
4-M
ethy
l-2-
pent
anon
e (M
IBK)
2-H
exan
one
(MBK
)
Carb
on d
isul
fide
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L50 100 100 100 100 100 20 5 5 5 5 5 5 5 5 5 50 50 50 50 5
430
30
<50 <100 <100 <100 <100 <100 <20 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5<50 <100 <100 <100 <100 <100 <20 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5<50 <100 <100 <100 <100 <100 <20 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
<50 <100 <100 <100 <100 <100 <20 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND<50 <100 <100 <100 <100 <100 <20 <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND25 50 50 50 50 50 10 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 25 25 25 25 2.525 50 50 50 50 50 10 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 25 25 25 25 2.50 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
25 50 50 50 50 50 10 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 25 25 25 25 2.5
MAH's VOC'sTPH
2.2-
Dic
hlor
opro
pane
1.2
Dic
hlor
opro
pane
cis-
1.3
-D
ichl
orop
ropa
ne
tran
s-1.
3-D
ichl
orop
ropa
ne
1.2-
Dib
rom
oeth
ane
(ED
B)
Dic
hlor
odifl
urom
etha
ne
Chlo
rom
etha
ne
Viny
l Chl
orid
e
Brom
omet
hane
Chlo
roet
hane
Tric
hlor
oflu
orom
etha
ne
1.1-
Dic
hlor
oeth
ene
Iodo
met
hane
tran
s-1.
2-D
ichl
oroe
then
e
1.1-
Dic
hlor
oeth
ane
cis-
1.2-
Dic
hlor
oeth
ene
1.1.
1-Tr
ichl
oroe
than
e
1.1-
Dic
hlor
opro
pyle
ne
Carb
on
Tetr
achl
orid
e
1.2-
Dic
hlor
oeth
ane
Tric
hlor
oeth
ene
Dib
rom
omet
hane
1.1.
2-Tr
ichl
oroe
than
e
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L5 5 5 5 5 50 50 50 50 50 50 5 5 5 5 5 5 5 5 5 5 5 5
3 3
0.3 30 60 3 36500
<5 <5 <5 <5 <5 <50 <50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <50 <50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <50 <50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0<5 <5 <5 <5 <5 <50 <50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND<5 <5 <5 <5 <5 <50 <50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND2.5 2.5 2.5 2.5 2.5 25 25 25 25 25 25 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.52.5 2.5 2.5 2.5 2.5 25 25 25 25 25 25 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.50 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2.5 2.5 2.5 2.5 2.5 25 25 25 25 25 25 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5
VOC's
1.3-
Dic
hlor
opro
pane
Tetr
achl
oroe
then
e
1.1.
1.2-
Tetr
achl
oroe
than
e
tran
s-1.
4-D
ichl
oro-
2-bu
tene
cis-
1.4-
Dic
hlor
o-2-
bute
ne
1.1.
2.2-
Tetr
achl
oroe
than
e
1.2.
3-Tr
ichl
orop
ropa
ne
Pent
achl
oroe
than
e
1.2-
Dib
rom
o-3-
chlo
ropr
opan
e
Hex
achl
orob
utad
iene Ch
loro
benz
ene
Brom
oben
zene
2-Ch
loro
tolu
ene
4-Ch
loro
tolu
ene
1.3-
Dic
hlor
oben
zene
1.4-
Dic
hlor
oben
zene
1.2-
Dic
hlor
oben
zene
1.2.
4-Tr
ichl
orob
enze
ne
1.2.
3-Tr
ichl
orob
enze
ne
Chlo
rofo
rm
Brom
odic
hlor
omet
hane
Dib
rom
ochl
orom
etha
ne
Brom
ofor
m
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5
10 20 0.3 1 5 550 0.7 300 40 1500 30 30 50 50 50 50
0.7 40 1500 50 50 50 50260 60 160 170 10
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.52.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.50 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5
VOC's
May GME
Table A1 - Replicate Quality Samples Table A1 - Replicate Quality Samples (Continued)
Legi
onel
la P
neum
ophi
la
Sero
grou
p 1
Legi
onel
la P
neum
ophi
la
Sero
grou
p 2-
14
Legi
onel
la Sp
ecie
s
Salm
onel
la sp
Faec
al C
olifo
rms
E. C
oli
Nitr
ite +
Nitr
ate
as N
Alka
linity
(Bic
arbo
nate
as
CaCO
3)
Alka
linity
(Car
bona
te as
Ca
CO3)
Alka
linity
(Hyd
roxi
de) a
s Ca
CO3
Alka
linity
(tot
al) a
s CaC
O3
Amm
onia
as N
Anio
ns To
tal
Catio
ns To
tal
Chlo
ride
Elec
tric
al co
nduc
tivity
*(
lab)
Fluo
ride
CFU/mL CFU/mL CFU/mL - CFU/100mL cfu/100 ml mg/L mg/L mg/L mg/L mg/L mg/L meq/L meq/L mg/L uS/cm mg/LEQL 10 10 10 1 1 0.01 1 1 1 1 0.01 0.01 0.01 1 1 0.1
Site ID Lab Report NumberSample Code Field ID DateCamperdown Compost EM2008003 EM2008003-001 MW4 13/5/20 <10 <10 <10 0#1 <10 <10 0.42 497 <1 <1 497 0.05 82.2 73.1 2490 7340 1.2Camperdown Compost EM2008003 EM2008003-004 QAQC1 13/5/20 <10 <10 <10 0#1 <10 <10 0.42 500 <1 <1 500 0.01 84.8 73.1 2580 7360 1.1
0 0 0 0 0 0 0 0.6 0 0 0.6 133.3 3.1 0 3.6 0.3 8.7
Comments#1 Not Detected
RPD
Biological Inorganics
EQL
Site ID Lab Report NumberSample Code Field IDCamperdown Compost EM2008003 EM2008003-001 MW4Camperdown Compost EM2008003 EM2008003-004 QAQC1
Comments#1 Not Detected
RPD
Table A1 - Replicate Quality Samples (Continued) Table A1 - Replicate Quality Samples (Continued) Table A1 - Replicate Quality Samples (Continued)
Lead
Ioni
c Bal
ance
Kjel
dahl
Nitr
ogen
Tota
l
Nitr
ate
(as N
)
Nitr
ite (a
s N)
Nitr
ogen
(Tot
al)
pH (L
ab)
Reac
tive
Phos
phor
us as
P
Sodi
um (f
ilter
ed)
Sodi
um A
bsor
ptio
n Ra
tio
(filte
red)
Sulfa
te as
SO4
- Tu
rbid
imet
ric (f
ilter
ed)
Tota
l Car
bon
Tota
l Diss
olve
d So
lids
(Cal
c.)
Tota
l Ino
rgan
ic C
arbo
n
TOC
Hard
ness
as C
aCO3
(fi
ltere
d)
Lead
(filt
ered
)
Arse
nic (
filte
red)
Cadm
ium
(filt
ered
)
Calc
ium
(filt
ered
)
Chro
miu
m (I
II+VI
) (fi
ltere
d)
Copp
er (f
ilter
ed)
Mag
nesiu
m (f
ilter
ed)
Mer
cury
(filt
ered
)
Nick
el (f
ilter
ed)
Phos
phor
us
Pota
ssiu
m (f
ilter
ed)
Zinc
(filt
ered
)
% mg/L mg/L mg/L mg/L - mg/L mg/L - mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L0.01 0.1 0.01 0.01 100 0.01 0.01 1 1 1 1 1 1 1 0.001 0.001 0.0001 1 0.001 0.001 1 0.0001 0.001 0.01 1 0.005
5.86 0.2 0.42 <0.01 0.6 7.87 <0.01 1050 12.4 97 122 4770 125 <5 1350 <0.001 <0.001 <0.0001 143 <0.001 0.006 242 <0.0001 0.01 <0.01 14 0.0397.4 0.2 0.42 <0.01 0.6 7.9 <0.01 1050 12.4 99 125 4780 127 <5 1360 <0.001 <0.001 <0.0001 143 <0.001 0.003 243 <0.0001 0.007 <0.01 13 0.03
23.2 0 0 0 0 0.4 0 0 0 2 2.4 0.2 1.6 0 0.7 0 0 0 0 0 66.7 0.4 0 35.1 0 7.4 26.1
Inorganics Metals
Lead
Benz
ene
Tolu
ene
Ethy
lben
zene
Xyle
ne (m
& p
)
Xyle
ne (o
)
Xyle
ne T
otal
Tota
l BTE
X
Nap
htha
lene
Lead
Arse
nic
Cadm
ium
Chro
miu
m (I
II+VI
)
Copp
er
Mer
cury
Nic
kel
Zinc
C6-C
9
C10-
C14
C15-
C28
C29-
C36
C10-
C36
Sum
C6-C
10
F1 m
inus
BTE
X
Styr
ene
Isop
ropy
lben
zene
n-Pr
opyl
benz
ene
1.3.
5-Tr
imet
hylb
enze
ne
sec-
Buty
lben
zene
1.2.
4-Tr
imet
hylb
enze
ne
tert
-But
ylbe
nzen
e
p-Is
opro
pylto
ulen
e
n-Bu
tylb
enze
ne
Viny
l Ace
tate
2-Bu
tano
ne (M
EK)
4-M
ethy
l-2-
pent
anon
e (M
IBK)
2-H
exan
one
(MBK
)
Carb
on d
isul
fide
2.2-
Dic
hlor
opro
pane
1.2
Dic
hlor
opro
pane
cis-
1.3
-D
ichl
orop
ropa
ne
tran
s-1.
3-D
ichl
orop
ropa
ne
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
Lab Report NumberSample Code Field ID Date DepthEM2008003 EM2008003-005 RB1 13/5/20 <1 <2 <2 <2 <2 <2 <1 <5 <0.001 <0.001 <0.0001 <0.001 <0.001 <0.0001 <0.001 <0.005 <20 <50 <100 <50 <50 <20 <20EM2008003 EM2008003-006 TB1 13/5/20 <1 <2 <2 <2 <2 <2 <1 <5 <20 - - - - <20 - <5 <5 <5 <5 <5 <5 <5 <5 <5 <50 <50 <50 <50 <5 <5 <5 <5 <5
Metals TPH VOCTable A2_BLANKS QUALITY SAMPLES
BTEX
1.2-
Dib
rom
oeth
ane
(ED
B)
Dic
hlor
odifl
urom
etha
ne
Chlo
rom
etha
ne
Viny
l Chl
orid
e
Brom
omet
hane
Chlo
roet
hane
Tric
hlor
oflu
orom
etha
ne
1.1-
Dic
hlor
oeth
ene
Iodo
met
hane
tran
s-1.
2-D
ichl
oroe
then
e
1.1-
Dic
hlor
oeth
ane
cis-
1.2-
Dic
hlor
oeth
ene
1.1.
1-Tr
ichl
oroe
than
e
1.1-
Dic
hlor
opro
pyle
ne
Carb
on
Tetr
achl
orid
e
1.2-
Dic
hlor
oeth
ane
Tric
hlor
oeth
ene
Dib
rom
omet
hane
1.1.
2-Tr
ichl
oroe
than
e
1.3-
Dic
hlor
opro
pane
Tetr
achl
oroe
then
e
1.1.
1.2-
Tetr
achl
oroe
than
e
tran
s-1.
4-D
ichl
oro-
2-bu
tene
cis-
1.4-
Dic
hlor
o-2-
bute
ne
1.1.
2.2-
Tetr
achl
oroe
than
e
1.2.
3-Tr
ichl
orop
ropa
ne
Pent
achl
oroe
than
e
1.2-
Dib
rom
o-3-
chlo
ropr
opan
e
Hex
achl
orob
utad
iene Ch
loro
benz
ene
Brom
oben
zene
2-Ch
loro
tolu
ene
4-Ch
loro
tolu
ene
1.3-
Dic
hlor
oben
zene
1.4-
Dic
hlor
oben
zene
1.2-
Dic
hlor
oben
zene
1.2.
4-Tr
ichl
orob
enze
ne
1.2.
3-Tr
ichl
orob
enze
ne
Chlo
rofo
rm
Brom
odic
hlor
omet
hane
Dib
rom
ochl
orom
etha
ne
Brom
ofor
m
µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L
<5 <50 <50 <50 <50 <50 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
VOCTable A2_BLANKS QUALITY SAMPLES
Legi
onel
la
Pneu
mop
hila
Se
rogr
oup
1
Legi
onel
la
Pneu
mop
hila
Se
rogr
oup
2-14
Legi
onel
la S
peci
es
Salm
onel
la sp
Faec
al C
olifo
rms
E. C
oli
Nit
rite
+ N
itra
te a
s N
CFU/mL CFU/mL CFU/mL - CFU/100mL cfu/100 ml mg/LEQL 10 10 10 1 1 0.01ADWG 2015 AestheticADWG 2015 HealthANZG 2018 FW 95%ANZG 2018 Livestock DW Low Risk Trigger Values 100NEPM 2013 Table 1C GILs, Drinking WaterNEPM 2013 Table 1C GILs, Fresh WatersNEPM 2013 Table 1A(4) Comm/Ind HSL D GW for Vapour Intrusion, Clay 2-4m 4-8m >8m
Site ID Lab Report Number Sample Code Field ID Date
Camperdown Compost EM2008003 EM2008003-001 MW4 13/5/20 <10 <10 <10 0#1 <10 <10 0.42Camperdown Compost EM2008003 EM2008003-002 MW5 13/5/20 <10 <10 <10 0#1 <10 <10 9.48Camperdown Compost EM2008003 EM2008003-003 MW6 13/5/20 <10 <10 <10 0#1 <10 <10 6.93
StatisticsNumber of Results 3 3 3 3 3 3 3Number of Detects 0 0 0 0 0 0 3Minimum Concentration <10 <10 <10 0 <10 <10 0.42Minimum Detect ND ND ND ND ND ND 0.42Maximum Concentration <10 <10 <10 0 <10 <10 9.48Maximum Detect ND ND ND 0 ND ND 9.48Average Concentration * 5 5 5 0 5 5 5.6Median Concentration * 5 5 5 0 5 5 6.9Standard Deviation * 0 0 0 0 0 0 4.795% UCL (Student's-t) * 5 5 5 0 5 5 11
* A Non Detect Multiplier of 0.5 has been applied.
Comments#1 Not Detected
Environmental StandardsDoE, 2000, ANZECC 2000 slightly-moderately disturbed systemsNHMRC, 2015, ADWG 2015 AestheticNHMRC, 2015, ADWG 2015 HealthDoE, 2000, ANZECC 2000 FW 95%DoE, 2000, ANZECC 2000 Livestock DW Low Risk Trigger ValuesDoE, 2000, ANZECC 2000 Rec Water Quality and Aesthetics: Primary contactDoE, 2000, ANZECC 2000 Recreational water quality and aesthetics
Biological Inorganics
Alk
alin
ity
(Bic
arbo
nate
as
CaCO
3)
Alk
alin
ity
(Car
bona
te a
s Ca
CO3)
Alk
alin
ity
(Hyd
roxi
de) a
s Ca
CO3
Alk
alin
ity
(tot
al) a
s Ca
CO3
Am
mon
ia a
s N
Ani
ons T
otal
Cati
ons T
otal
Chlo
ride
Elec
tric
al
cond
ucti
vity
*(la
b)
Fluo
ride
Ioni
c Ba
lanc
e
Kjel
dahl
Nit
roge
n To
tal
Nit
rate
(as N
)
Nit
rite
(as N
)
Nit
roge
n (T
otal
)
pH (L
ab)
mg/L mg/L mg/L mg/L mg/L meq/L meq/L mg/L uS/cm mg/L % mg/L mg/L mg/L mg/L -1 1 1 1 0.01 0.01 0.01 1 1 0.1 0.01 0.1 0.01 0.01 0.1 0.01
250 6.5-8.51.5
0.9 2.42
1.5
497 <1 <1 497 0.05 82.2 73.1 2490 7340 1.2 5.86 0.2 0.42 <0.01 0.6 7.87527 <1 <1 527 <0.01 71.8 67.4 2080 7150 1.8 3.15 0.4 9.48 <0.01 9.9 8.06537 <1 <1 537 0.08 67.1 64.6 1890 6900 1.6 1.92 0.4 6.89 0.03 7.3 8.24
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 33 0 0 3 3 3 3 3 3 3 3 3 3 1 3 3
497 <1 <1 497 <0.01 67.1 64.6 1,890 6,900 1.2 1.92 0.20 0.42 <0.01 0.6 7.9497 ND ND 497 <0.01 67.1 64.6 1,890 6,900 1.2 1.92 0.20 0.42 0.03 0.6 7.9537 <1 <1 537 0.08 82.2 73.1 2,490 7,340 1.8 5.86 0.40 9.48 0.03 9.9 8.24537 ND ND 537 0.08 82.2 73.1 2,490 7,340 1.8 5.86 0.40 9.48 0.03 9.9 8.24520 0.5 0.5 520 0.05 74 68.4 2,153 7,130 1.5 3.64 0.33 5.60 0.01 5.9 8.06527 0.5 0.5 527 0.05 72 67.4 2,080 7,150 1.6 3.15 0.40 6.89 0.01 7.3 8.0621 0 0 21 0.04 8 4.3 307 221 0.3 2.02 0.12 4.67 0.01 4.8 0.19
544 0.5 0.5 544 0.09 82.6 73.4 2,507 7,385 1.9 5.97 0.47 10.98 0.03 11.5 8.27
Inorganics
LeadRe
acti
ve P
hosp
horu
s as
P
Sodi
um (f
ilter
ed)
Sodi
um A
bsor
ptio
n Ra
tio
(filt
ered
)
Sulfa
te a
s SO
4 -
Turb
idim
etri
c (fi
lter
ed)
Tota
l Car
bon
Tota
l Dis
solv
ed
Solid
s (Ca
lc.)
Tota
l Ino
rgan
ic
Carb
on
TOC
Har
dnes
s as C
aCO
3 (fi
lter
ed)
Lead
(filt
ered
)
Ars
enic
(filt
ered
)
Cadm
ium
(filt
ered
)
Calc
ium
(filt
ered
)
Chro
miu
m (I
II+V
I) (fi
lter
ed)
Copp
er (f
ilter
ed)
Mag
nesi
um
(filt
ered
)
Mer
cury
(filt
ered
)
Nic
kel (
filte
red)
Phos
phor
us
Pota
ssiu
m (f
ilter
ed)
Zinc
(filt
ered
)
mg/L mg/L - mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L0.01 1 1 1 1 1 1 1 0.001 0.001 0.0001 1 0.001 0.001 1 0.0001 0.001 0.01 1 0.005
180 200 1 30.01 0.01 0.002 2 0.001 0.02
0.0034 0.0002 0.0014 0.0006 0.011 0.0080.1 0.5 0.01 1 0.4 0.002 1 20
0.01 0.01 0.002 2 0.001 0.020.0034 0.0002 0.0014 6E-05 0.011 0.008
<0.01 1050 12.4 97 122 4770 125 <5 1350 <0.001 <0.001 <0.0001 143 <0.001 0.006 242 <0.0001 0.01 <0.01 14 0.039<0.01 1190 18.6 126 133 4650 129 <5 773 <0.001 <0.001 <0.0001 72 <0.001 0.009 144 <0.0001 0.006 <0.01 9 0.048<0.01 1140 18.4 148 133 4480 130 <5 728 <0.001 <0.001 <0.0001 69 <0.001 0.003 135 <0.0001 0.004 <0.01 18 0.018
3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 30 3 3 3 3 3 3 0 3 0 0 0 3 0 3 3 0 3 3 3 3
<0.01 1,050 12.4 97 122 4,480 125 <5 728 <0.001 <0.001 <0.0001 69 <0.001 0.003 135 <0.0001 0.006 <0.01 9.0 0.018ND 1,050 12.4 97 122 4,480 125 ND 728 ND ND ND 69 ND 0.003 135 ND 0.006 ND 9.0 0.018
<0.01 1,190 18.6 148 133 4,770 130 <5 1,350 <0.001 <0.001 <0.0001 143 <0.001 0.009 242 <0.0001 0.010 <0.01 18.0 0.048ND 1,190 18.6 148 133 4,770 130 ND 1,350 ND ND ND 143 ND 0.009 242 ND 0.010 ND 18.0 0.048
0.005 1,127 16.5 124 129 4,633 128 2.5 950 0.0005 0.0005 0.00005 95 0.0005 0.010 174 0.00005 0.010 0.005 13.7 0.040.005 1,140 18.4 126 133 4,650 129 2.5 773 0.0005 0.0005 0.00005 72 0.0005 0.006 144 0.00005 0.006 0.005 14.0 0.039
0 71 3.5 26 6 146 3 0.0 347 0 0 0 42 0 0.00 59 0 0 0.00 4.5 0.020.005 1,209 20.5 153 137 4,802 131 2.5 1,351 0.0005 0.0005 0.00005 143 0.0005 0.01 242 0.00005 0.010 0.005 18.9 0.05
MetalsInorganics
Appendix E Surveyors Report
Project: GROUNDWATER MONITORING BORE SURVEYLOCATION: CAMPERDOWN COMPOST COMPANY
BLIND CREEK ROAD, BOOKAAR
Client: CAMPERDOWN COMPOST COMPANY / SESL
2718
Date of Survey: 5/03/2020Datum: MGA2020 Zone 54, AHD
NRTK GNSS OBSERVATIONS USING SMARTNET AUS ADOPTED FOR MGA DATUM.KILNOORAT PM4 ADOPTED AS AHD datum (RL 149.898)ALL MEASUREMENTS IN METRES
Surveyor: Alastair Davies, LS
BORE ID EASTING NORTHING TOP OF PVC BORE SLEEVE NATURAL SURFACEMW4 682326.558 5772764.349 138.989 138.265MW5 682023.547 5772738.790 138.520 137.734MW6 681962.298 5772826.487 138.217 137.518
REDUCED LEVEL
Davies Simpson Pty. Ltd. Project Reference:
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Appendix H – Groundwater Monitoring Plan (SESL, February 2020)
Groundwater Monitoring Plan
445 Sandys Lane Bookaar VIC 3260
Prepared for:
Camperdown Compost Company
February 2020
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TABLE OF CONTENTS 1 BACKGROUND .............................................................................................................................................................. 2
1.1 OVERVIEW ....................................................................................................................................................................... 21.2 SITE PROCESSES, LAYOUT AND MONITORING .......................................................................................................................... 41.3 SURROUNDING ENVIRONMENT ............................................................................................................................................. 5
2 MONITORING OBJECTIVES ........................................................................................................................................... 72.1 SECTION 20 LICENCE CONDITIONS ........................................................................................................................................ 72.2 STATE ENVIRONMENTAL PROTECTION POLICIES ....................................................................................................................... 7
3 CONCEPTUAL SITE MODEL .......................................................................................................................................... 103.1 POTENTIAL SOURCES OF IMPACT ......................................................................................................................................... 103.2 POTENTIAL CONTAMINANTS OF CONCERN ............................................................................................................................ 103.3 POTENTIAL FATE AND TRANSPORT ...................................................................................................................................... 113.3.1 TransportMedium..................................................................................................................................................................................113.3.2 PotentialMigrationPathways...........................................................................................................................................................11
3.4 POTENTIAL SURROUNDING RECEPTORS ................................................................................................................................ 114 SAMPLING LOCATIONS, FREQUENCY AND PARAMETERS ............................................................................................ 12
4.1 SAMPLING LOCATIONS ...................................................................................................................................................... 124.2 SAMPLING EVENT FREQUENCY ........................................................................................................................................... 124.3 ANALYSIS PARAMETERS .................................................................................................................................................... 12
5 MONITORING METHODOLOGY ................................................................................................................................... 145.1 EQUIPMENT AND PROCEDURE ............................................................................................................................................ 145.2 LOW-FLOW PURGING ....................................................................................................................................................... 145.3 SAMPLE COLLECTION ........................................................................................................................................................ 145.4 DECONTAMINATION ......................................................................................................................................................... 155.5 CALIBRATION OF EQUIPMENT ............................................................................................................................................. 155.6 QUALITY ASSURANCE ....................................................................................................................................................... 165.6.1 FieldDuplicates........................................................................................................................................................................................165.6.2 RinsateBlank.............................................................................................................................................................................................165.6.3 TripBlank...................................................................................................................................................................................................16
6 REPORTING ................................................................................................................................................................ 177 REFERENCES ............................................................................................................................................................... 18
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1 BACKGROUND 1.1 OVERVIEW SESL Australia was engaged by Camperdown Compost Company (the Client) to develop this groundwater monitoring plan (GMP) for the Camperdown Compost operational site, located off Blind Creek Road, with the licensed address being 445 Sandys Lane, Bookaar VIC 3260 (the Site). The site currently operates as a composting yard, details of which are outlined in Table 1 below.
Table 1 - Site Information
Site Address 445 Sandys Lane, Bookaar VIC 3260 Lot and DP Number Portion of Lot 3, TP 430209 Local Government Area Corangamite Shire Council Current VIC EPA Licence 13415 (Amended 24/11/2017) Distance from Melbourne CBD Approximately 7 km north west of Camperdown and 170 km south-south west of the
Melbourne CBD Geographical Coordinates 38°10.45"S, 143°04'.85"E Site Area 2.4 ha approx. Site Elevation Approximately 139m AHD to 140m AHD Locality Map Figure 1 Site Layout Figure 2
The Camperdown Composting Company operates under an EPA license (13415) (Amended 24/11/2017) for scheduled activities A01 (Prescribed Industrial Waste Management) and A07 (Composting).
It is a requirement of the licence (Section 20) that the Client undertakes groundwater monitoring under a Groundwater Monitoring Plan to ensure that the water resources of the relevant water supply protection area are managed in an equitable manner and so as to ensure the long term-sustainability of those resources. This GMP outlines the monitoring requirements on the site.
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Figure 1 - Site Location Map
Image obtained from NSW LPI via NSW Globe Google Earth Plugin
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Figure 2 - Site Layout
Image obtained from NSW LPI via NSW Globe Google Earth Plugin 2020.
1.2 SITE PROCESSES, LAYOUT AND MONITORING The Site is currently used for the processing of up to 24,000 tonnes of compost materials. It is licensed to receive the following waste streams:
• K100: Animal effluent and residues. Examples: abattoir wastes, poultry wastes, fish and shellfish wastes;
• K120: Grease interceptor trap effluent; • K200: Food and beverage processing wastes, including animal and vegetable oils and derivatives; and • L100: Car and truck wastewaters.
SiteLayoutCamperdownCompostFacility
LegendProposedGroundwaterMonitoringWellLocations
200mN
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NImage©2020CNES/Airbus
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• L150: Industrial washwaters from cleaning, rinsing or washing operations, NOS. Examples: textile cleaning/processing effluent NOS, industrial plant and machinery washwaters, cooling tower washwaters;
• N150: Fly ash; • N190: Filter cake; • T130: Inert sludges or slurries, such as clay or ceramic suspensions, drilling mud, and pit water with
negligible hydrocarbon contamination; and • Compost: hard green wastes and municipal green wastes.
NOTE: NOS means Not Otherwise Specified
The Site is licensed to treat the waste by composting (treatment code: R16).
The site operations take place on a clay hardstand. Upon receipt, all wastes to be composted are delivered to the centre of the site. Solid waste products are added to the existing windrows, with the newest material placed on the end of the windrow that is closest to the centre of the site. Liquid waste is deposited onto a bunded area, which directs the flow of all liquids between the existing windrows at the site. Liquids are incorporated into the windrows via manual, mechanical mixing. Each windrow is ‘pushed’ atop the liquid that is present on the ground surface between the windrows. The material is then restructured into a windrow, approximately 4 metres in height. Windrows increase in maturity towards the outermost points of the site. Using this methodology, the windrows work as a continuous process, rather than a batch-styled approach.
All surface water and leachate from the windrows are directed to the onsite storage dams. The client has reported that during construction, the dams were lined with 500 mm of clay. No groundwater was intercepted during construction to a depth of approximately 4.0 m to 4.5 m.
The client identified groundwater at 3.0 m bgl when the first groundwater monitoring bores were installed in 2015. The integrity of the dam lining was assessed in June 2019 through geotechnical testing of the clay liner. The results indicate permeability of the dam floor and walls are 6 x 10-10 and 7 x 10 -11, and well below the 1.10 x 10-9 requirement.
1.3 SURROUNDING ENVIRONMENT The Site is located in Bookaar, an area of rural properties located approximately 7km north west of Camperdown, Victoria. A review of aerial photography indicates that the surrounding land uses are predominantly agricultural; all properties within a 1 km radius appearing to be rural in nature.
The Site is located approximately 450 metres north east of Blind Creek, which is the closest surface water body. Blind Creek is a tributary of Mt Emu Creek which spans approximately 250 km in length. Mt Emu Creek is
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known to contain breeding populations of platypus, and is home to native fish species, as well as introduced recreational species such as Redfin.
The site and its surrounds are predominantly flat, with a very slight slope (<1%) towards Blind Creek to the south west. It does not lie within any water protection areas.
A search of registered groundwater bores within 1 km of the site indicates that there is a single bore present (#133393) north and upgradient of the site. This 16.76 m deep bore is functional and has a registered use of Stock and Domestic; however, it is not being monitored.
Review of the regional geology maps of Victoria (Seamless Geology Victoria, Geoscience Victoria 2014) indicates that the site is located within the Brighton Group, which is characterised by gravel, sand and silt: variably calcareous to ferruginous sandstones and coquinas; marine to non-marine. A review of the Earth Eon groundwater bore logs (June 2015) indicate the site is dominated by clay and sandy clay textured soils.
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2 MONITORING OBJECTIVES The client is currently seeking development approval from the Victorian EPA for works at the site including the installation of hardstand; the filling in of existing dams; the replacement of old dams with new evaporation basins (to a maximum depth of 2.0 m bgl) lined with 500 mm of clay and a minimum permeability of 1 x 10 -9 as per Victorian EPA guidelines.
Due to expansion of the operating facility, the old bores require decommissioning (not included in this scope of works) and new monitoring wells will be installed at least 8 m from the footprint of the composting operations. The objective of this groundwater monitoring plan is to ensure that current and future composting operations do cause and negative impacts to groundwater quality and groundwater re-use.
2.1 SECTION 20 LICENCE CONDITIONS This GMP is designed to periodically assess groundwater conditions at the site to determine if the Camperdown Compost Company is meeting the compliance condition LI_DL1 (must not contaminate land or groundwater) of their Section 20 Licence.
2.2 STATE ENVIRONMENTAL PROTECTION POLICIES This GMP will enable groundwater conditions and impacts at the site to be compared against the Victorian State Environmental Protection Policy S 160: Groundwaters of Victoria. In accordance with Part III and Part IV of this policy, the GMP will assess groundwater underlying the site for determinations to be made regarding Beneficial Uses Utilising Groundwater Quality Indicators and Objectives.
A review of registered groundwater bores in the surrounding areas (Australian Groundwater Explorer, Bureau of Meteorology, 2017) indicated that bores in the vicinity of the site are primarily used for domestic and stock purposes. With the exception of Bore 133393, located 1 km upgradient from the site; most bores appear to be located at least 2 km away. Any impacts to groundwater quality from emissions from the site has the potential to negatively impact domestic and stock water quality.
In accordance with Section 16 (1) of the Environmental Protection Act 1970, groundwater is protected under the State Environment Protection Policy, (Waters) (Waters SEPP), Gazette no. S493 October 2018. This policy aims to maintain and where necessary, improve groundwater quality in order that the existing and potential beneficial uses of surface and groundwater are preserved.
In accordance with the Waters SEPP (2018), and based on the total dissolved solid (TDS) concentration in groundwater, the beneficial use of groundwater and associated guideline adopted for the assessment of groundwater quality is presented in Table 2.
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Table 2 – Groundwater Beneficial Use Criteria
BENEFICIAL USE ADOPTED GUIDELINE
Maintenance of ecosystems
ANZECC 2000 “Aquatic systems” guidelines for marine and freshwater species. Trigger values for 95% marine water. Also Hickey (2002) for nitrate criteria.
Acceptable Potable Water Supply
National Health and Medical Research Council (NHMRC) Guidelines for Managing Risks in Recreational Water, 2008. NHMRC National Water Quality Management Strategy, Australian Drinking Water Guidelines 6, 2011, updated in 2016.
Agriculture, Parks and Gardens
ANZECC, 2000 “Primary Industries” guidelines for irrigation water quality.
Stock Watering ANZECC, 2000 “Primary Industries” guidelines for livestock drinking water quality.
Industrial Water Use No specific guidelines as stated in ANZECC 2000.
Primary Contact Recreation
NHMRC Guidelines for Managing Risks in Recreational Waters, 2008 (Australian Drinking Water Guideline (2011 updated in 2016) value multiplied by a factor of 10)
Buildings and Structures
Australian Standard AS3600 – 2009 Concrete Structures.
The Groundwater Resource Report (Vic. DELWP) indicates the groundwater in the Hopkins – Corangamite surface aquifer has salinity/TDS of 1001 – 3,500 mg/L.
In accordance with the Waters SEPP(2018), Schedule 1: Salinity (as measured by total dissolved solids (TDS)) criteria must be used to categorise which ‘segment’ the site groundwater belongs in. The identified segment will identify which of the beneficial uses must be protected under the Waters SEPP. The salinity criteria is outlined in Table X indicates the site groundwater belongs to Segment B and C under the Water SEPP.
Table 3 SEPP (Waters) 2018 Groundwater Segment Total - Dissolved Solids Criteria
SEGMENT A1 A2 B C D E F TDS range
(mg/L) 0 – 600 601 – 1200 1201 – 3100 3101 – 5400 5401 – 7100 7100 – 10,000 >10,000
Under this classification, the protected beneficial uses include:
• Water dependant ecosystems and species; • Potable mineral water supply; • Agriculture and irrigation (irrigation); • Agriculture and irrigation (stock watering); • Industrial and commercial; • Primary contact recreation; • Traditional owner cultural values;
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• Cultural and spiritual values; • Geothermal properties; and • Buildings and structures.
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3 CONCEPTUAL SITE MODEL A conceptual site model (CSM) was developed based on the information obtained during a preliminary site investigation (PSI) to allow assessment of potential sources of impact, chemicals of concern, transport mechanism and receptors.
3.1 POTENTIAL SOURCES OF IMPACT Potential impacts to the quality of the groundwater at the site are related to both the receipt of waste and the composting activities at the site. These have been summarised below:
- Nutrient and pathogenic contamination associated with the receipt and processing of K100, K120, K200, L150 and L190 wastes;
- Hydrocarbon contamination, including halogenated volatile organic compounds associated with the receipt and processing of L100, N190 and T130 wastes;
- Heavy metal contamination associated with the receipt and processing of all waste streams; and - Pesticide (organochlorine and organophosphate) contamination associated with the receipt of hard
green wastes and municipal green wastes.
3.2 POTENTIAL CONTAMINANTS OF CONCERN Based on a review of the licensing documentation for the site, the potential contaminants of concern include the following:
- Total Recoverable Hydrocarbons and BTEXN: potentially present in car and truck washwaters, grease interceptor traps and industrial washwaters received at the site;
- Polycyclic Aromatic Hydrocarbons (PAH): potentially present in car and truck washwaters received at the site;
- Heavy Metals: potentially present in all waste streams received at the site; - Organochlorine and Organophosphate Pesticides (OC/OP): potentially present in hard green wastes
and municipal green wastes received at the site; - Plant Nutrients (Nitrogen and Phosphorus): potentially present in all waste streams received at the site; - Total organic carbon: potentially present in all waste streams received at the site; and - Volatile organic compounds including volatile halogenated organic compounds: potentially present in
car and truck washwaters and industrial washwaters received at the site.
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3.3 POTENTIAL FATE AND TRANSPORT
3.3.1 Transport Medium The anticipated primary transport media for the migration of potential contaminants of concern is infiltration of contamination into groundwater aquifers through permeable soils. As there are water storage facilities in the form of runoff-capturing dams, these provide a point source for additional infiltration of contaminated waters into the underlying groundwater aquifer.
Semi-volatile and volatile contaminants have increased potential to volatilise on-site due to the increased temperature within the compost media.
Biodegradation of contaminants occurs on-site via composting processes.
3.3.2 Potential Migration Pathways Recent monitoring has indicated that groundwater is present at < 3.0 metres below ground level (BGL). This shallow standing water level presents an increased risk of groundwater contamination via surface water infiltration. Though no data is available for the permeability of the clay used to line the dam floor and walls at the time of installation, the liner as assessed in 2019 and the permeability (of water) identified at 6 x 10 -10 and 7 x 10-11 respectively. The integrity of the lining may have degraded over time and as such presents a potential contamination risk to groundwater via advection.
Information derived from the client indicates the dams are approximately 4.0 m to 4.5 m deep. At this depth, based on the measured standing water level of < 3 metres BGL across the site, the dam water has potential to interact with the shallow groundwater. As such, pollutants present in runoff water that makes its way into the dam are directly interacting with the groundwater underlying the site and its surrounds.
3.4 POTENTIAL SURROUNDING RECEPTORS The most notable surrounding receptors are the users of groundwater in the area via groundwater bores and Blind Creek. Presence of the potential contaminants of concern within the groundwater has the potential to degrade surrounding waters, posing potential impacts to these receptors.
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4 SAMPLING LOCATIONS, FREQUENCY AND PARAMETERS 4.1 SAMPLING LOCATIONS Three groundwater monitoring wells were installed at the site in June 2015. The wells were surveyed and it is understood that groundwater at the site flows towards the west; MW1 being upgradient of the site and M2 and MW3 are located hydraulically downgradient.
Due to expansion of the site, extension of the dam and damage to one of the existing wells (MW1), three new wells will be installed at the site on the scheduled date of 4th March 2020. The wells will be identified as MW$, MW5 and MW6. For the future groundwater monitoring events, it is recommended that wells MW4, MW5 and MW6 are sampled at a minimum in accordance with this GMP.
4.2 SAMPLING EVENT FREQUENCY Monitoring of the wells since their installation in 2015 has occurred biannually in accordance with the recommendations in the SESL Groundwater Monitoring Event Report (C8080.B42507.Q6406.CC GME, June 2017). Following the installation of the new wells, SESL recommends that future groundwater monitoring events are undertaken biannually. Reducing monitoring frequency from twice to once annually must only be done where it can be demonstrated that contaminants in groundwater are not increasing in concentration.
Sampling should not occur within two weeks of a major rainfall event.
4.3 ANALYSIS PARAMETERS Based on the potential contaminants of concern as identified in Section 3, the following parameters must be analysed during each monitoring event:
Field Measurements
• pH; • Electrical Conductivity; • Temperature; • Dissolved Oxygen; and • Redox Potential.
Laboratory Analysis
• Total Recoverable Hydrocarbons; • BTEXN; • Hexachlorobenzene; • Polynuclear Aromatic Hydrocarbons (PAH); • Heavy Metals (As, Cd, Cr, Cu, Ni, Pb, Zn, Hg);
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• Organochlorine and Organophosphate Pesticides (OC/OP); • Polychlorinated biphenyls (PCB); • Volatile organic compounds (VOCs) including volatile halogenated compounds (VHCs); • Legionella; • Salmonella; • E. coli; • Faecal coliforms; • Total potassium; • Total sodium; • Sodium adsorption ratio (SAR); • Hardness; • Nitrate; • Nitrite; • Ammonia; • Total Kjeldahl Nitrogen (TKN) • Total Nitrogen; • Total Phosphorus; • Filterable Reactive Phosphate; • Total organic carbon; • Total carbon; and • Major cations and anions.
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5 MONITORING METHODOLOGY Monitoring methodology is to remain standard between monitoring events. This is required in order to produce reliable data, which can be used to accurately identify and monitor trends over time.
5.1 EQUIPMENT AND PROCEDURE The Groundwater Sampling Guidelines as developed by the Environmental Protection Authority of Victoria state:
“Groundwater sampling requires special expertise and should be undertaken by, or in consultation with, appropriately qualified and experienced personnel (eg hydrogeologists). This is especially critical in situations where a site is underlain by complex hydrogeology. Consultation with a qualified analyst before sampling is highly recommended, especially with respect to the preservation of samples derived from anaerobic environments.”
It is important that this is adhered to strictly to ensure accurate monitoring is undertaken.
In the context of the site, groundwater monitoring is to be conducted using low-flow purging (micro-purging).
5.2 LOW-FLOW PURGING A micropurge unit (or similar – peristaltic pumps not suitable) must be established by a suitably qualified professional with relevant experience in groundwater sampling. Prior undertaking sampling, all groundwater wells should be gauged, and groundwater depth recorded. When sampling, parameters listed in table 3 below must stabilise adequately before taking samples and recording official field parameters. The readings must be taken using a flow-cell to increase accuracy. Stabilisation parameters are outlined in Table 4 below.
Table 4 – Stabilisation Parameters (VIC EPA, 2000)
Parameter Stabilisation Criteria Dissolved Oxygen ± 10 % - three consecutive readings Turbidity ± 10 % - three consecutive readings Electrical Conductivity ± 3 % - three consecutive readings pH ± 0.05 pH units – three consecutive readings
Redox Potential ± 10 mv - three consecutive readings
5.3 SAMPLE COLLECTION Field-filtered samples must be collected into laboratory-prepared sample containers, containing appropriate preservation for each analyte. Sample collection must be undertaken in order from the most sensitive analyte
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to the least sensitive analyte. Following collection, samples must be immediately placed into a chilled cooler (esky or similar) and transported to a NATA accredited laboratory for analysis.
It is important that sufficient data is documented during each monitoring event. In accordance with the Groundwater Sampling Guidelines (VIC EPA, 2000), the following details should be documented during each monitoring event:
• Purpose of sampling; • Location, description and photographs of sampling point; • Detail of sampling site (elevation of casing, casing diameter, integrity of casing, casing depth, interval
sampled, condition of bore); • Weather conditions during and immediately preceding sampling (e.g., before a rain event); • Reference to procedures for preparation of reagents or supplies that become an integral part of the
sample (eg filters and absorbing reagents); • Identification of sampling team; • Decontamination procedures; • Sampling method (including purging); • Standing water level; • Pump rate for purging and sampling; • Purged volume; • Field measurements; • Potential for interference with field measurements; • Date and time of sample collection; • Number and volume of samples taken (including any QC samples); • Field observations; and • Signature and date, by the responsible personnel.
5.4 DECONTAMINATION Decontamination of sampling equipment between monitoring points using deionised water and phosphate-free detergent is essential. Each monitoring point is to have a dedicated new bladder, and point-specific tubing.
5.5 CALIBRATION OF EQUIPMENT The equipment requires calibration in accordance with the manufacturer’s specifications prior to sampling. Calibration documentation is to be retained and reported.
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5.6 QUALITY ASSURANCE All laboratory analysis is to be conducted by a NATA accredited laboratory under chain of custody procedures.
5.6.1 Field Duplicates A single field duplicate sample is required per monitoring event. This sample must contain no reference to the corresponding original sample. Duplicate analysis should be conducted for same analytes as primary samples.
5.6.2 Rinsate Blank A single rinsate blank must be analysed for each day during which sampling is undertaken. The following parameters must be analysed for each rinsate blank:
• Total Recoverable Hydrocarbons; • BTEXN; and • Heavy metals (As, Cd, Cr, Cu, Ni, Pb, Zn, Hg).
5.6.3 Trip Blank A single trip blank is to be analysed for each chilled esky of sample containers. The following parameters must be analysed for each trip blank:
• Total Recoverable Hydrocarbons (C6-C10); • BTEXN; and • VOCs and VHCs.
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6 REPORTING Following each monitoring event, a detailed report outlining the findings of the investigation must be developed. This report must contain (but is not limited to):
• Full description of the sampling methodology, including any possible factors that may impact the quality and reliability of the results;
• Review of bore construction details; • Details of the current site condition and land use; • Details of the surrounding land uses at the time of sampling; • A review of recent climactic data at the time of sampling; • Full summary of field observations (as listed in Section 0 above); • Summary of analytical results, comparing them against assessment criteria; • Summary of quality control; and • Conclusions and recommendations based on the findings of the assessment.
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7 REFERENCES Australian Groundwater Explorer, 2017; Bureau of Meteorology. Available from: http://www.bom.gov.au/water/groundwater/explorer/map.shtml [13/02/2017]
Groundwater Sampling Guidelines, 2000; Environmental Protection Authority, State Government of Victoria
State Environment Protection Policy S160 (Groundwaters of Victoria), 1997; State Government of Victoria
State Environment Protection Policy S 493 (Waters), 2018, State Government of Victoria
The Camperdown Compost Company Pty Ltd Licence 13415, 2008; EPA Victoria
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Appendix I – Site Risk Register
SITE RISK REGISTER
Hazard Category Aspect Specific Impact Receptor Inherent Risk Proposed Mitigation/Comments Residual Risk
Consequence Likelihood Risk Rank Consequence Likelihood Risk Rank
Waste Acceptance of Waste Accepting and processing a waste that is prohibited at site Environment Major Likely HIGH Waste Acceptance/ Movement/ Quarantine procedures Minor Likely MEDIUM
Odour
Product loading
Odour generated during loading of product
Social - Amenity
Minor
Likely
MEDIUM Aerate the product thoroughly before loading Advertise site contact phone number on signage at site entrance in the
event that there are issues of dust generation.
Minor
Unlikely
LOW
Windrows Odour generated off windrows Social -
Amenity Minor Likely MEDIUM
Identify source of odour and aerate with excavator. If odour persists then spread gypsum lightly over the rows with spreader truck.
Ensure a cover of matured material is maintained at >10mm thickness to reduce odour from fresh feedstocks introduced to site.
Minor Likely MEDIUM
Processing on site
Odour generated during mixing and blending
Social - Amenity
Minor
Likely
MEDIUM
Identify source of offensive odour and mix feedstock with carbon rich dry feedstock to create a carbon filter and oxygenate the feedstock
Minor
Likely
MEDIUM
Product receival receipt
Odourless material received on site
Social - Amenity
Moderate
Likely
MEDIUM Fresh material received on site will be covered with matured product. High risk feedstocks, i.e., liquid animal wastes (blood) and paunch (sludge),
and animal mortalities will not be processed on site.
Minor
Likely
MEDIUM
Windrows
Offensive odour reported by nearby resident
Social - Amenity
Minor
Likely
MEDIUM
Identify source of offensive odour. Ensure a cover of matured material is maintained at >10mm thickness to
reduce odour from fresh feedstocks introduced to site. Mix when wind is from south
Minor
Unlikely
LOW
SITE RISK REGISTER
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Hazard Category Aspect Specific Impact Receptor Inherent Risk Proposed Mitigation/Comments Residual Risk
Consequence Likelihood Risk Rank Consequence Likelihood Risk Rank
Noise
Earthworks
Noise and vibration from the excavation machinery result in loss of amenity to local residents
Social - Amenity
Minor
Likely
MEDIUM Operate machines in normal operating hours. Notify neighbours of the time
frame for operations and cease work when required.
Minor
Likely
MEDIUM
Noise
Operation of plant and equipment (within normal operations) results in generation of excessive noise, impacting sensitive receptors
Social - Amenity
Minor
Likely
MEDIUM
Notify affected neighbours about the excessive noise from operations being undertaken.
Discuss time frame for operation and excessive noise. Minimise impact where possible by avoiding works out of business hours.
Minor
Likely
MEDIUM
Noise
Operation of plant and equipment (within emergency operations) results in generation of excessive noise
Social - Amenity
Minor
Unlikely
LOW
Notify affected neighbours about the emergency operations being undertaken. Discuss time frame for operation and excessive noise. Minimise impact where possible.
Restrict hours of operation to normal business hours and avoid use equipment that may create excessive noise
Minor
Rare
LOW
Dust
Product loading
Dust generated during loading of product
Social - Health and Safety
Minor
Likely
MEDIUM Cease loading trucks at times of high winds or use alternative means.
Monitor weather conditions and plan activities to avoid times of day where forecast weather may create issues.
Negligible
Unlikely
LOW
Windrows
Dust generated off windrows
Social - Amenity
Minor
Certain
MEDIUM
Ensure that windrows are sufficiently watered at all times during operation.
When high winds are forecast institute Dust Management Plan.
Advertise site contact phone number on signage at site entrance in the event that there are issues of dust generation.
Minor
Likely
MEDIUM
Processing on site
Dust generated during mixing and blending
Social - Amenity
Minor
Certain
MEDIUM
Cease mixing and blending at times of high winds and wait for wind direction to change.
Locate dust generating activities to areas where winds will not distribute dust plumes towards sensitive uses.
Advertise site contact phone number on signage at site entrance in the event that there are issues of dust generation.
Minor
Unlikely
LOW
SITE RISK REGISTER
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Hazard Category Aspect Specific Impact Receptor Inherent Risk Proposed Mitigation/Comments Residual Risk
Consequence Likelihood Risk Rank Consequence Likelihood Risk Rank
Land & groundwater
Refuelling, Onsite Storage of fuels, oils or chemicals
Fuel spill resulting in contamination and environmental harm to surface water, groundwater and land.
Environment
Minor
Likely
MEDIUM
Clear any compost and feedstock from around the immediate area of spill with Front End Loader.
Move machinery away from the spill area. Cover spill area with diatomaceous earth powder to soak up fuel / oil.
Scrape up spill into bucket of FEL and dispose into containment bucket. Keep small volumes of fuel on site, and maintain fuel drums in bunded areas
Minor
Unlikely
LOW
Windrows
Sealed surface under windrows fail and contaminants enter groundwater
Environment
Moderate
Unlikely
MEDIUM
Conduct routine maintenance to surfaces on site to maintain surface seal, particularly in high traffic areas.
Repair compacted surfaces and maintain moisture by watering to ensure surface secure
Moderate
Rare
LOW
Processing onsite
Accessways become degraded and contaminants enter groundwater
Environment
Moderate
Unlikely
MEDIUM Maintain accessways to ensure vehicles do not degrade sealed surface.
Conduct routine maintenance to surfaces on site to maintain surface seal, particularly in high traffic areas.
Moderate
Unlikely
MEDIUM
Surface water
Onsite Drainage
Internal drains are not effective at draining the site and contaminated surface water does not drain to leachate dam
Environment
Moderate
Likely
MEDIUM
Undertake regular inspections of drains. Identify where there could be a break in the bank of the drain and repair
drain with clay soil using excavator.
Moderate
Unlikely
MEDIUM
Leachate dam Leachate dam silts up and storage capacity is reduced Environment Minor Likely MEDIUM Use excavator to remove soil and silt from dam to restore original capacity of
the leachate dam on an annual basis. Minor Unlikely LOW
Leachate dam
Leachate Dam overflows during heavy rain event Environment Moderate Likely
MEDIUM Make sure there is enough capacity in the leachate dam to retain water from heavy rain event (1 in 20 yr storm) by increasing flow to windrows during summer months.
Use excavator to remove soil and silt from dam to restore original capacity of the basin on an annual basis.
Should the basin overtop, the water will run into adjoining paddock to the south. Manage any overtopping so water is dispersed into the tussock grasses.
Moderate Unlikely MEDIUM
Leachate dam
Stormwater Basin exceeds capacity
Environment
Negligible
Unlikely
LOW
Undertake regular inspections of drains. Identify blocked storm water drain. Unblock the drain to restore normal flow and function of the pipe.
Negligible
Unlikely
LOW
Fire
Product loading/ unloading
Fire occurs on site generated by equipment
Social - Health and Safety
Minor
Likely
MEDIUM
Cease operation of machinery during high Fire Danger periods. Implement Fire Management Plan and maintain regular and up to date contact
with CFA and response agencies.
Ensure all staff are appropriately trained in fire management. Evacuate the site, as required and directed
Minor
Unlikely
LOW
Grassfire
Grassfire originating offsite spreads towards site
Social - Health and Safety
Major
Likely
HIGH
Implement Fire Management Plan and maintain regular and up to date contact with CFA and response agencies.
Ensure all staff are appropriately trained in fire management. Evacuate the site, as required.
Major Unlikely MEDIUM
Windrows
Feedstock or windrow on fire
Social - Health and Safety
Major
Likely
HIGH
Maintain moisture levels in windrows. Continuous Temperature and moisture monitoring on SCADA system with
alarm.
If fire starts, activate Fire Management Plan and use water from fire truck to wet adjoining windrows to reduce the spread of fire.
Evacuate the site, as required. Notify CFA, if required
Major
Unlikely
MEDIUM
SITE RISK REGISTER
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Hazard Category Aspect Specific Impact Receptor Inherent Risk Proposed Mitigation/Comments Residual Risk
Consequence Likelihood Risk Rank Consequence Likelihood Risk Rank
Biosecurity
Animals (domestic, Feral and/or wild) gaining access to FOGO, or animal waste onsite
Spread of pathogens offsite to neighbouring properties Biosecurity Moderate Unlikely MEDIUM
Manage rows of organic material to prevent vermin from nesting. Maintain fencing to eliminate introduction of vermin
Undertake regular pest animal eradication and control measures to reduce numbers.
Prevent water from pooling and stagnating across the site where insects can breed
Move rows of organic material regularly so as to prevent vermin from nesting
Move incoming feedstock into the pasteurisation phase quickly to prevent vermin nesting
Cover feedstock with dry organic material to prevent crows from feeding Keep the site free from any weeds and plant more trees to prevent weeds
blowing on site
Exclude all ruminant stock by securing fencing the site Remove waste contaminants and keep the site and sheds in a generally tidy
state
Control dust moving off site through appropriate management practices
Moderate Rare LOW
FOGO/Food/Animal waste containing Restricted Animal Material (RAM)
Delivering to customers a product that has not been adequately pasteurised Biosecurity Moderate Unlikely MEDIUM Pasteurisation procedure (including testing) Moderate Rare LOW
Cross contamination of pasteurised material with fresh feed stock Biosecurity Moderate Unlikely MEDIUM Segregation of pasteurised material from all feedstock Moderate Rare LOW
Feed stock not being pasteurised due to low temperature in rows Biosecurity Moderate Unlikely MEDIUM
Remove contaminated material from final matured product storage area and recommence pasteurisation process for this stockpile.
Reprocess material and maintain on site until concentrations are within acceptable levels.
Retest material during and after pasteurisation
Minor
Unlikely
LOW
Ruminant animals coming in direct contact with organic wastes and soil conditioner Biosecurity Minor Likely MEDIUM
Do not allow ruminant animals access to organic wastes
Advise customers to restrict ruminant animals access to piles of soil conditioner
Advise customers a withholding period of 3 weeks is required for treated paddocks before grazing
Minor
Unlikely
LOW
Disease Feedstock contaminated with Emergency Animal Diseases (EAD) Biosecurity Moderate Unlikely MEDIUM
Cease receivals from relevant farm. Isolate contaminated feedstock and commence separate pasteurisation
and testing regime. Clean all machinery used for this work. Maintain regular contact with feedstock supplier to understand any potential
disease threats within the feedstock supply farms
Moderate Unlikely MEDIUM
SITE RISK REGISTER
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Hazard Category Aspect Specific Impact Receptor Inherent Risk Proposed Mitigation/Comments Residual Risk
Consequence Likelihood Risk Rank Consequence Likelihood Risk Rank
Terrestrial ecology
Earthworks
Introduction and spread of weed species from construction vehicles and machinery on site
Environment
Minor
Unlikely
LOW Clean machinery after use, ensuring weeds do not spread between piles.
Undertake weed management program for site to minimise weeds growing on site.
Minor
Unlikely
LOW
Earthworks
Spread of existing weeds off-site
Environment
Minor
Likely
MEDIUM
Implement weed management plan for site. Undertake regular assessment of land surrounding operational area and apply
weed management measures to these areas as required. Undertake weed management program for site to minimise weeds growing on
site.
Minor
Unlikely
LOW
Earthworks
Inadvertent injury to threatened terrestrial flora and fauna.
Environment
Minor
Unlikely
LOW
There have been no registered siting's of threatened terrestrial fauna on the site. Remain vigilant and survey site for animals when undertaking process works.
Contact wildlife shelter if works result in injured animal. Contact local vet to assist if an animal needs to be put down.
Minor
Unlikely
LOW
Earthworks
Inadvertent destruction of threatened terrestrial flora and fauna
Environment
Minor
Unlikely
LOW There have been no registered siting's of threatened terrestrial fauna.
Contact environment officer from Council and advise of the problem.
Minor
Unlikely
LOW
Aboriginal cultural heritage
Earthworks
Disturbing cultural heritage sites, resulting in loss of heritage value
Social - Heritage
Moderate
Unlikely
MEDIUM
There are no records of Cultural heritage sites on the property. If a site of potential cultural significance or an artefact is found during work, cease work and contact Aboriginal Victoria for advice.
High risk activities that could compromise heritage are not being conducted on site.
Moderate
Rare
LOW
Greenhouse gas
Plant operation
Consumption of fossil fuel / carbon based energy resulting in greenhouse gas and other emissions
Environment
Minor
Certain
MEDIUM
Limit the use of diesel burning machines used on site. Don't leave equipment running while not being used.
Train operators how to drive Front End Loader, excavator and trucks so as to limit emissions by not revving engines excessively.
Minor
Certain
MEDIUM
End product
Quality
Problems with delivered product once it is received by the customer
Economic
Minor
Likely
MEDIUM
Contact the customer to identify problem. Cross reference the batch number with the customer.
Check the product that has been delivered. Replace the problem load of product with a new load from a different
batch. Return incorrect load back to site for further processing.
Minor
Likely
MEDIUM
Demand
There are no customers for the processed fertiliser because of drought
Economic
Minor
Likely
MEDIUM
Stockpile processed fertiliser in a safe manner until it rains and sales resume. Offer customers discount incentives.
Find alternative markets. Maintain mature material on site until customer demand increases
Minor
Unlikely
LOW
SITE RISK REGISTER
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Hazard Category Aspect Specific Impact Receptor Inherent Risk Proposed Mitigation/Comments Residual Risk
Consequence Likelihood Risk Rank Consequence Likelihood Risk Rank
Safety
Health and Safety
Staff are injured during on site works
Social - Health and Safety
Major
Unlikely
MEDIUM
Ensure staff are adequately trained for their respective roles. Implement safe work procedures and ensure staff are qualified to operate
machinery.
If injury occurs, implement Health an Safety Policy Procedures for injury incident including calling 000 with request for ambulance
Major
Rare
MEDIUM
Health and Safety
Staff are killed during on site works
Social - Health and Safety
Extreme
Unlikely
HIGH
Ensure staff are adequately trained for their respective roles. Implement safe work procedures and ensure staff are qualified to operate
machinery.
If injury occurs, implement Health an Safety Policy Procedures for injury incident including calling 000 with request for ambulance
Extreme
Rare
HIGH
Chemicals
Onsite storage
Flammable nature of some products (e.g. fuel) resulting in fire and run-off of fire water and ash
Environment
Moderate
Unlikely
MEDIUM Contain spill of fire waters and ash to incident site by creating a temporary
bunded area around the affected area. Clean up spill and dry the affected area.
Moderate
Unlikely
MEDIUM
Amenity
Traffic
Ingress and egress to external roads are restricted
Social - Amenity
Minor
Unlikely
LOW
Identify why there is a problem with ingress and egress to external roads. Notify Council roads manager to assist with traffic management to reinstate access while works are undertaken to rectify the problem.
Minor
Rare
LOW
Traffic
Traffic on Tall Tree Road creates nuisance for residents
Social - Amenity
Minor
Likely
MEDIUM
Identify any excessive traffic on Tall Tree Rd. Review delivery times to ensure vehicles visiting the site are not queueing on Tall Tree Road and use the road evenly throughout the day
Minor
Unlikely
LOW
Community
Community complaints received
Social - Amenity
Moderate
Likely
MEDIUM
Adapt site activities to reduce offsite impacts to sensitive uses. Discuss any complaints with council and EPA officers.
Implement mitigation measures as directed. Contact complainant if required and follow up with an explanation of how the
problem has been resolved.
Moderate
Rare
LOW
Camperdown Compost Works Approval Application July 2020
95 | P a g e
Appendix J – Environmental Management Plan
Environmental Management Plan
August 2019
Bookaar Compost Facility EPA Licence 13415
Document Control Information Environmental Management Plan Document Ref: 4-100 Author: Michael Wood Approved by:
Peter Harlock Operations Manager
Nick Routson CEO
Review Period: 24 months Last Reviewed: August 2019
Table of Contents
1 Introduction ............................................................................................................................................ 3
1.1 Background and Context ........................................................................................................................ 3 1.2 Reference Documents .................................................................................................................... 5 1.3 Purpose and Environmental Objectives ........................................................................................... 5
2 Scope and Format ........................................................................................................................................ 6 3 Description of Facility and Processes ............................................................................................................ 7
3.1 Facility Overview .................................................................................................................................... 7 3.2 Site Locality ........................................................................................................................................... 7 3.3 Management and Implementation of EMP ........................................................................................... 10 3.4 Operations Overview ........................................................................................................................... 10
3.4.1 Receipt Process ............................................................................................................................. 10 3.4.2 Feedstock Descriptions ................................................................................................................. 12 3.4.3 Open Windrow Process ................................................................................................................ 13 3.4.4 Screening Process......................................................................................................................... 14
4 Environmental Management Programs .................................................................................................. 15 4.1 Environmental Commitments ....................................................................................................... 15
4.1.1 Format of Environmental Management Plans ................................................................................ 15 5 Leachate and Contact Water Management ............................................................................................ 15
5.1 Scope ................................................................................................................................................... 15 5.1.1 Operational Phase Liquid Management ........................................................................................ 16
5.2 Geology ............................................................................................................................................... 17 5.3 Leachate Control during Normal Operations ......................................................................................... 17 5.4 Best Practice Leachate and Contact Water Management ...................................................................... 17 5.4.1 Process and Procedural Control Controls for Waste Water Management ........................................... 19 5.5 Contact Water Control During Upset Conditions ........................................................................... 22
5.5.1 Overflow ....................................................................................................................................... 22 5.5.2 Water Deficit/Drought .................................................................................................................. 23 5.5.3 Oversupply of Liquid Feedstock or Wet Solid Bulking Agents .......................................................... 23 5.5.4 pH ................................................................................................................................................ 23 5.5.5 O2................................................................................................................................................. 24 5.5.6 Dissolved Chemicals ...................................................................................................................... 24 5.6.7 Liquid Delivery Spill ....................................................................................................................... 24
6 Dust Management ...................................................................................................................................... 25 6.1 Potential Dust Impacts ......................................................................................................................... 25 6.2 Strategies............................................................................................................................................. 27
6.2.1 Statement of Commitments ...................................................................................................... 27 6.3 Corrective Action ................................................................................................................................. 28
7 Odour Management .............................................................................................................................. 29 7.1 Scope ........................................................................................................................................... 29
7.1.1 Operational Phase Odour Management ......................................................................................... 29 7.2 Surrounding Uses and Sensitive Receptors .................................................................................... 30
7.2.1 Surrounding Land Uses .................................................................................................................. 30 7.2.2 Sensitive Receptors ....................................................................................................................... 31
7.3 Potential Off-Site Sources of Odour .............................................................................................. 31 7.4 Optimal Weather Conditions ........................................................................................................ 31
7.4.1 Wind ............................................................................................................................................. 31 7.4.2 Sunshine Exposure ........................................................................................................................ 33 7.4.3 Precipitation ................................................................................................................................. 33
7.5 Identified On-Site Odour Sources .................................................................................................. 33 7.6 Odour Control during Normal Operations ............................................................................................. 37
7.6.1 Odour Control Strategies ............................................................................................................... 37 7.6.2 Waste Acceptance ......................................................................................................................... 37 7.6.3 Unloading of Wastes ..................................................................................................................... 38 7.6.5 Force Aerated Windrow Composting ............................................................................................. 39
7.7 Odour Control during Upset Conditions ................................................................................................ 40 8 Vegetation Management ............................................................................................................................ 45
8.1 Scope ................................................................................................................................................... 45 8.2 Site and Soil Information ...................................................................................................................... 45 8.3 Climate ................................................................................................................................................ 45 8.4 Weeds ................................................................................................................................................. 46
8.4.1 Weed Threat ................................................................................................................................. 46 8.4.2 Weed Control Options ................................................................................................................... 46 8.4.3 Weed Disposal Procedure ............................................................................................................. 47
9 Pest Management ...................................................................................................................................... 56 9.1 Scope ................................................................................................................................................... 56 9.2 Pests .................................................................................................................................................... 56
9.2.1 The Effects of Pests ....................................................................................................................... 56 9.2.2 Pest Control Measures .................................................................................................................. 57
10 Complaint Handling and Document Control ............................................................................................. 59 10.1 Complaint Management and Document Control ................................................................................ 59
10.1.1 Roles and Responsibilities ............................................................................................................ 59 10.1.2 Complaints Handling Procedure................................................................................................... 59
10.2 Document Control ............................................................................................................................. 60
1 Introduction
1.1 Background and Context
This document is the Environmental Management Plan (EMP) specific to the operation of the current Organics Recycling Facility at Sandys Lane Bookaar Victoria and the upgraded facility to be constructed through 2019-2020. The facility is owned and operated by The Camperdown Compost Company Pty Ltd.
The Camperdown Compost Company is responsible for delivering many services which are concerned with protecting and enhancing the environment. The Camperdown Compost Company always endeavours to minimize negative effects and maximize positive effects on the environment and to work towards achieving sustainable development and continual improvement. The environment is at the centre of all of our operations and as such, Camperdown Compost Company is committed to:
• Minimizing environmental impacts in all of its activities,
• Building environmental concerns into all of its policies, programs and services,
• Integrating key environmental information into all levels of its management structure,
• Achieving continuing improvements in environmental performance over and above
regulatory and legislative requirements, and
• Working in partnership with other organizations to promote the health of the environment
particularly in agriculture, horticulture and local waste management.
• Promoting the conservation and sustainable use of natural resources,
In order to achieve this, Camperdown Compost Company pledges to:
• Set environmental objectives and targets in carrying out all of its activities and monitoring its
performance against those objectives and targets,
• Adopt working practices that minimize negative effects and maximize positive effects on the
environment,
• Train and educate of its staff in respect of its environmental policies and objectives, and
• Strive to continually improve its performance in regard to environmental issues.
This document details the potential environmental impacts of Camperdown Compost Company’s composting facilities and the ways in which these impacts may be reduced through management strategies and site practices. The Environmental Management Plan:
• Provides clear direction on the selection and implementation of appropriate environmental
controls and monitoring techniques during the operational life of the current facility,
transition during construction and the operation of the new technology facility.
• Uses the principles of Camperdown Compost Company’s environmental policies to provide
the basis of operational procedures used to implement the control and management of
environmental impacts.
• Reflects the requirements of licence and approval conditions as well as Camperdown Compost
Company’s commitments to high standard environmental performance.
In order to ensure that the facility operates with the least environmental impact, the EMP addresses a wide range of issues including:
• Feedstock and Waste Acceptance management;
• Dust management;
• Odour management;
• Water, leachate & contact water management;
• Hazardous materials management;
• Finished Product management; and
• Vegetation management.
This Environmental Management Plan should be held in a location or locations to which all levels of
staff have access.
The purpose of the facility is manufacture high quality compost for use in support of the region’s
agricultural and horticultural industries and provide waste processing services to the regional food
processing industries supported by those primary industries and regional municipal organic recycling
programs. The facility can further work to minimise the amount of recyclable and putrescible waste
disposed of to landfill by the implementation of sustainable waste management processes including
sorting, recovery and composting with the best available technology.
Camperdown Compost Company at Bookaar holds an EPA license for the annual receipt and processing of 24,000 tonnes of:
Licensed for Description
Hard green wastes & Municipal green wastes
Hard green wastes & Municipal green wastes
K100 Animal Effluent and residues
K120 Grease interceptor trap effluent
K200 Food & Beverage processing wastes
L100 Car & Truck wash waters
L150 Industrial wash waters
N150 Fly Ash
N190 Filter Cake
T130 Inert sludges or slurries Inc Drilling mud with no free flowing liquid in it.
The feedstock list for the works approval will be extended with the addition of mixed kerbside food and garden organics, commercial food and category C soils.
1.2 Reference Documents
This document has been developed in accordance with all relevant legislation and guidelines. This includes:
• Environmental Protection Act (1970) As amended 2018
• EPA Guidance 1588.1 Design, Construction and Operating Compost Facilities
• EPA Guidance Management and Storage of Combustible Recyclables Waste Materials 2018
• Sustainability Victoria Guide to Biological Recovery of Organics 2018
• Biosecurity Strategy for Victoria (Government of Victoria 2009)
• Invasive Plants and Animals Policy Framework (DPI 2010)
• Catchment and Land Protection Act 1994
1.3 Purpose and Environmental Objectives
The purpose of this EMP is to ensure that appropriate environmental practices are followed during
operation of the current facility, the transition period of the construction schedule and the operation
of the completed upgraded facility.
The environmental objectives of the EMP are to:
• Implement and maintain effective environmental management systems for the all
operations and site activities;
• Document details of environmental protection infrastructure and controls and their
operation so that they function effectively to provide protection for the natural
environment; and
• Ensure compliance with relevant legislation, regulatory requirements and undertakings
given by Camperdown Compost Company.
2 Scope and Format
The format of this EMP is as follows:
• Section 1 provides an introduction to the project background and provides context,
including the range of potential environmental impacts identified during the
environmental assessment process. This section also cross-references licence and
approval conditions with the location within the EMP where the particular conditions
are addressed;
• Section 2 provides a brief description of the facility, including description of the waste
and environmental management practices employed;
• Section 3, 4, 5,6 and 7 (a) list the potential environmental impacts identified during the
assessment and approval processes as requiring Environmental Management
Programmes to be developed and implemented; and (b) provide the specific
Environmental Management Programmes, including monitoring and reporting
requirements.
• Section 8 and 9 outlines the Vegetation and Wildlife Management plans to be
implemented at Camperdown Compost Company.
• Section 10 describes Camperdown Compost Company’s complaint handling procedures
and the document control measures associated with this document.
3 Description of Facility and Processes
3.1 Facility Overview
The facility at Bookaar is a commercial organics recycling facility focused on composting. It processes
a variety of organic wastes over a 12-20 week period, converting these wastes into fully matured soil
ameliorant compliant with the Australian Standard AS4454. The facility currently employs open
windrow technology using large windrows to minimise the surface area to volume ratio of the emitting
surfaces and aeration by excavator agitation and turning methods. The upgraded facility will utilise a
force aerated concrete floor with smaller windrows turned with a self-propelled turner and a
hardstand pad for final pasteurisation assurance and maturation. It will also feature an upgraded
liquids receipt and handling system.
The finished product is a well-balanced, nutritious and microbiologically rich, stable compost of
maximum benefit to agricultural soils.
3.2 Site Locality
The site is located at 445 Sandy’s Lane Bookaar, Camperdown Compost Company’s operational facility is 9 Kms from the centre of Camperdown township and approximately 8 Kms from outlying residential areas
The locality of the site can be seen in Figure 1.
Figure 1: Site Locality
An aerial of the activity area is given in Figure 2.
Figure 2: Current Activity Area Aerial
Figure 3: Upgraded Activity Area Schematic
3.3 Management and Implementation of EMP
Protecting the environment and minimising Camperdown Compost Company’s impacts on the
environment is the responsibility of all Camperdown Compost Company staff. All Camperdown
Compost Company staff are required to have read the Environmental Management Plan and be aware
of their collective and individual responsibilities as defined by the plan. Where responsibilities pertain
specifically to one individual such as the Site Manager, this is explicitly stated in the document.
It is the responsibility of the Operations Manager at Camperdown Compost Company to take all
practicable measures to minimise its impact on the environment. The Operations Manager must
ensure all staff are aware of their environmental obligations. In the event that staff have any concerns,
questions or suggestions regarding Camperdown Compost Company’s environmental impacts, these
should be directed to the Operations Manager for consideration and amendment of the EMP if
required.
3.4 Operations Overview
3.4.1 Receipt Process
Camperdown Compost Company uses two distinct means of receipt at its facility. These processes
are designed to manage the risks associated with odour, contamination, biohazards and spillages.
These methods are:
• Receipt pad for solids
• Liquid receipt bund or pit for sludge and liquids
Solid Receipts
Feedstocks which have an associated contamination risk, primarily garden organics must be processed
on the receipt pad. The material is manually decontaminated by Camperdown Compost Company
pickers. Decontamination is important as it reduces the levels of litter in the final product to eventually
be sold and spread on land. Decontamination must be done effectively as once formed into windrows,
the contamination will travel through the whole process increasing the risk of litter on site and reach
finished products.
Pickers must wear all required PPE during the decontamination process including;
• Camperdown Compost Company-approved gloves;
• Hat;
• Protective glasses;
• Long sleeve top;
• 50+ Sunscreen; and
• Steel-cap boots.
All recyclable material extracted from garden organics deliveries is as far as locally practicable sent for
recycling in accordance with Camperdown Compost Company’s Sustainability Policy. Materials
deemed to be sufficiently clean and suitable for recycling by Camperdown Compost Company are as
follows:
• Glass;
• Aluminium;
• Recyclable Plastics; and
• Metals.
These materials are to be categorised into collection skips and sent to the nearest relevant recycling
facility. All non-recyclable materials material will be sent to the EPA-licenced Corangamite Regional
Landfill facility operated by Corangamite Shire at County Boundary Road West Naroghid. By
arrangement the local landfill is receiving oversize material for immediate beneficial reuse in landfill
operations and long term static windrowing where after it will be screened to recover clean fines to
minimize the contaminated oversize actually landfilled.
Hazardous materials which may be present in deliveries include:
• Asbestos;
• Syringes; and
• Biomedical wastes (faecal samples, sanitary materials etc.)
Any hazardous materials found in deliveries must be immediately reported to the Site Manager and
documented on a contaminated load form matched to the delivery’s corresponding weighbridge
docket. Hazardous materials found in deliveries must be handled in accordance with Camperdown
Compost Company’s Contaminants Procedure 4-305.
Camperdown Compost Company staff are required to wear approved gloves at all stages of the
decontamination process but any on-skin contact with hazardous materials must be reported to the
Site Manager immediately and documented on Camperdown Compost Company’s Injury and Incident
Report Procedure Report Form
Liquid Receipts
Liquids are currently received in a concrete receipts pit where they pumped out for absorption into
large windrows. Solid residue is blended with garden based organic solids and formed into windrows.
The upgraded liquid receipt system will feature immediate processing through a stainless steel star
screen de-watering unit where solids will be removed from the liquid receipts. The processed water
will be stored in an irrigation tank ready for application to the windrows. Solids from the de-watering
process will be blended with garden organics as will the residue from the liquid receipts pit.
Input waste waters and sludges are prescribed industrial wastes as listed below by waste codes. The precise receipt inputs are currently reasonably stable based on commercial need but vary seasonally and periodically based on demand or environmental need. For example the usual expected composition of receipts can be altered by a scheduled maintenance and cleaning event at a client waste producer, unscheduled breakdown or environmental issue requiring immediate disposal of PIW waters. Details of the sources of PIW waste waters are listed in the waste water section. The rates of inclusion of liquid wastes will be roughly half of all receipts counting liquids as whole tonnes.
Liquid wastes will be received in a dedicated concrete trough and mixing pit placed below the driveway where multiple trucks can simultaneously discharge. The receipts will be immediately de-watered by pumping the contents of the liquid receipts pit through a de-watering screen and the solids separated into a pit for blending. The solid residue of this process collected in the liquid receipts pit will be mixed with garden and food based solid organic bulking agents for formation into windrows. The solids from the de-watering process captured in the pit will be dug out and mixed with solid chipped municipal garden or food and garden organics ready for windrow formation. The separated processed liquid will be held in short term storage and be pumped onto the biological drying pad daily. Some liquids that contain only suspended solids that will not benefit from passing the de-watering screen may be received direct into the irrigation storage tank where appropriately assessed and pre-approved. The processed de-watered liquid storage irrigation tank will have a capacity of 225,000 litres, sufficient to manage a significant contingency over average daily receipts of 107,000 litres. In contingency situations where water cannot be pumped for application to the windrows, the irrigation storage tank will have controlled overflow capacity to the contact water dam. Upgraded Liquid Receipts Area
3.4.2 Feedstock Descriptions
3.4.2.1 Garden and Mixed Kerbside Garden & Food Organics (Solid) Garden organics includes some or all of the following: grass clippings, leaves, branches, twigs, foliage
cuttings, hedge trimmings etc. and in the case of FOGO also include domestic food wastes such as
peelings, rinds and left overs. These materials will come from both transfer station garden services
and kerbside bins (both garden organics and mixed green and food kerbside collections) and will form
the one of the base feedstocks to which all other feedstock types are combined in various proportions.
Garden organics which are received in the form of kerbside collections are likely to contain a degree
of contamination and for this reason will be carefully decontaminated upon arrival.
3.4.2.2 Commercial Food
Solid commercial food varies considerably depending on the source, ranging from vegetable offcut material to post consumer restaurant wastes. Commercial food selected for processing in the upgraded facility will be subject to careful risk assessment scrutiny under environmental operating procedure 4-330 Pre Receipt Feedstock Assessment & Approval.
3.4.2.3 Prescribed Industrial Waste Prescribed liquid waste treatment is in high demand in the region and Camperdown Compost
Company serves key local dairy processors, food processing and general regional liquid waste
treatment needs. These categories are also often taken as sludge. Contaminated soils are included in
the upgrade feedstock application and will be blended as a solid on the receipt pad. The range of
feedstocks and waste codes are listed below.
Table 1: Feedstocks
Feedstocks
Organic Wastes Municipal green wastes GO & FOGO
(including mixed kerbside food and garden organics)
Commercial Food
Organic PIW
K100 S Animal Effluent and residues
K100 L Animal Effluent and residues
K120 L Grease interceptor trap effluent
K200 L Food and Beverage processing wastes
L100 L Car & Truck wash waters
L150 L Industrial wash waters
T130 P Inert sludges or slurries
N121 S Category C soils
3.4.3 Open Windrow Process
Currently, liquids are pumped or blended into garden organics based bulking agents and formed into
large windrows to minimise surface area to volume ratio to reduce odorous emissions. Smaller
windrows trialled under the section 30 A with a self-propelled turner have proved to more odorous
than the traditional large windrows employed on site. These large windrows are carefully aerated by
excavators cracking fissures into the sides of the windrows to allow aeration and to form a pseudo-
biofilter layer on the large windrows as they convect and evaporate high moisture contents. This has
proved from experience to minimise odorous emissions, especially during periods where liquid receipt
volumes have been high due to cleaning or contingent events at key customers operations.
In the upgraded facility, after the de-watering of liquids in the liquid receipts area, solid material
separated through the de-watering screen will be unloaded from the pad using a front end loader or
excavator and blended with garden organic or FOGO material on the receipts pad. It will then be
formed into a windrow to initiate the composting process and await its schedule to be formed into
windrows on the biological drying pad. Windrows will be formed on the force aerated biological drying
pad and subject to regular turning and application of liquids from the de-watering process for a further
8 weeks. In this time they will be monitored for temperature driving a SCADA system activating the
force aeration on demand. Further manual testing will be routinely performed to measure oxygen,
carbon dioxide and methane levels. They will then be picked up by loaders and reformed on the
pasteurisation and maturation pad where no further liquids will applied and an AS4454 compliant
pasteurisation sequence will be completed over an 8 week pasteurisation and maturation timeframe.
Force Aeration Parameters
Table 2: Process parameters
Parameter Measured Requirements Action
Temperature >55°c If > 70°c Turn
Oxygen >10% If < 10% Aerate or Turn
Carbon Dioxide <8% If > 8% Aerate or Turn
Methane <1% If > 1% Aerate or Turn
Moisture 40-60% Irrigate to 60% Optimum
3.4.4 Screening Process
After 16 weeks on the compost pad, the compost will be screened. This involves the scooping of the
product with the loader and putting it through the power screen, which will sort the material according
to particle size.
4 Environmental Management Programs
4.1 Environmental Commitments
Camperdown Compost Company’s assessment strategy involved the identification of all
environmental issues associated with the current operation and future development and upgrade of
the Bookaar facility. A complete review of the Licence Compliance & Monitoring Plan was conducted
through early 2019 leading to a re-write of environmental and operational procedures used in the
operation of the facility. The review further fed into considerations for the design and proposed
methods and operations of the upgraded facility and Works Approval application.
Some of the issues are able to be dealt with through simple administrative actions, while others
require a more comprehensive and specification of future operational and monitoring actions.
4.1.1 Format of Environmental Management Plans
Most of the EMPs follow a set format with sub-headings as follows:
• Potential impacts;
• Operational objective/s;
• Performance criteria;
• Management strategy;
• Baseline data;
• Monitoring;
• Reporting; and
• Corrective action.
5 Leachate and Contact Water Management
5.1 Scope
This section aims to adequately address the following:
• An assessment of the risks of leachate and water problems, from normal and abnormal
situations;
• Worst case scenarios, for example of weather, temperature, or breakdowns;
• Accident scenarios;
• The appropriate controls (both physical and management) needed to manage those risks;
• Suitable monitoring;
• Actions, contingencies and responsibilities when problems arise; and
• Regular review of the effectiveness of Camperdown Compost Company’s leachate and water
control measures.
5.1.1 Operational Phase Liquid Management
Several forms of liquid are involved in the Camperdown Compost Company process. These are:
• Stored rain water;
• Dam water;
• Leachate and Contact water;
• Liquid feedstocks.
These liquids vary in their potential for environmental hazard and thus must be handled in
accordance with the procedures set out in this document. These liquids and their associated risk
levels are detailed in the table below:
Table 3: Liquids and Risk Factors
Liquid Risk Factors Risk Level
Leachate & Contact Water
• High concentration dissolved chemicals (potential for groundwater/soil contamination)
• Odour
Medium
Contact dam water • Relatively high concentration dissolved chemicals
(potential for groundwater/soil contamination)
• Odour
Medium
Liquid Feedstocks • Odour
• Biosecurity High
Dam water
• Flood Low
Table 4: Dam Information
Dam Number Common Name Volume Contents
1 Contact Water &
Settling Dam 7.013 ML
Leachate and contact water run off from force aerated
and hardstand windrow pads.
3 Process Water Tank 0.25 ML Water from PIW Liquids de-
watering process
4 Contact Water Sump 0.116 ML
Water from hardstand windrows. Returned to Contact Water Dam by
pump
Total Dam Capacity 7.37 ML
The contact water run-off from the force aerated & maturation pad is collected in drains under the
force aerated pad and surrounding the hardstand which drain to dam 1. For this reason, it is
important to monitor this dam, ensuring the addition of contact water does not cause it to become
odorous. The contact water dam monitoring plan is given in Table 5.
5.2 Geology
The geology of this site itself has been assessed as being effective in minimising intrusion of
groundwater. The site lies on a clay pad, which has a very low permeability, working to ensure a
separation between groundwater and the leachate on the surface. The geology of the region is defined
by State of Victoria (Agriculture Victoria) soil_landform_units147 updated 31/01/2019 as neogene
fluvial and marine sediments and quaternary scoria deposits with parent material being aeolian
deposits and alluvium; clays and silts and soils as neutral and alkaline black cracking clays which are
strongly structured but expansive clay soils, with moderate to rapid site drainage. High nutrient
capacity, calcareous and sodic, particularly at depth.
5.3 Leachate Control during Normal Operations
The application of good working practices, process control and monitoring is of fundamental
importance in eliminating and minimising the likelihood of liquid mismanagement. This approach is
preferred as it is difficult to rectify liquid mismanagement events such as flood and overflow once it is
occuring.
The overall aim in the operation of the facility is to apply Best Practice at all stages of the waste
treatment processes undertaken on site. Given that leachate is one of the higher risks, the facility is
and will be operated and managed in accordance with the accepted hierarchy of preferred controls,
that is:
1. prevent the generation of excess leachate and contact water;
2. where this is not practicable, control the release of excess leachate and contact water;
3. abate, ameliorate and manage any effects of excessive generation;
5.4 Best Practice Leachate and Contact Water Management
The best practice controls to be employed at Camperdown Compost Company are listed in Table 5.
The Risk Level referred to in the table refers to the potential for environmental impact (odour,
groundwater contamination etc. which could result from the mismanagement of liquids).
Water System Schematic
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Table 5: Process Controls
Process Stage Aspect Risks Risk Level Control Measures
Feedstock Receipt
Solid waste acceptance • Saturated material Low • Concrete receipts and blending pad
Liquid Waste Acceptance
• Spill
• Soil contamination
• Groundwater contamination
• Odour
Medium
• Sealed concrete liquid acceptance pits, enclosures and tanks
• De-watering process for PIW’s
• Immediate processing
• Daily blending of separated solids
• Periodic High pressure cleaning
Feedstock processing Decontamination, LAP loading
• Saturated material
• Odorous receipts Medium
• De-watering process for PIW’s
• Immediate processing
• Daily blending of separated solids & Residues
Leachate and Contact Dam Management
Monitoring of leachate and contact dam levels and conditions
• Anaerobic conditions in the dam causing odour
Medium • See Table 7
Force Aerated Open Windrow processing
Collection of leachate and contact water from windrows
• Pooling of leachate and contact water
• Contamination of soil/groundwater
• Odour
Medium
• Closed water drainage and dam system
• Concrete force aerated floor with underground drainage
• Gradient of concrete and hardstands to drain
• Force aeration and regular turning of windrows
• Large site liquid storage capacity
• Continuous monitoring of windrow temperature to ensure optimal aeration and moisture control
• Site selection (impermeable clay)
Screening and Batching
Screening of finished product • Excessive moisture and
leachate Low
• Hardstand
• Testing of product moisture levels prior to screening
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5.4.1 Process and Procedural Control Controls for Waste Water Management
Liquid Receipts
All receipts take place on either the concrete enclosure of the Liquid Acceptance Pit, or onto the
hardstand receipts area to protect groundwater and soil beneath. All liquid deliveries must be received
into the LAP. A random test monitoring regime will apply to risk assessed clients where analysis is not
regularly provided to ensure the suitability and safety of waste waters for composting. The whole area
can be pressure washed and contained to minimise odour from residue build ups.
As prescribed wastes, liquids will be accepted under EPA Trade Waste Certificates which will be
completed and filed appropriately for each delivery.
Solid Receipts
All solid wastes are to be delivered via the concrete Receipt Pad. Leachate and contact water risk from
solid materials is very low during this process. Mixing and blending of de-watered solids and LAP
residue will occur on the concrete pad which drains back into the liquid acceptance pit for processing.
The whole are can be scraped by the loader using dry garden organic chip to collect liquids and residue
and can also be pressure washed to minimise odour.
Leachate Collection
The windrow pads are built with a greater than 2% slight gradient to facilitate drainage to the
collection drain which runs along the rear base of pads.
Contact & Irrigation Dam Management
The contact water dam (total volume 7.013 ML) will collect all the leachate and contact water from
the concrete force aerated windrow and hardstand maturation pads. The contact water dam is the
most highly used and cycled water on the site, as contact water will drain to this dam. Following
settling in the Contact Water Dam, overflow will pumped to the Irrigation Dam containing a mix of
settled contact water and the fresh water captured on site. The two dam process will provide the
cleanest water available for application to the windrows. Water will be pumped out of the Irrigation
Dam as required for composting in conjunction with P.I.W. waters processed through the solids
removal of de-watering direct from the Irrigation Tank. Changes in the Contact Water Dam chemistry
and volume mean that failure to properly manage the dam could result in one or some of the following
upset conditions:
• Anaerobic conditions causing excessive odour;
• Algal blooms;
• Overflow; and
• Water deficit resulting extreme salinity and failure to comply with CFA requirements.
The Contact Water Dam monitoring requirements are outlined in the table below:
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Table 6: Contact Water Dam Monitoring Program
Parameter Means of Monitoring Performed by Acceptable
Bounds Monitoring Schedule
Responsible Staff Member
Water Level &
Freeboard Water depth gauge Site Supervisor 600mm Weekly
Operations Manager
pH pH probe Site Supervisor 4-9 Monthly Operations Manager
O2 Oxygen probe Site Supervisor > 3 mg/L Monthly Operations Manager
EC E.C. meter Site Supervisor < 8 Monthly Operations Manager
Dissolved chemicals
Sample sent to NATA accredited laboratory
External Environmental
Consultancy
Various in accordance
with EPA guidelines
Annually
Operations Manager
Solids build up on the bottom of the dam
Lower water and inspect
Site Supervisor 2 metre sludge
layer Annually
Operations Manager
Water levels in the dams on site, including the contact water dam, will fluctuate seasonally, as high
temperatures and strong sunlight significantly increase evaporation levels during the summer months
and windrow water use increases.
During these months, the dam is likely to become more highly saline. A minimum water level in the
dam is required to comply with CFA regulations and allow enough water in close proximity to the
windrows to extinguish any possible fires. Maintaining a minimum water level in the contact water
dam is also required to prevent it becoming too highly saline, which gives rise to more contamination
potential.
During the summer months, if the Contact Water Dam level drops towards the lowest acceptable
parameter from the table, the liquid application program will be reduced to assist hold the volume
stable to replenish the volume with the next rains and diluting the dam water as required
During winter and spring months, when rainfall is at its highest, the Contact Water Dam must be
monitored for flood risk. The overflow of the dam could result in contamination of the surrounding
soil and groundwater. To safeguard against this, if water approaches the upper bound, water should
be pumped for disposal by application to windrows to ensure the freeboard is maintained.
The oxygen level and pH of the dam will also be monitored monthly but odour is assessed on site daily
and if the contact water is odorous, then the oxygen level will be checked. Oxygen is particularly
important, as low oxygen levels in the dam can result in odour from anaerobic conditions. The Contact
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Water Dam aeration system will run as required to ensure aerobic conditions. The aerator pump
system responsible for maintenance of dissolved oxygen levels also disturbs the surface, preventing
algal blooms and stagnation.
Every year, a sample must be taken from the Contact Water Dam to be fully tested by a NATA
accredited Laboratory. A monthly pH, electrical conductivity and oxygen test will provide an indication
of the concentration of different solutes in the dam water which can be treated if required. The
samples must be taken from at least 30cm below the surface as surface water chemistry may differ
from the rest of the dam. The results of the monthly dam tests must be forwarded to Camperdown
Compost Company’s Site Manager and Operations Manager and filed appropriately.
Force Aerated Open Windrow Processing
During force aerated open windrow processing additional liquid will be added direct during turning
via attached hoses sourced from the process water tank receiving processed waste waters from the
de-watering unit on a daily basis. This is mixed along with water from the contact water dam. Water
in the contact water dam is received from rainwater runoff and settled. This will ensure lower odour
liquid application at turning by adjusting the blend. Water will be applied to range between 50 to 60%
optimum moisture levels within the windrows. The force aerated airfloor and well drained concrete
will evaporate water to atmosphere.
Reapplication of water processed through this system can return nutrients and provide biological
inoculation into the compost product. The application of this water as well as rain water results
inevitably in a degree of leachate from the windrows. Both compost surfaces are inclined at greater
than 2% to facilitate natural drainage towards the leachate collection drain.
Regular turning of the windrows and application of water through the self-propelled turner is an
essential water management and evaporation strategy. It aerates the piles, disturbs any saturated
materials at the base of the windrow and facilitates evaporation of moisture from within the pile. The
turning requirements of the windrows is dependent on continuously monitored temperature and
regularly monitored oxygen, carbon dioxide, methane and moisture level. Turning will be undertaken
as soon as practicable in working hours whenever parameter monitoring dictates.
The expected turn frequency will be managed to minimise odour and to complement the force
aeration. Windrows will require additional turns and force aeration during wetter months or during
periods of high liquid receipts to facilitate evaporation.
Table 7: Turn Frequency Parameters
Parameter Measured Requirements Action
Temperature >55°c If > 70°c Turn
Oxygen >10% If < 10% Aerate or Turn
Carbon Dioxide <8% If > 8% Aerate or Turn
Methane <1% If > 1% Aerate or Turn
Moisture 40-60% Irrigate to 60% Optimum
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Screening
Additional water is not usually applied after the material has been moved from the maturation pad.
Water may be applied as a dust suppressant during windy periods or to reduce the risk of fire during
periods of extreme dry heat. The amount of water added is unlikely to be sufficient to generate
leachate and the product is no longer biologically active at this stage, but the piles will be stored on
the hardstand as a precaution.
5.5 Contact Water Control During Upset Conditions
The force aeration technology to be used provides precise process control but is susceptible to a
number of potential process disturbances. The potential upset conditions that have been identified as
possible for the Camperdown Compost Company facility at Bookaar are identified below and
measures to be taken to control and ameliorate the system in the event of their occurrence outlined.
5.5.1 Overflow
Overflow of the all the dams one of the process upsets which carries the most serious ramifications,
both for the environment and for the facility. Overflow of the dams would mean the transport of the
dissolved chemicals in the water escaping the closed system to the surrounding soil and groundwater.
While all the solutes in the water will be naturally occurring and potentially nutritious for plants,
increasing their concentration beyond natural levels can be toxic to the surroundings. A severe
overflow could result in flood of the windrow maturation pad, resulting in odorous, anaerobic
conditions, though this scenario is extremely unlikely. While the risk of overflow of the dams is a
significant one due to its potential consequence, the likelihood is not high, and this is further
decreased with proper management of the liquids on site.
In the event of dam system overflow, the following steps must be taken for rectification
• The contact water dam must be lowered as far as possible by pumping to windrows for
biological drying and evaporation to create system freeboard
• Water must be immediately pumped from the contact water dam to the windrows for
evaporation to create freeboard capacity in the contact water dam. Water must be pumped
from the dam until the overflow has been controlled or freeboard restored
• Any continent water escape is to be managed so that only the contact water dam overflows
which is least worst option in terms of water quality escaping to the environment.
• Any area flooded will be outlined with physical markers to define the uncontrolled area;
• After the flood water has receded from the flooded area, the soil of the affected area must
be tested in accordance with EPA Publication IWRG702;
• The results must be compared with previous sample results to establish if any unacceptable
contamination has occurred; and
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• Contamination must be remedied appropriately (either with treatment of the affected soil or
removal from the site).
5.5.2 Water Deficit/Drought
Water is used at Camperdown Compost Company for the following:
• Maintaining moisture levels in windrows for optimal composting conditions;
• Cleaning machinery;
• Dust suppression (when required).
The consequences of water shortage are more easily rectified than the consequences of overflow,
however the dam must not reach deficient levels (<2.5ML or one third of its capacity) in order for
Camperdown Compost Company to comply with CFA requirements and prevent the soil beneath the
dam from contamination. If the water level in the contact dam reaches deficit levels the following
measures are to be taken to mitigate:
• Pump water from the process water tank at the liquid receipts processing area into the
contact water dam.
• Increase liquid receipts on a short term basis
Camperdown Compost Company will have water holding system capacity to buffer against drought
and the site enjoys regular rainfall. In the event that the water system is low in during extended
periods of drought, Camperdown Compost Company has the option to seek to an increase its liquid
waste volume receipt to compensate.
5.5.3 Oversupply of Liquid Feedstock or Wet Solid Bulking Agents
During winter months, some solid feedstocks will arrive at Camperdown Compost Company with a
higher than average moisture content. Garden organics can be vulnerable to the effects of wet
weather and moisture variation. Wetter feedstock cannot initially absorb as large volumes of liquid
wastes until they are formed up and the thermophilic process initiates. Moisture monitoring of the
windrows would then dictate less water applied at blending and the first turns to maintain aerobic
conditions. The use of constant force aeration is a valuable tool to assist rapid evaporation of surplus
water from the windrows and can be used as a contingency when managing surplus liquids on site. To
reduce moisture levels at initial blending, dry solids such as finished compost or local straw may be
added as required at blending.
In the event Camperdown Compost Company cannot accept any more liquid feedstocks, deliveries
will be diverted to a liquid processing facility.
5.5.4 pH
Monthly testing of the contact water dam pH will flag conditions where pH above 10 or below 4 will
be adjusted with Alum for alkaline conditions and Lime to correct acidity as required.
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5.5.5 O2
Dissolved oxygen level in the leachate dam is a critical monitoring parameter particularly for the
management of odour. In the event that oxygen levels become too low, the contact dam aerator will
have its timed operation hours increased.
The aerator pump will be subject to regular services to identify the potential for failures before they
occur. However in the event that the aerator fails a simple petrol or diesel portable pump will be used
to fountain water over the dam to effect aeration before the dam becomes anaerobic.
5.5.6 Dissolved Chemicals
The contact water dam is anticipated to have elevated concentrations of a variety of solutes. In the
event that any of these chemicals reaches an unacceptable concentration (as defined by ± 40%
variation in the average of any one parameter as taken from the mean of the 3 previous months’
measurements) remedial actions will be considered as appropriate to the risk. Dilution with fresh
water is the simplest ameliorant.
Sudden increases in the concentration of a particular solute in the leachate dam must be
communicated to the Site Manager and the cause of the spike should be investigated for risk
assessment and management in future. The main risk is elevated sodium from PIW waters processed
on site which may affect the finished product.
Variation in these concentrations is expected seasonally and is not generally a cause for concern.
Monthly testing is important for proper consideration of formula and product quality and
contamination risks or in the event of spill or flood.
5.6.7 Liquid Delivery Spill
Liquids are only to be unloaded directly into the LAP. For this reason, liquid spills are unlikely and
easily managed. In the event that liquid feedstock is spilled, the spillage can be swept into the LAP
and processed as normal.
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6 Dust Management
The generation of dust associated with the operation of the facility has the potential to impact neighbouring residents. This section of the EMP outlines:
• Camperdown Compost Company’s commitment to dust management; and
• Describes the measures to be taken to ensure best practice dust management
6.1 Potential Dust Impacts
Camperdown Compost Company’s Bookaar site is reasonably remote, surrounded by sheep paddocks
in a rural context. Off-site dust impacts are unlikely to be experienced as a result of Camperdown
Compost Company’s operations. However all measures will be taken to ensure dust impacts on-site,
and the potential for those off-site, are minimised. Prolonged exposure to excessive dust can have
adverse health impacts on staff as well as damage machinery. A number of measures will be taken to
manage dust produced at the site and protect staff from dust impacts.
The dust producing aspects of the facility’s operation and the strategies to be taken to minimise these
are given in Table 9.
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Table 8: Dust Sources Inventory
Source Location Process Activity and Material
Responsible Risk Control Measures
Waste delivery
Site roads Trucks driving along road Tyres disturbing the road surface
Low
• Roads will be graded and re-surfaced with gravel
• Regular inspection and re-surfacing of road as required
Receipts Pad Waste reception on receipt pad
Incoming loads of source segregated garden organics and FOGO
Low
• Waste enclosed in delivery vehicles
• Most waste types received by direct delivery
• PPE must be worn by decontaminators
Windrow Composting
Compost Pads
Transfer to windrow pads Blended compost Low • Application of water to 60% optimum
starting moisture will suppress dust
Formation of windrows Blended compost Low • Application of water to 60% optimum
starting moisture will suppress dust
Windrow turning Active compost Low
• Application of water during the turning process will suppress dust generated at turning.
• Windrow turner sealed cabin to protect driver
Maturation Active compost Medium
• Water will not be applied at turning on the maturation pad and dust risk may elevate.
• Turning to be avoided in windy conditions.
Refinement
Screening Pad
Screening of product Mature compost High • Screening during low risk dispersion
conditions
Storage Storage of finished product Mature compost Low • Wetting of piles as required
Dispatch Product dispatch Mature compost Medium • None required.
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6.2 Strategies
6.2.1 Statement of Commitments
The distance to sensitive receptors provides a reasonable buffer for the management of dust dispersal to minimise amenity impacts to the surrounding neighbourhood.
The following practices and procedures will be adopted to ensure that dust levels are adequately controlled:
• Regular cleaning of the concrete and hardstand working areas
• Dust suppression on unsealed surfaces and work areas using a water cart or alternative;
• Minimising traffic movements on exposed areas;
• Minimising heavy vehicle speed within the site; and
• Dampening of stockpiles;
where necessary;
• Cleaning up materials that might act as dust sources, as soon as possible;
• Conducting regular cleaning maintenance of machinery and vehicles;
• Ensuring any procedures for outdoor activities include a requirement for dust minimisation; and
• Providing awareness training through operations meetings and the daily environmental operations checklist in the importance of minimising dust generation at its source.
• Waste unloading of solids on a concrete receipts pad that has water access to dampen dust and wash the surface when required.
• Prompt clean-up of spills as soon as practicable; and
• Dampening of stockpiles.
• Regular inspections of dust emissions from truck movements will be conducted in the early stages of the facility operation to confirm the conclusions of the dust assessment;
• Maintenance of the surface seal of the internal site haulage/access road;
• Enforcing site speed limits for all vehicles, including trucks on site;
• Provision of an adequate water supply for dust suppression;
6.2.1.1 Monitoring Dust monitoring will be in the form of visual checks carried out throughout the day. These checks will
be undertaken by the Site Supervisor responsible for that area of the operation. All staff are required
to report excessive dust events to the Site Manager should they be observed. Operational procedures
are in place to minimise dust generating activities during high risk winds, namely Procedure 4-214
Wind Direction Monitoring & Activity Scheduling.
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6.2.1.2 Reporting All incidents of pollution will be recorded in accordance with Camperdown Compost Company
Procedure 4-303 Complaint Procedure and 4-301 EPA Notification of Breach Procedure and 4-302
Breach of Licence Condition Procedure
6.3 Corrective Action
In the event that the above management strategies are insufficient additional mitigation measures
are to be designed, trialled and implemented.
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7 Odour Management
This section of the EMP demonstrates that Camperdown Compost Company, as the operator of the
Bookaar facility, understands and accepts its responsibilities to manage and control odour produced.
Specifically, it should show:
• That Camperdown Compost Company either directly or through its contractors or
subcontractors will ensure that any odour control equipment is designed, operated and
maintained so that it operates effectively to control odour at all times;
• That Camperdown Compost Company is familiar with the characteristics of the process and
equipment on site and has identified the high risk odour emissions stages of its process;
• How Camperdown Compost Company will reduce or cease operations if necessary to avoid
nuisance odour events;
• How Camperdown Compost Company will engage and communicate with the community to
address their concerns; and
• How Camperdown Compost Company will handle and respond to any complaints received.
7.1 Scope
7.1.1 Operational Phase Odour Management
This section aims to adequately address the following:
• An assessment of the risks of odour problems, from normal and abnormal situations;
• Worst case scenarios, for example of weather, temperature, or breakdowns;
• Accident scenarios;
• The appropriate controls (both physical and management) needed to manage odour risks;
• Suitable monitoring;
• Actions, contingencies and responsibilities when problems arise;
• Regular review of the effectiveness of the odour control measures; and
• Emission limits where appropriate.
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Table 9: Camperdown Compost Company Feedstocks and Associated Odour Risks
Feedstock Type Overall Risk
Level Factors Affecting Odour Risk
GO & FOGO Medium • Seasonal moisture levels
• Summer FOGO rot risk eg seafood
Commercial food waste Medium • Delivery time
• Temperature
• Source and nature of feedstock
Grease trap wastes Medium • Temperature
• Solids Fraction
K100 High • Temperature
• Source & nature of feedstock
K200 High / Medium • Temperature
• Source and nature of feedstock
Drilling muds Low • Blending rate
7.2 Surrounding Uses and Sensitive Receptors
7.2.1 Surrounding Land Uses
The site is located in a farming zone, and surrounding properties are used for crops and sheep grazing.
Camperdown Compost Company’s operational facility is 9 Kms from the centre of Camperdown and
approximately 8 Kms from outlying residential areas who are highly unlikely to experience any odour
from the Camperdown Compost Company.
The property currently experiences and produces odours consistent with the rural nature of the area
on a day-to-day basis. Camperdown Compost Company has documented its Community Engagement
Plan and will engage directly with neighbouring residents to ensure clear and direct communication
and feedback. Four residents have been identified within a 3Km range of the facility for direct contact,
one of whom has complained in the past. The remainder of potential sensitive receptors are
associated with the land lessor or are relatives of the owners of the Camperdown Compost Company.
The nearest sensitive receptor is a farming property and lies 2.4 Km to the north-west of the site.
Red Circle 2100 m, Yellow Circle 2400 m, Blue Circle 3000 m
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7.2.2 Sensitive Receptors
Due to the remote location of the site, there are few sensitive receptors in the region. These receptors are listed in Table 11. Table 10: Odour Sensitive Receptors
Receptor Description Approximate Distance
Sensitivity Direction
R1 1.2 Km Medium (residential, but also an odour producer
itself) SSW
R2 2.4 Km Medium (Residential) E
R3 2.1 Km Low (Residential) ESE
R4 2.5 Km Medium (Residential) E
R5 2.7 Km Low (vacant farm cottage) E
R6 2.7 Km Medium (Residential) E
R7 3.0 Km Medium (Residential) NE
7.3 Potential Off-Site Sources of Odour
Agricultural odours may be reasonably expected to be present in a region of a predominantly rural
nature
7.4 Optimal Weather Conditions
The meteorological conditions to which the site is subjected on a day-to-day basis assist greatly in the
creation of ideal dispersion conditions. The weather conditions are usually the primary determining
factor in whether odour from an emitting site will sufficiently disperse to allow for the site to be
approved for operations. Given that, Camperdown Compost Company’s site at Bookaar has an
extensive buffer, the meteorological profile of the area plays a secondary but significant role in
ensuring no off-site odour impacts are reported. The three fundamental meteorological factors that
influence the generation of odour are:
• Wind Direction and Speed;
• Sunshine; and
• Precipitation.
7.4.1 Wind
Wind is the primary meteorological factor affecting the intensity of odour experienced off-site in
organics processing. Wind passes over the site and picks up odour particles, carrying and distributing
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them along its path. Windier conditions are more favourable for the dispersion of odour while calm
conditions result in odour remaining stagnant and lingering in the immediate vicinity of the source; in
this case, feedstock, and windrows.
For the purposes of this management plan, data from the weather station at Mortlake, Victoria has
been used. Mortlake is the most proximal weather station that has records of wind data, and is located
approximately 33km north east of the Blind Creek Road premises. A directional anemometer is
installed on site to monitor wind for environmental management purposes and logged to computer
for maintenance of site records.
7.4.1.1 Wind Direction The direction from which the wind blows is a significant influence on the ability of the odour of a site
to impinge on surrounding sensitive receptors. In the absence of buildings, wind disperses the odour
in the immediate vicinity opposite the direction from which it has blown.
Direction of wind in this region of Victoria most frequently blows from the North and North West and
South and South West dispersing odour to the South and South East and North and North East of the
site in the immediate vicinity. The greatest risk of wind borne odour travel is to the south of the site
from northerly winds and to the north east from south-westerly winds. The closest sensitive receptor
is to the east and site, where due westerly’s are infrequent. A wind sock on site helps inform operators
of odour risks to neighbours before turning operations are conducted. Turning and other odour
operations are guided and informed by Procedure 4-214 Wind Direction Monitoring & Activity
Scheduling.
9am Wind 3pm Wind
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7.4.1.2 Wind Magnitude The magnitude of force with which wind blows affects the diffusion and dispersal of odour, in that the
faster the wind speed, the better the likelihood of sufficient dispersion. Calm conditions, conversely,
are generally the least favourable for dispersion, allowing for odour to remain stagnant and radially
diffuse from the source at a slower rate, leading to higher concentrations of odorous particles in air.
In this region, calm is experienced only 4% of the time at 9am and 1% of the time at 3pm, indicating
there is almost always sufficient breeze to assist disperse odour. Nearly 25% of wind at 9am is
northerly and usually more than 10Km/pHr and at 3pm the wind is stronger and southerly or south
westerly.
These figures indicate the facility is in a suitable location for a compost operation. The typical
magnitudes of winds are sufficient to enhance odour dispersion and decrease the likelihood it will
affect the nearest sensitive receptors.
7.4.2 Sunshine Exposure
The amount of sun exposure that the site receives also contributes to how well or poorly the odour
from its operations can disperse. Under conditions up to moderate breeze wind speeds earth surface
heating and cooling is the primary factor in dispersion.
Long hours of sunshine contribute to ideal dispersion conditions for odour, minimising the likelihood
that odour will be an issue after the development of the proposed facility. No figures for sunshine are
available from Mortlake however the South West can experience overcast winters and spring in line
with the rainfall requiring more attention to odour management in the winter and spring months No
shadow-casting buildings or vegetation exist in the immediate vicinity of the site, so the maximum
available amount of sunshine at any given time will be able to reach the maturing windrows.
7.4.3 Precipitation
Camperdown is a relatively wet area, receiving an average 762mm per year and excessive precipitation
is a likely contributor to odour nuisance events at the Bookaar site. Being an open facility with force
aerated open windrow technology, Camperdown Compost Company at Bookaar will be somewhat
vulnerable to the effects of precipitation on site but windrows under force aeration treatment are
unlikely to become anaerobic at the base.
Mitigation strategies outlined in this document will be employed in the event of windrows becoming
disproportionately moist and producing anything other than average odour, both in terms of intensity
and character. Precipitation can contribute to odour at composting sites with general surface and road
puddling of contact water producing odours across the whole site which can be managed with good
housekeeping and site cleanliness.
7.5 Identified On-Site Odour Sources
There are number of sources of odour that arise from the Camperdown Compost Company
composting process. The application of best practice management measures would be capable of
minimising and managing odours to an acceptable level. Table 11 provides an inventory of the odour
sourced identifies at the Camperdown Compost Company facility.
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 34 of 56
Table 11: On-Site Odour Sources Inventory
Source Location Process Activity and Material
Responsible Type of
Emission
Likely Compounds
Emitted
Description of Atmosphere
Release Control Measures
Waste delivery
Site Access Waste reception on receipt pad
Incoming loads of source segregated garden organics FOGO and solid K200
Fugitive Fresh feedstock odours
Uncontrolled
• Waste enclosed in delivery vehicles
• Prompt delivery of material and no extended “waiting time” for trucks
Receipts Pad
Spreading, decontamination, and shredding of waste
Disturbance of waste deliveries, exposure to the air for an extended period during decontamination
Fugitive. Potential Spike during shredding
Fresh feedstock odours
Uncontrolled
• Priority processing and windrowing of odorous deliveries
• Rejection of deliveries deemed to be too odorous
LAPs Liquid delivery Loads of K120, K100 & K200
Fugitive Fresh feedstock odours
Uncontrolled
• Immediate de-watering processing
• Prompt blending of solids and residues with chipped solid wastes
• Wash down procedures
Water System
Contact water dam
Water storage Anaerobic conditions Fugitive Anaerobic compounds
Uncontrolled • Aeration of contact water dam
Force Aerated Windrow Processing
Force Aeration Pad
Transfer to windrow pads
Blended feedstock Fugitive Aerobic composting odour
Fugitive emissions as gasses are released from within active material
• Avoid this process in the morning where possible as morning are generally the stillest time of day
Formation of windrows
Active compost Fugitive Aerobic composting odour
Fugitive emissions as gasses are released from
• Use of Procedure 4-214 Wind Direction Monitoring & Activity Scheduling for windrow formation
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Source Location Process Activity and Material
Responsible Type of
Emission
Likely Compounds
Emitted
Description of Atmosphere
Release Control Measures
within active material
• Appropriate blend ratios for odour minimisation
Windrow turning Windrow force aeration
Active compost Fugitive Aerobic composting odour
Fugitive emissions as gasses are released from within active material
• Use of Procedure 4-214 Wind Direction Monitoring & Activity Scheduling for windrow formation and turning during adequate odour dispersion conditions
• Continuous and regular parameter monitoring for optimal force aeration
• Turning frequency increase if required
• Addition of zeolite or finished compost as odour ameliorants if needed
Maturation Active compost Fugitive
Aerobic maturation odour- reduced intensity
Fugitive emissions as product matures
• Dry process reducing moisture through maturity.
• Appropriate blend ratios for effective microbial breakdown
Screening
Screening Pad
Screening of product
Mature compost Fugitive
Mature product “earthy” odour character. Very limited odour
Fugitive emissions from storage piles
• Use of Procedure 4-214 Wind Direction Monitoring & Activity Scheduling
Storage Storage of finished product
Mature compost Fugitive
Mature product “earthy” odour character. Very limited odour
Fugitive emissions from storage piles
• Limits on the volume of mature product which can be stored on-site
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 36 of 61
Source Location Process Activity and Material
Responsible Type of
Emission
Likely Compounds
Emitted
Description of Atmosphere
Release Control Measures
Dispatch Product dispatch
Mature compost Fugitive
Mature product “earthy” odour character. Very limited odour
Fugitive emissions from disturbance of storage piles
• None required.
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7.6 Odour Control during Normal Operations
The application of good working practices and process control is of fundamental importance in
eliminating and minimising the generation of odours formed on site and their subsequent release to
atmosphere. These practices have written into operations procedures to limit activity during a range
of weather and atmospheric conditions experienced under normal operating conditions.
The overall aim in the operation of the facility is to apply best practice at all stages of the waste
treatment processes undertaken on site. For this reason, the facility will be operated and managed in
accordance with the accepted hierarchy of preferred controls, that is:
1. prevent the formation or emission of odorous compounds in the first place;
2. where this is not practicable, minimise the release of odour;
3. abate excessive emissions; then
4. dilute any residual odour by effective dispersion in the atmosphere
5. continuous meteorological monitoring with alarm function for high risk operational activity
7.6.1 Odour Control Strategies
Several control measures have been worked into the design of the facility in order to ensure best
practice odour management for this type of organics recycling process. The measures to be
employed include:
• Continuous temperature monitoring of windrows and SCADA system controlled aeration
• Continuous weather monitoring with Vaisala weather transmitter with pre programmed
alarms for calm and directional wind to identified receptors in mild wind conditions
• Regular monitoring of gases, oxygen, carbon dioxide and methane within the active
windrows to optimise force aeration cycles
• Turning of windrows
• De-watering of higher risk liquid feedstocks;
• Turning and other odour operations are guided and informed by Procedure 4-214 Wind
Direction Monitoring & Activity Scheduling.
In the sections below, the odour control strategies associated with each process step are described.
These strategies will be incorporated into Camperdown Compost Company’s process and are what
Camperdown Compost Company believes to be best practice odour management for a facility of this
size, technology and location.
7.6.2 Waste Acceptance
All incoming deliveries have been risk assessed and pre-approved in accordance with Procedure 4-330
Pre Receipt Feedstock Assessment & Approval and will be inspected and recorded appropriately. EPA
Trade Waste Certificates will be completed where required. Subject to risk analysis, a random
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sampling program operates to ensure the quality and consistency of feedstocks received at the site
using Procedure 4-232 Feedstock Receipts Monitoring and Random Sampling
A major factor affecting the potential for odour emissions at the waste delivery and reception stage is
the content and condition of the feedstock. It is within the site manager’s power to reject any material (e.g. contaminated or odorous wastes that have been stored too long) that will compromise
his or her ability to manage the site and prevent the emission of unacceptable odours.
Specific controls include:
• For general feedstock acceptance, the policy will require all deliveries to conform to the
specifications within the relevant contract; and
• In accordance with Camperdown Compost Company’s Feedstock Management Plan, all
deliveries must be inspected upon receipt to ensure compliance with the above specifications.
Staff will be trained as to the acceptability criteria for incoming loads. Waste will only be accepted if:
a) It conforms to the type and maximum quantity that is specified in Camperdown Compost
Company’s EPA Licence; and
b) It conforms to the description in the current contract. Receipt dockets will be completed for all deliveries received at Camperdown Compost Company and retained on-site.
7.6.3 Unloading of Wastes
As described, wastes received at Camperdown Compost Company’s Bookaar facility will be unloaded in one of two ways. They are:
• Liquid Acceptance Pit; and
• Receipt Pad.
7.6.3.1 Liquid Acceptance Pit Liquids at Camperdown Compost Company will be processed via the Liquid Acceptance Pit. Liquid will
be immediately processed through a de-watering screen with clean irrigation water stored for
application to windrows and solids and residues blended with chipped solid wastes on the receipts
pad. In contingency and during the transition period of the construction schedule, liquid receipts will
be accepted into bunded green waste bulking agent piles and immediately blended and formed into
a pile awaiting windrow formation on the aerated floor.
7.6.3.2 Receipt Pad The garden organics, FOGO, commercial food waste and solid K200 deliveries will be tipped onto the
receipts pad. The newly deposited feedstock is visually inspected by the decontaminators once the
waste is tipped on the floor. Any contaminants are removed and disposed in accordance with
Camperdown Compost Company’s Recycling Policy.
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Temporary storage in reception area The holding time of feedstock material stored prior to processing is a significant factor in a site’s
potential for odour generation. The holding times of the chipped garden organics and FOGO waste
delivered to the facility are to be carefully controlled to minimise uncontrolled decomposition prior
to processing. Piles waiting for windrow formation will be turned by loader or excavator to maintain
an aerobic state during favourable atmospheric conditions. Non-odorous materials will be chipped
and stored on the receipt pads until available for processing. Camperdown Compost Company will not
store material on the receipt pad for longer than 5 days.
• Holding time is limited to five days in order to minimise the potential for odour generation.
In practice, the feedstock will spend less than 3 day prior to being moved the windrow pad.
• Waste will be processed in the order delivered (with the exception of excessively odorous
batches which will be processed as a priority)
Cleaning
Regular scheduled cleaning of the handling equipment such as loaders and excavators used in receipt
areas as well as the roads, the receipt pad itself and drainage channels will discourage odour
generation from remnants of organic materials decomposing. The exact nature of these sweep and
wash procedures will be developed and detailed in separate procedures which will be developed
during the commissioning testing phase of the facility. This section of the document will be updated
once this has taken place.
7.6.5 Force Aerated Windrow Composting
Operation of Plant and Process to Minimise Odour Releases Each windrow will be independently monitored and managed to maximise compost efficiency with
the delivery of oxygen via the air floor as required per the continuous monitoring probes. This will
ensure optimal aerobic conditions to minimise offensive odour emissions.
Contact water and leachate from the process will drain into the collection drains located within the
air floor. This will keep leachate and contact water contained underground, minimising odour from
open drains. The drain connects to the contact water dam
The site’s rural context and appropriate management strategies will suffice in mitigating these odours. Strategies to be employed are:
• Continuous monitoring of temperature of windrows at three different depths driving
computerised automatic force aeration to ensure optimal composting conditions maximise
odour suppressing conditions.
• Regular monitoring of oxygen, carbon dioxide and methane will further inform windrow
management decisions on the effectiveness of temperature driven fans and their correlation
to levels of oxygenation, carbon dioxide and methane
• Turning to break up aerobic clumps and fissures forming to maintain even airflow and
convection within the windrows using the listed parameters to guide the frequency. This will
minimise odorous turning events.
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• Close monitoring of weather forecasts to couple odourous processes (i.e. turning) with
favourable atmospheric conditions for adequate dispersion.
Regular turning of the windrows is an essential odour management strategy used to compliment the
force aerated system by providing regular mixing and agitation to the static windrows. It
simultaneously aerates and irrigates the piles and facilitates evaporation of moisture from within the
pile, while the agitation breaks up any anaerobic clumps preventing the collection of water within the
pores of the pile. The parameters for force aeration and turning activities is listed below. Windrows
will be turned on a minimum weekly cycle and may be turned daily if required in the early stages of
the forced aeration process to minimize odour potential.
Table 12: Turn Frequency Parameters
Parameter Measured Requirements Action
Temperature >55°c If > 70°c Turn
Oxygen >10% If < 10% Aerate or Turn
Carbon Dioxide <8% If > 8% Aerate or Turn
Methane <1% If > 1% Aerate or Turn
Moisture 40-60% Irrigate to 60% Optimum
7.7 Odour Control during Upset Conditions
This section of the document deals with the management and control of odours during unusual or
emergency situations. It outlines the contingency strategies Camperdown Compost Company can
employ during abnormal events and process upsets (including emergencies, maintenance,
breakdowns, extreme weather events, etc.).
A risk assessment approach has been employed in the evaluation of odour control techniques during
maintenance and abnormal events. This approach is designed to:
• identify the location and conditions under which abnormal operational conditions or failures
might arise;
• summarise the potential impact or consequences of the identified abnormal / failure situation
and assesses the degree of those impacts; and
• describe how the conditions could be prevented and/or mitigated and controlled.
• use of the weather station and pre-set alarm for operational activity risks such as windrow
turning.
The majority of abnormal situations can be controlled in some way by good management of the facility
and feedstocks. Solutions to mechanical problems will necessitate the replacement or repair of
component parts. Breakdowns should be minimised, as maintenance of odour critical plant and
equipment will limit such occurrences. Furthermore, the system has been designed with key
redundancies to enable operation of the odour control system even with failures in other parts of the
system. The combination of the aerated floor and self-propelled turners allows the continuation of
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aeration operations and odour minimisation with the breakdown of either aeration option. The
chances of both aeration options simultaneously failing is very small.
Where planned or emergency maintenance of plant items has to be carried out and there is a
likelihood of odour being released to atmosphere, it can be managed so that it is highly unlikely that
this will be in quantities sufficient to result in detection offsite. Camperdown Compost Company’s
location provides some protection that even during periods of maintenance and upset conditions,
odour is unlikely to cause any prolonged disturbance to the community.
This document is to be retained on-site and will be referred to in the event of a process upset which
may cause excess odour generation. Below is summary of the foreseeable situations that may
compromise the operator’s ability to prevent and/or minimise odorous releases from the process and
the actions to be taken to minimise the impact.
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Table 13: Potential Upset Conditions Resulting in Excess Odour
Location of Emission
Circumstance which may lead to excess emission
Consequence Measures in place prevent or
reduce consequence Actions to be taken
Access Route
Delivery of larger volume of feedstock over a short period of time
Excessive material on site generating more odour than usual
• Carefully scheduled deliveries
• Planned major receipt events
• Prioritise batches and process those with potential for odour first
Gradual accumulation of spilt feedstock from delivery vehicles on access route and receipts areas
Uncontrolled breakdown of this residual feedstock, potential odour annoyance
• Covering of delivery vehicles
• Clean up and wash down procedures
• Regular inspection of the access route
• Collection of any feedstock along the route
Receipts Pad
Delivery of unusually odorous feedstock
Fugitive releases of highly odorous emissions
• Initial odour assessment of feedstock
• Training of all staff as to the grounds on which to reject a batch of feedstock
• Rejection of delivery if deemed necessary
• Quick response to blending & forming up into windrows
• Blending with odour reducers such as zeolite or finished compost
• Record odour event on corresponding feedstock receipt form
• Contact client and report odorous delivery
• Identify reason for odorous delivery and implement any prevention measures available for the future
Backlog of solid material becoming malodourous
Uncontrolled breakdown of this residual feedstock, potential odour annoyance
• Delivery schedules properly managed and adhered to
• Deliveries that cannot be processed in a timely manner to be sent to alternate organics recycling facility or landfill
• Cover material with mature compost to act as a bio-filter
• Prioritise Solid K200 and FOGO and for processing over garden organics
• Prioritise blending separated solids and liquid receipts pits residue material
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Location of Emission
Circumstance which may lead to excess emission
Consequence Measures in place prevent or
reduce consequence Actions to be taken
Gradual accumulation of feedstock on pads
Uncontrolled breakdown of this residual feedstock, potential odour annoyance
• Site Manager to make regular assessments of state of receipts pad
• Sweeping of accumulated material and wash down of receipts area
LAP
Delivery of particularly malodorous feedstock
Excessive odour
• Initial inspection of deliveries
• Clear and defined conditions for delivery standard made clear to customers
• Rejection of delivery if deemed necessary
• Record odour event on corresponding feedstock receipt form
• Contact client and report odorous delivery
• Identify reason for odorous delivery and implement any prevention measures available for the future
Delivery of larger than usual volume of feedstock Spill or overflow event
Excessive odour caused by exposure of large liquid surface area to air
• Carefully scheduled deliveries
• Planned major receipt events
• Volume buffer of LAP
• Immediate de-watering process for liquid receipts
• Give a short amount of time for sediment to form (20 mins approx.) and commence pumping liquid layer to storage tanks
• Sweep any overflow into LAP as soon as there is sufficient space
• Hose down spill area, directing run-off into LAP
Gradual accumulation of material in the receipts pit
Uncontrolled breakdown of this residual feedstock, potential odour annoyance
• Weekly inspection of LAP
• Cleaning as required following inspection
• Prioritise blending separated solids and liquid receipts pits residue material
• Clean when required as indicated by regular inspection
• Use appropriate cleaning materials and methods, such as high pressure washer to scrub walls and base of pit area.
Contact Water Dam
Anaerobic conditions Odorous emissions • Aeration of the contact
water • Run aeration system continuously
• Monitor dissolved oxygen
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Location of Emission
Circumstance which may lead to excess emission
Consequence Measures in place prevent or
reduce consequence Actions to be taken
Transfer to Force Aeration Pad
Unfavourable weather conditions (temperature inversion, low wind speed, wind blowing towards nearest sensitive receptor)
Accumulation of odour in the air, potentially detectable at sensitive receptors
• Close monitoring of weather conditions and scheduling accordingly
• Transfer when weather conditions improve, (usually wind picks up in the afternoon)
• 4-214 Wind Direction Monitoring & Activity Scheduling Procedure
Force Aerated Windrow Composting
Over wetting of material before windrow formation
Anaerobic conditions within windrow
• Additional dry feedstock available on site
• Addition of dry feedstock finished compost to absorb excess moisture
• Turn immediately on windrow formation
• Override monitored force aeration and manually run air continuously
Extreme weather events involving excess rain
Anaerobic conditions within windrow
• Monitoring of weather forecast, and modifying irrigation regime when heavy rain is expected
• Override monitored force aeration and manually run air continuously
• Increase turn regime accordingly. & Turn without water application
Hardstand Windrow Maturation
Over wetting of material before windrow formation
Anaerobic conditions within windrow
• Run fans continuously for 24 hours prior to formation on the hardstand
• Turn without water application
• Addition of dry feedstock or finished compost to absorb excess moisture
• Turn immediately on windrow formation
Extreme weather events involving excess rain
Anaerobic conditions within windrow
• Monitoring of weather forecast when heavy rain is expected
• Increase turn regime accordingly.
Batching and Screening
Unusual weather conditions at the site such as extreme temperature inversion
Poor dispersion of earthy odour of mature compost
• Daily checking of weather forecast
• 4-214 Wind Direction Monitoring & Activity Scheduling Procedure
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8 Vegetation Management
Camperdown Compost Company is located at in a rural region of south west Victoria. Camperdown
Compost Company is committed to environmental sustainability, and recognises the important role
the vegetation of the landscape plays in the region.
8.1 Scope
The aims of this section of the Environmental Management Plan are:
• To identify weed species which pose the greatest threat to the region and the Camperdown
Compost Company site;
• To provide weed management strategies.
8.2 Site and Soil Information
The geology of the region is defined by State of Victoria (Agriculture Victoria) soil_landform_units147
updated 31/01/2019 as neogene fluvial and marine sediments and quaternary scoria deposits with
parent material being aeolian deposits and alluvium; clays and silts and soils as neutral and alkaline
black cracking clays which are strongly structured but expansive clay soils, with moderate to rapid site
drainage. High nutrient capacity, calcareous and sodic, particularly at depth.
8.3 Climate
Camperdown experiences climatic conditions consistent with much of Victoria. It is temperate with a
warm summer and cold winters. January and February are the hottest months, when the average
temperature reaches 26.5°c. In winter, the weather becomes coldest in July when the minimum
averages 4.6°c and the maximum gets to 13°c.
Rainfall is seasonal throughout the year, however summer months tend to be the driest and the wettest period is May to October.
Figure 4: Mortlake – Camperdown Average Rainfall mm
010203040506070
Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec
Rai
fall
mm
Mortlake Camperdown Rainfall
Mean Median
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8.4 Weeds
Weeds cost industry millions of dollars each year in lost productivity and have a significant impact on
our customers and the natural environment. In Victoria, there are over one hundred declared noxious
weeds proclaimed under the Catchment and Land Protection Act 1994.
These weeds are classified under four categories: State Prohibited, Regionally Prohibited, Regionally
Controlled and Restricted.
All land managers have a responsibility to manage weeds on their land, irrespective of whether the
land is public or private land.
As a land manager, it is important to be able to identify weeds that may pose a threat to the site,
neighbouring land or customers. Early identification will enable implementation of management plans
that prevent weed establishment or spread.
The responsibility for management of declared noxious weeds varies for each category.
A number of different weed species are problematic at Camperdown Compost Company. The species
which are deemed to pose the largest threat are listed in Table 17. This table is not exhaustive and
other weed species may be present on site or appear on site in future.
8.4.1 Weed Threat
Weeds pose a significant threat to Camperdown Compost Company’s operations. Camperdown
Compost Company produces compost to be applied to agricultural land. The threat of weed
propagules within the compost material must be controlled to prevent the spread of weed species to
the lands to which the compost is applied. Weed species can devastate entire farms, as weed species
compete with crops. Moreover, farms which are organic certified cannot use herbicides to control
weeds and thus must carefully manage the threat using non-chemical methods.
8.4.2 Weed Control Options
Weed propagules are likely to arrive at Camperdown Compost Company daily in kerbside collection
bins and from other garden maintenance services. Weed seeds may also be blown in from the
surrounding area or be brought in attached to any visiting vehicles. Camperdown Compost Company
has a number of control measures in place to manage the risk associated with this aspect of its process.
Camperdown Compost Company seeks to minimise the use of chemical pesticides on site as this may
result in inorganic contamination to feedstock and compost material. The use of glysophate is
acceptable and the property will be periodically sprayed as required to ensure weeds are kept under
control. The alternative weed control measures Camperdown Compost Company will adopt are
outlined below.
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8.4.2.1 Litter Fence Camperdown Compost Company has a litter fence which runs along the perimeter of the site. This
fence plays an important role in managing the spread of weeds off-site. Material which is unloaded
on the receipts pad may be vulnerable to the effects of wind, and blown from the pad. The litter fence
will serve to catch any litter or plant material which is blown from the hardstand, preventing the
potential spread of weed species off-site.
8.4.2.3 Receipts Pad The receipts pad is where all the deliveries are unloaded from delivery trucks and spread for
decontamination. The concrete pad separates the weeds within the delivery from the soil below,
preventing the spread of weeds.
8.4.2.4 Staff Training All Camperdown Compost Company staff will be trained to be proficient at the following:
• Identify problem weed species at Camperdown Compost Company;
• How to remove weeds effectively; and
• How to dispose of weeds appropriately (minimising risk of spread or contamination of finished compost product)
8.4.3 Weed Disposal Procedure
1. Weeds are to be identified by a trained member of staff
2. Weeds to be sprayed as required.
3. Where weeds are to be manually removed. Staff members removing weeds must be wearing
PPE All effort is to be made to ensure the entire root system of the weed is removed during
the removal process (not just the visible section of the plant). For this reason, and to reduce
the risk of back injury, the winged weeder should be used.
4. Removed weeds are to be collected into a weed bucket
5. Contents of weed bucket are to be emptied onto the receipts pad and processed with other
feedstocks. The pasteurisation process ensures weed and seed destruction and renders the
weeds safe.
Under no circumstances is weed material to be added to Camperdown Compost Company’s compost
product at any stage other than at the formation of a new windrow. Weed material added at any other
stage may not be effectively pasteurised and may result in contamination of Camperdown Compost
Company’s product.
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Current 20 July 2017
SCHEDULE 1
State Prohibited Weeds
Common name Scientific name
Alligator weed Alternanthera philoxeroides (Mart.) Griseb.
Bear-skin fescue Festuca gautieri (Hack.) K. Richt.
Black knapweed Centaurea nigra L.
Branched broomrape Orobanche ramosa L.
Camel thorn Alhagi maurorum Medik.
Giant knotweed Fallopia sachalinensis (F. Schmidt ex Maxim) Ronse Decr.
Giraffe thorn Acacia erioloba E. Mey
Hawkweed Hieracium spp.
Horsetail Equisetum L. spp.
Ivy-leafed sida Malvella leprosa (Ortega) Krapov.
Japanese knotweed Fallopia japonica (Houtt.) Ronse Decr.
Japanese knotweed hybrid Fallopia x bohemica (Chrtek & Chrtkova) J.P.Bailey
Karoo thorn Acacia karroo Hayne
Lagarosiphon Lagarosiphon major (Ridl.) Moss
Lobed needle grass Nassella charruana (Arechav.) Barkworth
Marijuana Cannabis sativa L.
Mesquite Prosopis spp.
Mexican feather grass Nassella tenuissima (Trin.) Barkworth
Nodding thistle Carduus nutans L.
Parthenium weed Parthenium hysterophorus L.
Perennial ragweed Ambrosia psilostachya DC.
Poverty weed Iva axillaris Pursh.
Salvinia Salvinia molesta D.S. Mitch.
Tangled hypericum Hypericum triquetrifolium Turra
Water hyacinth Eichhornia crassipes (Mart) Solms
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 49 of 61
SCHEDULE 2
Regionally Prohibited Weeds (P), Regionally Controlled Weeds (C), or Restricted Weeds (R)
Common name Scientific name C
ora
nga
mit
e
East
Gip
psl
and
Gle
nel
g
Go
ulb
urn
Mal
lee
No
rth
Ce
ntr
al
No
rth
Eas
t
Po
rt P
hill
ip a
nd
W
est
ern
po
rt
We
st G
ipp
slan
d
Wim
mer
a
African boxthorn
Lycium ferocissimum Miers C C C C C C C C C C
African daisy Senecio pterophorus DC. P R C P R P P C P P
African feather grass
Pennisetum macrourum Trin. P P C P P P P P P P
African love grass
Eragrostis curvula (Schrad.) Nees C C R C R C C C C R
Amsinckia Amsinckia spp. P C P C R C C C P R
Angled onion Allium triquetrum L. Restricted weed (R) in the whole of the State
Apple of Sodom
Solanum linnaeanum Hepper & P.-M.L. Jaeger R C R R R R P C C R
Arrowhead Sagittaria L. spp. P P P C P C C P P P
Artichoke thistle
Cynara cardunculus L. C R R P C C P C P R
Asparagus fern
Asparagus scandens Thunb. Restricted weed (R) in the whole of the State
Athel pine/ tamarisk
Tamarix aphylla (L.) H. Karst. Restricted weed (R) in the whole of the State
Bathurst burr Xanthium spinosum L. C C C C R C C C C C
Bellyache bush
Jatropha gossypiifolia L. Restricted weed (R) in the whole of the State
Bindweed Convolvulus arvensis L. R P R R R R C C C C
Blackberry Rubus fruticosus L. agg. C C C C R C C C C C
Boneseed/ Bitou bush
Chrysanthemoides monilifera (L.) Norl. C P C C C P P C C C
Bridal creeper Asparagus asparagoides (L.) Druce Restricted weed (R) in the whole of the State
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 50 of 61
SCHEDULE 2
Regionally Prohibited Weeds (P), Regionally Controlled Weeds (C), or Restricted Weeds (R)
Common name Scientific name C
ora
nga
mit
e
East
Gip
psl
and
Gle
nel
g
Go
ulb
urn
Mal
lee
No
rth
Ce
ntr
al
No
rth
Eas
t
Po
rt P
hill
ip a
nd
W
est
ern
po
rt
We
st G
ipp
slan
d
Wim
mer
a
Bridal veil creeper
Asparagus declinatus L. Restricted weed (R) in the whole of the State
Buffalo burr Solanum rostratum Dunal R R R C R R P P R P
Californian/ Perennial thistle
Cirsium arvense (L.) Scop. C C C C R P P C C C
Caltrop Tribulus terrestris L. C R C C R C C P P C
Cape broom Genista monspessulana (L.) L.A.S. Johnson C C R C R R C C C C
Cape tulip (one-leaf)
Moraea flaccida (Sweet) Steud. C C C P P C C C C C
Cape tulip (two-leaf)
Moraea miniata Andrews P P C P P C C C P P
Cat’s claw creeper
Dolichandra unguis-cati (L.) L.G. Lohmann Restricted weed (R) in the whole of the State
Chilean cestrum
Cestrum parqui L'Her. R P R C R R C P P C
Chilean needle grass
Nassella neesiana (Trin. & Rupr.) Barkworth Restricted weed (R) in the whole of the State
Climbing asparagus
Asparagus plumosus Baker Restricted weed (R) in the whole of the State
Devil's claw (purple-flower)
Proboscidea louisianica (Mill.) Thell. R R C C R R C P R R
Devil's claw (yellow-flower)
Proboscidea lutea (Lindl.) Stapf R R C C R R C P R R
Dodder Cuscuta L. spp. R R R C R R C C P P
English broom Cytisus scoparius (L.) Link C P R C R R C C C P
Fennel Foeniculum vulgare Mill. C R R R R R R R R R
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 51 of 61
SCHEDULE 2
Regionally Prohibited Weeds (P), Regionally Controlled Weeds (C), or Restricted Weeds (R)
Common name Scientific name C
ora
nga
mit
e
East
Gip
psl
and
Gle
nel
g
Go
ulb
urn
Mal
lee
No
rth
Ce
ntr
al
No
rth
Eas
t
Po
rt P
hill
ip a
nd
W
est
ern
po
rt
We
st G
ipp
slan
d
Wim
mer
a
Fireweed Senecio madagascariensis Poir. Restricted weed (R) in the whole of the State
Flax-leaved broom
Genista linifolia L. C P R R R R P C C C
Gamba grass Andropogon gayanus Kunth Restricted weed (R) in the whole of the State
Golden thistle Scolymus hispanicus L. C R P C R C P C R R
Gorse/ Furze Ulex europaeus L. C P C C R C C C C C
Great mullein Verbascum thapsus L. R C R C R R C R R R
Ground asparagus
Asparagus aethiopicus L. Restricted weed (R) in the whole of the State
Hardheads/ Russian knapweed
Rhaponticum repens (L.) Hildalgo P R P C C C P P R C
Hawthorn Crataegus monogyna Jacq. R C R C R R C C C C
Hemlock Conium maculatum L. C R R C R R C C C R
Hoary cress Lepidium draba L. C R R C C R P C C R
Horehound Marrubium vulgare L. C C C C R C C C C C
Hymenachne, Olive hymenachne
Hymenachne amplexicaulis (Rudge) Nees
Restricted weed (R) in the whole of the State
Illyrian thistle Onopordum illyricum L. R P R P R C P P R R
Khaki weed Alternanthera pungens Kunth. R P R C R C P P R C
Lantana Lantana camara L. Restricted weed (R) in the whole of the State
Madeira vine Anredera cordifolia (Ten.) Steenis Restricted weed (R) in the whole of the State
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 52 of 61
SCHEDULE 2
Regionally Prohibited Weeds (P), Regionally Controlled Weeds (C), or Restricted Weeds (R)
Common name Scientific name C
ora
nga
mit
e
East
Gip
psl
and
Gle
nel
g
Go
ulb
urn
Mal
lee
No
rth
Ce
ntr
al
No
rth
Eas
t
Po
rt P
hill
ip a
nd
W
est
ern
po
rt
We
st G
ipp
slan
d
Wim
mer
a
Mimosa, giant sensitive plant
Mimosa pigra L. Restricted weed (R) in the whole of the State
Noogoora burr/ Californian burr
Xanthium strumariam L.
P R C C C C C C P P
Opuntioid cacti
Austrocylindropuntia Backeb. spp. Restricted weed (R) in the whole of the State
Opuntioid cacti
Cylindropuntia (Engelm.) F. M. Knuth spp. Restricted weed (R) in the whole of the State
Opuntioid cacti
Opuntia Mill. spp. (except O.aurantiaca Lindl., O. monacantha Haw., O. robusta H.L. Wendl. ex Pfeiff., Opuntia stricta (Haw.) Haw., O. ficus-indica (L.) Mill.)
Restricted weed (R) in the whole of the State
Ornamental asparagus
Asparagus africanus Lam. Restricted weed (R) in the whole of the State
Ox-eye daisy Leucanthemum vulgare Lam. C R R C R R R C C R
Pampas lily-of-the-valley
Salpichroa origanifolia (Lam.) Thell. R P R R R R C C R R
Parkinsonia/ Jerusalem-thorn
Parkinsonia aculeata L. Restricted weed (R) in the whole of the State
Paterson's curse
Echium plantagineum L. C C C C R C C C C C
Pond apple Annona glabra L. Restricted weed (R) in the whole of the State
Prairie ground cherry
Physalis hederifolia A. Gray C R R C C C C C R P
Prickly acacia Acacia nilotica (L.) Delile subsp. indica (Benth.) Brenan
Restricted weed (R) in the whole of the State
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 53 of 61
SCHEDULE 2
Regionally Prohibited Weeds (P), Regionally Controlled Weeds (C), or Restricted Weeds (R)
Common name Scientific name C
ora
nga
mit
e
East
Gip
psl
and
Gle
nel
g
Go
ulb
urn
Mal
lee
No
rth
Ce
ntr
al
No
rth
Eas
t
Po
rt P
hill
ip a
nd
W
est
ern
po
rt
We
st G
ipp
slan
d
Wim
mer
a
Prickly pear (drooping)
Opuntia monacantha Haw. R R R R C C C C P C
Prickly pear (erect)
Opuntia stricta (Haw.) Haw. R R R R C C C C P C
Ragwort Senecio jacobaea L. C C C P R R P C C R
Rubber vine Cryptostegia grandiflora R. Br. Restricted weed (R) in the whole of the State
Saffron thistle Carthamus lanatus L. R C R C R R C C C C
Sand rocket/ Sand mustard
Diplotaxis tenuifolia (L.) DC. R R C R R R R C R R
Scotch/ Heraldic thistle
Onopordum acanthium L. C C C C R P C P C R
Serrated tussock
Nassella trichotoma (Nees.) Hack. ex Arechav. C P P P P P P C C P
Silverleaf nightshade
Solanum elaeagnifolium Cav. C R P C C C C P R C
Skeleton weed Chondrilla juncea L. R R C R R R R P R R
Slender/ Shore thistle
Carduus tenuiflorus Curtis/ C. pycnocephalus L.
R C R R R R C C C R
Soldier thistle Picnomon acarna (L.) Cass. R R R C R P C P R R
Soursob Oxalis pes-caprae L. Restricted weed (R) in the whole of the State
Spear thistle Cirsium vulgare (Savi) Ten. R C R R R R C C C R
Spiny broom Calicotome spinosa (L.) Link C R R R R R P P R C
Spiny burr grass/ Gentle Annie
Cenchrus longispinus (Hack.) Fernald R R P C C C C P R C
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 54 of 61
SCHEDULE 2
Regionally Prohibited Weeds (P), Regionally Controlled Weeds (C), or Restricted Weeds (R)
Common name Scientific name C
ora
nga
mit
e
East
Gip
psl
and
Gle
nel
g
Go
ulb
urn
Mal
lee
No
rth
Ce
ntr
al
No
rth
Eas
t
Po
rt P
hill
ip a
nd
W
est
ern
po
rt
We
st G
ipp
slan
d
Wim
mer
a
Spiny emex Emex australis Steinh. R R R C C R C P R P
Spiny rush Juncus acutus L. R C C C R C C C C C
St Barnaby's thistle
Centaurea solstitialis L. P P P C R R C P P C
St. John's wort Hypericum perforatum L. C C C C R C C C C C
St. Peter's wort
Hypericum tetrapterum Fr. R R R R R R C C R R
Star thistle Centaurea calcitrapa L. R C R R R R C P C R
Stemless thistle
Onopordum acaulon L. R C R R R R C P R R
Stinkwort Dittrichia graveolens (L.) Greuter R R R R R R C C R R
Sweet briar Rosa rubiginosa L. C C C C R C C C C C
Thorn apple (common)
Datura stramonium L. R R C C R C C C C R
Thorn apple (long-spine)
Datura ferox L. R R C C R C C C C R
Thorn apple (recurved)
Datura inoxia Mill. R R C C R C C P P R
Tiger pear Opuntia aurantiaca Lindl. C P P C P P P C C P
Topped lavender
Lavandula stoechas L. R R R R R R C R R R
Tree of heaven
Ailanthus altissima (Mill.) Swingle R C C C R R C C C R
Tufted honeyflower
Melianthus comosus Vahl R R R C R R R C C R
Tutsan Hypericum androsaemum L. R C R C R R C C C R
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 55 of 61
SCHEDULE 2
Regionally Prohibited Weeds (P), Regionally Controlled Weeds (C), or Restricted Weeds (R)
Common name Scientific name C
ora
nga
mit
e
East
Gip
psl
and
Gle
nel
g
Go
ulb
urn
Mal
lee
No
rth
Ce
ntr
al
No
rth
Eas
t
Po
rt P
hill
ip a
nd
W
est
ern
po
rt
We
st G
ipp
slan
d
Wim
mer
a
Variegated thistle
Silybum marianum (L.) J. Gaertn. R C R C R R C C C R
Viper's bugloss
Echium vulgare L. C C C C R R C C C C
Wheel cactus Opuntia robusta H.L. Wendl. ex Pfeiff. R R R R C C C P R C
Wild garlic Allium vineale L. R R R P C C C R R C
Wild mignonette
Reseda luteola L. Restricted weed (R) in the whole of the State
Wild teasel Dipsacus fullonum L. subsp. fullonum R R R R R R C C C R
Wild watsonia Watsonia meriana (L.) Mill. var bulbillifera (J.W. Mathews & L. Bolus) D.A. Cooke
C C R R R R C C C R
Willows Salix spp. (except Salix alba var. caerulea (Sm.) Sm., Salix alba x matsudana, Salix babylonica L., Salix X calodendron Wimm., Salix caprea L. ‘Pendula’, Salix matsudana Koidz ‘Aurea’, Salix matsudana Koidz ‘Tortuosa’., Salix myrsinifolia Salisb., and Salix X reichardtii A. Kern.)
Restricted weed (R) in the whole of the State
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 56 of 56
9 Pest Management
Camperdown Compost Company’s Bookaar site is isolated and located in a rural region. Poorly
managed composting may encourage pests and vermin which can spread plant and animal pathogens,
cause environmental contamination and generate a product of inferior quality. There are some
wildlife species that inhabit the area, mainly snakes but are rarely seen on site because of the amount
of ground vibrating machinery that deters them.
9.1 Scope
The aim of this section of the EMP serves to identify the best practice management strategies and to provide a framework for how these strategies should be implemented. It seeks to outline:
• Pest population control measures to be implemented;
• Strategies for minimisation of the effects of pests on Camperdown Compost Company’s process;
9.2 Pests
Pests are defined as non-native species that are, or have the potential to become, established in the
wild through the landscape to a degree significant enough to have detrimental effects on the
Camperdown Compost Company process. Pests which have been identified as threatening to
Camperdown Compost Company are listed below:
• Foxes;
• Mice;
• Birds;
• Mosquitos;
• Rats; and
• Rabbits;
9.2.1 The Effects of Pests
Vermin, birds and wind can all act as vectors to transport waste, weeds and/or pathogens off site. This
can be a potential risk to the environment, biosecurity, amenity and human health. Many pests such
as mosquitoes and rats, are also vectors, acting as living transmitters of disease. Vectors are a health
hazard to site personnel and neighbouring residents as they are capable of transmitting diseases to
humans, pets and crops.
Staff should be trained to be able to identify indicators of vectors present at the facility, including
tracks, droppings, gnaw marks, and habitats (burrows etc.) in addition to visual sightings of various
pest species. Staff must notify management if pest indicators are observed on-site.
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 57 of 61
9.2.2 Pest Control Measures
The control measures to be used in pest management at Camperdown Compost Company are listed in the table below.
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 58 of 56
Table 13: Pest Management Control Measures
Process Step Risk Control Measures Comment
Receipt of Feedstock High • Receipt of chipped or shredded material
• Immediate processing into thermophilic piles
• Feedstock limited to 3 days on receipts pad
Shredded material reduces obvious pest food items by homogenisation with bulking agents. Direct delivery limits exposure of feedstock and gives pests no access.
Decontamination High
• Direct delivery of high risk feedstock
• Regular cleaning of receipts area concrete
• Processing of commercial food waste as a priority
Food waste is higher risk for vectors and will be processed as a priority over garden organics where possible. Blending into a thermophilic pile very rapidly degrades food items into inedible form.
Force Aerated Windrow Composting
Medium
• Inspection of windrows after turning
• Covering any exposed food scraps with mature compost
• Re-turning the windrow to further physically degrading food particles
Screening and Dispatch Low • Good housekeeping and maintenance of stockpiles By this stage of the process, product will be pasteurised and fully mature, and poses a very low risk for vector transmission
Overall site operation Medium
• Site fencing to prevent vermin entry
• Good housekeeping to maintained at all times
• Regular mowing of grass during summer period
• Careful management and upkeep of vegetation (particularly grass) around site office)
• Record keeping of pest sightings and events
• Baiting
Good housekeeping in everyday operations at the site are essential for pest management. Keeping records of pest sightings and events aids to monitor the efficiency of pest control measures and indicate if additional or alternative measures should be put in place. Baiting, particularly for mice and rats, is essential for the management of snakes as some snake species eat these pests and will be attracted to the site if they are present in large numbers
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 59 of 61
10 Complaint Handling and Document Control
10.1 Complaint Management and Document Control
This section of the Environmental Management Plan provides relevant information on:
• Staffing Responsibilities;
• Staff training;
• Complaint Management; and
• Communication with external stakeholders.
10.1.1 Roles and Responsibilities
Camperdown Compost Company is committed to effective management of the potential for
environmental impacts from its Bookaar facility. This commitment extends from policies made at
management level to the resources available to the staff managing odour critical operations on site.
This section describes the responsibility for the management and operation of the facility.
The company has appointed managers with the executive authority and responsibility for
implementing the Environmental Management Plan. The management odour and implementation of
environmental best practice is a responsibility shared by all members of the Camperdown Compost
team. It is the responsibility of the Operations Manager to ensure that all staff are adhering to
Camperdown Compost Company policy including the Environmental Management Plan.
Any deviances from the policy must be addressed with the staff by the Operations Manager. Any
breaches in environmental requirement including breaches in odour management requirement must
be reported to and promptly addressed by the Site manager to the Operations Manager. The CEO
must maintain good communication with the Environment Protection Authority to prevent nuisance
odour events and swiftly rectify any events which may arise.
More information on the roles and responsibilities of Camperdown Compost Company staff is
available in position descriptions.
10.1.2 Complaints Handling Procedure
Camperdown Compost Company is committed to best practice and believes the design of its Bookaar
facility in combination with the site location and Environmental Management Plan will effectively
manage odour generation at the site to ensure no off-site impacts are experienced. However in the
event that an odour complaint is received, it is essential that complaints are appropriately handled,
documented and acted upon.
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 60 of 61
10.1.2.1 Recording of Complaints Members of the community must be able to contact Camperdown Compost Company with any
environmental complaints about the facility. Community members looking to contact Camperdown
Compost Company can contact staff via the following:
• By phone: 03 5593 3737
• By email [email protected]
This contact information must be made available to the community to ensure facilitate quick and
effective communication of odour or other environmental events.
All complaints must be registered in the Camperdown Compost Company Complaints Register.
Complaint data will be recorded in a systematic way, enabling comparison with standard weather
conditions and other contributing factors.
10.1.2.2 Roles and Responsibilities for Complaint Management The following team members will deal with specific aspects of complaint management:
• The Site Manager or Operations Manager will receive any complaints; and
Wherever possible, the following information should be gathered for each complaint:
• The time and date the event occurred;
• The location the event was observed from;
• The complainants best description of the offence;
• The identity of the complainant; and
• Residential address of complainant.
Following the collection of this information, enquiries should be made as to the
• Wind direction and speed, atmospheric stability at the time of the odour event;
• What processes were being undertaken with what materials at the time;
• Any process interruptions or incidents at the time of the complaint; and
• Any off-site activities taking place in the area at the time.
10.2 Document Control
This document is a controlled document and forms part of Camperdown Compost Company’s
Management System.
This document is intended to be a live document which serves as a reference during day-to-day
operations, and as such would be updated on a more frequent basis should the following occur:
Camperdown Compost Company Pty Ltd Environmental Management Plan Page 61 of 61
• Significant changes to the facility and its operational process;
• Change in the management structure, designation of responsibility of training provision;
• The EPA requests changes to Camperdown Compost Company environmental management
procedures; and
• A significant volume of complaints is received and after subsequent investigation, result in the
identification of further control measures or remedial action, in addition to those set out in
this document.
Camperdown Compost Works Approval Application July 2020
96 | P a g e
Appendix K - Emergency Management Plan
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1. DISTRIBUTION LIST 1. Company Director 2. Site Manager 3. WHS Supervisor 4. Site Admin Manager
2. AMENDMENTS The Workplace Health and Safety Supervisor is the responsible person for amendments to this emergency response plan.
Rev Number
Date By Whom Reason for Amendment
1 14/02/2020 Nathan Hines - HSE Advisor
Update to align with CFA Guideline for the Provision of Emergency Information
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3. GLOSSARY AND ABBREVIATIONS Emergency Situation – means an incident occurring as a result of the Camperdown Compost
Company Pty Ltd activities which is an abnormal and dangerous or potentially dangerous situation that represents immediate danger to life, assets and/or the environment. This situation is deemed outside the sites capabilities to contain.
Emergency Controller – means the site manager until the Country Fire Authority, or Police arrive on scene.
Emergency Response (ER) – means actions required to address all types of emergency situations.
Emergency Response Team – means the Camperdown Compost employees trained in all areas of rescue, firefighting and advanced first aid treatment.
Employee – means an individual who works under the contractor employment, apprenticeship or traineeship with any company working at the site.
PLAN – means Emergency Plan.
Incident – Means a sequence of events that causes actual or potential harm to people or the environment, damage to plant or equipment, actual or potential harm to company reputation or involves non-compliance with legislative requirements or commitments otherwise applicable to our Operations and activities.
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4. INTRODUCTION 4.1. AIM
This emergency response plan describes the appropriate emergency response actions should an emergency situation occur at 445 Sandys Lane, Bookaar.
4.2. OBJECTIVE OF PLAN The objectives of the Emergency Response Plan (ERP) are: Provide Camperdown Compost personnel with an efficient and coordinated emergency
response plan to: Minimise consequences of an emergency situation arising from any aspect of the site
activities; and Protect the health and safety of any employees, contractors, subcontractors, the
community and the company; Work with external emergency organisations in the event of an emergency which could
threaten neighbouring personnel or properties.
4.3. REVIEW OF THE PLAN This plan is reviewed annually or following an audit or incident.
Changes to this plan shall be communicated to all relevant stakeholders as noted in the distribution list above.
Each person receiving a copy of the plan is responsible for ensuring their areas of responsibility are aware of the changes.
4.4. COMPATIBILITY WITH INCIDENT MANAGEMENT PLANS Currently this plan is intended to provide advice to site until combating authorities arrive onsite at this point Camperdown Compost Staff will take direction from the Incident Commander.
APPENDIX G EMERGENCY MANAGEMENT PLAN
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5. INFORMATION ON THE PREMISE AND HAZARDS 5.1. Name, location, address, and nature of operations:
This plan has been prepared for the waste storage and handling facility owned and operated by Camperdown Compost Company Pty Ltd at 445 Sandys Lane, Bookaar Vic. The site accepts a range of wastes including:
Hard Green wastes; Municipal Green wastes; Municipal Food waste from kerbside Food Organics Garden Organics (FOGO) collection; Commercial Food Waste (e.g. from restaurants, catering operations) Animal effluent and residues
including abattoir wastes and other wastes from animal processing; Grease interceptor trap effluent; Food and beverage processing wastes; Car and truck wash waters; Industrial wash waters from cleaning, rinsing or washing operations not otherwise specified; Inert sludges or slurries; Tannery wastes (not containing chromium) and wool scouring wastes; and Category C contaminated soil.
Currently the site uses diesel-powered front-end loaders and one diesel powered self-propelled windrow turner. There is no diesel storage onsite.
The site is approximately 7 Kilometres from the Camperdown Township.
This Emergency Plan (EP) is designed to cover all operations at the site.
The operating hours for the site are 6:00 am to 6:00 pm, Monday to Friday and during normal working hours there are approximately 6 people on the site.
5.2. Detailed map of the facility and surrounding area:
A detailed map of the site and surrounding areas is presented in Appendix A.
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5.3. Inventory of Combustible Recyclable Waste Materials:
The rate at which feedstock is presented to site is not consistent therefore quantities of waste onsite will vary. A weekly inventory of waste will be placed in the Emergency Information Book at the front gate.
Site Name: Camperdown Compost Occupier: Camperdown Compost Company Pty Ltd Address of premises: 445 Sandys Lane, Bookaar Vic Date of preparation: 14/02/2020 Emergency contacts
Name Position Telephone (BH and AH)
Nick Routson (CEO) Chief Executive Officer 0417 148 656
Peter Harlock Operations Manager 0409 734 343 Bray Wright Compost Site Manager 0407 721 291
1. Facility Summary Camperdown Compost operates an open windrow composting operation accepting approximately 35,000 tonnes of material per year (12,500 tonnes of Green Waste and 22,500 tonnes of liquid Prescribed Waste (PIW)). The site has the following operational areas:
Designated acceptance and sorting area; 290,000 Litre tank for the temporary storage of liquid PIW; Aeration floor approximately 100 metres by 65 metres containing underfloor aeration tubes; Self-propelled windrow turner with a hose to apply liquid PIW and water to the windrows; Segregated pasteurisation area; and 7 Megalitre leachate dam for the collection of run-off via hard pipe.
Total Quantity of CRWM at the Premises: 8437 Tonnes
2. CRWM Storage Summary
Name Area Average Tonnes Maximum Tonnes Green Waste Windrow Area A 5148 5148
Windrow Area B 3089 3089
Food Waste Garden Organics Receival Pad 100 200
Liquid Prescribed Industrial Waste (These wastes are not combustible but represent an environmental hazard if released offsite)
Liquid Receival Pit 150 290
Liquid Storage Tank 120 225
3. Operational Details THESE ARE MANAGED VIA RUNSHEETS KEPT AT THE OFFICE AND ELECTRONICALLY 4. Outgoing CRWM
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5.4. Maximum/minimum number of persons expected at the facility: During normal working hours there are approximately 6 people on the site and the number of people on site at any given time ranges from 2 to 10.
5.5. Infrastructure likely to be affected by an incident: In the worst-case scenario (major fire at the facility) a closure of both the Warrnambool-Melbourne Train Line and Princes Highway are possible if the wind during the incident is from the North. If the wind is from the west-Northwest it may be necessary to notify residents of Camperdown to stay indoors. This will only be for the duration of the incident.
5.6. Description of measures in place to control the consequences of hazards for major incidents (e.g. fire barriers, separation distances, drainage tanks):
Hazard Mitigation Measures Ignition of Receipts Stockpile
Daily Checklist inspection Receipts Inspection Stockpile size management Fire Fighting Equipment
Ignition of Pasteurising Windrows
Daily Checklist inspection Continuous Temperature and Moisture monitoring Training in use of Fire Fighting Equipment use (including Fire Drills)
Ignition of Maturing Windrows
Daily Checklist inspection Continuous Temperature and Moisture monitoring Training in use of Fire Fighting Equipment use (including Fire Drills)
Ignition of material in Screening Area
Daily Checklist inspection Moisture monitoring Temperature monitoring Stockpile size management Training in use of Fire Fighting Equipment use (including Fire Drills)
Ignition of material in Aging Stockpile
Daily Checklist inspection Temperature and Moisture monitoring Stockpile size management Training in use of Fire Fighting Equipment use (including Fire Drills)
Machinery Fire Daily Checklist inspection Fire Fighting Equipment
General Site Fire No smoking on site policy Training in use of firefighting equipment (including Fire Drills) Seasonal fuel check & reduction Stockpile Management Procedures Stockpile minimisation
External Fire (e.g bush or grass fire)
Daily Awareness SES APP on all phones Fuel reduction around site Fire Fighting Equipment & Procedures
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6. COMMAND STRUCTURE AND PERSONNEL 6.1. Roles and responsibilities of workers for implementing the plan:
Site Manager or Authorised Delegate OBTAIN all the facts about the incident/situation; DEVELOP actions to address the immediate needs of the Emergency Controller; PROVIDE high level direction to managing any emergency situation; COORDINATE and implement the requirements of this ERP; MINIMISE losses associated with any emergency situation; PROTECT the interests of Camperdown Compost and all other stakeholders associated
with the site. The Camperdown Compost Site Manager is also responsible for anticipating all potential threats during an emergency situation, developing and implementing preventative strategies and planning to minimise their impact if they do occur.
Fire Warden ENSURE that the appropriate emergency services are notified of an incident; INITIATE evacuation of the building/workplace; BRIEF emergency services when they arrive then acting on their instructions; BEING AVAILABLE, or organising warden cover, at all times when the site is occupied COMMUNICATE to all personnel information for use in an emergency, including details of the fire
alarm system, the emergency warning system and the emergency procedure. DISPLAY evacuation procedures and plans for the site; TRAINING, or organising the training of staff in emergency procedures
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7. RESPONSE ACTIONS 7.1. Evacuation Routes
Evacuation route maps have been posted in each work area. The following information is marked on the Site Layout Plan:
Emergency exits Evacuation routes Locations of fire extinguishers Isolation Points for Electricity and Water (there is no gas connected) Assembly point
Site personnel should know at least two evacuation routes. The call to evacuate will be given via the air horn and by voice. Site Personnel are accounted for when evacuating via logging all names on the “Evacuated Personnel Sheet” in Appendix B NOTE: PERSONNEL UNACCOUNTED FOR MUST BE COMMUNICATED IMMEDIATELY TO EMERGENCY SERVICES UPON THEIR ARRIVAL
7.2. Initial Emergency Resources The Site has the following resources to combat emergency incidents:
Fire Extinguishers Spill Kits First Aid Kit
7.3. Raising the Alarm
Once an emergency situation has been identified the most senior person on site at the time must first raise the alarm using the air horn. They will then immediately notify the relevant authorities via 000 stating:
Their name and contact details; Location of the pollution incident/emergency; Nature of the pollution incident/emergency; and Details of any assistance required.
Following this the neighbouring businesses must be warned as soon as reasonably practicable.
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7.4. TERMINATING AN EMERGENCY Generally, the Incident Commander from CFA or the Police will terminate the emergency situation. In this event it will be deemed safe for clean-up crews to commence once a Safe Work Method Statement or Job Hazard Analysis has been completed. NOTE: The termination of an emergency does not indicate that the site is clear to recommence operations.
7.5. SAFETY EQUIPMENT The following are the locations of safety equipment:
Fire Extinguisher On all mobile plant, Workshop, and Main Office Fire Water Tank 2 x 275,000L Tanks
Adjacent to aeration pumphouse; and South side of Workshop.
Back Up Firewater Leachate Dam can provide up to 5.4 ML Fire Fighting Equipment Two Hydrants adjacent to Spill Kit Workshop PPE PPE Store at Workshop SDS’S Office First Aid Kit On all mobile plant, Workshop, and Main Office Safety Signage A site Entrance and Entrance to operational area
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8. NOTIFICATIONS AND REPORTING An incident must be notified immediately to the relevant authorities if any of the following triggered:
Trigger Authority
CFA Worksafe EPA Victoria Police The site is unable to control incident X There is an actual or potential Injury/exposure onsite or offsite X
There is actual or potential damage to property onsite or offsite X X
Potential for escalation of incident X Potential of environmental damage X
In the event of a pollution incident Camperdown Compost will telephone to advise community stakeholders of the incident with recommended actions to prevent or minimise harm such as closing doors and windows, evacuate buildings or premises, not to drink or swim in water courses, etc.
IMMEDIATE NOTIFICATION
CAMPERDOWN COMPOST STAFF CONTACTS Nick Routson (CEO) 0417 148 656
FIRST AID OFFICERS Courtney Lenehan Bray Wright
0417 337 740 0407 721 291
Safety/Fire Warden - Office Peter Harlock
0409 734 343
Safety/Fire Warden - Compost Site Bray Wright
0407 721 291
APPROPRIATE REGULATORY AUTHORITIES Fire, Police, Ambulance 000 Environment Protection Authority (EPA) 1300 372 842 Worksafe Vic (Emergency Number) 13 23 60 Department of Health and Human Services 1300 650 172 Powercor (24hr) 132 412 Southern Rural Water 1300 139 510
EARLY WARNING AS SOON AS REASONABLY PRACTICABLE
Corangamite Shire Council 5593 7100
Telstra 132 203
Local Residents (Number in Princes Highway Office) SITE CLEAN UP Veolia (24hr) 0407 307418
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9. TYPES OF EMERGENCIES 9.1. MEDICAL
Call medical emergency phone number 000 Provide the following information:
a) Nature of medical emergency; b) Location of the emergency (address); and c) Your name and phone number from which you are calling.
Do not move victim unless absolutely necessary. Call the following personnel trained in CPR and First Aid to provide the required assistance prior to the arrival of the professional medical help:
Current First Aid/CPR Officers
Courtney Lenehan 0417 337 740 Bray Wright 0407 721 291
Hospital South West Health Care, 9 Robertson St Camperdown
5593 7300
Poisons Information Centre
131 126
If personnel trained in First Aid are not available, as a minimum, attempt to provide the following assistance:
Stop the bleeding with firm pressure on the wounds (note: avoid contact with blood or other bodily fluids).
Clear the air passages in case of choking. In case of rendering assistance to personnel exposed to hazardous materials, consult the Safety
Data Sheet (SDS) and wear the appropriate personal protective equipment. Attempt first aid ONLY if trained and qualified.
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9.2. FIRE When fire is discovered notify the site personnel about the fire emergency by Voice or via the Air Horn. FIGHT THE FIRE ONLY IF:
The fire is small and is not spreading to other areas; and The fire extinguisher is in working condition and personnel are trained to use it.
NOTIFY THE SITE MANAGER who will then call 000 and follow the notification protocol in Section 8. All building occupants must:
EVACUATE using the designated escape routes. ASSEMBLE in the designated assembly area at the front fence. REMAIN outside until the Site Manager announces that it is safe to re-enter.
Emergency Coordinator (Site Manager or most Senior Person onsite) must:
DISCONNECT utilities and equipment unless doing so jeopardises safety. COORDINATE an orderly evacuation of personnel. PERFORM an accurate head count of personnel reported to the designated area and fill in the
“Evacuated Personnel Sheet”. DETERMINE a rescue method to locate missing personnel and inform the CFA if any personnel
are unaccounted for. Provide the CFA personnel with the necessary information about the facility including location of
the Chemical Manifest on the outside of the front fence opposite the HAZCHEM sign.
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9.3. BOMB THREAT Evacuate building as soon as possible. INSTRUCTIONS: BE CALM, BE COURTEOUS. LISTEN. DO NOT INTERRUPT THE CALLER. YOUR NAME: _________________________ TIME: ____________ DATE: ________________ CALLER'S IDENTITY SEX: Male ____ Female ____ Adult ____ Juvenile ____ APPROXIMATE AGE: _____ ORIGIN OF CALL: Local __________ Long Distance ___________ Telephone Booth __________
VOICE CHARACTERISTICS
SPEECH
LANGUAGE
___ Loud ___ High Pitch ___ Raspy ___Intoxicated
___ Soft ___ Deep ___ Pleasant ___ Other
___ Fast ___ Distinct ___ Stutter ___ Slurred
___ Slow ___ Distorted ___ Nasal ___ Other
___ Excellent ___ Fair ___ Foul
___ Good ___ Poor ___ Other
ACCENT
MANNER
BACKGROUND NOISES
___ Local ___ Foreign Possible Race ___________
___ Not Local ___ Region
___ Calm ___ Rational ___ Coherent ___ Deliberate ___ Righteous
___ Angry ___ Irrational ___ Incoherent ___ Emotional ___ Laughing
___ Factory ___ Machines ___ Music ___ Office ___ Machines ___ Street ___ Traffic
___ Trains ___ Animals ___ Quiet ___ Voices ___ Planes ___ Party ___ Atmosphere
PRETEND YOU ARE HAVING DIFFICULTY HEARING - KEEP CALLER TALKING - IF CALLER SEEMS AGREEABLE TO FURTHER CONVERSATION, ASK QUESTIONS LIKE:
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When will it go off? Certain Hour ____ Time Remaining Where is it located? Building Area What kind of bomb? ___________________ What kind of package? ____________ How do you know so much about the bomb? What is your name and address?
If building is occupied, inform caller that detonation could cause injury or death. Call Police on 000 and relay information about call. Did the caller appear familiar with plant or building (by his/her description of the bomb location)? Write out the message in its entirety and any other comments on a separate sheet of paper and
attach to this checklist. Notify the site manager immediately. If necessary, EVACUATE using the designated escape routes. ASSEMBLE in the designated assembly area at the front fence. REMAIN outside until the Site Manager announces that it is safe to re-enter.
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9.4. SEVERE WEATHER AND NATURAL DISASTERS Severe Storm, Flood or Bush fire:
If indoors: Be ready to evacuate as directed by the Emergency Coordinator. Follow the recommended primary or secondary evacuation routes.
If outdoors:
Climb to high ground and stay there. Avoid walking or driving through flood water. If car stalls, abandon it immediately and climb to a higher ground.
If necessary, EVACUATE using the designated escape routes. ASSEMBLE in the designated assembly area at the front fence. REMAIN outside until the Site Manager announces that it is safe to re-enter.
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10. ADMINISTRATION OF PLAN 10.1. TRAINING
A toolbox talk outlining the key components on the Plan are presented to all Camperdown Compost staff and contractors. The objective of training is to ensure all staff and contractors are aware of the key steps to manage a pollution incident. If a pollution incident occurs refresher training will be delivered to staff and contractors.
10.2. TESTING OF PLAN 10.2.1. Routine Testing
The Plan will be tested every twelve months. The testing of the Plan is to be carried out in such a manner as to ensure that the information included in the plan is accurate and up to date, and that each plan is capable of being implemented in a workable and effective manner. Testing will involve undertaking desktop simulations of incidents and completing exercises or drills. Testing covers all the components of the Plan, including the effectiveness of training.
10.2.2. Following an emergency incident Plans must also be tested within three months of any emergency incident occurring to assess, whether the information included in the plan is accurate and up to date, and the plan is still capable of being implemented in a workable and effective manner.
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APPENDIX A - SITE LAYOUT PLAN AND LOCATION MAP
Evacuation Routes
Electricity Shut off
APPENDIX G FIRE AND EMERGENCY MANAGEMENT PLAN
APPENDIX B EVACUATED PERSONNEL SHEET
PERSONNEL ONSITE NAME POSITION
OFFSITE PERSONNEL NOTIFIED
Camperdown Compost Works Approval Application July 2020
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Appendix L – Fire Risk Assessment and Management Procedure
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Appendix F – Fire Risk Assessment and Management
PROCEDURE 4-311
Fire Risk Assessment Register & Control Plan
18th February 2019
Fire Risk Assessment Well-developed and well-communicated fire risk management ensures all stakeholders (including staff) at WRRF are aware of the fire hazards, the associated risk and controls implemented to reduce the risk of harm to human health and the environment from fire. There are three important elements to understand to implement this fire risk management framework:
1. Hazard is something that has the potential to cause harm or detriment to people or the environment.
2. Risk is the possibility of harm that could happen as a result of an event. The level of risk is influenced by two factors, consequence and likelihood: • Consequence is an outcome or impact of an event. • Likelihood is the probability of that outcome occurring.
3. A control is something which eliminates or reduces a hazard or risk. This includes equipment, work processes or monitoring systems.
Description
BACKGROUND Licence condition LI_WM4 of EPA licence number 13415 states “You must ensure that waste does not burn at the premises” Camperdown Compost Company stores and processes organic material and wood and therefore must meet the guideline, Management and storage of combustible recyclable and waste materials 1667-2 PURPOSE To meet the Company’s Fire Prevention Policy this risk assessment must be performed regularly and discussed at tool box and management meetings to ensure it is updated every two years. To prevent fire in waste stockpiles and product in process on site the Camperdown Compost Company has implemented a range of company procedures including this fire risk assessment, total fire ban policy, stockpile management and windrow management procedures which will require update or improvement to ensure the risk of fire is minimised and controls are in place to extinguish any fire occurring on the facility.
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The matrix below will be used to assign quantitative values to the likelihood of occurrence of
a particular fire risk and the consequence expected. The product of these two values
corresponds to a risk rating defined below.
Tables 1, 2 and 3 below describe the risk assessment criteria for this report.
Table 1: Likelihood Scale
Exposure Description Frequency
5 - Almost certain
Event will occur on a regular basis Several times a year or more often
4 - Likely Event has occurred several times on-site already
Several times per year
3 - Possible Event might occur on-site in the foreseeable future
Once every year
2 - Unlikely Event has occurred on other sites at some time
Once every 1 - 10 years
1 - Extremely Unlikely
Event may have occurred on another site Once every 10 - 100 years
Table 2: Consequence Scale
Severity Impact
5 – Severe Major long term damage, extending the spread of fire beyond company boundary and affecting the property and lives of the community
4 – Major Major short term effect extending the spread of fire beyond company boundary and affecting the property and lives of the community
3 – Moderate Impact largely confined to company boundary, addressed/cleaned-up by site staff or contractors
2 – Minor Impact confined to part of company boundary, addressed/cleaned-up by staff
1 - Negligible Contained to limited area of site, rapid clean-up/management
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Table 3: Risk Matrix
Likelihood
Consequence
Insignificant (1) Minor (2) Moderate (3) Extensive (4) Severe (5)
Almost certain (5)
5 10 15 20 25
Likely (4) 4 8 12 16 20
Possible (3) 3 6 9 12 15
Unlikely (2) 2 4 6 8 10
Extremely Unlikely (1)
1 2 3 4 5
Risk Assessment Scores
20-25 Emergency, unacceptable risk
10-19 High risk, senior management attention must be given
8-9 Implementation of strategies for regular monitoring by management
3-7 Monitor and implement control measures
1-2 Manageable by routine procedures
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Key Risk Factors and Advice
EPA Management and storage of combustible recyclable and waste materials – guideline
Particle Size
Temperature and Moisture level of Organic Stockpiles
Food organics and garden organics (FOGO) decompose through microbial and chemical
action, which can generate considerable heat. They will spontaneously combust when the
heat generated is higher than that lost to the surrounding environment.
Allowing a pile to get to an internal temperature of over 90 °C can trigger rapid self-heating
and eventual combustion. FOGO undergoing composting typically ignite between 150 °C and
200 °C.
Moisture content will also influence spontaneous combustion - low moisture levels will stop
biological activity (stopping self-heating), and high moisture levels will allow for evaporative
cooling of the pile. To reduce the risk of spontaneous combustion, organics storage (i.e. any
FOGO not being otherwise actively managed) should be kept below 70 °C and moisture
content should be maintained at either less than 20% OR more than 45% (Rynk, 2000).
Piles or windrows should not be opened up with machinery or turned in case of fire.
If smouldering fires are detected in CRWM storage (organic or otherwise), the introduction of oxygen (e.g. through turning the pile) may cause flames to develop. Suitable firefighting equipment should be set up and ready for use at the scene if turning combustible recycled waste matrial (CRWM) that is self-heating, or that you suspect is already smouldering.
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Sustainability Victoria - Guide to Biological Recovery of Organics 2018
Other factors which contribute to spontaneous combustion include:
• Pockets of dry material
• Significant proportions of bark, soil and leaves
• Large piles, which trap heat due to low surface area to volume ratio
• Limited pile aeration (to allow heat to escape) due to highly compacted material
• Prolonged storage of undisturbed piles, which enables excessive heat accumulation
To minimise fire risk:
• Smaller piles are preferred
• Prolonged storage of unprocessed organics should be avoided and stockpiles should be turned occasionally to provide ventilation
• Separation should be provided between piles to stop fires spreading and allow access for fire-fighting equipment
• Regular monitoring and inspection procedures should also be in place including testing the pile internal temperatures and moisture levels, and looking for signs of smouldering (hot gases, smoke).
It should be noted that steam arising from compost piles is normal but may be mistaken for smoke by members of the public so this should be considered in community engagement activities and communications.
Organics stockpiles are also prone to ignition from other sources including arson, lightning, discarded cigarettes, hot ashes in incoming loads, and heat or sparks from plant and equipment. Operational procedures and security measures (see below) should be designed to mitigate these risks.
Organics processing facilities should have plant and facilities on site to combat fires which may include:
• Fire hoses, hydrants, extinguishers and / or high capacity pumps
• Sufficient storage of fire-fighting water (tanks or ponds)
• Mobile plant to move and isolate burning material (e.g. front end loader or excavator)
• Staff trained safely respond to and contain a fire in its early stages
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Hazard Potential Causes
Initial Risk
Controls
Implemented
Post-control risk analysis
Control
Checks
Further Controls or Actions
Actions
Likelihood
Consequence
Likelihood
Consequence
Due Date
Completion Date
Receipts Stockpile
• Self-Combustion
• Ignition from external source
• Smouldering or high risk on arrival
Possible Major
• Daily Checklist inspection
• Receipts Inspection
• Stockpile size management
• Fire Fighting Equipment
Unlikely Moderat
e
• Visual Checks
Pasteurising Windrows
• Self-Combustion
• Ignition from external source
Unlikely Moderate
• Daily Checklist inspection
• Moisture monitoring
• Temperature monitoring
• Fire Fighting Equipment
Extremely
Unlikely Minor
• Temperature logs
• Moisture tests
Maturing Windrows
• Self-Combustion
• Ignition from external source
Possible Moderate
• Daily Checklist inspection
• Moisture monitoring
• Temperature monitoring
• Fire Fighting Equipment
Unlikely Minor
• Temperature logs
• Moisture tests
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Hazard Potential Causes
Initial Risk
Controls
Implemented
Post-control risk analysis
Control
Checks
Further Controls or Actions
Actions
Likelihood
Consequence
Rating Likeli
hood
Consequence
Due Date
Completion Date
Screening Area • Self-Combustion
• Ignition from external source
Likely Major
• Daily Checklist inspection
• Moisture monitoring
• Temperature monitoring
• Stockpile size management
• Fire Fighting Equipment
Possible Moderate
• Temperature logs
• Moisture tests
Aging Stockpile • Self-Combustion
• Ignition from external source
Likely Major
• Daily Checklist inspection
• Moisture monitoring
• Temperature monitoring
• Stockpile size management
• Fire Fighting equipment
Possible Moderat
e
• Temperature logs
• Moisture tests
Machinery
• Self-Combustion
• Oil / fuel fire
• Sparks from grinders/welders
Possible Moderate
• Daily Checklist
inspection
• Fire Fighting Equipment
Unlikely Minor
• Daily Site checklist
•
General Site • Smoking Risk
• Ability to fight a fire outbreak
Unlikely Moderate
• No smoking on site
policy Unlikely Minor
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Hazard Potential Causes
Initial Risk
Controls
Implemented
Post-control risk analysis
Control
Checks
Further Controls or Actions
Actions
Likeli
hood
Consequences
Likeli
hood
Consequences
Due Date
Completion Date
General Site • Fuel reduction on site
• Stockpiles
• Training fire fighting equipment & procedures
• Loader, Excavators Electric pump Seasonal fuel check & reduction
• Stockpile Management Procedures
• Stockpile minimisation
• Daily Operational checklist
External Fire • Bushfire spread
• Lightning strike Possible Extreme
• Daily Awareness SES APP on all phones
• Fuel reduction surrounding site
• Fire Fighting Equipment & Procedures
Unlikely Major
• Daily SES App check
• Total fire ban check
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POLICY 4-102
Fire Prevention Policy Thursday 14th February 2019
Performance outcomes for assessing the risk from fire
• Identifying all possible fire hazards and their potential causes at your site.
• Assessing the risks to human health and the environment from identified hazards.
• Meeting these outcomes involves:
• Ensuring that our documented hazard list is comprehensive and new hazards are added as they are identified.
• Understanding why the fire risks exists.
• Assessing the fire risks with consideration of the consequence and likelihood of the identified fire hazards.
Performance outcomes for controlling fire hazards and risk
• Identify appropriate controls to minimise the risk of harm from fire.
• Describe how the controls will be implemented and continuously improved.
Description
BACKGROUND Licence condition LI_WM4 of EPA licence number 13415 states “You must ensure that waste does not burn at the premises” Camperdown Compost Company stores and processes organic material and wood and therefore must meet the guideline, Management and storage of combustible recyclable and waste materials 1667-2 PURPOSE To prevent fire in waste stockpiles and product in process on site by following a range of company procedures including fire risk assessment, total fire ban policy, stockpile management and windrow management procedures
PROCEDURES ASSOCIATED WITH THIS POLICY WILL
• Outline a process for fire risk assessment
• Identify controls to prevent and mitigate fires at Camperdown Compost Company
• Sets out Combustible Recycled Waste Materials storage guidance
• Outline emergency management plan requirements for fires at Camperdown Compost
Company
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• Describe how controls will be checked for their effectiveness, any actions to improve your site’s risk management and how this process will be verified.
• Meeting these outcomes involves:
• Choosing and implementing controls based on their effectiveness in managing hazards and risks, practicality and feasibility.
• Assessing and documenting effectiveness of your selected controls.
• Re-evaluating the consequence and likelihood of the identified fire hazards, with consideration of how the implementation of controls are reducing the initial risk and what the remaining residual risk would be.
• Documenting implemented controls, measures of effectiveness and how these will be checked.
Performance outcomes for effective storage management
Arrange CRWM in a manner that
• Facilitates safe and efficient evacuation of occupants.
• Allows emergency vehicle access in and around the site.
• Allows emergency responder access to fire protection systems and equipment.
• Allows effective and safe fire-fighting operations.
• Limits the potential for fire spread between piles, to buildings or surrounding premises.
Meeting these outcomes involves
• Providing information on the site to the emergency services (e.g. inventory, location of storage).
• Ensuring site access points (including any rear access) are evident and unobstructed.
• Separation between piles, buildings, non-CRWM and surrounding premises.
• Separation between piles and other hazards onsite (e.g. hot works).
• Management of pile dimensions (heights, widths and lengths).
Nick Routson CEO Camperdown Compost Company
Updated by: Date: Next Review date:
Peter Harlock 14/02/2019 14/02/2019
Camperdown Compost Works Approval Application July 2020
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Appendix M – Correspondence to surrounding residences
7
Proposed Site Upgrade
Information Package
August 2019
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Camperdown Compost Company Pty Ltd Introduction
Camperdown Compost is applying to Corangamite Shire Council and EPA Victoria to upgrade our compost site located on Blind Creek Road, Gnotuk
This information package is being delivered to residents within three kilometres (or a bit more) of the compost site
Why are we upgrading?
We currently blend a mix of organic wastes with excavators in large rows. The current system is not considered best practice, as it is difficult to keep oxygen in the windrows at all times. A lack of oxygen can lead to odour production, and increase the time taken to make compost. Aerobic = with oxygen Anaerobic = without oxygen
We need to upgrade to a system that ensures aerobic conditions at all times.
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What are we upgrading to?
We have spent over five years looking at the options for upgrading our compost site. We have settled on a large aerated concrete slab, with smaller windrows turned with a compost turner. Each windrow has a remote temperature sensor. The temperature sensor continually sends information to a computer system. The computer system turns on a large electric blower, that will supply oxygen to the row as required.
Concrete tubes will be buried Air tubes under the concrete will run back to fans. In the concrete slab.
Odour Reduction
Research conducted by Compost-Systems in Austria shows a significant reduction in odour associated with adding aeration to the composting process.
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Is this proven technology? Yes. The site upgrade has been designed by compost-systems in Austria. It is similar to over thirty sites currently in operation around the world in places such as Austria, Poland, Germany, Greece, Italy, and South America. Compost-Systems has recently designed and built a 300,000t compost facility for the city of Mumbai in India. Although similar to other facilities, this upgrade has been designed specifically for our location and inputs. Bernhard Gamerith, part owner and senior engineer at Compost-Systems has spent a number of days at our facility understanding the local issues we face. Please see their website for more information about Compost-Systems.
http://www.compost-systems.com
Is the site getting bigger? The area on which we make compost is not getting bigger. However, we wish to make the site around 30 metres wider, and 40 metres longer. This is an increase of around 45%. The extra area is to allow trucks to turn around more safely off the road, and to add trees around the perimeter of the site.
Do we want to take more waste? We do want to increase the amount of waste we want to take. Not a lot, and not until we are sure the new system is working properly.
Who would build it? Subject to Council and EPA approval, we propose to engage Greencon in Cobden to build the facility upgrade. Wherever possible, we will use local tradespeople and contractors.
Who are our customers? We receive green organics (from green bins), from The City of Greater Geelong, Colac Otway Shire, Warrnambool City Council, and Glenelg Shire. We receive food waste from industry including Saputo, Fonterra, Bulla, and others.
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Do we employ locals? All of our full-time employees live in, or close to, Camperdown. Wherever possible, we try to spend money as close to home as possible. That does not however give us the right to run a non-compliant business, or cause annoyance to our neighbours.
Timelines
We propose to submit an application to both Corangamite Shire Council and EPA Victoria in mid-August. The EPA application, called a “Works Approval” will be able to be seen on the EPA website from around this date. We assume the Planning Permit will be able to be viewed via the Council website.
Information Session We propose to hold an information session in Camperdown some time in late August or early September. This will be advertised, but we will ensure that we make residents close to the compost site aware of this date.
More Information
If you would like more information about what we are proposing, we would suggest one of the following:
• We can come to your house and answer any questions you have.
• You can come to our office, 4915 Princes Highway, Camperdown, and we can show you through the plans and answer any questions you have.
• After a suitable induction, we can show you around the site and explain why we need to upgrade our site.
Please call or text us if you want us to catch up and discuss further
NICK ROUTSON PETER HARLOCK CEO OPERATIONS MANAGER 0417 148 656 0409 734 348
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Proposed Site Layout
13
Proposed Site Layout – Truck Access
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Facility Design
15
Community Update
15th May 2020
In August 2019, we sent out an information package about our proposed site upgrade. This is an
update on what has happened since then.
The aim of this upgrade is to allow us to improve the compost making process, while reducing any
impact we may create on our neighbours.
Works on site
Over summer, with the approval of the EPA and Corangamite Shire, we have been making repairs to
the surface of our existing site.
Odour Assessment
EPA recommended we perform an assessment studying Odour, Dust and Bio Aerosols potentially
coming from our site. We engaged GHD to carry out a comprehensive study, producing a 47‐page
report. A copy of this report is available for anyone in the community if requested. Please contact
the feedback line shown below.
Resubmission of Works Approval and Planning Permit
We plan to resubmit an updated Works Approval with the EPA and an updated Planning Permit with
the shire in the next two weeks. The main changes to our application are as follows:
Clarification of tonnes received (See below)
More details regarding biosecurity, odour and the composting process.
Details of a similar facility (reference facility)
A community feedback number and email
Tonnes Received
In 2019 we were made aware that some compost facilities in Victoria were calculating tonnes
received on a percent solids basis, that is, the liquid component was not calculated in the tonnes
received figure. The reason for this is the composting process uses a lot of water.
Our original works approval application of 35,000 tonnes was based on the above calculation
method. For the purposes of clarity and consistency, we have reverted to including all wastes
including liquids in our calculations.
Our new application is for 50,000 tonnes per annum. For the last two years, our average receivals
have been around 42,000 tonnes. We report our receivals monthly to the EPA.
Reference Facility
Our facility has been designed by Compost‐Systems in Austria. They have built over 50 facilities
around the world. They would be able to log onto our system and assist us with any problems that
we are having. The facility they have built that is closest to what we are proposing is near
Wieselburg in Austria, called Seiringer Umweltservice, (see photo below)
This facility processes 25,000 tonnes per annum of wastes similar to what we take. The facility is
outdoors and uses the exact same technology that we are proposing. There are over 4,000 residents
within a 2lkm radius.
Community Feedback
We have set up a community feedback phone number and email. We encourage you to contact us
with any feedback you may have in relation to our site, whether it be odour or any general
information you require. This is not designed to discourage you from calling the EPA on 1300 372
842. If not answered immediately, we will monitor messages and respond to them accordingly. We
have included a fridge magnet with the details for your convenience. This number and email are:
0499 933 737 (Please no texts)
Please contact me with any questions you may have.
_________________________ Nick Routson CEO Camperdown Compost
01/06/2020
Request for Feedback
In a previous community update we mentioned that part of our site upgrade was to do repairs on a
section of the site floor. This section has now been completed to EPA specifications and we are now
in a position to use it.
We propose to put out material and process it using our Komptech compost turner. This is a change
from our current process, and as such has the potential to cause odour.
If and when our site upgrade is completed, our turner will be used on top of an aeration system that
will continuously add oxygen to the windrows to reduce odour. At this stage, we propose using the
compost turner without the aeration system.
After working on the compost site for a number of hours, it becomes more difficult to be aware of
odours coming from the site. That is why we are asking for your help.
If you notice odour, or have any questions please ring the feedback line 0499 933 737 (no texts
please) or email [email protected] and let us know and we will change our
process accordingly.
We are making this change because we believe it represents an improvement on our current
practices, and we will be monitoring these changes as best we can.
Thanks for reading this
Nick Routson
CEO Camperdown Compost Company
Camperdown Compost Works Approval Application July 2020
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Appendix N – Letters of Support
PO BOX 82 Level 1, 284 Bellerine Street SOUTH GEELONG VIC 3220 BELMONT VIC 3216 117 Brown Street HAMILTON VIC 3300
Phone: 03 5223 2622 Email: [email protected]
Website: www.bswwrrg.vic.gov.au ABN: 73 398 361 474
8 January 2018 To whom it may concern
RE: CAMPERDOWN COMPOST COMPANY FACILITY UPGRADE PLAN:
RESOURCE RECOVERY INFRASTRUCTURE FUND – INFRASTRUCTURE GRANTS
On behalf of the Barwon South West Waste and Resource Recovery Group (BSWWRRG), I am pleased to write a letter
of support for the Camperdown Compost Company’s Resource Recovery Infrastructure Fund – Infrastructure Grants
application.
BSWWRRG acknowledge their professionalism and dedication to promoting sustainable practices and taking a pro-
active role to innovate and deliver continuous improvement. Camperdown Compost continues to be an organics
recovery industry leader in the Barwon South West region and beyond. They are willing to liaise and work with key
stakeholders in improve their business and community relationships.
BSWWRRG has utmost confidence in Camperdown Compost Company’s ability to deliver the project outcomes
required, especially in implementing new and innovative technology. Their staff have considerable experience,
knowledge and qualifications in the development and delivery of environmental and sustainable infrastructure and
operations.
This site and businesses would benefit greatly from a positive result under this grant program. This program would
dramatically improve the capacity to recover organic material from community, industry and agriculture.
The Barwon South West region continues to work with business to lead resource recovery infrastructure enhancement
and be more sustainable with the ultimate result to divert waste from landfill and recover more resources.
BSWWRRG looks forward to a positive outcome for Camperdown Compost Company and working with them in the
future on a range of resource recovery initiatives.
Yours faithfully,
Ashley Pittard Executive Officer
Camperdown Compost Works Approval Application July 2020
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Appendix O – Financial Assurance Calculation
Waste code Unit disposal cost Storage Amount (in m3 or T) Total
M100 or M260 $20,000.00 $0.00
Calculating a Consumer Price Index (CPI) adjustment for the financial assurance:
The following formula is used when calculating the financial assurance subsequent to 2015: N = E x
(1+(A‐B/B))
Where:
M110 $10,000.00 $0.00 E= $79,000.00 E is the financial assurance calculated in 2015 dollars
D120 or D121 $3,000.00 $0.00 A= 112.3 A is the CPI number for the previous December quarter of the year that the calcuation is being performed
G130, G150 or M220 $2,000.00 $0.00 B= 108.3 B is the CPI for the December quarter of 2015
A100 $1,500.00 $0.00
H100, H110, H160 $1,500.00 $0.00
$0.00 N= $81,917.82 N is the updated financial assurance calculation
$0.00
Table 2: $0.00
Waste code Unit disposal cost Storage Amount
J codes and T130 $500.00 50 $25,000.00
L codes $250.00 50 $12,500.00
K codes $100.00 415 $41,500.00
$0.00
$0.00
Table 3: $0.00
Waste code Unit disposal cost Storage Amount
N100 (if waste stored in containers) $20.00 $0.00
N100 (per kg) $2.00 $0.00
N105 (if waste is stored in containers) $50.00 $0.00
N105 (per kg) $1.00 $0.00
$0.00
$0.00
Table 4: $0.00
Waste code Unit disposal cost Storage Amount
N119 $800.00 $0.00
N120 $450.00 $0.00
N121 $180.00 $0.00
$0.00
$0.00
Default rate $0.00 5148Waste code Unit disposal cost Storage Amount 3089Any other waste code $1,000.00 $0.00 200
Grand Total $79,000.00
Total Storage Capcity for PIW (Tonnes) 515
Acceptance Pit 290
Process Water Tank 225
CPI calculation