Answer all 1 This question is about Period 3 elements and ...

2

9701/22/F/M/16© UCLES 2016

Answer all the questions in the spaces provided.

1 This question is about Period 3 elements and their compounds.

(a) Give an explanation for each of the following statements.

(i) The atomic radius decreases across Period 3 (Na to Ar).

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(ii) The first ionisation energy of sulfur is lower than that of phosphorus.

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(iii) Sodium is a better electrical conductor than phosphorus.

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(iv) Magnesium is a better electrical conductor than sodium.

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9701/22/F/M/18© UCLES 2018


1 (a) �The�graph�shows�a�sketch�of� the�first� ionisation�energies�of�six�successive�elements� in� the�Periodic�Table.

� �The�letters�are�not�the�symbols�of�the�elements.

firstionisation

energy

A B C Delement

E F

(i) �Explain�what�is�meant�by�the�term�first ionisation energy.

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(ii)� �Suggest�why�the�first�ionisation�energy�of�B�is�much�less�than�that�of�A.

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(b) P–T�are�successive�elements�in�Period�3�of�the�Periodic�Table.

� �The�letters�are�not�the�symbols�of�the�elements.

� �On�the�axes,�sketch�a�graph�to�show�the�trend�in�the�atomic�radius�of�the�elements�P–T.

� �Explain�your�answer.

atomic radiusof the element

P Q Relement

S T

� explanation� ................................................................................................................................

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� [Total:�9]

5


2 The elements in Group 17 of the Periodic Table are called the halogens. They form stable compounds with both metals and non-metals.

The table gives some data about F2, HCl and CaF2.

F2 HCl CaF2

boiling point / K 85 188 2773

relative formula mass 38.0 36.5 78.1

(a) (i) State what is meant by the term relative formula mass.

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(ii) F2 and HCl are both covalent molecules.

Suggest why the boiling point of HCl is higher than that of F2.

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(iii) Explain why CaF2 has a very high boiling point.

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(iv) CaF2(aq)canbemadebythereactionofcalciumcarbonatewithhydrofluoricacid,HF(aq).

Write an equation for this reaction. Include state symbols.

....................................................................................................................................... [2]

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9701/22/F/M/19© UCLES 2019

(b) (i) Completetheelectronicconfigurationofachlorideion.

1s2 ................................................................................................................................. [1]

(ii) When Cl 2 is passed over hot iron, FeCl 3 is formed.

However, when I2(g) is passed over hot iron, the following reaction occurs.

Fe(s) + I2(g) FeI2(s)

State what you would observe during the reaction between Fe and I2. Explain why FeI2(s) is formed rather than FeI3(s).

observation .........................................................................................................................

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explanation .........................................................................................................................

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............................................................................................................................................. [2]

(iii) FeI2 is soluble in water.

AstudentcarriesoutachemicaltesttoconfirmthatasolutionofFeI2 contains aqueous iodide ions, I–(aq). The student adds a single reagent and a precipitate forms.

Identify the reagent the student uses. State the colour of the precipitate that forms.

reagent ...............................................................................................................................

colour of precipitate ............................................................................................................ [2]

(iv) Compounds containing I– are often contaminated by bromide ions, Br –.

Identify a further reagent that the student could use to show that the precipitate formed in (iii) contained iodide ions.

....................................................................................................................................... [1]

7


(c) HOFistheonlyknownmoleculethatcontainsonlytheelementshydrogen,oxygenandfluorine.

(i) Draw a ‘dot-and-cross’ diagram to represent the bonding in a molecule of HOF.

Show the outer shell electrons only.

[2]

(ii) HOF can be made by the reaction of F2 with ice at – 40 °C. The reaction is similar to the reaction of Cl 2 with cold water.

Suggest an equation for the reaction of F2 with ice.

....................................................................................................................................... [1]

(iii) HOF is an unstable compound and decomposes to form HF and O2.

HOF→HF+12 O2 ΔH = –139 kJ mol–1

Draw a fully labelled reaction pathway diagram on the axes provided to show the decomposition of HOF into HF and O2.

enthalpy

progress of reaction [2]

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9701/22/F/M/19© UCLES 2019

(iv) Pure HF is a colourless liquid at 273 K. The liquid contains HF molecules that have strong hydrogen bonds between them.

Draw a fully labelled diagram to suggest how a hydrogen bond can form between two HF molecules.

[3]

(d) Interhalogen compounds, such as BrCl or IF5, contain two or more different halogen atoms that are covalently bonded.

Disaninterhalogencompoundthatcontainsonlychlorineandfluorine.

At 0 °C and 101 325 Pa, 1 dm3 of D has a mass of 4.13 g.

(i) Use the general gas equation to calculate the relative molecular mass, Mr, of D.

Mr = .............................. [3]

(ii) Use your answer to (i) to determine the molecular formula of D.

If you were unable to calculate the Mr in (i), assume that the Mr is 130.5. This is not the correct value.

molecular formula of D = .............................. [1]

[Total: 25]

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9701/2/M/J/02

1 Sir James Jeans, who was a great populariser of science, once described an atom of carbonas being like six bees buzzing around a space the size of a football stadium.

(a) (i) Suggest what were represented by the six bees in this description.

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(ii) Explain (in terms of an atom of carbon) what stopped the bees from flying awayfrom the space of the football stadium.

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(iii) What is missing from Jeans’ description when applied to an atom of carbon?

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(b) The diagram below represents the energy levels of the orbitals in atoms of the secondperiod, lithium to neon.

(i) Label the energy levels to indicate the principal quantum number and the type oforbital at each energy level.

(ii) In the space below, sketch the shapes of the two types of orbital.

ener

gy

nucleus

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(iii) Complete the electron configurations of nitrogen and oxygen on the energy leveldiagrams below, using arrows to represent electrons.

(iv) Explain, with reference to your answer to (iii), the relative values of the firstionisation energies of nitrogen and oxygen. The values are given in the DataBooklet and should be quoted in your answer.

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(c) (i) State the formulae of the negatively charged ions formed by these elements insimple binary compounds (nitrides and oxides).

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(ii) Why do nitrogen and oxygen form negative ions, but not positive ions, in simplebinary compounds?

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[Total : 11]

nitrogen oxygen

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© UCLES 2004

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9701/02/M/J/04 [Turn over

2 Compounds of phosphorus have many uses in everyday life, e.g. fertilisers, matches and in watersofteners.

(a) State the full electronic configuration of phosphorus.

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(b) Phosphoric acid, H3PO4, is used in the manufacture of phosphate fertilisers.

Deduce the oxidation number of phosphorus in H3PO4.

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(c) The salt sodium phosphate, Na3PO4, is a water-softening agent.

(i) Write the equation for the complete neutralisation of phosphoric acid with aqueoussodium hydroxide.

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Sodium phosphate was prepared from 50.0 cm3 of 0.500 mol dm–3 H3PO4 and an excess ofaqueous sodium hydroxide.

(ii) How many moles of H3PO4 were used?

(iii) Use your equation in (c)(i) to calculate how many moles of sodium hydroxide arerequired.

[3]

(d) Phosphorus sulphide, P4S3, is used in small amounts in the tip of a match. On striking amatch, this compound burns.

(i) Construct an equation for this reaction.

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(ii) Both oxides formed in (i) dissolve in water to give acidic solutions. Construct an equationfor the reaction of each oxide with water.

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[Total : 9]

6

9701/02/M/J/07© UCLES 2007

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3 This question is about the elements in Group II of the Periodic Table, magnesium to barium.

(a) Complete the table below to show the electronic configuration of calcium atoms and of strontium ions, Sr2+.

1s 2s 2p 3s 3p 3d 4s 4p 4d

Ca 2 2 6

Sr2+ 2 2 6

[2] (b) Explain the following observations.

(i) The atomic radii of Group II elements increase down the Group.

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(ii) The strontium ion is smaller than the strontium atom.

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(iii) The first ionisation energies of the elements of Group II decrease with increasing proton number.

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9701/02/M/J/07© UCLES 2007

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(c) Samples of magnesium and calcium are placed separately in cold water and left for some time. In each case, describe what you would see and write a balanced equation for each reaction.

(i) magnesium

observation ...............................................................................................................

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equation ................................................................................................................... (ii) calcium

observation ...............................................................................................................

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equation ...................................................................................................................[6]

(d) Strontium nitrate, Sr(NO3)2 undergoes thermal decomposition.

(i) State one observation you would make during this reaction.

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(ii) Write a balanced equation for this reaction.

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[Total: 16]

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9701/02/M/J/08© UCLES 2008

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2 The Periodic Table we currently use is derived directly from that proposed by Mendeleev in 1869 after he had noticed patterns in the chemical properties of the elements he had studied.

The diagram below shows the first ionisation energies of the first 18 elements of the Periodic Table as we know it today.

2500He

H

Ne

Li Na

Ar

2000

1500

1000

500

2 4 6 8 101 3 5 7 12 14 179proton number

firstionisation

energy/kJ mol-1

11 13 15 16 180

(a) Give the equation, including state symbols, for the first ionisation energy of fluorine.

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(b) Explain why there is a general increase in first ionisation energies from sodium to argon.

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(c) (i) Explain why the first ionisation energy of aluminium is less than that of magnesium.

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9701/02/M/J/08© UCLES 2008 [Turn over

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(ii) Explain why the first ionisation energy of sulphur is less than that of phosphorus.

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The table below refers to the elements sodium to sulphur and is incomplete.

element Na Mg Al Si P S

melting point high

conductivity high

(d) (i) Complete the ‘melting point’ row by using only the words ‘high’ or ‘low’.

(ii) Complete the ‘conductivity’ row by using only the words ‘high’, ‘moderate’ or ‘low’. [5]

(e) When Mendeleev published his Periodic Table, the elements helium, neon and argon were not included.

Suggest a reason for this.

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...................................................................................................................................... [1]

[Total: 15]

2

9701/21/M/J/09© UCLES 2009

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1 Copper and titanium are each used with aluminium to make alloys which are light, strong and resistant to corrosion.

Aluminium, Al, is in the third period of the Periodic Table; copper and titanium are both transition elements.

(a) Complete the electronic configuration of aluminium and of titanium, proton number 22.

Al 1s2

Ti 1s2

[1]

Aluminium reacts with chlorine.

(b) (i) Outline how, starting from aluminium powder, this reaction could be carried out in a school or college laboratory to give a small sample of aluminium chloride. A diagram is not necessary.

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(ii) Describe what you would see during this reaction.

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(iii) At low temperatures, aluminium chloride vapour has the formula Al2Cl6. Draw a ‘dot-and-cross’ diagram to show the bonding in Al2Cl6. Show outer electrons only. Represent the aluminium electrons by . Represent the chlorine electrons by x.

[6]

3


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Copper forms two chlorides, CuCl and CuCl2.

(c) When copper is reacted directly with chlorine, only CuCl2 is formed. Suggest an explanation for this observation.

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..................................................................................................................................... [1]

Titanium also reacts with chlorine.

(d) When an excess of chlorine was reacted with 0.72 g of titanium, 2.85 g of a chloride A was formed.

(i) Calculate the amount, in moles, of titanium used.

(ii) Calculate the amount, in moles, of chlorine atoms that reacted.

(iii) Hence, determine the empirical formula of A.

(iv) Construct a balanced equation for the reaction between titanium and chlorine.

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(e) At room temperature, the chloride of titanium, A, is a liquid which does not conduct electricity.

What does this information suggest about the bonding and structure in A?

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[Total: 14]

2

9701/22/M/J/09© UCLES 2009

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1 Copper and titanium are each used with aluminium to make alloys which are light, strong and resistant to corrosion.

Aluminium, Al, is in the third period of the Periodic Table; copper and titanium are both transition elements.

(a) Complete the electronic configuration of aluminium and of titanium, proton number 22.

Al 1s2

Ti 1s2

[1]

Aluminium reacts with chlorine.

(b) (i) Outline how, starting from aluminium powder, this reaction could be carried out in a school or college laboratory to give a small sample of aluminium chloride. A diagram is not necessary.

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(ii) Describe what you would see during this reaction.

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(iii) At low temperatures, aluminium chloride vapour has the formula Al2Cl6. Draw a ‘dot-and-cross’ diagram to show the bonding in Al2Cl6. Show outer electrons only. Represent the aluminium electrons by . Represent the chlorine electrons by x.

[6]

3


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Copper forms two chlorides, CuCl and CuCl2.

(c) When copper is reacted directly with chlorine, only CuCl2 is formed. Suggest an explanation for this observation.

..........................................................................................................................................

..................................................................................................................................... [1]

Titanium also reacts with chlorine.

(d) When an excess of chlorine was reacted with 0.72 g of titanium, 2.85 g of a chloride A was formed.

(i) Calculate the amount, in moles, of titanium used.

(ii) Calculate the amount, in moles, of chlorine atoms that reacted.

(iii) Hence, determine the empirical formula of A.

(iv) Construct a balanced equation for the reaction between titanium and chlorine.

.................................................................................................................................. [4]

(e) At room temperature, the chloride of titanium, A, is a liquid which does not conduct electricity.

What does this information suggest about the bonding and structure in A?

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[Total: 14]

9701/22/M/J/10© UCLES 2010

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1 In the 19th and 20th centuries, experimental results showed scientists that atoms consist of a positive, heavy nucleus which is surrounded by electrons.

Then in the 20th century, theoretical scientists explained how electrons are arranged in

orbitals around atoms.

(a) The diagram below represents the energy levels of the orbitals present in atoms of the second period (Li to Ne).

(i) Label the energy levels to indicate the principal quantum number and the type of orbital at each energy level.

ener

gy

(ii) On the axes below, draw a sketch diagram of one of each different type (shape) of orbital that is occupied by the electrons in a second-period element.

Label each type.

zy

x

zy

x

2

3


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(iii) Complete the electronic configurations of nitrogen atoms and oxygen atoms on the energy level diagrams below.

Use arrows to represent electrons.

ener

gyen

ergy

nitrogen

oxygen [6]

(b) (i) Use the Data Booklet to state the value of the first ionisation energy of nitrogen and of oxygen.

N ............................... kJ mol–1 O ............................... kJ mol–1

(ii) Explain, with reference to your answer to (a)(iii), the relative values of these two ionisation energies.

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[Total: 9]

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9701/23/M/J/10© UCLES 2010

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2 The alkali metals are a series of six elements in Group I of the Periodic Table. The first ionisation energy of these elements shows a marked trend as the Group is descended.

(a) Define the term first ionisation energy.

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(b) (i) State and explain the trend in first ionisation energy as Group I is descended.

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(ii) Suggest how this trend helps to explain the increase in the reactivity of the elements as the Group is descended.

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(c) In a redox reaction, 0.83 g of lithium reacted with water to form 0.50 dm3 of aqueous lithium hydroxide.

2Li(s) + 2H2O(l) 2LiOH(aq) + H2(g)

(i) Calculate the amount, in moles, of lithium that reacted.

5


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(ii) Calculate the volume of hydrogen produced at room temperature and pressure.

(iii) Calculate the concentration, in mol dm–3, of the LiOH(aq) formed.

[5]

(d) When heated in chlorine, all of the alkali metals react to form the corresponding chloride.

Describe what you see when sodium is heated in chlorine and write a balanced equation for the reaction.

description

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equation

.......................................................................................................................................... [2]

[Total: 12]

2

9701/21/M/J/14© UCLES 2014


1 (a) Explain what is meant by the term ionisation energy.

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(b) The fi rst seven ionisation energies of an element, A, in kJ mol–1, are

1012 1903 2912 4957 6274 21 269 25 398.

(i) State the group of the Periodic Table to which A is most likely to belong. Explain your answer.

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(ii) Complete the electronic confi guration of the element in Period 2 that is in the same group as A.

1s2 ................................................................................................................................. [1]

(c) Another element, Z, in the same period of the Periodic Table as A, reacts with chlorine to form a compound with empirical formula ZCl 2. The percentage composition by mass of ZCl 2is Z, 31.13; Cl , 68.87.

(i) Defi ne the term relative atomic mass.

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....................................................................................................................................... [2]

(ii) Calculate the relative atomic mass, Ar, of Z. Give your answer to three signifi cant fi gures.

Ar of Z = ....................... [2]

3


(d) The chlorides of elements in Period 3 of the Periodic Table show different behaviours on addition to water, depending on their structure and bonding.

(i) Write equations to show the behaviour of sodium chloride, NaCl , and silicon chloride, SiCl 4 , when separately added to an excess of water.

NaCl ...................................................................................................................................

SiCl 4 ...................................................................................................................................[2]

(ii) State and explain the differences in behaviour of these two chlorides when added to water, in terms of their structure and the bonding found in the compounds.

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(e) Sulfur reacts with fl uorine to form SF6. State the shape and bond angle of SF6.

shape of SF6 ..............................................................................................................................

bond angle of SF6 ......................................................................................................................[2]

[Total: 18]

2

9701/22/M/J/14© UCLES 2014


1 (a) Explain what is meant by the term nucleon number.

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.............................................................................................................................................. [1]

(b) Bromine exists naturally as a mixture of two stable isotopes, 79Br and 81Br, with relative isotopic masses of 78.92 and 80.92 respectively.

(i) Defi ne the term relative isotopic mass.

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....................................................................................................................................... [2]

(ii) Using the relative atomic mass of bromine, 79.90, calculate the relative isotopic abundances of 79Br and 81Br.

[3]

(c) Bromine reacts with the element A to form a compound with empirical formula ABr3. The percentage composition by mass of ABr3 is A, 4.31; Br, 95.69.

Calculate the relative atomic mass, Ar, of A. Give your answer to three signifi cant fi gures.

Ar of A = ....................... [3]

3


(d) The elements in Period 3 of the Periodic Table show different behaviours in their reactions with oxygen.

(i) Describe what you would see when separate samples of magnesium and sulfur are reacted with oxygen.

Write an equation for each reaction.

magnesium

.............................................................................................................................................

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sulfur

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.............................................................................................................................................[4]

(ii) Write equations for the reactions of aluminium oxide, Al 2O3, with

sodium hydroxide,

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hydrochloric acid.

.............................................................................................................................................[2]

(e) Phosphorus reacts with chlorine to form PCl 5.

State the shape of and two different bond angles in a molecule of PCl 5.

shape of PCl 5 ............................................................................................................................

bond angles in PCl 5 ............................ ............................[2]

[Total: 17]

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3 The elements in Period 3 of the Periodic Table show variations in their behaviour across the period.

(a) The bar chart below shows the variation of melting points of the elements across Period 3.

Na Mg Si P S ArAl Cl

18001600140012001000800600400200

0

meltingpoint / K

In each of the following parts of this question you should clearly identify the interactions involved and, where appropriate, explain their relative magnitudes.

(i) Explain the general increase in melting point from Na to Al.

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(ii) Explain the variation of melting points from P to Ar.

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(iii) Explain why Si has a much higher melting point than any of the other elements in the period.

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....................................................................................................................................... [1]

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9701/22/M/J/14© UCLES 2014

(b) The graph below shows the variation of the fi rst ionisation energies across Period 3.

Na Mg Si P S ArAl Cl

first ionisationenergy / kJ mol–1

1600

1400

1200

1000

800

600

400

200

0

(i) Explain why the fi rst ionisation energy of Ar is greater than that of Cl.

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....................................................................................................................................... [1]

(ii) Explain why the fi rst ionisation energy of Al is less than that of Mg.

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....................................................................................................................................... [1]

(iii) Explain why the fi rst ionisation energy of S is less than that of P.

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....................................................................................................................................... [1]

[Total: 10]

2

9701/21/M/J/15© UCLES 2015


1 (a) Chemists recognise that atoms are made of three types of particle.

Complete the following table with their names and properties.

name of particle relative mass relative charge

0

1/1836

[3]

(b) The relative atomic mass of an element can be determined using data from its mass spectrum.

The mass spectrum of element X is shown, with the percentage abundance of each isotope labelled.

73 74 75 76 77 78m / e

79 80 81 82 83

60

50

40

30

20

10

0

percentageabundance

0.89

9.37 7.63 8.73

23.77

49.61

(i) Defi ne the terms relative atomic mass and isotope.

relative atomic mass ...........................................................................................................

.............................................................................................................................................

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isotope ................................................................................................................................

.............................................................................................................................................[3]

3


(ii) Use the data in the mass spectrum to calculate the relative atomic mass, Ar, of X. Give your answer to two decimal places and suggest the identity of X.

Ar of X ....................................

identity of X ....................................[2]

(c) The element tellurium, Te, reacts with chlorine to form a single solid product, with a relative formula mass of 270. The product contains 52.6% chlorine by mass.

(i) Calculate the molecular formula of this chloride.

molecular formula .................................... [3]

(ii) This chloride melts at 224 °C and reacts vigorously with water.

State the type of bonding and structure present in this chloride and explain your reasoning.

.............................................................................................................................................

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....................................................................................................................................... [2]

(iii) Suggest an equation for the reaction of this chloride with water.

....................................................................................................................................... [1]

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9701/21/M/J/15© UCLES 2015

(d) Sodium and silicon also react directly with chlorine to produce the chlorides shown.

chloride meltingpoint / °C

difference between the electronegativities of the elements

NaCl 801 2.2

SiCl 4 –69 1.3

(i) Describe what you would see during the reaction between sodium and chlorine.

.............................................................................................................................................

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....................................................................................................................................... [2]

(ii) Explain the differences between the melting points of these two chlorides in terms of their structure and bonding. You should refer to the difference between the electronegativities of the elements in your answer.

NaCl structure and bonding ...............................................................................................

.............................................................................................................................................

SiCl 4 structure and bonding ................................................................................................

.............................................................................................................................................

explanation .........................................................................................................................

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....................................................................................................................................... [4]

[Total: 20]

2

9701/22/M/J/15© UCLES 2015


1 (a) Chemists recognise that atoms are made of three types of particle.

Complete the following table with their names and properties.

name of particle relative mass relative charge

+1

1/1836

[3]

(b) Most elements exist naturally as a mixture of isotopes, each with their own relative isotopic mass. The mass spectrum of an element reveals the abundances of these isotopes, which can be used to calculate the relative atomic mass of the element.

Magnesium has three stable isotopes. Information about two of these isotopes is given.

isotope relativeisotopic mass

percentageabundance

24Mg 24.0 79.0

26Mg 26.0 11.0

(i) Defi ne the term relative isotopic mass.

.............................................................................................................................................

.............................................................................................................................................

....................................................................................................................................... [2]

(ii) The relative atomic mass of magnesium is 24.3.

Calculate the percentage abundance and hence the relative isotopic mass of the third isotope of magnesium. Give your answer to three signifi cant fi gures

percentage abundance = .................................

isotopic mass = .................................[3]

3


(c) Magnesium can be produced by electrolysis of magnesium chloride in a molten mixture of salts.

(i) Give equations for the anode and cathode reactions during the electrolysis of molten magnesium chloride, MgCl 2.

anode ..................................................................................................................................

cathode ...............................................................................................................................[2]

The electrolysis is carried out under an atmosphere of hydrogen chloride gas to convert any magnesium oxide impurity into magnesium chloride.

(ii) An investigation of the reaction between magnesium oxide and hydrogen chloride gas showed that an intermediate product was formed with the composition by massMg, 31.65%; O, 20.84%; H, 1.31% and Cl, 46.20%.

Calculate the empirical formula of this intermediate compound.

empirical formula .................................... [2]

(d) The acid/base behaviour of the oxides in the third period varies across the period.

(i) Describe this behaviour and explain it with reference to the structure and bonding of sodium oxide, Na2O, aluminium oxide, Al 2O3, and sulfur trioxide, SO3.

.............................................................................................................................................

.............................................................................................................................................

....................................................................................................................................... [2]

(ii) Write equations for reactions of these three oxides with hydrochloric acid and/or sodium hydroxide as appropriate.

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

....................................................................................................................................... [4]

[Total: 18]

2

9701/22/M/J/16© UCLES 2016


1 (a) Complete the table to show the composition and identity of some atoms and ions.

name of element

nucleon number

atomic number

number of protons

number of neutrons

number of electrons

overall charge

boron 10 5 ............. ............. ............. 0

nitrogen ............. ............. ............. 8 10 .............

............. 208 82 82 ............. 80 .............

............. ............. ............. 3 3 ............. +1

[4]

(b) ThefifthtoeighthionisationenergiesofthreeelementsinthethirdperiodofthePeriodicTableare given. The symbols used for reference are not the actual symbols of the elements.

ionisation energies, kJ mol–1

fifth sixth seventh eighth

X 7012 8496 27 107 31 671

Y 6542 9362 11 018 33 606

Z 7238 8781 11 996 13 842

(i) State and explain the group number of element Y.

group number ...............................

explanation .........................................................................................................................

.............................................................................................................................................[1]

(ii) State and explain the general trend in first ionisation energies across the third period.

.............................................................................................................................................

.............................................................................................................................................

....................................................................................................................................... [2]

(iii) CompletetheelectronicconfigurationofelementX.

1s2 ................................................................................................................................. [1]

3


(c) A sample of oxygen exists as a mixture of three isotopes. Information about two of these isotopes is given in the table.

mass number 16 17

abundance 99.76% 0.04%

(i) Calculate the abundance of the third isotope.

abundance = ............................. % [1]

(ii) The relative atomic mass of this sample of oxygen is 16.0044.

Calculate the mass number of the third isotope. You must show your working.

mass number = ............................. [2]

[Total: 11]

2

9701/22/M/J/17© UCLES 2017


1 The composition of atoms and ions can be determined from knowledge of atomic number, nucleon number and charge.

(a) Complete the table.

atomicnumber

nucleonnumber

number ofelectrons

number ofprotons

number ofneutrons symbol

3 2 6Li+ 3

23 26 32

[2]

(b) Boron occurs naturally as a mixture of two stable isotopes, 10B and 11B. The relative isotopic masses and percentage abundances are shown.

isotope relative isotopic mass abundance / %10B 10.0129 19.7811B to be calculated 80.22

(i) Definethetermrelative isotopic mass.

.............................................................................................................................................

....................................................................................................................................... [2]

(ii) Calculate the relative isotopic mass of 11B.

Give your answer to sixsignificantfigures.Showyourworking.

[2]

[Total: 6]

8

9701/21/M/J/18© UCLES 2018

3 The elements in the third period exhibit periodicity in both their chemical and physical properties.

(a) A graph of the atomic and ionic radii across the third period is shown.

0.25

0.20

0.15

0.10

0.05

0.00

atomic orionic radius/ nm

atoms and ionsNa Na+ Mg Mg2+ Al Al 3+ Si Si4+ P3–P S2–S Cl –Cl

= atomic radius / nm = ionic radius / nm

(i) Explain the decrease in atomic radius across the third period.

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

....................................................................................................................................... [2]

(ii) Explain why, for sodium to silicon, the ionic radii are less than the atomic radii.

.............................................................................................................................................

....................................................................................................................................... [1]

(iii) Explain why, for phosphorus to chlorine, the ionic radii are greater than the atomic radii.

.............................................................................................................................................

.............................................................................................................................................

....................................................................................................................................... [2]

(b) The first ionisation energies of the elements across the third period show a general increase.

Aluminium and sulfur do not follow this general trend.

(i) Explain why aluminium has a lower first ionisation energy than magnesium.

.............................................................................................................................................

.............................................................................................................................................

....................................................................................................................................... [2]

9


(ii) Explain why sulfur has a lower first ionisation energy than phosphorus.

.............................................................................................................................................

.............................................................................................................................................

....................................................................................................................................... [2]

(c) The elements in the third period, from sodium to silicon, can react with chlorine to form chlorides.

(i) State and explain the pattern of change of oxidation number which occurs to both chlorine and the different Period 3 elements when they react together.

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

....................................................................................................................................... [3]

(ii) Give the equations to show the reactions of sodium chloride and silicon(IV) chloride when separately added to water.

sodium chloride ..................................................................................................................

silicon(IV) chloride .............................................................................................................. [2]

(iii) Complete the table to describe the structure and bonding in sodium chloride and silicon(IV) chloride.

structure bonding

sodium chloride

silicon(IV) chloride

[2]

[Total: 16]

Answer all 1 This question is about Period 3 elements and ...

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