Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals Intermediates by

M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

ANNEXURE - A DETAILS OF PRODUCTS AND IT’S END-USE

Sr. No.

NAME OF PRODUCTS CAS Nos. Quantity [MT/Month]

End use Category LD50 Existing Proposed Total

1. Ortho Dianisidine 119-90-4 2 --- 2 Use as Dyes

Intermediates. 5(f) 1920 mg/kg

2. 4-Nitro 2 Amino Phenol 6 Sulfonic Acid(4-NAPSA) 96-67-3 15 --- 15 Use as Dyes

Intermediates. 5(f) NA

Agro Chemicals Intermediates [5(b) Category]

3. 2,3 Di Chloro Phenol 576-24-9 --- 20 20 Use as Agro chemicals

Intermediates. 5(b) 2376 mg/kg

4. 8 Hydroxy Quinoline [8-HQ] AND/OR 148-24-3 --- 10 10

Use as Agro chemicals Intermediates.

5(b) 1200 mg/kg

5. 5-Chloro-7-IODO-8-Hydroxy Quinoline [IODO] 130-16-5 --- Use as Agro chemicals Intermediates.

5(b) 1200 mg/kg

Speciality Chemicals [5(f) Category]

6. Meta Chloro Aniline 108-42-9 --- 30 30 Use as Speciality Chemicals.

5(f) 256 mg/kg

7. 2 Mercapto Benzimidazole AND/OR 583-39-1 ---

10 10

Use as Speciality Chemicals.

5(f) 300 mg/kg

8. Meta Amino Phenol 591-27-5 --- Use as Speciality

Chemicals. 5(f) 924 mg/kg

TOTAL 17 70 87

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

ANNEXURE – B

DETAILS OF PRODUCT WISE RAW MATERIAL AND IT’S CONSUMPTION

Sr. No.

Product Name Raw material MT/MT CAS No.

1 2,3 Di Chloro Phenol 2,3 DCA 1.06 608-27-5 Sulfuric Acid 1.00 7664-93-9 Nitrosyl Sulfuric Acid 1.00 7782-78-7 TOTAL 3.06

2 8 Hydroxy Quinoline [8-HQ] 2 Amino Phenol 1.16 95-55-6 Glycerine 0.83 56-81-5 Sulfuric Acid 1.31 7664-93-9 Acetic Acid 0.10 64-19-7 C.S.Lye 1.84 1310-73-2 TOTAL 5.24

3

5-Chloro-7-IODO-8-Hydroxy Quinoline [IODO]

4 Chloro 2 Amino Phenol 0.87 95-85-2 Glycerine 0.89 56-81-5 Sulfuric Acid 1.40 7664-93-9 Acetic Acid 0.10 64-19-7 C.S.Lye 2.94 1310-73-2 Iodine 0.40 7553-56-2 TOTAL 6.60

4 Meta Chloro Aniline 3 Chloro Nitro Benzene 1.34 121-73-3 Iron Powder 1.31 7439-89-6 Hydrochloric Acid 0.10 7647-01-0 C.S.Lye 0.08 1310-73-2 TOTAL 2.83

5 2 Mercapto Benzimidazole O-Phenyl Diamine 0.80 95-54-5 Carbon Disulfide 0.70 75-15-0 NaOH 0.29 1310-73-2 Activated Charcoal 0.02 64365-11-3 HCl 0.90 7647-01-0 TOTAL 2.71

6 Meta Amino Phenol Metanilic Acid 1.60 121-47-1 Caustic Lye 0.75 1310-73-2 HCl 0.35 7647-01-0

TOTAL 2.70

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

ANNEXURE – C

MANUFACTURING PROCESS DESCRIPTION 1.] 2,3 Di Chloro Phenol

Process Description of 2,3 Di Chloro Phenol:

STEP:

2,3Dichloro Aniline [2,3 DCA] is converted to its diazonium compound with Nitrosyl

Sulfuric Acid in presence of Sulfuric Acid. The reaction is carried out under very controlled

condition of temperature.

The Diazonium salt formed is further subjected to acidic hydrolysis leading to formation

of the product 2,3Dichloro Phenol. The product formed is isolated by means of distillation.

Chemical Reaction of 2,3 Di Chloro Phenol: Flow Chart 2,3 Di Chloro Phenol:

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

2.] 8 Hydroxy Quinoline [8-HQ]

Process Description of 8 Hydroxy Quinoline [8-HQ]:

STEP:

2-Amino Phenol is reacted with Glycerine leading to cyclization in presence of Sulfuric

Acid. The reaction leads to form 8-Hydroxyquinoline; the excess of 2-Amino Phenol is

removed by distillation.

The residual mass diluted with water and pH adjusted with C S Lye followed by filtration

and washing. The wet cake dried to obtain product 8-Hydroxyquinoline [8-HQ]

Chemical Reaction of 8 Hydroxy Quinoline [8-HQ]: Flow Chart 8 Hydroxy Quinoline [8-HQ]:

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

3.] 5-Chloro-7-IODO-8-Hydroxy Quinoline [IODO]

Process Description of 5-Chloro-7-IODO-8-Hydroxy Quinoline [IODO]:

STEP:

4-Chloro-2-Amino Phenol is reacted with Glycerine leading to cyclization in presence of Sulfuric Acid. The reaction leads to form 5-Chloro-8-Hydroxyquinoline; the excess of 4-CAP is removed by distillation.

The residual mass diluted with water and pH adjusted with C S Lye followed by filtration

and washing. The wet cake is further taken for Iodination with Iodine.

The Iodination is carried out under controlled parameter in alkaline condition. The

Iodinated mass is then subjected to filtration and washing. The wet cake obtained is dried

to obtain product IODO.

Chemical Reaction of 5-Chloro-7-IODO-8-Hydroxy Quinoline [IODO]:

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

Flow Chart 5-Chloro-7-IODO-8-Hydroxy Quinoline [IODO]:

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

4.] Meta Chloro Aniline

Process Description of Meta Chloro Aniline:

STEP:

3 Chloro Nitro Benzene [3 CNB] is subjected to reduction using Iron Powder under acidic

condition to form 3 Chloro Aniline. 3 Chloro Aniline thus formed is then suitably isolated

from the reaction mixture by means of filtration and distillation.

Chemical Reaction of Meta Chloro Aniline: Flow Chart Meta Chloro Aniline:

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

5.] 2 Mercapto Benzimidazole

Process Description of 2 Mercapto Benzimidazole:

STEP:

O-Phenyl Diamine is reacted with Carbon Disulfide along with Sodium Hydroxide leading

to form 2-Mercapto Benzimidazole which is isolated by filtration and further washed.

The wet cake of 2-Mercapto Benzimidazole is converted to its alkali salt, treated with

activated charcoal and then again acidified to obtain 2-Mercapto Benzimidazole. The

product is filtered and dried. Is further dried to obtained 2-MBI.

Chemical Reaction of 2 Mercapto Benzimidazole:

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

Flow Chart 2 Mercapto Benzimidazole:

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

6.] Meta Amino Phenol

Process Description of Meta Amino Phenol:

STEP 1: Charge in vessel caustic lye/flakes, Metanilic acid and heat up to 2500C to 2600C

under string and after complete reaction, charge water and make slurry of reaction

mass and transfer to isolation vessel.

STEP 2: Take slurry in isolation vessel and isolate material with Ice and slowly add

Hydrochloric acid in it to isolate material, after complete isolation do centrifuge and

then transfer for Drying. Take Centrifuge wet cake for Drying and pack Meta Amino

Phenol. Generated waste water from centrifuge will transfer to ETP for treatment.

Chemical Reaction of Meta Amino Phenol: Flow Chart Meta Amino Phenol:

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

ANNEXURE – D

DETAILS OF WATER CONSUMPTION AND WASTE WATER GENERATION

DETAILS OF WATER CONSUMPTION:

Sr. No.

Purpose Consumption, KL/day

Existing Proposed Total

1. Domestic 1.0 1.0 2.0

2. Industrial

a. Process & APCM 3.4 3.2 6.6

b. Boiler 1.8 1.6 3.4

c. Cooling 1.5 1.0 2.5

d. Gardening 1.0 1.5 2.5

TOTAL [2] 7.7 7.3 15.0

TOTAL [1+2] 8.7 8.3 17.0

DETAILS OF WASTE WATER GENERATION:

Sr. No.

Purpose Generation, KL/day

Existing Proposed Total

1. Domestic 0.8 0.7 1.5

2. Industrial

a. Process & APCM 3.5 3.7 7.2

b. Boiler 0.3 0.2 0.5

c. Cooling 0.2 0.1 0.3

d. Gardening 0.0 0.0 0.0

TOTAL [2] 4.0 4.0 8.0

TOTAL [1+2] 4.8 4.7 9.5

Note:

1) Existing: Domestic sewage is being disposed through septic tank - soak pit system.

Generated Industrial waste water is treated into ETP and then treated water will be

send to Common Spray Dryer/CMEE for further treatment and maintained Zero

Liquid Discharge [ZLD].

2) Proposed: Domestic sewage disposed through soak pit/septic tank system.

Generated Industrial waste water will be treated into ETP and then treated water

will be send to Common Spray Dryer [CSD] facility/CMEE for further treatment and

will be strictly maintained Zero Liquid Discharge [ZLD] for the Proposed Expansion.

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

WATER FLOW DIAGRAM:-

FLOW DIAGRAM OF EFFLUENT TREATMENT PLANT:-

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

ANNEXURE – E

DETAILS OF HAZARDOUS WASTE GENERATION AND ITS DISPOSAL

Sr. No.

Name of Hazardous

Waste

Source of Generation

Category as per

HWM,2016

Quantity MT/ Year Remarks

Existing Proposed Total

1. Empty barrels/ containers/liners contaminated with hazardous chemicals/wastes

Raw material & Packaging

33.1 120 ---- 120 Collection, Storage, Transportation, Decontamination, reuse or send back to supplier, and sold to Authorized recycler.

2. Spent/ Lube Oil Plant Machinery

5.1 0.12 ---- 0.12 Collection, Storage, Transportation and sold to authorized recycler.

3. Spent Carbon Process 36.2 0.78 ---- 0.78 Collection, Storage, Transportation and sent to CHWIF Facility. 4. Off-Specification

products Process 28.5 0.12 ---- 0.12 Collection, Storage,

Transportation and send to co-processing or CHWIF.

5. Spent mother liquor

Process --- 8.28 ---- 8.28 Collection, Storage, Transportation and sent to CHWIF Facility. 6. Spent organic

solvents Process 28.6 0.72 ---- 0.72 Collection, Storage,

Transportation and sent to CHWIF Facility. 7. Process Residue Process

[1] 2,3 Di Chloro Phenol

[4] Meta Chloro Aniline

28.1 0.02 196 196.02 Collection, Storage, Transportation and send to co-processing or CHWIF.

8. ETP Sludge ETP

35.3 18 126 144 Collection, Storage, Transportation and sent to TSDF site.

9. Spent Acid Process [1] 2,3 Di

Chloro Phenol

26.3 Nil 520 520 Collection, Storage, Transportation and sell to authorized end users registered under rule-9.

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

10. Iron Sludge Process [1]Meta Chloro Aniline

26.1 --- 504 504 Collection, Storage, Transportation and send to co-processing or CHWIF.

11. Spent Carbon Process [1]2Mercapto Benzimidazole

36.2 --- 5.0 5.0 Collection, Storage, Transportation and sent to CHWIF Facility.

12. Sodium Hydro Sulfide Solution

Process [1] 2

Mercapto Benzimidazole

A13 Nil 220 220 Collection, Storage, transportation and sell to authorized end users registered under rule-9.

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

ANNEXURE – F

DETAILS OF AIR POLLUTION CONTROL MEASURES

DETAILS OF FLUE GAS EMISSION

Sr.

No.

Stack attached to Name of fuel &

its

consumption

Stack

Height

[m]

Air pollution

Control

System

Parameters

Existing

1.

Boiler [Cap. 800 kg/hr]

Natural Gas

9300 m3/month Or

LDO 800 KL/Day

11 --------------

PM < 150 mg/Nm3

SO2< 100 ppm

NOx< 50 ppm

Proposed

1. Boiler [Cap. 800 kg/hr]

Natural Gas

500 m3/Day

11 --------------

PM < 150 mg/Nm3

SO2< 100 ppm

NOx< 50 ppm

2. Thermic Fluid Heater [Cap. 2 lakh. Kcal/hr] [2 Nos.] 11 --------------

DETAILS OF PROCESS GAS EMISSION:

Sr. No. Stack Attached to Stack

Height

[m]

APCM Permissible

Limit

Existing

1. Reaction Vessel 9 Water Scrubber HCl-20 mg/Nm3

Proposed

1. Reaction Vessel-I 11 2 Stage Caustic

Scrubber H2S- 45 mg/Nm3

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals Intermediates by

M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

ANNEXURE – G

PLANT LAYOUT

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

ANNEXURE – H

PROPOSED TERMS OF REFERENCE

The generic structure of Environment Impact Assessment Study Report will be as

under:

1. Introduction

This will cover the location and justification of the proposed project and scoping and

methodology for the EIA study.

2. Project Description

It will include the below mention details.

• Location of the project

• Product profile

• Resources requirement

• Manufacturing process and raw material requirement

• Material handling and storage

• Details on proposed Environmental Management System and Monitoring.

• Storage and handling of hazardous chemicals

3. Baseline Environmental Description

The data regarding baseline environmental conditions will be collected

/generated as per the guidelines of MoEF. The methodology for collection of

baseline data for each of the component/environmental attribute is as follows:

1. Air

a. The study area will be of 10 Km radius considering the project site as center and

study period will be of one season except monsoon.

b. For estimation of back ground concentration of PM10, PM2.5, Oxides of Nitrogen

(NOx), Sulphur Dioxide (SO2), H2S within study area, and 6 monitoring stations

will be established as per the guidelines of CPCB and Ministry of Environment &

Forest, Government of India. At each station monitoring will be carried out on 24

hourly bases twice in a week for entire study period except monsoon.

2. Meteorology

Meteorological data like wind speed, wind direction, humidity, temperature, will

be collected at the location under consideration / from authorized agency, so as to

prepare wind-rose diagram and to predict the concentration of pollutants using

dispersion models. These data will be collected for a period of 12 weeks.

Annexures to Form – 1 & Pre Feasibility Report Proposed Expansion Project for manufacturing of Speciality & Agro Chemicals

Intermediates by M/s. Shraddha Finechem Plot No. 2933, GIDC, Industrial Estate Panoli, Dist.: Bharuch, Gujarat

3. Water

Water samples will be collected and analyzed of raw water supply of the Notified

area.

4. Noise

The noise level will be measured once in a study period in Leq. at least at 6

different location within study area using an integrated sound level meter.

4. Identification and Assessment of the Impacts

The activities having the potential to cause environmental impact will be

identified and the degree of impact will be assessed using standard matrix methods.

The following environmental attributes will be considered to establish the cause-

effect relationship with the various activities of the proposed project.

5. Environmental Management and Monitoring Plan

Environmental Management and Monitoring Plan will be prepared based on the

anticipated environmental impact. It will also cover details on Occupational Health

programs and as well as for corporate social responsibilities.

6. Risk Assessment:

The study will include risk assessment for storage, handling, transportation etc.

for the raw material(s) and products to be used in the plant. Occupational risk

involved during operational phase of the plant will be assessed and necessary safety

and protective measures will be recommended.