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Transcript of Andreas Weger
Folie 1 © Fraunhofer UMSICHT
Digestate management with the
TCR®-process – add-on for AD plants
ADBA R&D Forum 2015
14-15 April 2015 Southampton
Andreas Weger, Rolf Jung, Fabian Stenzel, Andreas Hornung
Fraunhofer UMSICHT, Institutsteil Sulzbach-Rosenberg
Folie 2 © Fraunhofer UMSICHT
Our motivation …
Energy conversion and storage
Raw and functional materials
© Fraunhofer
Agenda
Motivation
TCR®-process
Efficiency increase of AD plants
Digestate management
Conclusion
Folie 4 © Fraunhofer UMSICHT
Motivation
Folie 5 © Fraunhofer UMSICHT
Motivation
New challenges for AD plants in Germany
Amendment of the Renewable Energy Act (EEG 2014)
Upcoming amendment of the Fertiliser Ordinance
Recycling competition between manure and digestate
Efficiency increase possible through
Reduction of substrate quantity
Nitrogen removal in digestate (liquid phase)
Further value chain increase
Carbon-rich char valuable fertilizer (Taylor-made fertiliser)
Oil as possible fuel blend
Folie 6 © Fraunhofer UMSICHT
TCR®-process
Folie 7 © Fraunhofer UMSICHT
TCR®-process
Process description
Pyrolysis with integrated reformer unit
Temperature: 350 - 450 °C / 550 - 750 °C
Feed: organic residues from AD or bioethanol plants
TCR®-process converts organic residues into high-value products
Bio-Char (material or energetic usage)
Syngas/Oil (energetic usage)
Only solid digestate phase necessary
Fertilizer effect remains (liquid phase)
TCR®-
process
Folie 8 © Fraunhofer UMSICHT
TCR®-process
Process scheme
Pre-treatment Fermentation
Biomass
Dewatering
Gas Digestate
.
Char
TCR® CHP
Power
Heat
Thermal drying
Oil
Digestate
Folie 9 © Fraunhofer UMSICHT
TCR®-process
Elementary analysis and heating value (HHV)
Bio-Char Oil Syngas
C 55 wt.%
H 2 - 3 wt.%
N 0,5 - 5 wt.%
S 0,5 wt.%
O 20 wt.%
Ash 15 wt.%
HHV 22 MJ/kg
C 50 - 70 wt.%
H 8 - 10 wt.%
N 2 - 5 wt.%
S 0,5 - 2 wt.%
O 9 - 11 wt.%
Ash 0,2 wt.%
HHV 31 MJ/kg
H2 30 - 40 v/v%
CO2 20 - 30 v/v%
CO 10 - 20 v/v%
CH4 4 - 8 v/v%
CxHy 5 - 10 v/v%
HHV 14 MJ/kg
Folie 10 © Fraunhofer UMSICHT
TCR®-process
Product yields
Folie 11 © Fraunhofer UMSICHT
Efficiency increase of AD plants
Folie 12 © Fraunhofer UMSICHT
Efficiency increase of AD plants
Reduction of substrate quantity
489 m³ i.N./h
AD plant 1 MWel
Substrate (Mix) 24.000 Mg/a
Operating hours 8.000 h/a
Biogas:
Gross Energy
20.426.412 kWh/a
Biogas 3.909.900 m³ i.N./a
489 m³ i.N./h
CH4-Yield 52,4 v/v%
CO2-Yield 47,6 v/v%
Heating value 5,22 kWh/m³ i.N.
Density 1,32 kg/m³ i.N.
Folie 13 © Fraunhofer UMSICHT
Efficiency increase of AD plants
Reduction of substrate quantity
Digestate
170 kg/h
85% DM
60 m³ i.N./h
TCR®
Syngas:
Gross Energy
1.872.661 kWh/a
Heating value 3,92 kWh/m³ i.N.
Density 1,02 kg/m³ i.N.
Mix Gas:
Gross Energy
20.607.586 kWh/a
Density 1,28 kg/m³ i.N.
Reduction of substrate quantity ≥ 10% possible!
Substrate (Mix) 21.600 Mg/a
Operating hours 8.000 h/a
Biogas:
Gross Energy
18.734.925 kWh/a
Biogas 3.586.126 m³ i.N./a
448 m³ i.N./h
CH4-Yield 52,4 v/v%
CO2-Yield 47,6 v/v%
Heating value 5,22 kWh/m³ i.N.
Density 1,32 kg/m³ i.N.
508 m³ i.N./h
AD plant 1 MWel
Folie 14 © Fraunhofer UMSICHT
Digestate management
Folie 15 © Fraunhofer UMSICHT
Separation
fester Gärrest
flüssiger Gärrest
Input
24.000 Mg/a
18.100 Mg/a
TS = 9,8%
5.030 Mg/a
TS = 25%
13.070 Mg/a
TS = 4%
Digestate management
Example nutrient balance
N P
6 2,5 kg/Mg
109 45 Mg/a
N P
4,5 3,6 kg/Mg
23 18 Mg/a
N P
6,6 2,1 kg/Mg
86 27 Mg/a
80% of nitrogen remains in the liquid phase [P as P2O5]
Solid phase
Liquid phase
Digestate
separation
Folie 16 © Fraunhofer UMSICHT
Digestate management
Nitrogen removal
Output Char
N-enriched
Output liquid phase,
low nitrogen amount
Input liquid phase
Input Char
Folie 17 © Fraunhofer UMSICHT
Conclusion
Folie 18 © Fraunhofer UMSICHT
Conclusion
Can you get £100 per tonne from digestate?
Reduction of substrate quantity
Cost reduction ≈ 80.000 €/a in the case of energy crops (in Germany)
Nitrogen Removal
Lower demand of arable land, transport costs depends on situation
Bio-Char
Soil fertiliser (up to 600 € per tonne; Source: Sonnenerde.at)
Oil
Possible fuel blend
Folie 19 © Fraunhofer UMSICHT
Thank you for your attention!
Contact:
Fraunhofer UMSICHT
Institutsteil Sulzbach-Rosenberg
An der Maxhütte 1
92237 Sulzbach-Rosenberg
E-Mail: info-suro[at]umsicht.fraunhofer.de
Internet: http://www.umsicht-suro.fraunhofer.de
M. Eng. Andreas Weger
Telefon: 09661-908-434
E-Mail: andreas.weger[at]umsicht.fraunhofer.de
Prof. Dr. Andreas Hornung
Telefon: 09661-908-403
E-Mail: andreas.hornung[at]umsicht.fraunhofer.de
Digestate management with the
TCR®-process – an add-on for AD plants