ANALYTICAL REPORT 6 - Osceola County Home Page · ANALYTICAL REPORT Eurofins TestAmerica, Tampa...

ANALYTICAL REPORTEurofins TestAmerica, Tampa6712 Benjamin RoadSuite 100Tampa, FL 33634Tel: (813)885-7427

Laboratory Job ID: 660-96392-1Client Project/Site: CCR

For:Waste Connections, Inc.5135 Madison AveTampa, Florida 33619

Attn: Kirk Wills

Authorized for release by:8/13/2019 10:05:04 AM

Willie Hallmon, Project Manager I(813)[email protected]

The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

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Table of Contents

Client: Waste Connections, Inc.Project/Site: CCR

Laboratory Job ID: 660-96392-1

of 14Eurofins TestAmerica, Tampa

8/13/2019

Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

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Sample SummaryJob ID: 660-96392-1Client: Waste Connections, Inc.

Project/Site: CCR

Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID

660-96392-1 8/15/19 CCR Solid 08/05/19 08:50 08/05/19 11:29

Eurofins TestAmerica, Tampa

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Case NarrativeClient: Waste Connections, Inc. Job ID: 660-96392-1Project/Site: CCR

Job ID: 660-96392-1

Laboratory: Eurofins TestAmerica, Tampa

Narrative

Job Narrative660-96392-1

Comments

No additional comments.

Receipt

The sample was received on 8/5/2019 11:29 AM; the sample arrived in good condition, properly preserved and, where required, on ice.

The temperature of the cooler at receipt was 4.7º C.

Metals No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.

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Definitions/GlossaryJob ID: 660-96392-1Client: Waste Connections, Inc.

Project/Site: CCR

Qualifiers

MetalsQualifier Description

U Indicates that the compound was analyzed for but not detected.

Qualifier

GlossaryThese commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains No Free Liquid

DER Duplicate Error Ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL Detection Limit (DoD/DOE)

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision Level Concentration (Radiochemistry)

EDL Estimated Detection Limit (Dioxin)

LOD Limit of Detection (DoD/DOE)

LOQ Limit of Quantitation (DoD/DOE)

MDA Minimum Detectable Activity (Radiochemistry)

MDC Minimum Detectable Concentration (Radiochemistry)

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not Detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative Error Ratio (Radiochemistry)

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)


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Detection SummaryJob ID: 660-96392-1Client: Waste Connections, Inc.

Project/Site: CCR

Client Sample ID: 8/15/19 CCR Lab Sample ID: 660-96392-1

Barium

PQL

0.050 mg/L

MDL

0.0046

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

TCLP10.11 6010D

Selenium 0.10 mg/L0.025 TCLP10.13 6010D


This Detection Summary does not include radiochemical test results.

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Client Sample ResultsJob ID: 660-96392-1Client: Waste Connections, Inc.

Project/Site: CCR

Lab Sample ID: 660-96392-1Client Sample ID: 8/15/19 CCRMatrix: SolidDate Collected: 08/05/19 08:50

Date Received: 08/05/19 11:29

Method: 6010D - Metals (ICP) - TCLPPQL MDL

Silver 0.0073 U 0.050 0.0073 mg/L 08/08/19 14:05 08/09/19 10:10 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.050 0.0093 mg/L 08/08/19 14:05 08/09/19 10:10 1Arsenic 0.0093 U

0.050 0.0046 mg/L 08/08/19 14:05 08/09/19 10:10 1Barium 0.11

0.020 0.0023 mg/L 08/08/19 14:05 08/09/19 10:10 1Cadmium 0.0023 U

0.050 0.0055 mg/L 08/08/19 14:05 08/09/19 10:10 1Chromium 0.0055 U

0.050 0.010 mg/L 08/08/19 14:05 08/09/19 10:10 1Lead 0.010 U

0.10 0.025 mg/L 08/08/19 14:05 08/09/19 10:10 1Selenium 0.13

Method: 7470A - Mercury (CVAA) - TCLPPQL MDL

Mercury 0.00050 U 0.00070 0.00050 mg/L 08/09/19 01:00 08/09/19 18:03 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier


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QC Sample ResultsJob ID: 660-96392-1Client: Waste Connections, Inc.

Project/Site: CCR

Method: 6010D - Metals (ICP)

Client Sample ID: Lab Control SampleLab Sample ID: LCS 660-214114/2-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 214171 Prep Batch: 214114

Silver 5.00 4.86 mg/L 97 80 - 120

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

Arsenic 5.00 4.91 mg/L 98 80 - 120

Barium 5.00 5.11 mg/L 102 80 - 120

Cadmium 5.00 4.95 mg/L 99 80 - 120

Chromium 5.00 5.16 mg/L 103 80 - 120

Lead 5.00 5.05 mg/L 101 80 - 120

Selenium 5.00 4.92 mg/L 98 80 - 120

Client Sample ID: Method BlankLab Sample ID: LB 660-214108/1-BMatrix: Solid Prep Type: TCLPAnalysis Batch: 214171 Prep Batch: 214114

PQL MDL

Silver 0.0073 U 0.050 0.0073 mg/L 08/08/19 14:05 08/09/19 10:01 1

LB LB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

0.0093 U 0.00930.050 mg/L 08/08/19 14:05 08/09/19 10:01 1Arsenic

0.0046 U 0.00460.050 mg/L 08/08/19 14:05 08/09/19 10:01 1Barium

0.0023 U 0.00230.020 mg/L 08/08/19 14:05 08/09/19 10:01 1Cadmium

0.0055 U 0.00550.050 mg/L 08/08/19 14:05 08/09/19 10:01 1Chromium

0.010 U 0.0100.050 mg/L 08/08/19 14:05 08/09/19 10:01 1Lead

0.025 U 0.0250.10 mg/L 08/08/19 14:05 08/09/19 10:01 1Selenium

Client Sample ID: 8/15/19 CCRLab Sample ID: 660-96392-1 MSMatrix: Solid Prep Type: TCLPAnalysis Batch: 214171 Prep Batch: 214114

Silver 0.0073 U 5.00 4.98 mg/L 100 75 - 125

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Arsenic 0.0093 U 5.00 5.10 mg/L 102 75 - 125

Barium 0.11 5.00 5.12 mg/L 100 75 - 125

Cadmium 0.0023 U 5.00 5.08 mg/L 102 75 - 125

Chromium 0.0055 U 5.00 4.99 mg/L 100 75 - 125

Lead 0.010 U 5.00 4.80 mg/L 96 75 - 125

Selenium 0.13 5.00 5.21 mg/L 102 75 - 125

Client Sample ID: 8/15/19 CCRLab Sample ID: 660-96392-1 MSDMatrix: Solid Prep Type: TCLPAnalysis Batch: 214171 Prep Batch: 214114

Silver 0.0073 U 5.00 4.96 mg/L 99 75 - 125 0 20

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Arsenic 0.0093 U 5.00 5.04 mg/L 101 75 - 125 1 20

Barium 0.11 5.00 5.05 mg/L 99 75 - 125 1 20

Cadmium 0.0023 U 5.00 5.03 mg/L 101 75 - 125 1 20

Chromium 0.0055 U 5.00 4.97 mg/L 99 75 - 125 0 20

Lead 0.010 U 5.00 4.76 mg/L 95 75 - 125 1 20

Selenium 0.13 5.00 5.17 mg/L 101 75 - 125 1 20


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QC Sample ResultsJob ID: 660-96392-1Client: Waste Connections, Inc.

Project/Site: CCR

Method: 7470A - Mercury (CVAA)

Client Sample ID: Lab Control SampleLab Sample ID: LCS 660-214190/14-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 214198 Prep Batch: 214190

Mercury 0.00140 0.00150 mg/L 107 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 660-214190/15-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 214198 Prep Batch: 214190

Mercury 0.00140 0.00153 mg/L 109 80 - 120 2 20

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD

Client Sample ID: Method BlankLab Sample ID: LB 660-214108/1-CMatrix: Solid Prep Type: TCLPAnalysis Batch: 214198 Prep Batch: 214190

PQL MDL

Mercury 0.00050 U 0.00070 0.00050 mg/L 08/09/19 01:00 08/09/19 17:56 1

LB LB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

Client Sample ID: 8/15/19 CCRLab Sample ID: 660-96392-1 MSMatrix: Solid Prep Type: TCLPAnalysis Batch: 214198 Prep Batch: 214190

Mercury 0.00050 U 0.00140 0.00138 mg/L 99 80 - 120

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: 8/15/19 CCRLab Sample ID: 660-96392-1 MSDMatrix: Solid Prep Type: TCLPAnalysis Batch: 214198 Prep Batch: 214190

Mercury 0.00050 U 0.00140 0.00124 mg/L 88 80 - 120 11 20

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD


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QC Association SummaryJob ID: 660-96392-1Client: Waste Connections, Inc.

Project/Site: CCR

Metals

Leach Batch: 214108

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Solid 1311660-96392-1 8/15/19 CCR TCLP

Solid 1311LB 660-214108/1-B Method Blank TCLP

Solid 1311LB 660-214108/1-C Method Blank TCLP

Solid 1311660-96392-1 MS 8/15/19 CCR TCLP

Solid 1311660-96392-1 MSD 8/15/19 CCR TCLP

Prep Batch: 214114


Solid 3010A 214108660-96392-1 8/15/19 CCR TCLP

Solid 3010A 214108LB 660-214108/1-B Method Blank TCLP

Solid 3010ALCS 660-214114/2-A Lab Control Sample Total/NA

Solid 3010A 214108660-96392-1 MS 8/15/19 CCR TCLP

Solid 3010A 214108660-96392-1 MSD 8/15/19 CCR TCLP

Analysis Batch: 214171


Solid 6010D 214114660-96392-1 8/15/19 CCR TCLP

Solid 6010D 214114LB 660-214108/1-B Method Blank TCLP

Solid 6010D 214114LCS 660-214114/2-A Lab Control Sample Total/NA

Solid 6010D 214114660-96392-1 MS 8/15/19 CCR TCLP

Solid 6010D 214114660-96392-1 MSD 8/15/19 CCR TCLP

Prep Batch: 214190


Solid 7470A 214108660-96392-1 8/15/19 CCR TCLP

Solid 7470A 214108LB 660-214108/1-C Method Blank TCLP

Solid 7470ALCS 660-214190/14-A Lab Control Sample Total/NA

Solid 7470ALCSD 660-214190/15-A Lab Control Sample Dup Total/NA



Analysis Batch: 214198


Solid 7470A 214190660-96392-1 8/15/19 CCR TCLP

Solid 7470A 214190LB 660-214108/1-C Method Blank TCLP

Solid 7470A 214190LCS 660-214190/14-A Lab Control Sample Total/NA

Solid 7470A 214190LCSD 660-214190/15-A Lab Control Sample Dup Total/NA




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Lab ChronicleClient: Waste Connections, Inc. Job ID: 660-96392-1Project/Site: CCR

Client Sample ID: 8/15/19 CCR Lab Sample ID: 660-96392-1Matrix: SolidDate Collected: 08/05/19 08:50

Date Received: 08/05/19 11:29

Leach 1311 08/07/19 19:30 GH1214108 TAL TAM

Type

Batch Batch

MethodPrep Type LabAnalystRun

Prepared

or Analyzed

Batch

Number

Dilution

Factor

TCLP

Prep 3010A 214114 08/08/19 14:05 GH1 TAL TAMTCLP

Analysis 6010D 1 214171 08/09/19 10:10 GAF TAL TAMTCLP

Leach 1311 214108 08/07/19 19:30 GH1 TAL TAMTCLP

Prep 7470A 214190 08/09/19 01:00 GH1 TAL TAMTCLP

Analysis 7470A 1 214198 08/09/19 18:03 GH1 TAL TAMTCLP

Laboratory References:

TAL TAM = Eurofins TestAmerica, Tampa, 6712 Benjamin Road, Suite 100, Tampa, FL 33634, TEL (813)885-7427


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Method SummaryJob ID: 660-96392-1Client: Waste Connections, Inc.

Project/Site: CCR

Method Method Description LaboratoryProtocol

SW8466010D Metals (ICP) TAL TAM

SW8467470A Mercury (CVAA) TAL TAM

SW8461311 TCLP Extraction TAL TAM

SW8463010A Preparation, Total Metals TAL TAM

SW8467470A Preparation, Mercury TAL TAM

Protocol References:

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL TAM = Eurofins TestAmerica, Tampa, 6712 Benjamin Road, Suite 100, Tampa, FL 33634, TEL (813)885-7427


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Accreditation/Certification SummaryClient: Waste Connections, Inc. Job ID: 660-96392-1Project/Site: CCR

Laboratory: Eurofins TestAmerica, TampaUnless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.

Authority Program EPA Region Identification Number Expiration Date

Florida E842824NELAP 06-30-20

The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which

the agency does not offer certification.

Analysis Method Prep Method Matrix Analyte


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Login Sample Receipt Checklist

Client: Waste Connections, Inc. Job Number: 660-96392-1

Login Number: 96392

Question Answer Comment

Creator: Fullwood, Kierston R

List Source: Eurofins TestAmerica, Tampa

List Number: 1

N/ARadioactivity wasn't checked or is </= background as measured by a survey meter.

TrueThe cooler's custody seal, if present, is intact.

TrueSample custody seals, if present, are intact.

TrueThe cooler or samples do not appear to have been compromised or tampered with.

TrueSamples were received on ice.

TrueCooler Temperature is acceptable.

TrueCooler Temperature is recorded.

TrueCOC is present.

TrueCOC is filled out in ink and legible.

TrueCOC is filled out with all pertinent information.

TrueIs the Field Sampler's name present on COC?

TrueThere are no discrepancies between the containers received and the COC.

TrueSamples are received within Holding Time (excluding tests with immediate HTs)

TrueSample containers have legible labels.

TrueContainers are not broken or leaking.

TrueSample collection date/times are provided.

TrueAppropriate sample containers are used.

TrueSample bottles are completely filled.

TrueSample Preservation Verified.

TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs

TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").

TrueMultiphasic samples are not present.

TrueSamples do not require splitting or compositing.

N/AResidual Chlorine Checked.

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ANALYTICAL REPORT 6 - Osceola County Home Page · ANALYTICAL REPORT Eurofins TestAmerica, Tampa...

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