13 7

i00297 _

-nometa ~EPO~T middot prepared for

middot CANNONS ENGINEERING CORPORATION

CASE NO l3692

I ~ iCE V D

)J ~ 1960I _ _--middotu-s aiw

~- shy _ - - lt bullbull

tcimeu ~TI BJJJilJICllfIOrL-eS CJII Hew EnQ-nd Llbouorho~

) TECHNICAL REPORT------------------------ shy

OJ November 1980

Pa ge 1 of 3

Canmiddotnons Engineering Corpo r a tion First Street Bridgewate r MA 0 2324

Attention Mr Tony Salina

13692 ~middot Per your r equest ~middot

PROJECT DESCRIPTION

Analysis of six (6 ) stack gas samples

SlMPLE IDENTIFICATION

Six (6) stack gas samples identified as follows

l of 3 - Permuthan~ middot - Skinner Sherman Tubes 7844 and 7847 330 PH

_2 of 3 - Permuthane + Xidex - Skinner amp ShermanbullTubes middot78middot20 and 7841 400 PH

3 of 3 - Permuthane + Xidex + Aqueous - Skinner amp SherlnCln Tubes 7818 and 7-832 510 PM

The above samples were taken in duplicate on-s ite on 10 2fiO by a representative of Skinner amp Sherman Laboratories~ Inc

METHOD OF TEST

The mass spectrometer was Qumpe~ out tomiddot the gas cylinder inlet A backqround spectrum was then recorded The gas cylinder inlet was then opened and the mass spectrummiddot was recqrded at different senai- tivities The intensity of each substituent could then be converted to percent concentration from the s ensitivity factor of each molecule

_ __ _n_bull_ _____ _ _ ___ ~~

- __iQ_~--Jl-bull41_bull~- middot-- ~_ _____ ~ n__bullr _ ___ ___ ---middotlw-t-__-w--- s _-_ _s_ _ -middot- bull - -

Eaa~e sthHfiUTif11111 ealJnrmttUJuies e111a middot~fgt middot~middotmiddot ~ middotmiddot ~ S~middot middot N~ En~nd Llbotbulllorlfl

03 November 19 80

Sample Identification

Permuthane

Permuthane + Xi dex

Permuthane + Xidex + Aqueous

Sample Identification

rmuihane --

Permuthane + Xidex

Permuthane + Xidex + Aqueous

Sample Identification

Permuthane

Permuthane + Xidex

Permuthane + Xidex + Aqueous

Engineering C~rporation

Concentration by volume

SampS Tube No Oxygen

7844 130 7847 131

7820 154 7841 15 4

7818 12 4 7832 124

SampS Tube No ~

7844 o 32 7847 0 34

7820 0 34 7841 034

1818 038 7832 0 39

SampS Tube No Phos gene

7844 C1 ppm7847 lt1 pp~

7820 lt1 ppm7841 lt1 ppm

7818 lt1 ppm7832 lt1 ppm

Carbon Nitrogen Dioxide

782 7 55 7831 7 38

764 5 79 765 s 74

78 0 7 72 778 7 77

Carbon Hydro-Monoxide carbons

lt1 ppin lt1 ppmltl ppm ltl ppm

lll lt1 ppm104 ltl ppm

056 lt1 ppm0 70 ltJ ppm

Hydro2en Chloride

lt1 ppm ~ 1 ppm

lt1 ppm lt1 ppm

lt1 ppm lt1 ppm

Argon

094 0 92

094 0931

0 93l 0931

Chlorinated Hldrocarbons

lt1 ppm ltl ppm

lt1 ppm lt1 ppm

lt1 ppm ltl ppm

c 1oz -bullmiddot-~-bull~__n_ ~ ____ ____ r -___Sl_4_~ Sl_4S-LIoo--k-~-----middot-N k-r_middotmiddot---o~ooo- ~___ ____-middotmiddot--middot ---- -- --- --- 41-__ ___ - -

Jmr fE Sllletrmiifl IEDht1imllll11Ties fUia New Engl1nd UfontOfJ

__ ccHNflAL HttUH I

OJ November 1980

Page 3 of 3

~ Cannons Engineering Corporation

~ l3692

Notes The sensitivity limit for chemical components was 10 ppm by volume

The principal chemist assigned to this case was Robert E Sacher PhD

Respectfully submitted

SKINNER SHERMAN LABORATORIES INC

rII middotmiddot bull fmiddot Ralph Berger PE President

RBls

(103

1w bull--bullNlt_n__ ____ TollooWio J-middotmiddot-bull-10-otl-middotmiddot--at--W-bullbulllaoloMl_bull_ _ _ -- middotmiddot--middotmiddot-fll-middot- __ _ r - --- - - -

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~ --~ - middot- middot tmiddot-~6~ middot - middot _ _middot _ l

~slnj ~sulk 6 76tJk Ftrtn

~on -lmbullbullnl 6errtor 7dltl 11-lbullf Jltlals ~( 3TV F4s-~(avltr) (as ~r) oinf middot I (bullf) -JLtlyen -ISlo

lfIIMI ~No lt7orshyD YJeilho- ~2 (oJ) 5000jal mt~d (s-) 3 I lo Bampr~~IJL II J1 (OFshy

Tmiddot v iJI- r(bullf) SOPijAI J bull ~-q To ltot=~ ft~~~ u3 (otj )Ooo_jltl middotNto (bull) IJrlt1 Ne ampitojtJ ltor

tag) 9ooyt --) bull31o 1 e_ Flt~jN- lt7or (bullf) IOOOOjal mbullAltd() aomiddotto BffFi AJs 1lfo lt57shyPIJ OfN]- 1l +5 (Of OOOOj41 iltJ(~J to1o fn lt70r- I~p[L~-~~J( (orJ) 3~-middotmiddots lnJtd(zJ Slo FL ~ N7tJ (7oPPtt-r)

(a f) 100jal j bulllllo middot13 Nlt- bull - bull (o Jshy7 (org) 1SOOjal A~~~~~- 1213of lto _F

l4fJ s-soosa ~ 7tgt() r 8 (psect) looosbull t(bull J2bullto ll(~~Vl t75Jo (70 r-

f OIJ-ol (af) _sectuOo_jal bull 131o MJ 1 1J1 2t (7oFI(PJ bullbullbull 0Y~ shyI (otj) 1-gtoo_s_r LtJampJ bull 3flo 6Jltt~ ~ ltt tgtJ70 (7iil

(bullf) -itooyl )

oslo I 11 1 2o1N _t (7or

N tor~ rnultd u) gt9Q~ 8 Flt1 t11 l 1707 ~(azj ~ ID 6 I fi1 Jj Aitt(J AJ4 7Fs vz~(Pl oil(~ bullbull 1

G GG middotflt rtsuigtmiffcJdr- 6CjMtz Spec F hof0jltn4U fxtrlocor6lf

_ I (ar9) lj-lo

)

shy -middotmiddotmiddot

interstate laboratories inc

Testing RE7sul ts on Tenk rarm

I Emission Spectre (Only metals with concentrations greeter than 100 ppmreported here)

Tank 1

metal 8

Aqueous 1-1

Organic

re 1-1 Pb 01-1 mg 001-01 mn OOl-01 K 003-03 Na 01-1 Sn 001-01 Zn 1-1

2 8 09-9 044-44 Ca 027-27 044-44 Cu 0027-027 re 09-9 044-44 Pb bullbull 09-9 013- 13 mg 009-09 044-44 p 0027~027 K 0027-027

Na 027-27 04-4 Sn 0021-027 Zn 009shy ~09 Ti 1114- 04 v 004-04

3 8 018-18 044-44 Ca 0018-016 re 018-18 [117-17 mg

middot_ Na 0018- 018 018-18 017-17

4 8 039bullbull ~9 Ca 0039-039 re Pb

039-39

0012-012 c1oo Na 0039-039 Sn 0012- 012

5 8 033-33 re 0033-033 Ph

) ill ~

interstate laboratories inc

Emission Spectra (cont )

Tank metal Aqueous Organic6 8 a53-SJ Na as3-53 Pb aa15- a1 5Fe aa1s-a1s Ca aas bull as mg aa14- a1 4 ~ a18- 18Na a48- 48 aa18-a18Pb middot aa14-a14 aa1 8-a18Zn a48- 48 a18-18c aas- asp a18- 18Sn aa18- a18

aas4-as4_ ~

J

9 Co aa1 - a1 aa1 2- a12No a1-1 Zn a1- 1 aa4- a4Fe aa4- a4 mg aa4-a4v aa12-a12 Pb aaa4- aa4

10 Al aa2-a2Co aa6-6Cr aa2-a2Fe a2-2Pb a2-2mn aa2- a2sl aa5-a6No a6-6Sn aa5-a6Ti a2-2Zn a2- 2

14 8 14-14 aas- asFe Pb

aa14- a14 aas- asOa42-a42 aaasbullbull aa5 (108

-- v aa14- a14 aa1s-a1sZn a014- au aa5-a5 mg aa42- a42 mn a014-a14 K aa14-a14 Ne 042-42 Sn rnu_ n111

)

interstate laboratories inc

11 Total Halogen as Chlcrlde

Tenk Aqueous Orgenic

1 45 2 59 39 3 33 44 4 30 5 10 6 22 65 8 23 22 9 OS 39 14 41 59

Ill BTUs

Tank BTUlb (~r9onic phose _onh)__)

3 6810 8 17530 9 15170 10 11988 11 9774 12 13807

) i002Ho

CHEMICAL bull PHYSICAL

ELECTRICALbull BACTERIOLOGICAL

UCiiNICAL REPORT prenared fQr

CANNONS ENGINEERING CORPORATION

QSE NO 13756

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

) TECHNICAL REPORT------------------------ shy

OJ November 1980

Pa ge 1 of 3

Canmiddotnons Engineering Corpo r a tion First Street Bridgewate r MA 0 2324

Attention Mr Tony Salina

13692 ~middot Per your r equest ~middot

PROJECT DESCRIPTION

Analysis of six (6 ) stack gas samples

SlMPLE IDENTIFICATION

Six (6) stack gas samples identified as follows

l of 3 - Permuthan~ middot - Skinner Sherman Tubes 7844 and 7847 330 PH

_2 of 3 - Permuthane + Xidex - Skinner amp ShermanbullTubes middot78middot20 and 7841 400 PH

3 of 3 - Permuthane + Xidex + Aqueous - Skinner amp SherlnCln Tubes 7818 and 7-832 510 PM

The above samples were taken in duplicate on-s ite on 10 2fiO by a representative of Skinner amp Sherman Laboratories~ Inc

METHOD OF TEST

The mass spectrometer was Qumpe~ out tomiddot the gas cylinder inlet A backqround spectrum was then recorded The gas cylinder inlet was then opened and the mass spectrummiddot was recqrded at different senai- tivities The intensity of each substituent could then be converted to percent concentration from the s ensitivity factor of each molecule

_ __ _n_bull_ _____ _ _ ___ ~~

- __iQ_~--Jl-bull41_bull~- middot-- ~_ _____ ~ n__bullr _ ___ ___ ---middotlw-t-__-w--- s _-_ _s_ _ -middot- bull - -

Eaa~e sthHfiUTif11111 ealJnrmttUJuies e111a middot~fgt middot~middotmiddot ~ middotmiddot ~ S~middot middot N~ En~nd Llbotbulllorlfl

03 November 19 80

Sample Identification

Permuthane

Permuthane + Xi dex

Permuthane + Xidex + Aqueous

Sample Identification

rmuihane --

Permuthane + Xidex

Permuthane + Xidex + Aqueous

Sample Identification

Permuthane

Permuthane + Xidex

Permuthane + Xidex + Aqueous

Engineering C~rporation

Concentration by volume

SampS Tube No Oxygen

7844 130 7847 131

7820 154 7841 15 4

7818 12 4 7832 124

SampS Tube No ~

7844 o 32 7847 0 34

7820 0 34 7841 034

1818 038 7832 0 39

SampS Tube No Phos gene

7844 C1 ppm7847 lt1 pp~

7820 lt1 ppm7841 lt1 ppm

7818 lt1 ppm7832 lt1 ppm

Carbon Nitrogen Dioxide

782 7 55 7831 7 38

764 5 79 765 s 74

78 0 7 72 778 7 77

Carbon Hydro-Monoxide carbons

lt1 ppin lt1 ppmltl ppm ltl ppm

lll lt1 ppm104 ltl ppm

056 lt1 ppm0 70 ltJ ppm

Hydro2en Chloride

lt1 ppm ~ 1 ppm

lt1 ppm lt1 ppm

lt1 ppm lt1 ppm

Argon

094 0 92

094 0931

0 93l 0931

Chlorinated Hldrocarbons

lt1 ppm ltl ppm

lt1 ppm lt1 ppm

lt1 ppm ltl ppm

c 1oz -bullmiddot-~-bull~__n_ ~ ____ ____ r -___Sl_4_~ Sl_4S-LIoo--k-~-----middot-N k-r_middotmiddot---o~ooo- ~___ ____-middotmiddot--middot ---- -- --- --- 41-__ ___ - -

Jmr fE Sllletrmiifl IEDht1imllll11Ties fUia New Engl1nd UfontOfJ

__ ccHNflAL HttUH I

OJ November 1980

Page 3 of 3

~ Cannons Engineering Corporation

~ l3692

Notes The sensitivity limit for chemical components was 10 ppm by volume

The principal chemist assigned to this case was Robert E Sacher PhD

Respectfully submitted

SKINNER SHERMAN LABORATORIES INC

rII middotmiddot bull fmiddot Ralph Berger PE President

RBls

(103

1w bull--bullNlt_n__ ____ TollooWio J-middotmiddot-bull-10-otl-middotmiddot--at--W-bullbulllaoloMl_bull_ _ _ -- middotmiddot--middotmiddot-fll-middot- __ _ r - --- - - -

~~~aJmiddot~- -middotmiddotmiddotmiddot-middot middot-middot~middot middot-middotmiddot ~

~- ~~middot ~

I

bull r~rz_~

- _~7_-~ -- middot-- ~tt~-~5~lt~middot ~ ~middot middot~ ~middot ~middotJ~middot-~~~ middot middotmiddot middot ~

~~~ middotmiddot--

middot middotmiddotmiddot-shy

~~I ~ 1

~ )T ~ ) ~-~~

( r~l

y g=al

middot--=-shy f~l

~ l-

~

~

DI ~

lti ltS

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~t -g

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s ~

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middot middot

~

~

sa~

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~ 7

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)

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~-

~ --~ - middot- middot tmiddot-~6~ middot - middot _ _middot _ l

~slnj ~sulk 6 76tJk Ftrtn

~on -lmbullbullnl 6errtor 7dltl 11-lbullf Jltlals ~( 3TV F4s-~(avltr) (as ~r) oinf middot I (bullf) -JLtlyen -ISlo

lfIIMI ~No lt7orshyD YJeilho- ~2 (oJ) 5000jal mt~d (s-) 3 I lo Bampr~~IJL II J1 (OFshy

Tmiddot v iJI- r(bullf) SOPijAI J bull ~-q To ltot=~ ft~~~ u3 (otj )Ooo_jltl middotNto (bull) IJrlt1 Ne ampitojtJ ltor

tag) 9ooyt --) bull31o 1 e_ Flt~jN- lt7or (bullf) IOOOOjal mbullAltd() aomiddotto BffFi AJs 1lfo lt57shyPIJ OfN]- 1l +5 (Of OOOOj41 iltJ(~J to1o fn lt70r- I~p[L~-~~J( (orJ) 3~-middotmiddots lnJtd(zJ Slo FL ~ N7tJ (7oPPtt-r)

(a f) 100jal j bulllllo middot13 Nlt- bull - bull (o Jshy7 (org) 1SOOjal A~~~~~- 1213of lto _F

l4fJ s-soosa ~ 7tgt() r 8 (psect) looosbull t(bull J2bullto ll(~~Vl t75Jo (70 r-

f OIJ-ol (af) _sectuOo_jal bull 131o MJ 1 1J1 2t (7oFI(PJ bullbullbull 0Y~ shyI (otj) 1-gtoo_s_r LtJampJ bull 3flo 6Jltt~ ~ ltt tgtJ70 (7iil

(bullf) -itooyl )

oslo I 11 1 2o1N _t (7or

N tor~ rnultd u) gt9Q~ 8 Flt1 t11 l 1707 ~(azj ~ ID 6 I fi1 Jj Aitt(J AJ4 7Fs vz~(Pl oil(~ bullbull 1

G GG middotflt rtsuigtmiffcJdr- 6CjMtz Spec F hof0jltn4U fxtrlocor6lf

_ I (ar9) lj-lo

)

shy -middotmiddotmiddot

interstate laboratories inc

Testing RE7sul ts on Tenk rarm

I Emission Spectre (Only metals with concentrations greeter than 100 ppmreported here)

Tank 1

metal 8

Aqueous 1-1

Organic

re 1-1 Pb 01-1 mg 001-01 mn OOl-01 K 003-03 Na 01-1 Sn 001-01 Zn 1-1

2 8 09-9 044-44 Ca 027-27 044-44 Cu 0027-027 re 09-9 044-44 Pb bullbull 09-9 013- 13 mg 009-09 044-44 p 0027~027 K 0027-027

Na 027-27 04-4 Sn 0021-027 Zn 009shy ~09 Ti 1114- 04 v 004-04

3 8 018-18 044-44 Ca 0018-016 re 018-18 [117-17 mg

middot_ Na 0018- 018 018-18 017-17

4 8 039bullbull ~9 Ca 0039-039 re Pb

039-39

0012-012 c1oo Na 0039-039 Sn 0012- 012

5 8 033-33 re 0033-033 Ph

) ill ~

interstate laboratories inc

Emission Spectra (cont )

Tank metal Aqueous Organic6 8 a53-SJ Na as3-53 Pb aa15- a1 5Fe aa1s-a1s Ca aas bull as mg aa14- a1 4 ~ a18- 18Na a48- 48 aa18-a18Pb middot aa14-a14 aa1 8-a18Zn a48- 48 a18-18c aas- asp a18- 18Sn aa18- a18

aas4-as4_ ~

J

9 Co aa1 - a1 aa1 2- a12No a1-1 Zn a1- 1 aa4- a4Fe aa4- a4 mg aa4-a4v aa12-a12 Pb aaa4- aa4

10 Al aa2-a2Co aa6-6Cr aa2-a2Fe a2-2Pb a2-2mn aa2- a2sl aa5-a6No a6-6Sn aa5-a6Ti a2-2Zn a2- 2

14 8 14-14 aas- asFe Pb

aa14- a14 aas- asOa42-a42 aaasbullbull aa5 (108

-- v aa14- a14 aa1s-a1sZn a014- au aa5-a5 mg aa42- a42 mn a014-a14 K aa14-a14 Ne 042-42 Sn rnu_ n111

)

interstate laboratories inc

11 Total Halogen as Chlcrlde

Tenk Aqueous Orgenic

1 45 2 59 39 3 33 44 4 30 5 10 6 22 65 8 23 22 9 OS 39 14 41 59

Ill BTUs

Tank BTUlb (~r9onic phose _onh)__)

3 6810 8 17530 9 15170 10 11988 11 9774 12 13807

) i002Ho

CHEMICAL bull PHYSICAL

ELECTRICALbull BACTERIOLOGICAL

UCiiNICAL REPORT prenared fQr

CANNONS ENGINEERING CORPORATION

QSE NO 13756

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

03 November 19 80

Sample Identification

Permuthane

Permuthane + Xi dex

Permuthane + Xidex + Aqueous

Sample Identification

rmuihane --

Permuthane + Xidex

Permuthane + Xidex + Aqueous

Sample Identification

Permuthane

Permuthane + Xidex

Permuthane + Xidex + Aqueous

Engineering C~rporation

Concentration by volume

SampS Tube No Oxygen

7844 130 7847 131

7820 154 7841 15 4

7818 12 4 7832 124

SampS Tube No ~

7844 o 32 7847 0 34

7820 0 34 7841 034

1818 038 7832 0 39

SampS Tube No Phos gene

7844 C1 ppm7847 lt1 pp~

7820 lt1 ppm7841 lt1 ppm

7818 lt1 ppm7832 lt1 ppm

Carbon Nitrogen Dioxide

782 7 55 7831 7 38

764 5 79 765 s 74

78 0 7 72 778 7 77

Carbon Hydro-Monoxide carbons

lt1 ppin lt1 ppmltl ppm ltl ppm

lll lt1 ppm104 ltl ppm

056 lt1 ppm0 70 ltJ ppm

Hydro2en Chloride

lt1 ppm ~ 1 ppm

lt1 ppm lt1 ppm

lt1 ppm lt1 ppm

Argon

094 0 92

094 0931

0 93l 0931

Chlorinated Hldrocarbons

lt1 ppm ltl ppm

lt1 ppm lt1 ppm

lt1 ppm ltl ppm

c 1oz -bullmiddot-~-bull~__n_ ~ ____ ____ r -___Sl_4_~ Sl_4S-LIoo--k-~-----middot-N k-r_middotmiddot---o~ooo- ~___ ____-middotmiddot--middot ---- -- --- --- 41-__ ___ - -

Jmr fE Sllletrmiifl IEDht1imllll11Ties fUia New Engl1nd UfontOfJ

__ ccHNflAL HttUH I

OJ November 1980

Page 3 of 3

~ Cannons Engineering Corporation

~ l3692

Notes The sensitivity limit for chemical components was 10 ppm by volume

The principal chemist assigned to this case was Robert E Sacher PhD

Respectfully submitted

SKINNER SHERMAN LABORATORIES INC

rII middotmiddot bull fmiddot Ralph Berger PE President

RBls

(103

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(a f) 100jal j bulllllo middot13 Nlt- bull - bull (o Jshy7 (org) 1SOOjal A~~~~~- 1213of lto _F

l4fJ s-soosa ~ 7tgt() r 8 (psect) looosbull t(bull J2bullto ll(~~Vl t75Jo (70 r-

f OIJ-ol (af) _sectuOo_jal bull 131o MJ 1 1J1 2t (7oFI(PJ bullbullbull 0Y~ shyI (otj) 1-gtoo_s_r LtJampJ bull 3flo 6Jltt~ ~ ltt tgtJ70 (7iil

(bullf) -itooyl )

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interstate laboratories inc

Testing RE7sul ts on Tenk rarm

I Emission Spectre (Only metals with concentrations greeter than 100 ppmreported here)

Tank 1

metal 8

Aqueous 1-1

Organic

re 1-1 Pb 01-1 mg 001-01 mn OOl-01 K 003-03 Na 01-1 Sn 001-01 Zn 1-1

2 8 09-9 044-44 Ca 027-27 044-44 Cu 0027-027 re 09-9 044-44 Pb bullbull 09-9 013- 13 mg 009-09 044-44 p 0027~027 K 0027-027

Na 027-27 04-4 Sn 0021-027 Zn 009shy ~09 Ti 1114- 04 v 004-04

3 8 018-18 044-44 Ca 0018-016 re 018-18 [117-17 mg

middot_ Na 0018- 018 018-18 017-17

4 8 039bullbull ~9 Ca 0039-039 re Pb

039-39

0012-012 c1oo Na 0039-039 Sn 0012- 012

5 8 033-33 re 0033-033 Ph

) ill ~

interstate laboratories inc

Emission Spectra (cont )

Tank metal Aqueous Organic6 8 a53-SJ Na as3-53 Pb aa15- a1 5Fe aa1s-a1s Ca aas bull as mg aa14- a1 4 ~ a18- 18Na a48- 48 aa18-a18Pb middot aa14-a14 aa1 8-a18Zn a48- 48 a18-18c aas- asp a18- 18Sn aa18- a18

aas4-as4_ ~

J

9 Co aa1 - a1 aa1 2- a12No a1-1 Zn a1- 1 aa4- a4Fe aa4- a4 mg aa4-a4v aa12-a12 Pb aaa4- aa4

10 Al aa2-a2Co aa6-6Cr aa2-a2Fe a2-2Pb a2-2mn aa2- a2sl aa5-a6No a6-6Sn aa5-a6Ti a2-2Zn a2- 2

14 8 14-14 aas- asFe Pb

aa14- a14 aas- asOa42-a42 aaasbullbull aa5 (108

-- v aa14- a14 aa1s-a1sZn a014- au aa5-a5 mg aa42- a42 mn a014-a14 K aa14-a14 Ne 042-42 Sn rnu_ n111

)

interstate laboratories inc

11 Total Halogen as Chlcrlde

Tenk Aqueous Orgenic

1 45 2 59 39 3 33 44 4 30 5 10 6 22 65 8 23 22 9 OS 39 14 41 59

Ill BTUs

Tank BTUlb (~r9onic phose _onh)__)

3 6810 8 17530 9 15170 10 11988 11 9774 12 13807

) i002Ho

CHEMICAL bull PHYSICAL

ELECTRICALbull BACTERIOLOGICAL

UCiiNICAL REPORT prenared fQr

CANNONS ENGINEERING CORPORATION

QSE NO 13756

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

__ ccHNflAL HttUH I

OJ November 1980

Page 3 of 3

~ Cannons Engineering Corporation

~ l3692

Notes The sensitivity limit for chemical components was 10 ppm by volume

The principal chemist assigned to this case was Robert E Sacher PhD

Respectfully submitted

SKINNER SHERMAN LABORATORIES INC

rII middotmiddot bull fmiddot Ralph Berger PE President

RBls

(103

1w bull--bullNlt_n__ ____ TollooWio J-middotmiddot-bull-10-otl-middotmiddot--at--W-bullbulllaoloMl_bull_ _ _ -- middotmiddot--middotmiddot-fll-middot- __ _ r - --- - - -

~~~aJmiddot~- -middotmiddotmiddotmiddot-middot middot-middot~middot middot-middotmiddot ~

~- ~~middot ~

I

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lfIIMI ~No lt7orshyD YJeilho- ~2 (oJ) 5000jal mt~d (s-) 3 I lo Bampr~~IJL II J1 (OFshy

Tmiddot v iJI- r(bullf) SOPijAI J bull ~-q To ltot=~ ft~~~ u3 (otj )Ooo_jltl middotNto (bull) IJrlt1 Ne ampitojtJ ltor

tag) 9ooyt --) bull31o 1 e_ Flt~jN- lt7or (bullf) IOOOOjal mbullAltd() aomiddotto BffFi AJs 1lfo lt57shyPIJ OfN]- 1l +5 (Of OOOOj41 iltJ(~J to1o fn lt70r- I~p[L~-~~J( (orJ) 3~-middotmiddots lnJtd(zJ Slo FL ~ N7tJ (7oPPtt-r)

(a f) 100jal j bulllllo middot13 Nlt- bull - bull (o Jshy7 (org) 1SOOjal A~~~~~- 1213of lto _F

l4fJ s-soosa ~ 7tgt() r 8 (psect) looosbull t(bull J2bullto ll(~~Vl t75Jo (70 r-

f OIJ-ol (af) _sectuOo_jal bull 131o MJ 1 1J1 2t (7oFI(PJ bullbullbull 0Y~ shyI (otj) 1-gtoo_s_r LtJampJ bull 3flo 6Jltt~ ~ ltt tgtJ70 (7iil

(bullf) -itooyl )

oslo I 11 1 2o1N _t (7or

N tor~ rnultd u) gt9Q~ 8 Flt1 t11 l 1707 ~(azj ~ ID 6 I fi1 Jj Aitt(J AJ4 7Fs vz~(Pl oil(~ bullbull 1

G GG middotflt rtsuigtmiffcJdr- 6CjMtz Spec F hof0jltn4U fxtrlocor6lf

_ I (ar9) lj-lo

)

shy -middotmiddotmiddot

interstate laboratories inc

Testing RE7sul ts on Tenk rarm

I Emission Spectre (Only metals with concentrations greeter than 100 ppmreported here)

Tank 1

metal 8

Aqueous 1-1

Organic

re 1-1 Pb 01-1 mg 001-01 mn OOl-01 K 003-03 Na 01-1 Sn 001-01 Zn 1-1

2 8 09-9 044-44 Ca 027-27 044-44 Cu 0027-027 re 09-9 044-44 Pb bullbull 09-9 013- 13 mg 009-09 044-44 p 0027~027 K 0027-027

Na 027-27 04-4 Sn 0021-027 Zn 009shy ~09 Ti 1114- 04 v 004-04

3 8 018-18 044-44 Ca 0018-016 re 018-18 [117-17 mg

middot_ Na 0018- 018 018-18 017-17

4 8 039bullbull ~9 Ca 0039-039 re Pb

039-39

0012-012 c1oo Na 0039-039 Sn 0012- 012

5 8 033-33 re 0033-033 Ph

) ill ~

interstate laboratories inc

Emission Spectra (cont )

Tank metal Aqueous Organic6 8 a53-SJ Na as3-53 Pb aa15- a1 5Fe aa1s-a1s Ca aas bull as mg aa14- a1 4 ~ a18- 18Na a48- 48 aa18-a18Pb middot aa14-a14 aa1 8-a18Zn a48- 48 a18-18c aas- asp a18- 18Sn aa18- a18

aas4-as4_ ~

J

9 Co aa1 - a1 aa1 2- a12No a1-1 Zn a1- 1 aa4- a4Fe aa4- a4 mg aa4-a4v aa12-a12 Pb aaa4- aa4

10 Al aa2-a2Co aa6-6Cr aa2-a2Fe a2-2Pb a2-2mn aa2- a2sl aa5-a6No a6-6Sn aa5-a6Ti a2-2Zn a2- 2

14 8 14-14 aas- asFe Pb

aa14- a14 aas- asOa42-a42 aaasbullbull aa5 (108

-- v aa14- a14 aa1s-a1sZn a014- au aa5-a5 mg aa42- a42 mn a014-a14 K aa14-a14 Ne 042-42 Sn rnu_ n111

)

interstate laboratories inc

11 Total Halogen as Chlcrlde

Tenk Aqueous Orgenic

1 45 2 59 39 3 33 44 4 30 5 10 6 22 65 8 23 22 9 OS 39 14 41 59

Ill BTUs

Tank BTUlb (~r9onic phose _onh)__)

3 6810 8 17530 9 15170 10 11988 11 9774 12 13807

) i002Ho

CHEMICAL bull PHYSICAL

ELECTRICALbull BACTERIOLOGICAL

UCiiNICAL REPORT prenared fQr

CANNONS ENGINEERING CORPORATION

QSE NO 13756

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

bull r~rz_~

- _~7_-~ -- middot-- ~tt~-~5~lt~middot ~ ~middot middot~ ~middot ~middotJ~middot-~~~ middot middotmiddot middot ~

~~~ middotmiddot--

middot middotmiddotmiddot-shy

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~on -lmbullbullnl 6errtor 7dltl 11-lbullf Jltlals ~( 3TV F4s-~(avltr) (as ~r) oinf middot I (bullf) -JLtlyen -ISlo

lfIIMI ~No lt7orshyD YJeilho- ~2 (oJ) 5000jal mt~d (s-) 3 I lo Bampr~~IJL II J1 (OFshy

Tmiddot v iJI- r(bullf) SOPijAI J bull ~-q To ltot=~ ft~~~ u3 (otj )Ooo_jltl middotNto (bull) IJrlt1 Ne ampitojtJ ltor

tag) 9ooyt --) bull31o 1 e_ Flt~jN- lt7or (bullf) IOOOOjal mbullAltd() aomiddotto BffFi AJs 1lfo lt57shyPIJ OfN]- 1l +5 (Of OOOOj41 iltJ(~J to1o fn lt70r- I~p[L~-~~J( (orJ) 3~-middotmiddots lnJtd(zJ Slo FL ~ N7tJ (7oPPtt-r)

(a f) 100jal j bulllllo middot13 Nlt- bull - bull (o Jshy7 (org) 1SOOjal A~~~~~- 1213of lto _F

l4fJ s-soosa ~ 7tgt() r 8 (psect) looosbull t(bull J2bullto ll(~~Vl t75Jo (70 r-

f OIJ-ol (af) _sectuOo_jal bull 131o MJ 1 1J1 2t (7oFI(PJ bullbullbull 0Y~ shyI (otj) 1-gtoo_s_r LtJampJ bull 3flo 6Jltt~ ~ ltt tgtJ70 (7iil

(bullf) -itooyl )

oslo I 11 1 2o1N _t (7or

N tor~ rnultd u) gt9Q~ 8 Flt1 t11 l 1707 ~(azj ~ ID 6 I fi1 Jj Aitt(J AJ4 7Fs vz~(Pl oil(~ bullbull 1

G GG middotflt rtsuigtmiffcJdr- 6CjMtz Spec F hof0jltn4U fxtrlocor6lf

_ I (ar9) lj-lo

)

shy -middotmiddotmiddot

interstate laboratories inc

Testing RE7sul ts on Tenk rarm

I Emission Spectre (Only metals with concentrations greeter than 100 ppmreported here)

Tank 1

metal 8

Aqueous 1-1

Organic

re 1-1 Pb 01-1 mg 001-01 mn OOl-01 K 003-03 Na 01-1 Sn 001-01 Zn 1-1

2 8 09-9 044-44 Ca 027-27 044-44 Cu 0027-027 re 09-9 044-44 Pb bullbull 09-9 013- 13 mg 009-09 044-44 p 0027~027 K 0027-027

Na 027-27 04-4 Sn 0021-027 Zn 009shy ~09 Ti 1114- 04 v 004-04

3 8 018-18 044-44 Ca 0018-016 re 018-18 [117-17 mg

middot_ Na 0018- 018 018-18 017-17

4 8 039bullbull ~9 Ca 0039-039 re Pb

039-39

0012-012 c1oo Na 0039-039 Sn 0012- 012

5 8 033-33 re 0033-033 Ph

) ill ~

interstate laboratories inc

Emission Spectra (cont )

Tank metal Aqueous Organic6 8 a53-SJ Na as3-53 Pb aa15- a1 5Fe aa1s-a1s Ca aas bull as mg aa14- a1 4 ~ a18- 18Na a48- 48 aa18-a18Pb middot aa14-a14 aa1 8-a18Zn a48- 48 a18-18c aas- asp a18- 18Sn aa18- a18

aas4-as4_ ~

J

9 Co aa1 - a1 aa1 2- a12No a1-1 Zn a1- 1 aa4- a4Fe aa4- a4 mg aa4-a4v aa12-a12 Pb aaa4- aa4

10 Al aa2-a2Co aa6-6Cr aa2-a2Fe a2-2Pb a2-2mn aa2- a2sl aa5-a6No a6-6Sn aa5-a6Ti a2-2Zn a2- 2

14 8 14-14 aas- asFe Pb

aa14- a14 aas- asOa42-a42 aaasbullbull aa5 (108

-- v aa14- a14 aa1s-a1sZn a014- au aa5-a5 mg aa42- a42 mn a014-a14 K aa14-a14 Ne 042-42 Sn rnu_ n111

)

interstate laboratories inc

11 Total Halogen as Chlcrlde

Tenk Aqueous Orgenic

1 45 2 59 39 3 33 44 4 30 5 10 6 22 65 8 23 22 9 OS 39 14 41 59

Ill BTUs

Tank BTUlb (~r9onic phose _onh)__)

3 6810 8 17530 9 15170 10 11988 11 9774 12 13807

) i002Ho

CHEMICAL bull PHYSICAL

ELECTRICALbull BACTERIOLOGICAL

UCiiNICAL REPORT prenared fQr

CANNONS ENGINEERING CORPORATION

QSE NO 13756

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

0 l ~ t f r middot i bull

~ c

A

r I

i~~ic~~i~~~~-~-Aii~~~~=~~cu~t~bullbull~-i~Y_Y

)

IIII

~-

~ --~ - middot- middot tmiddot-~6~ middot - middot _ _middot _ l

~slnj ~sulk 6 76tJk Ftrtn

~on -lmbullbullnl 6errtor 7dltl 11-lbullf Jltlals ~( 3TV F4s-~(avltr) (as ~r) oinf middot I (bullf) -JLtlyen -ISlo

lfIIMI ~No lt7orshyD YJeilho- ~2 (oJ) 5000jal mt~d (s-) 3 I lo Bampr~~IJL II J1 (OFshy

Tmiddot v iJI- r(bullf) SOPijAI J bull ~-q To ltot=~ ft~~~ u3 (otj )Ooo_jltl middotNto (bull) IJrlt1 Ne ampitojtJ ltor

tag) 9ooyt --) bull31o 1 e_ Flt~jN- lt7or (bullf) IOOOOjal mbullAltd() aomiddotto BffFi AJs 1lfo lt57shyPIJ OfN]- 1l +5 (Of OOOOj41 iltJ(~J to1o fn lt70r- I~p[L~-~~J( (orJ) 3~-middotmiddots lnJtd(zJ Slo FL ~ N7tJ (7oPPtt-r)

(a f) 100jal j bulllllo middot13 Nlt- bull - bull (o Jshy7 (org) 1SOOjal A~~~~~- 1213of lto _F

l4fJ s-soosa ~ 7tgt() r 8 (psect) looosbull t(bull J2bullto ll(~~Vl t75Jo (70 r-

f OIJ-ol (af) _sectuOo_jal bull 131o MJ 1 1J1 2t (7oFI(PJ bullbullbull 0Y~ shyI (otj) 1-gtoo_s_r LtJampJ bull 3flo 6Jltt~ ~ ltt tgtJ70 (7iil

(bullf) -itooyl )

oslo I 11 1 2o1N _t (7or

N tor~ rnultd u) gt9Q~ 8 Flt1 t11 l 1707 ~(azj ~ ID 6 I fi1 Jj Aitt(J AJ4 7Fs vz~(Pl oil(~ bullbull 1

G GG middotflt rtsuigtmiffcJdr- 6CjMtz Spec F hof0jltn4U fxtrlocor6lf

_ I (ar9) lj-lo

)

shy -middotmiddotmiddot

interstate laboratories inc

Testing RE7sul ts on Tenk rarm

I Emission Spectre (Only metals with concentrations greeter than 100 ppmreported here)

Tank 1

metal 8

Aqueous 1-1

Organic

re 1-1 Pb 01-1 mg 001-01 mn OOl-01 K 003-03 Na 01-1 Sn 001-01 Zn 1-1

2 8 09-9 044-44 Ca 027-27 044-44 Cu 0027-027 re 09-9 044-44 Pb bullbull 09-9 013- 13 mg 009-09 044-44 p 0027~027 K 0027-027

Na 027-27 04-4 Sn 0021-027 Zn 009shy ~09 Ti 1114- 04 v 004-04

3 8 018-18 044-44 Ca 0018-016 re 018-18 [117-17 mg

middot_ Na 0018- 018 018-18 017-17

4 8 039bullbull ~9 Ca 0039-039 re Pb

039-39

0012-012 c1oo Na 0039-039 Sn 0012- 012

5 8 033-33 re 0033-033 Ph

) ill ~

interstate laboratories inc

Emission Spectra (cont )

Tank metal Aqueous Organic6 8 a53-SJ Na as3-53 Pb aa15- a1 5Fe aa1s-a1s Ca aas bull as mg aa14- a1 4 ~ a18- 18Na a48- 48 aa18-a18Pb middot aa14-a14 aa1 8-a18Zn a48- 48 a18-18c aas- asp a18- 18Sn aa18- a18

aas4-as4_ ~

J

9 Co aa1 - a1 aa1 2- a12No a1-1 Zn a1- 1 aa4- a4Fe aa4- a4 mg aa4-a4v aa12-a12 Pb aaa4- aa4

10 Al aa2-a2Co aa6-6Cr aa2-a2Fe a2-2Pb a2-2mn aa2- a2sl aa5-a6No a6-6Sn aa5-a6Ti a2-2Zn a2- 2

14 8 14-14 aas- asFe Pb

aa14- a14 aas- asOa42-a42 aaasbullbull aa5 (108

-- v aa14- a14 aa1s-a1sZn a014- au aa5-a5 mg aa42- a42 mn a014-a14 K aa14-a14 Ne 042-42 Sn rnu_ n111

)

interstate laboratories inc

11 Total Halogen as Chlcrlde

Tenk Aqueous Orgenic

1 45 2 59 39 3 33 44 4 30 5 10 6 22 65 8 23 22 9 OS 39 14 41 59

Ill BTUs

Tank BTUlb (~r9onic phose _onh)__)

3 6810 8 17530 9 15170 10 11988 11 9774 12 13807

) i002Ho

CHEMICAL bull PHYSICAL

ELECTRICALbull BACTERIOLOGICAL

UCiiNICAL REPORT prenared fQr

CANNONS ENGINEERING CORPORATION

QSE NO 13756

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

)

IIII

~-

~ --~ - middot- middot tmiddot-~6~ middot - middot _ _middot _ l

~slnj ~sulk 6 76tJk Ftrtn

~on -lmbullbullnl 6errtor 7dltl 11-lbullf Jltlals ~( 3TV F4s-~(avltr) (as ~r) oinf middot I (bullf) -JLtlyen -ISlo

lfIIMI ~No lt7orshyD YJeilho- ~2 (oJ) 5000jal mt~d (s-) 3 I lo Bampr~~IJL II J1 (OFshy

Tmiddot v iJI- r(bullf) SOPijAI J bull ~-q To ltot=~ ft~~~ u3 (otj )Ooo_jltl middotNto (bull) IJrlt1 Ne ampitojtJ ltor

tag) 9ooyt --) bull31o 1 e_ Flt~jN- lt7or (bullf) IOOOOjal mbullAltd() aomiddotto BffFi AJs 1lfo lt57shyPIJ OfN]- 1l +5 (Of OOOOj41 iltJ(~J to1o fn lt70r- I~p[L~-~~J( (orJ) 3~-middotmiddots lnJtd(zJ Slo FL ~ N7tJ (7oPPtt-r)

(a f) 100jal j bulllllo middot13 Nlt- bull - bull (o Jshy7 (org) 1SOOjal A~~~~~- 1213of lto _F

l4fJ s-soosa ~ 7tgt() r 8 (psect) looosbull t(bull J2bullto ll(~~Vl t75Jo (70 r-

f OIJ-ol (af) _sectuOo_jal bull 131o MJ 1 1J1 2t (7oFI(PJ bullbullbull 0Y~ shyI (otj) 1-gtoo_s_r LtJampJ bull 3flo 6Jltt~ ~ ltt tgtJ70 (7iil

(bullf) -itooyl )

oslo I 11 1 2o1N _t (7or

N tor~ rnultd u) gt9Q~ 8 Flt1 t11 l 1707 ~(azj ~ ID 6 I fi1 Jj Aitt(J AJ4 7Fs vz~(Pl oil(~ bullbull 1

G GG middotflt rtsuigtmiffcJdr- 6CjMtz Spec F hof0jltn4U fxtrlocor6lf

_ I (ar9) lj-lo

)

shy -middotmiddotmiddot

interstate laboratories inc

Testing RE7sul ts on Tenk rarm

I Emission Spectre (Only metals with concentrations greeter than 100 ppmreported here)

Tank 1

metal 8

Aqueous 1-1

Organic

re 1-1 Pb 01-1 mg 001-01 mn OOl-01 K 003-03 Na 01-1 Sn 001-01 Zn 1-1

2 8 09-9 044-44 Ca 027-27 044-44 Cu 0027-027 re 09-9 044-44 Pb bullbull 09-9 013- 13 mg 009-09 044-44 p 0027~027 K 0027-027

Na 027-27 04-4 Sn 0021-027 Zn 009shy ~09 Ti 1114- 04 v 004-04

3 8 018-18 044-44 Ca 0018-016 re 018-18 [117-17 mg

middot_ Na 0018- 018 018-18 017-17

4 8 039bullbull ~9 Ca 0039-039 re Pb

039-39

0012-012 c1oo Na 0039-039 Sn 0012- 012

5 8 033-33 re 0033-033 Ph

) ill ~

interstate laboratories inc

Emission Spectra (cont )

Tank metal Aqueous Organic6 8 a53-SJ Na as3-53 Pb aa15- a1 5Fe aa1s-a1s Ca aas bull as mg aa14- a1 4 ~ a18- 18Na a48- 48 aa18-a18Pb middot aa14-a14 aa1 8-a18Zn a48- 48 a18-18c aas- asp a18- 18Sn aa18- a18

aas4-as4_ ~

J

9 Co aa1 - a1 aa1 2- a12No a1-1 Zn a1- 1 aa4- a4Fe aa4- a4 mg aa4-a4v aa12-a12 Pb aaa4- aa4

10 Al aa2-a2Co aa6-6Cr aa2-a2Fe a2-2Pb a2-2mn aa2- a2sl aa5-a6No a6-6Sn aa5-a6Ti a2-2Zn a2- 2

14 8 14-14 aas- asFe Pb

aa14- a14 aas- asOa42-a42 aaasbullbull aa5 (108

-- v aa14- a14 aa1s-a1sZn a014- au aa5-a5 mg aa42- a42 mn a014-a14 K aa14-a14 Ne 042-42 Sn rnu_ n111

)

interstate laboratories inc

11 Total Halogen as Chlcrlde

Tenk Aqueous Orgenic

1 45 2 59 39 3 33 44 4 30 5 10 6 22 65 8 23 22 9 OS 39 14 41 59

Ill BTUs

Tank BTUlb (~r9onic phose _onh)__)

3 6810 8 17530 9 15170 10 11988 11 9774 12 13807

) i002Ho

CHEMICAL bull PHYSICAL

ELECTRICALbull BACTERIOLOGICAL

UCiiNICAL REPORT prenared fQr

CANNONS ENGINEERING CORPORATION

QSE NO 13756

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

)

shy -middotmiddotmiddot

interstate laboratories inc

Testing RE7sul ts on Tenk rarm

I Emission Spectre (Only metals with concentrations greeter than 100 ppmreported here)

Tank 1

metal 8

Aqueous 1-1

Organic

re 1-1 Pb 01-1 mg 001-01 mn OOl-01 K 003-03 Na 01-1 Sn 001-01 Zn 1-1

2 8 09-9 044-44 Ca 027-27 044-44 Cu 0027-027 re 09-9 044-44 Pb bullbull 09-9 013- 13 mg 009-09 044-44 p 0027~027 K 0027-027

Na 027-27 04-4 Sn 0021-027 Zn 009shy ~09 Ti 1114- 04 v 004-04

3 8 018-18 044-44 Ca 0018-016 re 018-18 [117-17 mg

middot_ Na 0018- 018 018-18 017-17

4 8 039bullbull ~9 Ca 0039-039 re Pb

039-39

0012-012 c1oo Na 0039-039 Sn 0012- 012

5 8 033-33 re 0033-033 Ph

) ill ~

interstate laboratories inc

Emission Spectra (cont )

Tank metal Aqueous Organic6 8 a53-SJ Na as3-53 Pb aa15- a1 5Fe aa1s-a1s Ca aas bull as mg aa14- a1 4 ~ a18- 18Na a48- 48 aa18-a18Pb middot aa14-a14 aa1 8-a18Zn a48- 48 a18-18c aas- asp a18- 18Sn aa18- a18

aas4-as4_ ~

J

9 Co aa1 - a1 aa1 2- a12No a1-1 Zn a1- 1 aa4- a4Fe aa4- a4 mg aa4-a4v aa12-a12 Pb aaa4- aa4

10 Al aa2-a2Co aa6-6Cr aa2-a2Fe a2-2Pb a2-2mn aa2- a2sl aa5-a6No a6-6Sn aa5-a6Ti a2-2Zn a2- 2

14 8 14-14 aas- asFe Pb

aa14- a14 aas- asOa42-a42 aaasbullbull aa5 (108

-- v aa14- a14 aa1s-a1sZn a014- au aa5-a5 mg aa42- a42 mn a014-a14 K aa14-a14 Ne 042-42 Sn rnu_ n111

)

interstate laboratories inc

11 Total Halogen as Chlcrlde

Tenk Aqueous Orgenic

1 45 2 59 39 3 33 44 4 30 5 10 6 22 65 8 23 22 9 OS 39 14 41 59

Ill BTUs

Tank BTUlb (~r9onic phose _onh)__)

3 6810 8 17530 9 15170 10 11988 11 9774 12 13807

) i002Ho

CHEMICAL bull PHYSICAL

ELECTRICALbull BACTERIOLOGICAL

UCiiNICAL REPORT prenared fQr

CANNONS ENGINEERING CORPORATION

QSE NO 13756

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

) ill ~

interstate laboratories inc

Emission Spectra (cont )

Tank metal Aqueous Organic6 8 a53-SJ Na as3-53 Pb aa15- a1 5Fe aa1s-a1s Ca aas bull as mg aa14- a1 4 ~ a18- 18Na a48- 48 aa18-a18Pb middot aa14-a14 aa1 8-a18Zn a48- 48 a18-18c aas- asp a18- 18Sn aa18- a18

aas4-as4_ ~

J

9 Co aa1 - a1 aa1 2- a12No a1-1 Zn a1- 1 aa4- a4Fe aa4- a4 mg aa4-a4v aa12-a12 Pb aaa4- aa4

10 Al aa2-a2Co aa6-6Cr aa2-a2Fe a2-2Pb a2-2mn aa2- a2sl aa5-a6No a6-6Sn aa5-a6Ti a2-2Zn a2- 2

14 8 14-14 aas- asFe Pb

aa14- a14 aas- asOa42-a42 aaasbullbull aa5 (108

-- v aa14- a14 aa1s-a1sZn a014- au aa5-a5 mg aa42- a42 mn a014-a14 K aa14-a14 Ne 042-42 Sn rnu_ n111

)

interstate laboratories inc

11 Total Halogen as Chlcrlde

Tenk Aqueous Orgenic

1 45 2 59 39 3 33 44 4 30 5 10 6 22 65 8 23 22 9 OS 39 14 41 59

Ill BTUs

Tank BTUlb (~r9onic phose _onh)__)

3 6810 8 17530 9 15170 10 11988 11 9774 12 13807

) i002Ho

CHEMICAL bull PHYSICAL

ELECTRICALbull BACTERIOLOGICAL

UCiiNICAL REPORT prenared fQr

CANNONS ENGINEERING CORPORATION

QSE NO 13756

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

)

interstate laboratories inc

11 Total Halogen as Chlcrlde

Tenk Aqueous Orgenic

1 45 2 59 39 3 33 44 4 30 5 10 6 22 65 8 23 22 9 OS 39 14 41 59

Ill BTUs

Tank BTUlb (~r9onic phose _onh)__)

3 6810 8 17530 9 15170 10 11988 11 9774 12 13807

) i002Ho

CHEMICAL bull PHYSICAL

ELECTRICALbull BACTERIOLOGICAL

UCiiNICAL REPORT prenared fQr

CANNONS ENGINEERING CORPORATION

QSE NO 13756

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

) i002Ho

CHEMICAL bull PHYSICAL

ELECTRICALbull BACTERIOLOGICAL

UCiiNICAL REPORT prenared fQr

CANNONS ENGINEERING CORPORATION

QSE NO 13756

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

---~oT~~~~middot----middot---- ___-shyr~-rli~ALt1tUt-il middot middot----------------------

04 November 1980

rat~c 1 ot J

Cannons Engineering Corporation First Street shyBridgewater MA 02324

Attention Mr To ny Salina

~ 13756

~ Per Request of Dr Kathleen Swallow

PROJECT DESCRIPTION

Analysis of four (4) waste samples

SA1PLE IDENTIFICATION

Four (4) bottles of waste identified as follows

1 Ot 4 Tank lA Plymouth 2 of 4 - Tank 18 Plymouth 3 of 4 - Tank 2 Plymouth 4 of ~ - Ta~k 2 Plymouth

Samples received OS September 1980

METHOO OF TEST

Emission Spectrographic Analysis Parr BoruQ Ignition - Total Haloq~ns

EaCh s~ple was shaken and tr~nsferred to a centrifuge tube After one hour the samples wereexarttinecf_for evidence of stratification The samples middot were then centrifuged and examined again

Composites of samples 1 and 2 and of samples 3 and 4 were prepared Determination of total haloge ns and semi - quantitative emission spectrographic analysis were performed on the composite s amples

(~11

~- _ _ __n_ _ _ __ __ ~

____~bull~~ooo- loc_i~ -_ -Nomiddotl_ _ u -- _ _~ - bull _ _ _ _ bullbullbullt - _ _

loo _OOI M lt-bullu-w tl o~ -- -- - - _ _l _ltll ~-

New England Laboratories

) Jfo~~~~middotmiddotmiddot middot 04 November 1980

Page 2 of 3

Cannons Engineering Corporation~

13756CASE NO

~middot The samples exhibited no stratification after being allowed to settle one hour After centrifuging each middotsample separated into three layers a dark oily top layer a dark brown aqueous middle layer and a bottom layer of grayish-brown sediment The results are sununarized below

Percent br volume

Dark brown

Oily l ayer (toE l azer )

aqueous layer (middle larcr)

Sediment (bo t tom lazer)

Plymouth Ta nk lA (sample 1 of 4 l

10 86

Plymo)Jth Tank lB (s ainp l e 2 of 4 l

-n

Plymouth Ta nk 2 ~0 65 15

(s amp le 3 of 4)

Plymouth Tank 2 (sample 4 o f 4 l

50 30 20

Emission spectrographic Analysis as Received Range )

Compos te 3 4cameos r te 1

0013 - 013ooo1 - oorAluminum 0000000 - 0000004 BariWll 0004 - 0 04 0002- 002Boron 004 - 04omiddoto2 - o middot2calcium 0 00004 - 0 00040000000 - 0000002Chromium

(12

n-middot-middot-- ~_-n _ _ ~ --~-- - -- ~~ _- ---s--bullso-ws~bullbull~oa-bull~oobull--middotmiddot M rLobull- ~ -r ~ bull bull - - _h _ -- __-lbull _ -~_ - - _ _ -middot --bullbull-rbullbullmiddotbull---J_ ~ _-middot- - middot

~Ifamp sfflnTiiffll JaJ8JIDffiiJ3rDilMS ampilcr -New England Laboratories

- -- -middot middot- - TUOI~ t t bull CCA f~l t~ms 02254 fl 617-SQo-72

) 04 November 1980

Page 3 of 3

Cannons poundnqinccring C~rporation~

13756CASE NO

composite 3 comoosite 1 2

0004 - 00400002 - 0002Copper 04 - 4002 - 20Iron 004 - 04002 - 02Lead 0 4 - 4 o 02 - 20Magnesium 0 004 - 0040002 - 002Manganese 00004 - 000400002 - 0 002

Nickel 0013 - 0130 007 - 001Phosphorus 0013 - 0 130007 - 001Silicon 0 4 - 4002 - 20Sodium 0013 - 0130002 - 002

Tin 0 004 - 004

0002 - 002Titanium 004 - 0400002 - 0002 0013 - 013=)~~diWil 002 - 0 2

Ash cOntent~ 4 23 2 31 by weight

Total halogens 193 (as Cl) by 143

weight

Respectfully Submitted

SKINNER SHERMAN LABORATORIES INC

~aud~r~~ - 8Daniel Wetnore Chemist

DWls

---tl-middotshy ___ -__ _ 110 - ~~ middot _ bull---~middot middotu- bulls-t _ middot-w--bull- shy____ ___--_ - - _ lo - ___ - -- - middotbull - -

)

middot middot tmiddot~-rmiddot middot

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1. barcode 557888
2. barcodetext SDMS Doc ID 557888

)

middot middot tmiddot~-rmiddot middot

~~~middot middot ~(~middot

----------- NOnCE If tho film Image

CAJIfON IIIIGIIIUIUJia (BRIDollliAlD)lo 1101 clear than thla

ADHDfiSIRAlIVE ucoaonotice It It due to the

of the document

__ ~

----i __ lt-)_ --~- I

lliil middoti ---------lt --~middot----

middotmiddotmiddot)

--r~~~

middot-ymiddotshy- middot ~middot middotmiddot

lbull-~gt16 bull wldb76 (t0)wJijjigt0J fj1J1i LOI

______ r-yAi PV~rll ~~tnbJo

~11 ~tampv -bY _ lJ~J~o~raquoyoL ~~ulbullampf Y~

(n) AbullP bullrJ-ZI( (

~

1. barcode 557888
2. barcodetext SDMS Doc ID 557888

middot middot tmiddot~-rmiddot middot

~~~middot middot ~(~middot

----------- NOnCE If tho film Image

CAJIfON IIIIGIIIUIUJia (BRIDollliAlD)lo 1101 clear than thla

ADHDfiSIRAlIVE ucoaonotice It It due to the

of the document

__ ~

----i __ lt-)_ --~- I

lliil middoti ---------lt --~middot----

middotmiddotmiddot)

--r~~~

middot-ymiddotshy- middot ~middot middotmiddot

lbull-~gt16 bull wldb76 (t0)wJijjigt0J fj1J1i LOI

______ r-yAi PV~rll ~~tnbJo

~11 ~tampv -bY _ lJ~J~o~raquoyoL ~~ulbullampf Y~

(n) AbullP bullrJ-ZI( (

~

1. barcode 557888
2. barcodetext SDMS Doc ID 557888

----------- NOnCE If tho film Image

CAJIfON IIIIGIIIUIUJia (BRIDollliAlD)lo 1101 clear than thla

ADHDfiSIRAlIVE ucoaonotice It It due to the

of the document

__ ~

----i __ lt-)_ --~- I

lliil middoti ---------lt --~middot----

middotmiddotmiddot)

--r~~~

middot-ymiddotshy- middot ~middot middotmiddot

lbull-~gt16 bull wldb76 (t0)wJijjigt0J fj1J1i LOI

______ r-yAi PV~rll ~~tnbJo

~11 ~tampv -bY _ lJ~J~o~raquoyoL ~~ulbullampf Y~

(n) AbullP bullrJ-ZI( (

~

1. barcode 557888
2. barcodetext SDMS Doc ID 557888