Analysis of Hydroxyl Radical Reactivity in the Sierra Nevada Mountains

8/20/2019 Analysis of Hydroxyl Radical Reactivity in the Sierra Nevada Mountains

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Cmrlstmn, Oulkm H.=1 Scbriener, Omsi` T.41Deyersnirj, M`nrems O.31 Dlmae, Ni`mln T.4

=

U`kverskty ij Wmsbk`gti`4U`kverskty ij Cmlkjir`km Krvk`e3@MSM Lm`gley Tesemrcb Ce`ter

Stune`t Mkrdir`e Tesemrcb Vrigrmh (SMTV) 46=5


2/31

! @VS k`nkcmtes tbmt hm`y pmras bmve bkgb levelsij iziè-hmxkhuhs mriu`n 26 ppd

! EVM hm`nmtes hmxkhuh iziè levels ij 75ppd

! Iziè khpmcts buhm`, m`khml,m`n vegetmtkve bemltb

Ak`g‛s Cm`yi` @V [isehkte @V

@VS


3/31

! Bkgb levels ij izi`e see` k` sktu mdive Skerrm@evmnms

! Wk`ns mre hivk`g ti tbe Emst

! @Ix ci`ce`trmtki`s ij 7 ppd k` Hmnerm

k`nkcmte urdm` pillutki`

@VS

CM Mkr Tesiurces Dimrn


4/31


5/31

Smhple

Tegki`

[isehkte @V

Sequikm m`n

Ak`gs Cm`yi` @V


6/31

37.3

37.4

37.=

37.6

3:.;

3:.2

3:.7

L m t k t u n e

-=46.6 -==;.2 -==;.: -==;.> -==;.4 -==;.6 -==2.2Li`gktune


7/31

37.3

37.4

37.=

37.6

3:.;

3:.2

3:.7

L m t k t u n e

-=46.6 -==;.2 -==;.: -==;.> -==;.4 -==;.6 -==2.2Li` ktune

;6

26

76

:6

56

>6

36

Iz i` eH

k x k ̀ gT m t k i ( p p d v )

Hmxkhuh I

3

73 ppdv

^ipigrmpbkc

dmcagriu`n

Smhples deliw

3666 jt MGL


8/31

37.3

37.4

37.=

37.6

3:.;

3:.2

3:.7

L m t k t u n e

-=46.6 -==;.2 -==;.: -==;.> -==;.4 -==;.6 -==2.2Li` ktune

;6

26

76

:6

56

>6

36

Iz i` eH

k x k ̀ gT m t k i ( p p d v )

Dix = Dix 4 Dix 3

Hmxkhuh I

3

73 ppdv

^ipigrmpbkc

dmcagriu`n

Smhples deliw

3666 jt MGL


9/31

! IB rmnkcml remctkvkty cm` de usen ti k`nkcmte

izi`e jirhmtki` pite`tkml k` priperci`nktki`s

Omcid, N (=;;;)


10/31

! CI

! Hetbmè

! @i`-Hetbmè Mlamès? etbmè, pripmè,dutmè, pe`tmè, k-pe`tmè, bexmè, beptmè,4,3-nkhetbyldutmè, cyclipe`tmè

! Mlaeès? etbeè, pripeè, trm`s-4-duteè,cks-4-duteè

! Dkige`kcs? ksipreè, mlpbm-pkèè, detm-pkèè

! Mrihmtkcs? de`zeè, tilueè

Mtak`si`, T1 Mrey, O. (4663)


11/31

Mvermge griu`n elevmtki`? ;=; jt

îtml IB Tmnkcml Temctkvkty? =.7 ½ 6.5 s-= (=! )

îpigrmpbkcdmcagriu`n

37.3

37.4

37.=

37.6

3:.;

3:.2

3:.7

L m t k t u n e

-=46.6 -==;.2 -==;.: -==;.> -==;.4 -==;.6 -==2.2Li`gktune

;6

26

76

:6

56

>6

36

Iz i` eHk x k ̀ gT m t k i ( p p d v )

Jlkgbt 5? Jlkgbt ^rmca Vlitten wktb respect ti Iziè


12/31

Hkxk`g Tmtki (ppd)

Hetbmè =;46

CI ==7@i`-HetbmèMlamès

=.36

Mlaeès 6.65;

Mrihmtkcs 6.6>4

Dkige`kcs 6.=>;

îtml IB Tmnkcml Temctkvkty?=.7 ½ 6.5 s-= (=! )


13/31

Mvermge griu`n elevmtki`? 337; jt

^itml IB Tmnkcml Temctkvkty? =.> ½ = s-= (=! )


37.3

37.4

37.=

37.6

3:.;

3:.2

3:.7

L m t k t u n e

-=46.6 -==;.2 -==;.: -==;.> -==;.4 -==;.6 -==2.2Li`gktune

;6

26

76

:6

56

>6

36

Iz i` eHk x k ̀ gT m t k i ( p p d v )



14/31

! Lmrge grmnke`t mcriss dix

5>34=

IB Tmnkcml Temctkvkty (s-=)

=6x=63

2

:

>

4

T m n

m r M l t k t u n e ( j t )

IB Tmnkcml Temctkvkty wktb respect ti Mltktune k` Dix 4


15/31

Hkxk`g Tmtki (ppd)

Hetbmè =;36


=.36

Mlaeès 6.=36

Mrihmtkcs 6.6:;

Dkige`kcs 6.>65

îtml IB Tmnkcml Temctkvkty?=.> ½ = s-= (=! )


16/31

Mvermge griu`n elevmtki`? ::54 jt

^itml IB Tmnkcml Temctkvkty? 6.2 ½ 6.3 s-= (=! )


37.3

37.4

37.=

37.6

3:.;

3:.2

3:.7

L m t k t u n e

-=46.6 -==;.2 -==;.: -==;.> -==;.4 -==;.6 -==2.2Li`gktune

;6

26

76

:6

56

>6

36

Iz i` eHk x k ̀ gT m t k

i ( p p d v )



17/31

Hkxk`g Tmtki (ppd)

Hetbmè =;66

CI =6:@i`-HetbmèMlamès

=.36

Mlaeès 6.62>

Mrihmtkcs 6.654

Dkige`kcs 6.=:3

îtml IB Tmnkcml Temctkvkty?6.2 ½ 6.3 s-= (=! )


18/31

Mvermge ^itml

Temctkvkty s

-=

)

Hmxkhuh

Temctkvkty s

-=

)

Hk`khuh

Temctkvkty s

-=

)

Dkige`kc

K`jlue`ce

Dix = =.7 ½ 6.5 4.3 6.7 4>%

Dix 4 =.> ½ = >.2 6.5 3;%

Dix 3 6.2 ½ 6.3 =.7 6.5 3=%

`8=: `8=4 `846


19/31

3>.4

3>.6

33.2

33.:

L m t k t u n e

-==2.> -==2.4 -==2.6 -==7.2 -==7.:Li`gktune

;6

26

76

:6

56

>6

36

Iz i` e

Hk xk ` gT m t k i ( p p d v )

Jlkgbt 3? Jlkgbt ^rmca Vlitten wktb

respect ti Izi`e Ci`ce`trmtki`

Hmxkhuh I

3

;4 ppdv

^ipigrmpbkc

dmcagriu`n

Smhples

deliw3666 jt MGL


20/31

Hkxk`g Tmtki (ppd)

Hetbmè =;:6


3>43

Mlaeès 6.6:2

Mrihmtkcs 6.67:

Dkige`kcs 6.6=6

îtml IB Tmnkcml Temctkvkty?=.= ½ 6.: s-= (=! )


21/31

! Dkige`kc k`jlue`ce k` tbe Skerrm @evmnmhiu`tmk`s ks stmtkstkcmlly skg`kjkcm`t

V-vmlue

Dix = 6.66=

Dix 4 6.64

Dix 3 6.666=


22/31

Mvermge griu`n elevmtki`? 433 jt

^itml IB Tmnkcml Temctkvkty? =.= ½ 6.: s-= (=! )

`8>2 `843`8=:


23/31

! IB rmnkcml remctkvkty jir liw m`n hkn-

elevmtki` sktes k` tbe Skerrm @evmnm hiu`tmk`sks bkgber tbm` k` LM, k`nkcmtk`g bkgb levels ijiziè jirhmtki`.

! Dkige`kc cihpiu`ns bmve m skg`kjkcm`tk`jlue`ce i` iziè jirhmtki` pite`tkml k` tbehiu`tmk`s tbmt ks ìt see` k` LM.

! Vritecten lm`ns mre stkll dek`g nmhmgen dym`tbripige`kc mkr pillutki` khpmctk`g tbebemltb ij vksktirs, vegetmtki`, m`n wklnlkje.


24/31

!

Vrijessir Ni` Dlmae! Nr. Omsi` Scbriener

!

Dlmae-Tiwlm`n Lmd

! Nr. Ehkly Scbmller

! Tkca Sbetter!

@SETC

! Sem` Jreehm`

!

S`mae ‒`‛ Dlmae temh


25/31

! Mkr ]umlkty K`jirhmtki`. @mtki`ml Vmra Servkce. Wed. 36 Ouly

46=5.

! M]HKS Hmnerm Ciu`ty. Mkr Tesiurces Dimrn. Wed. 36 Ouly

46=5.

! Mtak`si`, T1 Mrey, O.“ Mthispberkc Negrmnmtki` ij Zilmtkle

Irgm`kc Cihpiu`ns.‘ Cbeh. Tev. =63 ( 4663)? >:65->:32.Vrk`t.

! Elevmtki`s m`n nkstm`ces k` tbe U`ktes Stmtes. US Nepmrthe`tij tbe K`terkir. Mpr 4665. Wed. Ouly 43 46=5.

! Omcid, N1 K`trinuctki` ti Mthispberkc Cbehkstry. Vrk`ceti`

U`kverskty Vress, =;;;. Vrk`t.

! @mtki`ml Mhdke`t Mkr ]umlkty Stm`nmrns. US E`vkri`he`tmlVritectki` Mge`cy. Ict 4= 46=>. Wed. 47 Ouly 46=5.


26/31


27/31

! IB rmnkcml remctkvkty jir liw m`n hkn-

elevmtki` sktes k` tbe Skerrm @evmnm hiu`tmk`sks bkgber tbm` k` LM, k`nkcmtk`g bkgb levels ijiziè jirhmtki`.

! Dkige`kc cihpiu`ns bmve m skg`kjkcm`tk`jlue`ce i` iziè jirhmtki` pite`tkml k` tbehiu`tmk`s tbmt ks ìt see` k` LM.

! Vritecten lm`ns mre stkll dek`g nmhmgen dym`tbripige`kc mkr pillutki` khpmctk`g tbebemltb ij vksktirs, vegetmtki`, m`n wklnlkje.


28/31

Ivermll Mvermge Temctkvkty (s-=) Dkige`kc K`jlue`ce

Dix = =.2 ½ 6.7 =2%

Dix 4 =.; ½ =.5 33%

Dix 3 =.= ½ 6.> 43%

Lis M`geles =.: ½ 6.: 4%


29/31


30/31

bttp?//www.k`tecbipe`.cih/diias/mthispberkc-merisils-regki`ml-cbmrmcterkstkcs-cbehkstry-m`n-pbyskcs/prinuctki`-ij-seci`nmry-irgm`kc-merisil-jrih-hultkpbmse-hi`iterpe`es


31/31

! M`mlysks ij merisil ci`ce`trmtki` nue ti

dkige`kc m`n m`tbripige`kc siurces! M`mlysks wktb @Ix, bynrige`, ixyge`mtes,

suljmtes

Analysis of Hydroxyl Radical Reactivity in the Sierra Nevada Mountains

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