UNITED STATES

DEPARTMENT OF THE INTERIOR

GEOLOGICAL SURVEY

ANALYSES OF ROCK SAMPLES FROM THE

KETCHIKAN QUADRANGLE, SOUTHEASTERN ALASKA

OPEN-FILE REPORT 78-156-A

This report is preliminary and has not been edited or reviewed for conformity with Geological Survey standards and nomencla- ture

Menlo Park, California

UNITED STATES

DEPARTMENT OF THE lNT ERlOR

GEOLOGICAL SURVEY

ANALYSES OF ROCK SAMPLES FROM THE

KETCHIKAN QUADRANGLE, SOUTHEASTERN ALASKA

By R D. Koch and R. L. Elliott

OPEN-FILE REPORT 78-156A

This report i s preliminary and has not been edited or reviewed for conformity with Geological Survey standards and nomencla- ture

Menlo Park, Califomin

Table of Contents

Page

Introduction ............................................. 1

Geologic s tud ies i n the ~ e t e h i k a n area ------------------ 2

Sampling ................................................. 3

Sample preparat ion and ana ly t i ca l procedures ------------- Geochemical d a m .........................................

Analytical values -------------------------Ah--------

Precision ........................................... Sta t i s t i ca l summary ......................................

Bias and v a r i a b i l i t y a f fec t ing in te rp re ta t ion ------------ Achawl&grnents .......................................... References c i t ed .........................................

I l l u s t r a t i o n s

P la te I. Map showing rock sample locat ions.

Tables

Table 1. Lower determination limits and u n i t s fo r analyses- 6

2 . Qual i f i ca t ion codes ............................. 5

3 . Class intervals of t h e six-step sca le ----------- 7

4. Rock name and mineral modifier codes ------------ 1 7

5. S h t i s t i c a l summary ............................. 19

6. Analytical da ta f o r rock geochemical samples ---- 5 6

Analyses o f rock samples f r o m

Ketchikan quadrangle, southeas te rn Alaska

by

R. D. Koch and R. L. E l l i o t t

f ntroduct ion

.A reconnaissance geochemical sampling program was conducted between

1975 and 1977 i n t h e Ketchikan and Pr ince Rupert 1:250,000-scale quad-

rangles , southeastern Alaska. This study was done t o a s s i s t i n a

mineral resource eva lua t ion of t h e a r ea a s p a r t of the Alaska Mineral

Resource Assessment Program (AMRAP). This r e p o r t conta ins t he ana ly t -

i c a l d a t a f o r 1 ,591 rock samples co l l ec t ed i n the Ketchikan quadrangle

during t h i s and previous U.S. Geological Survey mapping p r o j e c t s be-

tween 1968 and 1977. These samples comprise a l l o f the normal rock

geochemical samples co l l ec t ed during t h e U.S. Geological Survey geolog-

i c a l napping inves t iga t ions wi th in t h e Ketchikan quadrangle through 1977.

A b r i e f s t a t i s t i c a l summary of t h e a n a l y t i c a l data i s included i n t h i s

r e p o r t .

Analy t ica l da t a from stream-sediment geochemical sampling wi th in

t h e Ketchikan quadrangle and from a l l geochemical sampling i n the Pr ince

Rupert quadrangle d i r e c t l y south of the Ketchikan quadrangle, a r e con-

ta ined i n two companion r e p o r t s (Koch and E l l i o t t , 1978a, 1978331. Geo-

chemical da t a from the : sou the rn po r t ion of t h e Bradfield Canal qwd-

r ang le ( d i r e c t l y north of the Ketchikan quadrangle) a r e repor ted i n

Koch and o t h e r s (1976a). Analyt ical data from rock samples co l l ec t ed

by U.S. Bureau of Mines' engineers during the Grani te Fiords Wilderness

Study (Berg and o the r s , 1977a) were included i n a previous work (Koch

and o t h e r s , 1976b). Data from all of t h e normal U.S. Geological Survey

rock and stream-sediment geochemical samples co l l ec t ed i n t h e Ketchikan

and Prince Rupert quadrangles a r e a v a i l a b l e on magnetic computer tape

(Koch, Van Trump, and McDanal, 1978) .

Geologic s t u d i e s i n t h e Ketchikan area

The western ha l f of t h e Ketchikan quadrangle i s under la in by a

broad b e l t o f r eg iona l ly metamorphosed Paleozoic and Mesozoic sedi-

mentary and volcanic rocks which grade f r m gxeenschis t t o amphibolite

f a c i e s . These rocks a r e in t ruded by numerous g r a n i t i c s tocks of Cre-

taceous t o Miocene age. Gran i t i c and amphibolite-grade r eg iona l ly meta-

morphosed rocks of t he Coast Range metamorphic-plutonic c m p l e x occur

throughout t h e e a s t e r n and northern po r t ions of t h e quadrangle.

The e a r l i e s t comprehensive d iscuss ions of the geology of t h e

Ketchikan area a r e contained i n r e p o r t s by Wright and Wright (1908)

and Buddington and Chapin (1929). Buddington (1929) a l s o descr ibed

t h e Hyder mining d i s t r i c t loca ted near the Canadian border 120 km

no r theas t of Ketchikan. Other d iscuss ions of t h e geology of t h i s

area include a r e p o r t by Hutchison (1970) on the Coast Range meta-

morphic-plutonic complex i n t h e Pr ince Rupert reg ion of B r i t i s h Columbia

and a sumnary of t h e Coast Range metamorphic-plutonic complex by Roddick

and Hutchison (19741 . Recent geologic i n v e s t i g a t i o n s by the U . S . Geological Survey i n t h e

Ketchikan quadrangle began i n 1966 with mapping on Annette I s l and (Berg,

1972) . Mapping began on Gravina I s l and i n 1967 e erg, 1973; B e r g , Jones,

and Richter , 1972) and i n t h e Hyder area i n 1968 ( S m i t h , 1977). Recon-

naissance mapping i n t h e Nakat Bay-Boca de Quadra area was carried out

i n 1969 and 1970 (Smith, 1973). A mineral resource evaluation of t h e

Granite Fiords Wilderness Study area e a s t of e a s t B e b Canal was con-

ducted i n 1972 and 1973 (Berg and others, 1977a). F ie ld s tudies con-

tinued as part of the AMRAP program from 1975 t o 1977 (Berg, E l l i o t t ,

and Koch, 1976; E l l i o t t , Smith, and Hudson, 1976; Berg and others,

L977b). Reconnaissance mapping o f t h e Ketchikan and Prince Rupert

quadrangles has been completed and a geologic map a t a sca le of

1:250,000 has been published (Berg and o thers , 1978).

Sampling

Standard procedures were followed i n co l l ec t ion , preparat ion, and

ana lys i s of rock geochemical samples. The samples are primarily grab

samples chosen t o provide data on background values fo r a lithologic

u n i t . The majoxity of these samples a r e representa t ive of the domi-

nant l i tho log ies a t the sample s i t e . A l e s s e r number of samples were

col lec ted from minor l i tho log ies , known mineralized occurrences, o r

outcrops that a r e conspicuously iron-stained o r contain v i s i b l e metal-

l i c minerals.

Sample preparat ion and ana ly t i ca l procedures

Samples were crushed, a s p l i t was pulverized and a s p l i t of t h i s

material analyzed. Analyses were performed by the Branch of Exploration

Research of the U . S . Geological Survey for up to 30 elements by the six-

s t e p semiquantitative emission spectrographic method (Grimes and

Marranzino, 1968), and f o r gold, copper, lead and zinc by atomic

absorption spectrophotmetry (Ward and o the r s , 1969) - Samples col lec ted in

1972 and 1973 were analyzed f o r mercury by a flameless atomic absorption

mercury-vapor detection technique (Vaughn and McCarthy, 1964). Some

analyses were not performed on a l l samples. The semiquanti tat ive

spectrographic analyses w e r e performed by J. E, Abrams, E. F. CooZey,

K. J. Curry, G. W. Day, C. L. Forn, R. T. Hopkins, R. C. KarLson,

J. W. McNamera, and D. F. Siems. The atomic absorption analyses

were done by R. B. Carten, J, A. Criswell , D. E. Detra, J. D. Hoffman,

R. W. Leinz, A. L. Meier, R. L. Miller, D. G. Muxrey, R. M. O'Leary,

J. A . Roybal, R. F. Sanzolone, A. J. Toevs, and W. W. Vaughn.

Geochemical data

Locations of rock sample sites a r e iden t i f i ed by s t a t i o n numbers

on plate 1. The a n a l y t i c a l data f o r the samples a re 'g iven i n t a b l e 6

and a r e iden t i f i ed by station number w i t h a letter appended t o the

s t a t i o n number t o d i s t ingu i sh d i f f e r e n t samples from the same station.

Some samples were re-analyzed a s part of a t e s t of ana ly t i ca l variance.

These sample numbers appear twice i n t a b l e 6 along with da ta f o r both

analyses.

Each sample has been assigned a rock type and is labeled i n

t a b l e 6 with a rock name code consis t ing of a tm-letter rock-name

symbol which may be followed by one o r more two-letter mineral-mdifier

symbols. An explanation of these rock-name and mineral-nwdifier codes

is l i s t e d i n t a b l e 4 (p. 17).

Analy t ica l Values

Analy t ica l r e s u l t s a r e repor ted a s percent of t h e sample ( f o r

spectrographic ana lyses o f Fe, M g , Ca, and T i ) and as parts pe r mi l l i on

(pprn) for a l l o the r analyses . The minimum l i m i t s o f determinat ion and

the u n i t s used f o r each a n a l y s i s are l i s t e d i n table 1 (p. 6).

A s i n g l e - l e t t e r symbol i s used by USGS a n a l y s t s t o i n d i c a t e t h a t

no a n a l y s i s w a s performed for a n element or t h a t t h e a n a l y t i c a l r e s u l t

is o u t s i d e the limits of de te rminabi l i ty . These symbols (commonly

c a l l e d "qua l i f i ca t ion codes") a r e used i n t he s t a t i s t i c a l sununary but

some a r e represented d i f f e r e n t l y i n t h e data t a b l e . An explanat ion

of both forms i s l i s t e d i n t a b l e 2. The code T does not appear i n

t hese da t a .

Table 2 . - - ~ u a l i f ica t i o n C sdes . Qua l i f i ca t ion Form in

code t a b l e 6 Explanation

B - - N o a n a l y t i c a l data f o r t h i s ana lys i s .

N N Nothing de tec ted by ana lys i s .

c Element de tec ted but below l i s t e d value (lower l i m i t of de t e rminab i l i t y ) .

> Element de tec ted i n amount g r e a t e r than

l i s t e d va lue (upper l i m i t o f determina- b i l i t y ) .

H (value = 0) In t e r f e rence - no v a l i d data.

Because the o r i g i n a l computer p r i n t o u t is used i n t h e t a b l e s , e le -

ment symbols a r e i n c a p i t a l l e t t e r s : f o r example, the symbol f o r i r o n ,

Fe, i s shown a s FE, magnesium, M g , is shown a s MG, and so on. I n t h e

Table 1. Lower determination limits and units for analyses performed Exom

1968 through 1977. S - indicates spectrographic analysis, AA - indicates atomic absorption analysis and INST - indicates flameless

atomic absorption mercury-vapor analysis. The units used to re-

port values for each analytical procedure are l is ted after the

determination l i m i t .

S-AT-------- - 5 ppm S-Mo--------- 5 PFPn S-Zr----------- 10 Ppm

S-As--------- 200 ppn S-N2'------- 20 PPm AA -Au.Z/- - - - - - - - -05 Ppm

S-Au--------- 1 0 ppm S - N i -------- 5 PPm M - C u - -- - -- - --- 5 PPm

S-B- --------- 10 ppm S-pb--------- 10 Pan W-Pb---------- 5 P P

S-Ba/------- 20 ppm S-Sb-------- 100 ppm AA-zn---------- 5 PPm

S-Be--------- 1 ppm S-Sc--------- 5 PPm . 0 2 ppm

S-Bi--------- 10 ppm S-Sn--------.. 1 0 P P

5 ppn prior to 1970.

4' 10 ppm prior to 1975.

- " -02 ppn prior to 1972.

- 6/ .01 ppn prior to 1972.

tables, the p r e f i x S stands f o r spectrographic a n a l y s i s , AA for atomic

absorp t ion and INST for f lameless atomic absorp t ion mercury-vapor

ana lys i s .

Resul t s from semiquant i ta t ive emission spectrographic ana lyses

(also r e f e r r ed to as s ix-s tep spectrographic ana lyses) are repor ted

as the midpoints of geometric c l a s s i n t e r v a l s . Midpoints of the c l a s s

i n t e r v a l s and t h e assoc ia ted c l a s s i n t e r v a l boundaries are listed i n

t a b l e 3. Reported va lues may be an i n t e g r a l power of 10 times one of

t h e l i s t e d c l a s s i n t e r v a l midpoints.

Table 3 . Class i n t e r v a l s of t h e s ix-s tep sca l e .

Class I n t e r v a l M i d p i n t C l a s s I n t e r v a l Limits

1.0 0.83 1.2

1 .5 1.2 1.8

2.0 1.8 2 .6

3.0 2.6 3.8

5.0 3.8 5.6

7.0 5.6 8 . 3

10.0 8.3 12.0

P rec i s ion

Tests have been performed t o determine t h e a n a l y t i c a l p rec i s ion

of the s ix-s tep semiquant i ta t ive spectrographic technique used by t h e

Branch of Explorat ion Research (Motooka and Grimes, 1976). These t e s t s

i n d i c a t e that the frequency with which values from repeated analyses

of the same sample w i l l f a l l within t h e c l a s s interval containing the

"true" value ( a s measured by t h e mean of a s e r i e s of a n a l y t i c a l r u n s ) ,

p lus o r minus one and two adjoining i n t e r v a l s is approximately 83 per-

c e n t and 96 percent, respectively. For example, i f a value k s reported

as 3.0, the p r o w i l i t y is -83 t h a t a repeated analys is w u l d be re-

ported as 2.0, 3.0, or 5.0. T h i s study found a n a l y t i c a l variance to

be consistent f o r a variety of geologic materials and t o show no

appreciable d i f ference between elements or concent ra t ion ranges ex-

cep t near the l i m i t s of determinabil i ty. Another experiment (Johnson

and o t h i r s , 19771 suggests that ana ly t i ca l pxecision v a r i e s appre-

c iably between elements. Analyses by the atomic absorption m e t b d s

are not reported on the six-step sca le ; they a r e more sens i t ive and

more p rec i se than spectrographic analyses.

S t a t i s t i c a l summary

The ana ly t i ca l da ta were processed by a computer program known

as GEOSUM and the program's output is presented i n t a b l e 5. For sam-

ples which have been re-analyzed, the values l i s t e d second i n the data

t a b l e have been arbitrarily omitted from t h e s t a t i s t i c a l summary t o re-

duce bias . The GEOSUM program i s designed t o summarize and tabula te

geochemical data--primarily from semiquanti tat ive spectrographic analy-

ses. A l l d i s t r i b u t i o n s a re t r ea ted i n terms of the six-step class

i n t e r v a l s described above and thus the atomic absorption data are

regrouped to fit into these i n t e rva l s . The program output consists

of: (a) a frequency d i s t r i b u t i o n table , histogram, summary of quali-

fied values, range of values and geometric mean and deviat ion f o r each

element, and (b) a s t a t i s t i c a l summary for all elements, which includes

geometric means and geometric deviat ions.

The histograms are on a logari thmic s c a l e and a r e computed using

the c l a s s i n t e r v a l s of t h e .s ix-s tep semiquant i ta t ive s ca l e . The h i s to -

gram b a r s a r e canposed of X ' s ; each X r ep re sen t s approximately 1 per-

cent of the t o t a l number of samples analyzed f o r t h a t element. Decimal

numbers are p r i n t e d by the computer as powers of 10 , f o r example:

-1 ' 7.0e-01 means 7 . 0 ~ 1 0 o r 0.7

7.0ei00 means 7 . 0 x 1 0 ° o r 7.0

7.0e+01 means 7.0 x 10 or 70.0

7.0e+02 means 7 . 0 ~ 1 0 2

o r 700.0

The frequency d i s t r i b u t i o n t a b l e s , histograms, and s t a t i s t i c s f o r

each element =re derived us ing on ly data values wi th in the range of

a n a l y t i c a l de te rmina t ion which have been used s i n c e 1975. Between

1968 and 1975, t h e lower l i m i t s of de t e rminab i l i t y were r a i s e d f o r

atomic absorp t ion a n a l y s i s of Au and Hg and f o r spectrographic ana lys i s

o f T i , Ba, C r , and Nb. Unqual i f ied va lues l e s s than t h e cu r r en t de te r -

minab i l i t y l i m i t s and a l l values q u a l i f i e d wi th N, L, G , o r H were ig-

nored i n these computations. The r e s u l t i n g frequency t a b l e s and sta-

t i s t i c s a r e biased and t h e histograms incomplete.

The sumnary a t t h e end of table 5 shows which elements have qua l i -

fied values , as w e l l a s t h e number of va lues having each type o f quali-

f i c a t i o n . The summary a l s o p r e s e n t s a recomputed geometric and geo-

me t r i c dev i a t i on using a method devised by A. J. Cohen f o r t r e a t i n g

censored d i s t r i b u t i o n s . If an element has no q u a l i f i e d data va lues ,

t h e mean and geometric devia t ion w i l l be t h e same i n both t h i s s m a r y

and on t h e page wi th in t h e t a b l e f o r t he p a r t i c u l a r element. For ele-

ments with q u a l i f i e d d a t a , t h e es t imates of mean and geometric devia-

t i o n are unbiased i n a s t r i c t sense only where the data are derived

from a log-normal parent population, but experiments have shown t h a t

Large departures from t h i s requirement do not usually inva l ida te the

r e s u l t s . Acceptance and use of t h e est imates, however, are the

r e spons ib i l i ty of the user .

The geometric mean is the anti logari thm of t h e ar i thmet ic mean

of the logarithms of the analyses. It is not a n est imate of geochem-

i c a l abundance bu t of "cent ra l tendency" (or c h a r a c t e r i s t i c value)

for a frequency d i s t r i b u t i o n that is approximately symmetrical on a

logarithmic sca le . The geometric mean i s use fu l f o r characterizing

many geochemical d i s t r ibu t ions . The geometric devia t ion i s the ant i log-

ar i thm of the standard deviat ion of the logarithms of the analyses.

For fu r the r discussion of geometric mean and geometric deviat ion

and of Cohen's method f o r censored d i s t r i b u t i o n s , see ~ i e s c h (1963,

1967) . B i a s and v a r i a b i l i t y a f fec t ing i n t e r p r e t a t i o n

In reviewing t h e data i n t a b l e 6 and the s t a t i s t i c a l summary i n

t a b l e 5 , severa l sources of bias and v a r i a b i l i t y i n the data must be

considered. Factors including time l imi ta t ions , weather, snow and

vege t a t i ve cover, outcrop exposure, and a v a i l a b i l i t y of he l icopter

landing s i t e s prevented uniform sampling i n all areas. Uneven sample

dens i ty a l s o resul ted from more concentrated sampling of some areas

which show evidence of mineral izat ion such as i ron-staining o r v i s i -

ble meta l l i c minerals. This p rac t i ce has biased the data s l i g h t l y i n

favor of samples containing values above t r u e background l eve l s . The

requirement of t r u l y random sampling--that a l l p o t e n t i a l samples have

an equal likelihood of being selected--is not-met. I n addi t ion , the

rock samples were col lec ted from a l a rge a r e a , where l i t h o l o g i c units

of various o r i g i n s or rock types may comprise several d i s s imi la r geo-

chemical populations. N o attempt has been made here to group samples

on the bas i s of geological o r geochemical a f f i n i t y . The summary of

the values thus provides only a general indica t ion of the trends t h a t

may be present .

Var iab i l i ty of any value i s influenced by many f a c t o r s , including

the d i f f i c u l t y of obtaining representa t ive samples o f inhomogeneous

media, va r i a t ion i n sample preparat ion, and v a r i a b i l i t y inherent i n

the ana ly t i ca l techniques. It is likely with any l a rge data-set t h a t

e r r o r s have occurred i n recording, key-punching and ed i t ing t h e data

which have gone undetected. Therefore, high values f o r a s ing le ele-

ment o r a s ing le s i t e should be considered questionable ind ica to r s o f

bedrock mineral izat ion.

Acknowledqments

We wish to thank several U.S. Geological Suntey colleagues for

t h e i r considerable cooperation and ass is tance . George Van Wump, Jr.,

provided invaluable a i d by resolving campu ter-programming problems.

Steven K. McDanal and Chr is t ine M. McDougal helped loca te and c o l l e c t

computer da ta - f i l e s from previous p ro jec t s and w i t h en t ry of data i n to

the computer. Michael F. Diggles worked t i r e l e s s l y proofing enormous -

lists and c lu t t e red maps. We a l s o wish t o thank ~ e n n e t h ~ i c h e r o f

TEMSCO Helicopters who w a s most generous with h i s t i m e and advice; and

volunteered logistical assistance which greatly aided our field efforts.

The skillful flying of TEMSCO p i l o t , Barry Roberts, allowed us to sample

t h i s particularly inaccessible terrain.

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rangle, southeastern Alaska: U.S. Geol. Survey open-file r ep t .

78-156C, 214 p.

Koch, R. D., E l l i o t t , R. L., Berg, H. C. , and Smith, J. G. , 1976a,

Analyses o f rock and stream-sediment samples from the Bxadf ie ld

Canal quadrangle , s o u t h e a s t e r n Alaska: U.S. Geol. Survey open-

f i l e r e p t . 76-486, 136 p.

1976b, Analyses o f rock and stream-sediment samples from the - Ketchikan quadrangle , s o u t h e a s t e r n Alaska: U.S. Geol. Survey

o p e n - f i l e rept. 76-427, 252 p.

Koch, R. D., Van Rump, George, Jr., and McDanal, S . K., 1978, Magne-

t i c tape c o n t a i n i n g a n a l y t i c a l d a t a for rock and s t ream-sediment

samples from Ketchikan and P r i n c e Rupert quadrang les , s o u t h e a s t e r n

Alaska: U.S. Geol. Survey Rept., 8 p., computer t a p e [Ava i lab le

from t h e Na t l . Tech. InP. Service, U . S . Dept. Commerce, S p r i n g f i e l d ,

VA, NTLS PB-276-7771.

Motooka, J. M . , and Grimes, D. J . , 1976, A n a l y t i c a l p r e c i s i o n of one-

s i x t h o r d e r s e m i q u a n t i t a t i v e s p e c t r o g r a p h i c a n a l y s i s : U.S. Geol.

Suntey C i r c . 738, 25 p.

Miesch, A. T., 1963, D i s t r i b u t i o n o f e lements i n Colorado P l a t e a u

uranium deposi ts - -a p r e l i m i n a r y r e p o r t : U.S. Geol. Survey

Bull. 1147-E, 57 p.

1967, Methods o f computation f o r e s t i m a t i n g geochemical abundance:

U.S. Geol. Survey P r o f . Paper 574-B, 15 p.

M d i c k , J. A . , and Hutchison, W. W . , 1974 , S e t t i n g o f t h e Coas t Plu-

t o n i c Complex, B r i t i s h Columbia: P a c i f i c Geology, v. 8, p. 91-108.

Smith, J. G . , 1973, A T e r t i a r y lamphrophyre d i k e p rov ince i n south-

e a s t e r n Alaska: Canadian Jour . Eareh S c i . , v . 1 0 , p . 408-420.

S m i t h , J. G., 1977 , Geology of the Ketchikan D-1 and Bradfield Canal

A-1 quadrangles, Alaska: U . S . Geol. Survey Bull. 1425, 49 p.

Vaughn, W. W . , and McCarthy, 5 . H . , 1964, An instrumental technique

for the determination of submicrogram concentrations of mercury

i n s o i l , rock and gas: U . S . G-1. Survey Prof. Paper: 501-D,

p. D123-D127.

Ward, F. N., Nakagawa, H. M., H a r m s , T. F., and Van Sickle, G. H.,

1969, Atomic-absorption methods of analysis useful i n geochemical

exploration: U.S . Geol. Survey Bull . 1289, 45 p.

Wright, F. E . , and Wright, C . W . , 1908, The Ketchikan and Wrangell

mining d i s t r i c t s , Alaska: U . S . Geol. Survey B u l l . 347, 210 p.

Table 4. Rock N a m e and Mineral Modifier Cddgs

P lu ton ic Rocks Veins

GR - Grani te QM - Quartz Monzonite GD - Granodior i te ( including t rondhjemite) QD - Quartz D io r i t e GB - Gabbro DI - D i o r i t e UH - Ultrarnafic

Metamorphic Rocks

AM - Amphibolite FV - F e l s i c Metavolcanics GG - G r a n i t i c G n e i s s

c-. GS. - Greenschis t (mainly chlorite o r c h l o r i t e - a c t i n o l i t e 4 s c h i s t and p h y l l i t e )

MB - Marble MG - Migmatite

. MS - Metasedirnents ( l o c a l l y tuffaceous, including s l a t e , a r g i l l i t e , g ray p h y l l i t e )

MU - Undivided metamorphic rock MV - Intermediate or mafic metavolcanics P N - Paragneiss o r s c h i s t QF - Quartzofeldspathic s c h i s t o r gne i s s

VQ - Quartz vein, pod, lens ... VN - v e i n other than q u a r t z

Dikes and S i l l s

DG - Gran i t i c DF - F e l s i c (not including DG, DP, DQ) DQ - Quartz ~ o r p h o r i t i c DP - P q m a t i t i c DM - Mafic o r in te rmedia te composition DL - Lamprophyre

Other

BS - Basalt FZ - F a u l t , shear , gouge or breccia

Mineral Modifiers

flA - B a r i t e CP - Chalcopyri te GN - Galena HM - Hematite MG - Magnetite MO - Molybdenite P Y - P y r i t e SL - Spha le r i t e

T m m O q P v i r m J O P h r U ~ Q m Q t ~ a m h ~ ~ P n u m P ~ m ~ - r * r m X U . . . . . . . . . . . . . . . . . w m ~ o - m m r n ~ ~ u ~ ~ n m ~ h w r n u o m + o w o w m a m o m h u n c c Q UJ w a 0 u

x x X X X X x x x X X X X X X x X x x x % x x x x

x x x x X X X X X X X X X K X X X X X X X X X X X X X X X X X X Y X X X X X X X X

I x x * % z . m . * Y Y

YI - H U U U - -

m ~ - o m ~ ~ a o ~ m n a n - - ~ m u ~ ~ ~ n n n m ~ ~ m - h - ~ u o m u . . . . . . . . . . . . . . . . . a o o ~ ~ ~ m n n b - m ~ m + u - p

a Y - C r r r

w 0

X X x x X

x x x X x x X x x X Y Y X

X X X X X X X X X X X X X X X X X X X X

x x x x x x X X X X X X X X X X X X x x x x x x w ?

X X x X X X x X x X X X X X X X X X X

X % X x X x x X X X X X X x X x

-1 4 W -4nm C W * * D m A d - * * zt > 4

C N e u u ~ h u ~ Q h c * C I r W - r 5 0 m m - Y < Q N * V h m N N C * * * - a L U Y . . . . . . . . . . . . . . . . . U a r O r r N ~ U Q h h l n m ~ * W 0 0 K L C.-.-

W a

x x X x X X X X X X X X X X X X X X X X X X X X X X X X X

X X X X X X X X X X

A470 T a b l e 5.-- S T A T I S T I C A L S U M M A R Y -- contlnutd

F R E Q U E N C Y T A B L E FOR COLUMN 4 IS-T1X >

L I M I T S LOUER - UPPER

1 .8 t -05 - 2.6e-03 2.6e-03 - 3 .8e -03 3.8e-03 - 5.6e-03 5.6e-03 - 8.3e-03 8.31~-03 - 1.2e-02 1.2e-02 - 1.8e-02 1.8e-02 - 2 . 6 ~ - 0 2 2 . 6 ~ - 0 2 - 3 . 8 ~ - 0 2 3 . 8 ~ - 0 2 - 5.6e-02 5.6r-02 - 8.3e-02 8 . 3 e - 0 2 - 1.2e-01 1 .Ze-01 - 1 . 8 ~ - 0 1 1 . 8 ~ - 0 1 - 2.be-01 2.6e-01 - 3 .8e -D l 3.8e-01 - 5.6c-01 5 . 6 ~ - 0 1 - 8 .3e -01 8 . 3 ~ - 0 1 - ?.2e+OO

*

F R E Q C U M

0 0 1 2 6

1 0 3 0 5 1 8 1 98

1 5 7 280 5 2 8 94 5

1 2 3 7 1 3 6 5 1399

H I S T O G R A M F O R COLUHN 4 I S - T I X )

PERCENT F R E Q

0.00 0.00 0.07 0.07 0.28 0.85 0.85 1.78 1.85 1.21 4.19 8.74

t 7.63 29.64 20.75

9.10 2 . 4 2

1 . s t - 0 2 X 2.Ot-02 X 3.0t -02 X X 5.0e-02 X X 7.0e-02 Y ? .a t -01 X X X X 1.5e-01 X X X Y X X X K K 2.0t-01 Y x Y x x R x x r w x x x x x x X r 3 .0e-01 X X X X X Y X X Y X K X K X X X X W X Y X X X X X X X X X X 5.0e-01 X X X X X X X X X X Y X X X X X X X X X X 7.0e-01 Y X X X X Y X Y W 1.0e*OO X X

M A K I HUM = 1.00000e+00 M I N I M U M = 5.00000e-03 G E O P i E t R I C W E A N = 2.6SS07e-Dl G E O f i E T R I C OEVIATION = .?.22328e+00

P E R C E N T F R E O CUR

100.00 100.00 100.00

99.93 99.86 99.57 98.72 97.87 96.09 94 .24 93.03 88.84 80.10 62.47 32.84 12.08

2.99

A N A L Y T I C A L T G V A L U E S 0 8 1 5 9 9

0.00 0.57

A 4 70 T a b l e 5 . - - S T A T I S T I C A L S U M M A R Y -- cont inued

T I T L E K E T C H I K A N PUID. ROCK GEOCHEH

f REQUENCY TABLE F O R COLUHI 5 ( S - M H )

L I M I T S LOHER - UPPER

8 . 3 e t 0 0 - 1 . 2 e t O l 1 . 2 e t O l - 1 .8e tO1 8 e O 1 - 2 . 6 e t O t 2 .6e+01 - 3 . 8 e t 0 1 3 . 8 e + 0 1 - ' 5.6e+O1 5 . 6 e t O t - 8 . 3 e t 0 1 8 . 3 e t 0 1 - 1 .2e tO2 l . 2 c * 0 2 - 1 . 8 e t 0 2 8 e O 2 - 2 .6e+02 2 . 6 e t 0 2 - 3 . 8 c t 0 2 3 . 8 e t 0 2 - 5 . 6 e t 0 2 5 . 6 e t 0 2 - 8 . 3 e t 0 2 8 . 3 e t O 2 - l . ? e + 0 3 1 . 2 e t 0 3 - l . % e + 0 3 1 . 8 e t O 3 - 2.6e+OJ 2 . 6 e + 0 3 - 3 .8e tO3 3 . 8 c t 0 3 - 5.6e+03

H I S T O G R A M F O R COLUMN 5 ( S - M N >

X X X X X X I( X X X K K X X X x X X i X X X x X X X X X X X Y X X X X X X X X X I I X X X X X X X I X K X X X X r ~ x x x x x x n ~ x x x x ~ x x x n x W X X X K I X X I X K X X X X K Y X X X X I X X

P E R C E N T P E R C E N T F R E O F R E G CUM

0.08 99.92 0.0 0 99.85 0.15 9 9 . 8 5 0.23 9 9 . 7 0 0 .68 99.4 7 0.76 9 8 - 7 8 2 - 3 6 9 8 . 0 2 3.19 9 5 . 6 7 5.78 92.47

13.00 8 6 . 6 9 1 2 . 7 0 7 3 . 6 9 17.49 60 .99 19.54 43 .50 15 .51 2 3.9 5

3 . 8 8 8 . 4 4 1 . 5 2 4 . 5 6 1.75 3 .0 4

ANALYTICAL G VALUES

1 7 1 2 9 7 1 - 2 9

M A X I M U M = 5 .00000e+03 R l t 4 l N U H = 1 . 0 0 0 0 0 e t 0 1 , G E O M E T R I C BEAH = 6 . 4 1 1 6 9 e t 0 2 GEOMETRIC D E V I A T I O N = 2 . 4 0 2 2 8 e t 0 0

-

J X 0 x x x x x x a . W cna

0 -1 + a a m - 3 u ~ I I I I I I I I I I I I I I I

W O t -

W W . . . . r. w e e 0 0 0

X X X X X X X X % x x X Z I X

2 u U -VIN C W O 1 * 3 N A d - - & z > 4

X K x - Y x X X X

.5 x m x X I X X X m X X X Y x x x -

X X X 0 X X X - X X X

X X X X X X X X X X X X X X X X Y X X X

I X X X X X X 5 X x x X X x x X a Y X X X X X X X -1 X X x x Y X x X x X X 0 X X X X K X X X X X X X X X X

mu-

m U H U U 0 I -

x r s ~ r r a 0

X K W W - 4 - L r

X Z O O 4 r r l W Y T X C 3 W

U

- m a C W N

X X x X x x X X X x X x X x x X X x X Y X x x x X x X x x x x x x x = = X X X X X X X X X X X X X X X x x x x x

a . W 'AP 0 A C 3

x X x X x X X X X X x X X X X

X X X X X X K X X X X X Y X X X X X X X X X X X X X X X X X X X X X X x X X X X X X X X Y Y X X X X X X X X X X X

q o ~ . - r - r r w w m w ~ ~ n n n P O O O w O O O m O O O O O O O O + + + + + + + + + + + + + + + + + U V l i U U U U & U V U U V U F C U o Q b m 0 0 0 0 o ~ O Q 0 0 0 ~ 0 . . . . . . . . . . . . . . . . . ~ ~ - r N m n ~ ~ + - N m ~ f - c r N

O O r r r r ~ r N N m N N N w l ~ ~ 0 0 0 0 0 0 D 0 0 0 0 0 0 0 0 0 D + + + + + + + + + + + + + + + + + U ~ Y U w U U U U * * U * w * m U 9 1 - ~ m 3 ~ m a n ~ m ~ r n ~ m m m a

E . . . . . . . . . . . . . . . . .

a m o h aosu * + .

- -

- - 5 r X Z O O < - Lu Lu S Z U W

C Q m - r O - N * H 3 G n m P m ~ - P T Q N * . - k O * Q m - N m * + + O r W W . . . . . . . . . . . . . . . . - ~ a k ~ ~ ~ t - P ~ a W N r 0 0 0 0 C g u W a

K X

X x x X X X X X X X X X X X X X X X X X X X X X X X X x x X x X X X x X x X X x X x x X X x X x x X X X X x X X X x x x x X x x x

r r - r v - W r u N N N N H 3 n n n Q 0 0 0 a 0 0 0 ~ ~ 0 0 0 0 0 0 + + + + + + + + + + + + + + + + U * . % * U U * * * U U & U U U U 0 ~ 0 0 0 0 0 ~ o O a O o m 0 0 . . . . . . . . . . . . . . . . r r ~ m m h . - r ~ m m h r - ~ m

Q W - 0

0 C 3 a m - 3 4 ~ l l 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

4 u n .-- r'-

P N f 0 + YI

U N h . P CI h

- 0 - r 0 0 - 4 + * .

(D D Urn z 0 00 0

4 -0 - WOO 0 0 H W - 00 e

0 0 2 - .a>

Nu-uLLr r 0

P Y n v u 0 c. c.I

Z Q . P E E & uc? 3 4 c r

L r w w ~ ~ n a m h m m ~ ~ n m - ~ o o m m u - m n r n * ~

c a m m ~ ~ n ~ ~ u ~ n w ~ e o m ~ - h ~ ~ o ~ ~ Z V . . . . . . . . . . . . . . . . . . . . . . . w m u ~ o u u u u e ~ ~ n N ~ - ~ ~ m ~ ~ ~ ~ O U - ~ O k h G ~ P l N - r a w w a a -

X x X X X X X x x x

X x x X X X Y X K X X X - X X X X X X X X X X X X

Y X X X X X ~ x X X x x X x X X x X X X x x x x x X X X Y X X X X X X X X Y Y Y X x X x X X x x x x x X X Y

O O r r c - r + N N N N N N m - m r n f l M U U * 0 ~ m 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 w . . . . . . . . . . . . . . . . . . . . . . . U U U U U U U U U U U D V V U U U W U V U U U o O 0 ~ O O w O o m Q O O o O m O O O o ~ * o ...........*........I..

m + r , ~ n n h c ~ ~ m ~ ~ h - ~ ~ n r n ~ ~ - ~

A470 T a b l e 5 . - - S T A T I S T I C A L SUMMARY -- cont inued

7 I TLE K E T C H I K A N QUAD. ROCK G E O C H E M

FREQUENCY T A B L E F O R COLUMH 17 ( S - L A I

L I n I r s LOUER - UPPER

1 . 8 e t 0 1 - 2 . 6 e t 0 1 2 . 6 e t O t - 3 . 8 e t 0 1 3 .8e+Of 5.6e+01 5 . 6 e t 0 1 - 8 . 3 e t 0 1 8 . 3 e t O t - 1,2c+O2 1 . 2 e t 0 2 - 1 . 8 e + 0 2 f . 8 c + 0 2 - 2 . 6 e t 0 2 2 .6e+02 - 3. S e t 0 2 3 . 8 e t 0 2 - 5 . 6 e t 0 2 5 .6e tO2 - 8 . 3 e + 0 2

H I S T O G R A M F O R C O L U M N 17 ( S - L A

PERCENT F REP t 0. A 3 12.27 30.56

6 + 8 3 2 . 2 5 1.69 0.56 0.31 0.06 0.06

PERCENT F R E Q run

6 5 . 6 4 56 .60 4 2 . 5 3 1 1 . 7 7

4 . 9 5 2 . 6 9 1 .a0 0 . 4 4 0 . 1 3 0 . 0 6

A N A L Y T I C A L T G VALUES 0 0 1 0 4 5

0.00 0.00

M A X I M U M = 7 . 0 0 0 1 0 e t 0 2 #INlHUN = 2 . D D 0 0 0 e + 0 1 G E O M E T R I C MEAN = 4 . 3 6 9 0 5 t * 0 1 G E O M E T R I C D E V I A T I O N = 1 . 6 8 6 5 7 e t 0 0

~ N ~ m m m r ~ m V I r Q ~ r r n p r 3 O r w - t m Q W 0 ~ w m u I t m W N - tu............... W N ~ R ' n ~ v l . u r - a 0 0 0 0 0 u - a w w a a u

X X X X X X X X X X X

A 4 7 0 Table 5. - - S T A T I S T I C A L SUMHhRY -- continued

T I T L E K E T C H I K A N QUAD. R O C K G E O C H E M

F R E Q U E N C Y T A B L E F O R C O L U M N 19 ( S - M B

L I M I T S L O V E R - U P P E R

1.Be+01 - 2.6e+01 2.6tt01 - 3 . 8 c t O t 3.8tt01 - 5.6et01 5 . 6 c t O t - 8.JetOl 8.3e+01 - 1.2e+O2 1.2ct02 - 1.8tt02

F R E Q FREP c un

11 4 1 5 1 6

13 59 0 59 1 bO 2 62

PERCENT PERCENT F R E P F R E Q C U M 2.57 25.30 0.31 22.73 0.81 22.42 0.00 21.60 0.06 21.60 0.13 21 - 5 4

A N A L Y T I C A L 7 G VhLUES 0 0 4 0 4 0.00 0.00

nhxlnun = 1.50010e+02 H I N l MUM = 1.00000e+ 01 G E O R E T R I C M E A N 8 l.ZO195etOl G E O M E T R I C D E V I A T I O N 1.51921t+00

4 r. U .-. u7 u C U D - 3 - a d - * u z > <

c P Q m m m u S r m t n U n S Q Z ~ O + C O ~ D - N C ~ + U - O C Y W . . . . . . . . . . . . . . - u a m ~ h b h P * Q m - ~ O O O r r v - Y 0

LJ L N Y 0 3 X X W d O O F r r r r r N N N n J N N 15 X X X C? o ~ ~ o o a n o o a ~ a a ~ ~ X X X ~ X X

- Q Y i n m r r w m * ~ r r ~ ~ m ~ ~ 4 x x x ~ x % ~ x x x

n o X X X X K X X X X X o o H r a0 4 D O T - . . u > * W VIO U

a -I 1-3 00.--,-.--FNNNNNN U r n - w O D O O D O O O O D O O O ~ 3 - S l l l l l l l l l l l l l l l 0 + + + + + + I + + + + + + +

m .-

I1 H U U c. ."

Z Q . z z - a Ylm 3 5 c l -

Z T W U - - S 5 n 2 0 0

X X X X X X X X X X X X X X X X X X X X X X X X X X X Y x x x x x x x x X X X X X X X X X x x x x x X X X X X X X X X X X X X X X X X X X

x x Y X X X Y x x x

X X X X X X X

x x x x x X X X X X X X X X X X X X X X X X X X X X ~ X Y X X X X X X X X X X Y X X X X X X X X x X x X X x X X X X X % X X X X X X X X X

U h. .- n

arc + 0 U e 0 * m c u

N O * OO*?W + + . U U r Z 00 0 -0 - o o n r 00 e 0 0 2 -

. 4 > r m W W

t

~ = a = 7 3 l - c L I W Y

X X x x X X

X X x X X X X X X X X X X X

X X X X X X X X X Y X X K X X X X X X X X X X X X X

X X X X X X X X X X Z L X X X

Y X X X X X X X X X X X x x X x X X X X X X X X X X S I Y X X X X X

N N N N N N n m n n ~ ~ o a O o O o O o a O + + + + + + + + + + + U U u u U U U u u U U o n o a o o o y o q q . . . . . . . . r - N m m b . - - N m m

. . . . . . . . . . . 0 0 e a LC w r - N V l m m r r N m m

a . u V I P a A c a

n n u u - - szacc 3 3 c t Z Z W W - - f # X Z ~ Q 4 W W u l z z - 0

r r n ~ ~ ~ ~ ~ ~ n e ~ n o - u n ~ o a ~ ~ u m s p o ~ u ~ ~ ~ h ~ ~ ~ u - ~ ~ ~ ~ W W . . . . . . . . . . . . . . . . . . . - U L N r W l Q h r c Q m - U - 0 0 0 0 0 0 e Q rc .-c--.- Y 0

X X x X X K X X X Y X X X X

X X X X X Y % X X X X X X X X X X X X X

Y X X X X X X X X X X X X X X x X x X X X X X X X X X X %

* X X x X x X X x X x X X X x X X X X X X X X X x X x X x X

P . . . . . . . . . . . . . . . . . . . . ~ ~ ~ ~ n m m ~ - ~ r n m m - r ~ * t a a . r a

m P I- 3 - X l l t 1 l I l 1 I l l 1 I 1 1 I ~ I 1 1 c. d Q D F r - - - - N N N N N m m m m m m m

w . a 0 0 0 0 0 0 0 0 0 9 0 0 0 0 0 0 0 0 . . . . . . . . . . . . . . . . . . . . O u U U U U & U & ' ~ U v U U v * Y U U U ~ m r w ~ ~ Q Q * N m Q m Q m m m * m * m . . . . . . . . . . . . . . . . . . .

~ - ~ ~ m m m - ~ ~ n m m - ~ m m m ~

0 a

C O . 0

N o W O N N

U IU rn 0

m - N

W F P O O h ll + + . u urn t a 0 0 -0 - O O n c 00 a 0 0 2 - . . u > .-u-Luw

f o

. - -w 0 0 0 + + + U V U o a a . . . u - b -

x X x X X x x X X

X X X X X X X X X X X X X X X X X X X X X X X * X X X X X X X X X X X Z I X X X X X X X X X X X X X X X X X X X X X X X X k X X X X X X X X X X X X

r v r r r r N N N N N N Q 0 0 0 0 0 0 O W 0 0 0 + + + + + + + + + + + +

I V N I V N ~ W I ~ ~ M ~ O O O O O O O O D O + + + + + + + * + + U U U U U U U U & U . ~ r n d m ~ m ~ m a w l

LI: . . . . . . . . . . W N m m Q - r ~ ~ ~ W 0

vr a + =

Z 5 3 d x x 0 x x x Y

N N N N m n m m m m Q O a o O o O o o o 0 0 + + + + + + + + + + u * U U U V U U U U U

a 0 0 0 0 m o D 0 0 f . . . . . . . . . . 4 m n m F . - r N n m h a 0 0 C n - I

U J

N m or- + 0 U J h . - N *

m m m a o m l l + + .

C N r n V I ~ ~ . - O U ~ h ~ ~ W Z Q m O m m m m - 7 l n D I . ' c n W , " . . . . . . . . . . . . . - u & r O W U P O h Q e m N r D a Y rv-.- LY P

X x x X X X X X X X x x x x x %

X K X X x X X X X

X X X X X X X Y X X X X X X X X X X X K K X X K X X X X X

X X X X X X X X X X X X X X

X X X X X X X X x X X X X X X X X X x x x X X X x X X x X

r t - t . - , - N N N N N N n 00000000000Q0 + + + + * + + + + + + + + ~ U U U U U V U V V V U U 0 m 0 0 0 0 ~ m 0 0 0 0 0 . . . . . . . . . . . . . r r N V l m h r r N V l V 3 h v

T a b l e 5.-- S T A T I S T I C A L S U M M A R Y -- c o n t i n u e d

e T I T L E K E T E H I K A N Q U A D . R O C K G E O E H E H

I F R E Q U E N C Y T A B L E F O R COLUMN 32 (AA-CU-P 1

t i # 1 T S L O U E R - U P P E R

3 . 8 e t 0 0 - 5 . 6 e t 0 0 5.6etDO - 8 . 3 e t 0 0 8 . 3 e t 0 0 - 1 . 2 e t O l 1 . 2 e t O l - t . l e t 0 1 l .Be+Ol - 2.6e+01 2.6ecOl - 3 . 8 e t 0 1 3 . 8 e + 0 1 - 5 . 6 e t 0 1 5 . 6 e t 0 1 - 8 . 3 c t 0 1 8 . 3 e + 0 1 - ? . 2 e t 0 2 1 . 2 e t O 2 - I . S e t 0 2 1 . a c t 0 2 - 2.6e+OZ 2 . 6 e t 0 2 - 3 . 8 e t 0 2 3 . 8 e t 0 2 - 5 . 6 e t 0 2 5 . 4 e t 0 2 - 8 . 3 c t 0 2 8 . 3 e t O 2 - l . 2e+O3

F R E O F R E Q P E R C E N T C U M F R E Q

236 236 20.52 0 236 0.00

1 6 2 398 1 4 . 0 9 1 1 7 515 1 0 . 1 7 1 4 2 6 5 7 12.35

6 4 721 5.57 9 2 8 1 3 8.00 52 865 4.52 35 9 0 0 5 - 0 4 1 3 9 1 3 1 .13

b 9 1 9 0.5 2 3 922 0 . 2 6 4 926 0.35 2 9 2 8 0.17 1 9 2 9 0.09

a HISTD6RAH FOR C O L U M N 32 [Ah-CU-P )

ul o s . o e + o o x r x x x n x x w ~ x x x x ~ ~ x x x x w

b ?.Oe+OO 1 . 0 e + 0 1 Y X X X X X X X X W X X X X 1.5e+Ot X X l K K H X X M X

0 2 . o e t o 1 x x x x x x x x x x r r 3 . 0 e t 0 1 X x Y X x X 5 . 0 e t 0 1 K X Y I X X Y X

b 7.Det01 K I R Y H 1.0e*02 Y X X $ . S e t 0 2 x

b 2.OetO2 I 3 . 0 e t 0 2 S.Oe*02

a 7 .0e+02 1 .OetO3

P E R C E N T F R E Q C U M

80.78 60 .26 60.26 46.17 36.00 25.65 18.09 10 .09

5 . 5 7 2 .52 1 .39 0 . 8 7 0 .61 0.2 6 0 . 0 9

A N h L Y T l C h L T G V A L U E S 0 0 9 7 9

0 . 0 0 0 .oo

II R A X I M U H = - 1 .20010e*03 M I H I M U R 5.00000c+00

# G E O M E T R I C MEAN = l . b 8 6 0 7 e + 0 1 G E O M E T R I C D E V I A T I O N = 2 . 7 6 0 4 4 e t 0 0

A 4 70 T a b l e 5.-- S T A r I S T l C A L S U M M A R Y -- c o n t inucd

T I T L E K E T C H I K A N QUAD. R O C K GEOCHEM

FREQUENCY TABLE F O R COLUMN 33 ( A h - P B - P )

L IMlrs LOWER - UPPER

3.8e+00 - 5.6e+00 5.6et00 - B.3etOO 8.3et00 - 1.2etOl I.Ze+Ol - 1.8et01 1.8et01- ? . b e t 0 1 2.6etOl - 3.8et01 3.8etOt - 5.6ct01 5.6etOI - 8.3e+01 8.3e+01 - . 1 .2etO2 1 .2e+OZ - l.8tt02 1.8et02 - 2.be+O2 Z.betO2 - 3.8et02 3.8et02 - 5.6et02

FREQ FREQ P E R C E N T C UM F R E Q

464 464 40.38 0 464 0.00

2 9 4 758 25.59 64 822 5.57 2 1 843 1.83 1 4 857 1.22 3 860 0.26 1 861 0.09 2 863 0.1 7 o 863 o .oo 2 865 0.17 0 8 6 5 0.00 2 867 , 0.1 7

H I S T O G R A M FOR C O L U M M 3 3 ( A n - P B - P

PERCENT F R E Q C U M

75.4 6 35.D7 35.07 9.4 9 3.92 2.09 0.8 7 0.6 1 0.52 0.35 0.35 0.17 0.17

A N A L Y T I C A L t G V A L U E S 0 0 867

0.00 0.00

nnxInun = 4.50000~+02 MINIMUH = 5.00000et00 G E O M E T R I C M E A N = 7 . 5 9 8 9 9 r + 0 0 G E O M E T R I C D E V I A T I O N = t.74548e+00

X x X X X X X X X Y X X X

x X X X X X X X X Z X X X Y X X X X X X X X X X X X X X X X X X X X X

X 1 I X X X X X X X X X X X X

X X X X X X X X x X X X X X X X X X x x X X X X X x X X X X X X X X X X X

T a b l e 5.-- S T R T I S T I C A C S U N M A R Y -- c o n t i n u e d

T l T l E K E T C H I K A N Q U A D . R O C K G E O C H E H

F R E Q U E N C Y T A B L E F O R C O L U M N 35 ( I N S T - H G )

L I M I T S L O W E R - UPPER

1 .be-02 - 2.6e-02 2 . 6 ~ - 0 2 - 3.8e-02 3 . 8 ~ - 0 2 - . 5.6e-02 5 . 6 ~ - 0 2 - 8 . 3 ~ - 0 2 8 . 3 t - 0 2 - 1 .Ze-01 1.2e-01 - 1.8e-01 l . 8 e - 0 3 - 2.6e-01 2 . 6 ~ - 0 1 - 3 . 8 ~ - 0 1 3.8e-01 - 5.6e-01 5 . 6 ~ - 0 1 - 8 . 3 e - 0 1 8 . 3 t - 0 1 - 1 . 2 e t 0 0 1 . 2 e t 0 0 - 1 . 8 e t 0 0 1 . 8 e t 0 0 - 2 .6e t00 2.6etOO - 3. RetOO

F R E Q F R E Q P E R C E N T C UM F R E O

1 5 3 1 5 3 19.82 1 4 167 1 .R1 94 261 12.18

1 1 2 373 14.51 34 4 0 7 4.40 1 2 5 1 9 1.55 1 8 4 3 7 2.33

6 4 4 3 0.78 1 444 0.1 3 1 4 4 5 0 .13 0 4 4 5 0.00 0 4 4 5 0.00 0 4 4 5 0 .oo 1 4 4 6 0.13

H I S T O G R A M F O R C O L U M N 35 ( I N S I - H G 1

2 . O e - 0 2 X X K K K X K X X X X M X K X X H X X K 3 . 0 ~ - 0 2 X K 5.0e-02 x X X x K % K x X U x X 7,Oe-07 X X X X K X X X K X X X X X X 1 .0e -01 X X X X t .Se-Ol U X 2.0e-01 1 IX 3 . 0 ~ - 0 1 X 5.0e-01 7 . 0 ~ - 0 1 1.OetOD 1 . 5 e t 0 0 2 . 0 e t 0 0 3 . 0 e t 0 0

M A X 1 MUM = 3 . 0 0 0 0 0 e t 0 0 nrMInun = 1 . 0 0 ~ o o e - 0 2 G E O M E T R I C M E A N = 4.35805e-02 G E O M E T R l C D E V I A T I O N = 2 . 1 9 1 9 5 e t 0 0

PERCENT F R E O C U M

58.81 38.99 37.18 25.00 10.49

6.09 4 .53 2 . 2 0 1 .L2 1.30 1.17 1.17 1.17 1 .17

A N A L Y T I C A L T G V A L U E S 0 0 4 5 4

0.00 0.00

Q Z C I Z W A ~ r 3 - x I0 P x r 3 W C W E * . U 0 n z n w t a z w u z a o w w o 0 0 m o o w - - - A Z E C W U J O !

c n u o w f a z u t r 2 u r a 00. u a x - VL W ln w U W C P: t o x U t C W W C - 0 X U W > - x c m w w c a o a a u a w ~ ~ w

w o m u z a + L a 3 z w m a o o * a A W 2 *

I J r n C l l V ILCCQ w x Z O W f v r o C l V I 0 W C VIW T - a z m H V I

L Y O W t P u r - - ~ ~ u l - A u C q u3 * - * x u C d d - - o C w - < > c u t u 3 w n 2 3 0 - a - w o a W C 3 C

+ . A C W x - * r c c < a x o ~ C 0 3 a W W . l l C 3 0 X X V I A P W w 3 o V I a o a w ~ o w n O O Q C L O U X C . . O L

- 2 7 a

g g ; " Z . & Z I- a w r < " I u r

W d t U O e t ~ u o w r v l u - 0 ~ Z ~ m ~ P

T a b i e 5. - - S T A T l S T I C A t S U M M A R Y -- c o n t i n u e d

E L E H E N T S - F E X 5 - R G X S - C A X S - 1 1 % S-MPI S - A G 5 - A S S - B S - B A S-BE 5 - 8 1 s - C 0 5 - t o S-CR 5 - C U S - L A S - N O S - N B S - N I 5 - P B S - s e S - s C S - S N S-SR S-V s-u S - Y S-/El S-ZR A A - A U - P A h - C U - P A A - P B - P A A - 2 M - P I N S T - H G

G E O M E T R I C M E A N

75950047 1.041506

4 4 1 1 1 1 1 1 1

* * * * * * & + * * t b * + * * *+*I****

C t * * * * t + 4 .534263

* * * * * * a +

0 . 8 9 3 9 5 9 17.369298

* * a + * * b *

9.357561 * * * + * * + * I + * * * * * *

2 6 . 4 4 7 1 9 5 15 .671003

* * * + + & . b

8.402309 * + * * + * * *

0.000000 + * a * **.*

15.1 0 8 6 6 8 4 . * * * * * *

t 0 5 . 9 8 0 1 7 3 58.01 4771 16.658313

*+* * * . * * * * * * * * * * * + * * * + I *

11.033381 5 . 7 6 8 4 1 0

3 7 . 5 5 7 7 0 6 t l t * * * * t

G E O M E T R I C D E V I A T I O N R E H A R K S

h a l l b t 1 5 G R E A T E R T H A N V A L U E S . NO C O M P U T A T I O M S . 2.91 3 N O T D E T E C T E D B L E S S T H A N , OR T R A C E V A L U E S . 1 5 1 2 R E P O R T E O V A L U E S .

* + * + * b 4 G R E A T E R T H A N V A L U E S . N O C O R P U T A T I O M S . + I * & * * 8 G R E A T E R T H A N V A L U E S . N O C O M P U T A T I O N S . t * a + h * 1 7 G R E A T E R T H A N V A L U E S . N O C O M P U T A T I O N S .

~ + b * * 1 G R E A T E R T H A N V A L U E S . N O C O M P U T A T I O N S . * * + * * I 1 G R E A T E R T H A N V A L U E S . N O C O M P U T A T I O N S ,

3.08 9 0 1 N O T O E T E C T E D B L E S S T H A N , OR T R A C E V A L U E S . 4 1 1 R E P O R T E D V A L U E S . + c a b * * 10 G R E A T E R T H A N V A L U E S . N O C O M P U T A T I O N S .

1 .89 677 N O T D E T E C T E D , L E S S THdN, OR T R A C E V A L U E S . 920 R E P O R T E D V A L U E S . 2 .19 1 3 9 9 H O T D E I E C T E O I L E S S T H A N , OR T R A C E V h L U E S . 8 R E P O R T E D V A L U E S .

* * a + * . 1 G R E A T E R T H A N U h L U Z S . N O C O M P U T A T I O N S . 5 . 3 8 4 2 4 N O T D E T E C T E D , L E S S T H A N , O R T R A C E V A L U E S . 1 1 7 3 R E P O R T E D V A L U E S .

+ * a * + * 5 , V A L U E S L E S S T H I N S P f C I F I E D L I M I T O F D E T E C T I O M . M O C O M P U T A T I O N S . * * * * & a 3 G R E A T E R T H A N V A L U E S . N O C O M P U T A T I O N S ,

2 .5C 552 N O T D E T E C T E D , L E S S T H A N * OR T R A C - E V A L U E S . 1 0 4 5 R E P O R T E D V A L U E S . 1 . 2 2 1 4 0 5 N O T O E T E C T E D I L E S S T H A N , OR T R A C E V A L U E S . 1 9 2 R E P O R T E D V A L U E S .

a * * * * * 342 V A L U E S L E S S T H A N S P E C I F I E D L I M I T O F D E T E C T I O N . N O E O M P U T I T I O N S . 4 . 4 7 4 9 3 N O T D E T E C T E D , L E S S THAN, OR T R A C E V A L U E S . 1104 R E P O R T E D V A L U E S .

a d * * k * 1 G R E A T E R T H A N V A L U E S . N O C O M P U T A T I O N S . a t * * * 1 5 9 4 N O T D E T E C T E D , L E S S IHAN, OR T R A C E V A L U E S . 3 R E P O R T E D V A L U E S .

t t * t + * f G R E A T E R T H A N V A L U E S . N O C O M P U T A T l O N S ,

2 . 2 7 1 5 8 2 MOT D E T E C T E D B L E S S THAN, OR T R A C E V A L U E S . 1 5 R E P O P T E O V A L U E S . t a b + * * 3 G R E A T E R T H A N V A L U E S . N O C O M P U T A T I O N S .

3.00 4 7 N O T D E T E C I E O * L E S S T H A N * OR T R L t E V A L U E S . 1 5 5 0 R E P O R T E D V A L U E S . 1 . 3 0 1 5 8 3 N O T D E T E C T E O , L E S S T H A N , OR T R A C E V A L U E S . 1 4 R E P O R T E O V I L U E S . 2.01 264 N O T D E T E C T E D , L E S S T H A N * OR T R A C E V A L U E S . 1 3 3 3 R E P O R T E D V A L U E S .

* * + t * * 3 G R E R T E P T H A N V A L U E S . N O C O M P U T A T I O N S . c * + * * & 3 G R E A T E R T H A N V A L U E S . N O C O M P U T A T I O N S . * * + * * I 2 V A L U E S L E S S T H A N S P E C I F I E O L I M I T O F D E T E C T I O N . N O C O H P U T A T I O W S .

3 . 6 3 2 2 1 N O T D E T E C T E D , L E S S THAN, OR T R A C E V A L U E S . 929 A E P O R T E O V A L U E S . 2 .03 282 N O T D E T E C T E D , L E S S THAN, OR T R A C E V A L U E S . 867 R E P O R T E D V A L U E S . 2 . 4 3 1 5 N O T D E T E C T E D , L E S S T H A N , O R T R A C E V A L U E S . 1 4 2 0 R E P O R T E D V A L U E S .

4 * . ~ t + 8 V A L U E S L E S S T H A N S P E C l F I E O L I M I T O F D E T E C T I O N . H O C O M P U T A T I O N S .

m O 0 0 0 0 m a m 0 o O m * D 0- o m Vtv! m h O w t z t = x . X Z t . . . . . . . . .z . . r .t . = = = . . z t z = * = t . . . . . . . . C - O O m h m - - - 8 - W O V V N r V m V V V I a nc m

V 8-

ul 0

YI A

x Q P O O O Q O O O O 0 0 0 0 0 o a a o o O O O O ~ a 0 0 0 0 o m o o a o o o o o o o o o o o D O O O O a - o c c oocaao e o o m a o o a o m o o o o m o o m o o o m c o c a c o o 0 0 I - W O O O W - n q m * h o b 0 O h o h m 0 0 m 0 - m o o o m O a c o a ~ n h h - n o ~ o w Ln * * C . * U S * U \ * * * * * * 8 C * * S * \ * 8 * %

Y l N N r m r r r r r - r m m w m * W m n P l m A

m m m m A h A A h

- r 0 0 9 0 0 O O O O D O O Q O O 0 0 0 0 0 O O O D O 00000 0 0 0 0 0 t m m m w m o o o o m a m 0 0 0 o a o a m o o a a m o o o m o o o c o a I q-,-,-*q r w W N 0 m - m m n m l n h m r k O b h P N k m - Q O k m o o

UI . . . . . . . . . . . . . . . . . * . . . . . . . . . . . . w U 0 0 0 0 0 0 0 0 O h O O O O O D O O O O Q O Q O O O O O W O O O O O O u - ~ m 0 0 N N 0 0 0 V t W c P O O D O O m O O m m h . . . . . . . . . . . . . . . . . . . . . . . . . . u? -0

3 9 9 9 9 930.99 e - o ~ m m m r u N N N ~ C m n m - t w o m o o - h e h a

r N r - r v r r N 4-

H W 00000 0 0 0 0 0 O P O O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a a a o a b m 0 0 0 0 O O O O O 0 0 0 0 n o o m 0 0 0 0 0 I . . . . . . . . . . I.... x * . . . r . . . . . . . . . 0 0 = 0 0 ? a Q O = = * * . .

m r t - Q * v ! 0 0 0 0 m n h h m h b m v * a - m - h O m O 0 Q O O m m N m r r w r N t r W C N N N 8 - m - -

A A A

w u u m e w m u a ~ m ~ w m m m m m c m b h h h e - b b u u u w o o ~ m m a b w u e ~ m m m o n m m - + u u m m r n n m n n m m m n n m m m m m m m u u n n m m m N N - m m

w 2 -.---- . - -000 0 0 0 0 0 a 0 0 0 0 0 0 0 4 0 w 0 0 w 0 0 0 0 0 0 0 0 0 0 0 0-+-.- o n n e m m m m m m m n n m n m m m n w , m w ~ n n n n nnnnn m m m m n nnnnn nnnnn d C C F C C F - Y C C F - C ~ F c c c c c c c c c c - - - P C C - C C - r - r r - c - . - - c

4 .c I I I f < m u m e m u m * a w h ~ n u - m v m v , a m e m s a m . u n v r v r v r v r n v , v rv rv ,v ,v r v , v , v r o - c - ~ W O O A m m m m m m ~ m n m n a h m o . - w N ~ J ~ G U U ~ M m m n ~ y - 3 Q 9 h m c - - m r u N N O D O F a +.bhhh h h a ~ r u NNNNWI nnnnn m n n n n n m m m m m m m m w m o o 0 0 r r r v r z W Q W Q W w w x x x X Y X X X Y Y X Y X X X X X X X X Y X Y Y X Y Y X Y X X Z Z - J O - U W c m m m m m m m u u u u u u u u u u u u u U U U U ~ u u u u u u u u u u u u u o a m m m m m n m m ~ m m m m a m a m m m w m m w m m m a w m m m m w a m c ~ m c ~ m r n m m m m ~ Q * ~ c - *

Q e o - a * - * * . a * * . a * - a m * * * Q 9 Q * W * a * * * -*a** d Q 9 - Q ****a

m t z z z z z z o o o o 0 0 0 - 0 00 -00 o o o o o e a o * ~ - o m 0 0 0 0 0 0 0 o z z z z I N C r r r r r r p - - - P C F C C - - ~ r r r r c + c r r r r r - r r

Y) v v v V v V v v v v v

4 A O O Z Z Z O D 0 0 0 O O O O W 0 0 0 o z 0 0 0 0 0 O O O O O 0 0 0 0 0 0 0 0 0 0 O Z X Z Z 1 00 ~ ~ N N N N ~ N N N N N ~ W N N ~ N W ~ N N N N N N N N N N W N r n ~ h N

VI .rr r V V v V v v v v V V V V v v V v v v v

3 O O o m m O o o m 0 0 0 0 0 0 m 0 0 0 0 O O P O O 0 0 0 0 0 O m 0 0 0 O m m m o m o o 0 0 V o a r r a m w r o b o b o r " a m 0 0 o h m a h Inn-00 m h u - b n h V I r r r r O O Q Q I 0 0 0 0 r u m c rr 0 - N r O N - C - o o m o n c s 5 5 5 5 - 5 1

N r 0 nl r N 0 0 0 N r r u .- A

P: u 0 0 0 0 0 o m o h k o a o h o c m e o c o o o o o e m m o e o m a m o o m o o m m o o a a I c r r m N V I r r r t b ri r r n n m b k - F w l - r n N m v m - v - v r h - m N - . - n F

W m o o m o d o o o m o o o m m m m m o o o m m o o 00 o m o o o m o ~ l o o ( r . . . . ..tt . . * . * . . e . 5 . . . . . . Z T P . . Z Z Z . . . " . . . * n F - ~ C C r m - r f U r W r r r - r s - r r - r r r C - - c r v r r - - r r

v v v V V V v V V v v

< 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Q O O O O Q 0 0 0 0 O O W d O O Q ~ O O O O O D 0 0 0 0 0 0 ffi O O O O O 0 0 0 0 " O O Q O O a 0 0 0 0 0 0 0 0 0 o m o m 0 0 0 m 0 0 O N 0 0 0 0 0 0 0 0 I c o m r u o N O O R ~ O O Q O m o o m c ~ m a m o o o m n r e m t ~ m m c f i n o m o o o *

Ln ... 5 5 5 b b 5 5 5 5 . 5 . . \ S C S b 5 5 . 5 5 - 5 5 5 8 * .

4 u I Z I I a m u m e m u m * a u C U N ~ + Q m r ~ * 4 m x u m v a m m m m m n m m m m m w m m 0 ~ P b m m O

n m m m m m g ~ W n W i n w ~ O r N w N W u d u - u nnn+u 9 0 Q h m m - m ~ r u N O O P r e h h h h h ~ ~ O O N N N N N ~ n n m m n m n n m n ~ m ~ l m ~ l m m m m m m a u a o o - - - F -

f W U W 0 0 C l O Y Y X X X Y X X X X X X Y X Y X X X X X X X Y Y X X X X X Y Y Z Z T W O O W u m m m m m m m v v u u u w u v u v u v v u v u u u v u u v u u v v v v u u u n o m m m m m n m m m a m m m w m m m m a m q m m m m m m d m m m m m w m m m a m m a m c m m m - - - w e

Q - Q Q Q 9 - Q e Q - Q G Q e a Q a Q Q Q a Q 0 0 d Q 9 Q a 9 - Q e Q Q Q Q Q Q S Q Q G Q

5 7 P L d. 1 5. * - - - - - -

I 3 O ~ N N W N W W N N N N N N N N N N N N N N N O O N N N W N N N N N N N m O m m u c o a o m o o a q o c q o a o q q q q q c o c a - o e a o o eo,coa o c m o o 1 r z z z 2 . . . * . . . . . . . . . . . . . . . . . . . . I . . I . . . < W I V V V N v V V v v v v V V V V V V V V * V v V V V V v V V v V v v a

a ~ 0 0 o t 0 0 0 0 0 D O D O O o m a ~ o 0 0 a o 0 Q O O O O O D O O O o o o o o o z c z t o n - r o a a r =oar-h h k c m b k ~ w m k & o m - o ~ o k m o O - m k w h c

I c r u r - V N - c hl F N r N V N m N r n m v VI

X Z Z X Z S ~ o Z X Q 0 0 0 0 0 O Z Z O Z O O O O Z Z t d O O a 0 0 0 0 c Z O 2 t 2 2 2 2 2 w O P Q 0 0 0 0 O 0 0 0 0 0 0 0 O O O C J O 0 D I N o v r n w r u r u N 51 P N N N N ~ N ~ N I U I W N N m m V V V V b * V V V v v v v v v v V v

0 r * h

* I o o o o o m w o o o o m r n o o o o m o o o o o m o m o o 0 0 o o o o o 00-u-o a c o o m VI ~ r r r r r O N W I v n r r N m ~ m t n r r f U t u r r r m N n W l c w m M N - F - - N --I--

v v C v V v v v v

3 I z o a o t O Z O Z O O Z Z Z Z Z Z X Z O 5 t T Z O Z Z t O Z Z Z Z T Z Z Z d Z Z Z Z Z Z Z VI m m m m u- m u- rn VI YI m

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h r - r - r - ~ F N N N N N N N N ~ U U - a + * < + e u f i m m m m m a g d h h r - h h h h h m h m n m m n nnnnm n n n m n m m m m n e n m r n n nnnnn n n n n m n m n m n n n n m - 7 u U W W W W w w U J w w W W W W W W W W W W U J W W U u 4 W W W W W W W W W W W w W W w W W W W W

VI N N N N N N N N N N N N N N N N N N N N N W N N - I NNNrWN N N N N N N N N N N W W N N f u hhhbh bhbhh hhhhb hhhhh hhhbh k h h h c W h b h h h h h h b hhhhh

T A B L E 6 . A N A C Y T I C A L D A T A F O R R O C K G E O C H E M I C A L S A M P L E S - - c o n t l n u e d

' SAMPLE L A T I T U D E LONG I T UO E R O C K & M I N E R A L C O D E S 5 - F E X S-MGX S - C A X S-T 1%

w P N - P Y G D Q D P M - P Y

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v v v v v v VVI *

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VI v v V v v V V- V v v v v v V v V V v V V V

C A a 0 0 0 0 0 0 ~ 0 0 o z o o o o o o o z ~ O O O O a a o a z o o o o o t c a o t a o o o o o I W N N O P l N N NFI N fUNW N W N N NNNN h ~ m c ~ W W N ~ . W N tn W ~ N N ~ V1 v v v r u v v v v v v v v v v v C v V - V v

3 o o m n a - o h m * m o o r n o o o o o o * * c o b o h o - h o h m o h U N e l N r N W l t w r ~ W h r m h W l m m N r r m r r r r C - r c O h O g r C - O O h z z c m I r

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v v v v. v v v v v v v v v v v v V v v

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m I t o 0 0 0 Z O Z Q U o o o z o D O P O O o z x z z z s x s z Z O O Z Z t o t z c a 0 0 0 ~ 3 0

VI c r r r - t r F-r t C - ~ r - r r F P r P C - - -

V V V V v v v v v v v v v v v v v v V v v v V V V

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n m m m m c - P P O P P e e m - o P Q O O O O O O D - .-.--.-F .-.---- N N N N N N O O D O E n m m n n n m n m m ~ n m n u u u u u u d u e v u U G - U - d u u u u u u u e u u O O o Q 4 W W W W W Y U W W Y W W W W U W W W W U I W W 4 U W U w u l w w w W W W Y W W W W W W w m m m m rn N N N N r u N N N n t N W r n N N N N N N N r u N W N N N N N N f U N N N n I W N N N N r u i u N N N N N

h W C h I . hhhhh h h k h b h h h h h hhhhb bhhhh h k h h b h % h h h hkP-hb

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m O WrnmmU- m m m U - @ O m m m * n m m u ' b m m m m 0 m m m m m m m n m m n v t m m m m m ~ m m m I V V V V V V V V V r V V V V V V V V r c V - V V V V V C V V - 4 *

a 0 0 0 0 0 o o o o o o o o o o o c o o c o o a o o o c o o c o o o o o o e o o c c m c o o N o o o a m a m m o m ~ ~ C Y Q O ~ b c h m h a b o a o o h o w m w m - m r - ~ h ~ aomeU- I - r W l m \ - m~ r - r r r m wt r - N r m N r - r r V r V V n .-I.-, ,-- m

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~3 - w - r r - n - m - r N N - N - N N r r t - ~ N F ~ c n - N m r r - r n v ' v V V v v v V v

s C O W - o O O ~ E O O O P ~ Q a 0 0 0 o o o o o o m o o m W O ~ O O o a o m o o o o o o I m k h r h r u o t m m o m m - a h m m o a d h o r n h m m k r m o m 0 0 , - a r n F m m h h m m

V) N F r r r - r r m n + N F F t - F

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Y D - ~ m w D r m m e m 9 h m a 0 r r u m u m 0 h m m 0 - N m U m Q h m P O r ~ m u - S r m h P

a m m m m m o m o . z - P * - * h a 0 0 0 0 0 0 o O O r c - - r r ~ r r - N N N N N N N O O O O r m m n n m r n n n m m m n n r u U U - u u ~ U - . T * U J Y V J Y J U V J q u ~ g u U O O O O < Y W W W W W W W W Y W Y Y U W W Y U I Y W W W W U J W W U W W W W W Y W W Y W W W W w b 7 m * m u, N N N m N N N N W N N N N W N N N N N N N , w N N N N N N N N W N N N N N N N N N N N N N N

hhhbh C b h h C hhhhh C h h h h hhhhh hhhhh h C h h C C f - h h , % hhhCh

T A B L E 6. AMALYKICAL O A K A T O R R O C K G E O C H E B l C l t SAMPLES--cont inued

R O C K L MINERAL C O D E S S-FEX S-MN

QD P N P W P N PN-PY

Q D Q D P N AH P N - P Y

TABLE 6 . ANALYTICAL DATA F O R R O C K G E O C H E M I C A L SAMPLES--continued

S - A S S-IU S - 0 5 - B I S - C D S - S O S - E R S-C A

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C O O 0 0 C O O X 000 0 Q O O O O 000 0 O O O W O O O O O o O O O o o 0 0 0 0 C L4 P O O V I O 000 000 0 00000 O O Q 0 00000 00000 00000 0 0 m 0 0 I U $ + m r m h h m m b m h W h b h 0 h h h r h m W h h h - h m n m h h R O O b - m b LII " h %

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b T A B L E 6 . A N A L Y T I C A L D A T A F O R R O C K G E O C H E M I C A L S A M P L E S - - c o n t i n u e d

b

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DP PN-PY DL D P AH-PY

PN-PY G D QD 66 PN

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I V v v v v v v V V v cn

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4 z x w z s 90~300 z o o o a o z x z o ~ o o b o GOOD ~ o o c o o o c z z oooam I VI N N N N N m w w m n N m w m n , m N N N N N L N ~ N ~ W NU,- m m m & m VI v V v

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u .x o o o o c O ~ O P O ornoam ~ O ~ O O O m a o n o o o o q o a o n o m o o m o o c w o e o I a , . . . . . . . . . a * . r r . , . . . . * . . . . . . . . . . . . . . . . . . * w r r r r c - - r c r - r w N + r r r - c r v r - + r - r c r - r r r r r r r -7 N - r v r

v v v v v

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h h R h h hhhhh + C h h h hhhl.h b h h h R hhhCh % C h C P - hhhhh h h h h C

a x I 9 - m a Q N N N W W e w W * d - N Y N - Q U W O Q W u Q e u N e N w u

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v v V v V

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VI V V r N r v V V + r - r r r F r N N r

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HS-PY D G - P Y V Q - P Y O G - P Y US - P Y

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m a 1 m 1 m m m m m 1 m m m a m m W I I 1 1 1 1 1 1 1 I I I I I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 8 1 1 V I V F ~ I I I I 1 1 1 1 1 1 1 1 1 1 1 1 8 1 1 1 1 1 1 1 1 1 1 8 1 *

a : 1 * 1 m m * * O I W o m * * * O I I I I I I I I l I I I I I # I t 1 1 . I l l 1 1 I I I I I U l V l V V V r l r V V V W l l l l l l l l l 1 1 1 1 1 1 1 1 1 1 I l l 1 1 1 1 1 1 1 I

L e c o o c o o o o o e o o o o 0 1 I I I I I I I I I 1 1 I I I I I I I I I I 1 1 I I I 1 1 N m m m m n m m t n w h a m o o m n~ I I I I I I I I I I I I I I I 1 1 I I I I I I I I I 1 1 I r F r r * f u r - - n

I o o o o m 000 o o m o o o z z o z Z U - X C ~ m m o o o O O Z C J W O Z Q O X z z x t z Y) -rrr.- - - + N F c r N r N r mwU r r N N N N N O N N r N

V "

B o o o o o 0 0 0 a o o o e o a e o o K Y ~ P O O c o o o o o o o o o o o o o o c o o o w I m o C a o o 0 0 0 01-"ON n 0 h m w h a h o g m a - m o O O ~ O O o o m o o O O ~ O O Y) r - r r P - v N F N - n WUN r r r r r u W r m ~ m m ~ n 0 m r r m

u a u m e m u u r n u u u a ~ m - s m u m a < < u u u m w a < w n u m m ~ . o n m m ..-.ummo o - ~ n e w ~ m - a j m m m - 0 A v m m 9 h - 0 0 0 - N n U m I c ~ N N N N w m d q ~ u m m m e b a r n a m 0 0 0 0 0 O O O O r L O D O O O 0 0 - r r F - r r r d - - - - - r r r r - r r c r r - r - + N W N N N NNNCuN E r r r r - ~ r r r - r r r F . - O W W O W 0 W W W W W W 0 W 0 U O O O W W O O W W O W W W W c w w w w w U J W W W W w w w w w m m m m m m m m m m m m s m m m m m m m m m m m m m m m m m w nnnnn n m n n n n n m n n n m m m m m m n m m m m m u t m m m m t n m n m n m m * m m m m

hCkl .C hhhhb hhhhh h h b r c k h h c h h hhhhh h h C b h h h h h r c hhhhk

TABLE 6. ANALYTICAL DATA F O R ROCK G E O C H E H I C A L S A M P L E S - - c o n t i n u e d

S A M P L E L A T I T U D E L O N G I T U O E R O C K L M I W E R A L CODES

5 5 2 3 4 1 3 1 2 8 1 D G - P Y 5 5 2 3 3 4 1 3 1 2 8 1 8 QD 5 5 2 3 3 4 1 3 1 2 8 1 8 HS-PY 5 5 24 3 2 1 3 1 2 9 2 HB 5 5 2 4 4 6 1 3 1 2 9 2 1 HS-PY

HS-PY HS-PY H S - P Y QF-PY HS-PY

QV-PY OF-PY HS C D H S - P Y

5 5 1 9 0 1 3 1 2 7 2 9 G D 5 5 1 9 2 7 1 3 1 2 5 50 HS-PY 5 5 1 9 2 7 1 3 1 2 5 5 0 . MS 5 5 20 1 7 1 3 1 2 3 48 HS 5 5 2 0 3 5 1 3 1 22 54 H S

5 5 2 0 4 4 1 3 1 2 2 54 M S - P Y 5 5 2 1 2 1 3 1 2 2 58 HB 5 5 2 2 2 4 1 3 1 1 9 50 , M S 5 5 2 2 5 1 1 3 1 19 1 9 V Q ' 5 5 2 3 2 3 1 3 1 19 2 9 M S

5 5 2 9 2 1 3 1 1 8 t HV 5 5 29 2 1 3 1 1 8 1 D G 5 5 3 0 1 2 I 3 1 18 29 QH 5 5 3 0 5 1 1 3 1 1 8 3 8 HS-PY 5 5 32 9 1 3 1 19 5 0 HS

, 75BG289A 5 5 3 2 3 5 1 3 1 2 0 4 QF-PY 7 5 0 G 2 9 1 A 5 5 3 3 5 5 1 3 1 2 0 7 HE-PY 7 5 0 6 2 9 3 8 5 5 3 4 2 4 1 3 1 2 0 16 H S - P Y , 7 5 8 ~ 2 9 6 ~ 5 5 3 5 2 1 1 3 1 20 4 4 QF 7 5 B G 2 9 6 8 5 5 3 5 21 1 3 1 2 0 4 4 A H

m 2 zrzzz O Z Q ~ Z t o o t z o o o z z z r t x z z x z z o Z Z E Z Z x z z z z ~ z z z t 4 VI N N N N N N N

Y)

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m 1 1 1 1 1 1 1 1 1 I l 1 l 1 1 1 1 1 1 1 1 I I I I I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 t w 1 1 1 1 1 1 1 1 1 1 I I I I I 1 1 1 1 1 l l l l l 1 1 1 1 1 1 l 1 1 1 1 1 1 1 1 I 1 1 1 1

m u m u 4 u e e m a u < u m < w O - r u m r n m e - 7 m a c e - 2 - ~ r - r F - . - - - N u u u v e NNNNN N N N N N W N N N ~ € w w w w o W U O W O W O O 0 0 c m m m m m m m m m m r n m m m m rn m m m m v ~ v ~ m m m m m m m n m

b b h h f . h h h b h hhhhh

4 u m u 4 0NNVI.Q m m m m * N N N N N w w w w w m m m m m m m V I V I V I hhhhh

< u < - u a < = < * h @ U m . Q h m P O , % m v r . O Q a Q Q S h h N N N N N N N N r u m O I l O W W W U r 1 0 0 m m m m m m a m m a , Y I m Y I m m VlYIYIV lVI h h b h r c b h h h h

u u u m u * l * r - h O . h h l c h r c rYNNNN u w m w w m m m m m V IY ImVIY I r s l c t c h t c

d m e a u u u m u a - . - u m r p *r--i.Q.Q

o 3 m m m m W P O . P * NrU.ZINr., N N r u m m C ? W W W W W ~ U O ~ m m x m m m m m m m I F \ ~ ~ V I V I V I V I ~ V I ~ l c r c t c h h h h r - h r c

a NNNNN mJrurUNN N N N - N WNNNru NNrnNN ruNNNN NNNNnl NWr"NN WNNNN r m o w 0 0 w w u w m u m w m u w * m a w W O W O W w w w w w w w w w w m w o w w w w w - 0 4 m m m m m m m m m m m m m m m m m m m m m a m m a m m m m m m m m m m m m m m m m m m m m Ln mmmm". m m m m m m m m m m " . m a m m b - . m m m m m m B n m l A m . A * m m m m m m m m m m m m

h h h h h h h h L L * h h h h L L h h L C h h h h hhhhh k h h h k h h h h h h h h b h

T A B L E 6. A N A L Y T I C I L D A T A F O R R O C K G E O C H E M I C A L S A N P L E S - - c o n t j n u e d

SAMPLE LATITUDE LONGITUDE ROCK 8 MIHERAL C O D E S S - F E X S - M G X 5 - C A X S - T I %

7 5 8 6 3 2 4 1 5 5 2 0 2 6 1 3 1 I S 3 4 G S 7 5 0 G 3 2 4 8 5 1 2 0 26 1 3 1 1 5 3 4 O G 7 5 8 6 3 2 4 C 5 s 20 2 6 1 3 1 I 5 3 4 HS-PY 7SBG329A 5 5 2 1 11 1 3 1 1 6 27 G 8 7 5 B G 3 3 3 1 5 5 2 2 b 1 3 1 16 5 8 HS-PY

7SBG335A 5 5 1 7 3 5 1 3 1 1 6 50 HS 750G335C 5 5 1 7 3 5 1 3 1 16 5 0 D G - P Y 7 5 8 6 3 3 7 A 55 1 8 20 1 3 1 16 23 G D 75BG338C 5 5 1 9 0 1 3 1 16 0 D F 750G339A 5 5 19 6 1 3 1 1 5 26 D F

75BG341A 5 5 1 9 4 7 1 3 1 1 5 7 G D 7 5 8 6 3 4 1 8 5 5 19 4 7 1 3 1 1 5 7 G G 758G341C 5 5 19 4 7 1 3 1 I S 7 QF 7 5 6 6 3 4 2 1 5 5 19 5 8 1 3 1 1 5 7 Q F - PY 75BG343A 55 20 J 1 3 1 1 5 1 7 HS-PY

v Q Q F - P Y QV-PY

-PY HS-PY

HS-PY H S QF Q F - P Y M S - P Y

- z o o m o o O Z O O Q ~ Z O O D tztzt o o z x o o r 0 0 0 o o o o o O O O ~ O Q O O D O I Nn m h 0 rhlh N O * r r h m m g h N h W O m W b m n o o n h Y I

Y) r - r r h v

0 0 0 0 0 o a ~ c o n CIN N

O P m O O r n F Y I

I I I I I I I I I I

I I I I I 1 1 1 1 I

1 1 1 1 I I I I I I

.Q 4 I I I I I I I I I l I I I I I I I I I I ' I I I I I I I I I I I I 1 1 I I 1 I I I 1 1 l l O m 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 0

W I 0

m I 1 1 1 1 1 I I I I I 1 1 1 1 1 1 1 1 1 1 1 1 1 8 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 m V) 1 1 1 1 1 I I I I I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 l l l l "

3 u 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I I I I ~ I I I I I I . I I I I I I I I I I I I I I I I I I I I I I I I I I I 1 I I I I I I I I l l 1

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u u m e e c m m c c c m u r u U V ~ U U u m u u u w onnrnh m m r - ~ u u - m n m m h m P - 7 - N m A w o o o o 0 0 - W N N N F U N ~ n n W m n u * - r u v o n n m m n n n n m n n n n m m n n n n m n n m m m x w w a w w U W U U W w C . o w 0 w'swum w - w w w - m m m m m m m m m m m m m m m m m m m m m m m m m rn 4Aw,w."-.m VI*mm"-, &nmmmm Y IY Im-m m m - m *

khhhh h C h h b bbbhh bhhhh hhhhh

< m u < < .J w - * m u . r * u w n n m m m w w w u w m m m m m VIVIYIVIYI h k h b b

m u o U J * m c o m m * * u u * * n n m n n W W W O W m m m m m mVIYImw. hhhhh

U U < U U p w m + o h YI9 .09 .Q nnnnn OLaWWW m m m m m rnYIYImLn hhbhh

I TABLE 6. A N A L Y T I C A L O A l A FOR ROCK GEOCHEMIChL SAMPLES--continued

L SAMPLE LATITUDE L O N G I T U D E ROCK g M I N E R A L C O D E S S-FEZ 5 - M G X S - C A X S - T I %

) 7 5 8 U 1 9 1 B 5 5 2 0 4 1 1 3 0 5 8 1 9 PM-PY 7 5 0 U 1 9 1 D 5 5 2 0 4 1 1 3 0 5 8 1 9 PH-PY 7 5 8 W 1 9 2 C 5 5 24 1 5 1 3 0 32 52 6 0

8 7 5 0 U 1 9 3 0 5 5 2 5 31 1 3 0 29 1 4 QD 7 5 0 U 1 9 3 D 5 5 2 5 3 1 1 3 0 2 9 1 4 DQ

7 5 8 U 1 9 4 A 5 5 2 5 3 1 1 3 0 2 7 3 3 Q D ,

7 5 B U 1 9 5 A 5 5 2 2 4 1 3 0 29 39 7 5 8 U 1 9 6 A 5 5 2 1 2 6 1 3 0 31 36

5Q Q D

7 5 8 U 2 0 2 A 5 5 1 7 2 1 1 3 0 2 6 9 P H 7 5 E R O 4 8 A 5 5 44 3 5 1 3 1 50 12 HS-PY

QF-PY PN DQ QO DL

G R GR G R GR-MO G O - P Y

P N PN-CP ,PY D G QM-PY HS-PY

H V MU GS-PY QF-PY H S - QD-PY Q1.I R S - PY C S C S - P Y

G S - P Y M V - HS - PY HS - PY HS-PY

I c I I I I I I I I l I I I I I I 1 1 1 1 1 I * I I I I I ~ I I I I I I I ~ I I I l l 1 1 I I I I I VI I I t I t I t t t I I ' l t I I I I I I I . l . ~ I I I 1 . I I I I I I I I I I I I I I ( I # # ) t

i P I I I I I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 4 4 1 1 1 8 1 1 1 1 1 1 1 1 1 I I I I I I l l l Q I I l l 1 1 I I I I I ( 1 1 1 . 1 I I I I I I I I I I I I I I I I I I I I I I I I I I I 1 I ) r ) e

u u m u * U C D L Q C U u m u a a LU O n W m w Q m - r N u u u - n d 0 0 0 0 u 0 0 . - N N N W N N W a n n n n m nnnp-,n nnnnn r w w 0 0 0 W W O W W W W W W W a m m m m m m m m m m m m m m m UY mmu-,mm m m m m m - m m * m

h b h h h h h h h h h h & + k

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1 C *

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m u n w u g l a 3 m m p u u u u u n n n m y l w w c ' w w m m m m m Y ImVIV lm h h h h h

u c c m u 0 - N N U m u - m m m n m n m n U O W W O m m m m m m m V I m u - k h h h h

4 u < u a * V Y I O t . u l . Q Q Q Q n m n n m W U U W O m m m m m VIVIrnVIVI h k h h k

- I . -

m 0 0 0 0 m 0 2 0 0 0 - o a a - 0 0 0 - a o a o a o o o o o o o o o o o o o a c o c o o a m & F N ~ N - VI w m N -nnNr N h h - m m n m m r r ~ m r r r m - r - r r N r r r r t - m - I v v v V

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V, N r r - m 2 2 0 ~ 0 t t X t Z Z 2 0 2 0 z t o o 0 0 O O O O Z Z Z S Z Z Z t Z t P c z o o z t 2 2 Z Z I N N N m N W W N P - I NNPIN n rum

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V a - u 0 0 0 0 0 O O T Z Z ~ 2 0 0 0 O O Z O ~ o o o o z o a o t o o o o o o o o o o o o o o o o r I d t m o a h OVr m o m O D 0 r--7 h r ~ n o a m n o h N m o h h000ln LY V ) NF r r N- r*? N V V V V V I N r r V I N C r I u 0 UJ 0 0

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I I I I I I I I 1 1 1 1 1 1 1 l I I t 1 1 1 1 1 4 YI

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m u m u m rsl m r - n r r c 2 O m N N m e ----.- € 3 3 1 3 3 4 m m m m m VI V I n m m m

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A l a m u s 1 I t 1 1 1 + t 1 1 1 1 1 1 1 1 r n m n a ~ 1 1 1 1 1 1 1 t t t 1 1 1 1 1 1 1 1 1 1 u 1 0 m w 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 v v - I 1 1 1 1 1 1 1 1 1 1 I I I I I 1 1 1 1 1 1 N

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v r v C V

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W m 0 0 0 0 0 O O D O O 0 0 P moo00 O O D O O 0 0 I o m n r m n m - m m N I I I I 1 1 1 1 1 1 1 1 8 1 1 8 1 1 1 1 1 1 1 1 I I I N I 1 1 1 1 1

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I YL I

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w w m r - h 9 ~ ~ h h C U C J P ~ o u q u 0 Q ~ q u n m o m m h - r r O O O d h m - N ~ O P P a nnn N N - . ~ - m m .- n u u e ~ e n q u w m n a - r ~ w w n n m r u m m - n n

0 2 r r - r r - - r - r r r r r r - - - P - C - C F C - C ~ ~ ~ F C - ~ C c c c c c C - C - c

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.,- 5 c1 A 0 0 0 0 0 Q O O O O 0 0 0 0 0 0 0 0 D O D O O O c P D O O o O O Q D O O O O O O O O D O O c I m m m m m m m n m m m m m m m m m m O m m m n h n m ~ m m m m m n n v r ~ V I V I ~ N w m m n ~

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4 u 4 4 4 a m m o - S Q Q I C h Q Q . Q Q . Q x x x x x n c C = = a z P : b h h h h b h C h C

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C A O O O P O 0 0 0 0 0 0 0 0 0 0 m o o ~ o D O 0 0 0 ODao- 0 0 0 0 0 0 0 0 0 0 O Q O O O t w m m o n m m m b m h m m m m m m h m n m m m m * m m w m m m m h m m h m n m m n m m m i n ur V r

0: z z o o o O O O O Q c a a z z t o r n o a x Z O O C J Z z z o o o o z ~ z t 0 0 0 0 0 P O O O O

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v V v v v N V v V r v V V V v - - V v

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V Q - c V V V u v u r c r V I

3 00000 00000 0 0 O D O O D O O W O O O O O 0 0 0 0 0 O O o o O O D O W 00 O m I O O Q O O m o o m o ~ n ~ m m o m 0 0 0 ~ ~ O Q O r a - - r orornu- a m r r w W N N N r - f 4 W r N N n - n r r V r r r V F V V V r v - F N N V N V

* 0 0 0 0 0 O O Q D O 0 0 0 a 0 O O O O O 00000 O O X Z Z O Z P O P 0 0 a a 0 0 0 0 u3 0 0 0 0 0 O O O W O O O O O Q O D O O W 0 0 0 0 0 0 0 0 9 0 0 0 0 0 0 PC! 0 0 I m m n w i n N W I M ~ N n o o a o m ~ h h o r m m m o m a k m o w m m m n h~ a h YI C . * * . I . * . .

U w o a o o m m o a m o o m m m m o o o o o h a o m o w o m m m o m o m r n o o h z m o - o z ~ I m N N N r v n N r W N r r r r v V F V V V N * r N N v m v n VI

m u - u c a e u u c IU m c - a r m m e m a * A - . - N N N N N W N W a m m o a ~ m m m c o m m t Y Y X Y X X X Y X X u a a m a a a e a a ~ m hfihhh hhhhh

bhhhb hhhhh

m m w m c a m m * m r n m m m m w 4 9 m r n m x x x x x X X X Y X X X X X Y x x x x x a a a a m ~ m 4 a ~ ~ a a g g a a e - u hhhhh hhhhh hhhhh hhhhh hhhhh hhhhh hhhhh hhbhh

m c * c c c u m m u 4 4 U C U r u v l Q Q h W N - O O r U l t U O r m m 4 n e Q O - r m N N m F l m Q a m m m m 0 0 0 0 0 o o o o a X Y Y X X r 5 l i a I Z S t f z E a g o e a ~ m e - e e a a a a hhhhh hhhhh hhhhh hhhhh hhhhk +hhhh

9 TABLE 6. R M A C Y T I C A L D A r A F O R R O C K G E O C H E M I C A L SAMPLES--continued

SAMPLE L l T l T U D E L O N G I T U D E R O C K B M I N E R A L CODES S - F L X S - R G X S - C A X

m o o a ~ o oooorn o o o o o , o ~ o ~ o a w o a o woomo o o o o o omao P r r ~ r r r r r r r r N r N r t r r r ~ r ~ m ~ m N f r r f C P ~ V P r - ~ r

I v v V v v v v v v v V V V V1

rn z O O O O O O O Q O O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 aaoraca O O O O P 0 0 0 ~ 1 NNNNN N N N N N NNNNN NNNNN N W r U N N N W N N N N r n N N N N N N N

V1 v v v v v v v v v v V V V V V v v v v v v v v v v V V V V V v v v v v v v v v

Z O O Q O 0 0 2 0 0 a 2 2 0 N O ~ Q r m mru o m

J W u Z '? Y999Z 9 9 9 9 9 9 9 3 9 9 9 , 9 9 3 9 9 9 , : 9 9 9 9 9 9 9 3 9 9 9 9 , : C k9 r r r - r N v r ~ r - r v - r C F ~ r - r F C C R N P C P C C ~ P C F

v V V v v v v V V V V V

c o o a o a O P O O P O P O O O oooam O Q O O O O O O P O o o o o o ~ O O P m opoom o a o o o o o o o o o o o o o ooomo o n o o m o o o o o o o o a

Y I ~ N D ~ V h m m m o m m r m m m r m m n m m n o a omv N ~ N O C nomn A n * 8 S b . . * * * * * b s 8 * s * 8 s m P C C - c c F r C C r F - F N - r r C C

a

m I o o o o o oacaoa o o o o o o a o c a oocawo o o n o o o a o o o o o a o

WI c r c r r r m N r r V v r r r r v r r r C P C F F r - v N v - ~ c c - r rc r v v V V V V v v v v

C 4 4 U 4 4 4 4 u 4 u 4 < u u < 4 4 C U 4 4 4 4 C 4 4 * C 4 4 4 4 u u U U U U Y Q m t - m m P - m m U a v U m m * m a * = O l n Q O F UQhDWl m h m ~ - e W N h 4 hkm*P 0-Nmn n - u v u m m d n m e h - m r n m m m m m m e e a a 0 0 . - m O O D 0 0 0 - t r r - r r r ~ ~ - r - - r - 4 q Q 9 90*9* Q - 9 0 m t a I 5 t a I t T T X P t ~ L ~ € E L S F L T T - , 7 - B l - B - 5 - 3 - , - , 7 1 1 7 7 - 7 7 1 - a a a a e ~ L ~ C L X a a e e e a ~ e e a e m ~ w m w m w m w n v r m v r n m m m w WY hhhbh h b h h h h k h h h hhhbb k k h b h h h h h h hhhhh h h h h

hhkhh hhhhh hhhhh hhhhh *hhhh h h h h h hkf.kk C C h h

0 I I c 1 1 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 t 1 1 1 ( 1 1 1 1 1 1 1 1 1 1 vr 1 - 1 1 1 1 I l l ( - I I I I I I I I I I I I - I l l 1 I I , I I I I I I I I I I I I a

I m n m m m m m 0 0 0 0 0 E m m m m m m o I n 0 r n O P 0 D m O O 0 0 0 m 0 l n o o m o m I V V r r r r r r r r r r r r r r r r r r P rrr - ,

* 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 O O O O O O O Q O O O O O O r m m h h - o o o m m N - % ~ o m m r n ~ o I f r - r " ~ ~ " ~ Ce T V F r 8 - r

- b o o m o o m o o m m n m

VY

t I o o n 0 0 0 0 00 o o o w o o o o o o o o o o o o o o ca o o o o m o m o cn N w r ~ r n r d N s - m r ~ N n r u r r u V N N N ~ r N t c N ~ F N - N - N

v v

> O O O Q O O D 00 0 0 0 0 0 O O O O O 0 0 0 0 0 0 0 0 D O O O O O 0 0 O I o m a m * n o 00 h m o m h h o m m ~ R ~ c O N C O O O m h ~ n n m h 0 Y) - m n - + - n .-- m *I.--v n m n N w F - c

. - - - - . . - - - - - - - - - - - - - - .~ - . -~ - . . cn hhhhh hhhhh hhhhh hbhhh hhLhh h h h L h h h h h i hhhh