An Outline? Animations Pasting figures Using Color Text! Molecular orientations.
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Transcript of An Outline? Animations Pasting figures Using Color Text! Molecular orientations.
An Outline?An Outline?
•Animations
•Pasting figures
•Using Color
•Text!
•Molecular orientations
H
B
HHHBH4
(in solution)
N N
N N
B N NH M
persists downto -85 oC(Tp*ZnBH4)
AnimationsAnimations
• molecular motion
AnimationsAnimations
• molecular motion
• reactions (wipe)
reactants products
• animations between slides
N O F NeB C
He
P S Cl ArAl Si
Ammine-borane Ammine-borane
ethane(g)
C C
H
HH
H
H
HC C
H
HH
H
H
H
N O F NeB C
He
P S Cl ArAl Si
Ammine-borane Ammine-borane
ammine-borane(s)
B N
H
HH
H
H
HB N
H
HH
H
H
H+
-
+
-
THFNaBH4 + NH4Cl H2 + BH3NH3 + NaCl
Ramachandran, P. V.; Gagare, P. D. Inorg. Chem. 2007, 46, 7810-7817.
AnimationsAnimations
• molecular motion
• reactions (wipe)
• animations between slides
• progressions in busy slides
N N
B N NH K
N
N
NNH
O
PEG
a,ba,b
c
d,e d,e
f,gl
f,g
h,i
h,i
j,k
j,k
……but will it…but will it…
• …bind nickel(II) effectively,
and then…
• control nickel(II)-cysteine properties,
• select for His6-proteins,
• facilitate reversible nickel(II)-NH3,
• and stabilize nickel(II)-BH4?
N N
B N NH K
N
N
NNH
O
PEG
a,ba,b
c
d,e d,e
f,gl
f,g
h,i
h,i
j,k
j,k
Scorpionate Scorpionate attachedattached
N N
B N NH K
N
N
NNH
O
PEG
a,ba,b
c
d,e d,e
f,gl
f,g
h,i
h,i
j,k
j,k
……but will it…but will it…
• …bind nickel(II) effectively,
and then…
• control nickel(II)-cysteine properties,
• select for His6-proteins,
• facilitate reversible nickel(II)-NH3,
• and stabilize nickel(II)-BH4?
An Outline?An Outline?
•Animations
•Pasting figures
•Using Color
•Text!
•Molecular orientations
Pasting FiguresPasting Figures
• transparent background
• device independent bitmapA cool biochem article.Click here.
Using ColorUsing Color
• be judicious, maximize effect
• for specific emphasis
0.0
0.5
1.0
1.5
2.0
2.5
3.0
300 400 500 600 700 800 900 1000 1100
wavelength (nm)
abso
rban
ce
NNB
NN
NN
H
SNi
H2N
CO2Et
O(CH3)3
NEt3H3C-NEt3
+
+
NNB
NN
NN
H
SNi
H2N
CO2Et
SolventCH3
An Outline?An Outline?
•Animations
•Pasting figures
•Using Color
•Text!
•Molecular orientations
Using ColorUsing Color
• be judicious, max. effect
• for specific emphasis
• to connect ideas
H- + H+ H2
Using Color – colored backgroundsUsing Color – colored backgrounds
Better off with light fontsBetter off with light fonts
pasting figures on dark backgrounds
Mg(BH4)2(NH3)2(s)
Soloveichik, G.; Her, J. –H.; Stephens, P. W.; Gao, Y.; Rijssenbeek, J.; Andrus, M.; Zhao, J. -C. Inorg. Chem. 2008, 47, 4290-4298.
original report: Konoplev, V. N.; Silina, T. A. Zh. Neorg. Khim. 1985, 30 (5), 1125.
m.p. 94 oC
Mg
NH3
NH3
H
BH H
H
H
BH H
H
• N-H…H and B-H…H parameters comparable to BH3NH3(s)• endothermic H2/NH3 release vs BH3NH3(s)
TEXT!TEXT!Click to add subtitle.
TEXT!TEXT!
• short, sweet, bulleted lists
Logical flow: Great science poorly presented is diminished. A complete talk usually begins with background, leading into the presentation of pertinent results, and followed by the important conclusions that can be drawn from those results. Background information must give context for the work. Why is this work important to the chemical community or the greater world? What problem(s) is this work addressing? It should describe any experimental techniques or methods that might not be common to the experiences of a typical chemist or your particular audience. Pertinent results should be presented in an organized manner, including clear spectra or summary tables. A running outline is one way to maintain organization during a talk. Plan smooth transitions between a slide just presented and the next one about to appear.
A complete talk
• background, results, conclusions
• Why important? Problems addressed?
• novel techniques described
• clear spectra, concise tables
• effective transitions
TEXT!TEXT!
• short, sweet, bulleted lists
• avoid reading long slides
• concise tables
Sørensen, R. Z.; Hummelshøj, J. S.; Klerke, A.; Reves, J. B.; Vegge, T.; Nørskov, J. K.Christensen, C. H. J. Am. Chem. Soc. 2008, 130, 8660–8668.Christensen, C. H.; Sørensen, R. Z.; Johannessen, T. ; Quaade, U. J.; Honkala, K.; Elmøe, T. D.; Køhler, R.; Nørskov, J. K. J. Mater. Chem., 2005, 15, 4106 – 4108.
Ca(NH3)8Cl2 9.8 0.116Mn(NH3)6Cl2 8.0 0.112Mg(NH3)6Cl2 9.2 0.115Ni(NH3)6Cl2 7.8 0.119
mass% H kg H/L
M
H3N
H3N NH3
NH3
H3N
NH3
X
X
incr
easi
ng T
des
• pellet 95 – 99% of crystalline• nanopores facilitate NH3 transport• heat transport controls NH3 loss
Orientations of moleculesOrientations of molecules
+
+
Orientations of moleculesOrientations of molecules
+
+
minimize changes fromone slide to the nexteasier to follow