amines

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1.Which of the following can undergo Hoffmann reaction most easily? 1 ) 2 ) 3 ) 4 ) 2.The correct order of decreasing base strength among the amines given is 1) III>I>IV>II 2) IV>III>I>II 3) I>IV>III>II 4)I>III>IV>II 3.Which of the following reaction can produce aniline as the main product? A) B) C) D) 4. Which will give positive isocyanide test 1) 2) 3) 4)

description

amine organic chemistry

Transcript of amines

1. Which of the following can undergo Hoffmann reaction most easily?1)2 CONHX2)2 CONH3 CH3)2 CONHCN4)2 CONH3 OCH2. he correct order of decreasing !ase strength among the amines gi"en is 2 NH#$)2 NH#$$)2 NO#$$$)3 NHCH#$%)2 NH3 CH1) $$$&$&$%&$$ 2) $%&$$$&$&$$3) $&$%&$$$&$$ 4)$&$$$&$%&$$3. Which of the following reaction can 'roduce aniline as the main 'roduct? ()) * 2C H N+,n - .+H +/)) * 2 4C H N+,n - NH Cl +C)) * 2 4C H N+0i (l H +1)) * 2C H N+2n - HCl +4. Which will gi"e 'ositi"e isocyanide test 1)C H3CH3NH22)C H3NHCH33)C H3NH CH34)C H3NCH3CH3*. (n organic com'ound u'on hydrolysis 'roduces two com'ounds one 'roductga"e sil"er mirror test3 other 'roduct reacts with Hins!erg reagent to 'roduce anal4ali insolu!le 'roduct. he organic com'ound is 1)3 2 355OCH CH C NHCH 2)HCO3 CHN3 CH3)3 NH C 2 CH 3 CHO4)C2 CH3 CHOHNH). he $67(C name of OCNis1) 28methyl838#18methylethyl)848o9o'entanenitrile2) 48cyano:38#18methylethyl):2:'entanone3) 38acetyl:2:cyano:4:methyl'entane4) 3:ethanoyl:2:methyl:3:#1:methylethyl) 'entanenitrile;. (cid strength of the cont gi"e

2 CHOH$2 CH$$

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$%OH%1) $3 $$3 $% 2) $$3 %3 $ 3) $3 $$3 $%3 %4) $$$ only